Chemistry - D&F Block Element - NEET - Final

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Chemistry-: : Previous Years NEET

Topics : d- and f-Block Element
1. Name the gas that can readily decolourise acidified KMnO4 solution.
(a) SO2 (b) NO2 (c) P2O5 (d) CO2 (NEET, 2017)

2. HgCl2 and I2 both when dissolved in water containing I– ions, the pair of species formed is
(a) HgI2, I– (b) HgI42–, I32– (c) Hg2I2, I– (d) HgI2, I3–
(NEET, 2017)
3. The reason for greater range of oxidation states in actinoids is attributed to
(a) actinoid contraction
(b) 5f, 6d and 7s levels having comparable energies
(c) 4f and 5d levels being close in energies
(d) the radioactive nature of actinoids (NEET, 2017)
4. Which one of the following statements related to lanthanons is incorrect ?
(a) Europium shows +2 oxidation state
(b) The basicity decreases as the ionic radius decreases from Pr to Lu
(c) All the lanthanons are much more reactive than aluminium
(d) Ce4+ solutions are widely used as oxidizing agent in volumetric analysis
(NEET,-II 2016)
5. Which one of the following statements is correct when SO2 is passed through acidified K2Cr2O7
solution ?
(a) SO2 is reduced (b) Green Cr2(SO4)3 is formed
(c) The solution turns blue (d) The solution is decolourised
(NEET-I, 2016)
6. The electronic configuration of Eu (Atomic No. 63), Gd (Atomic No. 64) and Tb (Atomic No. 65)
are :
(a) [Xe]4f65d16s2, [Xe]4f75d16s2 and [Xe]4f85d16s2
(b) [Xe]4f76s2, [Xe]4f75d16s2 and [Xe]4f96s2
(c) [Xe]4f76s2, [Xe]4f86s2 and [Xe]4f85d16s2
(d) [Xe]4f65d16s2, [Xe]4f75d16s2 and [Xe]4f96s2 (NEET-I, 2016)

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d- & f-Block Element 2
7. Gadolinium belongs to 4f series. Its atomic number is 64. Which of the following is the correct
electronic configuration of gadolinium ?
(a) [Xe]4f95s1 (b) [Xe]4f75d16s2 (c) [Xe]4f65d26s2 (d) [Xe]4f86s2
(NEET, 2015)
8. Assuming complete ionisation, same moles of which of the following compounds will require
the least amount of acidified KMnO4 for complete oxidation ?
(a) FeSO3 (b) FeC2O4 (c) Fe(NO2)2 (d) FeSO4
(NEET, 2015)
9. Magnetic moment 2.48 B.M. is given by

(At. nos. Ni = 28, Ti = 22, Cr = 24, Co = 27)


(a) Cr2+ (b) Co2+ (c) Ni2+ (d) Ti3+
(NEET, 2015 Cancelled)
10. Which of the following processes does not involve oxidation of iron ?
(a) Formation of Fe(CO)5 from Fe
(b) Liberation of H2 from steam by iron at high temperature
(c) Rusting of iron sheets
(d) Decolourisation of blue CuSO4 solution by iron (NEET, 2015 Cancelled)
11. Because of lanthanoid contraction, which of the following pairs of elements have nearly same
atomic radii ? (Number in the parenthesis are atomic numbers)
(a) Zr(4) and Hf(72) (b) Zr(4) and Ta(73)
(c) Ti(22) and Zr(40) (d) Zr(40) and Nb(41)
(NEET, 2015 Cancelled)
12. The reaction of aqueous KMnO4 with H2O2 in acidic conditions gives
(a) Mn4+ and O2 (b) Mn2+ and O2 (c) Mn2+ and O3 (d) Mn4+ and MnO2
(NEET, 2014)
13. Magnetic moment 2.83 BM is given by which of the following ions ?
(At. nos. Ti = 22, Cr = 24, Mn = 25, Ni = 28)
(a) Ti3+ (b) Ni2+ (c) Cr3+ (d) Mn2+ (NEET, 2014)
14. Reason of lanthanoid contraction is :
(a) negligible screen effect of ‘f ’ orbital (b) increasing nuclear charge
(c) decreasing nuclear charge (d) decreasing screening effect (NEET, 2014)

