FIITJEE – CM Monthly Test-1

PHYSICS, CHEMISTRY & MATHEMATICS

Pattern -1 QP Code: PAPER - 1

Time Allotted: 3 Hours Maximum Marks: 183

 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall befor e the end of the test.

INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCHES –2022

A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. All the section can be filled in PART-A of OMR.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.

B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.

C. Marking Scheme For Only One Part.

(i) Part-A (01-07) – Contains seven (07) multiple choice questions which have One or More correct answer.
For each question in the group Q. 01 – 06 of PART – A you will be awarded
Full Marks: +4 If only the bubble(s) corresponding to all the correct options(s) is (are) darkened.
Partial Marks: +1 For darkening a bubble corresponding to each correct option, provided NO incorrect
option is darkened.
Zero Marks: 0 If none of the bubbles is darkened. Negative Marks: 1 In all other cases.

(i) Part-A (08-14) – Contains seven (07) multiple choice questions which have ONLY ONE CORRECT answer
Each question carries +3 marks for correct answer and -1 marks for wrong answer.

(i) Part-A (15-18) - This section contains Two paragraphs. Based on each paragraph, there are Two multiple
choice questions. Each question has only one correct answer and carries +3 marks for the correct answer
and -1 marks for wrong answer.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
2

S
SEEC
CTTIIO
ONN--1
1 :: P
Phhy
yssiic
css
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE OR MORE may be correct.

1. Two charged spheres are kept at a finite centre-to-centre

spacing as shown in the figure. The force of electrostatic
interaction between them is first calculated assuming them
point like charges at their respective centres and then force is
measured experimentally. If the calculated and the measured
values are Fc and Fm respectively, which of the following
conclusion can you certainly draw?
(A) If Fc > Fm for like charges and Fc < Fm for unlike charges, both the spheres must be
made of insulating materials.
(B) If Fc > Fm for like charges and Fc < Fm for unlike charges, both the spheres must be
made of conducting materials.
(C) Irrespective of their materials, Fc < Fm for like charges and Fc > Fm for unlike chares.
(D) Irrespective of their materials, Fc > Fm for like charges and Fc < Fm for unlike charges.

1. D
Sol. In case of like charges, charges gets repelled and hence measured value is lower than
the calculated value.

2. Two equal point-like positive charges A and B are y

fixed on the y-axis equidistant from the origin. What A +

can you say for the net electrostatic force on a small C

electrically neutral conducting rod placed on the x- x

axis as shown in the figure? B +

(A) Not force at all (B) It points away from the origin
(C) It points towards the origin (D) Information is insufficient

2. D
a
Sol. Electric field increases till and then decreases. Hence, it is very essential to specify
2
the location of rod.

3. In another world, instead of the Coulomb’s law, electric force F on a point like charge q
due to another point like charge Q is found to obey the following law.

F

Qq 1  ar r
4 0r 3

Here, a is a positive constant and r is the position vector of charge q relative to the
charge Q.
Q(1  ar )
(A) Electric field due to a point charge Q is E  r
40r 3
(B) Line integral of this electric field  Edl over a closed path is also zero as in our
world.
qenclosed
(C) Gauss’ law  E  ds  0
also holds true for this electric field.
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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(D) All the above statements are true but this electric field is not conservative.

3. AB
Sol. This is conservative electric field as there are terms only of r in the direction of r.

4. Each of the following figures shown electric field vectors at two points A and B in an
electric field. In which figure or figures can the illustrated field be created by a single
point charge?

(A) A (B) A
B B

B
(C) (D) B
A
A

4. AC
Sol. Magnitude of electric field is represented by length of arrow.

5. Salt water contains n sodium ions (Na+) per cubic meter

and n chloride ions (Cl–) per cubic metre. A battery is
connected to metal rods that dip into a narrow pipe full of
salt water. The cross sectional area of the pipe is A. The
magnitude of the drift velocity of the sodium ions is VNa and
the magnitude of the drift velocity of the chloride ions is VCl.
Assume that VNa > VCl and e is the charge of proton, then
(A) Magnitude of the ammeter reading is enAVNa – enAVCl
(B) Magnitude of the ammeter reading is enAVNa + enAVCl
(C) mobility of Na+ > mobility of Cl–
(D) mobility of Na+ = mobility of Cl–

5. BC
Sol. Mobility is inversely proportional to mass.

6. An air-filled parallel palate capacitor with the plate area A is

connected to a battery with an emf V volt and negligible
internal resistance. One of the plates vibrates so that the
distance between plates varies as d = d0 + a cos t (where a
<< d0). The capacitor breaks down when the instantaneous
current reaches to the value of I. Choose the correct option(s).
Id02
(A) The maximum possible amplitude vibrations “a” is .
VA0
2Id02
(B) The maximum possible amplitude vibrations “a” is .
VA0
0 VaA
(C) The instantaneous current in circuit is sin t .
(d0  acos t)2
0 VaA
(D) The instantaneous current in circuit is sin t .
2(d0  a cos t)2

6. AC
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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0 A
Sol. C
d
dc dc dd A
    0 (aw sin wt)
dt dd dt d2
 Awa
= 0 2 sin wt
d
dQ dc
Q = CV ; i  V
dt dt
V 0 Awa
 I= sin wt
d2
d2
 a
0 A sin wt
1d2
amax 
VA

