(Carl L. Yaws) Handbook of Vapor Pressure Volume (BookFi)

Download as pdf or txt
Download as pdf or txt
You are on page 1of 375
At a glance
Powered by AI
The document discusses different volumes of the Handbook of Vapor Pressure series and other reference books that provide physicochemical property data for organic and inorganic compounds.

The different volumes in the Handbook of Vapor Pressure series are Volume 1 (C1 to C4 compounds), Volume 2 (C5 to C7 compounds), Volume 3 (C8 to C28 compounds), and Volume 4 (inorganic compounds and elements).

The Handbook of Transport Property Data provides comprehensive data on viscosity, thermal conductivity, and diffusion coefficients of gases and liquids in convenient tabular format.

HANDBOOK OF

VOLUME 4
INORGANIC COMPOUNDS
AND ELEMENTS
LIBRARY OF PHYSICO-CHEMICAL PROPERTY DATA

Handbook of Vapor Pressure


Volume 1: C1 to C 4 Compounds (Product #5189)
Volume 2:C5 to C7 Compounds (product #5190)
Volume 3:C8 to C28 Compounds (product #5191)
Volume 4: Inorganic Compounds and Elements (Product #5394)
Carl L. Yaws

Handbook of Viscosity
Volume 1:C1 to C4 Compounds (Product #5362)
Volume 2:C5 to C7 Compounds (product #5364)
Volume 3:C8 to C28 Compounds (Product #5368)
Carl L. Yaws

Handbook of Thermal Conductivity


Volume 1:C1 to C 4 Compounds (Product #5382)
Volume 2:C5 to C7 Compounds (Product #5383)
Volume 3:C8 to C28 Compounds (product #5384)
Carl L. Yaws

Each of the above series contains data for more than 1,000 organic compounds, including
hydrocarbons, oxygenates, halogenates, nitrogenates, sulfur compounds, and silicon compounds.
The data are presented in graphs for vapor pressure, viscosity, or thermal conductivity as a func-
tion of temperature and are arranged by carbon number and chemical formula to enable the engi-
neer to quickly determine values at the desired temperatures.

Handbook of Transport Property Data (Product #5392)


Carl L. Yaws
Comprehensive data on viscosity, thermal conductivity, and diffusion coefficients of gases and
liquids are presented in convenient tabular format.

Physical Properties of Hydrocarbons


Volume 1, Second Edition (Product #5067)
Volume 2, Third Edition (Product #5175)
Volume 3 (Product #5176)
Volume 4 (Product #5272)
R. W. Gallant and Carl L. Yaws
The four-volume series provides chemical, environmental, and safety engineers with quick and
easy access to vital physical property data needed for production and process design calculations.

Thermodynamic and Physical Property Data (Product #5031)


Carl L. Yaws
Property data for 700 major hydrocarbons and organic chemicals, including oxygen, nitrogen,
fluorine, chlorine, bromine, iodine, and sulfur compounds, are provided.
HANDBOOK
OF

4
VOLUME
INORGANICCOMPOUNDS
AND ELEMENTS

Carl L, Yaws
Gulf Publishing Company
Houston, London, Paris, Zurich, Tokyo
Handbook of Vapor Pressure, Volume 4

Copyright 9 1995 by Gulf Publishing Company, Houston, Texas. All


rights reserved. Printed in the United States of America. This book, or
parts thereof, may not be reproduced in any form without permission
of the publisher.

I S B N 0-88415-394-0

Gulf Publishing Company


Book Division
P.O. Box 2608, Houston, Texas 77252-2608

10 9 8 7 6 5 4 3 2 1

Printed on Acid-Free Paper (oo)

Library of Congress Cataloging-in-Publication Data


Yaws, Carl L.
Handbook of vapor pressure / Carl L. Yaws.
p. cm.
Includes bibliographical references and index.
Contents: v. 1. C1 to Ca compounds, - - v. 2. C5 to C7 compounds,
- - v. 3. C8 to C28 compounds - - v. 4. Inorganic Compounds and
Elements.
ISBN 0-88415-189-1 (v. 1: a c i d - f r e e ) . - ISBN 0-88415-190-5
(v. 2: a c i d - f r e e ) . - ISBN 0-88415-191-3 (v. 3: acid-free) - -
ISBN 0-88415-394-0 (v. 4: acid-free)
1. Organic compounds--Tables. 2. Vapor pressure--Tables.
I. Title.
QD257.7.Y39 1994
661 '. 8--dc20 93-34106
CIP

British Library Cataloguing in Publication Data. A catalogue


record for this book is available from the British Library.

iv
PREFACE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii

VAPOR PRESSURE GRAPHS FOR INORGANIC COMPOUNDS


ANDELEMENTS . . . . . . . . . . . . . . . . . . . . . . . . . . 1

REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344
APPENDIX A: COMPOUND LIST BY FORMULA . . . . . . . . . . . . .346
APPENDIX B: COMPOUND LIST BY NAME . . . . . . . . . . . . . . . . .349

APPENDIX C: COEFFICIENTS FOR VAPOR PRESSURE


EQUATION . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 352

APPENDIX D: CRITICAL PROPERTIESAND ACENTRIC FACTOR . . .358


CONTRIBUTORS
Li Bu Graduate student, Chemical Engineering Department,
Lamar University, Beaumont, Texas 77710, USA

Sachin Nijhawan Graduate student, Chemical Engineering Department,


Lamar University, Beaumont, Texas 77710, USA

Carl L. Yaws Professor, Chemical Engineering Department, Lamar


University, Beaumont, Texas 77710, USA

ACKNOWLEDGMENTS
Many colleagues and students have made contributions and helpful comments over the years.
The author is grateful to each: Jack R. Hopper, Joe W. Miller, Jr., C.S. Fang, K.Y. Li, Keith C.
Hansen, Daniel H. Chen, P.Y. Chiang, H.C. Yang, Xiang Pan, Xiaoyan Lin, Li Bu, and Sachin
Nijhawan.

The author wishes to extend special appreciation to his wife (Annette) and family (Kent,
Michele, Chelsea, and Brandon; Lindsay and Rebecca; and Matthew and Sarah).

The author wishes to acknowledge that the Gulf Coast Hazardous Substance Research Center
provided partial support to this work.

DISCLAIMER
This handbook presents a variety of thermodynamic and
physical property data. It is incumbent upon the user to exercise judg-
ment in the use of the data. The author and publisher do not provide
any guarantee, express or implied, with regard to the general or spe-
cific applicability of the data, the range of errors that may be associat-
ed with any of the data, or the appropriateness of using any of the data
in any subsequent calculation, design, or decision process. The author
and publisher accept no responsibility for damages, if any, suffered by
any reader or user of this handbook as a result of decisions made or
actions taken on information contained herein.

vi
PREFACE
Vapor Pressure data are important in many engineering applications in the chemical process-
ing and petroleum refining industries. The objective of this book is to provide the engineer with
such vapor pressure data. The data are presented in graphs covering a wide temperature range to
enable the engineer to quickly determine values at the temperatures of interest.
The contents of the book are arranged in the following order:

1 Graphs
1 References
1 List of compounds
1 Coefficients for vapor pressure equation
1 Critical properties and acentric factor

The graphs for vapor pressure as a function of temperature are arranged by chemical formula
to provide ease of use. Many of the graphs cover the full liquid range from melting point to boil-
ing point to critical point. English units are used, but for those involved in metric and SI usage,
each graph displays a conversion factor to provide SI units.
The coverage of inorganics is comprehensive and encompasses 343 compounds, including
carbon oxides such as carbon monoxide and carbon dioxide; nitrogen oxides such as nitric oxide
and nitrous oxide; sulfur oxides such as sulfur dioxide and sulfur trioxide; hydrogen oxides such
as water and hydrogen peroxide; ammonias such as ammonia and ammonium hydroxide; hydro-
gen halides such as hydrogen chloride and hydrogen fluoride; sulfur acids such as sulfuric acid
and hydrogen sulfide; hydroxides such as sodium hydroxide and potassium hydroxide; silicon
halides such as trichlorosilane and silicon tetrachloride; ureas such as urea and thiourea;
cyanides such as hydrogen cyanide and cyanogen chloride; hydrides such as silane and diborane;
sodium derivatives such as sodium chloride and sodium fluoride; aluminum derivatives such as
aluminum borohydride and aluminum fluoride; and many other compound types. A total of 82
elements are covered, including hydrogen, nitrogen, oxygen, helium, argon, neon, chlorine,
bromine, iodine, fluorine, sulfur, phosphorous, aluminum, lead, tin, mercury, sodium, magne-
sium, silicon, antimony, boron, iron, chromium, cobalt, titanium, tantalum, silver, gold, plat-
inum, radon, uranium, and many others.
The literature has been carefully searched. The following primary references were used exten-
sively in construction of the graphs:

1 Daubert, T. E. and R. E Danner, Data Compilation of Properties of Pure


Compounds, Parts 1, 2, 3, and 4, Supplements 1 and 2, DIPPR Project,
AIChE, New York, NY (1985-1992).

ll Nesmeyanov, A. N., Vapor Pressure of the Chemical Elements, Elsevier,


New York, NY (1963).

1 Yaws, C. L., Physical Properties, McGraw-Hill, New York, NY (1977).

I1 Yaws, C. L., Thermodynamic and Physical Property Data, Gulf Publishing


Co., Houston, TX (1992).

1 Yaws, C. L. and R. W. Gallant, Physical Properties of Hydrocarbons, Vols.


1 (2nd ed.), 2 (3rd ed.), and 3 (lst ed.), Gulf Publishing Co., Houston, TX
(1992, 1993, 1993).

vii
Additional references are given in the section near the end of this book. These primary and
additional references provide full documentation for the original sources used in regression of
the data.
A list of compounds is given near the end of the book to aid the user in quickly locating the
compound of interest from the chemical formula or name.
Coefficients for the vapor pressure equation are provided near the end of the book. Critical
properties and acentric factor are given in the last section of the book. The tabulated values are
especially arranged for quick usage with hand calculator or computer. Computer programs, con-
taining data for all compounds, are available for a nominal fee. The programs are in ASCII which
can be accessed by other software. Contact Carl L. Yaws, P.O. Box 10053, Lamar University,
Beaumont, TX 77710, phone/FAX 409-880-8787.

viii
HANDBOOK OF

VOLUME 4
INORGANIC COMPOUNDS
AND ELEMENTS
This Page Intentionally Left Blank
o o ooo ....................................
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
................ I ' ' :::::::::::::::::::::::::::: =======================================================================================================================

d .................. I A g SILVER ....... i- .......... ~ i-- . . . . . i .......................... f .......................... i ......

10000- ....................................................... i - _ 2 : : Y 2 . ~ 7 : ............................... i .......................... ~............................ ~ = . ~ ~ ~


= ~ ~. .... ":..~.."'2"2L."2..TE.TE..~...:'..:.~.7.:~'::'-~_..7..'2"..-7.TZ2=:Z::::

- t z ::..-z::::::: ::z--_-.--:-z::::

1 nnn ........... ~- ................ -4 t _ . , L ............. ~.......................... 1...............................~...............................


,.,-,,, = = = - - - = = = = = = = = = = = = = - = : . r - = = = = : - - : : . ~ - . . : - . ~ : ~ . ~ . : . . . . . , : : - : ~ e _ ~ z z e : . ~ z e . . : . . : , : : . - : ~ : z
= ~-'="="i~ ~ E-.~-.=I :-':5.~-Z~I2':.E'-" ~--..:~_".-.~!2~ = = ~ i =_.=.2.~-~--=_2" 2:..=-22 .'221213!:.:.:.!2--2 IYK!i!:.!:::::::::::::=========================== .4:::.'..-.::::::::::::
........................................................
-q . . . . ~ . : ................ ~-~ .. . ... ... ... ... ... ... ... ... .. . . . . . . .,." r.". ... . . . . . .
- ~ ~ : . i - .- . . . .. . . . .. . -" . . . . . .:I . . . . . .T. . . . . . . . . . . . . . . . . . . .
. . . . . . .
.......................... .."-...............................
: ............................. .................

/ i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
i- ......................
i9 ..................... i.
i . .
/ . . . . . . ~-
I ......................
I
~ ...................................
i
~ ..........................................
i
~. ..................................
-1"-- "t-" ., .I- " ' ~ ......... t"
I |
~ ~
i
I
t
/'f" i
|
i
i
!
i |
10 0 ~~~~:=:2~:~:~:~:::=:~:~:~::~:~;~::~=::~=:=:~5~:~:~::~5=~=:~=~:~2~2~2~1~~2~~~2~~:~:~:::~~:~~=~:~:~:::~
......................... r.:'=:.. . . . . . = ..................... # .............. = ....... ~ .............................. ~ ......... .-.": .................... ~ ............................... :":i ........ :: ............................ ~ . . . . . . . . . . . . . . . . . . . . . . . . ::::: . . . . . . . . . . . ' " ' " ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . :'-"""
~
. . . . . . . . . . . . . . . t..- . . . . . . . . . . . . . . . . . . . . . . . . t- . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~.. . . . . . . . . . . . . . . . . . . . ~.. . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ............................................. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . .i.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................... .: . . . . . . . . . . . . . . . . . . . . . . ~ ............................ ~ .................................. ..". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . § .......................................

.................. r ............................ ~...................................... t ............................ "i............................ t .................................. .......................................


9 I .............................................i .........................................

1 ~ .! . . . . . . . . . . . . . . . . . . . i.-~
......................................
. . . . . . . . . . . . . . . . . . . . . +~..................................
............................ { ~ ! ! ' ; .................................... ~..................................... ' .......................................... ~............................................
.................................... ~i................................................
..............................................
,m

i i ~ I i i I i
--I . . . . . ~'-- . . . . . . . . . . . . "-"!'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I ........................................
"1 . . . . . . . . ' .1 - - . . . . . I" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I .......................................

o
L_
"!"...................... I"................ ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . 1. ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~". . . . . . . . . . . . . . . . . . . . . . . . Y" ................... "~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ....................................... ! ..............................................
i ........................................
"~..............................................
I ~ I I | i i
. . . . . . . . . . . . . . . . . . . . . . . . . . ;.. . . . . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . L.................................... ~........................................ ~...........................................
::3

t:: ' , , '


0
, .................................. :::::z::_:::::~ i.................................. ,i.....................................
13_
i
I,i, ............................... . ~ . 4 " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . ;"............................... "

0 '
c~ ...... 1 :i . . . . . . . . . . . . . . . . . . . . . . .
0.1
~ ............................. .. .............................. -.

.................. .~~.:EE-!E!E~.:%:.?'EEE.--E%'.'::~!!:~ ::-".s


.............................
> ~"~".7"".7"-':=
r . . . . . . . . . . . . . - ~ L . . . . . . . ";--. . . . . . . . . . . . . . . . . . .
L ......... 4
4.. . . . . . . . . . . . . ~. . . . . . . . . . . . *..;. . . . . . . . . . . . . . . . . . . . . . . . :;.................................... ;

r- ........... f ....................... + .................. i ................... '


9. . . . . . . . . . . . . . . . . . . . ~ ............................. .~
'

i 1 1
0.01 .~ . . . . . . " ~-. . . . . . . . . . . . . . . . . . . . . . i

i / ' ~ : : : : : : - - : : - : ~ ...........................................................
,i ~';. . . . . . . . . . . . . . . . . . . :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
' t ' ' ........................
-]" ............... ~~........................... "..- ~' i .i'~......................................
................................. ~::.....................................
....................................... -,'
~".
'- T i :i ......................................................
i ;I ..................................
[~ ! r i, ,i i ,i J
,".................................. L..................................... [ .................................. , ....................................................................... , ............................................. ; .......................................... !.
0.001 -'7."..'::::1::1:'=:'.::'::.':-'7-':= 7..;=7".:::.".:::..:..:7.."..~-..=.;..=.~.-.====:==:=:=Z=7&~:~=:~22==~=~====:==~=====:=::======~=::======:=====:=::~=:=~=============~:
........................
,,' " 7 2 7".7/.." .7..7.------..:::; ~ " = : 2 : ~ 7 . _ " T - ~ - 2.7..-. Z ~ :""---7..':. 7.".::::=2" 2.5 :~.5~-..7..:.".': ZTET.-.. T :Z::~,:-...52"72:: .5.".":::".5::-.5 :.5::7.."."~:".SZ: :::E:..Z" : : ".5.5:::::Z:
.................... 4- .................................. 4.. . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
t I" .................................. t . . . . . . . . . . . . . . . . . . . . . . . ';.. . . . . . . . . . . . . . . . . . . . . . . . .t
i .................... - ! - , ........................ T ........................ t ......................... [

i ..........................."i.........................................................
!
i !
T,.......................... [ " ! i
1 psia = 6.895 kPa
0.0001 1 psia = 51.71 mm Hg
J " .'... i. . . . . . . . . . . . . . . . . . . . . t

....................... ....... ;. F.-. .. .. ..... .. ... .. ..... .. ..... .. ..... .. . . . . ~t .. ... .. ..... .. ..... .. ..... ..... .. ..... .. .. . . . . . . 4~ ............................. t ................................. 4............................................~...........................................1
! ! t ! ! ! ! !
..................... ~.................. ; ....................... ~.............................. ~ ...................................... 4...........................................4.........................................
I! i I I i i I
i i i i ! ~
: i

1 E-05 I I I I I I I I
1000 2000 3000 4000 5000 6000 7000 8000 9000 10000

Temperature, F
100

AgCI SILVER C H L O R I D E ...................................


u ........... !

.| _ _ ~l ............................ t

0- , ..........
jJ
9 . . l " .. f t ............

1 ................................. i

m n
u~

/
~D

/ I.................................. I

.... ii ii ill iiiiiiiii " ~ , ,


13_ i.
t,.,,,

O
Q.

>
Z
0.1
~-!Z-!!!!!!!!!!!!!!!!!!!!!!!i!!!!!!!!!!!!!!~!!!!!!!!!!!!!!!:!!!!!!!!!!!!!!~!!!!!!!!:!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!

~7_T~-_- ~ i~........!.........................................................
II~IIIIIZZ
....................................... 1 psia = 6.895 kPa ...........................................

1 psia = 51.71 mm Hg
...................................... i

0.01 I t i I
1600 1800 2000 2200 2400 2600 2800 3000
Temperature, F
100 ::::::::::::::::::::::::::::::::::::::::i :::::::::::: I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

{. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

-211111111111111:1111:.....................................................................
111::11 i~.~
!

i i
~o- , I..........................................................
~..................... 4
~
-f--- .
'
.
-
.
-
. .
L
,-
i
i
~ - ~ - ~ - : = ~ !
f. . . . . . . . . . . .
......................
- e - - - ......................... t . . . . . . . . . ~
~~::~:==
" t ................
.......
i ! t i ! ~ i
...................................................
i. . . . . . . . . . . . . . . . . . I-. . . . . . t. . . . . . . . . . . . r ....~ ........ -T . . . . . . . . . .
1 ............................. . I i i i f i ..................................
7. . . . . .
. . . . .
T
t,
i
-."
r ............
4. . . . . . . . . . . . . .
r .................... ~
~
...............................] ................. ..........- .........
........................ i .......................................................................................

-I----- ~ ~ ~ i .....
7-i ...........................................
T.................................
.............................. I, 1 i ........... --b- ..... ~ .........................
if) i I I i ~ ! !

J_j__ i ! w '! ~ ! i
~ i i 9
,t i
~ ! i ,. i
if} 4 ~ i i i
I i +---- .............
........
-I--------" . . . . . ~'
~ - - - i .
"I"--"-""--- ~ ~, ' --
,r'E_ ................. § ..................................... f ..................................................... ,.-.......................................................
L__
-I--~---I i i
....................... t' I
- i, i ......

i................................ T,---,,
! i
i

X-! F........................
- i --" - i" ........................ ~ ................................. ~-....................................
0 i ~
- i L . . . . . . § ~ ...................... ~- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i I
i i
> t I---/" t t....................................i..........................................
i ...............................................

i i i t !
I ,ti . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .............................

'i i
- , /
i I
i / i i i i
0.1- ?. . . . . . . . . . I" t" ...................... t .................................................. T - T Z : : : E Z E E : : : Z Z Z . C - : 7 :
i '~................................. 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i. . . . . . . . . . . . . . i I |.....................................
i. . . . T
i '
t" .................................

t i i "
i i-- .................................. i ...................................
t

-i i
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
!
I [ .........................
i !
! i i J
I !. !I ii
0.01 I I I I
1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F
100~
........ I . . . . . . . . . . . . . . . . . . . . . . . . . . . . t

2 I
~_ ....... _ I AI ALUMINUM ......... i ................. ............ ! . . . . I

.... I

..... ] ........ ~ _ _ _ [

L . . . . .

J . . . . . . . . . . . . . . . .

_ _ J

0.1 . . . . . i- .... !I . . . . . . . ',' . . . . . ,~ ,, _:- . . . . . . ~__(:- . . . . . . . . . . : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :

J_ .... ~ ................................ ] . . . . . . . . . . . .

/ i __

~. 0.01 - ._.

-= i / -
/ i '

u~ 0.001
I--
/
/
0
c~ 0.0001 . . . . . . . . . . . . . . . . . .

...... 3__ :........ :. . . . . . . I . . . . . . . . '. . . . . . _: . . . . . . . . .

I /
I

1 E-05~

1E 06

i1
9 ~.

1 psia = 6.895 kPa


1 p s i a = 51.71 m m Hg

_ k

1, t
1 E-08 I i i i i I
1000 1500 2000 2500 3000 3500 4000
Temperature, F
100.
't '|
_~iiiiiiiiiiiii4 .................... ! ~- .......................................... 4 ..............................................
J I } " ' ~ ............................................. ! .......................
] ....................................
I AIB3H12 ALUMINUM BOROHYDRIDE F . i - ................................... i ................... i

J~.................
Y ......I ..................................................................................................................................
~.::.~i~:...-~.~.i:..-~:~.~[~.:~.~.~.~:..-:~..::~:~.~.~:~:~.~2.:~....-::.-."-~::..

10
] . . . . . . . . . . . . .i. . .
Jiiiiii:iiiiii_:iiiiiiiiiiiiiiiii:iiiiiiii~!
9

i i ' i
[ .................. "..-...........................-r . . . . .

~ . , ~ . . . . . . - .................... i. ........................ ,e............................ ,! .....................

' ~ : Ziiiiii:;iiiii:--i :IIZL-2-1:/


] ~ i : - - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ................... ,'i ................................i ............................
].......................................... i9 ,. 9 9
I I
,t . . . . . . . . . . .~ . . . . . . . . . . . . . . . . . . . . . . . . .i. ................................ 4 .................................. .i ........................
i i i { !

. i.i,,
. . . . . . . i. . . . . . . . . . . . . t ..................... T, . . . . . . . . . . . . . . ........................~, .........................t ................................
i.;................................
i ..............................
Q. i i i i i f ! l
i ! i i i i l i
i.. .............................. j ........................... .-.............................. i ............................ .~............................ i ............................. ~ ......................................... ~ ....................................... .i."........................................ .i. .......................................
i i i i 9 i i i i
i i i i ,.- i i i i
i i i i i i i i i
=3 I i .~ !
! l " " i 9 i i i

1 . . . . . . ...................
9 ~ ................... ~ ...................... ~ .............. ~ ........................ '- .................................. ', ..................................... ~ ..................................... ~ ...................................

i i i ! ~ . . . . . . . ; ............................... :.- ............................... ".-:. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 .............................

13_ . . . . i . . . . . . . . . . . ..-'-" . . . . . . . t ................ "I, . . . . . . . . . . . .e. ................... ~ ......................... ~ .................................... .i ............................... ~ .............................

~L_
. . . . ~ . . . . . 4.. . . . . . . . . . ~ ; ; ; ; ;
O ,
i
"
;
"
I
.......................
-"
i
|
.~
.9 . . . . . . . . . . . . 't . . . . . . . . . . . . .
i
~
,,. .........................
-"
i
I" .................................
-"
i
I ......................................
-"
"
; ............................
"
i
c~ . . . . ,i-.. ................ ~." ..................... .~ ................. ~ .................... ~ ...................... ~ ............................ ~....................................... .I .................................. .~..................................
! i i i i " ": i "

> . . . . ,. . . . . . .....

- ~ ~
,'
-"
................. i ..................
i
i
t .......................
I
i
".,-..................
i
i
t .....................
,
,i } i
t .................................... t ................................... :,........................................ ~ ................................
i i i '."

0.1 ...........................................................................................................................................................................................................................

i .....
................................ r ....................................... [ ..............................................................................
i ...................................................................................
- -~ ~ i-. . . . . . . . . . . . . . . . . . ..............................
9
i
_ ,, t
, 1 psia = 6.895 kPa ...........................
i
i ~ i 1 psia = 51.71 mm Hg
! i ; i i

i i i

9 i ~ i i
i - - i i
0.01 I
-80 -60 -40 -20 0 20 40 60 80 100 120

Temperature, F
1 O0

" T'
AIBr3 ALUMINUM BROMIDE i i .......
i r "

10 ~ .......................................
!.......................
4~_

i ~!~~
~! !
i i ..............................

Q.
f ...........I...
(D
i L

(D
13..
'm.J
0
Q.
/
J ................................... ' I

>
,/

0.1 /
J i
i

r I
/ I
....... l..........................................
./
/ 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

J' i
!
z

0.01 I I
150 200 250 300 350 400 450 500
Temperature, F
100~
! - - ! i
!
! ii iiiii iiiiiii i I ~ _ _ , : + _ _
]iiiiiiiiiiiiiii12111221J . . . . ' .......................!..................................!
~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!1
A,c,3 ALUM,NUM C.LOR,OE
!

i i
1 L
i ............................
!
i
i .............................. ,a........................

i I
I i
!

J I i
I i....................... ,.--
i , t
i i
,t, i i
i j

(B § t ~ I
O_ i t ' i
F,

5--
i !
i

!
G)
aL_
t | !
I
n
~ ......... --4
O
O.
1 ! 1
>
i !
i ....

i i
ii ii
I :
0.1 i
! ! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

9 ' i
+ +............................................................ i ...................................... i ...................................
l ! i i

/
/
i
!
i
!
i
I
t

!
!

!
i .........................

1i
,
l
!
-""....

ii
i
i
1 1 psia
1 psia
= 6.895
= 51.71

i
!

i
kPa
mm Hg

i
i
.......................

0.01 I
i
I
i
I
200 220 240 260 28O 300 320 340 360 380

Temperature, F
100 t t

........................................ i ........................................................
i
...................................................... t ........................................... *
t . . . . . . . . . . . . . . . .

AIF3 ALUMINUM FLUORIDE


i, i
i ........ '
i
1
l

i -]
i ,
1
t ,

. . . .
!
! _ i
, /
10- ,= l i 27
.................... !............. ! /

m m i....................
Z .........................
i

l 'J
o.

(D
I,...

(D
. . . . . 1 i
(D Ii iii / i :
J/ i t
m
L _
ml
O

>
lb.
/
/ I

0.1 9 . t...............................................
:,.........:,,
:i ..... iiiii ............. /s ......... ii;iiii~i iii ...... iiii ....... s i ..................................................... t ...... -2 7 -s ........ ~ ...............................
I ~,/ [ i

t
i

! 1 psia = 51.71 mm Hg
9 . .... I

l
i ' i
I

0.01 -
i
:
!
.
t
:

I
2200 2300 2400 2500 2600 2700 2800
Temperature, F
1 O0 ~ ~ : . ,.. ~ ,
3-~--------~--Z::iZZZ-~ZZZ~-~Z}]~]Z~Z~"~-ZZ~ZZ~!ZZ-~-Z-~-T~--T--~-Z~:~]ZZ-::7Z~-~ZZZf~ZZZZZ~:~ZZZ~iZ7X~]ZZZZ:Z:ZTZZZZZZZ~Z~

i:•::!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!•!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!i!!!!!!!!
10-
.......................... .';................................................. 1 .................................................. F .................................................. ~ ................................................... 4 ...................................................... i- ............................................... ~ .....................................................

........................ J.............................................] ....................................................


i ............................................i .........................................................................
t 9 9 . i ................................... 7 i

t__

if}

L_

0
Q.
>

0.1

1 psia = 6.895 kPa


1 psia=51.71mmHg

i
0.01
Ji !
I I
350 400 450 5OO 550 600 650 700 750

Temperature, F
1 O0
i
.......................
............................
T
i 1
.
i
.

AI203 ALUMINUM OXIDE ......................... I ........................................

/
Ib'"

10

e ~

ffl
if) ................................

i! IIIIIIIIIIITi ..........7 .... [ ........................... J

0 t ............................
I

>

0.1
ili ..................................................

........................................................................

............................................
.t".........................................................................................

r ...................................................................................................

P ................................. I ....................................

.............. iiiiiii ~ ......... ........................................j .......7 iilZ~Eiii~


1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

0.01 i I
E

i
r
!

I
i
J
I I
3800 4000 4200 4400 4600 4800 5000 52OO 5400
Temperature, F

10
100::::::::::::::::::::::::::::::::::::::::: i --i !
3Z-ZIZZZZI
3111111111111111111111111111111111111
AI2S3012 ALUMINUM SULFATE

]i
............................................. i |

i
!
-- i ............................. ~ ...................................... "!"---"-"t
J i " /
/

i i -
J i i
: i i "
i i : i

- i i J
10- i t.......................... + - ....... . t . . . . . . . . . {. . . . . . . . . . . . . . . . . . . . . .
.. . ... . .. . ... . ... . .. . ... . .. . ... . . . . . . . . I~.- . ..........................
.............. ...t .. . ... . .. . ... ... . .. . ... . .. . . . . ,,".. . .. . .. . ... ... ... ... ... . .. - f ............................
.......................................~, . ~~~ ,.............................
i, f .............................
..................................
..ii

. ~ z I ! --7[ ............................i
................................................... .. . . . . . . . ----"r . . . . . . . . . . . . . . . . . . . . : .................... t ............................ i ........................
. . . . . . . .

...................................................... ! ..................... , . . . . . ---t---------V- . . . . . . i- ............ 7 " ...... ~ ..... i .....................


4 . . . . . . . . . . .-'_L.. . . .
i I I/ i i
................................................ _ ! _ . . . . . . . . . ~ ~ ~ . . k ....... .,,<'.
............ L. . . . . . . . . . . . . . . . . . . . . !....................
o
L _
!
. . . .
------m--
. . . .

,
. . . .
~
. . .
|
,
.
,
i" . . . . . . . . . . . . . . . . . .
!
,
1i
-
/ i
7
-~ .......................
| ~ - r
t ...........................
:
i
#..........................
I
i
. . . . . . . . .

(!) . . . . . ~. . . . . . . . . . . .
I
l
i .......................
,
i
-i--. ....................
i
!
i .................
i
I /
"7 .....
-4 ..........................................
~
!
~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

!
,~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i
...............
IL

13_ i i .-" i " i "

L
i I I 9 i ! i
. . . . . . . . . . . . ~ ............................... ? ................................... I" .......................................................................................................................................................................................
i t i i i i
0
i I ~ i i i
i ! !
tl:i
t i -".t"I i i i
I i t I i i

> ! I

1 . . . . -i- ............ !
i ~ , , . } . . . .
!

1 !

i ~ i............... I. . . . . . . . . . . . . . . . . . . .
7 ............................................
/

l | 9

i ." 9 $ ...................................................................
i T

t ! i ! i
i ~: i i
.- ....................................... ! ...............................

l i i
,
i
9 1 i
1 psia = 6.895 kPa
9 i i
"i . . . . . . . . . . . . . . . . . . . . . . . . . . ",. . . . . . . . . . . . . . . . . . . . . . . . . . r,..................... :~............................. ~,................... 1 psia = 51.71 mm Hg ..............................
; I ~ i i
i ! i i I
i i i i I
! i i i ! m
i i

0.1 : 1 "
I I
1 O5O 11 O0 1150 1200 1250 1300 1350 1400 1450

Temperature, F

11
-I 'aJn~,eJaduJa/
08 L- 00~- 0~- 01;,;3- 09~- O~ 008- 0~8-
I I
I.
. .
.................................. 6 H ~ U J LZ'L~=~! s d I, ......................
~cl>l ~ 6 g ' 9 = ~ ! s d I.
. . . . . . . . . . . . . . . .
ZEZZIIIZ-ZI/_I_~I--]EEI-III]ZZ_ZEEZIIEII--IIZT--- ................................... -II IIIIILEI IIIIII IIIIE
:~-~.--~:~...~:~:~-..~.~-.~.~.-...--~--.~:--::---~::~-~.~:...-:::~.---.~:::~.~....................................
iiii 0
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
............................................................................................................................................................... IZo0
7~ ...........
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~.
4 ! . .~.-....~..-~.. .~..~..~."~;:,;:
. . . . . ..;~-~:
.. ===========
i
.................................................................................................... ,.,...............................................
9 ! ............................ f ................................. i '...............................i[
100~ ................................._~ ............= ; ; = = : : , ..............._ _ _ = . , ; ............._ = = - . : ~ = = = _ . . . . . ..1:---. . . . . -:-.=:==-= ...................................................,.........................................=......................................

J ; i IL;;; i;;! " ' l-..~_ . . . . . t. . . . . . ,. . . . . . . r ................... T ................... ; ...................... ~. . . . . . . . . . . . . . . . .


3 ...... ' ' .......~........................................i ......................................" ~ - - - - ' - . . . . . . . . . . . . . . r. . . . . . . . . . i........... t . . . . .
]ZLZZILZZt As ARSENIC I_--_~j~= i........Z Z Z Z I I ~ ~ .............. i............ T..................... 1. . . . . . . . . .

10
] ~ ~ 4 ~ = - - ~ = - -I: . - . ~ = - ~ = = - - - - - = : ; - - - - ~ - - - - ~ =I]: ~ - - - - . - - - - - - - ; ~ - - - -C---t
= 1............................................................................................................................
.... i .......................... r.......................
- - ~ : ~ = = : ~ : ~ : ~ = : : : : : : : : . = ~ . ~ - ~ =,~.............................. :-=~--=~-==:
r ....................
::~!
= ~ = : : : = : ~ = ~ : .,`..............................................
. . . . . .

..........
. . . . . . . . . . .

~ ----'--'---i"~---="--=~=-------~F----------=--=F~=--" ....... ==================================


..... ='i = = ~ -:'-:'~- == = ' - = - =
!. . . . . . .
.................................... . ~ ~ r ............ !. . . . . - " l " - ~ r ........................
T .................. 3 ......7 " ......... .i". . . . . . . . . .
~ZIZIIZIYZIYTYIIIII 7 ......................................- t " ............................... i - ~ - " - - r ~ t ............................... t .......................... i- ...... "---'i".7" . . . . . -i . . . .
3 ................................... I - - ~ - - - T - - - . . . . ! ......... 1. . . . t ~ ' - ! . ........... T................ 7 . . . " . . . . . . . 7 . . . . . . .
7 ......................................... i . . . . . . . . . . . . . . T - " - - ~ - t - - .......... r--- . . . . . . . t . . . . . - I ' , ............................ § ...............
7" ..... ~ - - - i ..................
I i I l '
,I
i ~ .....................................
,
: .....................................
j...... i
",. . . . . . . . .
i
,. . . . . . . . .
i
4. . . . . . . . . . . .
,
~. . . . . . . . . . . . . . . . . .
, /
~.....,~- . . . . . . . . . . . . .
i
4-- .....................
i
4...........................

=~_=-_====I~==.-.===_E_~_--_~-=_-~= ........... =================================

....................................................................
-4.'................. '.................. 4 . ~ - - - - - - L ~ ~ - ~ ................... +."................ ~................... ~................
] L ~ :I ---4, ~ ~ - - 7 ~...........t ................ i ................... ]:....... 1
1 .......................................... !---~ i. . . . . ~~ , - - ~ [ ~ ' ~ - ' - ~ .............
I
O. I J~ . =: ~
]
- ~ - - ~ ~".==--~-~=---~:.-...~--~.~..~::..~-~-.:r~%~--.=:=..~..-~=.-::I:=~:=~====.~..::~=:~=~=~=~:::=~=
. . . . . . . . ;. . . . . . . ; . . . . . . . . ~ . . . . . . . . . . . . . .~. : = ~ = ~ : : = = ~ = = = . . . ~ ~ ~ ~ = -~ : :~: : : =- ~ ~::.-=:::::.-::.-::
- ~ ; . =::::::::
~ . ~::
~ =::
- ..-.~=::.-.
- :::::
` =::r-:::::==::
~ . ~ ` ~:::::::==::::::=
~ : ~ . ~ =::::::
. ~ :::::::
~ .-.:::~::::::
. ~ . ~..::::::.-.:=::
. . . . ~. . .=.=. :. =:=:::
..

~ ~ ~ - - ~ . . . . . . . . . 9. . . . . . . . t. . . . . . . . . . . . ~. . . . . . . . . . 1" . . . . . . . . . . . . . . . . . . . . !" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
:~Z2ZZZZZZZZ2ZYZZZ22Z]~-'~ ~ " ~ * ~ r - " - - - ' - - - - ' - ~ - " - ~ . . . . . . . . t'--- . . . . . . . _~ . . . . . . . . . . . I" ............................... ~ ............. ~. . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ._. - ! - - - . - - - - ~ - . 7
~ . . _ . . . . . .. . .. . .. ._.. . .. . .. . . . . . .-.! ., . .. .. . .. .. . .. . . . ~ ",~.. ... ._. . .. ... .. . _. §=_...........................................................
............
_ _ 7' . . ......_................... ......_..................~.t............................. i ..........................

. . . . . ~. . . . . . . . . . . J ......... t. . . . . . . . . . . . . . . . . . . . . . . .
I i ~ = = /
O. 01 ..................................................................................
=i.. ~ : =-===-] ~ : - - ~ :'=='7".::=: ~ - ~ ' . " - ~ : " " 2 - Z E ~ "."L ~ . = ~ - ~ ! ! E ! ! E " ! . " . ' E ' : . : ! ~ E . : E E - E Z ' E ! ! E E!E-E!E!!E!!!E!.".'EE! E ! ! - ~ " ~
~9 ........... .~...----.~-..4 . . . . . . . . g..... . . . . . . . . . . . . . 4. . . . . . . . . .4 ............... : .................. ~. . . . . . . . . . . . . . . . . . . . . . .L . . . . . . . . . . . . . .

~ i - - - . - - . ............................ .~ . . . . . . . . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . i .............. $ ............................. ";........................................ .i ................................... .i ...............................

" 1 ......................................... t . . . . . . . . -"! . . . . . . . . . "~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t


/ i ~ i i
i
'
I
i. i
,
"
i
i9 I= i, i
,
. . . . . . . . . ~ .................. s......................... =. . . . . . . . . . . . . . . . . . . . . . . . . s..................... :z ................................. i ..................................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . =l=......................................
. =
- - ~ .?E....= . . . . . . . '. . . . . . . {" . . . . . . . . . . . . . . . . . . . . . . . . '
~. ~" ~ - - " ~ " ~ - ~ . _ . ~ - _ Z . . ~ _ _ . ~"~-"-__~.==:~". . . . . . . . . . .-~ :."."~E:=== . ~ . . . . . . . ~ = ..'~.:..-...-"__.~. ~ : : :'."E."~:::: =: = : = . 7 : : =::: .".".:=:::~:-";:==.: "."= ..7"c:: =:::."=: ~::::::::: :.".:::::: =:::."~ ::::.T.:: ~ ":::=.= .7 T_: ::: ==:.-E .".::"_7
~.-...---..-.-~ . . . . . . . J. . . .4' 9 | ..J. L ." J

J ...................... __~
. .

. . . . . . . .
. . . . .
-.- " 1, .. . .. . .. . .. . .. . .
]. . . . . . . .
. . . . .

i.
~. . . . . . . . . . . . . . . . . . i' . . . . . . . . . . . . . . . . . . I ............. i .............................. .'............................... i .................................... ' ..................................... ..................

t
/

O
c~
: ~ : ~ ~ ; --.'= = ~ . " = : == _ - = . = " . ~ = = ' = = = . " ::::=::=:===:=:::~

> ~~~=~[=:=---ZEE!!b!!U:-~E E ~ ~ E EE E E ~ E E E ~ ! { E ! ~ E - E ~ - 7 ; ! ? i E - T E = = = = : : ? t
~. . . . . . . . . . L ....... ::::::::::::::::::::::
I ! i I
. . . . . . . . . . . . . . . . . . . . . . . . . . .

~ - ~ " ........... ~ . . . . . . . . . ~ ..................... f ...................... {,. . . . . . . . . . . . . . . . . . . . . . . . + .................................. ".,'.................................... .i ........................................ ~ .................................

T ~ ~ -?'--i ..................... [...................... i ........................ i ..................................[ ....................................


]........................................
t .......... 1
1 E-05 ~--~----~~-::::--:-:~::~~-~:--~~:-~--:~-~---ia~i~~iii~i!~ii~ii~i~i~ii~ii~iii~iii~iiiii~ii~ii~iiiiii~ii~iiiii~!iiiii~ii~ii~iii~iii~i~iiiii~ii~i~iii:::::::::::::::::::::i t
~I:~-T.--"~'==:="::=:=-='.'.=~ =::::=:::=::=:1
1 ..................................... !. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
"~---------T- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1 E-06 ....................................
i
, .................... ~ . . . . . . . . . . . . . . . . ~............... . . - ~ . . . . . . . . . . . . . .
/i i i i i i
~.............................~................................................................................................................................
i j,
~ ~ ~i ' ..... .. ... .. ..... . . . :. .:. :. .:.: : : : : :-4..
: :.: : .: : .: : :. : :. : :. : : : : : : :i':.:. .:.:. :. .:. :. .: : : : : : : : : : : :4: :. :. .:.:. .:.:. .:.:. :. .: : : : : : : : : :4: :. .:.:. .:.:. :. .:. :. .:.: : : : : : : : : : :. i:-:. -: :. .:.:. .:.:. :. .:. :. .:.:. .:.:. : : : :~.: :............................... ~. . . . . . . . . . . . . . . . . . . . . . . . . ~..........................
........................
=============..............................
============================= _:~. . . . . . . . . . . . . . .
I i | | = ~ i Ii

,,.....................
-, - ~,- - - - - . - 4 ............ -4 , .........
........... .I............
.............. ~t ................
.............. "i .....................
.............. 1] p _sJ_,a = 6:895 }.;_ 1".,".............................
....................
~gI
"11:=_1"17
, ,-- v , ~ ~ .................
~'7'..~" 1. . . . . . . . . . . . . . . . . . . . ~............................ ~. . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . : .......................... ] psla = oi .II m m I__ I'~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . T.,.V.='~.~=::" .= ~.".=."~"='~ ~ , : : : I . ~ : : . % ~ , = : : ~ - ' = === ~. . . . . . . . . . . . . . . . . . . . . . . . . ,i,. . . . . . . . . . . . . . . . . . . . . . . :,~= ::::=.".':=:= -..".:.~:.T.= = " ~ = = = = ==.":::::"::=:': ::::::::::::::::::::::::::::::::::
----'-'~------i..- . . . . . . . . 4. . . . . . . . . . . ,,4 .~ ,i}. . . . . . . . . . . . . . . . .-!-. . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
....... , ............ , ; .................... ........................ , ' , ...................................
~ ~ + - - f .........
................. --4, ',. ~. . . . . . . . . . . . ~ .............. ~-.~-.-.....-~.~-J,.- ...........................
~ : ....................................... 4 ~ . . . . . . . ~. . . . . . . ~ i .~. . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . i............................. 4............................. 4..................................
1 i i i i i ! i i
3------T-- ..... t ............ i t i - t ..............................
t.............................................................
' .................................
41:: t ~ ~ I i I i ! i i
9' - - - " - ' ~ i i i i i i i
200 300 400 500 600 700 800 900 1000 1100 1200

Temperature, F

13
1O0

AsBr3 ARSENIC TRIBROMIDE

10
Z _ i ~ ~ ' ...................
. . . . J

J ......................

,,.,..

Q.
(D
:3

(D j # - - !
........ iiiii ii i i i i i i ~ ~ ......... ii--i-ii-i,ii-iiiiiiiii'i'iiiiiiiiiii!
13_
IL__
......... . / /
0
Q.
>
/
/

0.1
y i

i/ ~ZIIZZIZZ.-Z_-T2.-:I

/]

...................7 ........................
!
i

1 psia = 6.895 kPa


1 p s i a = 51.71 m m H g

0.01 I
i ! ! ..,
i I I I
1O0 150 200 250 300 350 400 450
Temperature, F

14
lOOi ~~ , ................ j. ........................................................
i ....................................... ' ~
I ................................... !..................................
i i
IZL-ZIZZZZEI]
TIZIIIIIIIZ~ZI AsCI3 ARSENIC TRICHLORIDE
!............................................
i....................................
iiiiiiiiiiiiiii ............................................................................... 'i i
L.................................
i
! !
i J
!........................................
f

lj
10-1 r
'
i i .....

l i7

mm

! i
i
1l,,,,. i i
Z3 t !
I 9............................................... I
,t,,

Q ! I. !
..
,}
i i z !

13_ !
: i.
t ......................................... t
[ .
i i
0 i- 1
c}
>
"i~ i: ti. ...................................
~ -ti

! i i i 9 ,'.

I i ' J
i i i

0.1
I i
, i ! !

i i i i
,' T ! 9 ~
: !
.

i ! i
l ii i
I , i
i ......................................i i 1 psia = 6.895 kPa
i i i 1 psia = 51.71 mm Hg

!' I i
/ "I ......................................
i
!
!
!
0.01 t i i !
i t t I
50 1 O0 15O 2OO 25O 300
Temperature, F

15
100
i I
AsF3
I ...........
ARSENIC TRIFLUORIDE
f i i i

10

or)

(D
:3

....................
(D
I...
~ jjl
n J
0

>
~'- ....... - - - - I J~-
. . . . .

I.
1 psia = 6.895 kPa
i.... 1 p s i a = 51.71 m m H g

, l
0.1 I I i i I
20 40 60 80 1 O0 120 140
Temperature, F

16
100 .......... , ..............................
, .................................................................. ,

9 ' ~...... 4 ................................... i 4

J____________l AsF5 ARSENIC PENTAFLUORIDE ................................................


, ......................................................i ...........................................

_]_iiiiiiii iiiiiiiiiiiiiiii] ............................................................

I
l
iiiiiiiiiiiiiiiiiiiiii
iiiiiiiiii.....__i .........................................................................................................................................i....................................................
I..............................................
.........................................................
I 0 ..................... . i :::::::::::::::::::::::::::::::::::::::::::::::::::::::
............................................
:;

l ................................. i ................................ T......................................... T........................................................


