SAFETY DATA SHEET

Product Trade Name: PARAGON EA

Revision Date: 12-Jan-2016 Revision Number: 14

1. Identification
1.1. Product Identifier
Product Trade Name: PARAGON EA
Synonyms: None
Chemical Family: Organic hydrocarbon
Internal ID Code HM001168

1.2 Recommended use and restrictions on use

Application: Solvent
Uses Advised Against No information available

1.3 Manufacturer's Name and Contact Details

Manufacturer/Supplier
Halliburton Energy Services Inc.
P.O. Box 1431
Duncan, Oklahoma 73536-0431
Emergency Telephone: 1-866-519-4752 (US, Canada, Mexico) or 1-760-476-3962

Halliburton Energy Services

645 - 7th Ave SW Suite 2200
Calgary, AB
T2P 4G8
Canada

Prepared By Chemical Stewardship

Telephone: 1-281-871-6107
e-mail: [email protected]

1.4. Emergency telephone number

Emergency Telephone Number 1-866-519-4752 or 1-760-476-3962

2. Hazard(s) Identification
2.1 Classification in accordance with paragraph (d) of §1910.1200

Aspiration Category Category 1 - H304

Skin Corrosion / Irritation Category 2 - H315
Germ Cell Mutagenicity Category 1B - H340
Carcinogenicity Category 1B - H350
Specific Target Organ Toxicity - (Single Exposure) Category 3 - H336
Acute Aquatic Toxicity Category 2 - H401
Flammable liquids. Category 4 - H227

2.2. Label Elements

Hazard Pictograms

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Signal Word Danger

Hazard Statements H227 - Combustible liquid

H304 - May be fatal if swallowed and enters airways
H315 - Causes skin irritation
H340 - May cause genetic defects
H350 - May cause cancer
H336 - May cause drowsiness or dizziness
H401 - Toxic to aquatic life

Precautionary Statements

Prevention P201 - Obtain special instructions before use

P202 - Do not handle until all safety precautions have been read and understood
P210 - Keep away from heat/sparks/open flames/hot surfaces. - No smoking
P261 - Avoid breathing dust/fume/gas/mist/vapors/spray
P271 - Use only outdoors or in a well-ventilated area
P273 - Avoid release to the environment
P280 - Wear protective gloves/eye protection/face protection

Response P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or

doctor/physician
P331 - Do NOT induce vomiting
P302 + P352 - IF ON SKIN: Wash with plenty of soap and water
P332 + P313 - If skin irritation occurs: Get medical advice/attention
P362 - Take off contaminated clothing and wash before reuse
P304 + P340 - IF INHALED: Remove to fresh air and keep at rest in a position
comfortable for breathing
P312 - Call a POISON CENTER/doctor/physician if you feel unwell
P370 + P378 - In case of fire: Use CO2, dry chemical, or foam

Storage P403 + P233 - Store in a well-ventilated place. Keep container tightly closed
P403 + P235 - Store in a well-ventilated place. Keep cool
P405 - Store locked up

Disposal P501 - Dispose of contents/container in accordance with

local/regional/national/international regulations

2.3 Hazards not otherwise classified

None known

3. Composition/information on Ingredients
Substances CAS Number PERCENT (w/w) GHS Classification - US
Naphtha, hydrotreated heavy 64742-48-9 60 - 100% Flam. Liq. 4 (H227)
Asp. Tox. 1 (H304)
Skin Irrit. 2 (H315)
Muta. 1B (H340)
Carc. 1B (H350)

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STOT SE 3 (H336)
Aquatic Acute 2 (H401)

The exact percentage (concentration) of the composition has been withheld as proprietary.