7. There is an infinite wire grid with regular

hexagon cells. The resistance of each wire
between neighboring joint connections is equal
to R. Choose the correct alternative
2R
(A) Equivalent between A & B is . A
3 C
B
(B) Equivalent between A & C is R.
(C) Equivalent between A & B is R.
2R
(D) Equivalent between A & C is .
3

7. AB
Sol. Using principle of superposition.
2I 2R
VAB = I Req = R  R eq  .
3 3
 1 1
VAC = I Req = 2    R  Req = R.
3 6

(Single Correct Choice Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

8. Two large identical plates are placed in front of each

other at x = d and x = 2d as shown in figure. If Q -5Q
charges on plates are Q and -5Q, the potential x
versus distance graph for region x = 0 to x = 0 3d
3d is (d is very small and potential at x = 0 is v0) d 2d
V V V V
v0 v0 v0
v0
(A) (B) (C) (D)
x x x x
d 2d 3d d 2d 3d d 2d 3d d 2d 3d

8. D
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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4Q 2Q
Sol. Slope of potential from x = 0 to x = d is  
20 A 0 A
3Q
Slope of potential from x = d to x = 2d is 
0 A
2Q
Slope of potential from x = 2d to x = 3d is
0 A

9. In the above circuit, find the potential difference 8f 8f

P A
across AB.
10 1 3
(A) 10 V (B) V 8f
4 8f
3 10 V 2
10
(C) V (D) 2 V Q B
4

9. D
Sol. Let us mark the capacitors as 1, 2, 3 and 4 for identifications. As is clear, 3 and 4 are in
series, and they are in parallel with 2. The 2, 3, 4 combine is in series with 1.
C .C
C34  3 4  4f, C2,34  8  4  12f
C3  C4
8x12
Ceq.   4.8f, q  Ceq. V  4.8x10  48C
8  12
48c
The `q’ on 1 is 48 C, thus V1=q/c=6v [v1 =  6v ]
8F
 VPQ = 10  6 = 4V
By symmetry of 3 and 4, we say, VAB = 2V.

10. Charge Q is given to the upper plate of an isolated parallel plate capacitor of Q
capacitance C. The potential difference between the plates
Q Q Q 2
(A) (B) (C) (D) zero
C C C
2

10. C
Sol: In general, for charge Q1 and Q2on upper and lower plate respectively the charge
distributions on outer and inner part of the plates are shown in figure.
Here Q1 =Q, Q2 = 0
Q Q1
 Charge on inner side of plate are Q1+Q2
2 2
and Q1Q2 (Q1Q2)
Q 2
 respectively. Q2
2
2 Q1+Q2
Q 2 2
Hence V =
C
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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11. For the circuit shown, all wires have negligible resistance, the
battery has a constant internal resistance of r = 8.0  and the two
light bulbs (B1 and B2) are identical, each with resistance Rbulb.
The variable resistor is initially set R = 26.0 . The switch S in the
circuit now is closed. To what resistance must the variable resistor
be set if bulb B1 is to have the same brightness after the switch is
closed as it did with the switch open?
(A) 9.0 
(B) 13.0 
(C) 16.0 
(D) The answer can be computed only if the bulbs resistance Rbulb
is known.

11. A
Sol. Before switch is closed.
 
 V 1
Power of B, P1    RB
 8  R  RB  4
 2 
P1  P1
1

V 2RB V2 RB
 
(34  RB )2
(8  R  RB / 2) 4
2

 (34 + RB)2 = (16 + 2R + RB)2

 34 + RB = 16 + 2R + RB
18
 R   9
2

2E
R
12. In the circuit shown in the figure, I1, I2, I3, I4 denote 2R
current in the branches. Choose the correct option. I1
R E
(A) I1 > I2 > I3 > I4 E R
(B) I1 = I2 > I3 > I4
(C) I1 < I3 < I2 < I4 R I2 4R
(D) I2 < I1 < I3 < I4

I3 4E

3R I4
13E

12. D
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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Sol. Through AB 2E
E E
IAB = ; IAGF 
R R R
A B
E E G
IBC  ; IDC  2R
R R R R E
Loop ABCD, E
E E E I1
2R   R  4R   1, R  0 F
D C
R R R I2 4R
E
 I .
R I3 4E
E
In AFD, E – I2R –  R = 0.  I2 = 0. 3R 13E I4
R
E
Adjunction D, I2  I1   I3 = 0
R
E 2E
I3 = I1  
R R
13E – 3RI4 – 4E = 0.
9E 3E
 I4 = 
3R R
 I4 < I1 < I 3 < I4

13. Eight identical resistances r, each are connected along edges of O

a pyramid having square base ABCD as shown in figure. The
equivalent resistance between A and D is
2r r B C
(A) (B)
15 15
4r 8r
(C) (D)
15 15
A D