15. Which of the following statements about the interstitial compounds is incorrect ?
(a) They are much harder than the pure metal
(b) They have higher melting points than the pure metal
(c) They retain metallic conductivity
(d) They are chemically reactive (NEET, 2013)

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d- & f-Block Element 3
16. Which of the following lanthanoid ions is diamagnetic ?
(At. nos. Ce = 58, Sm = 62, Eu = 63, Yb = 70)
(a) Eu2+ (b) Yb2+ (c) Ce2+ (d) Sm2+
(NEET, 2013)
17. Identify the correct order of solubility in aqueous medium
(a) Na2S > CuS > ZnS (b) Na2S > ZnS > CuS
(c) CuS > ZnS > Na2S (d) ZnS > Na2S > CuS (NEET, 2013)

18. Sc (Z = 21) is a transition element but Zn (Z = 30) is not because


(a) both Sc3+ and Zn2+ ions are colourless and form white compounds
(b) in case of Sc, 3d orbital are partially filled but in Zn these are filled
(c) last electron is assumed to be added to 4s level in case of Zn
(d) both Sc and Zn to do exhibit variable oxidation states. (Karnataka NEET, 2013)

19. Identify the alloy containing a non-metal as a constituent in it


(a) Invar (b) Steel (c) Bell metal (d) Bronze
(NEET, 2012)
20. Which of the statement is not true ?
(a) On passing H2S through acidified K2Cr2O7 solution, a milky colour is observed
(b) Na2Cr2O7 is preferred over K2Cr2O7 in volumetric analysis
(c) K2Cr2O7 solution in acidic medium orange
(d) K2Cr2O7 solution becomes yellow on increasing the pH beyond (NEET, 2012)

21. The catalytic activity of transition metals and their compounds is ascribed mainly due to
(a) their magnetic behaviour
(b) their unfilled d-orbitals
(c) the ability to adopt variable oxidation states
(d) their chemial reactivity (NEET, 2012)

22. Which of the following exhibits only +3 oxidation state ?


(a) U (b) Th (c) Ac (d) Pa (NEET, 2012)

23. Which one of the following does not correctly represent the correct order of the property
indicated against it ?
(a) Ti < V < Cr < Mn; increasing number of oxidation states
(b) Ti3+ < V3+ < Cr3+ < Mn3+ : increasing magnetic moment
(c) Ti < V < Cr < Mn : increasing melting points
(d) Ti < V < Mn < Cr : increasing 2nd ionization enthalpy (NEET, 2012)

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d- & f-Block Element 4
24. Four successive members of the first series of the transition metals are listed below. for which
o
one of them the standard potential (EM2+ / M ) value has a positive sign ?
(a) Co (Z = 27) (b) Ni (Z = 28) (c) Cu (Z = 29) (d) Fe (Z = 26)
(NEET, 2012)
25. For the four successive transition elements (Cr, Mn, Fe and Co), the stability of +2 oxidation
state will be there in which of the following order ?
(a) Mn > Fe > Cr > Co (b) Fe > Mn > Co > Cr
(c) Co > Mn > Fe > Cr (d) Cr > Mn > Co > Fe
(At. nos. Cr = 24, Mn = 25, Fe = 26, Co = 27) (NEET, 2011)
26. Acidified K2Cr2O7 solution turns green when Na2SO3 is added to it. This is due to the formation
of :
(a) Cr2(SO4)3 (b) CrO42– (c) Cr2(SO3)3 (d) CrSO4
(NEET, 2011)
27. Which of the following ions will exhibit colour in aqueous solutions ?
(a) La3+ (Z = 57) (b) Ti3+ (Z = 22) (c) Lu3+ (Z = 71) (d) Sc3+ (Z = 21)
(NEET, 2010)
28. Which of the following ions has electronic configuration [Ar] 3d6 ?
3+
(a) Ni­ (b) Mn3+ (c) Fe3+ (d) Co3+
(At. nos. Mn = 25, Fe = 26, Co = 27, Ni = 28) (NEET, 2010)
29. Which of the following pairs has the same size ?
(a) Fe2+, Ni2+ (b) Zr4+, Ti4+ (c) Zr4+, Hf4+ (d) Zn2+, Hf4+
(NEET, 2010)
30. Match the Column-I (Substances) with Column-II (processes) employed in the manufacture of
the substances and select the correct option :