4. First-Aid Measures
4.1. Description of first aid measures
Inhalation If inhaled, move victim to fresh air and seek medical attention.
Eyes In case of contact, immediately flush eyes with plenty of water for at least 15
minutes and get medical attention if irritation persists.
Skin In case of contact, immediately flush skin with plenty of soap and water for at least
15 minutes. Get medical attention. Remove contaminated clothing and launder
before reuse.
Ingestion Get medical attention! If vomiting occurs, keep head lower than hips to prevent
aspiration. Rinse mouth. Never give anything by mouth to an unconscious person.

4.2 Most important symptoms/effects, acute and delayed

Causes skin irritation. May cause headache, dizziness, and other central nervous system effects. May cause heritable
genetic damage. Carcinogen. Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty
breathing, wheezing, coughing up blood and pneumonia, which can be fatal.

4.3. Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically.

5. Fire-fighting measures
5.1. Extinguishing media
Suitable Extinguishing Media
Carbon dioxide, dry chemical, foam.
Extinguishing media which must not be used for safety reasons
None known.

5.2 Specific hazards arising from the substance or mixture

Special Exposure Hazards
Use water spray to cool fire exposed surfaces. Closed containers may explode in fire. Decomposition in fire may produce harmful
gases.

5.3 Special protective equipment and precautions for fire-fighters

Special Protective Equipment for Fire-Fighters
Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use appropriate protective equipment.
See Section 8 for additional information

6.2. Environmental precautions

Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up

Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.

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7. Handling and storage
7.1. Precautions for Safe Handling
Handling Precautions
Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated
clothing before reuse.
Hygiene Measures
Handle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities

Storage Information
Store away from oxidizers. Store in a cool well ventilated area. Keep from heat, sparks, and open flames. Keep
container closed when not in use. Product has a shelf life of 24 months.

8. Exposure Controls/Personal Protection

8.1 Occupational Exposure Limits
Substances CAS Number OSHA PEL-TWA ACGIH TLV-TWA
Naphtha, hydrotreated heavy 64742-48-9 Not applicable Not applicable

8.2 Appropriate engineering controls

Engineering Controls Use in a well ventilated area. Local exhaust ventilation should be used in areas
without good cross ventilation.

8.3 Individual protection measures, such as personal protective equipment

Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Not normally needed. But if significant exposures are possible then the following
respirator is recommended:
Organic vapor respirator with a dust/mist filter. (A2P2/P3)
Hand Protection Impervious rubber gloves.
Skin Protection Normal work coveralls.
Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.
Other Precautions Eyewash fountains and safety showers must be easily accessible.

9. Physical and Chemical Properties

9.1. Information on basic physical and chemical properties
Physical State: Liquid Color: Translucent
Odor: Paraffinic Odor No information available
Threshold:

Property Values
Remarks/ - Method
pH: No data available
Freezing Point/Range No data available
Melting Point/Range No data available
Boiling Point/Range 198 °C / 390 °F
Flash Point 68 °C / 155 °F
Flammability (solid, gas) No data available
upper flammability limit 8
lower flammability limit 0.65
Evaporation rate No data available
Vapor Pressure 0.75

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Vapor Density No data available
Specific Gravity 0.78
Water Solubility Insoluble in water
Solubility in other solvents No data available
Partition coefficient: n-octanol/water 4
Autoignition Temperature No data available
Decomposition Temperature No data available
Viscosity No data available
Explosive Properties No information available
Oxidizing Properties No information available

9.2. Other information

Molecular Weight 154
VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity
Not expected to be reactive.

10.2. Chemical Stability

Stable

10.3. Possibility of Hazardous Reactions

Will Not Occur

10.4. Conditions to Avoid

Keep away from heat, sparks and flame.

10.5. Incompatible Materials

Strong oxidizers.

10.6. Hazardous Decomposition Products

Carbon monoxide and carbon dioxide.