13. D
Sol. The circuit can be represented as C1 O C2 B C2 C
r
So we can arrange the circuit in following way
2r
1 1 1 1
    O
r r
Re q 2r 2r r
2r  2r
3 A C1 D r
3 1 1
=  
8 r 2r r
8r
Req =
15
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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14. A parallel plate capacitor is connected with a resistance R and a v

cell of emf  as shown in figure. The capacitor is fully charged.
Keeping the right plate fixed, the left plate is moved slowly
towards further left with a variable velocity v such that the current R
flowing through the circuit is constant. Then the variation of v with
separation x between the plates is represented by curve


v v v v
(A) (B) (C) (D)

x x x x

14. B
0 A x
Sol. q  C   IR     IR  … (i)
x
 0 A  IR  R
x … (ii) 
q I
On differentiation of equation (ii) and (i)
Ix 2
v
 0 A  IR 

(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Paragraph for Question no. 15 to 16

A uniform ring of mass m and radius R can rotate freely E0

about an axis passing through centre C and
– + + y
perpendicular to plane of paper. Half of ring is positively –– +
–
charge and other half is negatively charge. Uniform – +
– x
electric field E0 is switched on along –ve x-axis (Axis –
+
are shown in figure) – C +
– +
– +
[magnitude of charge density ] – – ++

15. The equilibrium of ring is

(A) stable (B) unstable (C) neutral (D) can’t say

15. B
Sol. Because potential energy is maximum.
So equilibrium is unstable.
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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16. If ring is slightly disturb from given position, find the angular speed of ring when it rotate
by /2.
E0 16E0 8 E 0
(A) 2 (B) (C) (D) none
m m m

16. B
1 2
Sol. I  PE0  4R 2E 0
2
1 mR2 2
  4R2E0
2 2
16E0

m

Paragraph for Question no. 17 to 18

Earthing of Transmission Lines:

(The principle behind the possibility of earthing and
the necessary conditions for earthing)
Since the electrical conductivity of the soil is quite
high, so Earth can behaves as a conductor of electric
current. Such an electric circuit is shown in Figure-I.

Let A and B are two spherical electrodes of radius r0 each, embedded into the earth.
D (>>>r0) is the distance between the centres of the electrodes. In order to simplify
calculations, we assume that the medium is infinite (as shown in the figure-II) and the
charge distribution on the electrodes is spherically symmetric.
Let x be the distance between the centre of the left electrode and a certain point P on
the line connecting the centers of the electrodes. The field at this point is given by
Q 1 1 
EP  E   E     i
40  x 2
(d  x)2 
d  r0
d  r0
Q
d  r0
 1 1   Q 1 1 
V 
r0
EP  d 
40 
r0
 2 
x (d  x)2
 dx  

  
 40 x (d  x)  r0

Q  1 1 1 1  Q
 V      …(1)
40  d  r0 r0 r0 d  r0  20r0
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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Q
As we know that I 
S
 J  dS   
S
E  dS 
0
…(2)

Where I is the current in the medium and S is a closed surface surrounding one of the
electrodes. From equations (1) and (2), we obtain for the resistance of the medium

V 1
R  ….(3)
1 2r0
The most important property of resistance is its independence of the distance between
the electrodes. The main contribution to the resistance of the medium comes from the
regions adjoining the electrodes. Hence, it is especially important to ensure their good
conductivity. For this reason, electrodes with large surface area are used, which are
buried deeply into the Earth, where the ground water ensures a good conductivity of the
soil.
Physically, this is explained by the fact that as the distance between the electrodes
increases, the effective area of the medium through which the current is passing also
increases accordingly. An increase in the distance between the electrodes increases the
resistance white an increase in the area decreases it.

17. The resistance does not depend on the distance between the electrodes because
(A) The effective cross section area through which the current flows is proportional of the
distance between the electrodes.
(B) The resistivity of earth is very high.
(C) There is no interaction between electrodes and earth.
(D) The potential of earth is very high.

17. A

18. Two long parallel electrodes (each of length L) are located in a poorly conducing
medium with resistivity . The distance between the axis of the wires is equal to , the
cross-section radius of the each wire equals a. In the case a << . The potential
difference between the electrodes is equal to V. choose the correct option(s).
(A) The current density at the point equally removed from the axes of the wires by a
V
distance r is 2 and the electric resistance of the medium per unit length of
r n( / a)
2  
the wires is n 
 a
(B) The current density at the point equally removed from the axes of the wires by a
V
distance r is 2 and the electric resistance of the medium per unit length of
r n( / a)
  
the wires is n
  a 
(C) The current density at the point equally removed from the axes of the wires by a
V
distance r is and the electric resistance of the medium per unit length of
2r n( / a)
2

2  
the wires is n 
 a
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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(D) The current density at the point equally removed from the axes of the wires by a
V
distance r is and the electric resistance of the medium per unit length of
2r n( / a)
2

  
the wires is n
  a 
18. D

Combined Solution:

Q Q
Ep = 2E0 cos  = 2   
2r0L 2r 2r2L
Q
(a) For paints on the x-axis EP 
r0L
a Q a dr Q  a
V  VA  VB   EP dr    n
a
L0 a
r L0  a 
Q   L0 V
V n   Q  [Because  >>> a]
L0  a   
n 
a
Q   L0 V E V
V n   Q   jp  P 
L0  a      
n  2r 2 n  
a a
(b) E10  Electric field just outside the first wire
Q V
E10  
20La  
2a n  
a
E V
J10  10 
 2a n( / a)
V LV
I  J10  Area   2aL 
2 n( / a)  n( / a)
V  n( / a)
R 
I L
R   
Resistance per unit length  n
L     a 
Second Method
dr  dr  a
L a
dR    R n( / a)
rL L r
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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S
SEEC
CTTIIO
ONN--2
2 :: C
Chhe
emmiis
sttrry
y
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE OR MORE may be correct.

