DMK 5022 Chapter 1

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DMK 5022

LOGISTICS IN OIL AND FAT


INDUSTRY

CHAPTER 1: QUALITY OF OIL & FAT AND


THEIR SOURCES

By: Nor Aziyan Mohd Nasir


Essential fatty acid

• Essential fatty acids (EFA) are fatty acids that humans and other


animals must ingest because the body requires them for good
health but cannot synthesize them.
• The term "essential fatty acid" refers to fatty acids required for
biological processes but does not include the fats that only act as
fuel
• Only two fatty acids are known to be essential for
humans: alpha-linolenic acid (an omega-3 fatty acid) and linoleic
acid (an omega-6 fatty acid).
• Mammals lack the ability to introduce double bonds in fatty acids
beyond carbon 9 and 10, hence ω-6 linoleic acid (18:2,9,12),
abbreviated LA (18:2n-6), and the ω-3 linolenic acid(18:3,9,12,15),
abbreviated ALA (18:3n-3), are essential for humans in the diet.
• In humans, arachidonic acid (20:4,5,8,11,14, abbreviated 20:4n-6)
can be synthesized from LA by alternative desaturation and chain
elongation.
Roles of essential fatty acid

In the body, essential fatty acids serve multiple functions. The balance
between dietary ω-3 and ω-6 strongly affects function.
• They are modified to make

- the classic eicosanoids (affecting inflammation and many other cellular


functions)
– the endocannabinoids (affecting mood, behavior and inflammation)
– the lipoxins which are a group of eicosanoid derivatives formed via the
lipoxygenase pathway from ω-6 EFAs and resolvins from ω-3 (in the
presence of acetylsalicylic acid, downregulating inflammation)
– the isofurans, neurofurans, isoprostanes, hepoxilins, epoxyeicosatrienoic
acids (EETs) and Neuroprotectin D
• They form lipid rafts (affecting cellular signaling)
• They act on DNA (activating or inhibiting transcription factors such
as NF-κB, which is linked to pro-inflammatory cytokine production)
Reference intake values

Reference intake values for as published by the Panel on Dietetic


Products, Nutrition and Allergies of the European Food Safety
Authority
 (EFSA)
Conjugated linoleic acid
• Conjugated fatty acids are polyunsaturated fatty acids in
which at least one pair of double bonds is separated by only
one single bond. Example: conjugated linoleic acid.
• Dairy products and beef are the major sources of
conjugated linoleic acid in the diet.
• An average diet supplies 15-174 mg of conjugated linoleic
acid daily.
• Conjugated linoleic acid is commonly taken
by mouth for weight loss.
• It is also often used for bodybuilding and fitness, but there is
limited scientific evidence to support these uses. 

How does it work?

Conjugated linoleic acid might help reduce body fat deposits


and improve immune function.
Polyunsaturated fatty acids

• Polyunsaturated fatty acids (PUFAs) are fatty acids that contain


more than one double bond in their backbone.
• This class includes many important compounds, such as essential
fatty acids and those that give drying oils their characteristic
property
• Polyunsaturated fats — along with monounsaturated fats — are
considered healthy fats, as they may reduce your risk of heart
disease, especially when substituted for saturated fats
• the two major classes of polyunsaturated fats are omega-3 and
omega-6 fatty acids
• Both are essential fatty acids that your body needs for
brain function and cell growth.
• Your body cannot make essential fatty acids, so you
must get them from your diet
• Polyunsaturated fatty acids in culinary oils
undergo oxidative deterioration at temperatures of
150 °C (302 °F).
• The heating causes a free radical chain reaction,
which oxidizes the PUFAs into hydroperoxide, which
further decomposes into a complex mixture of
secondary products.

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