[ .......................~ ..........................
F ............................ t ......................... T ........................ r ................................... [ ...... ~ ................... ~ .......................
.............................................. t ............. -i ......................... i" ........................ " ................................................. ~ ............................
i ~ ................................... " ............................................... ~- .............................................. ~ ...................................................... ~ ......................................................... 4 ....................................................
l 1 ! i .....
i i i + i
. . i
- ! ......................................... , ........................................................: ...................................................+ ..............................~ i ..............................................................
............i ............................................................
Q_
_ 'i
, ......................................... .'! ............................................. +!
.... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i" /
....................................................... i
, ............................................................ !
...... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(D I i i / / ~ ." I
i
i i . i i i
L_
i! iI It -
Z3
i i i
t ! I
1 - '.,................................................i .....................................................,. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!,--
- !t..............................
............................. rt ...................................
.................... t1........................................
.. :7:'77Z
========================_~::::::::::::::::::::::::::::::::::::::::::::
................................................... ,i.........................................................:
CZZZ.'.ZZ.'_].ZZZL".; i ZZZC]ZZ]].'..'Z.']; ..................................................................
I i .................................................... t ........
13_ - ~......................................................................................................................... ~ ................................................... ~-.........................................................

I.i
!
- t . I § .................................. t ........................................... T.......................................................
I ........................................................
O I i 9 .. -i
Q. - + i..
, _ , Z _ i I ................................... ~ -! .........................................:.":......................................................
.+..................................................

i
i
! / ,
I i
,
i
,
i
..
> -- ! ...................................... ! ............ ",+". . . . . . . . . . . . . . . . . "i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . F .................................................... i" ......................................................... i ............................................................
i ! / i i ! i
i, i" /'" i,i ,I i" ii

...................................
i...................................................
!........................................................................................
i.........................................................
T.......................................................
~............................................................

i i ~ i i
"2.'----~'---'----";;-'L;-L-';i;"--E';;7"Z-'L"Z-7LZ-i;ZT---LZL--"Z~7 CLL"...-Z.~T"_CZ"L;;;; ;';-;Z:ZZZTZ;;i;;;.-EZTZZZZZ;ZT;;II;i;;;;ZZZ.CZZII77.ZZZ
.......................... i ................................................................................. } ...........................................................
i ............................................................
i ...........................................................
- F ........ ~ ~ ............
T .................................. T ....................................................... i....................................................... i........................................................
- .-". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
! ............................................... t ........................................................... t ............................................................ ~
i ~ ................. i ! .~ I
.............................................................

- I........../ . . ~ ..................... i........................................ ~......................................... : - - - - - - ~ .........................................

- }..~./ ..................... 4 ~ ................ i .............................. [ ................................. 1 psia = 6.895 kPa .........................................

i/ I i i , ~,,a - ~,.~, mm .~
- i.- i- ...................... ' ; . .............................. "-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i i i
i

0.01 " I '


-200 -180 -160 -140 -120 -1 O0 -80 -60

T e m p e r a t u r e , F

1"7
1000_
. . . . . . . . . . t i
l .............

i
lAsH3 ARE31NE [ .........
. . . . .

.......i .................................... ....... :__?


ii ii i i] . .......... z I ........... i ....................................... .,

i ............................... !

i i
i ....................................................................... ! ..................................

1 O0 . . . . . . . .
2 z i ....................................~ : .......................z .................................................... i

; ............. !. . . . . . . . / [ ~-
- , . . . . . . . . . . . . . i . . . . . . . . . ,i .....................

i ......... iil / r .... ' ............


!...................... ~ . . . . . . . . ~ "I .........................
_~.............................
........ r / .......

....iii . . . . . . . . . . . . . . . . . . . . . .
Q.
,i9 ~ /i, 7 ......................................... !........................... i ..............................
! t
(D
. . . . . . . . ,,,. . . . . :. ~- - ....... ::.: :::

[ I ................................

(D
10~ l.....................I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

Q_
0
1 !
............................................................. -L ................................

Q.
> ! ...................... i
i
i............................... i

. iJ
i. . . . . . . . . . . . . . . . . . L ..........................
i

~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . $ ............................................ : .......................................... . ..............................................

1 ......................................................................... ~ ..........................................................................................

, l ! J T
. . . .

'
711111111~iiii~ i................................................. ~i.................................................................................................... , ...........................................................................................
" " ......................................................................... T ....................................................................................

F ....................... 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i

! 1 psia = 6.895 kPa .................................... !

1 psia = 51.71 mm Hg

!
i

,i

0.1.L I I I
-200 -150 -1 O0 -50 0 5O 1 O0 150 200 250
Temperature, F

18
lo~ .....................
:............:: ......................i .............................. !

:::::::::::::::::::::::::::::::::::::::::::::::::::::::: ..... :-
] ...........771171117] ......................... l ............................. ~ .....................

L ................... i ...... ........ _

t /i i

M(
I/ I
i
i!
i /i I i
............................................ ! I
i- . . . . . . . . . . .
/ !
;--i- ..................................
i
.-'+.......................................
i
+" .............................
- l, I
- .i .................................
9
'.i
! i ................ + ....
if) - t t ~ t .....................................................................................................................................
i i i i
t i -~+ . . . . . . . . . . . . . . . . . . . . . . . . . . . T..................................................,,"........................................................+......................................................
i ! i i i i i
i ........................... ,~ .,~,__,_~i ................... .~.......................................... l .................................................... "i .....................................................
i I i i i
!
t. . . . . . . . . . . . . . .
i
"-'? . . . . . .
/
~' . . . . .
i
.'P-" .....................
,
!"" .....................................
!
:" ............................................... "P ........................................
i i / : ! i !
if)
if) ! 9 I/ 9 !
: i 9 i
: i
,i

.......................................... i . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...... i .......................... T ....................................... l .......................................................+.................................................


t i I i i
13_ ! /r, i ~ i +
I._
i / ! i ! t i
. . . . . 7"---"-T ............... T ..................... * ..................................... : ................................................ +".....................................
0 i / 'i i, 'I !" 'i
i / I i i z
! / i I i i i
> ! / J I i i 1
I / ! l I i !

0.1 - - - - - - - -
!/
'

- - ~ ~ - + :
i
i

: : [ -
i
l

...........
,
t
i
:

~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +. . . . . . . . . . . . . . . . . . . . . . . . . .
i
l

[ ................. - . . . . . . . .
................................................/ ~ .......t - - ~ - - - t ............. . .................... ~. . . . . . . . . . . . . . . . .
~ ~ - / - ~ 9 i f ............ ,+- . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . . . . . . . . . . . . . . . . . . . . + . . . . . . . . . . . . . . . . . . . . . . . . . . .
........................................../ - ....... " 9 i ! ....... - 4 .................................. ~.................................... ~ ................................
i i i i + +
........... -• ................ 4 b l- . . . . . . . . . . . . . 4- .............................. l ................................. -i ................................
i; i!, t
+. . . . . . . . . . .
~
- .............................
+
.+..........................................
i
+........................................
! i i i i i
l + i............... - .......... Li .........................................'i ......................................................
l ........................................................
i i

i
' "

l
i
i
Ii_. . . . . . . . . . . . . i
-i-. ..........................
i i
' ..................................... l .....................................
i i " : :
I I i '

! I +i 1 psia = 6.895 kPa


! 1 psia = 51.71 mm Hg ..............................
! I
!
I
i i i

i
! !
!
i
i
! t
i
! I
! i i i
0.01 I I I
300 350 40O 450 5OO 550 600 650

Temperature, F

19
1004 , . ,. .: . ,. ~. ~ .
. . . . . . . . I .................................... i ..................................... i .................................... { ........................ "................................... ! ........................................ i ......................................... i ......................................... i .......................................

4 j i l T - , .........................................................................
] ; ........................................ ; .................. -..l~ Z iilt[i-i[ Z Z:-[ZZ i lIIIIII~IZIII~III:I::I~IIIIIIII I[:IIIIZZII]IIZ:III ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: [ii~:i]iiii

............... E . . C T .OX.OE .............[........................................


i ..........................................
i .........................................
..........................................
i ........................................
. . . . . . . . . . . . . . i ................................... t ......................................... i ........................................ i ....................................... ~......................................
] ~ _ 1 ] ............................................................................................................................
T.....................................i ....................................L..........................................
~.........................................
J..........................................
j ..........................................
t
- { .................................... ; ...................................... {"....................................................................... r ......................................................................................................................................................................
i L i

! i i
a .................................................................................
i .............................................................................T...............................................................................................................................
] ...........................................
~ t

i I

i 1 i ~ i ,
-- 4 ......................................................................................... g ....................................................... ' ........................................................................................................................ "!..........................................
10 _ +.' .......................... ;T........................ t"................................ i' . . . . . . . . . . . . . . . . . . . 't ........................ rr ..........................................
r ....................:::::::::::::::::::::::::::::
" r":: ....................................

t ................... ;} ....................................... i ................................... .':........................................ T....................................... T.......................................... T..................................... r ......................................... i .......................................... i ...........................................
....................................... ~I...................................... ~I......................................... ~I......................................... ['.......................................... ~~.~~~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.!~.~.........................................
.~.~.~.~.~.~.~.i~.~.~.~.~.~.~.~.~.!~.~.~.~...........................................
~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.~.!~.~.!~...........................................
.~.~.~.~.~.i~.!!~`~',
................... : ......................................... T......................................... T.......................................... T.......................................... t ....................................... : .......................................... ..."......................................... ~.......................................... I ...........................................
/ J ! ! ! i / i i i !
o .,.,,,
"~ . . . . . . . . . t ................................ t ................................... t ..................................... t ..................................... ! ....... ~ ...... ".T ........................................

13. J ~ i i t-i, i i i i

:3
O3
o3 :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
1
::::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
1 1
12122211121212121222112111112112211122222

.................. ~ .................................... ~"..................................... t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .


................... i .................................... 1 .................................... §. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
................. ]i ....................................... ]t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

0 ...................... T.......................................1..........................Zi .........................................


[ .........................................
t .........................................
! ..........................................
r.........................................
i ..........................................
i ..........................................
Q.
i 7 ............[ .........................................
i .........................................
T........................................
T.........................................
i .........................................
] ..........................................
T
> - t .......................................... f . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

9 /I i i t ~ i i i
! / i i i ~ ! i i !

............................... !...~~:~!~::~ ......................................


~..........................................
i ..........................................
~..........................................
~..........................................
~..........................................
~...........................................
~...........................................
..,L..-..............._.........$....

....................... 7i " ..........................................


i ..........................................
f ..........................................
f ..........................................
f ..........................................
i ..........................................
f .........................................
~..........................................
! ...........................................

2' .......i ..........................................


!.... i ~ i ~
.............. -7" .............. i ..........................................i ..........................................t ..........................................t ..........................................f ..........................................i ................................... ~ psia = 6.895 kPa 'i ...........................................
i i i i i i i ~ psi~ = s~.7~ turn H~ i
............ I/
.......... Ii.............................. ii.........................................
; ..........................................
~..........................................
i ..........................................
~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~...........................................

, ! ! i i
i i i ~ i i
I i i : i
i
0.01 I I I I
400 450 500 550 600 650 700 750 800 850 900

Temperature, F

20
00 ~ : ! :::::::::::- :::::: : : ....... : ...............................................; . . . . . . . . . . . . . . . .
............:r::----;...........-::.-.-:
.......--+ ................... ~ ....................................
:::::::::::::::::::::

~IIIIIIISIIIIIIIIIIIIIJIIIIII] ..................................... | ...... ,


] i/iiiiii...... iiiiiil/l At ASTATINE ! .............................. , ..............
_. . . . . . . . . . ~| '~

...................... ! ....................................... j ................. i ........ ~ ? ................. "

1 I I HI .......................................
iiiiii i_ ! ..................
S ~ ................. _.'.
.................

==========================================
...................
;-- ..,./,i i,~ ....i i . . . . . . . . . . . . .

' i + i t

:.- : t
c~

c~ 0.01= I i ! !
- i i - - - -
t f
G) _
... ._.

i i
l
0.001 = ' ~ . . . . . . . . . . . . . . . . . . . .

G) ~, !_,
-----------~
_-

_ I - - T 9 ! }
{-- ................................. ? ............................................. .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

0
c~ o.oom - i i + i
c~
> t .............................
...........................
~ .......................................
9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4 ..................
4 .............

F-- . . . . . . 4.
i i
.

. .}
.............................. j +
! i
!
+ i
1 E-06
! t ........ :+.........................................................
i
i t +
T i
i i 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
..., ; + +
:9 ! . {
! | - .:
+ ,;., ,.,
E i i
i t ;
1 E-08 I I I I I
100 200 300 400 500 600 700
Temperature, F

21
0 0 ~ :_ ::___:___ ::: .... : : : : : : : : :::~ : . : : : : ::: :: .......... : :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: . . . . . . . . . . . . . . . . . . . . . = = = = = = = = = = = = = = = = = = = = = = = = = = = = ............................... ,~

IAu GOLD !:-: : ................... l ................................ ] i I---" .........

0 ~ .,,
I I*,. .i ......... I .....................................
1 i ~- ................................
; ......... .. :.:. F : " T " ~ ' i ' :~:::-,~::-~:t?:::"::-:-~_'~ . . . . . . . . . . . . j
i " l .............. - --:-..: --.~: :~:::::::::::::::::..-.... ::::::::::::::::::::::::____._ _-=~.,~176176
;::::::,,: [ . . . . ==============================================================

: i .... I ..... : " . , ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

[ .,I i

0,1~ :~.
: . . . . . . . . . .

..:. :.-::: :::: ......... ::-----:-::::: :i -~- :-:--


. . . . . . . . . . . =====================
.........:::::::::::::::::::::::::
....... -':=::--:"::Z :,:~--::Z'-_::~-::
........... . . . . . . . . . . . ~,~!~E,~-'_---'__-~L-:

.,=,.=

Q. 0,01
(D . . . . . . . . . . . . . . . . ~, . . . . . . . : 9. . . . . . . . . . . . . . . . . . . . . . . ...... _ • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~....~ . . . . . . . . . . . . . . . . . . . . . . . . 9

-.- . ..... / 9 i .................................


/
O, O01 ~. . . / . ~ ,
(D
.. ......... . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . . . . . . ........... :.-.:.:...: ........... , ....... ...... . - ...... : ..... . ........... ::..::_ ...... '.,'---7_T__Z:Z::~tt~,~,_,,,_~,-..-gZ.;-~j
---, _ ; . . . . . . . . . ......... i .......... i . . . . . . . . . . . . . . . . . 9
.......... ~ ....... ,i
I.__ ~,
9 , i . . . . . . . . . / , ,i ........... ..... ~_ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
fl _ .

; .............
.... ..
. /
! .... :
~- . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
_- ........ 1 ......... , .. ~ .............................. J

O
-- " ". . . . " / ~ ~ . . . . . . . . . . . . . . . . . . -- ............... I. . . . . . . . . . . . . . . . . . . . . . 3

c~ 0.0001 : -::::: ....... .....:~#-=:A ~ ............ " . ~ - . ~- ......................... .... :: :=,::::::==.-==',


>
: ................ .... . .............. ,_. . . . . . . . . . ..--__.-- ........ ....
9 ~ - - .--:---__::,

- E .... :::::::::,:::,:::/: i : .........!: . . . . ! : ......... ::::::::::::::::::::::::::::::::::: ...........................' ..............::::::::::::::::::::::::


: : G i
.............: ~ . : .......................... - -: i - ~ '~:::....--.-.-::

l .

.......... : : . . . . . J . . . . . . . . . . . . . . . . . . . . . . . . . a,,.. .................................. ~ ........................

, ........
LI._:_:,_: . . . . . w'--'------~ ~ - - - - - ; . . . . - ' ~ ~ ~ : , ~ ' Z ~ -_': .......................... ~- .....................................

!!!! !!:?
:::::i
1:
IE 07--....... I
- "~ :'::' ~::: L : i
f:: :: _~ ::: : ................. :. . . . . . . . . . . . . . . . . . . . . . . . . . . ~-~-=-= 1 psia = 51.71 mm Hg
-- ! z
! !
. . ..................................

1E-08 I
1500
1
2000 2500
L 3000 3500 4000
I

4500 5000 5500


Temperature, F

22
100-, ++,,,,+++,++++~++++,++++,,+~,+,+,~,+++~. . . . .
........
=============================================================================================: :
9 .................. ,
+: _: :::::::::::::::::::::::::::::::
........ 9 . . . . . . . . . . . . . . . . . . . . . . . . . .. -.-.' -.- . . . _ _ ' " ~ . . "
:::::: L ~ ::::::::::::::::::::::::::::::::::::::: ...... .:LL:
,
"

.7. . . . . . . . . . . . . . . . . . . . . . . . . .]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [. . .
B BORON I~iiiii+i+iiiiiiiiii+i+~+_.'~__--~.__. _I~T_~--_----~2;::ZTY_-Z--]
, ............................................. , .............................................. ; . . . . . . . . . . . . . . . . . +~ .!

1 o J .........................
I_.= .... _.......+ _ [ . - - = ~ i = ~ . . . . . . _ i _ ................ t...................... ~ .......................
= ~ ~ . - . . . . . . . . . . . . .
-,..-=-=-====+,+++~+-.--=-++,+--=
++~. . . . . . . . . . . . . . . . . . . . . . [ ......................................................
~I .......... T-_..=====.F=:=====..-.-_~+--_-_+:.-=_=-+
-+ : +--. . . . . . . . . . . . . . . . . . . . . .

............................. .+................................... .r ............................................t .................................. 1 l 9 .L___

--ITTTL22LL~21111~I2LLL]II i171~............................ i I LLL L__LL........................ ,+....................................... I ............................................ t ........... -+7


~1]i]iiiiiii iii-iii-[--- i . . . . . . . IIIILI/i i/ii i/iiiiiill i [ .............
..................... t ......... " i
. . . . i--7-]

+'
~l++i~i++ +++!+++++++++++++++~+:!!!!!!!!:!!!!!!!!!!!!!!+~+~' _ _ + ..~ +

~
O. O. 01 =. _ _ ~ +i +- - -
:;~--:-~• I+ i ~ : ~ - i - - N ~ N i - i i ~ ; - 2 . : - ~,-.:.~.2.~..- .g.i -.~...i.................................................................
......................
t ......................... ~....................................
(1) - --+--------.i. i-!"..........
.............. .+ ,.~
9 1........................ 4..............................

,9 i............... 4 ............................ +."................................


- "TI.."
t ......... i----/
!
, , ,
if) + ~ I ' i i
m 0.001 +, p..-~
............. ..". . . . . . . . . . . ..~ . . . . . . . . . . . . . . . . .
+.
"... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ..................................... .~

. . . . . . . . . ,r.. . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . -,
s,.__ ~t. ______+~t.. l t + +
t'3 - + {" i".................................. ~.............................................................
]7---_ ................... +...... ! i I i. i. +
I---7--I ! i i
,..__

o 0.0001
7'IITI i
+.___ +--
> -
+ 7 - .............................................. + ...........
L~
~--'T"~--um~
i
.,.-7 ~ . . . .
i : - - - -
~
it
i
,'! i! i i!
1E-05~ !
__--~--+-=---~
.+.

9
...... ,+.............. 4
++
.+
*
+

1
i! i: i i! i! I
1 E-06
I + .t
, +..
, .+ r L... ; i +

f iiiiiiiiiiiii
............+
+.
+'
..............................................

'"--
.+". . . .
------'-:!
z' .....................
t:ii+-' +
t:::: I 1 psia
~"I
1 psia = 6.895
= 51.71
kPa
mm Hg

----I "~ !--+=-+-+++++???+??i????+???????????7i_ : "]


.... t .........................
iii~!.........
ZIZZZZZZZZZ! ................................ l: ............... i
] ............ / l !.... i | i t "+ i
-'/ .........................................."i-! 't+ " t+ [, t, i

1 E-08/ + i +
,, ,i ,, ,, I
I I
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000

T e m p e r a t u r e , F

23
1 O0

fl
.

BBr3 BORON TRIBROMIDE

,.=

J
10- m

................................ ............................................................

>
1-

............................... t .............................................................

t 11 psia
................................ psia == 51.71
61.895mm
kPaHg ................................

I
0.1- T [
20 40 60 80 1 O0 120 140 160 180 200
Temperature, F

24
1000 .................................
~ii~_~:i:::~;~i~i~iiiiii~iiii::::~.::::::::::~~E~. .......................................................... :,[................................................ ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . :~ZE'TT...'~:Z:T"..C..'.:---_'Z.:E-Z.Z.-..
I ................................ '.. . . . . .~
zl ...................................
i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...................................................................................
~. . . . . . . . . . . . . . . . . . . . . . . . . " ............................................. .i:'..................................
4
3,....................................
! BCI3 B O R O N TRICHLORIDE ---§ .............................. ,'...................................- : : ~ J : ~ ' ............ ]1

_1 ' f ! .~__J ............. 1

t' r t
i
!

| !

l i

to
= ,,.=B

c~

I,,..

0r)
(D
13_
O
C~
t0
>
0.1

0.01

1 psia = 6,895 kPa


| 1 psia = 51.71 mm Hg
i
i I [
I
J
...... i .........

i
0.001 I
-200 -100 100 200 300 400
Temperature, F

25
1000 ] .....................................
1 !
! i ....................................... j
!
. . . . . .

BF3 BORON TRIFLUORIDE ~-~-_i--~-ii~-~.~i . . . . - ~ . ~ ................ '


_ _ _ , _ _ _ _ _ ...............................................................................................

1 O0

,m
Z.

(D

or)
(1)
13_

0
c')
>
10

/
...................................... i ................................................................... i
l

2111iiiilliii/ ....................................................... i .....................................................................

1 psia = 6.895 kPa


...................... 1 psia = 51.71 mm Hg ..........................................

1
-200 - 150 - 1 O0 -50 50

Temperature, F

26
100j ........................................ _~
I ! i ...................................
[ .............................
i'
T
3111111111:ii:11111:iiiiiiii
: iI
BORINE CARBONYL i i
................................. .................................... "i.'

!
| !

9 |
i9 !
/

I
il i
i
illml
........................................
9 "I ..................................... I,

Q.

d
i i i
(B
4".................................. 9............................................... q
I

I 9 =

I
! i, t ..........................
|
t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4'
:

!.__ ! i

Ji
I .

0 !
ii i.
c~ . ............................................
.
,b................................................... 4

> i~ ~r....
/7............................. ~ 1 i
r "~" i i! i
i i
' t'

i i
i i

,i / i, i, iI ii
/ ! t ! i

0.1 ;-.--.f-- ...................


~-z" .................
~ .............................
4 ..........................
~. . . . . . . . . . . . . . . . . . . . . . . . . . . .
~
; ................................................
i - ..........................................
~................................................... 4...........
~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ..........
i + ................................... : ......................................... "i .......
................................................................ i .............................................................

i I i i ;
,I I
i,......................................i,.........................................................................
.
,
1 psia = 6.895 kPa
'.
,} . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
i .......................................
i
+ .............................................
i
~ ..........................................

i ! i i 1 psia = 51.71 mm Hg
i ! '
, i ......................................... 4............................................. .~.........................................
' i i i
i i I ~ i
I 'i i i'
0.01
i i ! ! i
I I I I
-220 -200 -180 -160 -140 -120 -1 O 0 -80

Temperature, F

27
8E
.:1 'eJn],eJadLu81
OOg Os OOg 0s I. O0 I. 0s
I, I I I I~0" 0
!
|
i
............................ j 6HLUU~ L Z ' L s I. I
i s ed)t= e!sd L
I '
Ji
....................................................................................................................................................
i
7Z2:ZZZI-I:ZZiT~::Z-~::Z:7_-..Z:I-:T-J
L'O
<
"13
0
"13
(1)
o~
(-
wi
(1)
13
m , i
/ . . . . . . . . . . . . . . .
CllOV Off:lOB 80erie
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiFI
i " t, I OL
1 vvu ...................... 1 ....................... |. ,, ................. |. . : ._ .............................

J,_L_ZZZZZZ]I
] .......I B2D6 DEUTERODIBORANE ...........................
]IIIIIIY IIZIII .........................................................................................................................................................

lO!_.................... I , t
! ........................ i ..................................... T. . . . . . . . . . . . . .
. . . . . . . . . . . . l l I

.................................. [ . . . . . . . . . . . . . . . . . "! . . . . . . . . . . . . . . . . . . . . . . . . . "~ . . . . . . . . . . . . . . . . . . . . " - - "

] .................. _____, , -r, -7" ........ i .................... T -


-T~
. . . . . . "mr . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T ............................. "4" . . . . . . .

I ! T , ,
1 ................. , , , ................... l ............................. ~ .......

l .........................-F ........ '!........... ~! . . . . . . ~. ................... ,I................................,i..........................


i -r , r-7 '~ -i i |

I. i, ,i i/ I' J' i
4J I ! !
I ~Z~Zi~i~iiiiiiiiltiiiiiiltttttT'Tiiiiiiiiiiltti-"1,--~--T
. . . . . . . . . . . . . .
J .................................
.................. I............
~ ..................................................... ~ . . . . . . . . . . . . . ~. . . . . . . -1',.,. . . . . . . . . . . . . . .

if_ 9 ........................................i..-..- - - - - - - - - - - - 1 . . . . . . . . . . 1
I I

J ............................................. !- - - - - - ~ - - / ..... t "- ............... i....................~ . . . . . . . . . . '


...........................................................
9 ~....................................................
~ . . . . ' L _ ............................. i ................................ 1. . . . . . . . . . . . . . . . . . . . . . ,
/ /
> - - J ........................................................... [. . . . . . . . .. . . . . . . . . . . . . . . . . .

/ i
/ i
! i
/ 1
/ i
9 i / i i i i i
" d - i !
/
, i i i i ,
O. I -I-------- ::_-----_____-~::m-,-':-: .................... :................................. - ...................

/ i
-
........................................................................
,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
t -,4
~ , i
] ..... / i ! i
J__ . iiii ! .............................................. ii ............................................................ '~........................................... ~. ,!

] ....... i
1 psia = 6.895 kPa
I
1 psia = 51.71 mm Hg

i
i
i
9
!
i
! i
|

'
I!
i.
0.01 I i i I I
-260 -24O -220 -200 -180 -160 -140 20
Temperature, F

29
OZ:
3 'oJn:leJaduJa/
O0 I. 09 0 09- O0 I.- 09 l.-
I I
I i. 1.0"0
6 H uJuJ LZ" L9 = e!sd L
ed)l $ 6 9 ' 9 = e!sd I.
...-.-.-i.........--i
i,l.i, ......11__ ............... i ................ i . . . . . . . . . . .
i i
' T ~_iilLiiiiiiill iiiii' 1'i'111
;/
[/
- -/ I.'0
= ..... i'
<
. . . . . . . . L 0
. . . . . . . . L
9 [ii .............~ii'i ........... .... : , _ ....... L
"13
{n
o~
c-
Gg

i i
r/ m Q
i
= . . . . . . . . . . . . . . . . . . . . . . li . . . . . . . . . . L
........ 01.
TF ..............................................................................................
3ClIIAIOI=IBOIdGAH 3NVEIOBICl JIBSHEIB
.!
...............~" ' ~ -00
1000 q ..................~............. ~, ~............................................. i, -.: {,
::I:: ::::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::
:1:
]
...........................
i...............
" f ~...... ........

~-;Z]
[
, r ..........
i..............................I....................... T ....................
i.......
========.......... ===========[==
===l==i::::i
==.......................
...... ~ _

] ....I.........
T i ~ i !
.................................................

.................................
l ~ ~ 9

I00~---........................
!......................!'
............... [ ~ - - ~ - ~ - ............i.........................
.... ii

em
f~

Z~

13_
i I
0 '! I
: --,}

>
i i
i- ........................................i [ [
: f .......................... . ............................. i
I I , , ,
,I i '
i
' i i
I. i i ~.9..........................................i.I.......................................4.'
! i i

i i i 1 i
i ! i ~ i
0.1 I !!...............,!........................
J..........................................
L..........................................
i
i i
;
i, it ..............................!
i I
-'-~- ......... 4 ......... |
I
1 psia = 6.895 kPa
I F ......
1 p s i a = 51.71 m m H g
[ i........
, i ! i
i i
! i i;
I 9 ! , i ! i
o.oll I
i
I I I I
i
I I
-300 -25O -200 - 150 - 1 O0 -50 0 50 I O0
Temperature, F

31
100_.

B3N3H6 BORINE TRIAMINE

J
10-
f
,L

!iiiiii~i............ii.i ................i ~ il
, f

. , i

CL
e,,
J
(D

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(D j I 84

13..
7
0 /
Q.
/
>
/
0.1 _- z ...............................................................
I
i

/
/

/ 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 mm Hg

0.01 -
-1 O 0 -50 0 50 1 O0 150

Temperature, F

32
100~
!

J ........................
I B4H10 TETRABORANE 1
~ T Y Z ! .............................................., ....................................................................

I O ~::::::::::::::::::::::::::::::::::::::::
. . . . . . . . . . . . . . . . . . . . . . ...............
. . . . . . . .~. . . . . ......................
.............................................. ....................................... q r .............
.........
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I .................................................................... I .....................................................

-l~~--:z_-:--: : i..................................... :::::::::::::::::::::: .................................................


] ~ ...............................................
i .......................................................................
................................................I- ..............................................i .............................. ~ ........:::::::::::::::::::::::::::::::::::::::::::::::::::::::......................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................................ "4 ........................................................ " ................................................... !

i i i ...........................i ..................................................................................
o,,~, . . . . . . . . . . . . . . . . . ~i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii . . . . . . . . . . . . . . . . . . . . . . . . . . . . . §, ................................................................ ~i ..................................................................

Q.
i !
i l i i
O ................ i .................................... r ........ -Y- ....... f .............................................. f ...............................................................
i i / i i
L _

I= I~711111111111?IIIIIIIIIIIIIIIIIIIIIII~~~-Z'I.~~Z~'~I:Z{LT~III.__.__4_
I ~
J ......./ :-~~--~'~-'~'--'i--'~---ZZ3--~:7;ZZI:7~-:7-ZZ'z-:~Z:Z'Z:ZZZZZZLTLZZ
h i .....-ZZ:
o
!,__

.- . . . . . . - - ~ ~L . .-. . .~. . . .-. . .-. . .~. : : : . L T - ~ I-Z Z]Z;- ................................. -:r ...................................................................
. . . . . . . . . . . . ................................. .. . . . . . :! .............................................................................
..................................................
O
Q.
. . . . . . . . i.................
_ 7 ........ i............................................ t ..................................................................
i.............................................................. !
>
. . . . . . . . . I .............. . t ......................... --t ...................................................... ~J..................................................................
i / ! ! i
. . . . . . . . ~. . . . . . . . . . -/ i ....................................... ~,................................................................ ~.................................................................

oi .
-
. . . . . .
~
/
~.
i
:iT_L_--=---
~
!...........................................
;
i...................................................... ,.....................................................
!
Z:i: ~. . . . . . ~ r....................................................
- 7--r i ......... r................................................. t ...................................................
]............................................
...............................................
/--i
. .9~ ~ - . t , .
!.4... ..... ... ..... - ti....................................................... i ..........................................................
........................................................ .i.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
/ ! i i i
. . . . -/~-~[ ~ . !. ~
4 . . . . . . . . L. . . . . . . . . . . . . . . . . . . ,' ............................

i I i
- ------7 z i .......................................... t ................................... t ...................... I psia = 6.895 kPa ......................................
/ j i i 1 psia = 51.71 mm Hg
............ / "+ .............................................. {'.................................. - ................. -i::. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

' I
0.01
I I
-150 -~00 -5o 0 5o ~00
Temperature, F

33
1000 + {

--I1 I i ~:~§
! !

B5H9 PENTABORANE

100
f
l
J':i

o3
u)
1:3. 10
/
r/
Q~ /

s
Q) /
I J....
I

/
IL._

s 1
!
O i
1:3.
> /
!
/ i
1
]i
i....................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

0.1~
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
J

i
0.01
!
I I
-100 100 200 300 4O0 5O0 600
Temperature, F

34
100 ,
......................................
ILL ....... 1 [ [ ..........................................................................................

1 TETRAHYDROPENTABORANE .......... _ ~ .................................

10 - I, ~;. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ZZZT_':E:Z: 7.ZTTZZ:"TT'7.:~Z-'-7::


- ! T............................................ ' .......................................................... { ........................................................
- ~ .................................... ~t....................................... ~i........................................................
!!!~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!'~ ...........................................................
- . ................................................................ t .............................................. ~t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................ t ..................... r .................. [ ....... ~ .....................................................


i
.................... I ....................................... I' ..................................... ~ ........................................... T.................................................................. T.........................................................

lm i I i ....XI ..................................................................
i
7 ............. F ........................... T - .............................. i .................. 7 .............!.........................................................
i............................................................
J__ l
i= i, / i: i9
7 ............................................... -r . . . . . . . . . . . . . . . . . . . I- . . . . . . . . . . . . . . . . . . r. . . . . . . ~ ....................... ~ ............l .............................................
L / ii i~ i /
i
ii ii
/ i i i/ i i
1 _~. . . . . . . . . . . . . ................................ ~............................... ~ ..........,:...............................................................
t ~ . . w / _ } ! }-= ~-=

n
L_ . . . . . . . . . .
............ "1".,..................................
...........................
,..".......................
.............................. t .................................... t ................................................................ " .........................................................
====================================================================================================== .............................................

L
4 ............... 1.............................. b ................ ~ ...... { ......................................................
0
c~
...................... T,........................................ ?~.............................................
i~il-.-_-Jll i,~iiii~-i~iiiiiiii~iiiiiiiiiiiiiiilJiJiiill
....................................................... "s.................................................................
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii,.................................................................
ii........................................................

J E i i i
> ~- ........... ~.................................. r / - ........................... F .................................... l .......................................................i ..........................................
l

i- . . . . . . . . . 1. . . . . . . . . . . . . . . . . . . 7i .......................... I .............................. i .................................................i ......................................................


! /! '
i
"
i
!
i
i

0.I .... ,-i- ..... _ ______.__..Z__ :::::::_. ....... ::::::::::::::::::::: : ...........................................


. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1 i
i
. . . . . i7" ............ F ...................... r,................................. F I ..... i
. . . . . . ~ ................................... { . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................................... tl 1 p~!~ -- 6.89s kP~ ..................
/i i i i 11 psia = 51.71 mm Hg
. . . . . . l .................................. i .......................................... t .................................................. !1 .................................
i i i i
J i i ~ i
! , i i !
0.01 i i
-1 O0 -50 0 50 1 O0 150 200

Temperature, F

35
10

B10H14 DECABORANE
i
.......................................... i

I r a .

.u

Q.
(D
r Z
(D
13_
O
Q.
>
0.1

, [.......................................

1 psia = 6 . 8 9 5 k P a
..................... 1 psia = 51.71 m m Hg .........................

i
i
l
0.01 i I J i
100 150 200 25O 30O 350
Temperature, F

36
1 O0 ~:::::i::
...........................................................
::::::::::::::: ::::: :...........................................................................................................................................................................................................................
......................... _ | , . ............. ~ m,.~, ................................................... ~ ...............~ _ ~ ........................................

3-:::::::i:--::11111:111::i::11111111
]:: :- :_::::: ::1 B a BARIU~ .....................................................

................ .............................. :-:-- . . . ~ . - . = ~


-::::T:T--:T:i:i::::iZi:ii:Z:::::::::::::::::::::::::::: ......................

i 2::::::2::222:2222::22:::::::::::2:::::::::::::::22::2::

= t : ~ ! !==
...........
---.

t
]iii iii:i-i---i::i:iii:iiiiiiiiiiii::iii::iiiii:iii iiiii i ii --.-:i:i .......................................................................

0.1
'
I i

tO
m i i ~-/
i

'
t .............................................
'
"
,t,

Q. 0.01
i !/ i i
(D
! =7:~
(~ 0.001
(p
13_
I ........... 7

0 t..../ I............................. :
1

Q- 0.0001
tO
>
P f. l t .....................................................
',t" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "," . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4,

i i
1 E-05
| ! . .

p . . . . . . . . . . . . . . . . . . . . . . . . ~................................ ~.....................................................................
4
I t. . . . . . . . . . . . . . . . . . . . . . . . . . . . '~" .............................................................. "I.."
, I i

. I
1 E-06
tz r .................................................. 4
t f
t F ....................
9 L...............

,,I !i i
I..... . . . . . . . . . . . . . . . .
1 psia = 6.895 kPa
,p . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................... 1 psia = 51.71 mm Hg
~ ~. . . . . . . . . . . .
! |

l i t
i ii I! ii
1E-08 I
i

I I I I
500 1000 1500 2000 250O 3000
Temperature, F

37
1 O0~c!!!::!::~!~!~t!::::i:~::::::i::::::il ::::::::::::::::::::::::::::::::::::::::::::
............= = - - - - ; = = = - : : : : - ~ : ~ : : " = ~ - - : ' - ............................................................................................................. , ................................................. ::::,

~ ! ~ ! ~ ~ - _ ~ _ ........................
, : _ - = - . ) ~ ......... i ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...............................
#l .................................

f f ~ ............ : - _ . . . . . . . . ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,_ .................................

J / j
, , m . . . . . . . . . . . . . . . . . . . . . . . . . . . i ........... [ . . . . . . . . . . . . .

0.01 = ................... -./.- ....................... -_:~._~_-~....................... : ~ - .............

(D Z.-':ZZZZZ'L':ZZ:;..-.".ZZZ;:Z!Z";":----.;T.~Z::Z;::Z'ZZ::ZZ:::
....................................... ,I...................................................

Z~

0.001~ ' - - - - "~ ~I~Z:


O~

I--..

13_
.... . I .... ~ . . . . . . . . . . . . . .

.... ~ .... ,/ . . . . .
_ .. . . . . . . . . ~#" ......

0 #

0.0001 . . . . . . .
_~_ - _ ._ . . . . . . . . . . . . . . l
:::::::::::::::::::::::::::::::::::::::::::::::: ........ ................ .

/
>
- ! ........ - : .......... ..::.: ..............................x,:::::::::::::,
-- . / . . . . . . . . . . . . . . . . . . . . . . . . ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-- ...-/ . . . . . . . . . . . . . . . . . . . . . . 9 ...................

-- .............. Y . . . . . . . . . . . . . - ..........................................

1 E-05- ~ ~ ~ - ~ ~ - . - = - = = - - - - - = ' , :i

T I ~ .................................................
/ Z}-..-.-_.T.Z~ZZ.-.Z..-.Z[S.ZZZ-}-.:ZZT-[Z
1E- 06-_---_
....................
i _-......
}----/;------;
............-----~::::::..:..:.:..........::-:--:--T:~='-:
/ .......................... ....... - - .....:-::-:::::::::::::::::::::::::::::=:::
................~..-.._...- _ . _ ~
- 9 : ..........................
? . . . . :................................................
]
/
'"" 1 psia = 6.895 kPa .............................
1E 0 7 - / Ei 1 psia = 51.71 mm Hg ii~.-~--E~.~Z-:--"iEEi
~:."-': :._-TZ Z Z " E "_-_Z'T.:Z."_" Z " ',
Y

_/
i ...

~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ............................................
t

1E-08 I i i i I
1500 2000 2500 300O 3500 4000 4500
Temperature, F

38
I O0_]~:::::::::y::::::::
.4I !! ..................L!........................
L ~...............................II !
i
] IYZ21111 , . . . . . ,...... , [
]YY YTYIII ............................... ~ ......................... :
-]iii-iiiiiiiiiiiiiiiiiiiiiiiiiiiiii! BeB2H8 BERYLLIUM BOROHYDRIDE ......................................................................
T-
7111111111 ii.......I i...........................
] ..............................................

i "
i I
I
I
!
,! ~
I 0 ............................................i ~ l i ..................... t .....................................-i-.:-....................... ~ ~ ...................
............................................. - - ....... t " i ......................... ~ .................... ...".......................................... t . . . . . . . . . . . . . . . . . . . ~ .... --'-T-i_,__,-_ ~
................................... ~ . . . . . . . . . 4 "; (.-------- ....... " ............... .~................................ ,:. . . . . . . . . . . . . . . . . . . . . . . 2 - - - . . - . . . . . . . . . . . . . . . . . .
[ i I i i i i i J i
................................ " . . . . . . . " ~" |. . . . . . ,. . . . . . . . . . . . . . . -' ..................... I" . . . . . . . . . . . . . . . . . . . . . . . . . . . . I " . . . . . . . . . . . . . . . . . . .

............................
.............................................. TI. . . . . . . . . . . . -!-! [i ~!. . . . . . . . . . . . . . . . . !i......................... I:........................................... - :i :~7 :_: :_: : :L: :_: : _: - :_: :_:..................................
.~i...................................
:::::::::::
____i
.............................................. i . . . . . . " i. . . . . . . . i ............... "t.. . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................... -I. .................
-I ~ l F i ~ [ ....~ ................... -i, ............
7 ' ~ I ' t. . . . . . . . . ] ti" 1I . . . . . . . . . . . --t i ................... i' . . . . . . . . . . . . . . . .-. ". .7.-. ]. I. . . . . . ......................... ]]. . . . . . . . . . . . . . . . . .
c~ / l i I i i I / I i
=m
(/) -i-......................................... ~ . . . . . . . . . . . . . . . . . . 1" f I" . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . ..'....... ~ ................

I , I ! i ' i/ J i
i I I ! i
c1. , i i , ! -.~ i i
.............................................
". . . . . . . . . . . f ] ................... T ............................ "....................................t ....................................! .............................
(D
!--
I i I , , i ......~ t i
I Ii I ! iI ,
i
/ iI !
! ii
oo / t i ! , i / i i i
1 j . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . ~ ~... .,}. . . . . .. . .. . . . . . i . . . . .. . . . . . . . . . . . . . ~ . . . . . . ... . . . . . . . . . . . . . . ... . +-
. . . ... . . . .. . . . . . . . . . . . . . . . § ..................
(D
I,.. 9 . . . . . . . . . . . . . . . . . . . . . . . . . . |. . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ............................... - - 1 " . . . . . . . I" .............................. I '"i . . . . . . . . . . . . . . . . . . . . . . 41". . . . . . .. . .. . . . .. .
(3_ -i ............................................... ,, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d
i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i-.9. . . . . . . . . . . . . . . . . . . . . . . .
, ,
! .........................
.............
:. . . . . .

!,_.
] . . . . . . . . . . . . . . .t. . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . .i . . . . . .~. . . . . . . .i . . . . J - ...............
- ~ "1,. . . . . . . . . . . . . T
0
Q.
I
- , i ~ - - ~
J . . . . . . . ~~ . . . . .
I
§. . . . . . . . i. . . . . . . .

{tl l i i i
l I ! ,
>
i
.......... ',....... !
-',.I .................
-7 T-'! ......... i....................... i..............................i ............................1'
I ! I :
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

~ /, i i i ! i
' I ; i i i ": i
i ! ; z z 9
~ ,
!

/ ~ _ _ / i 1 ....... , ................. i j ...................... ..,.............................


9 -:.:...................................,:..-............................................
j~...............................
o.1 - - - -- - - - - - -~ . - - -- - - - - - -- . - , -- -- ~ - - -- -- .: - ~ . - - - , ",, . . . . z .... :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ....

~
-I771111711171777~i:i........... - - , , . . . . . . . . . 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............ -.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ; ........................................... , ........................................... , ........................................

___L
' I
......................... ~, ..................... i~............................ i: ............................. 'i.,....................................~i .............................................
4i .............................................
~i ...........................................
................................................................................................. .LC7
~ ......... t- ........
! .........
.................................... ! -

4 ..........................................!-,;, L . . . . . . . . . . . . . . i !J , , i i I I _psia = 6.895 kPa .......................

I
x/
I
i
!
I,
I
.
1
' !'
I
il
i I
I 1 psia = 5 1 . 7 1 m m Hg
i ...............................
" ..........i ~ i ~ i i i I ,
I I i i I ' ~ ! t
i ' ~ , i i i
I i' i ! ! ,I ,
i
,i
O.Ol / i ' i ' i
20 40 60 80 1 O0 120 140 160 180 200

Temperature, F

39
_______

10-

tm

7 ~ ...................................
.,.
L_
L_

1
0

>

0,1-"

1 psia = 6.895 kPa ............................


1 psia = 51.71 mm Hg

i ............................
!
0.011 ]
550 600 650 700 750 800 850 900
Temperature, F

40
100,
~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiI I ..... I ............................................... i '
. . . . . . ' ................................. J, ....................... i
~ITTYZZZZZIIYI
],iiiiiiiiiiiiiiiiiiiiiiiiiii BeCl2 BERYLLIUM CHLORIDE ........................ i |

1 ............. - i ..................................................................... [ .................................... i |


l ..... I ! i t I

!I Ii
I " i !
|' 1
] !
!
' I
!
,~.

ii |
I
I {,
i
t t
I
i|
e ~

c)

13_

0
c~
>

I
0.1
....... -/:::::z-i
,/
I i :
i

t ',
i i
1 psia = 6.895 kPa
j I I i

! i
i 1 psia = 51.71 mm Hg
!
! i i

i
! I
! i! i
i
i
!

i
! !
t ! i
0.01 I I I
550 6O0 650 700 750 800 850 900 950
Temperature, F

41
10
J
i
BeF2 BERYLLIUM FLUORIDE

l--

om
7 b
F
03
(Q.
ID
t.__

03
03 I .......... . . . . i ..................
(D
L_.
13_ i................ _--_- --~-~_- ............................................................... l............................
L_
O
O.
>

I !

t-" I
I 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.1 I I I
1600 1650 1700 1750 1800 1850 1900 1950 2000 2050

Temperature, F

42
100, " , " _...... , . . . . . . . . . . , ............ ,_ .__ '

]::::: :::::: ::: :i: j. i ...... t2; ;;;;;; ;;;


]772-;2;;;;;~__];77 ' * ' ii]iiiiiiiii_iiiiiiiiiiiii
} ......................
::::::::::::::::::::::::::::::::
............. Bel2 BERYLLIUM IODIDE !

T
il ...................... m m

....... f .................................... r ..............

J i
I

! .......................... i
i i '
i I I
i { t---2 ...................... ..
--; .................................. t .............................................. I ........ 7
i "
f_-........-.........._....~ : L. ........................... -i--
..... , ..................................... L _ _ _ _ _ _ ~ .................................. i-
............................ i. ................................... "i ................................... .i...
i ! : i
i i i i . . . . . . . i
t...................................~........f......................"~...................................... +"
I i ! i i" .......................................
/ i
T, j
i i t, ....................... !' .......................... ~-.................................... !""