1. CH2Cl
O 2N NO 2
NaOH1 eq 

HO
 Product P 
2

Cl
Correct statement(s) regarding product(P) is
(A) it is an alcohol
(B) it is a phenol
(C) the longer C – Cl bond breaks in the reaction
(D) the NO2 groups favours substitution of benzylic chloride

1. ACD
Sol. CH2Cl CH2OH

O 2N NO 2 O 2N NO 2
NaOH1 eq

HO

2

Cl Cl

2. Which of the following reactions produce(s) a ketone?

Cl
1. Ca OH H O/OH
(A) CH3COOH 
2.Heat
2
 (B) CH3CH2CCH3 
2


Cl
OH
1.NaNH
CH3  CH  CH  CH3 
2
2  o
(C) 2. H2SO 4 /Hg (D) CH3  C  CH3 
Cu/300 C

Cl Cl
CH3

2. ABC
Sol. CH3COOH  Ca  OH2  Ca  CH3COO 2 

 CH3COCH3  CaCO3
NaNH
CH3  CH  CH  CH3 
2
 CH3  C  C  CH3  CH3CH2C  CH

Cl Cl
Both product will give CH3COCH2CH3 upon hydrolysis with H2SO4/Hg2+.
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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3. Which reaction(s) take(s) place with retention of configuration of the reactant in the
product?
SOCl
CH3CH2CCH3 
2

(A)
OH
OH
CH2  CH  CH3  
HCl
ZnCl  anhy 
(B) 2

OH

O
1. LiAlH /ether
CH3  C  CH2  CH  CH3 
4
 
2. H
(C) OH

OH

(D) 
Na

CH2CH3

3. ACD
Sol. In(A) retention takes place in reaction with SOCl2.
In(B) racemisation takes place for SN1 and inversion for SN2.
In(C) OH-group can’t be attacked by LiAlH4 which converts ketone to 2o-alcohol
In(D) No C – O bond cleavage takes place.

4. CH3OCH2CH2OCH2CH3 
HI
Pr oducts .
The product of above reaction can be
(A) CH3OH (B) CH3CH2I
(C) H2C = CH2 (D) C2H5OH

4. ABCD
Sol. CH3OCH2CH2OCH2CH3 
HI
CH3OH  CH3I
C2H5OH  C2H5I
ICH2CH2I  CH2  CH2  I2
CH2  CH2 
HI
CH3CH2I
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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H P
NaO
l .
di
(1) I2 /NaOH
Q + .PPt.
  X
o
CH3CH2OH 
Cu/300 C
(2) H+
5. NH
2O
H/ +
1.C H
H
3M
2.H gB R
r
3O +
S

Correct statement(s) regarding products of above reaction(s) is/are

(A) P, Q and R contain pi-bonds (B) P and R exhibit geometrical isomerism
(C) R and S show optical isomerism (D) The ppt. is yellow colour

5. ABD
Sol. X = CH3CHO
P = CH3 – CH = CH – CHO
Q = HCOOH, PPt. = CHI3
R = CH3 – CH = NOH
S = CH3COCH3

6. Which compound(s) form(s) the same product when reacts through SN1 or SN2
mechanism with OH–?
Cl

(A) (B)
Cl

Cl

(C) (D)
Cl

6. CD
Sol. In (A) and (B) rearrangement of carbocations takes place. So the products will be
different by SN1 and SN2.

7. CH2 - CH = CH 2


EtONa/EtOH

 B 

(A)
(A) and (B) can form the different product(s) when they react with
(A) KMnO4/H+/Heat (B) KMnO4/OH–(1%)/Cold
(C) H2/Ni (D) O3/Zn/H2O
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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7. BD
Sol. CH = CH - CH 3

B is

KMnO4/H+/ forms same product benzoic acid and H2/Ni also forms the same product
n-propylbenzene.

(Single Correct Choice Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

8.
OH

Conc.H SO
 2 4
High temperature
 Products

How many products in above reaction form substituted cyclohexanone upon reaction
with O3 and Zn/H2O? [Do not consider stereoisomers]
(A) 2 (B) 4
(C) 3 (D) 5

8. A
Sol. The products which give susbsituted cyclohexanone is/are

and

9. O


1. LDA
2. Br
 Product P 
2

In above reaction (P) is

O O
(A) Br (B)
Br
OH O
(C) Br (D) Br
Br
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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9. A
Sol. Since LDA is a bulky base it abstracts proton from the least hindered side.
O O O
O Li
Br2 Br

LDA
 
 Br

O
Br

10. O

ZnHg

Conc.HCl
 Product P 

In above reaction (P) is:

(A) (B)

Cl

(C) (D)

10. C
Sol. O

ZnHg

Conc.HCl
 
HCl


Cl

11. Which reactant forms maximum number of isomeric products with KCN?
Cl

(A) (B)
Cl

Cl

(C) (D)

Cl

11. C
Sol. In option(A) two products are formed
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
17

and
CN NC
In (B) two products are possible
In (C) geometrical and optical isomers are possible. So number of products is four
because cis configuration is given.
In (D) two products are formed.