Column-I Column-II
(Substances) (Processes)
(A) Sulphuric acid 1. Haber's process
(B) Steel 2. Bessemer's process
(C) Sodium hydroxide 3. Leblanc process
(D) Ammonia 4. Contact process

Code :
A B C D
(a) 1 4 2 3
(b) 1 2 3 4
(c) 4 3 2 1
(d) 4 2 3 1 (NEET, 2010)

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d- & f-Block Element 5
31. Which of the following oxidation states is the most common among the lanthanoids ?

(a)
4 (b)
2 (c)
5 (d) (NEET, 2010)
3

32. Which one of the elements have the following outer orbital configurations may exhibit the
largest number of oxidation states ?
(a) 3d54s1 (b) 3d54s2 (c) 3d24s2 (d) 3d34s2
(NEET, 2009)
33. The correct order of decreasing second ionisation enthalpy of Ti(22), V(23), Cr(24) and
Mn(25) is :
(a) Mn > Cr > Ti > V (b) Ti > V > Cr > Mn
(c) Cr > Mn > V > Ti (d) V > Mn > Cr > Ti (NEET, 2008)

34. Which one of the following ions is the most stable in aqueous solution ?
(At. nos. Ti = 22, V = 23, Cr = 24, Mn = 25)
(a) V3+ (b) Ti3+ (c) Mn3+ (d) Cr3+ (NEET, 2007)
35. Identify the incorrect statement among the following :
(a) Lanthanoid contraction is the accumulation of successive shrinkages
(b) As a result of lanthanoid contraction, the properties of 4d series of the transition elements
have no similarities with the 5d series of elements
(c) Shielding power of 4f electrons is quite weak
(d) There is a decrease in the radii of the atoms or ions as one proceeds from La to Lu
(NEET, 2007)
36. In which of the following pairs are both the ions coloured in aqueous solution ?

(At. nos. Sc = 21, Ti = 22, Ni = 28, Cu = 29, Co = 27)


(a) Ni2+, Cu+ (b) Ni2+, Ti3+ (c) Sc3+, Ti3+ (d) Sc3+, Co2+
(NEET, 2006)
37. Copper sulphate dissovles in excess of KCN to give
(a) Cu(CN)2 (b) CuCN (c) [Cu(CN)4]3– (d) [Cu(CN)4]2–
(NEET, 2006)
38. More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The
main reason for this is :
(a) more active nature of the actinoids
(b) more energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals
(c) lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals
(d) greater metallic character of the lanthanoids than that of the corresponding actinoids
(NEET, 2006, 2005)