Q. I i i I i
i t
t i ! L ............l . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .' ...................................

L_

t '
i/ i
t
i I I _4...................................,....................................
J........................................
L
..... { . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~..................................... ~..
r ...................... t : | -
.... t ..................................... * ........................................ 'I ......................................... 4...

n ...... i .............................................................................................................. j.
i ! i
I,__ ..... i ....................... ~ ...................................... .l{.............................................. T'}

Q.
, I,! i

I i i ', i
> T
i
--.4
9 ......................
i
~ ...............................
'
4 ..................................
I
4.-
i
i i I i i

o,J
............................ ft .............................. t ...................................... .!..,
i i i i i'!
i! : i !

...........................................
!
i
!
LI ......................... 4................................. i-
- T r ........................
l. . . . . . . . . . . . .
...........................
9
i,. ..........................
" .................................
4 ...............................
i"
~.-
- ? r w I l
i ....................
i
; ................................. -r, .................................. T
i

l i i f .......................... I' ............................... t ................................. ~"


' i i ..................... ~ ................................. ~............................... ;..

" 'F ! i { .........................


i
4 ...................
i !
i

i t [
i t i
1

!,........................
.......................t,'i1 ~ Ho

!
1 /"'~ '~ .......
i
I

l
i
1
!
i 1 i i iI
i 1' I1
0.01 i i" ' I I I I
500 550 600 65O 700 750 80O 850 900 950

Temperature, F

43
100_---- F...... '..........................................................~.............................................................

Bi BISMUTH
10-

:-!

0.1
[ f _ . . . . . . . . . . . . . . ~ .....................

o m

03
Q. 0.01~
(P
t . _

I
u~ .................................................. I

oo 0.001 -
(P
t__

13_
L _

0
Q. 0.0001
>

1 E-05 L. . . . . . . . . . . . . . _ . . . . . . . . . . . . . . . . . ~_. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , .....................................................

1 E-06=

EZ"----:'2:-,, ................................. ! ....................... C2.-::"::::::::::'.':::::"2,.E::


], . . . . . . . . ] .............................

1 psia = 6.895 kPa i


.................... 1 psia = 51.71 mm Hg ~-EEi!iE?~E~iii!i

1E-08 I I I
500 1000 1500 2000 2500 3000
Temperature, F

44
I
100,
! i
! !
...................................... to. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 . . . . . . . . . . . . . . . . . . . . . . . . . .

BiBr3 BISMUTH TRIBROMIDE


H
i

I
I
i i
i i
!i
i i
O.

l---

(p
L_
i i
13_ t !

0
O.
i
t. . . . . . . . . . . . .

> ..............................
I

t .............................. i ............................................... r ................................................; ..............................................


l ! i i i ! t
i i i.............................i .............................i ................... -1
i I..........
0.1
I i !

i ".-"E-2-2"~:72T-.I.-:T~2T_--_'--_ET;2T'ITCI2~21~EZ2T;E2~
! i................................. ~ .................................. ~...........................
i
,j
~~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
+ .......................
I
,.". . . . . . . . . . . . . . . . . . . . . .

m ..................... ~,. . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................................... .J . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .


!
...............................................................
i
i
i ............................................. 1 psia = 6.895 kPa ...................................
i i 1 psia = 51.71 mm Hg
....................................4
!
i
I! i i ,

0.01
l i
i. E
:

1 i
9 !

I I I I
500 550 600 650 700 750 800 850 9( )0
Temperature, F

45
1 O0 ; ; ; i~
_
[; .

BiCI3 BISMUTH TRICHLORIDE

1
I
mm
! 9

/
10

................... f
7

o.,m,

c}

J
(D

/
1 ,
(D ,, ii:i ~i~i;i ~
.J
J
n
f
0
r~ /
>
/
..~#
/

0.1

1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

0.01 I
400 450 500 550 600 650 700 750 800 850
Temperature, F

46
100, ......... ,........................................................................
,
.......................

3111111111,ii ~i i iiI
][ .....iiiiiiiiiiiii I BrF5 BROMINE PENTAFLUORIDE I

11111................
i1 ..... I !
j i

] ........ ! i
r.....................................................

i
- ! !

- t
- 1
=,,m,
, !

r~
_ , !
(1) s i
i i
,I !!
- ,~ -~
(D
13_
i
0
c~ l
9 / ,i I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
|
I
i E
I
> .p ...............................................

i
!

i i
ii i
0.1
!
4 .......................................
4 ................................................ .$

.-~- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
I i
{ .................................. {
|

i i !
! 1 psia = 6.895 kPa
i i

! i 1 psia = 51.71 mm Hg

i
I
I
! ! i!
o.ol I I I I
-1 O 0 -50 50 1 O0 150

Temperature, F

4?
-1 'eJn},eJedwel
009 OOCj 0017 00~ 00~ O0 I. 0
I
L'O
6 H W W L / _ ' L s = e ! s d L .-
ed>l 969"9 = e!sd L
/
/
/
....
/
<
....
~01. "13
0.=~
==~
i /:: i
-0
..... / I 0
oo
oo
e-
.=~
/
J
/
0
!oo~ "13
m =
/ oo
/
!
L f
................................... .I v
000 L
=INIIAIOEI8 ~J8
4
0000
100] ......................................
t
i I
T'
]iiiiiiiiiiiiiiiiiiiiiiiiiiiii~iiii] C CARBON
~111111111 l L
i .......................................................
i
] i
i
i
i
i'
I
t
I

10~m

ffl
. m

EL.
0

>

!
i
/I
,m,} .....
i
I! 1 psia = 6.895 kPa
! i 1 psia = 51.71 mm Hg ...............................
I
II i

0.1
!
!
I
i
I
5OOO 5500 6000 6500 7000 7500
Temperature, F

49
1000-1 l , ..............................................................................................................
, ............................................................
~: ..................................
:-:---...-~-~. ,T :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ......~.~::::-::--:':'::'
: ::: ::::::-:::-:::::::::::::: . . . . . . . . . . . . . . . . . . . . . . . . t .................................: : : : : : : : : : : : : : : : : : : : : .............:'::
:::::::::::::::::::::::::::: C C I 2 0 PHOSGENE :•--=---=•••••••••••••=••••••••••••••••••=:====•••••••••••••••••••••••••-••••••••
q Z---- m _ _ _................~..,,,,,~.____.,..,...T,_.... ......__..._____.,,.,..,..,
I ........ ............ ................. 7 ....................... , ......... ---.-...---....~.._..._._...____...]_____.___....._____.,

I I . ~~I, !
~ i i i : : ::~: ~ : : : : I ~ : .....................................................
:i~z~~-:..:.~iiiiiiiiiii!iiI!z!i~ii!!!iiiiiiiiiii~ii~i-iz~:iiiK....ii~.~iii~!iiii~i!ii!!!!:...:.:~.~i~ii
]::z::::::::::::::::::::::::::: :::: ':i : --!.----,,,--,-~:____~IZ_T_T_:::,~~------ 7 ............................................... f .................................................................] ................................................
]] . . . . . . . .j . . . . . . -- : ...... : , / " -. . : . .~ . . . . ... . . !l ............................
.............................. ..................................
.........................

,o i .........i-- ~-- i~ ..........................il ........................................

:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ..................Y::Y: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ............................................ [......................................


] . . . . . !. . . . . . . . - -.- - / I ............................... ' . . . . . . . . . . . . . . . :..................................... i....................................................
cO
im
or)
c~
O~
i: :!:...............
..... ~Z
s .........

-/
l. . . . . . . . . . . . . . . . .::Z. . . .ill. .iiiiiiiiiii
. . . .ii:i:iiiiiii
...
n /
0 0.1 ................................ 4................................................
13.
................................................ p. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................................... 4 .................................................

> i

/
0.01 ---__~....~..~::.~ :::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
~ - ~ 1 :.T_:'::.'ZZ::.-Z::::::.-:.":::..-:::":I:_":::::: ..".-:::::::::::~-.:...::::::::::::::::i::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::.::::::"::
| !

t ............................................................................................................................................... t ....................................................................... t .......................................................................


................................................. ................................................. i ..................................................................... i .....................................................................

i .i
0.001 :::-~-"--:.~.-.~.'.:.--:.:T.:::Z::::::~ :::: :::::::::::::::::::::::::::::::::::::::::
t
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

.................................................. F...I ......................................


z t!
................................. t ...................................................... ~ .................................................................. }| . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1 1
1
! !
0.00011 I I
-200 -100 0 100 200 300 400

Temperature, F

50
l ODD,1 .... I _ Z Z L .
i ! i............................................................................................
] ...............
........................... ! ; f..~..
~...i
......................................... T:.............................................................
~ i .
I cg20 CARBONYL FLUORIDE ~..-----_-.--~I~IZZ.-.]I~I}I~ZIZ~_--~I ..................
........................... i. . . . . i i
J__.__L ....................., ................................................................................................................................
L~ .............................................; .............................................
- ~ - - i ..................................................
~ I 1 1 i / i
+ - - - - .....................i .................................................I.....................................................T............................................................
i.......................~ ..........................
!...........................................................
'9 i i i / E
I . : .

.- -. -. -. -. -. -. -. -. . . . . . . . iI ............................................................................................. i ............................................................ .... "t ................................................................


~ " !~.......................................................

I i
............ 4. . . . . . . . . . . . . . . . . . !-. . . . . . . . . . . . . . . . . . . . . . . . ..................
9 ~ ...................................
i t i J i i

i i i /
!
i
'
i
;
9 i i ! l
i t ' i i

00
3-------__
.............. I .............................................................
.......... ,.............................. [...................... ZZZ]:ZZ72-ZZZZZZ]ZZZZZZZZZZiZ-:.ZZT.I......................
t ....................................................... ~ ................................................................. I .....................................................

J i ! " -'.
Q.
+ - - r..................
..............~ ........................... / ...............i................................................
....... J..........,.................................i................................
(1) i i i i i
..... i ! ~ E i
i i i i !
00
(1)
I,..,
13.. i
i
i
I
1
~ !
i i
i
.................... "+ .......................... f ................................... t ............................................... ."............................................................... " ..................................................
i i i ! !
O i i i E "
i i 9 i i
: ~ i " "
> I i i i
I O n ................................................
. . . . . . . . "~ ........................
J................................ 'L............................................
........................................ ~' ..........................................................
.........................................................~; .......................................................................
',."............................................................
.................................................................... ...............................................................
I i i .'. i
. . . . . . . . . . . . . . ~,....................................... i- ..................................................... ~ ............................................................. :.".................................................................... ~..................................................................

_.-72-_"-:::::::::7 :2:::::::::::::::::::::::::-:Z-ZZ:i::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::i:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~i~~~~i~~~~?~

i i i !
. . . . . . . . . . . . . . . ~ .......................................... - ........................................... ~ .................................................... } .................................................................. ,.,...................................................................
i ~ i ~ ;
i i ' i

i ............................................ ~..................................... ! .................................................... i""I I p s i a = 5 1 . 7 1 mm Hg

i i i i"
1 1 ! i ~
l i i i -'
I i , i i
I i
-200 -150 -100 -50 0 50 100

Temperature, F

51
0.001

t ..................................
I CH4N20 UREA I--
]IIZIIZIII iiiiiii!.................., ...........................................r_-

't .........................................................................................................

.................................................................................................. 't .................................................................

i m

Q.

(D
!,__

(D 0.0001 -
n

0
Q.
>

i 1 psia= 6.895kPa
1psia=51.71mmHg

1 E-05
160
I .....
170
!

i
!

180 1 90
i
'

200
i
I
2"
150
Temperature, F

52
10000. ............................... ,. , ,

i .........................................................

CH4N2S THIOUREA I .................... 4 ............................................... i" .................................................................

t
! i
liiiiiiiiiiiiiiiiiii1 ............................................................................................... ....................... d .............................................. .I.-...................................... .......................
9

,. . . . . . . . . . . . . . . . . . . . . . . . .
I

i .................................................................. & ........................................................................

i
I I ................................ ! ..........~ - -

if)

ffl

,8
' i
I
I
!.___
! i
0 i .J.

>

/l i 1 psia = 6.895 kPa


i I i
! 1 psia = 51.71 mm Hg
i ! i
..... i 9..........

i
....... T ....
I
!
i
I i!
i
i
I i
i II
i
11 I I I
i
I
300 400 5OO 600 700 8OO 900 1000 1100
Temperature, F

53
1oj .................................................
! i, !
i I
!
....................................... f"........................ t .................................
CNBr CYANOGEN BROMIDE ~i
I
7 iiiiiii_-
[ iiiiii

4
]

Ay
...................................................................

,,m
i
i
(D
t
(/,j
............................................. l .............................................................................................. i
i
.......................................... i ............................................................................
i i
i ...............................................................
c~

> .... . / J I ......................................... 1 ........................................ ' ...............................................

J
, ............................. I .......................................... } ......................................... [ ....................................................

II r
i
I j

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
i
I
] !
0.1 I i i
30 40 50 60 70 80 90 100 110
Temperature, F

54
1000
i I
!
i .........................................

CNCI CYANOGEN CHLORIDE

....................................................................................... i
!

I i I
ii
!

,~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ? ................................................... ,
I 7-"', !

(B
omm

i
Q.
i
(D
'/ i 1!
|
1/ i i !
l i = ! :

(1) i i i! i
n !
F ............................. ...........................
t..
!
0 i! i! 1
i i
!
! I
> 1 i
ii i,
i i, ~ ........................... 'tT.......................................
........................................
1 i ! i,
i i i i
.
t --/
. . .

................................ ~ ~ w ~ . . . -
I

i
]..... - ..................... ~ ]
!
, i
--.J ~--- . . . . . . . . . . -i- ................................. { ....................................... ~ ...................................
I9 i i' i :
i i
l .........................................
i |
..........
..................... - ................................
r T
.9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
:

S
ii
i 1 psia = 6.895 kPa
!

i i! i ...........................
i
;'- ..........................
i
1 psia = 51.71 mm Hg ..............................

i
! !

_
! !

i ii 9
'
i
'!
i, :
!i!
I I I I I
0 50 1 O0 50 200 250 300 350

Temperature, F

55
100 ...................................... i

r ................................................... ,..................................................

CNF CYANOGEN FLUORIDE


J ._
......................................... i ....................................

m...,m
0t)

(D
$.,..

(D 10
i
13_
O
c~
>

j
l

f
J

1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

J
!
11 I I
-110 -100 -90 -80 -70 -60 -50
Temperature, F

56
1000
! i
CO CARBON MONOXIDE

,,, . , , , , ~

5...

L_

0
c)..
>

1 psia = 6.895 kPa


=. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~............................................... t ............................................................. T .....
1 psia = 51.71 mm Hg

i i i i
1 I I I
-340 -320 -300 -280 -260 -240 -220
Temperature, F

57
Vapor Pressure, psia
0
0 0 ..L 0
o b P --,. o o
-'~ -" '-" 0 0 0
t~ I I li I I I I I I I II I I i I i Iil

iiiiiiiii ii i l "I'Ii I If! !


- i il ii! I ~ i Jtt Jl ~
~176 ~i iliii i iiiJiiiJ i i l tlIitJ i i l'i~ill i il II ;
!I ~I,,i ii!II!~ i t I Ii! 1 !

' , ,~I! i ~ ~i,, iI t ! I i I'll


ili] i iiiiiill i t Fillill i i iiilili i 1i i~l i i
- ~_! ..... i__~........! ~,L, ~ !i~j!i~, ! , !Illtii , ,~i!,,l! i I II!Iii~ ! !,
I !i i
----i~ --, ,- i-~ LZ_L~J.~~ ............!........! ....!~!IJ!L ............L..A.._LLL!]:!i ............... ! .............! _ L I J . I ! ! ! .....................! T ~ _ L L _ ~ . i l
~ / ~.~. Iii i i ii iiiii i i Ii iii!l i i iiiiiii i i iiiilii i N !i iiiil
/ / ~,~, Ii i i i i iliiil i I i liiii! i i i i!!i!i i I i iiIi~! i ~!iiliil

ii ! ! " i '~ ' i t'i i ' , ! ,'..i," i I I ! , i , ~i ,,

ii i i i, i!l, i !i i i! I , , i,,,,I! ' ,,' li", i , Ii i:,,


iiiilili i ii " ' i ii!iliI ~ iliiii!i i ii!ilili i i i~~,
! i iiiiii i ii i i~ii~'i
" "l i iiii~i i i Ii i, !i ~ ~IHil
i iiiiiii " i l ! if!!! i iiiiiii i l i 1i !l!!lii /
" 9 ii ~ii,i i~ ~ !' I,!' i !i iiii: i , !, ,i i i !i i,,l
! I ii!Ii . . . . i i i, , i, : ! : ill.!
, , i, i ,i , i,i,i ,, i i, i i, iI ', i :i ,i I,ii
,
100+ ........ 9 m .................................................................. , .................................... 4 ................................

[-- .................. I i ................................


........................................i ...................................i .............................
~ ................................ ~ ........................ 4[

~Ii]iiii i i i i i iiiii i i i~ici~oisi ]e


~iiiiiiiiiiiiii-iiii:ill ....... CARBON OXYSELENIDE ~
l
,
................................ IIZ:I:IIII.7.~I::~.~.I.~LT2~.E_T..~I
.....
i "f'i
i12121::iii:i::12221121111111212112 .......... ............................. ....................................... ................................ : ........................

i [!.......... _" .......................... ' .......................................


il..................................
ii............................
I

i ................
~9 , "........................................................... I ........................ "
i !
!
I !
i
............................... r ............................... [r ! .._

T-- ...................... .,."


, t "T........................... T
L [ ;...........................t
! i i
l i
.{~...+. ......................
j
p

i I
I +L
i n

(/3
o.
(D
I...

:3
03
03
(D
t__

EL
t.__

0
El.
>

0.1

I
.... ,},
T ............................... .t.,..,~ . . . . . . . . . .
!
I! i i
b ..................... i .... 1 psia = 6.895 kPa
i ! i 1 psia = 51.71 mm Hg
i
{ i ........................ ~ ....
!
t 9 i
i I i 84 i
i! i i
i i i
0.01
! ! I ! ! !
i .... I I i
-180 -160 -140 -120 -1 O0 -80 -60 -4O -2O
Temperature, F

59
10000 i I i i i I
. . . . .
] ,r ! F ................... |............................i ............................................
m . "| ....................

.i ~ .............................. ~ ......................
CO2 CARBON DIOXIDE [ i ......................
................ i i
b
~ -

i ...... . . . . . . . .
I
~r
t

t I
! .................... t ~, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . , ..........................

........................ 1

, t
]

1 000 ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 ....................................................

! !!!i !!!!!!!!!
e .....m

Q.

(1) ............................... I .......................... , ...............................

(D
r~

O
C).
>
100 f
....................................... p. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

................................... , ......................................................................................... ~ .............................................

............................. '........................................ 1 ....................................... i ........................................

................................................................................................ i ............................................. ] ...............................................

1 psia = 6.895 kPa


......................... 1 psia = 51.71 mm Hg ...............................

L !
r , ,i i
L
101 I I I I I
-80 -60 -40 -20 0 20 40 60 80 100

Temperature, F

60
10000-~ ~
................................................. ! ~ ........... ==:-= ........... = .........................
~l::~:~:i !!!!!!!!!!!!!i!!Yiii iiii~iii: ::~ ::::::::::::::::::::::::::::::::: ........................ ~ .................. ~" ~---..-'_".'..-'..-..:::::_-z..::
~::ii:::::::t::
Z~I::ZZ] .....................
~: .......::::::::::::::::::]
CS2 CARBON DISULFIDE ----i i. . . . . . . . . . . . . . . . . . . . . . . . . . . . .

,ooo 7 ...............::::::::::::::::::::::::: :: :: !
! -:: -
! ,,
'........................ ~iI
t...............
i
i=-"---'.~'-'=.'-'.".'='-..--'-~ . . . . . . . . . . . . . . . . ~ . . ~.='G.=~..._-=~--=.._--_-=-_-

::::::::::::::::::::::::::::::::::
3 ~ .........................
| I'. J .,.
i .........
........ iiiiiiiiiill i !i.......... -!! s T i
! l i ........................
ij t! h"
;--': =q .................................................................... ,
9 § ..........................................................................................................................
- i t....................... t
..................... t .......................... .." ................................................. t ................................................. ".-
k ............... ...........................
9 -'-............................................ ~................................................4
- ! i
i-- ............................... t ........................................F........................................
..........................................I I _/_ ............ ~............................. " ................................................
L.............................................
i
,2
~ m ,o_
- ........................
i
!
iFz.~=:--~
:F--_7!~-__-=__!~
. . . . . . . . . . . . . . . . . .

....... 5.--~5=~:-= ............. ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::


i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . q. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~

n ',~"--~~t . . . . . . I". . . . . t...................... I ................................ t ............................... t


t-----~----t------------~ . . . . . . . . T ............... t..................... T
"F-----7"~-~.----------3--- . . . . . . . . T . . . . . . . . . . . . . . . . . . . . T. . . . . . . . . . . . . . . . . . . . . . !
(D ~_..M/ ....... +........................................................................................................ I
--/
I,..,
~..-../_ ............. ~ ................... L . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4

i
oo
! /_
..} :~'.~"~-~..~".E~"~Z~ZZE~7"1:"".:~Z"~"~"Z~"~.-.~Z~[~Z~E2~ZZZZ~:::Z:~::~
(D
I,...

n $

i..~9. . . . . . . . . . . . . . . . . . . .~ . . . . . . . . . . . . . . . . . . .
F~ . -. . -. . . ........................................................................................................
................ ., ......................................... ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

> 0.1 :.~


:~
.9. . . . . . . . . . . . . . . . . . . . . . . . . . ..,--.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~."::EEZ~..Z:"-"E.'Z"Z"Z"::~Z::Z::"ZZZZZ";:~I
~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

! . .~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................... ,- ...............................................
0.01
t ~ t ' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9. i
t t. . . . . . . . . . . . . . . . . . . . . . . . . f ....................................................................................................................... I

0.001 ::f=~-=-~"-Z-:-="~Z:~Z-~:::~==:=====-=:==.~Z:~T~:~:L~:G~Z~:~Z~i:~i?~ii~i: 1 psia = 6.895 k Pa


,I.. . . . . . . . . . . . . . . . . . . . . . . . . . . ~ !....................

, ~ {
. . . . . . . . . . . . . . . L-- . . . . . . . . . J. . . . . . . . . . . . . . . . . ~...............
, - ............. 1 p s i a = 51.71 mm Hg

i i 1 " i

i..................... i'~ i ....................... 4l,.................................... ~i,.........................................


0.00011 1 I I I
-200 -1 O0 0 1 O0 200 300 400 500 600

Temperature, F

61
1 O0
i i ..................................................
! t!"...........................................
CSeS C A R B ON S E LE NOSUL F IDE
E.....................................................................................

......................................................................................

j
10 ............. iiiiiiiiiiiiiiiiiiiiiiii~iiiiiiiii ~ i ! il ~ .

iiiiii ~ i i i iiiiiii iiiiiiiiiiiiiiii~

u)
(D
13_ ~iiiiiiiiiiiiiiiiiiiiiiiii........ i iiiiiiiii--i~ii~ii-iiiiii~ii~

//
t,,...
0
Q. 9 ~ / ! .... iiiiii _

> ' !
1
I
i i ..................................................
1 i

0.1

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
.......................

0.01 I i i i I
-1 O0 -50 0 50 1 O0 150 200
Temperature, F

62
1 O0 , , ..................., .......................................... , ..................................................................................... }
l ........................ . I .:..:...::...,.
:...:. iii ii ii ii i iiiii_i_ __[_iiiiiiii12111111111111111111111111111111111] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IIIIL_
.

:::::::::::::::::::::::::: .......... i ' ' L::::If .... 1..........................................:Z .... 1

.... _ :::l ................ q ,i

i i

' _._~.__
,
lo- ......................................
~! t I, I.............. q ......................................................
::::::::::::::::::::::::::::::::::::: :::~E-!Z- ............
~:::::::::::::::::::::::::~::::
..................
i............................
i ~ ..................i.........................................
T .........
~ ..........................

] .......................................i . . . . r ".I...................... ] ...............................::::::::::::::::::::::::::::::::::::::::::::::::::::::: ........


................................................................................... f ................... ! ............................... . ...................................... ".,......................................
] .....................................................
!. . . . . . ,. ~i . . . . . . . . . . . . . . . . . . . . ,i .................. : : ~ Z : Z :! Z : : : : : : Z : . Z ] Z Z : Z Z : :i Z : : ..........
t i ! i / i I
. ~~I _ L _ _ _ _ _ L ~ _ _ . L .!. . . . . . . . . . . . . . . . . . i . _ . z _ _i ~ ~ ~ !. . . . . . . . . . . . . . . . . .

13. / I ! ii I" / ii ii
_~ . . . . . . . . . . ! . . . . . . . . . . i . . . . . . . . . . . . . . . . . . ~ ..........................

t ~ i i / ! i l
g ! i i i i i
i i i i i i i
1 -_-:::-=:==::~: i : ::::::::::: :::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
~ ~ - - . ' . ......................... ~-, " '. ............................ 4............................................ .';-................................................ -.".........................................
3 _L i -'..
............................................ i ............... ~" i ....... i ........................... i ........................................... i .............................................. i .......................................
....................... i~. . . . . . . . . . . . . . . . . . . . . ~F.
/ ~t~ t !
-+---------~ . . ./ . . i. . . . . . .! . . . . . . i . . . . .
]___
_+, ........
~: ....................................... ~I........... i
~_...Z ...... iI ................. Ji.....................................ii .............................................
ii......................................
I ~ i
> 1 ............................. il -I . . . .!. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . l
'..........................................
;
i i i

/ i :
i
i I / I! ii i' i ' i'

----------~ .......................... ~......................... i ........................... i ............................... i ................- ............................


i ..............................................
i .....................................
.... ,. . . . . . . . . . . . . . . i ........................... [ ......................... [ ................................. i.....,.....................................[ ........................................
............ i . . . . . . . . . . . . . . . . . . ,......
J------------~
1-'---------, ............. , , , , '_.__L
---":- '.-.-_~_-_ _ L -. "]..--.--].-- .......

J ~..---Zi ............. ii ................. !I ......................... ~i ............................... "ii .................... 1 psia = 6.895 kPa ...............................

.I/ i i i i ;psia 5i']71mrnHg =

, I i i . ..
I i i i i i i
/-- ~ i ! i i. "

i I ! ~ i i i
i ~ ~ ~ i

O.Oll i " i " i


-160 -140 -120 -1 O 0 -80 -60 -40 -20 0

Temperature, F

63
10
! t ...................................................... i ....................................... i

.................................................. ~ ................................................. i~
C3S2 CARBON SUBSULFIDE ........................................

i J ......

eu

r~
~-TI T~] ~......................................;
Y i~-~[:i : i~iiiii:iT~ii i~il
.z............................................... !
(D
13_
!--- ....... !............ / -
0
Q.
>
0.1 =. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.................................................... i

! .........................................

!
!

S ....................I i !
I
! i
J! 1 psia = 6.895 kPa
i' ........................ ~ 1psia=51.71mmHg ......................................

i ,
I e
0.01~ i j i i
50 1 O0 150 200 250 300
Temperature, F

64
1 O0 ---~.................t ....................................................................................................................
~Z~:~::~!~!~:!!~!~!~!!~!!!E!!!~z!!!:~!!!!~:!~-!~!~]~:~-~:~:-~!E~!!!~:!-!!z55!E!~=~a!:

~.ZZ..Z::-:-Z::::Z-Z:-...Z::-::T.ZZ:Z:J.:::Z::-..:;Z::-.---:T
~ , ..... t ~Ts
Ca C A LCIU M

........ r .................. -It.. . . . . . . . . . . . . -1. ............. ~ .......................... ~ ............................................

tO
,,,~m

13. 0.01
.L.9 t

iI
(D 0.001

13_
0
Q- 0.0001
to
>

[! ...................................... ~ii ...................................... zi


1 E-06

!
1 psia = 6.895 kPa
! i S
1 psia = 51.71 mm Hg

z !

i t ................................. i
! ........... i,....................................... T,.....
1E-08 I I I I
50O 1000 1500 2000 2500 3000
Temperature, F

65
100.. ~ ............................................. 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~TTTTTT-",TTTTTTTTTT"-~TITT'T-T,--TTTTTT-"--T"~,",-T-,, ..... " - , . . . . . m ' , , ' - " T - " ......
i
~. 1
CaF2 CALCIUM FLUORIDE
. . . . . . i
.... i . . . . . . . . . .

10 ..............................................................................................................................................
/ " /
i. . . . . . . .. . . . . . .. . . . .. . . . . . ~'~
j- .......
/ . . . . . . . i
f

1
. m

Q. L z i

CD
/ L
t _

0.1 J
/
z
J : '

13.. /
O r,
/
>
0.01 Z
/ F
/ i,
/
/
0.001 - Z

1 psia = 6.895 kPa


.............................. 1 p s i a = 5 1 . 7 1 mm Hg

...................................................................... 4....................... - . , . : _ : ...................................


!
i

0.0001
!

i I
25(}0 3000 3500 4000 4500 5000
Temperature, F

66
100~ ............................... [
1 i,
! i-
CbF5 COLUMBIUM FLUORIDE | ~.~
!
i

-J ............................................... ...................................... | ................................................................................

!
........................... I.

!
,i !t ~.
i
i

i
10 T ........................................................ L::Z:ZZZ::L-Z:Z Z:7
311111111111111111111111ZI
. I.III~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~............................... .............................

=====================================
03
i =...=,
00 ] ....................................................................... 't....................~ .... i.........................
o.

(D
t__
] - - - - - - ii
~
~
. . . . -~ ......................... 4..................
i J
~
i i
.......................

(D
t,.=, 5-- ' .........
. . . .
~
I ' .~- i
................................... t................................... t ......................................................T..................................................
J - i
t__ .......... ~........................................... , .......................................... ~.......................................................... ..:..............................................

0 .... i ..... i i i

>03 ~ I /i i !
I ..............................................
. . . . . . . . .
::::::::::::::::::::::::::::::::::::::::
::=:=-, !
,'
S i
'i........................................................................................................................
~, - ~ . . . .. .. . . .. . ,L . . . .......... . . . . .......... .
1
~J ...............................
............................... ~s ........................
................................
1
-F . . . . . . . . i. . . . . . . . . . . . . . .
J_ ............................................. .,~ ...........
I z
i i : '" "
J 9 .../___" ............................... l ............................................ ! ..................................................................
! .............................................
- ~.-I ........................ --4 .................................. '.,............................................. ~..................................................................,..".............................................................
! :: i ! .-"
i

............ ' ......................................i .........................................................


i ..................................................
i ................................................................
:..........................................................
i ............................... 4 ........................................... U .................................................... j ..... 1 psia = 51.71 mm Hg
' I I

9 1 ..,

0.1 ~
150 200 250 300 350 400 450

Temperature, F

67
89
.4 'eJn],eJedLtJel
009 I. 0017 I. 00~ L 000 L 008 009 0017 00~
! ! !
I i i i 180-~ i-
..................................................... t' ....................................................... ~ ................................................... t'
:::::::::...'--"'-.....--'-.::":.':.'::::-':.:
:.- ......................................4,
iiiiiiiiiiiiiiiiiiiiiiiiiiii;,/iiiiiiiiiiil:
tI
.........................
!i!']!!:'-"!:']E.:.-i!!!!!'-.--!:'-ii! 6 H LULU LZ" Ls = e ! s d L iiiiiiiiiiiiiii~ii::i~::--i!~i~ iiE~--::.-Ei--~--'.:'-"-~-~-..
/
ecl>l s = e!sd L
......................................
~ ;............................. 4 J ~ ~ II/ZZZZZZ[-
T.Z."IZZZZ:Z~. ..............i .................................................
i ................................................
~.............................
I-
...... ~...........................
..................... "r~- s I.
1.000"0 "13
i i 0
'='1
-13
='I
(I)
1.00"0 f./)
f./)
r...
" I
(I)
"c..=:::::::-.._."-::_'~:'-'--_.-.~. . . . . . . . . . . . . . . . . . . . . . . . . ~-___-='_=-~
1.0"0
m =
J ~- [2_
1.......................
/ /~'o
. . . . . . . . I-
.......~ ...............i .... L .l ................
~__.._~_ . . . . . . . . . . . . . . . . . . . . . .
~...-- .................................... :-: .... F
============================================================================================
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :: : :: ::::::: .... z
ZZ-2ZZd z
..................................... :............................ IAInlIAICIVO PO
........................... -4 ,~
O0 L
1 0 0 ~ l .....i ............ ,
1 ......................... t

~ d C I 2 CADMIUM CHLORIDE ...................................... ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .


2
i "
j .....................................
!

i ................. , ...........................................................................................
4! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

' i
1 ................................................................................. i .........................................
t

1 0 J ..................................................
! .9 .................................. T.............................. ". . . . . . . . . . . . . . . . . . . . . . . . . . . .
.......................................................... t ..................... i- . . . . . . . . . . . -'.'.T_~_-Z.'---EZEZ .......

.
J .............................................
~ '
,
t
, .................................
' ...................................................................
. . . .

l ., i i i
. . . . . . . " . . . . . . . . . . . . . . . . . . . . . . . . . T..........................................".................................... ~ ............................................i .........................................................
~ .......................................................
i , i i i i
i i ............. ! ......................................... i ......................................................
i+..................................................~ ! ~ ..............

c~ i i i i i !
. . . . . . . . . . . . . . 4- .................................... i ...................................................... i ................................................. ~,.......................................................... .',........................................................... ~+........................................................
i i i i " i
i i i e ~ i
I i ! ....

1 ~ . . . . . . ..'. . . . . . . . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(!,) - ~ - - - - - - - - - t
~~-----------------Z__4-- ................. i . . . . . . . . . . . . . . . . .
......................... ~~Z-----T__-I-, -----i-.
+ _- .E. .-. . .Z. . Z. . .Z. . .-. . C. . .-. . .:. .:. . .:. ~ Z T"i,.:.........................................
: Z Z : - Z L Z Z Z - Z : : $"i.;Z...........................................
ZZZZ;ZZZ ........
J ........................... I !
13_
~ - ~ - - - - - ' ~ - - " - - - ~ - - i "~ . . . . . . . . i................ t ................................ i ............................................i ......................................
0
......................................... ~ - ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ---'+ ....................... "i"......................................... I .................................................... ~ .........................................

>
t . . . . . t. . .
-Sv . . . . . .
d ' . . . . .
i' . . . . .
i' .
'.................
I I
!
i t
- . . . . . . . . 4.. ..............
! i i i i

X i i i i i
i ! i i i i
O . 1 ................................. i ........................... l .............................. ~................................. ~ .............................................~...................................................
~................................................
................................. T ...................................... T .................................................... ; ........................................................ : ...................................................
- ': ,.". i-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . "~......................................... ; ...................................................... j ..............................................
i
...................................
l ............................... ! ....................................... .i"............................................................................................................................................................
l .................................................
i i i i
t i .....................................................
!
t ............................ o. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ...............................................

.....................................................

i
t i '
t .............................................................. 1 psia = 6.895 kPa
i
i 1 psia = 51.71 mm Hg

i i. . . . . . . . . . . . . . . . . . . . . . . . .
! i i
i
i !
!
i
!
i
i i
i I
0.01 I I i
1100 1200 1300 1400 1500 1600 1700 1800

Temperature, F

69
1 00 t t t I --
! I
--
'
CdF2 CADMIUM FLUORIDE

10

.-a
cn
Q

!E
3
cn
cn 1
2 I ......
..
L / .
/
5
Q
....... . ...

3 ...........
/ -.

0.1 ---UP- 4 .
.
. -....
...........................
- - ............ ! .................................................

'El
' - .
-- . ...... ......

/ I
......
, psia = 6,895 kPa
/ +. j 1 psia = 51.71 mrn Hg
I .

I
0.01 I
2000 2200 2400 2600 2800 3000 3:
Temperature, F
100~ ......... ,
] i i i
..._~
.... ,, ,~
...................................... | {
]yyi~.yyyT-y7 .......................................... i

Cdl2 CADMIUM IODIDE I"

i
i !I
!
.................................... ~. ........................ lrt

.... 1 ......... l I
..................... i i iI

3- , t " t .................... i .................................... t . . . . . . . . . . . . . . . / ~ ............................


] ............................................| ........................................ .r " [. . . . . . . . . . . . . . . . . . . . . . T.............................. ,..'................. 7 " ....... ! .............................
. . . . I-" ................ ' " '! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T ............................................... .r.......................................... i .............................................
. . . . . . . ! - 4 ........................... "~......................................... 4,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

----~-~--ff
r. . . . . .............
1' - l - -................................................ .........
i
~.
~.................... if .........................................
................................]~.............................
r ........................ ......................... ~
~ ~
................................. i .............................
. . . . . . . . . . . ,.:........................ . . . . . . . . . . . . . .
/ ! ! i i ! ~ i i
Q,II
~, ~ - - - - - , ................... i ..................... . ............................. i ....................................... i .........~ ....................... i, ................................................ |, ...........................................
Q. 9 | | i " i i

I ...........................................
L ............. ~ ................ L..................... i.............................~ . .......................................
.[........................................i ..........................................
Ii l i
'
I t
i i
i
i
7i i
i
i
i
i
CD I i ! ,
i

i
,i / ii i
i
!i
1 ~ _ . _ _ _ ".F.-_::-_--~_~---_-.q-----_--:-_-:--::-::~--_ i ..... ....
!../-..
....................
i i i
=======================================================================================================================================================~
............................................. t ........................................... i: . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(D
i.__

n .................................. - i " . . . . . . . . . . . . . . . . . . . . . . . i ................................... :.r................................. ! .............................................


i .....................................................
i"....................................................i ......................................................
--.-.4 . . . . . . . . . . . . . . . ". . . . . . . . . . . . . . . . . . . i. ..................... {. ....................................... .i ................................................... i. .............................................. .i ........................................
If.
....... ........ ,, ............................... , ........
0 i i i : ....... i ...................................................... t ................................................. T.....................................................
Q.
- i ................. i .............................. -[ ............................ i ........................................ 1.................................................... [ ............................................. i ............................................
> - !
!
9
i . . . . . . . . . . . . . . . . . . . . . . . . ...... ~.......................................... ! ............................................ ~......................................................L..................................................! .....................................................
i
i
i
,
T
I
:
I
"~
!
9 i i ' " !
! , i i ! i
- i l. . . . . . . . . . 4 i .~........................................ "....................................
i
,
i
i'
I i i

i i i i
i i
O. 1 ~ - , -. + ~. ~..................................................................

"1-'"-'-----i . . . . . . . . . . . . 7< . . . . . . . i . . . . . . . . . . . . . . . r .................................... t ............................................i.....................................................


.,................................................
i ................................................
9 ..........................._ _ i _ _ _ _ J ............ i........... '._L......................
i......................
~..........................................
t...............................................
i......................................
/ ! ~ i i i 9 i i
9 i ! i i ! ! !
...................................................
|. . . . . . I " T ................. -3" ......................... I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
, , , ,
"------'---- "--{ " ~............................
i...................................
i...................
I psia = 6.895 kPa ....................................
J i i i i I psia = 51.71 m m Hg

-i ....... i i i , ,
0 . 0 1 I I I I I
700 800 900 1000 11 O0 1200 1300 1400 1500

Temperature, F

71
100 1 I -_/...
I I I- -.*--..I-------
i - - -1

CdO CADMIUM OXIDE


I

I
3-.--
t--
-
.

----- \
I
10 ..
a
--
--

I ...
w.............. ..............

.-(d
V)
... . ...

Q .
@
3
V)
ul 1 /

2
a. ----"
.-
......

5
Q
I

3 -

0.1 .......
-
--a
-

-- ........ ....

...... .

0.01 i I !
1800 2000 2200 2400 2600 2800 3000
Temperature, F
100. , z . . . .

] .................................I I- ...... [ ............................. t ......................................] ................................... i .............................


/ i i i i i i Z i
A I 9 ! ~ " i i
7 ......................................... .r-- . . . . . --[ . . . . . . f ............ "I---- .............. T ........................ f ......................................... ! .......................... i ................
/ I I I ~ I ! i I

7 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i . . . . . -T-~-F ...... I. . . . . 7 ................ i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i . . . . . . . . . . . . . . . . i . . . . . . . . . . . .

,,,1 .......
J u 7 ....................................
,. . . . . . . . .
t j ,. . . . .
i
r. . . . . "--I . . . . . . . . .
I t. . . . . . . . . . . . . . . . .
i
"i . . . . . . . . . . . . . . . . . . . . . . . . . "+----7"
+ J ~ l ......... ! ...................
" I ~
~ - - '~ ~ + ...............
................ - +t .. ... .. . .. ... .. . .. ... .. . .. .. +......................... .............................
+.,. . . . . . . . . . . . 9. . . . . . . . . . . . - . ~ .....................
~................................ +~.............................
...........................................~
~ ~ .........
..... ~~ ....................................
.......................

3 .............................................. r . . . . . . . . . . . . r-. . . . . . . . . . . . . . ? ....................... T.................................. ~ ............................ , ................ ~ ..... ~ ..... i ....................................

~ ~ - ? .............. +................... i ............................. i ................................ t .......................................f ~ .........................i ...........................................i........................................


~ - - ' t . . . . . . . . . . . . . -- ................ " ........................ ~ . " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +................................... " ..................................... +................................... ~..........................................

]. ........... 9............................... [ ..................................


4 ..................................... ~..........................................
~................
Z;~ZZZ;ZZZ]ZZZZ:ZZZ[III ..........................................
._m 1 . . . . . . .
i I i ! i
,....................... - + ................................ L9................................... ~: .......................
; ..............
i i
,....~
:" . . . . . . . . . . . . . . . . . . . . . . . . . . ................."i ...........................................
........................................ IJ............................................
............................................~J..............................................
.....
i

i " i i i } " "


n
.................. +......................... +...........................+............................ ..................................
,.............................................
+..........................................
+.....................................
" I i i + 9 i "
i i ! " i " ..' i
i9 ! I, i, ~.
, i, i, i.
: ,I :i ; 2 +.
, :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
(f3 ~ I :
(f) ...............................

L . . . . . . . . ~. "~ .................. l. . . . . . . . . . . . . . . . . . . . .
".:. it . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t-'......................................... l~........................................ l~......................................
t.. ............................................
. . . . . .
9.................
" ....................
, ===============================================================================================================================
~. . . . . . . . . . . . . . . . . . . . . . . . .
........
"~.................................. i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ............................................" .............................................~.......................................... ': . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
s - ~ " .................... ~....................... ~.................................. +................................... ".;......................................... .';.............................................. -: ............................................. 4 ...........................................

0 1 i i 1 i i 1 i
. . . . ~ . . . . . . . . . . . . . . . . . . . . . *.. . . . . . . . . . . . . . . . . . . . . T............................. ";,.................................. t ............................................
f ..............................................
+.............................................
.:. i ............................................
I ~ i i i i i i
>
. ............ ~ ..........................

/i i
i
i
i
"
i
"
i
i ':
i
i
i
i

................................ ~ ..................................... ; ......................................... ~ ............................................. 0 .............................................. +.:.............................................. +..............................................

- t ......................... ~ ............................ +................................................................ i ..................................................................................... i ............................................. i ........................................


............................. -~............................. T ..........................................................................................................................
i ............................................................................................
i ...............................................
i ...............................................
.......................... P ................... "~...................................................................... t ..................................................................... i ......................................... ! ......................................
................................... i. . . . . . . . . . . . . . . . . . L. . . . . . . . . . . . . . . . ~...................... ,. . . . . . . . . . . . . . . . . . . . . . . ;. . . . . . . . . . . . . . . . . . . . . . . . . ..+ .............................. !..................

- I ~I i ~+ .......... :+ ..............i+...............................