12. OH

Br /H O

NaOH
 P 
2 2
Q

OH

Br /H O

2 2
Q

Br /CS

2 2
R  S
The incorrect statement regarding the unknown substances P, Q, R and S is:
(A) ‘Q’ is the heaviest one
(B) Yield of (Q) is higher when it is formed from (P) than from phenol directly
(C) R and S are more reactive than phenol towards ICl.
(D) molar mass of R and S are same.

12. C
Sol. O Na OH
OH OH
Br Br
Br
P= ,Q= ,R= ,S=

Br
Br

13. Lucas reagent(anhy.ZnCl2/Conc.HCl) is used to distinguish between

(A) CH3CH2OH and CH3CH2CH2OH (B) CH3COCH3 and CH3CH2CHO
(C) (CH3)3COH and CH3CH2OH (D) CH3CHO and CH3CH2OCH3

13. C
Sol. Lucas reagent is used to distinguish between 1o, 2o and 3o alcohols.

14. Which of the following reaction produces an aldehyde and a ketone?

Conc.H2SO4 Conc.H2SO4
(A) CH3COCH3  
 (B) HOCH2CH2OH  

Conc.H SO
Conc.H2SO4
CH3CHCH2OH 

2 4

(C) CH3CH2CH2OH 
 (D)
OH
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
18

14. D
Sol. Products are
CH3

(A)

H3C CH3
(B) CH3CHO
(C) CH3CH = CH2
O

CH3CCH3  CH3CH2CHO
(D)
O
H3
OH C-C
CH 3 -
=C H2
H+ CH 3C
-H2O
CH3  CH  CH2
H+
OH OH -H2O
CH
3 - CH
= CH
- O
H

CH3CH2CHO

(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Paragraph for Question no. 15 to 16

The , -unsaturated aldehydes and ketones undergo 1, 2 and 1, 4-addition product when they
reacts with a polar reagent.
O R O R
C C
H2O
C   C
R H R

C C
R R R OH
R
The addition takes place across C = C double bond when the reagent is a weakly ionizing
compound. Above reaction (1, 2-addition) takes place with H2O, ROH, RSH, RNH2 etc.
When the reagent contains a strong nucleophile then addition of Nu takes place at carbonyl
compound.
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
19

O R HO R
e.g.
C C
C LiAlH4 H
  C
R H3O R

C C
R R R R
When the reagent produces a very strong base like R–, then both 1, 2 and 1, 4-addition takes
place.
O R HO R HO R
e.g. C
C C
CH3MgBr H3C C
C   C
R H3O R R

C C C
R R R R R
R CH3
( 1, 2-addition product )
( 1, 4-addition product )
Answer the following questions on the basis of above write up.

15. In case of weakly ionized reagents(H2O, CH3OH) why 1, 2-addition takes place across C
= C bond not in C = O bond?
(A) C = C bond is non-polar whereas C = O bond is polar.
(B) C = C bond undergoes electrophilic attack whereas C = O needs nucleophilic attack
(C) C = C bond is weaker than C = O bond
(D) Electron delocalization in C = C bond is faster than in C = O bond

15. B

16. O R
C

R 1. CH Li,Hexane
C 
3
 P  Q
2.H3O

C
R R
Which reagent forms at least one common product when treated with P and Q?
(A) H2/Ni (B) CH3MgBr/H3O+
(C) Br2/CCl4 (D) KMnO4/OH– (1%)/Cold

16. B
Sol for Q. 15 & 16. CH3MgBr forms CH4 when reacts with the OH group of both compounds
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
20

Paragraph for Question no. 17 to 18

An aromatic compound ‘P’(C8H8O3) contains intramolecular hydrogen bond. When heated in

presence of sodalime it undergoes decarboxylation and form ‘Q’ (C7H8O). Reaction of ‘Q’ with
one equivalent of CH2N2 forms ‘R’(C8H10O). ‘R’ reacts with one equivalent of Cl2/h forming
compound ‘S’(C8H9OCl). Hydrolysis of ‘S’ with H2O produces T(C8H10O2). Heating of

OCH 3

‘T’ with Cu at 300oC produces

CHO
P  C7H8O  R C8H10O 
CH N Cl /h
C8H8O3 
Sodalime
Heat
Q 2 2
 2

OCH 3

S  C8H9OCl   T  C8H10O2  

o
HO
2 Cu/300 C


CHO

17. Which reagent can convert (R)  (Q)?

(A) Na in NH3(l) (B) zinc dust heating
(C) HI (D) AgNO3

17. C

18. Hydrolysis of (S) to (T) takes place favouralbly at pH?

(A) > 7 (B) < 7
(C) equal to 7 (D) all are correct

18. C
Sol. OH OH OCH 3 OCH 3 OCH 3
Q.17
COOH
& 18
P= ,Q= ,R= ,S= ,T=

CH3 CH3 CH3 CH2Cl CH2OH

CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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S
SEEC
CTTIIO
ONN--3
3 :: M
Maatth
heem
maattiic
css
PART – A
(Multi Correct Choice Type)
This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONE OR MORE may be correct.