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d- & f-Block Element 6
39. The number of moles of KMnO4 reduced by one mole of KI in alkaline medium is
(a) one (b) two (c) five (d) one fifth
(NEET, 2005)
40. Four successive members of the first row transition elements are listed below with their atomic
numbers. Which one of them is expected to have the highest third ionisation enthalpy ?
(a) Vanadium (Z = 23) (b) Chromium (Z = 24)
(c) Manganese (Z = 25) (d) Iron (Z = 26) (NEET, 2005)
41. The aqueous solution containing which one of the following ions will be colourless ?
(Atomic number : Sc = 21, Fe = 26, Ti = 22, Mn = 25)
(a) Sc3+ (b) Fe2+ (c) Ti3+ (d) Mn2+
(NEET, 2005)
42. Among the following series of transition metal ions, the one where all metal ions have 3d2
electronic configuration is :
[At. nos. Ti = 22, V = 23, Cr = 24, Mn = 25]
(a) Ti3+, V2+, Cr3+, Mn4+ (b) Ti+, V4+, Cr6+, Mn7+
(c) Ti4+, V3+, Cr2+, Mn3+ (d) Ti2+, V3+, Cr4+, Mn5+ (NEET, 2004)
43. Lanthanoids are :
(a) 14 elements in the sixth period (atomic no. 90 to 103) that are filling 4f sublevel
(b) 14 elements in the seventh period (atomic no. 90 to 103) that are filling 5f sublevel
(c) 14 elements in the sixth period (atomic no. 58 to 71) that are filling 4f sublevel
(d) 14 elements in the seventh period (atomic no. 50 to 71) that are filling 4f sublevel
(NEET, 2004)
44. Which one of the following characteristics of the transition metals is associated with their
catalytic activity ?
(a) High enthalpy of atomization (b) Paramagnetic behaviour
(c) Colour of hydrated ions (d) Variable oxidation states (NEET, 2003)
45. The basic character of the transition metal monoxide follows the order
(Atomic nos. Ti = 22, V = 23, Cr = 24, Fe = 26)
(a) VO > CrO > TiO > FeO (b) CrO > VO > FeO > TiO
(c) TiO > FeO > VO > CrO (d) TiO > VO > CrO > FeO (NEET, 2003)
46. The correct order of ionic radii of Y3+, La3+, Eu3+ and Lu3+ is :
(Atomic nos. Y = 39, La = 57, Eu = 63, Lu = 71)
(a) Y3+ < La3+ < Eu3+ < Lu3+ (b) Y3+ < Lu3+ < Eu3+ < La3+
(c) Lu3+ < Eu3+ < La3+ < Y3+ (d) La3+ < Eu3+ < Lu3+ < Y3+
(NEET, 2003)

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d- & f-Block Element 7
47. General electronic configuration of lanthanides is :
(a) (n – 2) f1 – 14 (n – 1) s2p6d0 – 1 ns2 (b) (n – 2) f10 – 14 (n – 1) d0 – 1 ns2
(c) (n – 2) f0 – 14 (n – 1) d10 ns2 (d) (n – 2) d0 – 1 (n – 1) f1 – 14 ns2
(NEET, 2002)
48. An atom has electronic configuration 1s2 2s2 2p6 3s2 3p6 3d3 4s2, in which group you will place it
(a) fifth (b) fifteenth (c) second (d) third (NEET, 2002)

49. Which of the following shows maximum number of oxidation states ?


(a) Cr (b) Fe (c) Mn (d) V
(NEET, 2002, 2000, 1994)
50. Zn gives H2 gas with H2SO4 and HCl but not with HNO3 because :
(a) Zn act as oxidising agent when react with HNO3
(b) HNO3 is weaker acid than H2SO4 and HCl
(c) In electrochemical series Zn is above hydrogen
(d) NO3– is reduced in preference to hydronium ion (NEET, 2002)

51. Which of the following statement is not correct ?


(a) La(OH)3 is less basic than Lu(OH)3
(b) In lanthanide series ionic radius of Lu+1 ion decreases
(c) La is actually an element of transition series rather lanthanides
(d) Atomic radius of Zn and Hf are same because of lanthanide contraction (NEET, 2001)

52. The most convenient method to protect the bottom of ship made of iron is :
(a) coating it with red lead oxide (b) white tin plating
(c) connecting it with Mg block (d) connecting it with Pb block
(NEET, 2001)
53. Which ion is colourless ?
(a) Cr4+ (b) Sc3+ (c) Ti3+ (d) V3+ (NEET, 2000)
54. Which of the following configuration is correct for iron ?
(a) 1s22s22p63s23p64s23d7 (b) 1s22s22p63s23p64s23d5
(c) 1s22s22p63s23p63d5 (d) 1s22s22p63s23p64s23d6 (NEET, 1999)
55. Which of the following has more unpaired d-electrons ?
(a) Ni3+ (b) Fe2+ (c) Zn+ (d) Cu+ (NEET, 1999)
56. Bell metal is an alloy of :
(a) Cu + Zn (b) Cu + Sn (c) Cu + Pb (d) Cu + Ni
(NEET, 1999)

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d- & f-Block Element 8
57. In which of the following compounds transition metal has zero oxidation state ?
(a) NOClO4 (b) NH2.NH2 (c) CrO5 (d) [Fe(CO)5]
(NEET, 1999)
58. Which one of the following elements consistent a major impurity in pig iron ?
(a) Sulphur (b) Oxygen (c) Silicon (d) Carbon
(NEET, 1998)
59. Which one of the following ionic species will impart colour to an aqueous solution ?
(a) Zn2+ (b) Cu+ (c) Ti4+ (d) Cr3+ (NEET, 1998)