- i" ii ............................ I psia = 6 , 8 9 5 k P a


i.......................................... ................................
I i 1 psia = 51.71 m m Hg
_ .,+. . . . . . . . . . . . . . . . . . . . . +..................................................... +.....................................~.......................................+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I i I I !
i I i I i i
i t i ; ; i

i
!
i
!
:
~
i
:
i i
-'..

i I i i i
0.01
I I I I I
-230 -220 -210 -200 -190 -180 -170 -160 -150 -140

Temperature, F

73
Vapor Pressure, psia
o __._1.
b o o
o b .o o o
0 o
IIII
I I I
oI
fJ"l I I I I I IIIII I I I I I

rb
0 I I Iiiii i ~
o
I 1 1 0
t Ii i ,,, ! ~o
0.)

g- i

l, liiii
ii.iiiil. .!!,*i. .!ii..II
'i '
Ii I I i
"-t~- i i.i
~ o
l!i!!il i i,,il!iil i lI,,i,,i iill
[]]iii' "i i!"
~o-
' Ii! i'i ..... !ii
c_,

mP~- ..... it
41,,,, ............... i
, 11
,,-- i:i 'i
!+''''!
, i i
il
i i... +',i! +i ' '
i '+ +' ....
ii
-i-~-l-i, "1-ITi.;I
ititi
it+if
i iIii Ii' I li i+I J :i'! ~I ,. ,~,i,i ii' 1 ii!il
,, , , , , , ,
,. . I t I ~ +i, :iii+i+i+
, , ,
, ~i , , ,i., '-i ,i
. . . . ' + , +,~,
! , , , 1! i I,e ,i ~9 I :. . . , . . I!i,I I ., . . I . .I, . . '-'.,,
, , I , ,IIi. i. , . i +
g- I . . . . . li I+ I , I t,.I + ' "
-" "" +, +........... - ' - + ...........+ - " , - P - P ~ , - ++.. . . . . i .......... , -,.~,. + - - - 4 ..... ++.H ......i : J : : + . ~ ! ......................-+'.............l .......i ......I + : H H ! ...............-+.:- .h-+.-
.-o-.o la, + + i ++! i+ , I ! lilt+ + + +J~s~+z i z +~+i+i ............-T~-I [ ....FH4.
+ iiit
-.-. Ii + i +ill ++ + ' ~1 i i i i i++l,+ i I Ii'!++ ' " !
m + i+ + + i "l+ I+ , i i ' i'ili i ; [~ + l , it ++it
,. , ,.,+, 9 " " "
i+. ! i i-I+-I, ' ' ' : I "1!,i, ,, , , i
II II "" ' i " ' :' ++ Il + ,il ++ , ; + I :''" I i' ~ ! l~'["l llill
u.z'.o', +, ~ + +++, +, l+~si+ + ~ I I,illi ~ I i i ' i iitll
I l k ....+-r.!J.l
ril!l/
: : |
+'"+++~r ' .m----p--lllll,
l ,l i!' l+! illllll
i:: l + ill" ...... . . . . . . li ....i, ,,+iN:,: i:l i l:,l ,,l,i
' 9 .............l+'l '- i,,:,llll,
l l !,,l' l lli,ll,.
. i, liI l ! ,!'i 'l ....................
+'i ll'!ll k
ii' , I , i,! I: I ll:iI'' i i , i ' I i i !I I' '
g_
o !I i+..."iii
i +! i ............. i -i+
i i~il, i
I,' ii ill
i ii Ii
+i l--l-i!li!!
i i I !iiii i
Ii I, !+!ii
ii..-+i
l' I-!---!-ii-ili
i ' i iili' + J :
l, :i ii:-'li!
i : i i ;i ii !i "i i",i .'.,"
i! !' "! '' i" :+i
ii,ii +: i" ii i'i,'l:
i i+iii I." i9 i ii ;i
i!!,i li i' ii ,I
-,'-+~+I
! ~ liiii ! ! i I -': i: i i i i'-iii I + i iii,i I i "i' i ' i i iii
! iiii' i i i , ili II , i i ;i',!' i I i ii~!! ' i ,!i i , .
, ,, ,i, ' ; , ,,, ,, J i , ,i,,~ , : ,,,+~ i ! ,i,,i,
It !~ili~iit=,.:
+i ii i+
+l ii ii i!.!! ii i 9 ~i i!iiiii
it!i.. iI ii i+li~i
i itli: I: !l i~
: t !iii
!.i-'i i
01 ii/
0
Vapor Pressure, psia
O
O ,,,,.i,
O 0
O CI

2~ 'I
0
0 iii!
!
i
i,ii i:, " I !- T
ili! ' I -r
i ii
t----i ....-+-+,-i m

0 ii
I ~!
<>i-- 84
I
ii ,

s : l m i
'
i
iii
i i ~i ~! !
i 9 : : : : :
i i i
0 !
~ i
!
i
1
i i, i'i"i'i
i!,! i
~ii i I i i~i o
--I 'i i
'' ii i
iiil
i !
I i
~..,_~,_.,,.,......,
ii E2
9 o . |
i..... __i .... _.i .__i__i.'....,~...i
i i I'I'1 I
i i ' I i i. . .i. "i i "'"iii
i 9 i ill, i i ! , i i Iii
i Ii!i c-' I
~ ~I ~I i~ ili
i i i i,-
,i!!i i\ i i i I i I~i
l-" , ! \ ~ i i !iii!
i....'~..~......".--~-~...-:.-.'.'...-i'.
'i
§....
,i...... "..i
i
L.!_.LIi,
ilili
i i iii
i ! i! ~i i!i
i i i ii.' i i IX i i i ili
"Ti t ! ::
,i! i I\i i i ~ii
i i\i ii !ii
iiili i i X,.' i! !~
! i ! !i i i i\ i! !i! i i
' i
t ....... ~i........i i " i " i! , ] i i " " ! i

.
~i !i i ii ii ! ~i \ i ~ i! i ii ' iI ii ii ,", !"l "
-o"o ~ i i il i\! i iil I i s
_~.__. .... i ,.. : il i~i !!i I i I i
lit ii)
II II
iilii ! i\iiii i , !
iiili i . i i ~ i l i 9
m ..................i._i....i...i-...................~ .....................
+ ........
: .....+......L-..~..-I-.,:
.......................
,:...........~..........
4m-i.--~.-~- 4.-I-i .......................
~ ....
i
i--
~ i
__.ii,.--4. ....
I
~
i llii , ~ : , i lxi,~, ~ , ! i ,
Z i i Zii Z i Zili i ! S i ~\ii t i i i i
lit
i i i iii i ,,I', , , , ' , ,,.', , , , ' ,
E i i ! iii .- i i l i i i i i i i ! i H \ i I i i I
...........i........ I......I...."-....L..I. ....................... ~ .......... i .......... i ................. "~..... ' ..... !...-i.4 .................... ............. 4 ........ 4--~ ..... ~4.4-.'-..~ ........... ~. i .,. .! i.... .

i , ii i
!
ii9 | i
:
i: I: !: ~'i , i~iI! ! !
\ %. i! i~ i| i:
i i i i! i' .t, . . . I i "' ii ii Iiiii '~ I \ ,i ,i ! ',

!
' ' -'- ' i '-~ iI--- ,: i
!
,i , , i ! , i! , i ! i i \ ,i , , ,
t
i i
: '
i i , ii , ,i!i ~i i, ,I ~t iii i iii \ !
i
! i
!' | i ~ ~, , ~ ! l !~!! i , 1 ! I,
' i
O
1 O0 == i ................................. i i i i [ i
m ' ~ . 9 , [...........................I.............................t................... r...............................................................................
1.........................................
i......................................
....................~......................................................................1............................! ..........................
- . . . . -I.. .................................................................. .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4- . . . . . . . . . . . . . . . . . . . . . . . . . .

CIF5 CHLORINE PENTAFLUORIDE L [ ] i

. . . . . . . . . . . . . . . . .................................................. i. . . . . . . . . . . . . . . . .

10

, , m
{/)
. ...........................................................................................................................................................

(D L I
5.. l
............................ !

0~
i
(D
I,==

a_
L _

0
Q.
>
.............................. !

................................. i ........................................................................ b. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

iii iiii Z
/ ..............................!..............................i ...........................................................

1 psia = 6.895 kPa


......................... i.......................... I ................................ + ............................. 1 psia = 51.71 mm Hg
l :
l
! l l
!

t
iI "l ~
'I [
;
[
i i
0.1 I I I I I I
-120 -1 O0 -80 -60 -40 -20 0 20 40 60 80

Temperature, F

?6
10000 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . :. : ! ................................. r ................... ~ . . . . . . . . . . . . . ... . . . . . . . . . "=+ 9. ..............


. . . . "P. . . . . . . . 1 " - - - - - = : = - ~ - - !

t"" ............... ..+


- CIHO3S CHLOROSULFONIC ACID i--.----:.:2:1
IOOO t"-+. . . . . . . . . . . i+
. . . . . . . . .

....

F . . . . ~ i
1 O0

I~-'=.-:Z--:_-_-~_~__.,
t - - - - - ' t - - - - P . . . . . . . t - - - - 7 ~ t
..~_.-_-~_--'-..-..-..I'-':'I - ......
-=9
4 .........................
!
~. ................................
l
.+. . . . . . . . . . . . . . . . . . . . . . .
I
..........................
i
, .... +
. . . . . . . . . + ....... t
i i +
10

=•=L--------_4_
. . . .
I
.; . . . . . . . . . . . .
! I
-~:~:~::~:~~~-~:i~~:~i~:~::i::::~::::::::::::::::::::::::::::::::::::::::!!iiiii!ii~!iiiii~
-L.J.. .......... 4 9 -- $ " "
|/ ............ ~. . . . . . . . . . . . . +. . . . . . . . . . . . . . . . . . . . . . . . T .................................. i ................................. i
"

F I r;. [ i9
. . . . -'----t- . . . . . . . . . . . . . . . ". . . . . . . . . . . ". . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . . .i ................................ +:. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~,

| I '
-~ :
.... " l
,
!
+: +;
................................................... / J + ! +
. m
1 ................ !

~_- ...................... : - - - - - =.-----:=+


: 1 i
i, ..... -Z ...............................
! i ..........................................
+ '!
Ik--
0.1
+ .'. +- +

t
......... 1............... t.............. Ii............... ~,
! ! ..... ]

s~_ T
n 0.01
! I I i ,
.L. . . . . . . . . . . + . . . . . . . ,i,

O ,L . . . . . . . . . . . . . .
_=
~. .................
! :

c~ +... . . . . . . . . . .
|
+ ..................
!
4
i
i.."
9. . . . . . . . . . . . ~ .................... 4.

>
0.001
,
i
i

! | t r ~ ! 9 ' "~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

~ ~ i + L
. i, :, +. . . . . . . . . . . . + '
0.0001
i ....
2 ...................., ,i..................................
it................ '+ +, i i 1
+t + .......................:;--,_..;------__:--_.=:--.u===::+..
~,. . . . . . . . . . . . ~ .................. ::::::::::::::::::::::::::::
I
9

:
.

l |
9 :

i
{.............................+.......................... +
+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 ............................... 4
i I ~ l
l ! i !
1 E-05

I E-06 ................................................................
:===== .............~.................... + ...........................,L...............................j ................ I p s i a = 51.71 m m Hg

-~--'r . . . . . . . . . . . . +,. . . . . . +.'. . . . . . . . . . . . . +. . . . . . . . . . . . . . . 4 ........................ ~ ........................ +.................................+................................+.............................. +..........................


........................................ t + t ......... §................... + ......................+............................+................................+.............................+...........................
.'
= ,,-,1 .................................
! ! , J i + + +
1'--"-1 ~ i i i i i i I' I:
-200 -1 O 0 0 1 O0 200 300 400 500 600 700 800 900

Temperature, F

77
1000

CIH04 PERCHLORIC ACID

1O0
i~i~iii~ii~i ill_L______ !

10 ~.!
./
/
/
/
/ f

-- L:::
-- zi..

Q. J

/
(D
I,=.
............................... I i................. --.

0.1
(D ,j

13. | 1
/
......................................... i .......................................... l ........................................

0
Q.
> 0.01
/ ..........................
i
:t' ......................................................................
!
I
~.:-:" ................................

iiiiiiii~-i~i~ii :~:i:..................... IIIIIII~I~II~,LIIIL~ILLLIIIIIIILLLL,IIL, I


1 1

0.001
/ ii12-:! .............................................
i ...................1....................................
9 .'j

/
1 . . . . . . . . . . . . . . . . . . . . . . .

1 I

0.0001
/ 7
.. i
,

- -...--.--.---4-c--
!
! .......
...........
..........
=~:=-----==.===---::==:::t;il!' 1 psia = 6.895 kPa

/ 'i r .....

i iiiiil1, ..... :

1 !
1 E-05 i I I I
-200 -1 O0 0 1 O0 200 300 400 500 600 700
Temperature, F

78
10000~ 7
......................,
II::77777-:Z__LZZI_J'i .....................
,
] ..........................
,
r

]717111~17 i:iJ C102 CHLORINE DIOXIDE

i i i i i i i i i i i i i i i i _i i ti __i-
! I !
i "
'I
i f
! i |

[ !
i i
i l
i............ ; .' ! i
1
I i
, l i ,. ............................. .,.! ., ...................................... .,
z t

i i ! i Ji
I i li i
i
. . . . t
c~
!

................ t
1
.

L_
...................... 4......................
.... T [ i 1

7---q t ' ................. i


,i t ............................................ ,. . . . . . . . . . . .

n
i t .................................... ,

o i
, /I ! 9
c~
10 t.............. ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . a . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............................. 4 .

>
,r . . . . . . . . ~ ........................ ,. ......................... 4 ................................... .,..
..................... , ................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . ~
i i
[. . . . . . . . . . . . . . . . . . . . . . . z. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -T' .................... '

t !
i
,s........................ 4

i i
.i
:L ...................... =_-i .................... ::::::::::::::::::::::::::::::::::::::::
i !..........................
i
J:_
I" ! f k .......................+.........................f ............... f ....
T ! ~ ~ . . . . . . . . . . . . . . . . . ",..................... T. . . . . . . . . . . . - r ....

I i
t-- ..................................... ..............................................................
9 1 psia = 6.895 kPa
i
i [ ............................................ 1 psia = 51.71 mm Hg
i ti!!!!!
I I l i i
E 9 } "

! i z ! i !
0.1 'I I I I I I
-1 O0 -50 0 50 1 O0 150 200 250 300 350 400
Temperature, F

79
10000-
t I i T

!
!
CI2 CHLORINE .....

1000 f
J

fJ
J
=,,~=

oo
lb. 1 O0 -~
x
(D J
L_ f

/
. . . . . . . . . . .
03
03
(D
!,-- /
J
13_
t._

0
lb. 10
> /
/
7
L Z
/
I
i

/
.......................... , ........................................... ! ...............................................................

111111111111111111111111111111111 iiiiii ii
"~ I IIIIIIIIIIIIIIIIIIIIZIIIII iii i

-if ill/ ~i 1 psia = 6.895 kPa


7 - 1psia=51.71mmHg

f
0,1- I
J
I I
-150 -1 O0 -50 0 50 1 O0 1 50 200 250 300
Temperature, F

80
I.- .................. t ........................ t L
.m. I
..................................................................... "r . . . . . . . . . . . . . . . . . .
........................ 4. .......................... ..!-. . . . . . . . . . . . . . . . . . . .
/ ........; ;;Z;Z ; ;I F--~
_1 ........iiiiiiiiiiiiiiiiiii CI20 CHLORINE MONOXIDE ]

1 ii 1 i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
..........................................

I
_ ______!
|
....................... I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i

............................ T

J- fl
J
t
i
i !

!!!1!!!!!
10- ) ~ ~

!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!i
I ................................ t ..................... "!. . . . . . . . . . . . .
i F ............................. ..i. . . . . . . . . . . . . . . . . . . . . . . . . . .!.". . . . . . . . . . . . . . . . . . . . . . . . . ..e. . . . . . . . . . . . . . . . . . . . .

- = ' ................. "T . . . . . . . . . . . . . . . . . . . . . . . . . . . . . r ........................ ~" E..................................... r ...................................... I .............................. I ..............................


- ! ...................... ,} . . . . . . . . . . . . . . . . . . . . . . . . , .............................. ~............................. ;.
; z |
- - - It . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ............................ ~.
, i

........................................ l T .................. I- .......................... t .......................... .~-


|

i / i
a:I
.m,i
!

I=l.
................... ..................... ~ .~ ............................. ; ................ ..~.

(D i ! i ! ' 7 i .......................................
i.................................................................................
I
! , i i 1
4_ . ' ,) : . i i .
I" .......................... ? ........................... ~'................................... ) ...............................

(1) - ) ....................:::::::::::::::::::::::::::::::::::::::::::::::::::::::
%--
~ ! ~ L .... ~..
13_

_ _ _ . ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i . . . . . . . . ~.~ ~,,. . . . . . . . . . . . . . . . . . . i.~.,

O
........................................ . . . . . . . r

> ,t"

i ': / i
- i
~. I i rI !
!

! ~
. . . . . . . . . . . . . . . . . . . . . . . . . .

1
/ t

i i !
/ i
i i i

0_. _1 -- ........................................{ ..................... '-'/-t ............


............ ~i ..............................
........................ ~' ............................
................
~:-L ................................... t .................................. ~ ......................................... .i ....................................... ; ...................................

~,-~
- ............ ......................... )............................, ...............................t ........................................
~ .9. . . . . . . . . . . . . . . . . . . .
~.....................................
~.......................
i ..........................................
+..................................
}" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................. .~...................................... 'i ....................................... .i . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- ....................................,I...............
, 4 L~............................ T...............................
t " " i

t ................................. r ..................................... ~.................................... ! ........................................ : ......................................


!............. 7"-i
-~. . . . . . . . . . . J ......... ".;. . . . . . . . . . . . . . . . . . . . . . . . .
m ....................
§ ..........................
[ ........................
.~. . . . . . . . . . . . . . . . . . . . . . . . . . .
r .............................. t .................................... t ....................................... t ...................................... ', ....................................
~ .............................. ~ .................................. ~ ................................... 4 ..................................... 4 ...........................
i | i i i i i
_.Z. ..................: i ! ~ " " .'. I
"
,
................................ ; ................................... "," ...................................... I' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I" ..................................... i" ................................... -" = - - - - - ~ ~ ~ - . - . . - 4 .................................

.................. i 9.......................... f~ ................................. i! ............................... i! .................................. ............................... .


! ........................................
/ ! ' :
i
,i I| 1 p s l a = 51 71 m m H g
_____,,_~ i". . . . . . . . . . . . . . . . . . . . . . .: . . . . . . . . . . . . . . . . . . . . . . ....................................
"

1 i ii
i ...................... i- .................................

, i '
i ! i '
0.01
, ) ! , 'i ! !
i I I I
-160 -140 -120 -100 -80 -60 -40 -20 0 20 40

Temperature, F

81
1 O0
.... i .................................................................................................

CI207 CHLORINE HEPTOXlDE


................................................................... i

II

lo

............................................................................................

m i

(D
:3
(/)
(D
IL_

s
I,.., .........7i~ .....~7 - - ~ !.............................................
0 ]
Q. .....1,1.,21

>

i
t i
1 I
0.1 ..................................................................

:TIII_IIIIIIIIIZ___II iiiii:i: ...... J ! ......................................................................... " ...................................................................................

777--;;;Z ;;;;; ;;: : ;! .__

_IIIIIIIIIIIZIII
...................................................................... i ....................................................................
z ~
.................................................. + ..............................

- i
.

L................................................................................................................ [ ................................. 1 psia = 6 . 8 9 5 k P a


i 1 psia = 51.71 m m Hg
-Jr ...........................

! i ,
!
i i
0.01 I
~ .

i I I
-50 0 50 1 O0 1 50 200
Temperature, F

82
...... ~ ................................... ~'_ . . . . . . . . . . . . . . . . . . . . .

u:: . . . . ;::::
. .::::~. .
. . . . . . . . . . . . .

::::::::::::::::::::::::::::::::::::::
:;;;;;;;;;;;;;;;;;;:
Co
. . . . .

COBALT
. . . . . .
-__---__Z~[
........... "~
!ZZ_C_-Z_-_--_;-ZZ;[ZZ;Z;ZZZZZZ;-Z-~ZZZ;ZZZZ;_Z~-~;
i, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~:TZZE:Z::Z:Z"::'::::::'.'.;..~-T...-7.-.'.'.

10 ...................................................... i=============== :: = = = - = = = - - i = : = = = = = = = = = - - = = =

l:--c::..~--~=-:--:---::::::::i::::::::::::::::::::::::::::::..--~::....:::::..--~:..-~...---~!~..~.-x~..-......-:::-.....-c...-::.---.-.-----~.-:
~
~! .................................................... t "...................................................

i
i
........................................... [ :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
2.
| !
!
i
0.1- 1
! ................................ 9............................................................ ~ ..........................................

= _ _ m
]i
i .................................................
:_.........................................................
., .................................................................
~ ....................................................................
$ ...................................................
~ ..............................................................
i

!
i ........................................................ t ...................................................................... '~ ...................................................................
9

O_ o.o~ : = 1 ~ . - - - -.......................... ,~.


!

1
9 ...... :.~"............................................... :, ......................................................... 9.................................................................... ~ ....................................................
4.............................................. '............................................................... , ................................................................. ; ....................................................................... : ....................................................................
................................. ......................................................... ; .................................................................
9 |, ....................................................................... ~ ................................................................
| 7
i
/ .... ,"............................................... t ..................................................................t .......................................................................
t ...............................................................
ffl
i / i i i i
m 0.001 =~--~-~--. ::=:=t=::=::=::=:=::=::=::.~f-:... "~=~:::::i:::::::::=:::::.".~:::::::=::~:::=:===:::::::=~::::==========================::::"::::..:.::::::=::::::::::::::::::::::::::i:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::i:::::::::::::

~ ========================================:::::::::::::::::::::::::::::::::: = : = = ==: = =: ==: == ::::::::::::::::::::::::::::::= :::::::~:::= :::= : : :::::::::::::::::::::= - - =


1. . . . . . . -~ .............. .~" ....................................................................................... .~................................................................ t ............................................................

~---t i [......................................................................................................................................................................
0 T--Z_ ,!.........................................',
o. 0.0001 ....
! ..i IL........... :--....."::: .".:....."~....."::'-".."...":.".
...............................................................................................................................................................................................
:; .'=.:: .'~:....".".".:: .".;::.T..T: ."..".:.".".:'..": :.."::.". 2:::;". .".:.".".:::.": ."...": ~:.". .".:::: ."..'::.': ."..".."..'=...-"~".-'.'::::: .':=:::.".::..".'::::'-::: .T:".:::: ~.:;..":::;::.".:: .".-';:: ::::::::::::::::::::::::::::::::::::::::::: .2:::::: ~*:::::::: .2::::::::::::::: .".:::.".::::....":.."::: .".:::.."....'-.:: .2:::::::.".

: i

1 E-05
/i
.......... .i .................................................
i
i. ................................................................
J 9................................................................... t ......................................................................
, 9....................................................................
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~::::::::::::::::::::::::::::~::::~:~:~::::t:::~:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~:::::::::::::::::::::::::::::::::::::::::::::::::::
. . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .............................................................. ~ ...................................................................... .: ......................................................................
~-'4' $ .................................. " ............................................. 4 .............................................................. ~ ...................................................................
.~ .~....................................... ~................................................... ~..............................................................
~...........................................................
| ~ ; :
...... ~ ..................................... § .............................................. t ....................................................... : ............................................................................................................................................
i i i i i
i
1 E-06 .... ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~.......................................... ~ ............................................................ ; ................................................................... ~............................................................

i ! , :"
|
_: .................................

} i j 1 psia = 6.895 kPa


1 E-07 t ............................................. :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: 1 psia = 51.71 mm Hg
..---4 4 ......................................... f. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i !, ............................................. ~i ...............................................................~i .......................................................

4................................ ; ......................................................................................... ~............................................................. 1.....................................................

1 E-08 I I I I I
15O0 2000 2500 3000 3500 4000 4500
T e m p e r a t u r e , F

83
I O0 i ] ; ................................ t ..............................................
I
,}...............................................
i

COCI2 COBALT CHLORIDE !


.................................................... I ...................................

t t

t, i!

I 0~ i r ...........................................ii............................................
-- . . . . . . . . . . . . . . . . . . . . . . ......................................................... [ r................................................!..................................................
i .,,,,,.
or)
- - - - - - - - - - - ~ - t ======================================
.............................................
C)_ . . . . . .-- . . . . . . I- .........~ 2 Z I Z i Z Z Z Z Z Z Z Z I - Z Z , ............................................................
cg . . . . . . ~" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~
~ I I
............... T..................................................................
I
l,,=.

Or)
U~
(D
L_

13_
L__

> i

...........................................................................................................................................

......................................................................................................... i ...................................................................... 1 ......................................................................


!

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . b. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
~ ......................................................................
!
t ................................................................
I
1 I
!
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T .......................................................... ~ .............................................................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ' ............................................................. T .....................................................................


i
? ..............................................................

1
1 psia = 6.895 kPa
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .' . . . . . . . '" i 1 p s i a = 5 1 . 7 1 m m H g .....................................
!

t
! i
i

! , I i
0.11 I I
1400 1500 1600 1700 1800 1900 2000
Temperature, F

84
1 00j ....... i ......... J.... i ..............................................
t ..... ,.,
:::::::::::::::::::::::::::::: , .... , , ................. , ,. . .............
J !

]ZZLZL]]I CONC304 COBALT NITROSYL TRICARBONYL


]iiii ............... I
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii
L!_Z ..... 2 1 , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1 0 - .......... - i ................................~t........
t i .................................... ~.:_ ....................... ~.................................
o~
.......................................
] 'i .............................................................................................................
i. i: i~!..............................................
~ !i-..........................................
. . . . . . . . . . . I ...................... "T. . . . . . . . . . T .................................. T .............................. T. . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I,., : I I i !

0~
........................................
i ~,'i
{
.....................
_~ ~',i~..................
.......................
"__
~'~ ..... ~~,' ~ ~ ........................ 4 .......................................
i'l...........................,~""
Ii..........................................
........................
"
+ .......................................

L_
: ! i i
i . . . . . . . . . . . . i
13_ ,
i
~ i
,
i
I
i
I
i
1 , ~ . . . _ . . ~ - ........................................ , .......................................
O i i i I , ,
it I i i l
ii
> i' / ii !i ii ii 'i
i i i 1 i i
1 .-.-~~.t-~'~.Z' .... T__'.ziz_-Z.2s= - 1 = ~ :Z:_'-Z2CL:iZ:ZZEZZZZi" Z Z:Z ZZ]ZZZ:;].Z Z.Z_-.Z-...__--Z].]]
................................... _ _ Z .. . -. . ~ ~~ :. . _ ~ -. ._ .. . ._ :~ . . . . . . . . . . . ,~'. . . . . . . . . . . . . . . . . . . . ',.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .'. . . . . . . . . . . . . . . . . . . . . .
.... ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ....................................................

- - - i
_ ~ 7- - - l
I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
I' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
Ii .................................................... r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- i, ,~. . . . . . . . . . . . . . . . . . . . . . . 4,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 .............................................. .i-...............................................................................

| i ! :" .: :.

-
!
l
i i i
~.................................... ~..................................................................................... 4.....................................................~................................................~ ..............................................
i i
i i
i
i': i ' '
! 1 psia = 6.895 kPa
............................ 4 .................................. 4 ....................
1 psia = 51.71 mm Hg .................................
i! i i i
i i i
i 1!
!
t
i i

0.1
I i
i ! i
i t
i I I I
20 40 60 80 100 120 14O 16O 1 80
Temperature, F

85
100~ - - ~............................................................................................................
i -'-'-'E~'.':EE:-'-"::-'-'::""':'::::::'"': .........~..........................................
............... ....................................................... ...............................................

Cr CHROMIUM i
1 O_ m
, - - ~--.=---~----.
- - = = = : : : :::::~!!!!!!!!!::!!
u

1=

0.1-

lu

o. 0.01=

l_

0.001 _=

13_
0
0.0001 -
>

1 E-05=

1~ t~
1

I1 psia = 6.895 kPa ~


...................................... il-'i'ii'~'~'iiii~ii'-"'-~''~'iiiill
E--E--'.EEE~-..-'-~.s = 51.71 mm ~ EiiE:.:Ei---.'.~-T.."..ii-.'..'i

1 T
1500 2000 2500 3000 3500 4000 4500 5000
Temperature, F

86
100 ,__ , ................. ,|.
9 . . . . . . . . . . . . . . i 1
I

~iii i 2121111 '............

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

10-1 ........ ;
i
t .................................
,
t ................................ ~
/i ..... ~-
9 i r. . . . . . . . . ! ................ 7' ...... T-
" ! ~ ...... r .......................... .,'..................../ . . . . . . . . . . .r-
-17112ZIIIZZ771 .............. ! ........................................... [. . . . . . . . . . . . . . . . . . . . . . . ~r................. 7 " ................ !-'
............................................. ........................................................
9 t. . . . . . . . . . . . . . . . . . . . . . . . . . . . t .......................................... t .................................
---------------- }............................ i ............................................... ,~....................................
I !
~ - r ................... ~ .......................................... i ...................................IIIZIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIlIIII ........................................ J
= m
. . . . . .
!
'" . . . . . . . . . . . . . . . . . . .
,
i" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I
: ...............................
/ J
"." . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
I ...................................................... i

s,~

! ~ i i !
! ! ! i
I i J i i
f,#'} ,1 .......................
I
~..............................
~
_1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
J - / 9 . . . . . . . . . . . . .
J
t ...........................
i
~.. . . . . . . . . . . . . . . . . . . . . .
/

13_
_L_: :~ J...............
:.......................... =================================================== ................... 1
]:::.___:_::_:
::_i
:i:::
i:::::::
::::-s_:::::~~! ~ - ' q __~.---~- .--.-_Z ............................. i............................ I
0
4 .................................. i .................. -7 i ....... ! ..... - ..................... i- . . . . . . . . 1
1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i. . . . . . . . . . . . . - [ - - - 7 - - [.................... [ ....................................... l ................................... 1
> 4----------~--__ ..___.x_ . . . . . . . . ,~ ........................... ~................................................i ..........................................
/ ! i ~ l i ., /
I I ~ i i
t i i i ~
1 !
i
/ ,
, !~ ,! ,j
/ i / i , , ,
i i i i i
O . 1 ~ .. . . . .. . . . .. . .. . . . .. : . 9... ... ..... ... ... .. ... ... ..... ... ... . . . - - ~ . ' _ ' T ~ =~.. ... .-. .:. :. .:. .:. :. .:. .:. . . . . ..........
......
. . _ _ . , i ................................
..................................... .~.........................................................
.'.................... i ..............................................
,
T 9 T .............................. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

~---------~ .---=T-:
,. = :::.--:--:Z=-
~ :,t::::_-::-.-_:::_-:_-
.----::=F:
:---:- :::-:
.-::::::i::::::
:::::=:::::
::::::::::
::::::::_::::
:~=:::::::::
=::=......
:-_-='
.j .................................................... , _ ~ ~ _ _ _ j ::::: ,. . . . . . . . . . . . . . . . . . . . . . ,.................................................., ..........................................
1 ,_ ......./ ...... i ., i z

[ z:--:
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!
i
i
~r i[ J 1 psia
=.
6 895 kPa

J...............................................................
................................. ~ .t . l Ii' il "
~1
! ~-"
! ' 9

i ~ I l i
i i I I ,
!
i
I
~! I
l
.
0.01 i i
50 1 O0 150 200 250 300 350

Temperature, F

8?
1 O0
i .... ~ ..... , .......................................... !Tr
9 ................................

Cr02CI2 CHROMIUM OXYCHLORIDE ...................................... T. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I


i

10

. m

03
C].
t____

oo
oo
(D ZI iii iii iiiiiiiiii ....... i iiiii iiii .... [iiiiiii~'m~--".~T'~
t__

13_
L_

0
C].
tO .... i .... S .......................
t .......................................i .......................................................
'.....................................................
i
>

0.1 & ....................................................................... ''Z'-.T'.'T_,';:'-::Z:':::':'_'Z.Z'Z'E.


,II"2"21"I'I21"T'-I"-"ET."T.-..'.'IIT..".211111"-I!IIT-E
/ - ................................ ,,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t .........................................
/
/

/ ,,Z~ ........................................................................................................T..............................................................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

I psia = 6.895 kPa .......................


I psia = 51.71 mm Hg
r ....
j I

i i
i

: ,

I i I
0.01 i I I I
-50 50 1 O0 150 200 250
Temperature, F

88
68
-I ' e J n l e J e d u J a /
001;' ~ 00~ ~ 000 ~ 008 009 0017 00~ 0
i i i i l 1 80-3 I.
i i i i +
+ + + i i
i i ! i 9 ! I I
.......................................................... P........................................................... "."..................................................... 4- ............................................. .'-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ . . . . . . .
....................................... ~ ......................................... § ............................................... + ............................................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ..........
............................................................................ ~............................................. +......................................... ,.,............................... i ................
.................................................................. @ .................................... .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . i . . . . . .
ii:.:E=Ei~i'E.".'i.:.'iiiiiEiiiii iiiiiEiiiiii.:.'E'Eiii~ .'+.'ii .:.'iii.:.'."::~:~.-'.'.:.':=:=::::: =: :":-" =:: =: =::F=: = ::::: ::::: =::::: = "-":: =:::: :-I ==: =: ::::= ==:: ==: "-"=--= :::'==.-':----:=,
.................................................................... ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: .... = = - = - = : - : = - = = Zo-:m
........................................J............................. i ............................ - . . . . . . . . . . . . . . . . . . . . . . . . . !. . . . . .
....................................... i j i T ----/ ..........................-1-
.................................. , , .......................................... + . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , .................................. . .......................... +. . . . _ ~ _ ~ ~ _
..=: :-=:::::::-: = - . = :.;..-..:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ~:-: :::-:: = : : : : = _ : :::::~-: : _ - : : : = _ : : : : = : i i:=-~:::!iiiiiii!i!!!!!~-~L
i ~:.--..-:-:-~::.:-::~:::~.::~::-.+.::~:-:::"--:~.:~:
::== :::::::::::::::::::::::
:::::::.::= -:::= = '= = : - = : - " : - = = = = = = = = ~ - - = = = - : - = ~ - "' - ---~=, ' -........................................
- ~
it=
i
"
i
"
,
!
! ] . . , i'=f"
!
[ 90-3 t
....................................................,'-...........................................................
" +..................................................+ ..................................................................................................... I' -------
............................................ ~,....................................................,.'.............................................. ~ ................................. 4 .............................. j i . : .. / ..- -.- : . . . . . . . .
t -/_
..................................................... F ........................................................ +................................................ +................................... ~. t. i. . . . . . . . . . . .
F. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~..................................... ~.. . . . . . . . . . . . . . . . . . . . . . . 4" = =,____ ....................................... _L
===:"=="=:"::"-'=': . . . . . . . . . . . . . . . . . . !". . . . . . . . . . . . . . . . . . . . . . . :::~:.T.~:::.~....~:~.~::::::.~:~..-~.:~....~2~T-..~:2~.~:~~:~ ~: ": :
r ................................................... "........................................................... i ....................................................... ~ ............................................ .i:........................................ +. . . . . . . . . . . . . . . . . . . . . . . . . . . . / . . . . . +. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +...
I.......................................... + ................................................ +..-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~ .................... I.. . . . . . . . . . . . . . . . . . . . . . . . i,. . . . . . . . . . . /__..L .............................................. L
<
ga
o
......................................................~..........................................................
i .....................................................i ........................................... ~................................................! ................................... i . . . . . . . . -u
! + i ! : i
,i/
t L (.-
.............................................. [~................................................... ,+................................................ ", . . . . . . . . . . . . . . . . . . . . . . . . . - P +. ,, :;f l.................................... r
::L::".-....-Z;.'Z.".::Z.."ZZZ:.".ZZ: Z: D,::Z: ZZZZ :::::::::::::::::::::::::ZZ: ::::::::::::::::::::::::::::::::::::_: :..-'-'..:...-Z"-." i:-"--".-E.-.~ "...--."..-~..--Z._-~ Z :~Z." .......... ."..-.~'LTL::."
-'.'.-~'.i: t "-- . : = ~
::."= . . . . . . . . . . . . . . . . . . . . . . . . . . • ........................................... .+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ----.i- . . . . . . . . . . . . . . . . 4- . . . . . . . . . . . .#, . . . . . ~ <,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,rL-
::==:':.'."-.'--"Z::EEE .":EE~i" "' ii"~iEE!! EE Ei~"i!~~"EEEE EEE" "EE E!'EEi E:":EEEE'Ei- ~.~E'~ .~"Ei EZ-~-E "~E----~ !~ .EEEE--iE E-".'!:'3..~.=.".'.--Z""-~ ~ E':"--'::':-: ="=: =:=+---='--=-----'-"--: -o
..................................................~ ....................................................... ....................................................~..................................... +.............. ~ i i # _ . : i ~ - . ; .............. = = = .........~ = = - - - = - - - - * ~ ~0"0
t i i ! / ! I i
...........................................................
; .....................................................................................................................
9 ............................................
9 : .....................................
...._TL_______i - - - - F
.....................................................~............................................................
+......................................................~.......................................
~ ~ ..................................
' ~ - ........................ ,.......
.......................................................,,........................................................+.......................................................,.,.......................................... r -..:::EZL".':=:"::.":::::T"~.~=::Z--"_-..."ELT'=."==:.~'=Z:=--=:.':Z.T___~.
i i ..' _ i i I /
.................................. + ................................................. ..... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . + ......... _ . . . _ ,_. . . . . . . . . . . . . . _ + _ _ .................. ,. . . . . . . ,_
............................. "i', . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i .................................. 4 - - - - = , L - ~ ................... i. . . . i .............................................L
.................................. .,.................................................-."..........................................-.+.-.~ .................. .i-.. . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . + .......................... 4 ...................................... ~ + . [ . . . . . . . . . . . . . .
i. . . . . . . . .
L-.-------.- . . . . . .
.!---,
i ..................................
.......................
L
.. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . . . ~t. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . ~+... .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . .: . ... . .. . .. . .. . ... ... ... ... . .. . .. . .. . ... ... .. . . . . . . ~L .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . " ~. L. .-... . .. .. .. .. . . . .. .. .. . . . .. .. .. . . . L__ ~ LLZZ]]L]]TLI771T--T--
~=..._. ._. _. ._. _ _ _ ........ ..................... 7Z~
::=:==~-~::=.:::=:=+=:~..~::=::-~~==:=:~:=::+=:::::::~=:=~=:::-~2u~--Z.~-E~Z~--~-~!iEL~-9--~--&:-5~-% ............ 4__ ....................
......................... P................................... +........................... ~ ' : . = ~ - - - = : - - - - = ; ~ - - - - - - = - - - - ' : " - - - = : t . : ' ~ I
. . . . . . . L ........... i ......... . . . . L_______L__ .............................
1 ! "
................ i+................... J ........... i__'_ ::::::::::::::::::::::::::::::::::
........
. . . . . . . . . . . . I.. . . . . . . . . - - i : ...........
: :::: ; : . . . . : : L
:::..--_..:.----__:.-- . . . . . ..._.__::L--._ ..... ..~::..:~.~..:...::~.:::.~:~:]:.-~:.:..:~.::::.~:.~:.~:.-.~-.~:.--..~+-.--+-~- .... 9 .............................. ~ , .............................................................................. ;...... : : , : L + ~
: : : = - = : = . - = . . : - = ~ ~ ~ ~ - - i i i, +.................................
.......................
~. .{. .i.~. . .-. .-. .+. . . . . . . . . . . . . . . . . +. . . . . . . . . . . . . . .'. . . . . . . . . . . . . . . . . . . . . . . += . .
-. . . .. . . . . . . . . .
~
= + - , - ..................................... :+:
= =7=[ - .................................................... ~ ...........
ii
i __L __L___ Ji l I L
....................... _+T................................ ........................
. . . . . . . . . . . . . . . . . . . . . . . . . . ii ...................................... J , _ ._ _. _ C. ~._ _ L . - - - _ . ! _ .... - - - - ~ Z _ Z L.[.Z. . .]. . VMI3151ElO S 0 .......................
1..... ::::::::::::::::::::::::
............................... :.9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _,_. ................. '. . . . . . . . . . . . . . . . . . . _....I _ _ . I ........
................................... +.............................................+...........................................~ ................................................................ ~ - : ,
~:Z:::::::::::::::::::::::::::::::::~::::::::::::::::::::::::::::::::::'.~:..::::::::::::::::::~::::::::::::::::::::::~::::~:::::~::::::~..~Z~:~ ~................................. 4 . . . . . . . . . . . . . . . . ~. ............................ :::::::::::::::::::::::::::::
....................... ~....................................... .+ :-_-===-:=::-==: ..... =.=.-_:t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . !:-~:,_-_: : !! !!!!!!!!!!!!7!!!~!7777777-:!~
........................................................................................................................................................................................................................... + ...................................................... +-". . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ 1301.
100 , ............................ , .................... ,_ _ _ ~ ........ ~ . . . . . . . , ........... ......................... +. . . . . . . . . . . . . . + ................................................

.............. 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ....................... "! . . . . . . . . . . . . . . . . . . "! .............................

CsBr CESIUM BROMIDE ..............t .....................................


i ............................~.................................... i .............................................
. . . . . . . . i ............................... l................................. ~ .......................................
i i
.............................. + ....f .................................. ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . .

10
. . . . . . . . . . . . . . . . . .

. m

co i ~.............................................................................................. ?i ...................................."
Q.
t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

t,... i
i

t~ _ _ - ................. ::::::::::::::::::::::::::::::::::::::::::::::

! / ...........................................................................
I...........................
13_
...............
i.................... .......................
/ -~....................:......................~..................
................ I....... i....................
0
0.. ...................................................... ~ i i !ZZZZ:IZZZZ I.s
>

.................................. ~ ...............................i ...................................~..................................."...................................

~
0 . 1 ~ ZTZZ2: __, ......
222Z:;Z;;II;IIZ21;
; :: ;;12;1111222
+
.... ,=; ; Z2 /_222......I::IZ- 222Z:222Z22;Z=222Z;22~
.................................... II-22"21.-2212ZITs
l ] . ,
I i ] i i : i :

- - ~ - .--~ .................- - - - ..... - . . . . . . . . . . . . . . . . . . . . . . . . . r ............. t ................................


+ ....................................
~ ..................................
i..................................
- - - - - - - ~ - / - - - - - - - - .......... " ....................................I ...................I ..................................
~...................................
z...............................
+.................................

................................
i- i ! i ~ " " i
....... : ............... i....................... ........................................................
,'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,..................................

, ~ ~ ~ l 1 psia : 51.71 mm Hg ' !


.............................
/ ...................................
~....................................................................................................
+..........................
,'..................
,I ,,+..................................
i 'I ii i. i
+ i i i '
i + ! !" I i
0.01 I I i i t i i ~ ~ i I
1 300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400

Temperature, F

90
100,
-Ii3111111i i iiiiiiii~ii iiillli..........
i i i!i !illi,...... J i i
. i ..................................................... i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

- - - ~ ....................................................................................................i .......................................................

1-11111 l ..................................................................................... ..... ~ ..................................................................................... t .................................


a

] iiiii.........
iiiiiiiiiiiiiiiiiii_i......................" i
!
................................................... ,

!
....................

$ ....................................................... ;

i
= m
!
t ................................................................
i
~

c~ !

~ ................................................. .
B~
i !
(1) 1 9

i i
i:
a.

0
c~
>

1 i
!

_1 i
olt .................. i . . . .
'i . . . .

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
I
i
!

!
0.01 I
1200 1400 1600 18OO 2000 2200 2400
Temperature, F

91
1 O0 , , ,t ........................... ~ + +
l I !~iiiii~::iiiiiiiiiii~iiiii iiii! .~

CsF CESIUM FLUORIDE +~ +

- , ....................................................................... i iiii:iiii-:iiiii .......................

i i

10

::: :::::: i:..... } :::::::::::::::::::::::::::::::::::::::::::::::::


1 --~-T T.....................................
............................. T...............................................................................
I / r 'i
!
+m ..................~ .........~......................................
................ /

Iill
~.............
ii i ~ iii :~:i
4 ................... ~.........................
L-_E_--_-_-_-~:iZZ-T--C:
rl -iiiiii .....iiii -ii/i ~iii-iiiiii --/i
A
0
Q.
> i" ............................................... 1 ...............................
/
.......................... "+ .................................... l ......................................................................................................
+ + + + . . . . . . . . . .

1 ,
i i
0.1
............................:.................................!"t.....................................
............................................................................... +....................................... i .........................................
................................................................................................................

::::::::::::::::::::::::::::::::::::
t
............................ T ......................................................................................................
................................................... :::::::::::::::::::::::::::::::::::::::::::::::::::::
........................... I ...........................................

1 psia = 6.895 kPa t ....................................


1psia=51.71mmHg !......................................

i i + :
9 i
0.011 ' I i ' I t i
1300 1400 1500 1600 1700 1800 1 900 2000 21 O0 2200 2300

Temperature, F

92
Temperature, F
176
cl ' a J n i < e J a d w a /
00~ 000~ 00~i' 00017 00~8 0008 O0~IE 000~ 00~; I.
I I I 1 80-::1I.
, , ~'- ......... !
8H uJuJ L/_"L~I = e ! s d I. 31.
ed)l ~6g'9 = e!~Id i i 1
...............................
'r__::::_:: ..... - ........ i
- L ...... -
- /
_ _ ,- ,/
i
<
Ill
1.000"0 "0
0
"--ll
/ J LJ "0
=-,I
(D
/ : ':'-'--:.... '::" . . . . . . . . . . . . . . . . - ~00"0 f./1
/ C/'i
/
="'ll
/
f . . . .
(O
"D
................... t ..~ ~ ~
~ 1.0"0 f.#l
.,mi
Ill
7 ....... ~......... ,- ,,~,,. i: , ~ t ...... : :,- ,. , 7
.......................................... i ..... r ......................r j i ........... r .............................................. I.'o
...... = !
- -- - , .... , , ~ ~ .............. ,,, . . . . . . ....... l . . . . .. . . . ....... i ....
,'," ~ ' ,/-,,, ~ ..... ~ ..... ~ ,,,,,,,,,,, :, ..... : ,,,,,, . . . . -i,i,; ;',:', ', '~. .
- - _,,, . . . . . . . . = . . . . . . .
l , -. . . . . . . . . . . . . . . . . . . . . . . . -OL
"- i ~ " ~ I:l=:lddO0 no
. . . . . . . . . . . . . .
L ,I . . . . . . . . . . . .
-~ . .
...... - ,. O0 L
1 O0
.... !. 1 ,.
I I ,,
1 ..........

CuBr CUPROUS BROMIDE


...... :

10- I ..... !
............................ [ .....................~ i i i ii----ii-]

i
tO
n

J i
cz. t
m,

r~
co

13_ E !

L._

0
cL / ....................N
....................................q

>
to ,[..................................................
i

0.1 | ................................................... |.

iiiiiiiiiiiiii::~
ii
i. i
I
71
_ ! 9 .!

t i
- ! !

i I
1 psia = 6.895 k P a ~
1 psia = 51.71 m m H g l
f
1
1 i
0.01 - i I
1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F

95
1 O0 I
, f

CuCI C U P R O U S CHLORIDE

. . . . . . , .............. ,w._~ . . . . . ,
I I IIII
I IIIII III I1 IIIIIIIII . . . . . . . m
I I1 I I II IIIIIIII. . . . IIIIII IIIIIIIm
~ f
IIIIIIIII IIII " i
II IIII II I III IIIII1.111111_]1 IIII m
:!
llllll Ilill llllllllllll liB ~ l lll
. . . . y

= m

03
1
Q~ J
L _
' l

//
r~
~ . J . .

r~
Q~
L_

13_
t.__

0
Q. 0.1
> /
I

. . . . . . . .
I
i
I

/
i

/
... ........................ . _

u.ul ~ ~ 9 . . . . . . . = . . . . . . . . . . . . . . . . . . . . ,

-! 9
, i iii_ 9

- / . . . . . . . . . . . . . . . , .......

. . . . . . . . . . . I
l
i

/
-! ] I . . . . . . =l

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

/
,=

0.001 I I
800 1000 1200 14OO 1600 1800 2000 2200 2400 2600 2800
Temperature, F

96
1 O0 . . . . . . . . ! ................... i ....
_: . . . . . . . i , ; .............