1. Let the function f :R  R be defined by f  x   x 3  x 2   x  1 sin x and let g :R  R

be an arbitrary function. Let fg :R  R be the product function defined by
 fg x   f  x  g  x  . Then which of the following statement is/are TRUE?
(A) If g is continuous at x = 1, then fg is differentiable at x = 1
(B) If fg is differentiable at x = 1, then g is continuous at x = 1
(C) If g is differentiable at x = 1, then fg is differentiable at x = 1
(D) If fg is differentiable at x = 1, then g is differentiable at x = 1

1. AC
Sol. f :R  R
f  x   x 3  x 2   x  1 sin x
g :R  R
(A) If g is continuous at x = 1 then fg is differentiable
Let h  x   f  x  .g  x 
f 1  h  g 1  h   f 1 g 1
 
RHD  h' 1  lim
h 0 h
f 1  h  g 1  h   0
 lim
h0 h
f 1  h   f  0 
 lim g 1  h  . lim
h 0 h 0 h
 g 1 f ' 1
LHD at x = 1
f 1  h  g 1  h   f 1 g 1
 lim
h0 h
f 1  h   f 1
 lim g 1  h  . lim  g 1 f ' 1
h0 h0 h
So, h(x) is differentiable at x = 1

(B) Given h  x   f  x  .g  x  is differentiable

f 1  h  g 1  h   f 1 g 1 f 1  h  g 1  h   f 1 g 1
lim  lim
h0 h h0 h
lim g 1  h  .f ' 1  lim g 1  h  .f ' 1
h 0 h0
f ' 1  0 and g 1 is not define
So, can not comment over continuity and differentiability

(C) Given g  x  is differentiable

CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
22

So, h  x   f  x  g  x 
h'  x   f '  x  g  x   g'  x  f  x , as g  x  is differentiable
 f ' 1 g 1  0 will exist

(D) Same as for B

lim g 1  h   lim g 1  h 
h0 h0
can not say about differentiability of the g(x)

2. Let R be a relation defined as a R b if 1 ab  0 . Then, the relation R is

(A) Reflexive (B) Symmetric
(C) Transitive (D) None of these

2. AB
Sol. Here relation R is reflexive since 1  a  a  0  real numbers a. It is symmetric since
1
1 ab  0  1 ba  0 . However R is not transitive: consider three real numbers 2, 
6
 1 2  1 4
and –2. We have 1  2       0 and 1      2    0
 6 3  6 3
 1  1
Hence, 2R    and    R  2 
 6  6
  2 since
But 2R 1  2  2   3  0

 tan2 x
 2 , for x  0
 x   x
2


3. Let f  x    1 , for x  0 where [x] is the step up function and x is the

 x cot x , for x  0


fractional part function of x, then
(A) lim f  x   1 (B) lim f  x   1
x0 
x0
2
(C) cot  lim f  x    1
1
(D) None of these
 x0 

3. AC
tan2 h tan2 h
Sol. RHL lim f  x   lim  lim 1
 h
2

x 0 h0 h2 h0 h2
LHL lim f  x   lim h cot h  hlim 1 h cot 1 h  cot1
 h0 0
x0

 
2
cot  lim f  x    cot 1
1 
2
cot1 1
 x0 
Hence, (A) and (C) are the correct answers.
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
23

4. Let f :  and g :  R be functions satisfying f  x  y   f  x   f  y   f  x  f  y 

and f  x   xg  x  for all x, y  . If lim g  x   1, then which of the following
x 0
statements is/are TRUE?
(A) f is differentiable at every x 
(B) If g  0   1, then g is differentiable at every x 
(C) The derivative f ' 1 is equal to 1
(D) The derivative f '  0  is equal to 1

4. ABD
Sol. f  x   x.g  x   x  R

x0
 
 lim f  x   lim x lim g  x 
x0 x0

 lim f  x   0
x 0

  
Also lim f  x  y   lim f  x   f  y   f  x  .f  y 
x0 x 0

 lim  x  y   f  y 
x 0
 f  x  is continuous  x  R
 f 0  0
f  x  h  f  x 
f '  x   lim
h 0 h
f  h   f  x  .f  h 
 f '  x   lim
h 0 h
f h
 f '  x   lim . 1  f  x  
h 0 h
f '  x  dx
   1 dx
1 f  x 
 n 1 f  x   x  c
f 0  0  c  0
 f  x   ex  1
 f '  x   ex
 f  x  is differentiable and f '  0   1
f x
Also g  x   ,x  0
x
Now if g  0   1
 ex  1
 , x0
 g x   x  g  x  is continuous at x = 0
 1, x0

CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
24

eh  1
g  0  h  g  0  1
1
 g'  0   lim  lim h 
h0 h h h 2
 g  x  is diff.  x  R if g  0   1

5. Let g :  be a differentiable function with g  0   0, g'  0   0 and g' 1  0 .

x
 g  x , x  0
Let f  x    x and h  x   e for all x  . Let  f oh  x  denote
x

 0, x0

f h  x   . Then which of the following is (are) true?
(A) f is differentiable at x = 0 (B) h is differentiable at x = 0
(C) f o h is differentiable at x =0 (D) h o f is differentiable at x = 0

5. AD
Sol. Differentiability of f  x  at x  0
 f 0  f 0    0  g   
 
LHD f ' 0  lim 
0 
  lim

0
  0
 f 0    f 0  g
RHD f ' 0   lim 

  lim 0
0
  0 
 f  x  is differentiable at x = 0
Differentiability of h(x) at x = 0
 
h' 0   1, h  x  is an even function
hence non diff. at x = 0

Differentiability of f h  x  at x = 0 
f h  x    g e  x R
x

f h  0   f h  0        g' 1
g 1  g e
    lim
LHD f ' h 0

0 
 lim
0 
f h  0      f h  0    
g e  g 1
    lim
RHD f ' h 0

0 
 lim
0 
 g' 1

 
Since g' 1  0  f h  x  is non diff. at x = 0
Differentiability of h  f  x   at x = 0

 fx , x  0

h  f  x    e

 1, x0
h  f 0  h  f 0   1 e
g  
g   

LHD h' f  0     lim  0 
 lim
0 g   
.