60. Which one of the following elements shows maximum number of different oxidation state in
its compounds ?
(a) Gd (b) La (c) Eu (d) Am (NEET, 1998)

61. Without losing its concentration, ZnCl2 solution cannot be kept in contact with
(a) Pb (b) Al (c) Au (d) Ag (NEET, 1998)

62. Which of the following does not represent the correct order of the property indicated ?
(a) Mn2+ > Ni2+ > Co2+ < Fe2+ (b) Fe2+ > Co2+ > Ni2+ > Cu2+
(c) Ni2+ > Cr2+ > Fe2+ > Mn2+ (d) Sc > Ti > Cr > Mn (NEET, 1997)

63. The lanthanide contraction is responsible for the fact that


(a) Zr and hf have about the same radius (b) Zr and Zn have the same oxidation state
(c) Zr and Y have about the same radius (d) Zr and Nb have similar oxidation state
(NEET, 1997)
64. Which of the following element is responsible for oxidation of water to O2 in biological
processes ?
(a) Cu (b) Mo (c) Fe (d) Mn (NEET, 1997)

65. The electronic configuration of gadolinium (Atomic no. = 64) is :


(a) [Xe] 4f3 5d5 6s2 (b) [Xe] 4f6 5d2 6s2 (c) [Xe] 4f8 5d9 6s2 (d) [Xe] 4f7 5d1 6s2
(NEET, 1997)
66. K2Cr2O7 on heating with aqueous NaOH gives :
(a) CrO72– (b) Cr(OH)2 (c) CrO42– (d) Cr(OH)3
(NEET, 1997)
67. A transition element X has a configuration [Ar]3d4 in its +3 oxidation state. Its atomic number
is :

(a)
22 (b)
19 (c)
25 (d) (NEET, 1996)
26

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d- & f-Block Element 9
68. When calomel reacts with NH4OH, we get
(a) Hg2O (b) HgO (c) HgNH2Cl (d) NH2–Hg–Hg–Cl
(NEET, 1996)
69. The electronic configuration of transition elements is exhibited by
(a) ns1 (b) ns2np5 (c) ns2 (n – 1)d1–10 (d) ns2 (n – 1)d10
(NEET, 1996)
70. KMnO4 reacts with oxalic acid according to the equation

2MnO4– + 5C2O42– + 16H+ → 2Mn2+ + 10CO2 + 8H2O

Here 20 mL of 0.1 M KMnO4 is equivalent to


(a) 50 mL of 0.5 M C2H2O4 (b) 20 mL of 0.1 M C2H2O4
(c) 20 mL of 0.5 M C2H2O4 (d) 50 mL of 0.1 M C2H2O4 (NEET, 1996)

71. Among TiF62–, CoF63–, Cu2Cl2 and NiCl42–, which are the colourless species ? (Atomic number
of Ti = 22, Co = 27, Cu = 29, Ni = 28)
(a) CoF63– and NiCl42– (b) TiF62– and Cu2Cl2
(c) Cu2Cl2 and NiCl42– (d) TiF62– and CoF63– (NEET, 1995)

72. The mercury is the only metal which is liquid at 0°C. This is due to its :
(a) high vapour pressure (b) weak metallic bond
(c) high ionization energy (d) both (b) and (c) (NEET, 1995)

73. Which of the following statement concerning lanthanide elements is false ?


(a) All lanthanides are highly dense metals
(b) More characteristic oxidation state of lanthanide element is +3
(c) Lanthanides are separated from one another by ion exchange method
(d) Ionic radii of trivalent lanthanides steadily increases with increase in the atomic
number (NEET, 1994)

74. To protect iron against corrosion, the most durable metal plating on it, is
(a) copper plating (b) zinc plating (c) nickel plating (d) tin plating
(NEET, 1994)
75. When CuSO4 is electrolysed using platinum electrodes,
(a) copper is liberated at cathode, sulphur at anode
(b) copper is liberated at cathode, oxygen at anode
(c) sulphur is liberated at cathode, oxygen at anode
(d) oxygen is liberated at cathode, copper at anode (NEET, 1993)