11. Toxicological Information

11.1 Information on likely routes of exposure
Principle Route of Exposure Eye or skin contact, inhalation.

11.2 Symptoms related to the physical, chemical and toxicological characteristics

Acute Toxicity
Inhalation Excessive inhalation causes headache, dizziness, nausea and incoordination.
Causes severe respiratory irritation. May cause chemical pneumonia.
Eye Contact May cause mild eye irritation.
Skin Contact Causes moderate skin irritation. Causes drying of the skin.
Ingestion Irritation of the mouth, throat, and stomach. Aspiration into the lungs may cause
chemical pneumonitis including coughing, difficulty breathing, wheezing, coughing
up blood and pneumonia, which can be fatal. May cause central nervous system
depression including headache, dizziness, drowsiness, muscular weakness,
incoordination, slowed reaction time, fatigue blurred vision, slurred speech,
giddiness, tremors and convulsions.

Chronic Effects/Carcinogenicity Contains petroleum distillates which have been shown to cause skin cancer in
laboratory animals. May cause heritable genetic damage.

11.3 Toxicity data

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Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation
Naphtha, hydrotreated 64742-48-9 > 5000 mg/kg (Rat) (similar > 1000 mg/kg (Rabbit) > 2.5 g/m3 (Rat) 4h
heavy substance) > 5000 mg/kg (Rabbit) > 5.2 mg/L (Rat) (similar
substance)

Substances CAS Number Skin corrosion/irritation

Naphtha, hydrotreated 64742-48-9 Causes moderate skin irritation. (similar substances)
heavy

Substances CAS Number Eye damage/irritation

Naphtha, hydrotreated 64742-48-9 Non-irritating to rabbit's eye (similar substances)
heavy

Substances CAS Number Skin Sensitization

Naphtha, hydrotreated 64742-48-9 Did not cause sensitization on humans or laboratory animals. (similar substances)
heavy

Substances CAS Number Respiratory Sensitization

Naphtha, hydrotreated 64742-48-9 No information available
heavy

Substances CAS Number Mutagenic Effects

Naphtha, hydrotreated 64742-48-9 Some in vivo tests have shown mutagenic effects. In vitro tests have shown mutagenic effects (similar
heavy substances)

Substances CAS Number Carcinogenic Effects

Naphtha, hydrotreated 64742-48-9 This substance is a potential carcinogen.
heavy

Substances CAS Number Reproductive toxicity

Naphtha, hydrotreated 64742-48-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal
heavy experiments.

Substances CAS Number STOT - single exposure

Naphtha, hydrotreated 64742-48-9 May cause disorder and damage to the Central Nervous System (CNS)
heavy

Substances CAS Number STOT - repeated exposure

Naphtha, hydrotreated 64742-48-9 No significant toxicity observed in animal studies at concentration requiring classification. (similar
heavy substances)

Substances CAS Number Aspiration hazard

Naphtha, hydrotreated 64742-48-9 Aspiration into the lungs may cause chemical pneumonitis including coughing, difficulty breathing,
heavy wheezing, coughing up blood and pneumonia, which can be fatal.

12. Ecological Information

12.1. Toxicity
Ecotoxicity Effects

Product Ecotoxicity Data

No data available

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Toxicity to Invertebrates
Microorganisms
Naphtha, hydrotreated 64742-48-9 EL50 (72h) 3.1 mg/L LC50 2200 mg/L No information available LC50 2.6 mg/L
heavy (Selenastrum (Pimephales promelas) (Chaetogammarus
capricornutum) LL50 (96h) 8.2 mg/L marinus)
(Pimphales promelas) EL50 (96h) 4.5 mg/L

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(Daphnia magna)

12.2. Persistence and degradability

Substances CAS Number Persistence and Degradability

Naphtha, hydrotreated heavy 64742-48-9 No information available

12.3. Bioaccumulative potential

Substances CAS Number Log Pow

Naphtha, hydrotreated heavy 64742-48-9 >6
1.0 - 8.0

12.4. Mobility in soil

Substances CAS Number Mobility

Naphtha, hydrotreated heavy 64742-48-9 No information available

12.5 Other adverse effects

No information available

13. Disposal Considerations

13.1. Waste treatment methods
Disposal Method Disposal should be made in accordance with federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.

