Thermal Energy and Work: Lesson 2: The First Law of Thermodynamics
Thermal Energy and Work: Lesson 2: The First Law of Thermodynamics
Thermal Energy and Work: Lesson 2: The First Law of Thermodynamics
ACTIVITY
Watch the video. The video describes work from expansion (or- pressure- volume work). Sal
combines the equations W=PΔV and AU=Q-PΔV.
ANALYSIS
1. If the volume of a system increases while pressure remains constant, is the value of work
done by the system W positive or negative?
An increase in the system while pressure is remains constant; the value of work done by the
system is “positive”.
1. What is the pressure-volume work done by a system if a pressure of 20Pa causes a change in
volume of ?
Answer:
Given:
Solution:
( )( )
2. What is the net heat out of the system when 25J is transferred by heat into the system and
45J transferred out of it?
Solution:
( ) ( )
ASSESSMENT
1. Identify the type of energy transferred to your body in each of the following as either internal
energy, heat transfer, or doing work:
a. Basking in sunlight –HEAT TRANSFER (heat of the sun gets transferred to the body);
b. Eating food –INTERNAL ENERGY (Eating food gives us energy which is stored in our body
as internal energy);
c. Riding an elevator to a higher floor –DOING WORK (against gravity to increase potential
energy).
2. How much heat transfer occurs from a system, if its internal energy decreased by 150 J while
it was doing 30.0J of work?
Given:
ΔU = 150J
ΔW = 30 J
ΔQ =?
Solution:
ΔQ= ΔU + ΔW
= -150 J + 30 J
= -120 J
120 J is transferred from the system to its environment.
3. How do heat transfer and internal energy differ? In particular, which can be stored as such in
a system and which cannot?
Heat transfers a process in which, due to the temperature difference, heat energy is
transferred from one system to another. The total energy is the energy sum of kinetic and
potential energy of the molecules.
Heat transfer cannot be stored whereas internal energy can be stored.