CuCI2 CUPRIC CHLORIDE


...i .......... I
J
t

10 ~

mm
(D
c~
(D
(D

G.
0
O. ..... L ~ ! /

>

9 I~ i

0.1 . . . . . . . . . . . ~:iii~iiii:iiiiiiiiiii~iiiiiiiiii:iiiiiiii~i~ i i '."

dv ~, [
, LI
i I
i i !
! ! i

r'- 1 psia = 6.895 kPa r


1 psia = 51.71 mm Hg l
/
L. ....................... ~, . . . . . . . . . . . -

: .............. i .................... --:--1----'--'i'----=---'---"--'


.......... "-'--

i i
1 i ,
!, !
0.01 1 l t I I I I
550 600 650 700 750 800 850 900 950 1000
Temperature, F

97
B6
..I 'eJnJ, e J a d L u e l
009~ 00~ 00~ 000;~ 0 0 8 I. 0 0 9 I. 0017 L 00~ L 0 0 0 I.
I ! ! ! I. I
'i
'~o'o
L i
6 H uJuJ LZ" LcJ = g!sd I.
gd)l ~6g'9 = g!sd L
9 i
/
<
/ "0
0
/
J .
"0
Y c-.
/. (D
"0
--i ":
o~
m m
iiiiiiiiiiii~. . . . i i i ./
.......................... iiiiiii / !iiiii . . . .
01.
i
L
3CIICi01 1::13ddO0 InO
.............. 1,
i ................l
i ...... ,.......................
i
i ~ t I I
O0 L
100-

DCN DEUTERIUM CYANIDE

!!
10

. B

(1)
L.,

:3

(D
0..
0
Q.
>

0.1

T T i

ii
!

1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

i
1 I
o.oii I l t
-I O0 -80 -(~0 lO -20 20 40 60 80
Temperature, F

99
1000 I t i

.... :::__ ::: :L::_ :

D2 DEUTERIUM

j/
/

1 O0
/
, m

Q.

(1)
::3

/
Z . ~ , ..

(D
n

0
Q.
>
1 mF,

/
,21
/
/
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

1 I
-4'}0 -425 -420 -415 -410 -405 -400 -395 -390

Temperature, F

i00
1 0 0 0 0 ~

D20 DEUTERIUM OXIDE

1000=

100=_

i
(/) 1
i m

C).
F.

(D

i
(/)
If) 10= ;

0 !"
C).
> [ i

1
' i

I |
..... t" . . . . . . . . . . . . . . . -,--!. . . . . . . . . . . . . . .

0.1

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

i i
0.01
t[ T
i
0 1 O0 200 300 400 500 600 700
Temperature, F

101
| :=~_- | ........................................................................................

] - _ Eu EUROPIUM
10~ ...........
| . . . . . . | . . . . . . . . . . . . . . . . . . . --

i .....
t !

0.1~
....... , ............... ....... ...., ~ - - ~ !-~-7-:.-..---.!-7Z:~---777~!~-E-!--!.:2!!7!!2!7-:.:!!77!777!!7:!!!!~:!-~..~7-!!!~:!!
--I ..... t - ~ ' . ~ / .........................................................................................................................................
1 ........ I / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

03
. m

Q. 0.01 -
(D
t__

03
03 0.001
(D
L__
n _

t__

O
Q. 0.0001 :::'--._:'.'~--"_-2~.
"..-.'._..---
z:,T-::.-::::::'-:.--...~::.-::::::::.~:::

>
...............................................

..............................................

1 E-05-- "E ".~ .--..:::::.':T":" "."..--..'.':


"::.T.-::
.'.::::.T.
"'z " ~.,".:""::,,,--',
:~C ."L":"".::".q:.-."_.':'...--:.."-."
........................................................................
,".,~:~.:":::::.".':
::.::"
"_ .-:'~ .':":"
~ ..............................................................................
...........................................................................
~ .............................................................................
................................................................................................................................................
...........................................................................................................................................
...............................................................................................................................................
.........................................................................................................................................

1E-06- ~.-...:~::::..::~'~:`~:`~.:~..-~.:::::::::::::::::~.-.:.-~.:z::::::~.~T.~-.-~.::::.-:~-..-..~...-.~..:z:::~:..-.:.....---~:~:.~:..-:~::::::::~".~:::~.~:.~..-.:::::::::::

1 psia = 6 . 8 9 5 k P a
1E-07~ 1 psia = 51.71 m m H g . . . . . . . . . . . . . . . . . . . . . . . .

iiiiiiiiiiiiiiiiiiiiiiiiiiii

I I
500 1000 1500 2000 2500 3000
Temperature, F

102
1 O0 .................................
. . . . .
',......................4.......................~...........
I
...............................................................

~- . . . . . . . . . ~. ..................... ~..................... 9. . . . . . . . . . ~ . . . . . . . . . . . . . . . . . . . 4 - ........................~ ............................~ .......................


i ! i
. . . . -i- . . . . ~ . . . . . . . . 4 ............................... 4 . . . . . . . . . . . . . . . . . . . . . . 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

F20 FLUORINE OXIDE


L ................... ] ................... ~. . . . . . . . . . . . . . . . ,w. . . . . . . . . . . . . . . . . . . . . . .
...................... i . . . . .
................... L ....................................
............... F ..........................
I
~ .......................... !-- 'i J,
i .............. -i

i
Ii

,o!
1

i ! . <

- i ==================================
:::::::::::::::
::::::::::::::::::::
- - = . . . . . . - ...... ' ................... ,............................... i ........................ i ........................... i ................................ :

(I)
iiiiii
i-- ii]iiiiiiiii-
ii-_liiiiiiiiiiiii
9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(I)
13_

>

0.1 / _
iii~i~iii:iiiiiii ii i~ii~iiiiii,,~
ilJi~is L!/
s I LII~I Z ......
! /L
.............................................................................. i..............................

t
I
.................. ~ ......................................
9 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg i
............................ I .............................................. .... t .................................

I I
j J I i
i
t , i J
0.01 i i
!

t 1 I I I
-330 -320 -310 -300 -290 -280 -270 -260 -250 -240 -230 -220
Temperature, F

104
~OI
_.4 'eJnleJeduJej.
0 0 ( )cj OOCj~, 000~ 00s 0008 O0s
1i 'i I ~000"0
.............................. edH 969'9 = emd ~ ............................ $ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . | _..i . . . . . . . I-
T''___~_-----.T--LT".' .......................... J....................................... :'_:":. . . . . . . . . . . . . . . . . . ..-r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...................................................... ~............................................................ r ....................................... 7- ......................................
: ~ooo
! , i
..................................................................... ........................................................................i .................. . L
i 1 ............................... 7 ................................. , . . . . . . . . . . .
! i i l
.................................................................... ~ ..................................................................... 4 ......................................................... L ................................................ ~ . . . . . . . . . . . . . . . . . . . . . .
................................................................... ~,........................................................................ ~ .............................................. i ............................... ,. . . . . . . . . . . . . . .
............................................................. ~ .............................................................
1 ..................................... i................................................................ =
................................................................
F ..................................................................... ~ ........................................... i..................................... i. . . . . . . . . . . . . -
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: .....= _ - ~ ~ _ - - f ~ z = m - ~ L - - - - - - ; ~0.0
' ' ' ~ i <
................................................
9 L............................................................ t ................................. !. . . . . ~_. . . . ~ _ _
~
!. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
: ........................................................
i
..........................................
i /
@. . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
ib. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "O
L i i z i O
I.................................. i~.......................................... ~ .................... ,,___/ . . . . - - --------L
L -O
-"ll
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~ 9........................................... . . . . . . . . . . . . .
i ....... ....... ....... ..... .. ..... .. ..... .. ..... .. ..... .. ..... .. ..... .. .... . . . . . . "~ ................................................... J ~ . . . . . . . . . . . . . . .. . . ... . . - - . . . . i:. . . .. . . . . _ _ _=============================================
L
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
, 0
'
:
'
i
'
i
/ !
i
i
l ~
/ c
............ i ................................................................................ i ........................................................................ T .......................................................... t .........................
i i i i 0
i i I
"0
];....................................................................
...................................................................................... -.ii.......................................................................
.................................................................................. il...............................................................................
i"............................................................................
il.........................................................
.............................................................................! ............................................................................~.:....ZL1..Z.-::L-.Z...~1Z::-.ZZZ:Z:Z:::..7Z~ZZZZ:::--2.-2..-21T2-~Z:L-.-..2L~:27I-ZZ.------2..--..2 ...........................__2-
iiiiiiiiiEiiii~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~:::::~!~.:::::::::.--==~=:=::::=::=:F:: = : : : : : = : : ..... ----- ..... : i = - - = - = - ' ~ "
........................................................... ~.. ............ :::::::::::::::::::::::::::::::::::::::::::::::::::::::: ........ ~'. ........................................... 7i; ................................ :....-~..~.-~--~:~'" . - " 7 " - - - ' ~ "
j L
L 1 i I
............................
s _..~.. _
, ...................................................
i
i ,
i --1
t ......................................................
[
F
..................................... :! ......................................................... ;
"!. '~.i --~!, I. . . . . . . .
I " z
...............................................
....................... ii~iiiiiiiiiiiiii~iiiiiii~!iiii~
............................................................... .i il i~~~~~_..................... _ ................
_....
....................... ~ ....................................... 4 ! -" _L
7_..---"" _.--L.T.,. ......................... ~ ....................................................... 4 i .~. ....................................... ] ] I ] I ] 7 1 T ~ T ~ I ~ L - _ ~ Z I ] : : L
i
i ! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!
................................................. ~.....................................................................~.................................... []]]]]]]]]- =
T......................................................... NOldl e_.-I ILZ]]7]TLLZE
, i 11111111111111][[11117111111;11[[i[[11_
i_ 9 [, . . . . . . . . . . ::::::::::::::::::::::::::::::::::::::
..... l '; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T ........ --7"- :::: .................... :::::: :: i--
................. ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .I . . . . . . . . . = = : : ...........F O 0 I.
100_
, E
|
. . . . . . . . . . l". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

FeC505 IRON P E N T A C A R B O N Y L
,i

............................................................... 1 ...............................................

10
J

.
m3
m

co
Q.
(D
K..

co 1
(D
&,.,
. fwiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill
5.--
O
c~ Z
>
/

0.1- i .......................................... ~.~"~.~..~'~~"~'~[~"~.~'~!`~[~[~~~~

i .....................................................................I ..............................................................
i ".......................................................... '!.............................................

1 psia = 6.895 kPa I


1psia=51.71mmHg ,

i
1
0.01 I I I I
0 50 100 150 200 250
Temperature, F

106
100] "
............... ,t................................ ,j' +, '"
========================================

~1+ ___________ I

!~IIIIZIZZIII~III] FeCI2 FERROUS CHLORIDE ...................................


,........................................................................
IIIZIIIIIZZZ1

10 i....................................................i
..........................................

--.-t ..T ~.., t!


. m

rn
13.

(D
i.__

c}
co
co
(D

Ik..,

0
................................t.............................] .........................................

>
i i i i i
==================================================
2 4 il;~T"- - ~ ~ ~ i i i i ~ i ~~~i~~~~i~~~~~~~~~~i~i~~~~~~~~~i[~~~~~~~~~~~~~i~i~~i~~~2~~~
/ ..........
.................................................
4/
i7 i................................
+ !
[i ................................1""'-
[ .........................................................................= = = ~ = "
+"
.........................................
.......................

! 9 i i
, ! !
0.1 i i . ; ,
I I I I
1200 1300 1400 1500 1600 1700 1800 1900

Temperature, F

107
100_
i; ................................. -'{ i....................................................................
{ ........................................... ~..................................
................... } ................................................. {. ............................................................................................

- ..................................t I |

I FeCI3 FERRIC C H L O R I D E l i
................. { t
9 i 1 ................................ i
................................... | i
f ~

1
i

10

IT!'_E~222222C
~22-~C2~2
!I~- -~I2;2~222112;2111~22~-~I~2
tO
oo / .........t.................................................
f ......................................................
Q.
~Z_ .................
............!........................................................
!
! .........................................................
........
9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
(1)
I,..

oO
oO
(D
a_ ......... iiiiiiiiiiiiill / : '
I,--

0
C1.
tO
>

~iiiiiiiiiiiiiiiiiii17------- ............ i ............................................................


!.............................................
~ I I I I I Z I ~ ............ i ............................................... i...........................................

~!~ [....................................................
Tk.. p,,osa osa
o ! ~, 7, mm.g .........................................
. . . . . . t" ....................................... } ...... ............................

I I i

I i i
I I ! !
0.01 I 1 I I I I I
350 400 450 500 550 600 650
Temperature, F

108
60I
-I 'eJn],eJeduJ81
00~ L 0 0 0 I. 008 009 00~ 00~
I I I I
I i 80-:1 I.
! I i
........... ~............ . . . . . . .~
i
i i
6 H Lu~ LL' I.cj = e!sd L ...............................................
I
LO-3 I.
edM 968'9 = e!sd L
..... , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
t
.................................................................... !,
t ................................................................... ?'
i I
<
1.000"0 "0
i .......................................................
i , .................................. J, /_[ , 0
"D
(1)
LO0"O o~
[i w i i _,Z__ ,i o~
.................................................................. ~.............................................. ~ ....................................... -4. . . . . . . . . . . . . . . . . . . . .
9
..,................................................................. J. .......... I_L_.....,Z______.
]. ............................................................................................ [
....................................................... .'.,.9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ i--.-. ~.Z. ' "~
I'
".,........................................................... -.". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................... -!.: . . . . 7 . . . . . . . . . . . . . . . . . . . i.
i I 1.0"0 "C}
! . , - , . ,,
f,/)
i i
.................................:'~---:-:---:-:-:::: .--:'::':.".'::'::---I
i i ...... ~ i......................................... i:i::i::iii:iiiiii::~_
............................................... ~.................................................~ ...... ,} F--...------------------~---'~.
. . . . . . . . . . . . . . . . . . . . . . . . .
::::::::::::::::::::::::::::::::::::::::::::::::::::. . . . . . . .
............................... , ........................................ .i . . . . . . . . . . . . 7.. .................... !
.................................... ~ .......................................... ..}. . . . .
....................................... ~..~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,.-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!....................... -':L_ ...............~ ~
............................
~ ==========
I======================== i....................................
,I F---I .........................~ = ~ - - - i~;~
~ .......... F o
.......................... r ....................................... ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . , .......... ~ ~
................................................ .i.9.. . ....... .. . ....... .. . ....... .. .. . ....... .. . ....... .. . . ....... .. . ....... .. . ..... . . . . . . . . . ~ .9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9 . . . . . . . . . . . . . . . . . . . . . . . . . 4 ................................................................ .~.~.~ ........ ~ ~ ~
I.
100. -:~'---'m ........... -7~--_":-'_:::: . . . . . . . . . . . . . . . . . . . . . . . '_~--~."2 ............ , .......... : .......... ::::::::~ ........................................ ::I ..................................................... "-

Ga GALLIUM
0 ~ ' ...... - ..... -- ----:--- ...... - - ........................ -'-" . . . . . . - - --
f | >"
: : ::: ] .... _ ======================== :::::::::::::::::::::::::::::::::::

:::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::

2Z__............. 4 : : : J . . ~ : - " - ......................... : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :

JJ _ _

.m / /
In
13. 0.01 ,2 ~ .....
..... / ..._:J:::
] ............................... ::::: ! _
(D . . . . . . . . . . . . . . . . . .

:D

(D o.ool

i__

O
Q- 0.0001
tO
> L . . . . . ! i
:L / J
[i i /ii ]
] / I
. . . . . .

1 E-05 _ _1 J
L
r ..........................................................................

::: : : / : : ::: ]I]IZZI '~ ] Z:ZI::: i [


~ . / : i;i:i::i;;; iiiii;iii ii;i! lr !

................... r[ ..............................................:::TZZZZ-.::::IZ. :TT:ZZ::::ZZT::


......... :7/ ............... 1
, E_o6 4
t- ........................................... i, .................................................................................................
t-...................................... : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : .................................................

L / _ .
] t t ................................

............................ L - _ : - Z Z : - : Z ::::ZC::L_--_-:
1 psia = 6.895 kPa
1E - 07 .-!I !! : - =~=- ............... ~................ 1 psia = 51.71 mm Hg "i.-]EilEiiEE~-'E::.ii:"
. . . . . . . . . . . . . . . . . . . . . . . . . T ....................................
!" ............................. ................................

......................... i ..... :--:::::--:::::::: ...........J............................... f ..............::::::::::::::::::::::::


T! .................................. !! .......................................T! ........................................
1 E-08 1 1 i i I I
1000 1500 2000 2500 3000 3500 4000 4500
Temperature, F

ii0
III
_.4 'ejn~.eJedwel
008 OOL 009 00s 0012 008 00~ O0 L
i l l I ~'0
' [ t!
: : .
................................. ~ ............................. ..L ............................. i . -
! i ' I
6 HuJw L L ' L s L J [ j
- 9 ! l I /
.............. ed)l s = e,sd I. .................... ! 'i { ,'~-~-------- ...........................................F
............................................................................ i .............................. L......................... [ L/ .............................................
L
...................... [.................................... i ................... L ................. L.................... i -/-~::- ............................................
F
................. : .... ,i ............. :._:._: ................~. ................... -;_i_ ............. t ............ ~ . / _ L _ . ~ L
............... i ......................... ; .......... , ...... ~ ..... -----.-.L- ............ l ......... Z ..... ~..................................................L
:-_-:-::_-::::-~:::: .........:::::::::::::::::::::::::::::::::::: .... --:~ ............... _ - - / _ ~ ! ~ L ,
.............................. t .............................................i ...............................................i .................................. t ..................... i ......... / .... ~ .............................................r'-
[ "
i
.=.
[! [I l[ / J;
i i i i ~ / i I
1 l 1 i L/ !
i
................................ [.....................................!_ ......................................~...................... J:.......... 2 _ Z - _ - - - 2 - _ [ ~ "0
0
,,%
: ....::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: -0
................ 4- ....................... .- .............. ~. . . . . . . . . . . . . . . . . . . . . . . . . . ~ - - - ~ . . . . . . . . - 4 ..........................................................
I ............................................................
~
........................... .,................................... ~...................... --.4 .................. 4- ..,z ................... I- --4 ..........................................................- _.. 0
............................. i ..................................... i .................................. -f ...................... 4----~- ..... ~ ........ I---------I-O ~- or)
! [ ! i / 1 t n (/)
(-,,
0
Wl
~ i , / I ! 1 / "0
....................................................
i.......................................................
i....................................................
l...........~ ~ ......... ~. . . . . . . . . . . ___L m .
......................................................
i.........................................................
i.....................................
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
:::::~:Z~:::~::::::::::::::~:::::::::::::::::::::::::::::::::::::::::::::::::::::::~[:::::::::~::::::::::::~:ZZ-.~:~...~
................................. ~ ............................... -__---'~I-
................................... ~ ......... =============================== ~ , . , .
....~ ................. 7,, ............................. [,.,,., u.
...................................... i ....................................
.................... .,........................... ~.................................................................. ::_::::Z i i iiiiiiiiiiiiiiiiiiiiiiiiii:ii
E
t I F
i ........................................ i -~-~ ~OlUO7HOiU• ~ n m v o ~loeo ::::::::::::::::::::::::::::::::::::
|
..................................... -4 . . . . . . . . i i ===========================================
*"..........................
9 ~................................................................................................................................... ' .......................... ~000 L
Eli
-19 ' e J n ] . e J e d w a l
O08g O09g O01~;g O0;g;g O00;g 008 ~ 009 I. 0017 OOg I. 000 I. OO8
I I I I 80-B~
, ,i ! L............................i ......... .......... ........
ZZi--:ZZZZZ:/_-
21211 ~::-21 ....TZIliZZL Z
! _ i ;Z____~ii-TZZZ:ZZIZ___LZZL •
i ........................ [.::::::::x: .......:::
w.....................
6 H ww ~L" I,s = e ! s d I. .................... -: ++!ii+ fILO-B I"
.... /-=Z;;I :i :i
[:17.11 :i. .:. -:7........ i :i:ii[i;i ;ii ; iiii.__-71
i . . . . . . . . . . . . . . :':: '!!- : f: i:]/ :~ : Z : : ! ;!:!!!!!!?:::::!!!!!!!Z:] 9 :::
::::~---'-~".----'~:::=:=.".~ .-........................ ",~=:.~:'-'=~--~"-"=::==: =."-z.".=:=~".:-'.=:~."~ ....................... 1 ...............................~90-:1 I.
........................... ......................... I
/_ . . . . . . .
............................
............................
i
SO-:I I.
! /
.............................~ ......... .... I 9 ........
........................... i ..................... ...............i::::7-/:-i : :ii:kk :i:::i] <
:~ : . . . . . _ . , , _ . ~ ~ ~
1.000"0 "0
............................. .................... t ........................ ............
:C......................... 1- .......... 4 ....... ~ ....... 0
. . . . . . . . . .
-0
................... i
0
!
Z ........................................ ! ...........................~oo'o
C
0
1 ........ M
i- - --+-- .:.".".".-".E E~ ........... "o
! ]
. . . . . . . . . . . . .
L _ . .1 i
i~' . . . . . ]][ ~]]~]]]]]]]]]-~]]]_'__~]]]]]]]]]]]]]~]]]]]]]]]]]]]]]]]]]]]~]]]] ........
ii i ..................... if ff 2222f2
==================================================== 2fff22-'
:::__,-L]j/2ffffffff222ffffff22J22/i222ff/22222222/J22f2
iI ~nlNI-IOaVO PO tlI:::IZIIIIIIIIIII-
O0
: ' ~ e I-----~ I: ~ ...............................::::::::::::::::::::::::::::::::::
- 1......................... i
~ o _~ ,~ . . . . . . . . . t J. . . . . . . .! . . . . '~. . . . . . . . . . . . . . . . . . . .
E --------t i ~............................
?:
d
i * i9 }
' ~ ~ - / - ........ i9 i i
~9 ~ . , 2
i i
0.1 ! i

i: i i
.......................................................... / ...... i ........................................ 9

! i / i 1
. m

0.01= _
- . . . . . .
!
. ......................
.....................................
--: .......................
..,
:
: .

(D i ! '
t............................ .
....................................
- J1 ~i ~
......... i I I
|' i: [
O. O01 _ '=. . . . . . . . . . . . . . . . . . *-" . . . . . . . . . . / ~ - - : : e : l
(D - l . . . . . . . , s . . . . . . . . . "i
13. _- : i.--- 2 ............ ~
i,___
_ , i-Z .................. :i
0
Q. 0,0001 - ............. .~..........................................
::::::::::::::::::::::::::::::
> 9 - ................... ~ ............................ ";.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -i.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 .................................................... ~ ................................................... ,'-"

{ ................ - - t - - - J ....................... ~........................................~.......................................4.....................................................


~................................................
.... i ! i ,. 9
..... ~ ............................... ~ ............................... ~ ........................................
4 ...................................................
.~...............................................
~" . . . . . . . . . . 7 . . . . . . . . . ' .......................... + .......................... ' ....................................... " ...................................................." ...............................................
1 E-05 i / . , i i i

{_/
~--/
.......................
",
i ............................
i
..,i...................................
..i
i

1 E-06
i :..

i i i

1 E-07 i i i i 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
..... .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...........
........................ , ..................................... ,~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .........
, . . .~
.... -4. ........................... ,. ................................... -4. ..................................... ; .........
! ! i ! ............ i .................................................. t ...........

i i i i
t ............................... -t .................................. i- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ............

i i
i i i !
1 E-08 I i i i i
1500
I I I
2000 2500 3000 3500 4000 4500 5000 5500

T e m p e r a t u r e , F

113
#1:1:
3 'aJn],eJadLual
0017 o~ oo~ o~ oo~ o~ O0 L
I ! ! I LO"0
i
i
'
!
' i
6H tutu L L ' I.s = e!sd L
ed~l s = e!sd L .......
........................................................
I
.................................................................................................................................................................................................
....................................................................... * .....................................................................
4......................................................
4................................. 4
9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 .......................................................... 4 .................................. ! ~--
...............................................................................................................................................................................................
~........................................... j . ............................................... .
! ..................................................................
............................................................................................................................................................................................................... ! ........................................ i ~ L'O
i
. . . . . . . .
13
.............................................. ......... ..... !. . . . . . . . . . . . . . . . . . . . ...... z ~ ii ..... ........
_:i ::~::~:::iii:~::iiiiii: II LIIL 0
"-I
"13
(1)
r-
"-1
[
d)
"tJ
08
m l
. . . . . . . . . . . 1
~--Ei-?i?? , oL
.................................. i ............................................ i
!
......................................... 4
i ..................................................! 3(]I~OI=IQ ~AINV~I=I30 ~JQeO
............................................. I~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ i
I i
9001.
100 , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ~......................................................................................................................
. . . . . . i" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

~ I .................. iiiiiii iii ! ......................... t ...............................................................................................


]iiiiiiiiii.....
iiiJ GeCI4 GERMANIUM CHLORIDE
-Ii:i::i:i i::ii:: I . . . . . . . . . . . . . . . . ii-ii~ii~ii[
..................................................................................................................

............................................................... ! .......~ ...........


10"t ~

-' 9 i
' i

i i

.m i i
co I
l
Q. 9 !
[ T
! i
K..

(n ,
I
i
09 T"

a_
K..

O
O.
>

0.1

................................................................................................................................ . .............................................................................

L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 ...............................................................................

.................................................................... ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

!..................................................... , ................................................................................................... 1 p s i a = 6.895 kPa


i i 1 psia = 51.71 mm Hg
| .................................................. ~..................................................................~............................
!. i !
i I I i
I

1 ;
o.oll I !
-50 0 50 100 15O 200

Temperature, F

115
100,
]!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!i!!/i
......................................
! ! !
i 9...........................................

31111111111111111111111111111111] 4
3 iii~iiiiiiiiI
...... GeCl3 TRICHLORO GERMANE .....................................................................
...............................................................
i ..............................................
i ...................................................................
9

. . . . . . . I
. . . ............................................................

.................i
I

10 ~ ] .... : ........ ~iiii~iiiiiiiiii~:: i~ i :~ ....................................................................


J I ................. i,i,ii,,i iiiiiiiiiiiiiiii, ........ t

_ [iiiiiiiiiiiiiiiiiiiiii ii ......... iiiiiiiiiiiiiiiiii-ii[................................................

. u

if)
Q.

L _

if)
if) j
J i i iii iiiiiiiiii
............. J ..............
iiii iiiiii I
~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii .....i]
L _
]iiiiiiii iiiiiii iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiI
9 !
] i ...............
]
L__

> ...................

0.1

]iiiiiiiiiiiilZ
1 psia = 6.895 kPa

]7 1 psia = 51.71 mm Hg

tiii-iiiiiiii-iiiiiiiii!iiiiiiiiiiiiiiiiiiiiiiiiill
. ...................................

a i i

!
'
i I
i J
0.01 I I I
-50 0 5O 100 150 200
Temperature, F

116
1000 i ......~........~:~:~ .......... ' ........................... i ..........................................
i" . . . . . . . . . . . . . . . 4}
i- . . . . . . dl

: !

;i I GeH4 GERMANE ;~ ..................................................


] 711171;;;;;i;;;;;i;i i I _i

!...... :-_~/_ ...... .;


- - - - - - - i.......... r |. . . . . . . . . . . . . . . . i'

! ............ i'-" ......................

. m i t
(/) t = i

{El. i i .........................
I ~ ......................... '
~,. . . .

(D ! i i
i..,
i i

i !
i 1 ~ ........................ ~. ......................... i. ......
(D
s,._ ; .................... _./. ................................
, ...........................
,. . . . . . . . . . . . . . . . . . . . . . . . . .
i . . . . . . . . . . . . . . . . .4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .................................. i ......

I". . . . . . . . . . . . . . . . . . . . . . . . . . . . . "t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "t ........................................... .~...................................... * ......

L_ ............................. ~.......................... ,i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4" .............................................. * ........

0 .......................
!
~ ...................
i
"!.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .................................... -'~'

ID. "
:
.
=
!

I". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "-". . . . . . . . . . . . . . . . . . . . . . . . . . . . "..!-.............................................. i. ............................................... ~ .........


> i
i
i
i
i

i
|

0.1
| |
&. . . . . . . . i ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ..................... ~- . . . .

L. . . . . . . . i i ........................................

i
~. ........................... ~ ...................... . ......

i
1

.,... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .............................
i '
~................................................ .=.................................................=........
o
! .} . .
............................ "I" ......................................... +... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~......

.=. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .L. . . . . . . . . . . . . . . . . . . . . . . . . J........................................ @ .......................................... 4 ......

i i i

.~]===============
il I! !. I-
0.01 ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ........................ q ................................................. ~ ........................................... i .......
r ...........................
.'."
~ ......................
~;
4 ............................................... ~ ....................................... i .......
1

Tti i-,,.............. 1 psia = 6.895 kPa


#
i ] ............ 1 psia = 51.71 mm Hg
i..................... i .................
i ] ............................. i ...........................
i i
i i i I
t
I
z i I
oool I
! t , J i

I I I I I
-300 -25O -200 -150 -100 -50 0 50 100
Temperature, F

117
81:'[
-I ' e J n } ~ J e d w e l
O0 L Og 0 0s O0 I.- Os L-
I ! !
!LO'O
!
...... n, .. _ ....
6 H uJku t z ' t g = e!sd t /" ..
eclM ~ 6 8 ' 9 = e!sd L
/
/
! ...... 1.....7 ....... ' ...........
=. . . . . . . . . . . . /
/
. . . . . . . . . . j .
iiiiii/; . . . . . . .
E . . . . . . . . . . . . / 2 . . . . . . . . . . . L
/
L'O
- //
./
. . . . .
<
Zilliii2 .... i--iii~ - i ..... ~ 0
/ L "13
/
:L
or)
OL
I
E
g ................ f ........................................... ~: 1
!
9H;~~ 9
~~i.!....................................................
i_=~i:INV~EI:IE'JIG
ii e.............
ZI::L.-C..LC::..-Z:.C-_-IZ.-.....-Z:L-:t;L_
..........................................................
L_
L......................................4
O0
100,
i
1
I
]:::::::: :::::::L::::::::::::Ge3H8 TRIGERMANE !

I!! ti
1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..... " . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i
I'
!
i t
!
i

:::::::::::::::::::::::::::::::::::::: ...............
' i
:::::::::::::::::::::::::::::::::
ii, ............................
................................. ii
,...............
/ ~ .................................
i.................
, i
,,m
,
i
! I

i
i !
i i
I
i i
J A
.......................................

i " i
i !
0 i,i .................................. i
Q.
T7 ........ i
> '. . . . . -t i
' ii
i i
i i
! !
! i
i ii
0,1 :
! i

i '4 .................................... t ........................


i! 84 ..i ................................. q,............................
'i ..... I
i

I........................................ i .....................................................

i ,.............................................
it
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i- ................................. i ............................................... 4t
J ' I
i Ii
i
1 J
0.01 t
I
!
I
!
I
i
I
-50 5O 100 15O 2OO 250

Temperature, F

119
10000

HBr HYDROGEN BROMIDE L

1000

u)
. m

CL

(1)
&-,

u)
u)
!

1 O0
(D
&.,,
. / i iiiiiiiiiiiiii!
a.. ISIII i iiii!i
I&..
0 / t
CL
>
/
.

0 - ...... i
i .............................................................................
................................................ |it ........................................................ "~........................................................
Z , Z, Z Z ......[.
"" ........................... i ..................................................................
_ ii i ..../ .....
. . . . . . . . . . . . . . . _ .
! t

1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m Hg
r
r
E
r

11 i I
-150 -1 O0 -50 50 1 O0 150 200
Temperature, F

120
1000 i i
,m..~ i
! !
.... t
HCN HYDROGEN CYANIDE ,--wt
i

i i/
i

i/
i

! |

i !

Q.
g,,
(D ! i
! i
c3 i '
,
I
i
(1)
L...,

s
0
13.
>

1 psia = 6.895 kPa


......................................! ..........................................................................................................................................................................1 p s i a = 51.71 mm Hg ...........................................

!
|

,
i! i
i i
!
! i i
I I I
50 1 oo 150 2O0 250 300 35O 400
Temperature, F

121
10000: 1 ....... 1 _1
! ....... ........ ]' !
1
fill ........
HCI HYDROGEN CHLORIDE 1

i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1000
, ~ ::...........................
:::::::::::::::::::::::

.,in.

tn
ID.
(D
&..

:::3
100 ~IFIIIiiiiiiiiiiiiiiiiiiIIIIIIIIFIIIIIIIIII~IFIiii~I~IIIIIT_FIIF_:_III21~F2~_I~I~--~F~I~IT,--_ ~-- .... ~ ....................... ! ......................................
(DL._

rt , /
K., 1
O ri' /
ID.
> i/

,o i
!7,
-~"~i~iii .........ii1177111111111
.......i~F/7_._._q_ z

....................... 1 psia = 6.895 kPa


I!!!!!!!!!!!!!!!
1 p s i a = 5 1 .7 1 m m H g
z ..........................................

P ' i
:! i! I.
11
i
I I I I
-200 -150 -1 oo -50 0 50 100 150
Temperature, F

122
1000 *, ~ ...................
'T........................................................
5

i! ii /

100~ .................................. ~
[
}. ................................................ T

........................
. . . . ~ i. .......................
i .....................

= i
= i

............... i i i

, i
ffl . I i

(1)

ffl

]iiiii;;;i;i;..........
;i;;;;;;iIiiiiiiiiiiii;i;;
ffl

7= ..........................................
! !
I|
0 !
Q. t ........................................... ~ ......................................................................................................................
, .......................................................................
.b....................................................~ ......................................................
? ................................................................
? .............................................................

> T .......................................
............................................... "%,
........................................... T, ................................................................
................................................................ ", .............................................................
.......................................................................
......................................................................

I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............................................................ , ...................................................................... ~ .............................................................

i i '"
r .................................................................................... f .............................................................. ~,.......................................................
' i i

_/_
/ ......................................... / I i ........................................................... 1..........................................................
! .... i i i
' i l
I , {
i. . . . t ...................................... ! ....................................... t .............................................................. i .........................................................
I I / I I I I
.~ l i i i
o.1 ..................................................
~~_~_ i ................................. i .................................... i .................... 1
............................ ~........................ !_.!..............!!!!!E.t! .... E!!:..-...2...........?.................!!!!...!....i....!!]!!!!!!!!!.!E.!E!!!!!!! .........!!EE!!..!.!?!.E?!!.!E!E..!.!..!..i!!E? ......... !.!.

~___,L;;~:._.::.;;_.._ ~ ...................................
~.....................................
,.....i ...............................

1_._.._.. _ .... _.'1----~ -T- . . . . . . . . . . ,.i........................................ ~........................................................ -,,i"| 1 psia : 6.895 kPa ...................................
7 ......................................... ~ .......... ~ ............................ ~ ......................................... }""t 1 psia = 51.71 mm Hg ................................
i 9
/ 1 ,........................................ T,........................................................,1
,i
I ..- .........................................
i i
I ! i t
i i
i
1
o.ol/ ,' ,
l

-200 -1 O0 0 1 O0 200 300 400


Temperature, F

123
-4 'ajn3,eJadwal
0s 008 Os 00~ 0s L O0 L 0s 0 0s O0 I.-
!
I I I I I .,I L
! : j i "
! l [
I
i 6 H w m LZ'Ls L
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . edit s = e!sd L ..................................................... 4
. . . . . . . . . . . . . . . . . . . . . ! 1................................ J
C;C;S;S;IL. ....................
.........................................
SC;;.C.LL- i
....................................................................
q.......................................
.............................................................
,................................... L
.................................
i........................ ,.................................
, I
,J
........................
r .~: ...........
"13
0
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . - ............... -: ..... . .... -, .... ...= "13
:iii:~ii-ii?ii~iiii;-i~i,,--/-.;ii~2~--:
............................. = = .......................................
t-"
i : I/
..........................................! ............................................................................... i ~.......... / 4
13
.....................................
[....................................
"t........................................
~..................
~ ' ~ " -
......................................
i.........................
-4 ...................................
~...........
~ -i
. .....................................i ................. t............................ ~ / i _
000 L
b
. . . . . . . . . . . . . . . . __= . . . . k::~ = . . . . . . . . . . . ;~ _
9 i
t n
........................... ! .............................. i L 301001 N3~C
...........................:.........................................
L .....................................
~ ...................
)WGAHI H ~
~- ...............~.... 0 0 0 0 L
tt:
I OOj ........... ,
:::::::::::::::::::::::
:::: :~:~ ::::,----~,~................
:::::-::::~:
~-~:::i:~---~-
i~ i ~::::ii
.... i:,:"': ....i:,::i~iiiiiiiiiiiiii
- iiiiiii,
. . . . . l!
] iiiiiii......i__I i i
]iiiiiiiiiiiiiiiiiiiii, I HN03 NITRIC ACID
i !
i
74
...... i
i

10 . . . . . . .

,I ! - - - - - .......................................

t I

! ,

' i i
if)
p__ . . . . . . . . . . . L..........
........./,,z Z:..7}
,
, ,
I /_ ...................f
L_

I
if) I I
!

!
i ! !

!
! t .............................................
!
i

0 ! !
t ! !
Q. 0.1
>
i i
! !

!
;
i
i
i! i
! !
0.01 .... - 94 .
i
. . . . . . . . . . . . I
I.! !i
! r . ............................................................. j ..............................................

I[
i 84 ~ ....

-- .....................
' ................................ !- 1 psia = 6,895 kPa
!

t
!
! i i
I i i
0.001 i i I I
-50 0 50 1 O0 15O 2OO 250
Temperature, F

125
1000
u J

1
L. . . . . . . . .
H2 HYDROGEN ! t

i
i

J
/
1 O0 /
........... -
.m /
C~.
cg 7
/
/ .......
u~
(D
13_
/
t,,...
0
Q.

>
10
/
r,
/
/ i

/
/
.......................................................................................... I ...............................................
9 ]

/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

/
_

-435 -430 -425 -420 -415 -410 -405 -400 -395


Temperature, F

126
] iii IIYII .......ii t
iii:::: ........I H20 WATER
|

]iiiiiiiiiiiiiiiiiiiiiiiii
l i .....................................i
] i i .....i i i ' ................

!
t ,
i
/

co
. i

ID. I i

(D
I,---
i i
i i
(D I
!
!
I
~n 10 ! i

ID
K I

13_ ......t ......................................


--4..--
,
...........................
t ............................................. i .......................
i, ................................
!
~.. ........................

,
-..&. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...........................
i
~........................

O ~!, ~ ............... }.i


4. . . . . . . . . . . . . . .
i
..... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . $ .....................................
i
4 .....................

ID. i
i
!_./_. ................. ! 'i
> '/ ! ..... 4.
9 ............................

i
.}............................... 4 .................

i
i
}
i
.i ..........

i " i
1 r ..............

.l 1!

0.1 4
i .
i ....................

.............. ~,----L-.2_-3..2-2:--~:13--233
!
1 psia = 6.895 kPa ...........................
Jiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill
................[
i". . . . . . . . . . . . . . . . . . . . . . . ~ .............................. . ..................
i

t , 1 psia = 51.71 mm Hg
i 9 ~i. . . . . . . . . . .
l i }
I ...................... ~ ..................................... ~................................. 4 ..................................
i I
i
I
i i
i
i
i

i! i i i i
0.01 i
i ~. i
I I
9

0 100 200 3oo 400 500 600 700 800

Temperature, F

127
10000
. . . . ; ! {i
; I t i .....................................
H202 HYDROGEN PEROXIDE

J ,
1000
]

100
~Jc_.
.............. !................. i ii:i: 1 !

!- :~ .... " :{'.........................::::::::::::::::::::::::::::::::::::::::::::::::::I


i
---[i L J j
. u
t~ / !
i
Q.
/
10 9 , . . . . . . . . . . . . . . . . .
ii : : /

. . . . . . . . . . ...........
!

/ i i
I

(D . . . . . . . . . . . . . . . . ! ~,..............................

13_ r
O IW
....... , ': ...........................
t
t
!
::::::::::::::::::::::::::
............................
c~
/
II i
> /
...................... ~..............................

/ ........ i.

0.1~ :
/
j-r
!
/
i 't
t i'
]
! t l
oo,7
:~ :...............
,__, ,, .',
,.....] 1 psia = 6.895 kPa
..[...................... :,~::::~ I:
-- ___Z[-I i- 9 [~ii[[[[[
_il i ZI .r.
, , , 1 psia = 51.71 m m Hg i
:::::::::: ..... zi : ................... :: ::::::::::::::::::::::::::::::::::::: .........................................
I i j
i i
i

[ T T
Ji i t
0.001 I I I I
0 1 O0 200 300 400 500 600 700 800 900
Temperature, F

128
10000., .............. , , , , :
q- 71;;777771;;;;;;;............. - - 1 ................. i ................... l .................................................... i .................................... i ....................
3 ......7 77771-77771T17771111 ' + ............. ~} "
.
i
j
[ t
t
..............i ............................ ,................................. ! i
3---7...... 777 _1 H 2 S HYDROGEN SULFIDE
---i ii.................................... "J...................................... 'i ...................................
-I77117111171111111111111t
............................................................................................ ..... 4 "- !
i i,...........................................[,.......................................i,
+............... " ............................................. I. ............................................. 4 ...........................................
i t i i

i
,1 !
i............................... L" , i9
i i i i
i i
i ! i
i i 1
I
i ................... J~:='L::'I.:'2E.'_T.;2::'..E2".:IilE'L:-2-.'..-'~EL...:EEIi:::E=:E:ZL~::I !
' " i!
-111111111117;1111111111111111.............
111111111i
I
I
I
'i 7 ~

i !
I=l. ! :

1
=3
cD i
~0 l o o 5 ...................................
j
!

13_ l

0
I=l.

>
i I
, !
i

I
i I
| _ i i !
10;{ .... i
............................ ~.................................................
I"................................................
i ...................................
: ................................... ..,-................................. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . .

+,. . . . . . . . . . . . . . . . 4. ........................................... ~........................................... i ....................................


I i , .......................................i ......................................,.................................
; i i ! !
!..........
= T. . . . . . . . . . . . . . . . . .
i t ......................... i ................................... ",.........................................",...................................
. :" : I
........ ..i. . . . . . . . . . . . L ................... -, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~...................................
i t i i i I
i i i ! i ! ...............................
r i ............................. I.....................
i i
.......................... i ................ 1 psia = 6.895 kPa

i it ' i 1 psia = 51.71 mm Hg


i i .'.
I
i i
i
iI '
i
' i! ,' ii i
' i
I ! , ! i
1 I I I I I
-150 -1 O 0 -50 50 1 O0 150 200 250

Temperature, F

129
100_~ ~ i

H2S04 SULFURIC ACID

10=

/ [
. . . . .

. . . . . . . . . .

/ ! ..........................

,9/ ............. I .....


ii iii/- i IIT;;III;~IIIIIII::II iiiiiii/iii:i:~i
r

0.1
/
~!!!! i~! / ~ ~! !!i ! !~!~:~!~~!!-!!~! i~~~ ......................!.......
. i

09
/ ................................. i .....................................................................................

0.01 / ............................. ~........ ! .................................. !:__


9
9 . . . . . I1 . . . . 1

07 9 ...... ] . . . . . . . . . . . . . . . . . . . . . T--I-i-ii .....................................


07 /

0.001 I
7:/
0

> /

0.0001
/
L ~i ....... i~:::/: ~i ~ii::i:ii:i~i~Si~ ~iiiii:i~ .........

/!
t

1 E-05 ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

! i
[ ,,,
!

i
1 psia = 6.895 kPa
1 E-06
, ,, ,
~- . . . . . . . . . . . . . . . . . . . . . . 1 psia = 51.71 mm Hg
l
/

1 E-07-
! !
I I I
0 1 O0 200 300 400 500 600 700
Temperature, F

130
100~ , ,
a i; ............. i :;;_ :C " - 3 - ~ ~- i Z:Z;~ZZ-ZZ::."_Z--_ZZZZTZZ.-----/_
..... ' '~, .......
4.........................................
] ...........................J H2S2 HYDROGEN DISULFIDE li .......
[.....................................................
] .................
I J"t
I ..........
il...........................................................
9 ....................................................................................................................................................................
,..~...........................................................................
.~.................................................................................

] ,r..........................................................
i i
................................................................

1 !.............................................................!.....................................................
10~ i i
I
i i

. u

--J. ~
(D
L_

i ........................................ i
0
i

> i .......... i
i

,/ i
: i
0.1
!i
-..i ....................................... :..................................................... ,.~..........................................
.........................................................................
...................................................
i
;t..........................................................
.~.................................................
i

i '
........................................................................ i ..................................................... 1 psia = 6.895 kPa
I i 1 psia = 51.71 mm Hg

i {i ............................ ' .......


t !
i ! !
1 i
0.01 I I
-50 0 50 1 O0 150
Temperature, F

131
100: I i I i
, ~ .,

................ F.ZZ..-.ZZ::::::::::::::::::::::::::::::::::Z:Z-Z:::ZZZl~:::~Z~::~ZZ...~..-TZZ
H2Se HYDROGEN SELENIDE

, I

~ f
10 [ i ~
................. : ........ ! ...........................................
~ .....................................................

. I

(D

.,_

13_ I

i ........... i............. / .........


[
0
c'J
>

0.1 --~ /
J
- j . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . :::::::::::::::::::::::: I ..........................................

/ [ i

L / / i ..........................................................
i.................................................
i ...............................................

1 psia = 6 . 8 9 5 k P a

_.7
.u . . . . . .

1 psia - 51.71 m m H g

0.01- I I
I I
-40
-180 -160 -140 - 120 - 100 -80 -60
Temperature, F

132
Vapor Pressure, psia
0 ..,.i,
0 0
0
0 0

i i

" i
0 -l"
,iiii
--I
iJJ! ltl
,ili
I
0 i i 0
0

0 m
0 .... i .... ' ..... ','......'ii ........i-, z
i i i i i

ii ! m
i ! | ! r-
f-.
i i ; i
. . . . . . . . . . . .
.~..-i ..... i...-~...4-, c
--,I &~ ! i " i 9 !
t'D o i ~ l iii
i " ! : , ! ! i
! i !t !'i
i i ! i i o
i! iiii m
j''' ii II i i"
('D i 1 : . I
........ . ........... .i .......... i. ....... i ..... i......i....i.-.i,
. . . .

e-,@ i

E
i iii ii ,iI i
i i i !i i
tl) I i i
i 1 i!ili "!i I
................... -i- ......... ~:.......... ~..........~,.......i ......i-.-.++..i i..........i........i--4.-+...~......................
-rl o I i . . .
I
I i
i
!
, i i I ., i i.,I !
i i i i i i ! i
i ! ... ._k
i
!i i! ii!~ii i i
ii
! i .
--" -" ] ..................... ! ................ .i--.i......i-d...l -..i...-i.....i....L.I........................l ..........
o .......................
[ l........
i i .......i i ~"l .. . . :
: : .. : :
: : .. : : ~..~
9 i iii
l : - : 9
! ~i iil
i!i!
~ "" i ii i ~'' " ' i "
' ,i 'Xii
o-- --,oi i JJi ; i i i j j!j z i t ; w,ii i i
3~
,~ ~
iiii
| 1 | :"
i~ : l
J| |i iilii . : i
i" i
!. il J.:. ~i
" " i\"
i| 1i
Ill i .~ " : i l i i .-" i "i i i : 9 i i i~i i ,
i !'..i ~ i i i I : i.'. i ! I i i !i,%, i
..l.. i iii " ": ~ ." i " I." i i i ! i ii.-' i E

r ~ . . . . . . . . ~ ...........~.............. t ..... i....4-i....~ ........................... ~ .................... .~. . . . i.-.4..-~.....f.-.!...i ................................ i ................................ i ..... 4.........i . . . . . . H 4 , . - i . . - - - ~ . . . . . . . . . . . ~ - - ~
0 i 1 I i i I ! " I i i "" i .~ i I i i i i i !