0

h  f 0   h  f 0   1 e
g  
g   

RHD h' f  0     lim  0 
 lim
0 g   
.

0
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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6. f is continuous function in a,b , g is a continuous function in [b, c]. A function h (x) is

 f  x  for x  a, b 

defined as h  x    . If f b   g b  , then
g  x  for x  b, c 

(A) h (x) has a removable discontinuity at x = b
(B) h (x) may or may not be continuous in [a, c]
    and h b   f b 
(C) h b   g b   

(D) h  b   g  b  and h  b   f  b 
   

6. AC
Sol. Given f is continuous in [a, b] ………..(i)
g is continuous in [b, c] ………..(ii)
f b   g b  ………..(iii)
h  x   f  x  for x  a, b  

 f  b   g  b  for x  b  ………..(iv)
 g  x  for x  b,c   
h(x) is continuous in a,b   b,c  [Using Equation (i) and (ii)]
Also,    
f b   f  b  ,g b   g  b  [Using Equation (i) and (ii)]…….(iv)

 h b   f b   f b   g b   g b   h b 
1 1  
[Using Equation (iv) and (v)]

Now, verify each alternative. Of course! g  b  and f  b  are undefined.

 

h b   f b   f b   g b   g b 
  

and h  b   g  b   g  b   f b   f b 
  

Hence h b   h b   f b   g b 
 

and h  b  is not defined.

7. Let f  x   1  x  x 3 . Then, the real values of x satisfying the inequality,

1  f  x   f 3  x   f 1  5x  , are
(A)  2, 0  (B)  0, 2
(C)  2,   (D)  ,  2 

7. AC
Sol. f  x   1  x  x3
 
Replacing x by f  x  ,f f  x   1  f  x   f 3  x 


Hence, the given equation is f f  x   f 1  5x ,  f  x   1  5x
f  x   1  x  x3
1 x  x3  1 5x
x3  4x  0
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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x  x  2  x  2   0
So, x   2, 0    2,  

(Single Correct Choice Type)

This section contains 7 multiple choice questions. Each question has four choices (A), (B),
(C) and (D) out of which ONLY ONE is correct.

8. If the function f :R  R is defined by f  x   x  x  sin x  , then which of the following

statements is TRUE?
(A) f is one – one, but NOT onto (B) f is onto, but NOT one – one
(C) f is BOTH one – one and onto (D) f is NEITHER one – one NOR onto

8. C
Sol. f  x  is odd, continuous function
 x  x  sin x  , x  0

f x  
 x  x  sin x  , x  0

for x  0, f '  x   2x  sin x  x cos x  x 1  cos x    x  sin x   0
for x  0,f '  x   2x  sin x  x cos x  x cos x  1   x  sin x   0 as x  0
 So f  x  strictly increases in  ,    f  x  is one – one
x   f x  
x   f  x    . So f  x  is onto

9. Let f :0,2  R be the function defined by

   
f  x    3  sin  2x   sin  x    sin  3 x   . If ,  0,2 are such that
 4  4
x  0,2 :f  x   0  ,, then the value of    is ____________
(A) 1 (B) 0.5
7 3
(C) (D)
5 2

9. A
 
Sol.  3  sin 2x  sin  x  

 sin  3x  
 4  4
   3 
  3  sin 2x  sin  x    sin  3x 
 4  4 
     
  3  sin2x  3  4 sin2  x    sin  x  
  4   4

     
  3  sin2x  3  4 sin2  x    sin  x  
  4   4
 
 sin  x    0
 4
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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
 0  x  0,2
   x 
4
5 1
  x   1
4 4

10. Let e denote the base of the natural logarithm. The value of the real number a for which

the right hand limit lim

1  x 1/x  e1 is equal to a non zero real number, is
x 0 xa
___________
(A) 2 (B) 1
(C) 3 (D) 4

10. B
ln1 x 
1 1
1  x 
1/x
 e x 
Sol. lim e  lim e
x 0 xa 
x 0 xa
  x  x2 
  2 
 e x  1
   x 
1  
 1  e 2  1
 lim  lim  
x 0 e xa x 0 e
 x
a

 
For value of limit to be a non – zero real number a = 1

11. In a certain town 25% families own a phone and 15% own a car, 65% families own
neither a phone nor a car. 2000 families own both a car and a phone. Consider the
following statements in this regard:
1. 10% families own both a car and a phone.
2. 35% families own either a car or a phone.
3. 40,000 families live in the town.
Which of the above statements are correct?
(A) 1 and 2 (B) 1 and 3
(C) 2 and 3 (D) 1, 2 and 3