14. Transport Information

US DOT
UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable

US DOT Bulk
DOT (Bulk) UN1268, Petroleum Distillates, N.O.S., Combustible Liquid, III (Classified in
accordance with 49 CFR 172.101(d)(4))

Canadian TDG
UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable

IMDG/IMO
UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable
Packing Group: Not applicable
Environmental Hazards: Not applicable

IATA/ICAO
UN Number: Not restricted
UN Proper Shipping Name: Not restricted
Transport Hazard Class(es): Not applicable

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Packing Group: Not applicable
Environmental Hazards: Not applicable

Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: Not applicable
Special Precautions for User: None

15. Regulatory Information

US Regulations
US TSCA Inventory All components listed on inventory or are exempt.

TSCA Significant New Use Rules - S5A2

Substances CAS Number TSCA Significant New Use Rules - S5A2
Naphtha, hydrotreated heavy 64742-48-9 Not applicable

EPA SARA Title III Extremely Hazardous Substances

Substances CAS Number EPA SARA Title III Extremely Hazardous
Substances
Naphtha, hydrotreated heavy 64742-48-9 Not applicable

EPA SARA (311,312) Hazard Class

Acute Health Hazard
Chronic Health Hazard
Fire Hazard

EPA SARA (313) Chemicals

Substances CAS Number Toxic Release Inventory (TRI) - Toxic Release Inventory (TRI) -
Group I Group II
Naphtha, hydrotreated heavy 64742-48-9 Not applicable Not applicable

EPA CERCLA/Superfund Reportable Spill Quantity

Substances CAS Number CERCLA RQ
Naphtha, hydrotreated heavy 64742-48-9 Not applicable

EPA RCRA Hazardous Waste Classification

If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA.

California Proposition 65 All components listed do not apply to the California Proposition 65 Regulation.

MA Right-to-Know Law Does not apply.

NJ Right-to-Know Law Does not apply.

PA Right-to-Know Law Does not apply.

NFPA Ratings: Health 1, Flammability 2, Reactivity 0

HMIS Ratings: Health 1, Flammability 2, Physical Hazard 0

Canadian Regulations
Canadian DSL Inventory All components listed on inventory or are exempt.

16. Other information

Preparation Information
Prepared By Chemical Stewardship

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Telephone: 1-281-871-6107
e-mail: [email protected]

Revision Date: 12-Jan-2016

Reason for Revision SDS sections updated:

2

Additional information
For additional information on the use of this product, contact your local Halliburton representative.

For questions about the Safety Data Sheet for this or other Halliburton products, contact Chemical Stewardship at
1-580-251-4335.

Key or legend to abbreviations and acronyms

bw–bodywei ght
CAS–Chemi calAbst ractsSer vi
ce
EC50–Ef fectiveConcent ration50%
ErC50–Ef fectiveConcent rationgrowt
hrate50%
LC50–Let halConcent r
ati
on50%
LD50–Let halDose50%
LL50–Let halLoadi ng50%
mg/ kg–mi lli
gram/ kilogram
mg/ L–mi ll
igram/ li
ter
NIOSH–Nat i
onalI nstitut
ef orOccupationalSaf
etyandHeal
t
h
NTP–Nat i
onalTox i
cologyPr ogram
OEL–Occupat ionalEx posur eLimit
PEL–Per mi ssibleEx posur eLi mit
ppm –par tspermi l
li
on
STEL–Shor tTer m Ex posur eLi mit
TWA–Ti me- Wei ghtedAver age
UN–Uni tedNat ions
h - hour
mg/m3 - milligram/cubic meter
mm - millimeter
mmHg - millimeter mercury
w/w - weight/weight
d - day

Key literature references and sources for data

www.ChemADVISOR.com/

Disclaimer Statement
This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The
information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in
any process. Final determination of suitability of any material is the sole responsibility of the user.

End of Safety Data Sheet

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