I I
i i. i, i9 ~i i
,
~
I
i, i~ ~
"
iI i' "iii!i
" ''I
'
i : t i : : i i i : i : : ~ ! i i .
i ; i i i ., I i i ,. i i ! i i i i i

0
0.001
! t !
H3N03S S U L F A M I C ACID

. ,..,,,,.
u)
c~
(D
L_

u)
u')
(1)
J
L_

13..
/
/

0 I
c~
> i

j 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.0001 I J
! t9
I I
60 80 1 O0 120 140 160 1 80 200 220

Temperature, F

134
Vapor Pressure, psia

O 0
.k" O O
I

0:}

"i-
01
i I
t i -1-"
i i I'rl
i i ! r-"
! t i C
U1
"-4 !

i
!
0"1 i i
. . . . . .
"-4 i.......!._.i ! b,l , 1i
---t

~n i !
I............i........i..... i.
ii i
I!

c ~ ii!
I i 9 I
| I
I
T...............i.........i.........r i
-rl
ii i i
-'
I! i
9 i i: i !
i ii ii,!i i
U1 I i
U1 i I
i
"o-o
'........i"-i,. t' I
__..~_. !
. ii
i i i ! i J
II II
i .........! .......i !"...........
9 ~ +, 4 l ..... 4,
U1
i i i ii i
!
z
i i i

s i i i I I
I ! i i
i . i
"1- i i
ii I i
'- i ! ii
t ......... 6
............... ".............
9 i
i
i i i i i i i !
i ! i i
i ' i i ti i i | i i : i
i I i !!i
i! i i ii
, i
,~ ii i i i
i
l
i
i : I ! ' i
i i . , i
i! i! i
ii
I i i i i I i ,! !~!~ , i
! i i !
100

He HELIUM-4

'7 i

10 E IIZI-ZI~IIIIIIIZ.-_Z~IZ.21~I
..m

O.
F............... i ..................................................
F
ID
...............................................

r7 ~
:3
(D
(D
(D
I..

13_
I,...
!
O
O.
>

:/ ........
/
/ I
I !

1 1 psia = 6.895 kPa


i ...................................... i 1psia=51.71mmHg .................................... i

I
i i
i
' i I

1 t
0.1 I
., i 1
i i i I
-457 -456 -455 -454 -453 -452 -451 -450
Temperature, F

136
100=j:========================================
.............................. ,...........................................
i:= ..........===~-F--~!!--~---!~:-~!~!!!!-:~-<e!-:e1!!!-!-!!!~::!!!!!!!!!:!!-~:!!~!!!~!~!!!!!!!!::!!~!!::!!z!z!!zI!zzz~z
= , T ...................................
~ .......................................
"................................................
~ ..............................................
~.................................
. ~ . . . . . . . . . . . . . . ~.................................t~............................ ,".............................................. .~.............................................
~ ...................................
- ~ ,.~. . . . . . . . . . . . . . . . . .....................................
9 ~...................................... ~.

- Hf HAFNIUM ~. ~,....................... ~,............................................. ~,...................................~,.............................


. . . . . . . . . . . . . . . . :".........................
9 t .................... ~ ............................................. t .......................................... t ...........................
,.,I i i, ! !
,'..........................................

t T t
,' { 9
}.
T| ::::::::::::::::::::::::
!
; l ! i i !

:::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::

t ....... 7" ....... t.......................... t ......................................I


i / i i !
0.1 ! !!!!!i
. ~............................... ,,,l!.............................................. i
,I-. . . . . . . . . . . . . . . . . . . . . . . ~.................................. .i--.............................................;
.m
i i i !
I:1. 0.01 ~............................... ~ ............................. 4...................................,

::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::

I,i
............................ " ............................... ",,............................................... i
::} l i

i i i
9

,." .,.
0.001
I,i
13...
.......................................
i'.....................................

i
I,i .....................................................
i-................................................

0
Q- 0.0001
>
" L ................................... i
t~ . ~ _7__ i i
l J-f i i
1 E-05

1 E-O6
! -.:

1 psia = 6.895 kPa


1 E-07: 1 psia = 51.71 mm Hg

}{ it, t,'.. t--..,


i .......................................
i
i !
.....

"l"
9 ......~....................................
t .....

1 E-08 I I
9 10 11
Temperature, F
(Thousands)

137
-I
---- ................... :,:.................... 1~ :~z :7/.T..T---=--:::.': :: .':2:: :..~.~'~'-.T.:: =:::~::::: .'..'2Z'..T.'.2=: .':'1 ::::: ::.:= ::: :: :'.: :"=----:::1:::: :.'.':" :::: ..:.:.:-.=:. ~ :::::::::::::::::::::. :::::~::::::: .: :::::::: :::::: :..:::::::::::: :::: ::::::::: ::::::::::::::::::::: :: ::::: .: :::: :::::::: =..:::::: L':::::::: .::
. , . ~ ..................... t tt ' - - ..+....................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +. ...........................................
............................. ,
+ ~; + .............................. ~................................
j ......... 9 _ _+ ,
Hg MERCURY
10000

i ~ iii ZZLZ iii ii ii ;i ii iii---! .................................................................................................. r ....................... " .................................

1 0 0 0 _ - +++++++++++++++++++++++++++++++++++=.-_=
-. ,. ======================================================
I ........................ !..............................................

::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
,
: ==========================================
..............

100-_-

10:
~~---==~~=~-s I!E":Z:!~EE!!!::'!E!!!EE!'E!!!
:LZZZ:IZ s163iJs Z 2}:/----:}Z:::2Z:Z:[Z:ZIZ:Z::-~~I! Z:::'27::::::.'.::L":
......-::Z'.'.'~:.-'/2".'::::::":..'::::ZT::Z:
,r. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

1-
. m

[ ZI ~ J !
:: ::::::::::::J + . . . . . . . .ZT-:ZZ:::Z:..... :Z:,

Z3 0.1~:
0 .....~,,`,,+`~,,,~.,,~:`+:~2-::-::::::::::::::::::::::::::::~:~:::~:::~-=:~-=~-=~-~--~%.-:~-----::~--~~-1!~-----=--~.~-=.~-a~:..:~..-:..~.~.~:..~..~-:-.-~.:.:-..:~.,.~:~:~=
~:~.~.~--~=~..~.~.:.~:z..~.~.~..:.~
00
0 ======================............
=====~===-==- t - +---":::::::: •::::::::::::::::::::•::::::F:••--••-:::::::::::::::•:::::::::::•::::::::!::•:•--•••-:::::::::::::::::•:::•::::::::::::
0.01

1
0

0.001
>

0.0001~

1E-05+ ............................................................ .

1 E - 0 6 - i- - ~ ~-.-=.~ =-~ii~71"s ~:~-~Z=.-:".:==.4":.::Z.ZZs~Z ~4~I~II~IIIIIIII~Z"'''=...............""-""


................................
~''FIIZlIIIIIZ~'.P-II':IIIIII'I

1 E-07= ...= .-..-..r

1E-08 I I
-500 0 500 1000 1500 2000 2500 3000
Temperature, F

138
100, l I ~ ........................... "8. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
'
t ............................................
'
I ........................
3----_~iiiiiiii;iiii;i iii/ii iiiii Z I _ _ i i .................................... t ......................................
...... ~................... 4...................................... ~..................................... .}."

H gBr2 MERCURIC BROMIDE LI E l

............................................t .................................. !
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . L........................................ I

] ........ i f.

1 0fl ~ ~ 1, --:::::::::::::::::::-:::::::::::::-::::::-::'::::::::
1
. , , . ~ ....._oliiiiiiiii.i ......f_
. . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .(, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,i,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

7 ................................. '-1' , ................. "7 ............................. T. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "I................................... ~ . . . . . . . . . . . . . . . . . . "'.,..............................................

f i ........................................ { . . . . . . . . . . . . . . . . . . . . { ............................... ~ .......................................... { ...............................................i .........................~ ~ ...... i ...................................................


4-------- ..... I .................................. ' ........................................ L..................................................................................................
9 J.............~ ........! ....................................................

~I i . . . . . .
I . . . .
J . . . . . . . ,i ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
i J i .....

: ! | ! / | ! i

" J ......................................i . . . . . . . . . . . ~ ....... i .................. ! .......z ......... i ........................................ !................................


[ ..........................................

,-- I i ~ I A i i i
9 , s , / ! i ! !
09 i i ' '
o~ 1 3 ......................................t - ............. ~ . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
tD Zl ........................................
---'- ....... --' . . . . i" . . . . . . . . . . . . . . . . . . . . . . . .
K___ ] ..............................................................
--~--' I " .............. ~i ./ . . . . . . . !. . . . . . . . . i . . . . . . . . .l . . . . . . . . ! . .

a_ 3 ~:::Z::::::::::::::::::J-I-:---~ZL---_-!---------j'-/I -- qZ-Z---tZ-_T--s ...............


:
.................
=======================================================================================================================
.........................................
0 ~ t !
c~ " I ~ - - - T . .................. i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

H . ~ I . . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i i I

I---:, ........ i ............................... ~......................... ~..................................." ............................................

i
i
i
~....................................................
:,........................................J .........................................

i i i
,.,., j ............. i
U . I __7 . . . . . . . . . . . . . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~. . . . . ,. . . . ._. . . . ._. . . . ._. . . . .z. . . . .:. . . .,. . . .~. . , , Fl . . .~. . . . ._. . . . .:. . . ... . . .-. . . .-. _ : . :I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...... : : :t:.:. :. .:. .:.:. .:.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. : : : : : : : : : : ".t: :.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. .: : : : : : : T: :...........................................
::::::::::::::::::::::::::: t ................................................. " ............................................... ............................

7"--'------i. ..... " 7 . . . . . . .


--!t . . . . . . . .
i' ................................................
......... h ................. i .......................... t .........................................
t .........................................
t .............................
; .................................... : ....................................... ; ..............................
J .............................. -.J1. .......................

4.._._~~_ ......... j ............ [ ............................ I .......................... i ..................... L _JL.


A-/' ]i !i !i . . . . . . . . . !, . . . . . . - - " ...............................
=,1........................................... _ ............................ ............................. .................................. .................. , psia = 6.895 kPa .....................................
9
1 / !
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

! i i ~ i "
i i J i i ;sia = 5i_7i mm- H9
-! . . . . . o!.............................. i .............................. ~................................... ~............................ ~ ...........................................

I i i i i i
1 j i } J j I
_.../ ~ i ! i J !

250 300 350 400 450 500 550 600 650

Temperature, F

139
1 O0
......................................... i

HgCI2 MERCURIC CHLORIDE ......................


......................................................
4 ........................................ ~.
! ............................................ ! .....................................

...................................................... [ ....................................... l .....................................


l i

'!............................

1
f
10

.m

Ch
(D
K..
E
(n
............................... }-.EZ21XZEE".2ZITZ2Z "~IZ.Z2Z2"II~'~Z2.
(D
fi~ii i i i i i ~5-2--2-~!i!i i!!i!i!-i~i i !!!
L__

13_
K..

0
CL
>
..................................... I ..........................................................................................

i
1

I r
0.1 ...............
~-....................................... ~ .......................................................
4 ....................................................

!!!!!!i!!!i!!!!!!!i!! !!!!
1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g

0.01 1 i I I
250 300 350 400 450 500 550 600
Temperature, F

140
100, !

J
]IIIIZIII i-ii-i__ii I
] iiiiiiiiiiiiiiiii ........ I Hgl2 MERCURIC IODIDE
, . _ _ : i ' ]
] i i i ........i i I !
!
................................ ,- ............................... ? ..................................

I
!
.............................. ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T .........................

10~ ................................ ~ [
i .7~.
..........................................~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

-!. ......................................i ,, :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::


~ .................................. i ........................ i .............................. r ........................................! ............................................
t ......................................
~ ~ ..........................................
] .......................................7 ........................ T...................... i ........................ ' ............................... ~.....................~ ' , [ ........................
"---i ........., - .................
7. . . . i ................ i ................. ";.................. t ...................................i .........~ ........................
t ..............................................
i .....................................
7. . . . r ...............................i ..............................t........................................
i...................................
~ .........................................
t....................................................
i....................................................
--- 4------------4- ........... 4 ........... 4-........................... ~. . . . . . . . . . ~ .................................
i ~ I i i / i i l
] ........................................k ! ~ i ......z .................. ! ..............................................
L....................................................
i ....................
7 ........................... w . . . . . . . . . . . . . . ~....................... T............................ ~ .........................................
i 1 1 1 ~ i i i
i i i i i i
1 ~ -.:--..:z: ........ .:::j------z::::!:::::::::: ::::: ::::::::::::::z:::::::::::: z=:==:::::=:==:=:==::==:====
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::z::::
4----------~Z ~t7L--~---[-2-~---~~[[[[:---[--2-~-[[---2~~i~~-i!i!i!i!i!!~!ii!!!!!!!!~~/~fiii~ii!i!!!!!!!!!i!i!!i!!!i!!!i!ii!ij!i!i!i!i!i!iiiii!ii!!!!i!!!!!!!i!!!iii!!!i!!i!i!i-iii!iiii!!i:~:[:[::~:--~[[~[~§
... t ........................................+...................................................
~...................................................
i ...........................................

/ ! I
~---------~ . . . . . . . . . . . . . . . . . . . -i . . . . . . . . . . . . . . . . . . . . . . . . . . . .
J ..................................... i ............ .----.4. . . . . . . . . . . . . . ~ . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . ~ .......................... ' ................ "~........................................ 4 ..................................
> ~ , , -/ ..... i ......... i ......................... ~...........................................i ........................................i ...............

. . . . . t. . . . . . . . . . . . ' ........................ 4 ............................ ;".............................. 4.................................................i ................................................{.........................................


1-------, 71" ........................ , ............................ i .............................. ] .................................................
[ ................................................
i ..................
i /I I i I i i
t i i i i i
~] ............................................
- .... /_.__i ............. _L ................. [........................ i........................................L.............................................
i............................................
"" :i ================================================================================================================================================================================================
] .......................... I. . . . . . . . . . ,. . . . . . . . . . ' ................ [ ................ ..-'r" . . . . . . . . . . . . . r ................ ! ...............

__----"-'.~-~-_-ZL, C-'-._j::_~_---..----:',.--.-..T-Z Z :.:::::::~::::-::::-::::7.::::::::::::::::::::::::::::::::::::::::::::::::


:Z:::::::Z:,,7:I/.T.-::::::::::::::-3--:: :-::,
! , i i i ! i
-I----A 9 I ......... -i ............. i ......................... 1........................... K .................~ .......................
+--/--4 , i ...................... ! .......................... i...........................................
1....................... '~s'a- "~ ..............................
|
I ................. Z . . . . . . . . . . . . . . . . . .
i
,. . . . . . . . . . . . . . . . . .
1
_, . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 psia
,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ...................
- 51.71 mm Hg
....................................

]. 'ii 'ii 'ii


O.Oll i , '
300 350 400 450 500 550 600 650 700

Temperature, F

141
1 O0 , ............... ~. . . . . . . . . , ............................... J
-- ~' ~ ~ i __i______i_j ~. ....... I~Z .............L:I ..............iI.., ,~ s ............. ,-LL .......--.4 .......................................................................
-- '. . . . . ' ..........--4 ,~..........................i. . . . . . . . . . . --4 .....................
ZZJlL ..... i~ I IF7 I O D I N E H E P T A F L U O R I D E F T--]..............[............. i ................................. -I ......................
...........................................................
, , [. . . . I ......................... I . . . . . . . ~ ............................... i.........................T~.............................
1............................ r . . . . . . . . . . . . . . . . .................

- I I ..... I ......... I ............................ L___ ........... i ..............................................


J.................................. ! ....................................

1.............................
f I I t / I i i,

1.............. I.....................
I ..... I . . . . . . .I.........................
...............................................
. l-- . . . .l.........................
. ................!....................
l ............ , ...................................................... ~ ........................... T ...................... ; ...............................

Ii ...... l ......... I ....................................................................


i i :~. ............ 2i- ' , ................................................................................
~ ! ! .:::::::::::::::::::::::::::

. m

r~
1 '...... , 'I ............................
1........ I ..................................
i ....................... _!.............................
(1)
:3

(D
i ', ! ! .............
13_
IL_

0
Q.
>
1 .... i .......... [ / Ii .......................................
Z_-22~iiii:22211 -i~212211~721112~.T.212271

i 1
O, 1
1!2
l
. . . .

:::::::::::::::::::::::: ~: ::~:~ ~: : ~ ~ ............


. . . . .

'S~~:;!--'-----
. . . . . .

..... - .....................
L..__.L__ZL._Z...TT.Z7...ZZZZZZ:::LTZZT:ZL-Z.':I:IZZ.'ZZ"L"..'..-.'L'Z-Z
! ..............................
I ]'
[ .............................................i ............................................. l ..........................................

............ ..i9..................... ,,!..............................................


~..............................................
~.............................................
I Z - - Z ......................... ...1.................................. , . . . . . . . , .... , .............................................

.................. }...........................H 1 psia = 6'895 kPa ..............................


9 __ ......................].........................I.....t , p~i~ = 5,.7, mmHg .....................................

,
t
I
i i
0.01 1 I I I
-140 -120 -1 O0 -80 -60 -40 -20 0 20 40
Temperature, F

142
i~"...-= "" ~---2." " = ":" .-.71"--""-::"2.:~:,~:::::::::::.~:::'--:"
..'7":::::"
".=":::,".:-__-.
""i:::~-" "=:.'.----T..---::::
= .':.
" : ~ ,~E:7=--72:=:../=.:;
============================================
................. i___;;;; ......... ;_;____;_;:_;;_ _;.......... ;_ _;; ; ;;'.
- - . : i . . . .....................................
. _____it ,#........................................ ..". . . . . . . . . . . . . . . . . . . . .

!~~------"
]]11;77777777777777;77777777777771711 I ~ ..............................................................................
................................................... i ................................... @ ...................

IODINE . . . . . . i ................................................ f ...................


. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................................. 4 ...............................

I ...... I , I t l-- . . . . . . . . . . . . . . [ - ~ - = . . - - = . - - . - . ~ . . . . . . . . .

==========================
J .......... t ......................................: ;: ~ : .............. ---m---i ......................
9 7 ......... ; i ; 1 ..... ;;;i ;1;;;;;;; ;;;;_dZt;Z; .....................
.....................................2 . . . . Ii
I
1 O0~!!!!!!~-~!!!!!!!!!~-!!!7!!!!!!!!!!;i!~>.~!!iiTzii' - - .~=_,=_. . . . . . . . . . . . . . . . . . . . . . . . . . .

_ _ _

r ...............................
. . . . . ...~.
9
!
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............................................... .......................................

"'" /~ - '- " "~li i Z --ti ii li

1 0 5_ ................................................ 9 .. . . . . . . . . . . . . . . . . . . . . . . . . . . . .~= =::::.."T'-=---:'-'::..:::=


L'.::--=:'~:::::::::::::::::::::::::::::::::
:::::::::::::::::::::::::::-'..".:::4
..:.~:::.-..-.:::.-.::::.--"TI::
7,.'-':::
.--'222..."
:-:.'.:::

~ 4 i ~i.:: :_5~ :"i.--~ E:2 .:":E:i.~i!iiiE'i 71:i:I!ii!iii!:.'~i".'i!!:!':"Fii-:,'i- :?i Z i.iZ.-"ZZZ i.i 21ZZ;',
. i !ZZZZZZ'Z.ZZZiZZZZZZ-ZZ-ZZ" .................................
Z.Z..~ ! .............................. , ......................................... .~.......................

. . . . . . . . . . . . . ~ ............................................
.~ ........................................................
~ ...........................................................
~ ......................................................

P,
l
1 = - - .................. ]:;:,_'=~.-;= = = T=:L-.. = =7.';=';:~;;;...~..:;
......... ,8.. . . . . . . . . . . . . . . . . . . . . .
.~;::7.;== ."::7":7:'.':.:: "=:=IZ:;;;:;::-~:.':':;::;::;:;:;::::: ~:::::::..'T::';:;.-..': 7.;".~=;..~ .~~;"=': 7.2;:.':."='::::: ~=;l 7..T".'-'_--22,~;; =:.'.;:
~ ............................................. ~ .......................................................
~ ............................................
............ ~ ............................. ~ .................................................
~ .......................................................
~ ............................................
f .............................. ~................................................... ~ ........................................................ 4. ...................................................
i' {" ..................................................................................
9 i
t .......................................... , .................................................... ., ....................................
I -- ................... ~........................................... ' .................................................. ! ........................................

13_
L 0.1 ~--ZIII-II--71.... 7 -i . . . . . . . . . . . . .
......... ~
..........................
........................ ~ ...................................... . ..................................................
. .....................................
~-"-".."~E"~E."...~.~.~E~.~"~E~E~"~"~Z~EZ~."~.".:7..-."/::"~"~."~EEL---~EE~"-"~,
.............. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . ~............................................ +.................................................... ~............................................
0 {, i.--
! ................................ , .............................................. "4...............................
...................~ .................................... ~.....................................................
~ ............................................................
~ ....................................................
" ~ ' i ...............
..................~ ...................................................
~-......................................................
~ ...........................................................
|......................................................
Cl:l
> i
...................! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I ! i

i! i!
I"......................................................................................................
~".....................................

',
0.01 ~~~-~7 ................ ~-........................................e ..........................
..................~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
".2"...................
~ ...............................................
~ ........................................................
9.............................................
. .......................................... ........................................

_ _ _ _ _ ~ ......................... ~ ............................ ,......................................


............................ § ......................................................................................... ~.............................................

........ i- ............. i ................................................................................... i ....................................


i i
! i , ,
0.001 .........................
~:~:."." ~ ::'.-..':~:::::=::::::
,"..............................
"=:: =:s :: ~:: .~.~::.".::::::::::::::::::::::::::::: i:::::::::: ~:::::::: ~ ":::::::::::::::::: .".:::::: ":::::: Z ~:..~:: .".::::::::::::::::::::::::: .T.."TA". ~"=:::::::::::
.~.............................................. ~ .................................................... ~ ...................................................
. . . . . . . . . . . . ~--.~.~--T~"-.-.~-".-..T."<~T~".~"Z~L~.Z"~."~"~L~-~.~.".~:~::~.~.~".~::.=7".~L".~"`...~T.~I~"~"~"~7....-~."~.~
t....................... t ......................................... t .................................................................................................
r................................ r ..............................................
t ...................................................
,"...........................................
,~....................................... ! ............................................. T .......................................
! !

] .............. ~1 [ [
n m n m 4 _ 1 ............................ ].. , I ....... ! .................. 1 psia = 6.895 kPa ....................
%.#, % . J % . # % J I ~ ; ~ ~ ' . . . - - . . . T ~ ":::"............................. ~................................. ~.:~ .~.
---'/".~= : ".:::..... T./.=:.~.~::=::.T_~'.~::.~:= . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
n ~ ~ , ............... ---'[ ...............-- ........~::.... :::--::::-:."--:=---:---';
-"c---:::::--c::--::::z:z::zz:I p s i a = 5 1 . 7 1 mm Hg ::::::::::=:-::-c=.--:::::
~17~iiii~ii~i~i~iiiiiiiiiiiiiiiiiiiiiiiiiiiiii17~--~ : i, i ~:E._--_"IIT..IZ.--..CII..~".-"_E."~'2.'.:Z'~-.~'Z.T..Z;T.I:Z" "-.E.-TCZ~~
J .................................................... ~ . 9 : .................... .4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
] .......f~ t r , . . . . .
] ...........................................--/~"i " [ " F-" ................ ; .......................... " .................................. t"......................

- ~ ! I I ! !
1 E-05/ i ' i i i i
-200 0 200 400 600 800 1000 1200
Temperature, F

143
1 0 0 ..................................
_ ........~
,.Z-__q--7-~jZT&-.,-1.:-_:.T---I~-E-
~ ~ ......................................................................................................................................................... : f : = = : : = = = ....... = = :, : = = = = = = - - = = = : ,

. ' ~ ~ ~ ~," . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

.,= - - __ ilZIZZZZII;T"ZZZZZ-'-1
I=

.=

,=

0.1= "-:'-----.'~.T.T':"--"::"::,
.-Z:,'..---
--'.----~--
""..:"-~: ---T-".'.
.'/:" --_.T.~:'C ~:::3:::'~::~'~ :::::

. m

03
(D. 0.01= .................................... ....T. .......................................

(D
t,..

03
03 0.001 =
(D
t__ .. ,.,--.--.

13_
!,_

O
(D. 0.0001=
>

1E-05= .....................................
:~-.:-T.-:.-.:.-::::::::3:::3:::3-..C:3.~.--.--
Z- ........................................

1 E-06-
.=

-" 1 psia = 6.895 kea t' ~'-:~'~....


'- ~"~'
1 E-07- ~-1 1 psia : 51.71 m m Hg I!~i~~_'~i~i

..................................... ii]~! .............................................................


i ......................... !;S--..;-!Z-;:
1 E-08- l .......................................................T..................................
T T
1000 1500 2000 2500 3000 3500 4000
Temperature, F

144
100~ :.-!!!!!!!!!!!!!!!!!!f!!!!:!::!!:::::i:::::::::::~ZT'_~ttZt
..................... ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::

-[TTIIZIZZIZZZ]I
! r i- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~..............................
~ ......................
9. . . . . . . . . . . . . . . . . . . .
,I. . . . . . . . . . . . . . . . . . . . . . . .

]ZT__LLLZLLI Ir IRIDIUM i f[ .....................................................................


..............................[......................................]-i.................................
....................... ..~ t ......................
....................

:~ ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: .....

-I!E!!!!!!!!!!!]]!!!!!!!:]~
................... l f ...................... ~s . . . . . . . . . . . . . t
!.............. i .......... i:::::::::::::::::::::::::::::::::::::::::::::::::::::::::i:::::::::::::::::::::::::::::::::~::::::::
" ..........................
~................................
P - - ..........................
4 .~

I ! i

.................................i"" . ..... ... ... .. ... ... .. ... ... .... . . .


" ..................................... i'"!"
~::/-:ZI]ZZ ZZ]ZZ [ _ r.-----,m~--7..T- !
i i.
l _ _
i
i 1 s
......... t
-- ~,

!' i
. u
(/) t i .t
i , !
Q_ 0.01
! , f .................. i ......................... f
(1)
l,--
| i t._...:...-.!.--.::..f~L.::..IZ:..:iiLZiZ_Z..q..::::::.,:
i i t /_................ ~i ..................... ,:
I .................. I-
(n ! i -[7 !
(/) 0.001
i i i
::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
i
(1) i ,,i ............ =====================================
4,
~.....~ ........................... $ .......................

I,..

,L:=t_- i ,i.,.
i. i
!..__

0
c). 0.0001
[-7
>
i / '. . . . . L
F, - - 7 /
-i ! !
::::::::::::::::::::::::::::::::::::::::::

::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ,.9 .........................................


,.9 .........................................
9
.,.
.,

~.....~ ......................... ~ ............................... ~ ................................ 4


f "i ......................................... 4.

! ! !
9i , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .,

1 E-06 .,-......................................... .o.:


.a. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.,. .................................. ,. ......................................... a,.. ..........................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 ...................................... .,

4................. t ......... :-::=::::i~EEiiEEiE-'::i ,.~.......................... .~...........................................................................: .................................4


.- : 9 . ,
!' 't ......................... -,t" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9~," ........................................
...................................... '," .................................. ',
4.

i t
.l. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.i, . . . . . . . . . . . . . . . . . . . . . . . . § ...................................................................... ~ ................................... 4
"
T i , ,~....................... ~ .......................
I !
i
4,'
i| i, ': '
il~].i~i.._:.._,.g~:._._i~i::i~::.:~F._:~i~i~i] 1 p s i a
1 psia
9 I = 6.895
= 51.71
kPa
mm Hg
li
.~------"---':~--------'4 i
t } ~
""-"----'-I' j t
4.................................................................
-------i s I i i ...................................................................
............i . . . . . . . ~. . . . . . . . . . . t. . . . . . . . . . . . t
4 ................................................... ~ ............................. ~ .................................... ~ ...........................

I i i s
1 E-08 I i i i i I I I
3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000

Temperature, F

145
1 ~~~~~::=~"~===~===:=~==F~:~=:~=i~~5::::=:==:==::::=:=:::::=:~5~:~~i~5~E~5~i~iii~::~:~5~:E~5E~:~:~i~~:~: I
,9 ~
../~--- ~ = : ' ~ ' = ~ - : ~ = ~ "
~.............................
====--~~
.....: ~ : Z : I Z Z ~ : I : Z C ~ . . . . . . . . ~ _ _
,
f
!- ................................... * ........................... ~................................. ,
4.......................................~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . " ................................. 9

~ _ _ ,' I, .{.............................
K POTASSIUM ...........................
~ 1 t- ........................... ~...... ---.~,
J 1 I....................... ~ ...... L.
. . . . . ~ ," g ~ . 5 . - - - - , -!::=::=-==::::=:-=-:-.-=
; ::::::::::::::::::::::::: :========================
..... ~ .......................................... !: ii .......;~......... ~ ......................... ~ ' ..................................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

......................... 1.............................................. i .......................... ]


.................................... ~ ..................................................................

'{ ................. ~ .................


;:/--~:-::t .....................................
=========================================================== :::::::::::::::::::::::::
~ .......................................................................................

!7 .......::::::ii::::iI........................................
_ / ................ r ....................................................~................................... ~ .......................................................................... !
(1:1 ......................
................................... h .......................................................................
. i
(#) / i .............................................
/
13.
0.1 ..................... 2 ~~-~ ~ :"_=!2"
":E~":!!:::"Ti!
~22!2!-"2~-=2!:2".-'2:":2!":'-."::':
2.'I,!T.':":!!!!!!!!!!!!!!!!!:21!
!2!!"!! :""2-"
2:.!2
(D
............................. ~7.~.-:"L~::::"-..".%.:::::::::":::::::::::2::::.~:::::::::::::::7.:::2::::::::2::::2::~::::."2:~:~:~::::::~::::::::::::::::::::::::::::::::::::
~~ . ......... .~
.................................... 3" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .........................................
i,.,,
/ ...............

:3
............................. T ..............................................T ...................................................
! ..............................................
:======--.:=-:=-:...=::: ::::::::::::::::::::: !~":~.~.E~:i~.5~:e"5..'~!=.::"~E"!~!!"~"~!!!!!!!i!!!!!!!!~!5!!!!!~!!i!!!!~!!!~ ~~5!!~5~!!!!!~!!5~!~!!--!!5!!!!!-!~!!~!!!!!!!!.~--!...-..:!.::-!-!!!!~!
0I i " ' ~ ~ " " ~ ' : !i ===================================================================================================

13_ ./~LZZZIZZI. ...................


. . . . . . . ..........................
. . . . . . . Z. i "_------ZZ'Z"ZZ:"Z::~Z.TZ2Z.T-:ZZ--Z-_~IE-ZZZZZ'Z-Z'ZZZZ

i,i
o oo, .......... !
I

0
l:i.
.......................................................... ::::::::::::::::::::::::::::::::::

cl:I
> !

...................................................... ::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::


_~ ; ......................... ;:-;:;_;;;r;:;_--:--:-; .....
! . . . . . . . . . . . . . . . . .
: ."~'~'.'"..:::::'~"".~".~'T_.~...-"
,i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-'--...~::::

[ ...... ..
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
-. _. . . ......... i..........L _ / [ ....................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I

!!2.~E.-..-~.:E5-!E-`..E!!!!Z!!!!!!!!!!!!!!!!!-!~!!!!!?!!.......!!!!i!!!!!E!!!~E!{!.....!!!!!!!!!!!!E!:s163
/

- ~ : ~ Z ~ Z ~ L:L% L:~:~ ~ -7~'~:L-.~.'~.~.--._'~~_" ..... ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ..................... ~ .................................... 9. . . . . . :::::::::::::::::::::::::::::::::::::::::

iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii;iiiiiiii ............. mZI:I:II::::I:::I:I:::I~I~:~-Z.Z~'~-~_Z~-.:Z~. ....... ZZZZ:tl Z- ......... 1 psia= 6.895kPa [................. ] .............
~- ,~--, l [ i ! 1 psia = 51.71 mm Hg
-- - - ~;,r;;~;r--~;;;~;::;-;:/:.7~T.:; :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::
.............................. ~..............................................................
[~
::

!' ~t ............................ -~z:::::-::::- ......... ,.......... ~............................. l__z::::::::::::: ....... z::::


1 1 ~....................................... ,;...............................................',.................................................
' ............................................................................................................... t ................................... "I ................................
1 E-08 I i ~ ~ ~ ~ I
0 500 1000 1500 2000 2500 3000 3500 4000

Temperature, F

146
100,
~i:::::ii::iiiiiiiiiiiiii:ii:i:il
......................
-i .................................................. [ ~........................................................................... "i
-I YIII~ ~IYY1
. . . . . . . . . . . . . . ~ ..... i.........................................Z:::::::::::::Z::ZZZ:ZZZZ~Z:IFE:ZZL-Z:-Z:-L-C_--:
....... , ......................................................................................................... ~.........................................
liiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill KBr POTASSIUM BROMIDE ..........i ..................................................................................................................
j .........................................................

................................................................ '............................. i ............................................................................................................................................................... ,..............

i
i i
"r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
!

i
!
t i
: 1 1
. i
I i !
i t............................................
i
Q. i !
I i i
(D i r....................................................
i

1 !
I
'
'

(D
I,...
! i ::=z:: : ::,
T ..................
i * ............... -,,;2
O_
i i " .......................
0
c~ !, ,./
L./_ ....................
i j..~_. .................................... ,

i|
i
0.1 t .......

T ......

--_.~ .........

........... ............

i
!
!

i 1 psia = 6.895 kPa


i
! 1 psia = 51.71 m m Hg
{
I !

!
i i
i
i i
i i!
0.01 l
I I I
1400 1600 1800 2000 22OO 2400 2600

Temperature, F

147
1 oo0o.=. !
_|
i ! ,l !

i I .... ::
KCI POTASSIUM CHLORIDE
| . _ . . . . . . . . . . . _

7 9 . ,~~~ -

1
i i :
i

1000 ' i I
. . . .

,I
j i i i ,, ! l I t i ' 1
I I I ! I i
I 1 I 1 i I I
,il i i i i
I I l I I I ~ I i

I I I I I f- !

loo, _i
'
1
i
'
i
i
i- ..,,..-.
J r
i" //ii
II
I
t
,
I i,
,
,,,,

- /
_1 I ! I ! , ,

u)
..=,.
i I , ~ 9

CL
10i i i , , i i I ,' : :,
(1)
i..
! '
l i I I I
t
t
I
,
,
, ,
j I I I I . , 9
I I i I I I , 9 ......... 9

u) .

(D
IL_

n
I

1' ,
L._
i
l I
o ,
r
t
O.
I |
I I t
I , 1 i ! i

> i

!
!

I
!

0.1J i'
: i ' } !
I , ,, !

t |

__1 , i 1
' i
I I , i
i
_1.
i! ' t . . . . . . . . l

0.01 '
i . . /! . . : :
_1 , , ' I i , , i ' ,
; , 1 psia = 6.895 kPa
. . . . .
'
!
I
i
'
I

'
I i
i i t lpsia 51.71mmHg ;l
._ ,

.... "i

0.001 i i i , , I i I I
1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000
Temperature, F

148
100
,,,I ~ ,, , ' ;,, ,
........ ,_,,,,

KF POTASSIUM FLUORIDE

10-
,
J
I I

,,m

o0
Q..
(D
L_

o0
i
(D
t__
i ,,,

13_ /
t.__
/"
O
O..
r
/.
>

0.1 _ ,/
!
i /

/ 9 1 psia = 6.895 kPa


1 p s i a = 51.71 m m H g

0.01 -
1600 1800 2000 2200 2400 2600 2~300
Temperature, F

149
OST
-.I 'eJn],eJedLuel
0098 OOtT~ I
0088 0008 008 L 009 L 0017 L 00;~
LO'O
814 muJ LL" Ls = e!sd k /
ed)l s = e!sd L
I m /
. . . . . . . . . . . . . . . i ....
/
/ -
~- -1 f , , ' ...... ~
/
9 L'O
/
/
13
. . . .
0
, L
-g
"/
l _
J
o~
r
/
/ 1
I i
. . . . . . . . . .
. . . .
/
/
I
I
=!(]1(]01 ~ N I $ $ Y I O d I>1
..... L
. . . . 1 _
. . . . . . . . . . . . . . I L ii
00 L
-~::::ii:::ii
~:: .... I : :: :!.!.!!.::i:.!::!ii....
~, .... ~ ~ : : : ::: : "' : , '...... , :~ ..: .::, , i...... ~.................
l..........
i:: ...... :]i : : ::::x:::X]

]::::::
9 :: ~ KOH POTASSIUM HYDROXIDE I ......................................
! ! ............ !. . . . . . . . . . . . . . . . ...................... - 1
] I I t ................................................................................
~ t 1 J

lo ! 'I I I I i ..............................................
....!... ! I
]!!!i:!i!:::i..... ::.....i i ' : "-'-'-'-
'~ I~ " ....... ' ~::' "~ .....~ ' : :::: ..........
:I:. .r.,;,, :,,.......... , ::::::: ....

! . ' ............ ! . . . . . . . . . . . . . . I I .~ t I ...................


......... iiii1 1 ..... I' "1 ........~ T - Z Z - - I ........1...............

, i ii/ i.....................................
~. . . . . .
i / ! L_
. . . .

. . . . . . . . . . . . . . . . I
I

. i
.

O.I ~..........
. .

~,,,,:~,~_:::
. .

...............
~......
. .

:_.ii....-~:~!:!~--.+!l:~!!!!!=
........
:~,-------~i:
iii~ ~
i .... ::::~::_~_:_t~:-_=:
/i .....iii:_iiii!
...................~-
'
[
co

....................... I ................. i ........ -7!. ................................. l


0L _

I i/ ...i..
YY"'II I ,",'",, iiii ........ / I ...... . '............ " _ ". . . . . . . 14 .............................

0
o9
i ,
:~2~:t~::::::~::::
......
:iiiii~::! :::::::::::::::::::::::::::::
.......
;....................
-X-~2@2~S~?~Y:::~tl;I~::~:?:IT::= ' IIIIT~---~~-----~ ................_.------C~.~":::: : T
0
13=
L__
- l ./ I /I i ...........................................
t ,

0 - - :... ! ....................
I.I.I-iYI.......
:.......
/ I ...... I ...... i I : _:....LL[ l

ooo,..............! I / ! ! ! I l
O=
>
~I .......... : :::::::::::::::::::::::::::::::::::::::::::::::
.......
:J- ..........................
| .... :: .....:..i.:..,::::::'.'-
::::: :: ::::::iiiiii:iZ:::::__;~~ .........~ C ~ L ' - ~ . - - ~ ' = = _ ~ . . ~.
_~ .: ...... i :::::_:::____:
.........
,: ~ .....
ii.......... i i. : I : :: : i ~- :::::::::::::::::::::::::::::::: . . . . . . ~, I

H ..................... I :____:__::::~ IY-Y--


.......... ! . . . . . . . . i ....I ...... I L__~-I
! ................................ .............................

..... ) ....
! ' ~ ...... ! ....... ! .... ~ " ......~::::: : ......... I: :_:::L.--__~__}:~ ..........~ ...................
:::::::::::::::::::::::::::
.......
! z .... [ ii:/J .......
i::::::.::i. . . . . ! ........ ! ............. !............. ! ! .............................
i ~ .......................
] ..... ! /]I]::]Z ....! . . . . . i i ............... I
................ .................
i.....................
-T . . . . . . . . - ~ . . . . . . . . . ~ ..........

"I .................'~~ ........................i,


!I ...................i' .......
......... 'I.................i,
... ..................... ai................~I................
... ~-----K I: . . . . . . . .

I ::::::::::::::::::::::::::::::::
......~-:.- ................. ", ,,:........... ' ............... Y " ! ...............
~ T'~_-~=qi
.................... I psia = 6 895 kPa ).----=-~'

3
3 ......
' '
:~:--:-:-:--I
/,
~................
~ 'i.........................i ................
..........
. . . . . . , .............. ~: ::::::::::::::::
I .......
~ .. : ........:iii
i
.....::t:::
..........i ................................
....::::::::::::::::::::::::::::: J I p s ~ a9 =
..................
"
51.71 mm Hg
i~:~_.--
L- ...............

I .I ......... ! ............. ! ..................


I................................................
_.,
....... ~ i............................
t

_ - ...... I I ! I t i i !
1 E-06 i ' I ' i i i ;
600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F

1 5 1
1000 I= i 1

Kr KRYPTON

Y
E /
/

.==m J
O3
Q. i

!.--
(D
/ =
O3
O3 I O0
(1)
L_
Q.
L_
0

> /
/
/

/~ r
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

101 I I
-200 -180 -160 -140
I
J
-120
i
-I O0
I
80
-260 -240 -220
Temperature, F

152
100, ' ':t:!:::! .....................:: ........::""~......... ! T -~. . . . . . r---- ..... T ~ " : - : , - - ' T , - = : T T ! = .........................................................................................................................,
| ............................
9 , . 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................... 4-

] J La LANTHANUM P ........................................
i ~ .........
o] .............
] .............................................................................. ..................... i ......
] I . . . . ............
.... , ............. ,. . . . . . . , .......... r..........................................
~ ~ I ~ ~ - ~ - : : : : : 2 : : : - : ] = - ~ ....."

l I ::-;,
_ I ......... I . . . . I . . ... . ... ... . ... .. . . . . . [. . . . .. ... ... . . I .......................
t -- " ......................... I ........................................

I !.............................................
F - - ~ -:~::::::-:---:
.............................
,
........................ i.....................
i

I _ i ., I .......... " " ,, " ,, I ....................... - ' I ........~.. .............. " T ~"
] . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I .......... v ..... , ............................. i
................ i .................. [. . . . . . . . i ............................. t ......................

O. I --'.............................
,-,. . . . . ~. . . . . . . . . . . . . . . . . . "~ . . . . . . . . . i............................ ~-. . . . . . . . . . . . . . . . . -x.....................
........ ...... !':::t: . . . . . . . . . ::': ............... ~ ......... i . . . . ' " =======================================
. . . . . . i. ...................... r ............... . ....... i
J ...... t . . . . . . . . . . . . . . . i. . . . . . . . . . . ! . . . . . ! /_ .............. ~ i . . . . . . . . . . . . . . . 1 ........ ,

................. ' . . . . . . . - .............. ' .... - " - .....l-~----~'--:::--::~....... ~ '. . . . . . . . . . . . . ~ .... i


....................................
~ ....................... . ',L-_-.-
-- _ L - - 2.L- - 9
J i /! i s i

ool] ! .... / ! ! 9 I i
_ ~ . . . . . . . . r ....................................... ,.-T"----# .................... I ........................... .'!"-" . . . . . . . "... . . . . . . . . . . . "T . . . . . . . . . . . ~ . . . . . . . . . .
9 i ................... i ....................................... I"--E_'I ........................... ! ......................... - - - - - ' T - - . .......... t ..................... "~. . . . . . . . . . . . . . . . . . . . . . "~. . . . . . . . . .
J ........... I . . . . . . . . II' I iiii i ....................................... [ [ ....................... ! ................ ! . . . . ~ . . . . . . . . . ~ . . . . . i+ . . . . . . . . . .

J i i ............................../ - - - ......... ; ...........................................


i ...... i ...................... ; . . . . . . . . . . . ~, . . . . . . . . . . . . .

.... ] ! T--TT-- i i i i i
........................................................ i"- . . . . i. . . . . . . . "i' . . . . . . . . . . . . f ................................... i ............................. ,............................

U. U 1,31 ~--i~7.Y!:_:_:_!:_::-:!~-&:-:-_:!_:_v-!
............, ' - - : ~ ~ = = - - " ~ - - ' = ~ ~ ~ . ~ ; .......... ==========================================================================================================
-;2; ......... --- . . . . . . ::::::::::::::::::::::: . . . . . . . . . =========================== --~"~----"--"---'-----:~~-"-~~-------"-----'---.-~-" .......... ;7-'"Z::.'~=::::;Z::"2".:":Z::2".:=~*Z:'-.:Z::.."Z:":=: ..... ~-'."~.~::Z::::::Z:Z"_'-_Z.7.Z"Z::"
~- zz_--:2zz7771 .... _ . . . . . .~-----::-...:--T-'-"-~. - .................. .---- .................. - -- --~- . . . . . . . . . . . . ~.. . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . ......................
9 .................. ! ................... [ ................ 7 " . . . . . . , ~ .... . .......... "I- ................. I . . . . . . . -----"I- ............
9 ...................... ~ ..................................... - i - - - - 7 - .......................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................................... - ! . . . . . ".,. . . . . . . . . . . . . . . . -~ ............... I ............
............................................................. -"i- ~. . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . "~ . . . . . . . . . . . . . . . . . .

B
.........

1 .................. ~ ------r-7 .............................F - - - i - - - - r ~ .................. I . . . . . . . . . . . F .................. ! ......... ]...................