11. C
Sol. n P   25%, n  C  15%,
n P' C'   65%, n P  C  2000
Since, n P' C'   65%
 n P  C  '  65%
 n P  C  35%
Now, n P  C   n P   n  C   n P  C 
 35  25  15  n P  C 
 n P  C   40  35  5
Thus, n P  C   5%
But, n P  C   2000
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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 5% of the total = 2000

2000  100
 total number of families   40000
5
 n P  C   35%,
Total number of families = 40,000 and n P  C   5%

12. The expression x2  4px  q2  0 for all real x and also r 2  p2  qr, then the range of
xr
f x  is
x  qx  p2
2

p q
(A)  ,  (B)  0,  
 2r 2r 
(C)  , 0  (D)  ,  

12. D
Sol. x2  4px  q2  0,  x  R
 4p2  q2  0 ………….(i)
r 2  p2  qr …………(ii)
xr
Let y 2
x  qx  p2
 x 2 y  x  qy  1  p2 y  r  0 ………….(iii)
x is real,
 q 2

 4p2 y 2  y  2q  4r   1  0
Equation (i)  Coefficient of y 2 is a positive discriminant.
  4r  2q  4 q2  4p2
2
 

 16 r 2  p2  qr  0  [by Equation (ii)]

Hence, Equation (iii) is true for all real y or y   ,   .

13. Let f:  , g:  and h:  be differentiable functions such that


f  x   x 3  3x  2 , g  f  x    x and h g  g  x    x for all x  . Then
1
(A) g'  2   (B) h' 1  665
15
(C) h  0   15 (D) None of these

13. D
Sol. g'  f  x   .f '  x   1
1
 g'  2  
3
h  x   f  f  x 
 h  0   16
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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h  x   f  f  x 
 h'  x   f '  f  x   f '  x 
 h' 1  f '  f 1 .f ' 1
 111 6  666

 1   1 
14. Let f :   , 2   and g :   , 2   be functions defined by f  x    x 3  3  and
 2   2   
g  x   x f  x   4x  7 f  x  , where  y  denotes the greatest integer less than or equal
to y for y  . Then
 1 
(A) f is discontinuous exactly at three points in   , 2 
 2 
 1 
(B) f is discontinuous exactly at four points in   , 2 
 2 
 1 
(C) g is differentiable exactly at four points in   , 2 
 2 
 1 
(D) g is NOT differentiable exactly at five points in   , 2 
 2 

14. B
Sol. f  x    x 2  3 
Which is discontinuous at x  1, 2, 3,2
g  x   f  x   x  4x  7 
f  x  is non differentiable at x  1, 2, 3 and x  4x  7 is non differentiable at
7
x  0,
4
But f  x   0 x   3, 2
 
Hence g(x) is non differentiable x  0,1, 2, 3 .

(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions
have to be answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which
ONLY ONE is correct.

Paragraph for Question no. 15 to 16

Consider the equation x  y   x  y   0, where . is the greatest integer function.

15. The number of integral solutions to the equation is

(A) 0 (B) 1
(C) 2 (D) None of these

15. C
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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Sol. For integral solution,

x  y   x  y   0  x  y  xy  0
 1  x  y  xy  1   x  1 y  1  1
i.e. Only possible, if
 x  1  1, y  1  1 or  x  1  1, y  1  1
 x  2, y  2 or x  0, y  0
 Solutions are (0, 0) or (2, 2).

16. Equation of one of the lines on which the non – integral solution of given equation, lies is
(A) x  y  1 (B) x  y  0
(C) x  y  1 (D) x  y  5

16. B
Sol. For non – integral solution,
Let x   x   f1
and y   y   f2
 x  y   x   f1   y   f2
 x  1  y  1  f1  f2  1
Now, 0  f1  f2  2
 f1  f2  1
  x  1  y  1  2
Which is possible for
  x   3 and  y   2
or  x   2 and  y   3
or  x   1 and  y   0
or  x   0 and  y   1
 The x  y   x  y  becomes x  y  6
or xy0
 Non – integer solution lies on x  y  6
or xy0

Paragraph for Question no. 17 to 18

Let f  x  is a function continuous for all x  R except at x = 0. Such that

f '  x   0 ,x   ,0  and f '  x   0,  x   0,   . Let lim f  x   2, lim f  x   3 and
x 0 x 0
f 0  4

17. 
The value of  for which 2 lim f x3  x 2
x 0
     lim f 2x
x 0
4
 x5  is
4
(A) (B) 2
3
(C) 3 (D) 5
CM Test (Class-XII)-(Test-1)-PCM-IITJEE/22
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17. C
Sol. x  0, x 3  x 2  x 2  x  1  0  y

x  0,2x 4  x 5  x 4  2  x   0  4
2  3     2    3
Hence, (c) is the correct answer.
3

f  x  x2
18. The values of lim where [.] denotes greatest integer function and 
.

x 0 1  cos x 
 
  f  x   
denote fraction part function
(A) 6 (B) 12
(C) 18 (D) 24

18. B
f  x  x2 3x 2
Sol. lim 
x 0  1  cos x   1  cos x  1  cos x
   0
 f  x    f  x   2
       
Hence, (B) is the correct answer.