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d- & f-Block Element 10
76. The transition elements have a general electronic configuration
(a) ns2 np6 nd1 – 10 (b) (n – 1)d1 – 10, ns0 – 2, np0 – 6

(c) (n – 1)d1 – 10, ns1 – 2 (d) nd1 – 10 ns0 – 2 (NEET, 1991)

77. Photographic films and plates have a essential ingredient of


(a) silver nitrate (b) silver bromide (c) sodium chloride (d) oleic acid
(NEET, 1989)
78. Nitriding is the process of surface hardening of steel by treating it is an atmosphere of
(a) NH3 (b) O3 (c) N2 (d) H2S (NEET, 1989)

79. While extracting an element from its ore, the ore is ground and leached with dil. potassium
cyanide solution to form the soluble product potassium argentocyanide. The element is
(a) lead (b) chromium (c) manganese (d) silver
(NEET, 1989)
80. A blue colouration is not obtained when
(a) ammonium hydroxide dissolves in copper sulphate
(b) copper sulphate solution reacts with K4[Fe(CN)6]
(c) ferric chloride reacts with sod. ferrocyanide
(d) anhydrous CuSO4 is dissolved in water (NEET, 1989)

81. The electronic configuration of four elements are given below. Which element does not belong
to the same family as others ?
(a) [Xe] 4f14 5d10 6s2 (b) [Kr] 4d10 5s2
(c) [Ne] 3s2 3p5 (d) [Ar] 3d10 4s2 (NEET, 1989)

82. The oxidation state of Cr in K2Cr2O7 is :


(a) +5 (b) +3 (c) +6 (d) +7 (NEET, 1988)

83. Hypo is used in photography to :


(a) reduce AgBr grains to metallic silver
(b) convert metallic silver to silver salt
(c) remove undercomposed silver bromide as a soluble complex
(d) remove reduced silver (NEET, 1988)

84. What is the correct electronic configuration of the central atom in K4[Fe(CN)6] based on
crystal field theory ?
(a) e4 t 22 4 e2
(b) t2g g
6 e0
(c) t2g g (d) e3 t23
(NEET, 2019)

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(BEST ONLINE STUDY SYSTEM)
    FOR NEET

A Venture of Helios Educore
Chemistry-: : Previous Years NEET

Topics : d- and f-Block Element

Answer Key

1. (a) 2. (b) 3. (b) 4. (c) 5. (b)


6. (b) 7. (b) 8. (d) 9. (c) 10. (a)
11. (a) 12. (b) 13. (b) 14. (a) 15. (d)
16. (b) 17. (b) 18. (b) 19. (b) 20. (b)
21. (c) 22. (c) 23. (c) 24. (c) 25. (a)
26. (a) 27. (b) 28. (d) 29. (c) 30. (d)
31. (d) 32. (b) 33. (c) 34. (d) 35. (b)
36. (b) 37. (c) 38. (c) 39. (b) 40. (c)
41. (a) 42. (d) 43. (c) 44. (d) 45. (d)
46. (b) 47. (a) 48. (a) 49. (c) 50. (d)
51. (a) 52. (b) 53. (b) 54. (d) 55. (b)
56. (b) 57. (d) 58. (d) 59. (d) 60. (d)
61. (b) 62. (c) 63. (a) 64. (c) 65. (d)
66. (c) 67. (c) 68. (c) 69. (c) 70. (d)
71. (b) 72. (d) 73. (d) 74. (c) 75. (b)
76. (c) 77. (b) 78. (a) 79. (d) 80. (b)
81. (c) 82. (c) 83. (c) 84. (c)

Head office: Offline Coaching :


HELIOS EDUCORE Pvt. Ltd. : Plot No 5 A, Sector- 94, Noida, U.P. 201301 “SURE SELECTION FORUM” : Sector 52 Noida
Email Id. : www.helioseducore.com, Contact No: 9599223002 Email Id. : [email protected], Contact No. : 8010000068, 9599223005

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