0.0001 4::-: ...............................
~:~:~:~ ...........= ~ : ........= : = L - - . - ~ 4 = = - - = . = b - - = - = = = = F . = = = = = = - = = & : = = = = = = _ _ . i = = = : = = = - _ =
> ~ ~
:::::::: :::
' : ' : = ~
i
~ - - ~ - -
~'i!iii[~::'
- - ~ ~
.........................~
~ ~ - - - - " - i
~
.......
.........
=~===:=:!:::==:::===::=-=:===~:="=====.-'.-'=.==---'=i=.--'-==:==::=====::
i ............... = ...... q ' = - - - T _ ~ = = = ..... "==:
J .................... i ....... ,2' ..-".EF.._~ ::[i:iii ~;7-;;;;;11111;17;::;;;........... , ~ - - - - - - - ' - - - - ~ - - ,. . . . . . . . . . . . . , ........................... ! ............... ~ ......................
3--_........... -................ i ......... .L ............ !___ i 'i ............................... i ............................ ! ................. ! ............ i .............
!
1 I::_n~
,
............
I_t~.............. ,r
. . . . . . . . -. . 7

........ -i--
i
i . . . . . . . . . . . . . . . . . . . . . . .
i
,
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
l :. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
J, ~,, i .9. . . . . . . . . . . . . . . .
i ..............................
,9
7 t..................
,
,...........................................................
J - i .#. ............................ [ ......... t : . ; "t

] .................................. ET ir . ....... - - - - 1 1-'----


" ---' , i' :, "i
....... - ..........
! . . . . . . . . . .i i . . . . . . . . . . .
.
~ ................
. . .
? .................................... $ .......................... ..i- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

........... ~t .................. -i .................. '


i i i
1 E-06:1===========-======:===========
............ ~. r': i i r~-...--.~=~....-...~-z~r~.~r~.z-..r-~r~:....--~z~z~z~~z~~+

3~_;; ........../ ...........i . . . . . . . i--~_ i; ............................... ! i il ' .............................


............................ i! ............... i! ri .............................. i i 9
i
i
.......................

1 ._-,,.~/=~~ ~:--: ~ ! ~ ~ ~===:==:=::=-:=:..-'Ei] 1 psia = 51.71 mm Hg ==::=== .... :=::


y: .... 9 ................. [---- -- p . . . . .t . . . . . . . . . . . . . . . i # i t
J .............. #__............... i. . . . . . . . i ............ I ; . . . . . . . . . . . . . ....... .. ..... .. ....... .. ....... .. .. . . ~t ......................... ~ r l

_ i ~. . . . . . . . i ........................... ~.. . . . . . . . . . . . . . . . . . . . .

i
! ! ~ i !
! i i !
1 E-08 i i i t i
2000 2500 3000 3500 4000 4500 5000 5500 6000 6500

Temperature, F

153
#CjT
-4 'eJnleJedwel
O00L 0009 0009 00017 0008: 000;~ 0 0 0 I. 0
I I ! I I 1 I E I.-=I I.
.. '4"..":.:-....- . . . . . :...... ~ - " - -~ . . . . . . . . . ,~ :
:..-----=:::.::..::...-:::: H I.L'I.S = ,~ I. i ~ . - : " . . . : 7 . . . . . . . ~. ~ ' -.. .......................
............................ r . . . . . . . . . . . . . l ; ~ I
..................................................................... ;: .......... [: . . . . . . . . . . . . . . . . . . J! . . . . . . . . . . . . ~L _ - _ ~ --
i,,, -- ,t....,.- . . . . . . . . . . . . . . . . . . . . . ;- . . . . . . . . . . . . . . . . . . . . :--:-: . . . . . . . : - : - - - - : :-:_-: .:_--: - .; ---: ],
~'~..'.-."..'..~~-.-'..'~.-....'.-=._~ .~-~.~=:~-.,.c:.~..".-~-.-'.~::~ !~'.-'.~'~-.',-~"~,:~.~.~.~.--~.::~ ! " - - ................ =~-~---" .....~::--~-::~':=~:
"= 6 O- = i I.
:::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::: r.=.-..~::::::::r..-~..-~.~. ..... .~.~-.:'=:=:.-. ::=.~.~-_.-.~..--a~-.~---_=:l ~ ; , ~ '- . . . . . . . . . ~ - - : : : : _ : _ : / - _-:::-: _ __ L:__ ,,,-
3
.................................. ~............................................................. i=_-=.=-- _ ~- _ _ - - ~ ___ ......................... ~ ................................................. ~ ................ ; . . . . , .....
. . . . . . . . . . . . "i ........... ..................... I i ...... i / ..............
1 t LI=LOI3
..................................................... ; . . . . . . . . . . . . . . . . . . . . . _ . . . . . __ __ j - - _ <
_
'!F!!E-::-.".'F!"~.!!E.":7!!!!!~:'.'F_'.-2.."s ================================ ::::::..':'::.':::::::::-::::::~:::...~-.--=..--~:.---:-;~:Z~--~,i:.~.~.~..~;~;~ 3--.'.'.'.'.'.'.'.~-~. . . . . . . . . . . . . . - " ~
...................... ~;;;;.;;~;:~ L,;;~::;,; ~,.;;;..;.LL;;.;,L....;;....... ......... ~ ........ - ~ . . . . . . . _- - . - . . . . . . . . ;L._.;,_,L';,__';:'_;__"_,.. , ~ ,..
i . . . . . . . . . . . . / .............. s O
.[-- :. ............ : --r . . . . . . . . . . . . . . . . . . =.. : ~i - --
::::::::::::::::::::::::::::::: : ~r-.~=.~.-~r~r..~:~4~`~.T~=:.~:::~:~:~:~:~::::`~::`::::::~::::~`~::::::~:::`~::~:~:`:~:~::;;~;~:`:L`````: :-:;: ::-:=;.L--_- . . . . . - . - - -- . . . . . . . . . . ,,....~.. . . . . . . . . . ::- - ~ - - . . . . . . .
"0
- - I . .: : ................. : : :, :- ~ooo'o O
9 9 _ ~ .... [ : ._- . . . . . . . /_ ........ [~
c
~ ~ - = : ' - - I ........................ t :::~ .... " ' :~ '................... :::: ...... :...........:/ ; " (1)
" - I I . . . . . . . . " " - 1.0"0 13
. . . . . . . . . . . . " " ..... i ...... i - [ / E -
i i
/
_ _ . .................................................. . ...... . . . .
_. . . . . . . . . ._. ..... ... .. ... ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -. . . . . . . . . . ... ..... ... .. ... ... .. ... ..... ... .. ... ... . . . . ! ..... I ....... 7-;, . . . . . ._ . _ L_
................................................ ;- . . . . . . . . . . . ~ ......................... -----::--:--~-:----:----:::--:-:::-:--::=--==--:==:::- ............ ~ ............................................. .';......=_ . . . . --_- _ '. . . . . . . . . . . . . -_-_-_
. . /
. . . . . . . . . . : ............ .: ....................... ,,!:':.'.'. ".i : -
: .......... : , ~ / ..... ':':":", ..... :.... , , , , , : . . . . . , .... ":
: i ......... . . . . . . . . . . . . . . . IAInlH• . . . . 00001.
' '~ 4 ~ - :..~
~.~L----..i~!!!"~!!!!!.".'7!RT..--.!"~!! i ! ! . . + . . - . . . ! . . . - . ~ ! ! ~ . " - . . . ~ E . ~ : ~ . ~ ! ! ! ~ E . ! ! i i ! ! ! ! ~ ! ! ! ! t! 7 ! ! ! ! ! ! ! . . - . . . " . - . . . . 7 . . " . . ! ~ ! ! ! - . . 7 ! E " ~ . ~ ! q ~ r 9 ............ 7...": ........................ E ~.--------.~----7.--.'.----..~:.--:~."~:~:.:.:.~::.:.~m::~:.~. 0 0 0 0 0
100

LiBr LITHIUM BROMIDE

10

..J,~

ID.

(D
&..

(D

(D
I,...
13_
Ik.,,,
O
ID.
> 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i

0.1
IIIIIII.~IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII.I~II~IIIIZ~IIIIIIIIIIII ........ l 't t - -
......-|i . . .i. . . . i. . . ...... . . iiiiii/
. . . . . . . . .. .. .
____/ . ... .. .. .. .. ... .. .. .
. ... .. .. .. .. ... .. . . . . . . . iiiiiiiiii
!

,8

I! 1 psia = 6.895 kPa

Z i

.
-.
1 psia = 51.71 mm Hg
. . . .
i
j
i

fE i
0.01 I
1I . . . . .
i
I . . . . I
1200 1 4O0 1 600 1800 2000 2200 2400

Temperature, F

155
1 O0
m ...... ~ ...............
,_ ! ........................ i .... /iiii,i
I i ii .
LiCI LITHIUM CHLORIDE ......... i ~ ~ j

. . . . . . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . J

,.. : : ;~ . . . . . . . . . . . . . . . . . . . . . .i. _ _ : . . . . . . . . . . . 9
|

9 . , ! ~
. . . . . . . . ~! . . . . . . . . . . . . . ,,._ ......................... 9
0 ~ ................ - . . . . . . . . . . . -,
. . . . . . . . . . . . . . . . . 1 . . . . . ..:::::. . . . . J ............................. ..i

........i ..........................~ : : I ~ ~,~..............===========================

!........... ,. . . . . . . . . . . .
!'; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "J
j" .

t,... !, . / ,...! L
L ........................ 9

13. ill;;.....................
:iiiii--"i........
L _

0
Q..
> . / ..................... ; ;;_-

0.1 ! M J
,6 .......

......... ~ ....................................................... J m m ~
,,L, "' ........ L/ - .......

/ ; .........

/
i l 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

t
0.01 i i i i I
1400 1600 1800 2000 2200 2400 2600

Temperature, F

156
1 O0

LiF LITHIUM FLUORIDE


, .. I

|
... ,,

10
, ~ ~ ~............. ~ ...... ~,!..........~ ............. ~ i ! ~............................
~,~..........~ ........ !~! ~!~i~!~:
_ --;i ..... i ....... i-ii ............... 1-71 ..................................... 7~ ......................... i..................!-'-i...........

........................................................................................ ! ............................. I_(LI ........................................................! .............


,,m

ID.
(D
I,---

:D
lD
(D
(D t ' t t -7"
//I }
i ,
'
I
i
i
,
i
r

13_
~qI.............................................................................................................................
t / !!.......................................................
. il .....................................................
. 11 ................

0 I
!
i
I
,
O.
> ,, ! I
. . . . . . . 1 ,,

0.1
i

ii . . . . . . . . . . . . . . . . . . . . . .

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
. . . . . . . . . . . _.

!
i
t
0.01- i ,, !
I
1800 2000 2200 2400 2600 2800 3000 3200
Temperature, F

157
1 O0
Bill
m ~

LU LITHIUM IODIDE

'I . . . . . . . . . . . . . . . J,

/
/
10 l
/
f ~ f --

,,m

Q.
/

U~ . . . . . . . ~ E i,i ' ~ "~iiii ........ ii ....... iiiii~ ..... iii'i iii'i iiiiii! iiii ..........................
CD ,/

13_

j/
t,.. Z
0
Q.
>
/
/
0.1 J /
/
ii...... /
/
. . . . . .

/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 -
1300 1400 1500 1600 1700 1800 1900 2000 21 O0 2200
Temperature, F

158
6ST
3 'eJn],eJadwel
00s 000~ 00s 0008 00s 000E 0 0 s I. 000 I.
I , ! I ! ! l !
i I 80-31.
...................i! ................. i,!--- ..........................
i............................................
[..................................
i ..................... I
............... ii, i:21_i i.... ii........:2111........ [ iiiiii ...... Z I _iliii i___iiii.....i_i i:i ii
-- : I ...........
2 ..........
Z,2L22:2 ........
1_2111 ......
: : Y 2 : ..............
:i: ......... 22___:_222~
212:/Y:2__:II ........... I::::
....... : f : : : - : ~ S : : : : ~ S S - - - S : : : . ~ : S : : : : ` ~ : : S 7 S : : ~ 7 S . - - Z : : : : . ` . : : : S : : : : : ~ : ~ 7 [ : : : ~ ? 7 ~ 7 S ` . ~ : : S : : ` T ` 2 ? : : 2 : : ~ 2 ~ 2 ~ : ~ ] ~'
:J Z:ZZZ2_.J2Z: L:: LZ:LZE_-
~ :Z:::2 2::: 7:7::::: 22 1:L1 ZZZZ ZZ 2777:1272-Z:777:7727Z__:22:2ZELLL2ZZZZLZ:7777:77:]
6H uJuJ I.L" I.s = e ! s d L
i ~ ~ /~
/..o-=! I.
ed)t s = e!sd I.
................. i ............................................................. ! ............................................................ ! ...............................................
_/.,:
............ ~ ............... i. . . . . . ! .... L I
...............................................
- ........:L .............................: ....... __i., ........................ I ......... :: ::: _ _7:::, .............. 22 :_ _/.__: : :: ___:7:77::7:__::_: : .......... 2::: ..... :::::~::::::: 777:7:7::__:::_:: ........ ::::2:: :::::::::::::::::::::::
' .................... T; ............................... i ................... = 9 0 - 3 I.
i !
_._i ............................................... t
L i ! .............. :I]711:::YTI::7:::II771Z77- .......................................................... ii ...... i_"_21:
i ! -s I.
I i
i 1 ]717
l!
" i#
<
.... ! I ...... 1 .... looo'o "13
..... = ..............
i 0
"'I
-T .......
............ 222._I .......
21_1.......
:22: .........22_:_!12222::Z_II_II .......
/ 2_::Z]2Y::IY 7O
........ 7____:L.I .......] _/121 .......iii_:,__iiii:~i. I__11121Z_ _ ii I iiii
. . . . . . . . . :::::::_::_:.___ ~ ........ : ::: ...... :::::: ............... :::_::: :_:_____~::: ======================== . ============================================
9 = --- 9 -- = .......
:7::
_s 0
~ [00"0
........................ !
O0
I i L
C
,,,-%
I ..................... :i L-
0
~ 1.0"0 "0
i i 1 oo
llm=
,, i ............................... A__J ............................................... 1....
L ........ IIIIIL]____Z .............. iliii. 21111 ......... 12] .... :]ii-
= . .= : = _ -- . == = = _-= . .== : :== = _-_ - _-= = --= . =:= : === | ::= = --- 7 =:- - ~=7 ~ :=~ = =~i ~ ~~- ..............=",._ - ---~_==~_---._-_=
~ VO
........................................... | ~ i ....22_L~ : / 2 : ..... : _:_:::i
7 ~ . . . . . . . . . . _7_7.. . . . ~:ZZ]2:Z22::I :I/2ZZ:__: .........: __:_::::::: ..... ~.:
. . . . . . . . . . . . . . . . . . . l ..............................__./'1 ........................... i . . . . . . . . . . . . . . . l . _ ]
~I~7_::::72Z~_]:22.-_7_:2_TT-_7~I iii -::7 - __ i :i i: ::L_: :.... 2_:: T:::: i: 2: i_: Y2: :7:17
. -. . . . . 7172:177722'i:22:77711277~ ...... _-_7__:]~:_2_ i .......... 2 s ......... 2 _ 1 2 ] ..... 21 ...... 2 Z 2 ' ........... 2__"_TI21L _i 22 22 ....... i i~
..... OL
: ! . . . . . . . j ................ ' ,
1
|
IAINII~IN7 n7
O0
" " - - - - ' - - L ' ~ - - - - T " ~ T ................................

_. ; I -

10 . . . . . . . = . . . . - . . . . . . . . . . . . . - - -,,, ---, ~,,, _ _;;- _;_-z-__;_~

- " ~ - - - E ,

- . . . . . : I ............ .............................

_~I__~I-----Z_7---_Z----_~....._L_-_---L_/---__-_-----___~----__
:---~_Z---__~7---___------__T----__~;~
Z-~ ....
- - - - ~ - -" . . . . . . . . . . . . . . . . . . . . '~ r " ~ . . . . . . . . . I

0.1 ..... : ....... . . . . i ~ : ..... : ..... ~.... T : ~ ~ . . . . ~ / - : : .......... ........ : : : - : - - - - - = - - ~ ' - ~ - - = ' ~ . . . . . . . ~ = ................ "-~'=~;
9 - ~ ]--/ . . . . . _ .- ._ __ _ . . . . . . . . . . . . . :

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i J" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- F I / !
o')
, , i

Q. 0.01 --
_
---
__ -
- ---
_ . . . . . .
L~2-
. . . . . .
Z
. . .
__L_Z~---
-
:
_ .
- -- - ~ -.~
I- . .
_4
. . . . .
.
-
. . . . . . . . .
. . . . . - .. . . . I . ~ . . . .

(D
&...

.. .

o')
09 0.001 - .............. .............. /
0L _
- - -___--__ --L -__ -_ --_ . . . . . -2Z_ _'_:.-: ...... - - _ " ' " " - . . . . :-- I" ..... " "
_

. . . . . . . . z -- 9 . . . . . . . .

13_
. . . . . . . . . . . . . . . . . J ...... T 1
- ...!... 9 ~
- - _ .... [ / ~

0
0.0001 / /~/
>
~ . . . . . . . ~ . . . . . . . -:- ......... :..... ' ........ I i. . . . . . . . . . . . . . . . . . . . . . . . . . . .

- /_ _
. . . . . J

1 E-05 ........... ....... : .......... ~:


9 . . . .
....
-/
-i

/
1 E-06 .................................

1 psia = 6.895 kPa

1E-07 ~ -i 1 psia = 51.71 mm Hg ..................... 1

............ .

1 E-0811 I I i I I I ' I
400 600 800 1000 1200 1400 1600 1800 2000 2200
Temperature, F

160
1 O0

MgCI2 MAGNESIUM CHLORIDE t

(D
. m

c~
, !
Y
1
!
I
! i
I I j i
(D
I,... , i
(D i !
!
(D F[ !
n
I,...

0 tt I
Q.
i i
> i i

0.1
I
!/
i
i

f ! t
i ! !
I

1I
. . . . . . . .

1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

oo11
I

i
t
i
!
t
I
[
1400 1600 1800 2OOO 2200 2400 2600
Temperature, F

161
1000

MgO MAGNESIUM OXIDE

J
100- . . . . . . . |
/
/ r

-,,i . . . . . .
/
/
. m . . . . . . .

C2. /
/
/
L _

r~
r~
O~
r

13_
O
C2.
tO
>
10 L
.... . . . . .

/
J

/
......

/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

10 11
Temperature, F
(Thousands)

162
1
........................~ - _ _ : }
~~176
l ~
!

0.1

03
EL 0.01
_._ _._ _. / . . . . . . . . . . . . . . . . . | |

(D 1 r -. .-. . .-. ./. . . . . . . . ......................................................


.i........ .t
/ !
=.. ............................................... ,, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -'!'
L_

~ i / [ ,
03 1.................................................,P--~
/, ...............................................
0.001 '!r . . = = . ~ " ~ . ~ . ' = = . - - . - - = = . - . " ~ : i: ~ = - . ' . . = . - : = ~ : ~ = ~ " = = = = : ! i

~
03
(1)
t,..,

13_
~----~----~
!._. ---~ ........ --i
0 i : . . . . . F ........... --7
i / I I ~ !
0.. 0.0001 ~_'=.~-.=__--_.~===:=::==f.::"_"='=:'.':::=:".'.:==:-=:=-====:}! ...............................

>
9 , m ~ i t'

......................................................"}l:: '~i } I"


1E-05= . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _. . . . . . . . . . . . . . . . . . . . . . . . . . . i i
!

- - i ]
!
1 E-06=
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _. . . . . . . ==_. . . . . . . . . . . . . .

b ,:.

1 E-07= ~EI 1 psia = 51.71 mm Hg

!
!

i
1 E-08- t r [ [
1000 1500 2000 2500 3000 3500 4000
Temperature, F

163
100 . . . . L . . . . . . . !
1

- |

MnCI2
MANGANESE
MnCI2 M A N G A N ECHLORIDE
S E CHLORIDE
I . . . . .

/
/
10 L

......... | f
I 7

/
/ . . . . . . . . . . . . . . . . . . . . .

. . . . .

I:L

f
O9
(D
1 .jj/
J. . . . . . . . i ..... i iii! .... iii ....... i ~
I..., I
CL. J
L_ /
0
Q.
cO
/
>
/
/

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
. . . . . . . . . . I

0.01
1300 1400 1500 1600 1700 1800 1900 2000 21 O0 2200

Temperature, F

164
Mo MOLYBDENUM [-----1 ! ! 1

0.1

I
0.01 ! .................................... ],

0.001 ~'-.-----------3-~
.==-'.""
-.-..==.
...... .--=.:-=::""-:::!~.."-.!~--~F-:.-~.---:..:.=.=--===:{!!|!H~=======:=:::=:====~:
,m i if ::=:::"-':'-:---'::'!~:":!~'.=-'!!'~"!!::::::~F~:-~-59-"~'~!~E~!~!:I
09
Q.
i
0.0001 9 1 ........... ,L . . . . . . . . . . . . . . . . . . . . . . . . .

(D
~L__

co . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i i! i
. ......
i
(D
K.. :~ -* :I
n
i __, I i '!
&.-- ...........
I i i i
O
CZ.
>
1 E-0'
i9 i
.
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
'-
i

1 E-08
! !

!I ~ t, tt
! i i i
I/ I ! i i I
:"!:.::=::: ."-.~= = =::=::::::=::-"::.".::::::--.:::::::::::
~ ::::::::
= ::::::::::::::::::::::= r.::.T.=::.~:::~.i=.-..%.--.::
.-u:::::::.-:=::.-.T.:::.~.T...':=
..-:::::::::::1

1E-1
- - - ;
[-~.= } i
-i--
'
t
,
,
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
1
1E-11 !. . . . . . ==~: .~. . . . . . . . . . . . . . . .
{ 4

1 T
t ]|
-- t
1E-1 I i [ i i !
2000 3000 4000 5000 6000 7000 8000 9000
Temperature, F

165
99I
-I 'aJn),eJedwal
O0 08 09 O~ O~ 0 OE- 0~- 09- 08- O0 r-
1 LL0"O
/
6HWW LZ'Lg=e!sd L /
edM ~68'9 = e!sd L . . . .
/
....
/
/
,,,
VO
"tJ
0
/ 73
/ 0
r oo
oo
0
o0
m =
./
7
/
....................... L
........ . . . . . . . . . . . j
ki , .... . ....... " ' " . . . . . . . . --01.
. . . . . . . . . . . .

J
._
I
~ 3alHOn7..-I la17N3as,~70~ 9_-IO~ .
1
I
! ,,
' :---00
1 O0
::. ...... :: ~:::: ............ ! I 84 i }i:........... ii .

MoO3 MOLYBDENUM OXIDE ' " ! ....


| ,,
l l ~ . ............. l

m i
.........................

|
[

10

i i ~-5,"-.................. [ .....................

4
.g

c~
1'
j ......... .
~ ' - ~" _
...............
|i !"
i !/ I
t / r " i i
u~
_- z ........... ~___ 121221221112221
............ [i./i/-_- _~
(D
tkm
/ ........................!......................... ! . . . . . . _j
13_ ,! /
&=. it"
0 /!
C~.
>
/ I
I - - [
i / .........!.... !
t

II II
i

! !

OI I ~_L i iii/ : i !

......... i.... / 11 i .............. ! F i


- : ~!~ / I ; i t
'T
!......................... T!
.........J /
/ I! i'
,[. . . . . . . . . . . . . . . . . . . . .

!
r I psia = 6.895 kPa
[_
!
I psia=51.71 m m H g
!
! i
0.01 I
l !1
I I i I I i i I
1300 1400 15OO 1600 1700 1800 1900 2000 21 O0 2200

Temperature, F

167
1 O0

NCI3 N I T R O G E N TRICHLORIDE

10
/
. . . . . . . . . . . .

u) ./
.,n,,,

(1) /
u)
u)
/
Z
(D

/
13_

0
CL
r
>
/
/

I
/
/
/
/
/

/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.1
-50 50 1 O0 150 200 250

Temperature, F

168
100 1 1..... t t i
!
| ! l

! i ! .... . . . .

I NDa HEAW AMMON,A 1.......I.........................I


; ............. ~-,, , _ J........ii .................
iii' ........iii] ..............................
,-

-+i ......iiiii I " iiii-+ ...... iiiiii--iiii ...... , [ ....... iii-+..ii~i-.__~,..........................................

l .........11..................................................................
........ ,,
...................................................................................................... I - 'l' ,

1i ...............................................................
'
i !

[....................... I

O9

i .
F
i
l
+ /
L_
, ' ' I j

L_
] ......................... ! --T---JJI ' ~ ! i, ]:.7 ~ ..... 1:
', ............... .................
i ..................
13.
-I ..............................................
i.............................................
i .......................................
i i .........................i ..r " i
0
] ...........................t ......... i .......... I................. i........................ +,i-~ ]
>
l+++++illlliillil ++ ++illi i i+i+ i .... _-T .... i !

1 84184184184184
- i
.......... ...... ...... ......! .................. ,

i""'l" 1 psia = 6.895 kPa


i I 1psia=51.71mmHg
; | =

/ i i !
i
' ! I
1 I ,
I

I
-110 -1 O0 -90 -80 -70 -60 -50 -40 -30 -20
Temperature, F

169
1000 l ,]
L _ _ _ : : L L L :L____:::LL: L:_____:LLL . . . . . . . . . . . : : : : i
t t t

i ................... ~ t-i ~i IIIZZIII iii l ii ~iii


NF3 NITROGEN TRIFLUORIDE
LI

100! .......................... - - - - - - - - - - - - - . - - - - - - - - .

~ . . . .

/
/
10 .
1
~ . . . . . . . . . . . . . . . . . . . . .

/
1
. . . . . . . . J

03
..,m, L . . . . . . . / z

CL /
/ ]
/
:::}
/
t__

o3
0.1- l . . . . . .

(D
t__
_

13_
/

O
Q.
/
> 0.01~
/
/
/
/

0.001 /
!
I
_ I
_ !
0.0001 .... ~
i: :~: ~i!J1ps'a--6895kPa 1 psia = 51.71 mm Hg

[ ......................!
1E-05 1 i
I I
r
-350 -300 -250 -200 -150 -100 -50
Temperature, F

170
TLT
-I 'aJnlejaduJel
OOg Os OOg OCj I. O0 I. 09 0 09- O0 L- 09 L-
I I = !
I I.'0
!
i i i
! !
6H u.luJ LL" Ls = e ! s d L .....
ed)1968"9 = e!sd L ....4
I , i
::::::::::::::::::::::::::
;;;i~,17~ii'171111111-i
]17]i]i]]]]i'i]i]]]i]
{7] ]]]]i177{]77]7]71117~
i'!'7{7117]]1]]]]]]]
71]]1111'77777{]
]]'7]i!']];7]]]]
............................................................................................................................................
I "
I
.............i .......
[ .......... r ............... 3 - ~ . . . . . "-
I i ' / _ _
................... i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ........................................ i ...... , . _ _ . __
............. T ............... ] -
! ..................I ................................ ! . . . . . . . . . . . . . . . . . . . . .
iiiiiiii17711111111111771177~.................
iiiiii~iii i #......iiiiiiiiiiiii 7..................[i:::::::::::::::::::::::::::::::::::::::::::::::::: _- <
1........................... ~' .........................................
ll)
..................... ;7.__]__.]]7]]]]]]]];7;;]_-]]_777]]777]] ........ L-_];;;];;]]L_LZT]7;]];];];]];]Z777-Z ]]Li;]]71717]]]]];];];L]L_;777];;];]]];]]_ ZTT]]7]]]];
01. "13
0
'==II
. . . . . . . . . . . . . . . .
..................... 7 1 "13
"==i
l i'D
......................... i I
......................
(#)
! '==I
. . . . . . . . . . i, . . . . . . . . . . . . . I---/-- . . . . . . ! .................. ! ................ t ..................................
.......................... ,i i'D
O0
~ a
l:i)
l " :' ; :-: ; ~ - ..." - - i
000 L
::::::::::::::::::::::::::::::::::::::: ! ...........................................
z_; ::::::: :;;i iiiill V I N O I A I I A I V s ::::::::::::::::::::::::::::
I -
, ~ .... r .............. I..... : - 0000 I.
ELI
3 'eJn},eJedLuel
OtTE OEE 00~ 0 8 I. 0 9 I. 017 I. O~L 001. Og
L i L L LO'O
. . . . . . .
uJuJ L L' l.Cj= e ! s d L
ed)t cJ69"9 = e ! s d L
i
Z
L'O
<
"(3
0
-0
/ CD
(/)
(/)
(-
(1)
r . : ,.
"0
I .
,,; . . . . . . . . . . ;
I
i
! ...... i
~j./- .... ; .- .
OL
/
i
.....
!i i
_ _ _ _ _ . ,F :INIIAIV-IAXOhlCIAH OE:HN
i
.,, [ .................
1_........i_i...................................... ii t li .......
-00 L
1 O0
] ]
H4Br AMMONIUM BROMIDE

10-
,=

. m
] ........ "i t
Q. i

(1)
'F/ ii
L_ l
i /
.A I, !i!
U3
03 _

(D
T
!._

n
L_ i I ,

O
Q. I
--i !
r ........................... t
03 i!
> !

1 i
!
I!
!
0,1- L. . . . . . . ,-!--- ........
=.
=..
i
i ......................... i
!
i............................... i 7"
I
!
........ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g

! i i
........................................ i ...............
!
I t
! i
0.01 -
350 400 450 500 550
i
600 650
t
700
i
750
Temperature, F

173
looo:l[ ] [ t
NH4CI AMMONIUM CHLORIDE
~

100-
. m

or)
Q.

L_

ffl
ID

>
10-
.=

.=

.= J

___/
~
I
111psia=51.71mmHg
psia = 6.895 kPa

1
500 550 600 650 700 750 800 850 900 950 1000
Temperature, F

174
100: ,., ........ I I
i
[

........ ~ NH41 AMMONIUM IODIDE


" l
.... ', ................... 4 ........................ ;
I.................... "

. . . . I i i

, i iiiii l;i;iiiiiiiiiiillil iiiiiii,ii i i~iiii ~iiii !~/r ~iiiii;iiii'i.............................................


i.......................

CD
li.

(I) ............... iiii~iiiii__iii ........................................................ / . . . . . . . . . . . . . . . I !


i,,,,, .,/ !
a.
i,.., / ............ ] i

O
ID.
> ! / ii......iiiiiil/iii'i'iilJ
..........................................
i ............. i
. . . . . . . i ....................
t .............................

i Ii
I |
0.1 -
"=- _
,iiiiiiiiii;;;;.___.iii;iI/7111171;7;77--ii
~ ~
........................ i ...................................
I
I.........................................

"i&

/
i

....... -..................... - ....... -...... - . . . . . . . . . . . . . c ...... 1 p)ssliaa = 6r 1. 86925 k P a ............... ;'


~ 1 psia = 51.71 mm Hg

i . . . . . . . . . .

0 . 0 1 ........ . . . . . . . i ....... i ............ i .. i ...........


400 450 5O0 55O 600 650 700 750 800
Temperature, F

175
1000

NH50 AMMONIUM HYDROXIDE

/ J

100
......................

/
J

/
/
.I

Q. /
(D

o3 10:, I m
IIw,~i
13_ ~m

O /
Q.
/
>
/

,/
/
7, 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0,1"
-100 -50 50 100 150 200
Temperature, F

176
100] ...........:::::::: .........JI ........ ~ iiiii:iiiiiiiiiiiiiiiii~!
I
........ ~~iiiilLiii ~):::
I
~iiiiii~ii::i:::: ! I . . . . . . . . . . . }.

]il ill iiiiiiiiiii | '


~;~:~iiiii] NH5S AMMONIUM HYDROGENSULFIDE !

!!!!!!!!i
,o- !
1 .............. ______i.....___i.... ,
2 i ........................................ : ....................................'
)
........................................... "F.i 212 ,, :,,,
, m ............................ z ......... ,

if) 'I I
c~ i , i !
!..__
,1 ' it /
i i
i
O9 I
I
i
t
!
i
L_
i............................ !
) t

I !
0 I
i I
> z !
i j
I i
i I
I i
i i
! I

0.1 ! +
I ............... . .t" r[ T!
i ....................................................i ............................................! ' '
. . . . . . . . . . . . . . 9
! !
| ..................................................................................... i
i !

)!................................................... i'
6
1 psia = 6.895 kPa
I ,
1 psia = 51.71 mm Hg
! i
ii i
l! !
o.o11
! !

I I I
-60 -40 -20 20 40 60 80 100

Temperature, F

177
1000 I ....... ~ f

I 1 I ! /]
NO NITRIC OXIDE i J
Il /
i ......................!.............................
/

/,
1 O0 i iiiiiiiiiiiiiiiiiiill iiiilZiiiiiiiii
i iii III/ZZIZI]
to
. m I /ZI .......
iiiili
rJ)
C~.
-7
/
Q~
/
7.

r~
O~

l/
13_

/
L_

0
C].
tO
>
10
/iiiiiiii iiiii
/
Z
/

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

11 1 I i i i
-280 -260 -240 -220 -200 -180 -160 -140 -120
Temperature, F

178
Vapor Pressure, psia
----L

--~ 0
,.,,.,IM 0 0
0 0 0 0
, -,. -" 0 0 0 0
I I I II I I I I I IIII I I I I I I I I III I I I I I I III

0
~
...........

_o
Z
r~

01

-4
G)
o
-!---iliii i
G)
r-@
,ii!!I
i !ii ,it irlii
! i
I ' iii I I9 I~
i
i
"11 , !
! ' , I
jl !~I ,
' ill , i ..- I i
!J! i
" ''! i
.......... ~"- 9 iI
IX)
44.." ........................... i
i,ii i
0
0 i !i~ i I I i ii
i''." i
iI iz i: :i
9 . I i
-- iii i i i
~~ iii
i,I 'i i I i ''
II II i ~ i
i i i !
~I! l i
01 (:~ -'t"H', ............. ,...... "-'!' .....4 ....+-"-!
i:::m If! i
',,I
9 r I
0 i
--'- r
i!i i
ill i
! i
i I
! i I i
9 i!i I
0
0 ! I
i I iiii
i i i iJii
i , i
I
ii i! ! '
U1
0
I iii,
1 O0 . . . . , ............... ~ ............ ,

I
NOF NITROSYL FLUORIDE
................ i
.................. i

,.. ,_ _ ,.:.._ ===================================

11:1
.m
I:1
. . . . . . .
! k
.,,

i '
!,.._

1~ E .......... ./,,
(D

13_ /
i._. y ,
0
I:1
/ J ! .......................... i
!
>
/ ,i

0.1

!.............................
J~
/
/ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g

i
0.01 I I I I
-220 -200 -180 -160 -140 -120 -1 O0 -80 -60
Temperature, F

180
10000 ......... I ....... ! ........... | , !
J:i . . . . . . . . J .... I:ZII ii ......... I

| ......: ::::Y : i: t:/: '~ -iii/ : Y::-Y---: ........... II


J ::: n ' .....
I I ..... ' .... - ............

- ................................................. t ......................

I ! .....................-1--
.i.................... !
J /

- : : : t . . . . . . . . . . . . . l. . . . . . . . . . . . . . . [ .............. L......... _~Z: ........... ' .............................

I ........... I...............
i i .............................................
............... I i .....................
~ .................. i. . . . . . . . . . . . . . . . . . . . . .

.......... : - + ~ ................I

i ........................................................ : ............... .7" ....... t t "

. I

.................................................. I
I
i
i
i
!
t / i + i
9i YYIA: ....... iii.......................... T - - 1 _..._+ ....................................... l ...........................................................
J. . . . ! I :/:i i
s,__

fl
J .... ~: ........... i:..... x / : ......i'
................. .......
.....
::.....:..'..- - .....................
--7' i__
0
J_............................. / 1 ~ l
>

o l ...........
I vn: :: :+:+--+........ : ................ :
i/ t ~
i
_
i
+.........................l . . . . . . . . . . . . . . . . . . . . . . . . -.,--
i
.......................
~
f. . . . . . . . . . . . .
I
~.--
J ..................... ~ : i : ............. i ............. ! ................... ~ . . . . . . . . . . . . . . ~ ......... ---r--

I / i. . . . . . . . + ............. + . . . . . . ~. . . . . . . . . . ---r--
---r . . . . . . . -t--- . . . . . T ....................... +................... - + -
" F - - - F - - I - . . . . . . . q - - - - ............ .................................
9 + ............... 4---
~_~.._~J/_. , , , i
...................... i .......................
---+ - ' . . . .
'i_ :'.." .__i ....... - -- l " l 1 psia= 6.895kPa
J ............................ J l + I psia = 51.71 mm Hg
............ + I
i i t i

9 i
. i '! !
:
1 I I I I I
0 50 1 O0 150 200 250 300 350
Temperature, F

181
1000

N2 NITROGEN
. . . . . . . . . . . . . . .

. . . . . . . . . . . .

J
. . . .

y
./

/
1 O0 ~ i/
/
, , n ii /
,,F/
ID.. /
(D /
/

/
I----

(/}
ID
13.. /
O /
/
O..
>
1
|
!
/
/

/
/ 1 psia = 6.895 kPa
1 psia = 51.71 m m Hg

1 I I
-360 -340 -320 -300 -280 -260 -240 -220
Temperature, F

182
1000.~
t
~ N 2 F 4 TETRAFLUOROHYDRAZlNE

1 OO=

u~
. i

Q.
|

(/)
(/)
(1)
L__
n
o
Q.
>
0.1

................... !

0.01 ,i
4 1 psia = 6.895 kPa !
[

1
i 1 psia = 51.71 mm Hg
i
t---"--'-'-"

0.001 -
1
!

T !
r l
i
-300 -250 -200 -150 -1 O0 -50 0 5O 100
Temperature, F

183
10000
........... . ..................... +. . . . . . . . . . . . . . . . . . . . . . ... . . .=.. .... ... .. . . . . . . . . . . . . ! ............. ,. ..................... 7Y~, ..................... i
N2H4 HYDRAZlNE

!
.....!' ...................... ..........

1000,

100-~
; ......... ; - ,, i:, / .... :i: '"::::::':............. !
.t'~__ ~ ~ ~ . . . . . . . . . . . . . . i /. .... i i IZ ii -'

~
m
/
I~
10, ~ ~ ,+/
,:,
.......... ,,:,, ,,: ............................
.. . . . . . . . . . . . . . . . . . . . . . .
m.. .,.:,, :
- : : ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

/.' .............
E / : : : ................ i
0 r ,/ !

>

~- - / - . ..... 1 ,. i .... i,' ..........


_- : 3' ........... , ." : I 2

' / - p +
--_ - ..... = . . _. .: . . . . . . . . . . . . . . . . . . - ............

1 psia = 6.895 kPa


1 psia = 51.71 mm H
i ....

o.o17 i 1 t t t ] 1
0 1 O0 200 300 4oo 5oo 600 700 800
Temperature, F

184
I O0 9
............................................ "I

N2H4C AMMONIUM CYANIDE


,?
,}

i / /

10- I t

oo
Q.

..................................... |
(D - t 1
I,i

13_ ! I
IL_
i t
0
i i
>
1 i
i
I................................ T
I
I
J i i i
I I
0.1 L ..___~ i i
......... [ :i
_- Z' ' ...... m J- i
_ L ....... I ............................... i. |

_'_ /i ................ i ............................ -1 i ...............

9 / ! I

!
__ / i !
1 psia = 6 . 8 9 5 k P a
i .......................... i ...........................i 1 psia = 51.71 m m H g

i i
!
,
', !I
0.01 1 !
i
i
i l
.
i I
-60 -40 -20 20 40 60 80 I O0
Temperature, F

185
100

N2H6CO2 AMMONIUM CARBAMATE

1 i/
LIL::L:: i: / ~ ..............................................

7 ~
/

J
,,m

y
ID.
(D
1.-

In
(/'j /
(D
l.-- 1
/
l.. . . / ..

O /

/
O. /

>

/
0.1
/
/
F,
/
/
/

/ 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01 I
-20 20 40 60 80 100 12O 140
Temperature, F

186
1 0 0 0 0 . . . . . . { ....... , ! ..........................

+ . . . . x o + ~ ,,,,,,_+

i
i

.: . . . . ; . . . . , ...................

........i...... .................i ~.... + ++........................ t _ ~


. i

L++++ii+..................
+i _iii iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii~-i ...... ~ ~ ....................
ID

o9

13_
O

>
100-
!!!

t i
i .'.
..................... !/

i ii + ................... ~ -
9
L 1 psia = 6.895 kPa
=...........+ 1 psia = 51.71 mm Hg "

lol i i i , ,
-150 -1 O0 -50 0 50 1 O0

Temperature, F

187
1 0 0 0 0 C...... ,,~,..................... ,,, [i

N203 NITROGEN TRIOXIDE


!m
1000~ _
' .'/' .. F

i~ '
lee ......

100~, , :,,,:;,,ii ,.... .....i, . . . . ,- , ............ [ 1 ,. .................................

y , iiiii?;ii,

2"
. i
f.t)
c~
_

(D . . . . . . , , .... ' ,

::l
I

(/)
(l) I /
13_
B nm '
0
m m
~' ,, / " r.
c~
>
V . . . . . . . . . |

" ,"/..

0.1- i ii/

/
0.01 /
........ 1 psia = 6.895 kPa
,,
..... 1 psia = 51.71 mm Hg

0.001
-200 -1 O0 1 O0 200 300 400

Temperature, F

188
100-

N204 NITROGEN TETRAOXlDE

.mt~
r~
c~ 84
Q~

10-
O~
13..
0
Q.
tO ........ ~........t ............................................
>

/ ii
""'~""-'- "='~"~'-'~"'- ml 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

i !
20 40 60 80 1 O0 120
Temperature, F

189
1 O0

N205 NITROGEN PENTOXIDE

10
......... f
J
ii.... i ..... 1. . . . Z / ..................

. m

O3
Q.
/
/
t._

O3 /
O3
(D
t__ /
Q. / L ,

/
t._

0
Q.
> Z . . . . . . . . . . . . ~. . . .

, , . . . . . . . . . . . . .

0.1 /
, / , 1
p -
/
/
/
n 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 I
-40 -20 20 40 60 8O 100
Temperature, F

190
10000~ .......................
~........~.........~.....=_.: ......................................................................
i ....................... ]

1000

i .............. i

1000~ . !

, .....

I i
..i

-~
i:.:-:~:..:-:.:m::.:::..:-:::..:.:-:-::::::.:..:-:.:...=::....~..-....--.::..-::.=i

f-- ...........................]
.m
c/) 0.1
r~ 2
e~
(1)
!.__ I I !
0.01
c/)

i
T.................................. ?4,
c/) 9
(2) !
T
!
n 0.001
!.__
f ! i--
o [: i'f.....................................i:
r~
I i '
0.0001 ,L.

>

i 1 1
|~--~---:..............
:=:~...~-~:::~:::..-::~::..-::."~=::~:=='.T.::::.--m:::x:::::r.::.':.-_..::==
,8
.z:..::=::::=.~~
L. . . . .

t . . . . . . . . . . . J:.................................
t ........................ ? r
i t i
1 E-06
~ m
i ; {'

I i I
1 E-07

:, mm.o
i---------i !
! i !
I i I
0 500 1000 1500 2000 2500 3000 3500 4000 4500
Temperature, F

191
1 O0

NaBr SODIUM BROMIDE

10 /,d'

/
.......... 7

/
lj 7
,m
O9
CL 1 /

/i
/
/ . . . .
/ 9
(1)
L_

cO
L_

13_
0
Q. 0.1 /

> /
/
|
/
0.01
/
]

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.001
1200 1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F

192
]
NaCN SODIUM CYANIDE

i r
!
tO
t I
. u

t
C}. i !
0.1 ................................... J
(1)
m,

::3
t~

13_
0.01 -
0
C~.
I
j 9
cO
>

i
0.001 - -
__,
_~ ...................
====:~ , .,
..................... I :;

"." 4
I !
0.0001
i

i'- 1 psia = 6.895 kPa


, 4 9

' ! ! t
t,
t,m
:E'
i :1'-: 1psia=51.71mmHg
i ' ! T
i
!
t
1 E-05 ! T
1000 1200 1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F

193
1 O0

,o 1 I I

,,m

..

ID... u

(1)
l..

(1)
I,.,.

l&..

O
ID. 0.1-
>

0.01

:i:- 6.8,5.Pa - - - -

= 51.71 mm Hg ................
...,,,...-

0.001
1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F

194
1 O0 ....... ;' I;.,.,F :ii . . . . . . . .

NaF SODIUM FLUORIDE

10 . . . . . . .
J ._.

. _ i l
, t /

t
...................

.
J

IllZIIi ~
, .................. / [
......................... / i I
i

. m

Q.
III
ml _IZ ~ 9
I
P
/ ii
/ ! ...........................
! ............
i i !
L . . . . . . . .

9
(D X
/'
/
I
(D
D_
i
0
Q.
I
0.1
!

> / !

i
!

.......................................... i .................................................
:

',_ ..............................
I ...............
:Z
! .........................
1.........................................i ....
i ! ..............................................., ...................................... !
i
/ ! ... I
i 1
/ 1
I........
t
!
0.01 . !
! t | ..........................................................................................
! 1 | t
~" ..................... i ................................... ,
| "- i

L
|
!
..........
.................
..........
I~.........
........ I psia = 6.895 kPa

! ...........................................J - 1psia=51.71mmHg
1 !

I 1
i I i
0.001 i i i
1800 2000 2200 2400 26OO 28OO 3000 3200 3400

Temperature, F

195
1 O0 I ,.
I

Nal SODIUM IODIDE I

,,

/
f
10
J
/
/
/
ltl
. m

c~

J
e,,

(1)

/
/
(D /- j
13_
0 /
CL /

>
/

/
0.1 /

/
Y
/

/
/ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g

0.01 - I
1400 15OO 1600 1700 1800 1900 2000 21 O0 2200 2300 2400
Temperature, F

196
100~

NaOH SODIUM HYDROXIDE

10-

1-

, m

co
0.1-
7 ,
1'!'
=.,
.,,
I
I
i
o.oi~ i.

cO .,.,,
ffJ

0.001-
0

>
0.0001=
=. i
I
1E-05- t.
=

l !

1 E-06- 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
!

I i
! i
. . . . . . . . . . . . . . . . . . . . . .

1E_071 ! i
500 1000 15O0 2OOO 2500 3000

Temperature, F

197
1 E-06
1 .... J................. !
Na2SO4 SODIUM SULFATE

.m
09
E).
e~
Q)
t,,.,,
J
u) _ / _ "
u) 1 E-07
/ i ~ ' _. ......... .. .......... ........

13_ i 9

L_ 5i- -
y,,d,~,
0
C).
> . j f
/
f

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

1E-08 I i I i I I
1650 1660 1670 1680 1690 1700 1710 1720 1730 1740 1750
Temperature, F

198
I00~ .................~ . . . . . . . . . . . . . , .... ............... i ...... .. . . . . . . . i,, ~.............................. _. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . ~ .....................
~g....~___:_:_:_:;_:;::_::_::;:[:::;;:~;; ..... :: 1l - ...... ~-:~7
~-_-:--_
_i . . . . i
. . . . . . . . j ..... I

i t I......... '
9 _ .... !
, . , . . . . . . . . . . . . -. . _. . .1 .

!
!
.... ' ..... i ....
: _1 N b NIOBIUI~ M
] ! i .......... ........................
i .........
I

10! ..............
_~. . . . . . . . . . . . . . . . .
' ..... :
". .......... :':. !' ...' i:ii: , " I
i ....
: ' :':]- 1 ,
i

i
1 ~.: ..... -.......... ;--]

| ..... I
I .... !
i

t ,

0.1 ~,...................................
JJ ................... i
. . . . _ .... T . . . ~ ~ . ~ -=:-4 F

--I :. - ..................................... t ............. / ....... i "I


I / i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .

I . ,
,,, - ....... " I

.G:I J
03
lz 0.01 ..... ~ ........ ~__+

J
|
: ::: ...... : ..... ' i T
I.__ JJ ........... i. . . . . .
9 ' ' i
i I
::3 j ,
O9
1
!
i
0.001
9

....... , ..... | T . . . . . . . . . . . . . .

11,..

i
r
L__

0
0.o001 i
- - i .......................................
i.......................

i
i *
i
1 E-05
I / ......
..... A.. . . . . i

i
! ............... - ...... t

i i
!
1 E - 0 6 .................................................. ~/

,:
,
..........
, ....
/
./
i
....... : ,, ,-, ,.....
................................................
-III:Ii:I::T=
.................................. T-'!
i ...........................................................
i.... 1 psia = 6.895 kPa
- / -~ |
' /, E !
u __ ============================ . . . . . . . . . . . . . . . : ; ; q _ ......... :::-~:-'::;~;;~;:~!'~!!;!::: ;::4 .................... :::..:' ~'::: :~ . . . . . . . .
;~!:-=i~!iii~!::-- ~.~ 1 psia = 51.71 mm Hg ~.......................................
~ ~ ;
". ' :~:~::i ........... : i . -' : ........................... ::[::::::
-- - : ! l . . . . . . . . I ....................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
! .................. 1..................
! ....................
,
1

1 E-08 I I i i i
3000 4000 5000 6000 7000 8000 9000

Temperature, F

199
3- - I It t | ; ; J

l ........ I Nd N E O D Y M I U M I!_i.....i__-.......... I.......................I.......


i .....
i.....ii: -_....! . . . . . . . 1 ..... --__-
.....]..........
- - - ~

...... i I i I I .... I ', ~ .....I ........... " _ '. ..........

,j .......! ! ! ! _
......

] 1 1 I I / 1 1 "

_1 l I [
9 ' ir[ '~ . . . . . . . .

-- l | I J" I . . . . . . . . . . . . . . .
~ ~ ~ , i ~ I . . . . . . . . . . . . . . .
1 l ..... l___ ! / 1 I ' ",.... " I . . . . I ....... "

-9
~
s 0.01
] J l . . }/ . l9 . .
"... ~ -
.
..........4
t 1
........... [ " r - ~ ........................... --:..:::-:--L.:.:.- .......................
] i ..... ]_ _ ,,,i I ' i .....

!--- I I / i I [ ...... : .. '


1 ...... I I I I I I

m 0.001 . . . . . . . . . . . . . . . . . . . . .
: ; .... -_ : _:_ :~ / i
'
i .......
,. . . . . . .
:::::::=.:--- ,. . . .
(D
I,..
I I l ~ '
I i .............. ]/ i I [ , ,,l ......
13_ ~ ...... _ ~. . . . . v ~ 1 [......... :..:..........
[. . . . . . . . . . . -.
_9 l~ _ I _ _ A t I I ..... I . 1 -_,

o ~ I /1 I I' ! ] ! :
~ . . . . . i ! I [ l - I .....

I I i , I , , l .... " " 1 .................. .i . . . . . . . . . . . . . . . .


~' 4-: - - ' " ' ' ' ' .......... ' ............... ' ' ::: '
] _ I _I . l '"I' I " I-

] ll ....... ~ ~ ! I ...... ~ ................... . , ......


r
i
_ /
/
: .......... 9 i . . . . . . . . ~ i ................... i ......... i . . . . -....... :::.......
-- 1 _ _. -..... 1 i- - - - .[ ....... --, .... i : . ~ - -~ -.
- l l [ [ - [ t ! . . . . .
: - .... _ / 7- 7-- r--i - ................ I- - i _ [ _-_ 7- 77 777 [ T~]

/ l ! I t I 'l p s i a = 6.895 kPa


1 ~r - - u / z.-~- i - . ...... -/ . .... : .... --- ~
;~:;- -:-;-- .
:-:-_-:__--;_-~:;; . ..: ......... if, ..... : -- :--~--: , .... -- ::::-::--i:_:: ,[ ~ : = _ - - - ~ - : i t =~.
Z1 1 psia = 51.71 mm Hg

- ,
_-:l l . . . . . . . . . " ~ _ _ _ .
[
r-
......
.. . . . .
: .......... .t::-:l
:[~.'_._-_. .L ....................

.t l . . ! .... I.

1E-08
Ii Ii !I
1500 2000 2500 3000 3500 4000 4500 5000 5500 6000

Temperature, F

200
1000

IZII~I~I'II
...-]ii
.....

I
f

L ~ . . . . . . . . . . . . .

1 O0 i .....4
i ~ i~i ............IZIIIIIII'ZZZZIIZZZZZZZZZ]ZII --I
. i

u~
...... i
-
]..
i
! t i i
.............. i ........... i- !
(D i
i9
I
!

ix -

(D

L_

>
IOE . Zi IIII!ILL2"~~:TI .........i
IIL2L]IZZ~Z21ZZI ...........V.......................................... 1
]IIIV ii--ii_ ]i ', ............... 1
I
/ i ........................ i
9................................ ! - - - . . . . . . . . . .

!
!

!
f
i 1
1
t ,
z
t
I ' 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
i ' l i

!
t

I I
i
i i

11 i
-415 -410
I I
-385
I i
-420 -405 -400 -395 -390 -380 -375
Temperature, F

201
1 O0
: ...... t :

Ni NICKEL r ]
:

10 ........ "~ ' ................... i,,,

L.
=,.
i ;' . . . , :-, /......~ . ~,--"~
;. . . . . . . ......
.. ,I

- ~ii~-- ii ii.] ,;; . . . . . . . " ' f ' ' r . . . . . . . . . . . .

i'
]
0.1--
~ ~L~ ~ iii ii;ii iii .........C........;ii ii~....... i; ii :'"'~ZI.....
~ ~ / i i i : .......:iii..... :ii i:iiiii:iiiiiii iiiiiiiiii ii iii iii i '
i / iiiiiiii ii iil Liiiii iiiiiii ................. '....
= m '/
O3
(D.. 0.01
(D

03
03 0.001
(D
t._,.

13. . . . . .

t,,.._

O
ID,. 0.0001 - ~
>

1 E-05

1 E-06

1 E-07
.............!.iI 1 psia
1 psia
= 6.895
= 51.71
kPa
mm Hg

1E-08 I
1000 1500 2000 250O 3000 3500 4000

Temperature, F

202
1 O0
!

NiC404 NICKEL CARBONYL

"i .................. i ......................... i

!
i .

10 .......... ] ................................. ]
............i ................................i ..............................
-~__C~ _ _

i m

_.__._____~_~_~~ ____._
Q.. .

1 , !
L _ i ] i

/ --
(D
13_

o
Q.
9 i

I
>

............................................................
!................................
!

-! .............................................................. i .................... .~
t ~ ~ t
i i , ,
I i : t
I |
i ...................... .--4

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

i i
t! i!
O.lt i i i ' i i
-20 0 20 40 60 80 1 O0 120

Temperature, F

203
10~ I I !
!

NiF2 NICKEL FLUORIDE L. . . . . . . . . . . . . .

!,ii ......iiiiiii.......7 ~;
ltl . . . . . . Z
. . . . . . . . . . . . . . . . . . . . . . . . .

i m

CL
(D

IB
/
j
J
L_

13..
/
L._

>
0.1 t
7
7
..... . . . .

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01 I
1950 2000 2050 21 O0 215O 22OO 2250 2300 2350
Temperature, F

204
0.0001-,

,.I
!
Np NEPIUNIUM

1 E-05 , ,
,.
I
..........................
i
Zl.
i
S ....................

.
ell
n
i--- i
el. ,x ! !
(D
:D
7i i I
1 E-06
!
i

(D / , f
/ /
!.__

r 1
L_
li
/
i. . . . . . . . . . . . . . . . . . . . . . . . . .
...........

O !
Cl.
/ ! I
. . . . . . . . . . . . . . . . . . . . . .

> I
i
I i I
i
! ....................

i 1

1 E-07-
/
/
.... ~" .............. ,

/ I

-
......

,,, , /
P"
,ii ! ....... !
- /
i"-'~i 1 psia = 6.895 kPa
i 1 psia = 51.71 mm Hg
I i
! i

1 E-08 I I
II
2400 2500 2600 2700 2800 2900 3000 3100 3200 3300

Temperature, F

205
1000

02 OXYGEN

100-
==

..=

u)
Q. 10:
(1)
:3

(D
L_
13_
L_
0
EL ...,

>
,m

0.1-

,==

~ ~ kPa
mm Hg

0.01 - [
-380 -360 -340 -320 -300 -280 -260 -240 -220 -200 -180
Temperature, F

206
1 0 0 0 ~

OZONE

100=

10=
z l
!

_
I
. m

i
!

i
! T'
!

4,

ffl i
0.1= . . . . . . ! ................................

13_
0
F 'i
i
I

> 0.01=

r i 9
i |
0.001 =
-_ q;
~ .....
!

0.0001

! !
1 E_05t 1 [ i t
-350 -300 -250 -200 -150 -1 O0 -50 0 50
Temperature, F

207
1 O0

0.1

e m

03
CL 0.01

(1)
t__

::3
03
03 0.001
t__

rl
t.__

0
Q. 0.0001
>

1 E-05

1 E-06-
w

psia = 6.895 kPa


1 E-07= psia = 51.71 mm Hg

1 E-08- ]
3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 8500
Temperature, F

208
10

OsOF5 OSMIUM OXIDE PENTAFLUORIDE

|mm
..... 1 2

i
ill
I

e3
. a

J
(o
O.
0
J
00
00
0!---
O_
/
/
&,..
!" ]
0
O.
>

ii . . . . . , , , !

i 1 psia = 6.895 kPa


!1 1 psia = 51.71 m m Hg
i
i
! !
t
!
I
!
! .,
0.1 I
80 90 1 O0 110 120 1 3O 140

Temperature, F

209
1 O0
...... t
~ . . . . . 11".'"i.i . . . . . . . . . . . . . . . . . . . . . . . . . . i

Os04 OSMIUM TETROXlDE- YELLOW E~I~II~IIIIIII~IIIIIIII


. . . . . . I i ii iiiiiiiii

10

./
. m ...........

co
Q.
(D

(D
!,--
/
13_ i ~ii iiiii ii i i

t,.,.

0
ZI / ..................... i
Q. , .... q

>
/
0.1 Z
E

/
/ . . . .

/
Z
/
i 1 psia = 6.895 kPa !. . . . . . . . . . . . . . . . . . . .
1 psia - 51.71 mm Hg !
f""l

i
0.01 i i I
f
I
o 50 1 O0 150 2OO 250 300
Temperature, F

210
1%,/%,./_I I _ I

Ji iiiiiiiiiiiiiiiiii+_iii...... ii.. i _ I._ . ... . . . . . .ii. . . . . . . .ii___


. . . . . . . . . . . . . . . . ii i __ I[
_ILIZIZII~IIZZZZLI
-]

3-III+~11111U11~III11]
_I_ZIIZ_ZIiiiiiZJ Os04 OSMIUM TETROXIDE-WHITE

]iiiiiillliiiiilllliiiiiiiiiii+iiill.........i:..... !+ II==:::::ILIL::I::III::_+__:I21:/221L
+++:+......+:+::+++++++++:
:++..............
++++ i++F~ ..................................
{ .........
. , m ] i+i++++iiiiiiiiii+i+iiiiiiiiiiiill;il
illl iiiiiiilill..........................................................
c')
]iiiiiii2111____i
iiii___ili21li_~-
_i___i.12 !!!i!!!!i-..................................
s,__

t
,! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -,

I,__

13_
'L_..
--"i .................... i
0 ] ..........................................................i............................................... 1 7 .................................................. ..... ~ .............................. t
t"J
> _-I IZIII iii11- 111111111]
..................................
i i
i i

!
.... " ~ .................................... ~. . . . . . . . . . . . . . . . . . . . . . . . . .

1 i

.+++++++_
. ........ . . .+++++i
. .. . . +. . . . .
' I

0.1-- ! 1
[ i
........................................................
i ................. i ...........................................................T....................................
! 1

i...................................... i
~ . . . . . . . . .

1 psia = 51.71 mm Hg

I'--I'....

! I
i'
i 19
0.01 t I I
0 5O 1 O0 150 200 250 300
Temperature, F

211
l~176 - i
,
! ~ I
! .........
i
i ....
l F

P PHOSPHORUS-WHITE ~. . . . . . . . . . . . . . . . . . . . . . i .......

10
(1I
c')
1
i /
:3

n
J
L..

>

-:::A

/I
. . . . . . . .

............. i
~;ZZZ-_.-Z;
........................... i

!......................................................... F ...................................... I
E
i...............................

/ 1 psia - 6.895 kPa


1 psia = 51.71 mm Hg

r J
!

0.1 I I
250 300 350 400 450 500 550 600 650

Temperature, F

212
1 O0

PBr3 PHOSPHORUS TRIBROMIDE I

i
[
i i

9 ~ ,
10"
, t

..... t ................ ! ~ ~.~


. . !. . . . . . . . ~[ [:. . . ....................
. . . . l! ......................
:: ~ / ||i ...................
. . . . . . .

1 i / .... l +
cO
. m L
c} !
CD
L._
+! : ..........> l 1 '

u)
co i i
(D ............ iiiiiii ill' . .
. . . . . .
. .
9r
. . t ......................
t 1
+......................................................

13_ J
Ij
0 ---S 1 !
>
cO i i
I
i

i!
0.1 t
--r---- t t
i + t

!
t
+ .

1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

i i i
i! !!
0.01 1 I I I I
0 50 100 150 2OO 25O 300 350
Temperature, F

213
10
i i i
I
. . . . . . . . . . . . . . . . .

................ I

PCI2F3 PHOSPHORUS DICHLORIDE TRIFLUORIDE

7
J
I . . . . . . . . . . . . I,, ! .......... i

, ! ...... i_ . . . . . . . . . . 1 /
/
............................................
,
/

: Jr , -----+-+ +=- .............

. . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...... . ..... _ . . . . ....J

03
. m

03
EL

t.__

03
03
I
-| . . . . . . . ,ll . . . . . . . . . I

LG)
_ ]"+ ........... ,_
Q. I . . . . 9. i .................... l

L_
0 , / i ,
EL I ........ i
03 . . . .

>
! . , ............................
J

/
.... = ... / .

c, I + B B

1 psia = 6.895 kPa


J 1 psia = 51.71 mm Hg

.......i

0 . 1 'i i I
- 120 - 1 O0 -80 -60 -4O -2O
Temperature, F

214
STE
-I9 ' e J n l . e J e d u J e l
098 008 09 L O0 L 09 0 09- O0 L- 0 9 L-
I ! ! I LO00"O
I
, - .................
i
l
'
l . . . . . . .
.
]! 6H ~uLu L/,'Ls = elsdL
~..~_ ed)l s = e!sd l f i
. . . . . . . . . . . .
77~7771i"?' ~ ..... " : :: :.i ~ ; .... : : : . i ~ i~i, /::: ::::::~::::i
:~c-
f-. . . . . . . .
i,,/, ,,'........ i,i,,,i.... '". ...... /..i..'i .......... ...i:-
.t ............. / . .
i [ / i .................
] ....... ; ...... ; ;; 9 , ,; ..... :' ,, :, - ,_
. . . . . . . [ ........ ]]] 7 __Jill ......... s .............. ;;;;17;;;;7___ ; i;L;i;7;;;;7;;77 .-
'! ..... ;;.; ' .L:;7: l:::C;77777:::::-!./ ...... , 2 , : : :::ii({i{i:i:::::r::::(i:{iiT:Ti.'-- ~0"0
<
. . . . . . . . . . . . . . . . . . . . . . : . . . . . . . . .
lit
........................... i / ............
I
0
I l l
. . . . 1_
. . . .
9 -
"U
9
............. .../
/ ..... ~
:. . . . . ~
i. ., . . . . . ,_
' / ! i ..... i.. ...~ .~ L
............................... ~........ --: ........................................... ,, ..L----;- 77;;;;; , / ....... _= . . . .
r .... - - - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~- ,. (#)
p / ,r
(#)
.i I
. . . . . . ~ ~ .-:.- :. : L
i i/ r ! (I)
....................... _--~- ............ ;. ....................... { . . . . . . . . . . . . . . . . . l . . . . . . . . . . . . . . . . . . . . . .
' /r i i ................ .-
r-"-------- -~................................................... . . . . -,:- . . . . . . . : . . . . . . i ... I . . . . . . . . . . . . . . . . . . i . . . . . . . L 13
. . . . . . . . . . . . . .
(#)
I .
, ~:~- .... ~........................................... 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . - 9~ - ..............
.......................... :::::::~ :::::::~: : ~ i ~-
;..i ;;;;.; ;" ....-; . . . . . i, ;;;;;;;;;;; ;;;;;;;;;;;;;;;;E Ill
______,,,,,,_._.,___,, ...... i; i ;71 . . . . . . . I . ; . . . . . . . . . . . . . . :~: ~.~ ~
....................... ; /_. ............. ]] .... ;7 i ! i
=================================== ~_J~c____"~;___::::; ....... : ~ ~ ~. . . . . .=- ..... ; .... ; ~ i;;.:;.;:'. ~_ L
r
L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i ' i
...... f I
.... ; .......... ! . . . . . . . . . . . . . . . . . . . . . . . . . .
!. . . . . . . . . . . . . . . . . . . . . i .................... ~ .....
..... i. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. ..,. ........... ; ..... ! . . . . . .
.... i ................ ! ..... i .......
;;;~:;]~]:]]~]:;~;;;ii]~_;i 711111...... J i .... :. i ::;"_ ....... i .~____ ..... :_:_: . . . . :____:::::. :
. . " . :;;";i. . i . ........
. . . ;. . ; .......
~...........
,;:ilj';,; ..... J.......................
ii J ............ i " .-:"
' - .................... - ......................................... " ............... " . i ~ ..;~ -.. " ....... "i I .... ;~;;::::~i:-;i ;;:;;;;:::::;::L 0
................. ................................................. ............... i ...... , -
1 L
m
[
l ! ............... :IEilI:IO-IHOlI:I/ snI:IOHdSOHd I~lOd ........... -
n ......:............ ..... i1 .... ~:....... i
t~.. .......... . ..... ' ;:;::~~i r ...... ~ :::~; i~ :,~:~:~~ ...... .~ ~,~1 l .... ~ ...... q I ...... --:oo
L
1~176l , ] i~ i
.__p, , ,

PCI5 PHOSPHORUS PENTACHLORIDE


I

03
. m

03
EL
(D
t=..

03
03
i,_
tt / J
!,.- ,J
o J
f
EL J
f
03
> I

J
J
J
J
J
7i
J
/
I
J

J
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

101 t t i t I I
310 320 330 340 350 360 370 38O
Temperature, F

216
1000
I ....
~! ~ .'r! ~ ....

PH3 PHOSPHINE
7

m
1 O0 ~ II |
_f
A, ..........i...........,_ J_ _i .............................................. | ................................................. _.
I /I i ! !
I 7 1 ! i t

t Y: F .... ....... .............................. i


|

. a

/i
K)
L..

09
09 10 i 9 t i I
(D
L_
I/ I I I
| !
|Y
13_ /I

F-I
t__
....../ 1 | I

0
(D. I

> ! i
/ ! i I, !i
/ I
I !
i t
!
t
I
i !
1 L/
v
I
Ii
1 1 |
! . . . . . . . . . .
!!
|
t

I !
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

ii !
i i=
0.1 I
-250 -200 -150 -~ O0 -50 50 1 oo 150
Temperature, F

217
1 O0

I ........ ! . . . . . . . . ! ....................................................................
PH4Br PHOSPHONIUM BROMIDE I
I
............ , ..........

. . . . . . . ~ ..........

...... ~ .................... ~ ~ e _ _
10- /-

/
. .,..

-i . . . . . . . . . . . . . . . . .

/
/
u)
. B

Q.
(D /

u~
/
(D
L. . . . . . L

L /
13_ 1
t=,,,

0 /
> /

/L, ,

0.1
/

/
~ ... 1

/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 -
-60 -40 -20 20 40 60 80 1 O0 120
Temperature, F

218
61E
-I 'aJn],eJaduJe/
o, o~- ot,- 099 - 08- O0 I.- 0~1.- Or7 I.-
I "~'~ I I I 1.0"0
' 1 1
....1:.....
BH u~uJ I.Z" Lg = ,~!sd L
!
I
i
z
L'O
I
i
li
<
i .................................
O
i
"13
i (1)
................... t
J
i r--
!
i (1)
w.
I'.........................................
i
OL
f
................................... m....... ~ imnml . . . . . . . .
....i I
I] 3CIlI:IO'IHO IAIfllNOHdSOHd IOt, H d I
......
..................................................................il
I....I...................... Ii IZIIII _F
......
i!
L - ............fILl J
I
' ~ ~ ~ OOL
100-
L

PH41 P H O S P H O N I U M IODIDE

I f
i /
10 r - 9

,=m

o0
c'J
(D /
L _

r
O3
t_.

13..
!,__

O - / ...........:
>
,S
/
0.1 . . . . .

,/ L ..... _~
Z
. . . .

/ E i

,/. 1 psia = 6 . 8 9 5 k P a
; / 1 psia = 51.71 m m H g

I
0.01 I i i J i
-20 20 40 60 80 100 120 140 160
Temperature, F

220
100 i . l . . . . I . . . . a " ~ '

//] . , ...... L ,.I,,..............


:..................................... I........
:ii................... ::..............
:::::i:i .......i , : : ........
]ii iiiiiiiiiiiiiiill
POCI3 P H O S P H O R U S O X Y C H L O R I D E IiIill--iiiiiii
iiiiii~iiiiii~iiiiiiiiiiiljIiiii~--:i
ii~iiiiiii~iii
iiiiiiiii
] I
II I

I _ ......i...... ii....iii__
..... I......... I__ _i ....- _ ......... i_

. . . . . . . . . . . . . . . . . . . . . . . . . . . i ............

im

L__

if}
ffl
I /

/
i1 ii_i!_iiiiiii_iiiii . i __
0
Q.
>

] ii i ii i .......... i ......... iiiiiiiiiiii l ..... iiiiiiiiii Jiiiiiiill i ..........

t .......
....... ii _iiii -- _ li _/ / - _ _ ii _ --__..... ..... _~_

I-__/I.__ ----

0.1 i ' I'


0 50 1 O0 150 200 250
Temperature, F

221
1 O0 ........ , ,
i
..... .... ..... ,,
I
....... ....... .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

!!!!!i!!t PSBr3 PHOSPHORUS THIOBROMIDE .....! !.....~ ~ ~ ~ ~~ ~~


. . . . . . . . . . . ! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i

. . . . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . . .

0 . . . .

.......... ! . . . . . . . . . . i ,, l , l/ .................. J

1 ..... 1 . . . . . . . . . . . . . . . . . / .............................................. ,I

........ i......... ....... ./iii IZIIIIII .........I I'IIZII~


/
m

j !

= m

if)
I ,, , / .......................iiii iiiiiiiiiii
1 . . . . . .

if) 1 . . . . . . . . . . . . .
.....
i. . . . . . . . . . . .
! , L i , ! J ........iiiii ~IIIIIIZIIIIIIIIIIIIIIIIIIIIIIIIIZZIZZZIIIIIj
,-.,,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J
! 1 ...................... J
13_
. . . . . . . . . . . . . ! . . . . . , , , /
1 ....
,! ........... i,, , / i

,/
=
l
0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

........... =- .................. .. . . . . . . . . . . . . . . . . . . . . . . . I

> i . . . . . . . . . . . . . . .
=
.

i i
i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i

t . . . . i'
i i

0.1--
....... i ..... : i / ii ii i
. . . . . . . ~ ,,.

....... ~ . . . . . . . . . . . . .

...... ,,,
..... ,

1 psia = 6.895 kPa


1 psia - 51.71 mm Hg
|

0.01. I I I i I
1 O0 150 2OO 25O 300 350
Temperature, F

222
100,_

PSCI3 PHOSPHORUS THIOCHLORIDE


I
m ,, ,

10-
9 ..... i-iiill' i iiiiiiiiii' iiiiiiiiiiiiil;i ~~ i iiiiiiiii-iil~!!!!iiiiiiii~iiiiiiiiii:!ililTiiiiiiiiiiiiiiil
, ::... ' .... ,. . . . . ~ ,, ~ i ii~~, ,
i~ :: ::: :i~~ ~::::::::::::::::::::::::::::::::::::::::::::::::::::~--~

u) ....... ]i............................................
... ~ ~ [
EL 1
.............................................................. 'I ................................................... }........................................................
(D
t.__
!
!

,I
! t
U3
U)
(D

/
L_

Q.
. . |

/,
L_

0
EL 0.1
cO
> iiili
...... ! ..........,_
.... / !
.......

/
! !

=,.............................................

0.01
._/!
9TiT~IIIIII/-
[
!
{ -,
b ,~i
l
iii/_~iiiiiii~iiiii
_~iiiii~iii:ii~i~i:i~ii_ Ii~ii , i t
| i
~,
- iiiiiiiii
.....
:i/
! ..................................
ii~iiii i ............................................................. i .......................................................... !

......................................
i ..... i.......................... i
1 psia = 6.895 kPa
, i
,r
1 psia = 51.71 mm Hg

0.001 I I
-50 50 1 o0 150 200 250 300
Temperature, F

223
100 ,

i
1

P406 PHOSPHORUS TRIOXIDE

J
/
10,
j ~ f

.,m f
03
E}.
/
Q~
I._

03
03
Q~ .l
m

....
t__

Q. //,,
.... ..........

,,i,,,i.......
L_

O
Q.

/
.....

>

0.1-~_- , ,

. . . . . . . . . . . . . . . . . . . . . I
11 psia
~ | ~
=~ ~6.895
~C
kPa
1 psia = 51.71 mm Hg

0.01 -
1 O0 150 200 25O 300 350
Temperature, F

224
1000-

ii
=

] .......... -. ......... ---

P4010 P H O S P H O R U S PENTOXIDE

03
I

03
EL
(D
L_

03
03
(D
13_
L_

0
EL i !
o3
> i

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

low
i
=

I I
! I
780 800 820 840 860 880 900 920

Temperature, F

225
10000 - iiiii 84 :iiii'iiiii:;?? ~ ~ ~ ......... j

9iiiii '~' + ii+i......... i!iiii!i!!i!iiiii+i+i~iiii~iiiii_+i+i~+!,

P4S10 PHOSPHORUS PENTASULFIDE Iii~iii~iiiiiiiiii 'i' .... i 'iii .....[+~ .......iiiiii'i'~ii'i~'ii'-i............


! ! .......... 15-++-,
I . . . . . . . -

.... . , , ;: ~ ~ ~:

1 . :
,. . .:.:

, ....... ;..i ;.i , ii .... i~ii ~ iiii,. ~ .;; ,; ....... i

~ ~ ......... ! ...................

-,-,, ,~ , . / .......... ii?i i~.,, i.,++ i, i+ iiiii+? ...............................................


+/'+ ..... + .....

- iii ~ ~ ........ ! ........... i, .......... ,. i . . . . . . . . . . . . . | ............................... J,


E ~ +
Z , , .......... + ................................... --.,J

100- i .... ii ............ ii 'i"+i iiiiii~

L.
. m 4

03
Q. ' , .......... J

- -/ +

(D
L_
. . . . . J

03
03 10
L_

13_
t.__

>
ID.
/ T ' r_____2

E.... /
i ,, , 9 . . . . . ' ......

I / L.................. i

4 i

........ I

0.1 . . . . . . . . . . . . . . . . .

F 1 psia - 6.895 kPa


1 psia = 51.71 mm Hg

0.01 I I
400 600 800 1 ooo 1200 1400 1600 1800 2000
Temperature, F

226
I O0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

10 ------

0.1~

a:l
.m

Q. 0.01
(I)
L_

09 0.001
(I)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .!.

13_
t,,,=
0
EL 0.0001
>

1 E-05
i . . . . .
T

1 E-06 i
!

t l psia = 6.895 kPa


1 E-07 1 psia = 51.71 mm Hg
.I

I "i
; J
.................................................. t
i i
[ 1
500 1000 1500 2OOO 2500 3000 3500
Temperature, F

227
8EE
4 'aJnleJadwal
OOLk 009 L 009 L 0017 L 008 L 00~ L O0 L L 000 L 006
I I I ! ~ ! I ~Lo'o
6 H ww i l'is = e!sd L /
ed)l s = e!sd L
/
.: ..... A:
rl J . . . .
J: /
. . . . . . . . . . . :
. . . .
<
/ li)
/ 0
i .......................................... / -
::L
i ......... S ... :[
' LIII 73
L-:: ..............................:....... i.,. :::., ,,:7':,.. :,..':::::::::., , ...................... ~ 71 !
(D
L_:::: - - ::: 21:111 :i:i,./
i ' ''- . . . . . . . . . . . . . . . . . . . - : L
i
C
.=.I
s
" ~i f 7
ll)
___::ii:i:i:ii__i_ii__~,,. -~ i,,. 7:::
-~ . ............................ -:
L
f ............. 7.......................... i OL
J
f
T
E
L ,i I J
i
3CII~0E18 CIV37 ~JSqd
:i ~ h O0 L
1 o0 ! !

i
! !

......! .......... !. . . . . . . . !

PbCI2 LEAD CHLORIDE


n ...... , ..........

/
f
10
[

....... i i
!
, i
i i
.... [

i I
, m

Q.

i i
L

CD
!,--

03
J

CD
L_
i
i
!
13.. -TP . . . . . .
t__
!
0 1
13).
!
> §
!
t

i
! !

i
t
e l l 1 ==JLm
...........
i
! :

, i i
l i i
i
I
i ................... 1 psia = 6.895 kPa
l
1 psia = 51.71 mm Hg

' ' !
!
0.01 i I I
1000 1100 1200 1300 1400 150o 1600 1700 1800
Temperature, F

229
Vapor Pressure, psia
0
o o o
0 0

o~
o

__L

o
o

(30
o
o

--I
CD
3
"tJ
(I)

c-
OD

-n

ro
o
o

ro H H
ro 01 o~
o
o

-1-
t~
ro
co
o

ro
o
o
100
~iiii "' "

11
_
Pbl2 LEAD IODIDE : 1
i

. . . . . i ' J ! , , . . . .

i ,

10 . i
[ i ' i . . . .
L I : i i : ........... 2 i: 1211............ -

,,m
u~
Q.

!
I__
!

I__

n
L _

O
Q. ..................! ..............................................
........................................
{ i
>
t I
9 1

! .... / i
i / '
I
T
i !
i L
0.1 ~__i-~___ - ..... .--~ ......... - .... --/i~i_ - .......... ~__i .... - ..... --- ~i _- ......... _ .... " __-~ _i-
' !.. ; i........... I
i .... /! .... !
9 !

I, i

II...
i !

............................... .:-9 psia = 6.895 kPa


p s i a = 51.71 m m H g
................................................

0.01 I
! i . .
i i I I
800 900 1000 1100 1200 1300 1400 1500 1600 1700
Temperature, F

231
1 O0 !
!
!

t
................... I
PbO LEAD OXIDE

10 L
J
Z

. m

EL
/

L_

u)
u')
......... 5 7
(D ./

13,. _ , /
L_

o
Q.
>
/
/

/
0.1
...........
./" '

/
/
/
/
/ . . . . . 1 psia = 6.895 kPa
/ 1 psia = 51.71 mm Hg

0.01 I I I
1700 1800 1900 2000 2100 2200 2300 2400 2500 2600 2700
Temperature, F

232
1 oo ]: tt ~1 !
!

I ...... I
! .... I
]Ti;il;illllllllllll;illlli,l PbS LEAD SULFIDE _____,
......................
1- ...... I .....

t-
o : -= !

] I '
!
I

Ill
L _

if)
(D
t ii

i
!

i
i
i
I
'
L _
i ....................... T! ............ i'!
13.. i .,' ' i '
!,___
i , [
0 " r t
Q.
I I
>
t i
i 1

0.1 I
i
9 '
i
i .....................
!
t !
I
i

i ..................... i ............................. i

-i--------~-/---i r
i--
i
i
i

i:

i-1
,!". . . .
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

!
O.Oll
15oo
i 1600
i
I
1700 1800 1900 2000
i I
21 O0
i
I
2200
I
2300 2400
Temperature, F

233
100 !~p~

Pd
10
,i

1=

0.1-

. i

l/}
Q. 0.01=
(D
L._
m

09 0.001-_
(D
L__

ii

I,..

0
Q. 0.0001=
>

1 E-05=

1 E-06_= .=
,.=

-i

1E-07~ ......................................... ii~1 1 psia = 51.71 mm Hg ......................

1 E-08-
1500 2000 2500 3000 3500 4000 4500 5000 5500 6000
Temperature, F

234
1 O0 .......................................................
----.------...--..

--.--.....--........

POLONIUM

10,., ,,u,,m, mm,

0.1
" : -V---zz" T "
- ~ :,z T i
- - - - - - - - ' ------ t 1
.m
! i 9
09 0.01 = ' "--~. , I

L_
: ~ '~,
I

r o.oo1-======.~ I ! i
(2)
" | .........................................................................................................

0
O. 0 0 0 1 -
= i . . . . . . . . . . . . . . . . . .
J,

> ---- J'j ~ "" i" t -.......................................


- - - ~ ~ l.....
...........................

ii T] i 'i i

- - - - - - - - - - T - - 7 - - - ~ T - - - - - I - ~ [. . . . . i ....

1 E-07

200 400 600 800 1000 1200 1400 1600 1800

Temperature, F

235
1 O 0 ........................................ i ........ ...?.. '...'. '_ .. '__: _-: . . . . . . . ~.
[

9 I 7 ............. ! i' ............... "


- I Pt PLATINUM i

10 ..... [ _ ........ :. .... ..................... '

] .............................

i ~ ...... ~],'- .....................................

[ ......... / .................. J. . . . . . . . . . . ---;

O , 1 ~ 9 . "~'~' . ' '

i "
f

. m /
c~ 0.01 t ............ ...................
_ _- _- : z ~ . . . . . . ._ . . . . . . . .

- ..i .... - . . . -- . . ./ . . ..........................

=9

o.ooi
-: ' . ~" _ i
/ [ r
. . . . . . . . . . / 9 .. , .,
. . . . . . . . . . . . . . . . ..........
n in ~

0
c~
0.0001
/
_ i":- ,...... ~7~,~,/ - ...... ! .... -- _...........~,.~,,- ', ....... i : : ~ : : : . : : : . ..............

> .... :/.


._ ..... /: ; ........ _

~ /~ [ [ [
/

1 E-05-- _
-
:
: .. z
.-
......
~
:i . . . .
~
. . .
~ ,,

. -~ ........ / -- .: . ~ ~ - _ ,~_

-- " / ] l .......................... ' .....


/ ~ [ ....r

1 E-06 _ - :__:::,;;;:~:,~
-/
;, ~ ~- . . . . . _ ' __ _~_
~ _ ,...,:,.:
[ .... : _ -- _ . _ , ......... _ u ~ =
r-
~.-;7;I:;:LZZZZZI;ZZZIi

A
!
: ....... . . . . . . . . . . . . . . . ..................... _,
/
_ ....................,
i i ' i
I i 1 psia = 6.895 kPa
!: 1 psia = 51.71 mm Hg

! "i
" I . - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

I _ _ _

1 E-08 I I I I I i i i I
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000

Temperature, F

236
100=

,oi Ra RADIUM

1=

0.I-

on,m,
u)
!
Q. 0.01-

(1)
l&..
:D t
09
u)
(!)
0.001- L................................................]
I
IL_

n t 1
IL_

0 I 9 |

0.0001 =

1 E-05-

il ................

1 E-06---
4

,-------
1 psia = 6 . 8 9 5 k P a
1 E-07= r ............
1 psia = 51.71 m m H g ........................

I
.... ===

i !
1 E-08- T I l
500 1000 15OO 2OOO 2500 3000
Temperature, F

237
S E E
-I 'oJnTeJeduJa/
0017 L 00~ L 000 L 008 009 OOP 00~ 0
I J J I I I I ~ ,80-=1L
.......................................... .. . . . . . . . J
................................... ............... '....... 1] 1] . . . . . . . . . " /
, I
............. "_ i. ' ..... ' !
............... I . ~ .... ,. . . . . . . . . . . . -" Jr
. . . . . . 9
13 H u J L u I.Z'Lg=e!sd L ' ,.... ' 'i " " .: ........ "
::: ! ....../: I LO-=IL
edM 968"9 = e!sd L
.,. ; ! __
9 ! ...... ; . . . . . . . e
................................................ .. . . . . . . .
... ,,, .... r /
..... -
................. ' _ ............ .... ! .-
.......................................... ... :[ ...... - . . . . . i . . . . . . . . . . . . . .
....
.., ! /
..... .........
/ '-90-=1 I.
........
.i
/, " ..
'_::::_:::::::::::::::--:-::--: ..... i ............... .~ - ........................
........="':-'---izii:z111~:---:-:::-::_ ::_:_ " -.-:--.::::: . . . . . . . . . . . . . . . . . . . . . .
... ' , , / ...
...... .................. i ......... - i : ........... -,,!!!i ..... . . . . . . . . . . . . . . . . , .........
.

7i::::::: i:: ,,
~/ ~;0-:I
I.
_ . . , , _ ................. . . . . . . . . . . . . . . . . . . .
. . . . . . <
. . . . . . . . . = 1.000"0 "0
............ =.._=_ .....
0
........................... .. . . . . . .
9 .

/ ,
-0
zzzzz:'.-.Z.z'_'zz/_z:'_'_'_'_.................._ L :: . . . . . . ,,,, """ , ..... , ,,,,h ....
: ............... . ....... " ' - ..... :---::: .......... ----!--:~!i;::;i~ ........... --:;;-i~ .................. , .......... 9 ' ~ ...-- '
" ,...' ". . . . . . . LO0"O
f~
c-
......................... 9 9 i . . . . . . . . . . . . . " / ....
:::::::::::::::::::::::::::::::::: ... . . . : . . . . . . . . . . . . . . . . . . . .. 9 . /
......................... ~ ............ i, '......... , , , i ..... ]
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . '"v - . . .
J . ....... . .
,,Zi/- - _ ....
"I '
"0
----- / - .......: LO'O
m l
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I #.,...
............:...... - = = - ............................... / '
....................................................:! ........... . . . . . . . '...... .. . . . . . . . . . " . . . . .
. . . . . . . . . . . ~ ..
.............................................................. . .... ~ . ,/.ill ..... . ,
................. ------.. .... . ..... . .. "._.:-.~_.,~._.__.:;.:.;..::_:_::_::_ ........ ~__ :-::~ . ..... .
.... / L'O
.......
f
/ " ,
Z : : : : : : : : : I L . ~ . . . . . . - 9 . . . . . . . . . . . . ....... ~ . . . . . . . I"
.-- . ~ , , ,
. . . . . . . . . . . . . . . . . . . . . . i.:'" i "" 9.,, . . . . .
T
........ ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........... _ ......
....................................................... ] NNICilSNI::::I q ff
1

RUBIDIUM BROMIDE

10- ..--.--.----------

, m

(/3

(1)
:3
(D

&=,,

(1.

0
c~
i T
>
i

0.1 T T

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.011
1400 1600 1800 2000 2200 2400 2600
Temperature, F

239
100
I

RbCI RUBIDIUM CHLORIDE

10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

o m

(D
t._

O3 /
(D
1 ,A
w
L_ /
EL mR,
t__
m
O
Q.
w
/
>
/
0.1 /
/
j
/
/
.....

/ 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01
1400 1600 1800 2000 2200 2400 2600
Temperature, F

240
100, . , 1 ,,, 1 ............... '1 ............... l .......... ! ........................................................... !
9 . . . . . . . . ! 1 I I iiiii , iiiits 7- I7 ............ iiii-i ................................................................................................................
_iI i ii|' " ....... ' ' CZZZ !i+ii 7 Z I ......... i i ] ................ 7 1 7 . . . . . .
] ........ s ! IC__il iiiiii i ....... " .................................................................................................

I +! ................ f ................................" ....... i ..................................

_ i 1 i i 171111/I'7111111171
.......iiiI........................Z2111111Ziii,iiiiiiiiiiiiill

! I 1 .... l ................... ! ......................... ! .......... . ] ~ ................................... |


~i . . . . . . I ..... i .............. I. . . . . . I ........................ I - - - - - - - - - I i- ...... ~7"-T--------T
1 7111 ii ~ 7111i ~ I , ~ ...................! .........................!. . . . . . . i ,t-+7"~ ........ F ' - - - - - - ~
] .................. i .......................... I + ~ .............i--------] ............. [ ~ ~ ...................... r .......... i
._m

Q. ............... F ..... ~ ..... T- ................ ------I


_1......... 1............. ! ....... I ...... !................. , .....- ~ ..................~.......................[+ ,

In I i i i
: ] ................................... ; : ] . . . . . . . . . . . . . . . . . . . t ........................... +...................................... J r +
.....................................
I----V----
r----~r ...... -r--------t
+
]ZZZZZTZ311:III~i:Z::I::I
~:: C ~ . ' - 7 " I i' ................... ~ ................. "i" ........... i
L__
..................... ! .............................. !_ . . . . . 1 2~'I
. ................... +I . . . . . . . T! ................. i T

0
9

Q. I ................................... ' ....... s [........ T............... --i i


t
................................................... 7 ...... -! [ .................. t ....................... i
>

I! l/i
-~i ~ ............~7 ................
........i..... ",, ',, :1........................
/ ......................................................
il,............................
-.
I,.......................
i,

] =YZZ77 Y-Z:! : ...... ::Y Z ZIZZZ'-'-'-ZZ~-'-ZI]ZTZT-'-'-ZZT'! .................................. [-- I ~,


7--Z77777 .......YE7177.........Z7 Zs s i_i_ !.71 ___iiiii I_ZI---, . . . . . . . . . . . . . . . . . . . . . . . ' !
] ii 7_i l !..........................
...... ....................................................................... [~ '! .......... '

......................
........................... ! Z
i v .................................................
.........................................
! ..................................
~.................................... i
i
_-, . . . .
1 psia = 6.895 kPa
1 psia = 51.71 m m Hg

-I !
i ........... _...........

0.01 I
J
I
i1
I

I
I

I
1600 1700 1800 1900 2000 21 O0 2200 2300 2400 2500 2600
Temperature, F

241
100_~
i~ii~iii:::iiii~iiiiiiiiiii::::i::::i:iii~iiiiiiiiill
ii~iiiiiiiiiiilii iiiiiii:~!iiii
Rbl RUBIDIUM IODIDE

10
i~/-: i,_,_.,::.1
....... L ; ................
_ ,ZI~I iiiiii

(O
,,m

Q.
(D
I,.,..

(o
(o
(D
13_
L_

0
Q.
>

0.1
/
/
/ i

.....
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 i I
1200 1 400 1600 1 800 2000 2200 2400
Temperature, F

242
~.=:::!::?~ ............. =!~!::::~ ..... ?:!:?::1::!?!_~!:?!:!_!__!:_!!_! ..............................

l -! , ! '
I
~IIIYIII i i YI[I IIIIIII:IIIIYIIIIIII]IIIi ii i i i i%::::::i:i:i:::: IIIIIIY:IIi
9 ii ..... --I
, . . . . . . . . i~e RHENIUM

::::::::::::::::::::::
............ .... , ::

i
i .... 1

)*'*:, _5: ::: : _......::::L:: " :__I

1- j-

; ........ ..... :iiili i::::i~ :!~i ......... i ; ........ i ;i ..... ,,i .......... :J
I . _ '" ! "

0,1 t ..... )' ...........I . . . . . . . .

! :: :::::L . . . . . . . . . L:i:ii:L:L :_ : . . . . . . . . . J1: : :i LL : . . . . 51:L2:i : i :: ::. . . . . . ::I: :/#" Y: _ ii2L Li . . . . . . . . . I]___I_L2LLL_.__LLLI

Ii ......... . . . . . . . . . . . . . . . . . X . "............ ,.! .............................. i ...........................................................

Ii iii.......
LLLLIIII .....i....LLLLI__ _ ii/_!LLL__]ILLI ........................
] ............................. l

c~ 0.01 ! .... .... /L]IIIIII]


.......iiiiii...........1 ...........................

I : :: ......... LL L__ .............


[LLL::/ .......... :T: ......L!:L:L: . . . . . i

I L l~ :L I : ~ ~ ....................................

(B
co 0.001 !......... ~ . . . . . . . .

i~........ kk_. ............. -:__


...........
_[...........................
i ,
~---'===--I =. . . . . . . .
,
i...................................i...................................

==-'~ . . . . . . . . ~
i . . . . . . . .
(D l. . . . . . . ! ............................................
:: __l . . . . . . . . . . . .

n
I:]:::]]]:L:::::/_:.......!:::::::iii::
ii i ]_i:i ..... i
0
O. 0.0001
>

i/ 1 " -'I .....................


.........~ . . . . ~ ~ I:
r
i
I .............................. . ]

1 E-O6 i [ , ,

1 E-07 . . . . . . . . . . . ! . . . . . . . .........................................
'=:::~::: 1 psia = 51.71 mm Hg
::: :::::::: ...... :: ) ,
::::::::::: :::: :: :::::::::::: ::::::: :::::: : : :
:!:::
:) ......

:::::::
:_:.,::::::
:::::::::::::::::::::::::::::::::
:.r::::::::
::::::::::::::::::::::::::::::::::::::
:::.___::
:::.r::::::::_:::
:;::::........

] 1
...........
::::::::::::::::::::::::::::: ,, 9 _........................
_ ] .............

!
i) t
1E-08 I ' i I I I
4 5 6 7 8 9 10 11
Temperature, F
(Thousands)

243
Re207 RHENIUM HEPTOXlDE

/
J

10

f ...........

Q. /
/
/
(D

/
CD ........ ,, .~,

13_
/
0
Q.
/
/
>
/
0.1 /
J
.... / , , . . . . .
.............

/
r

2,/,,, ~L
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01
400 450 500 550 600 650 700
Temperature, F

244
100-~ ............ I

9 i ! :: .......

~: ii :i: il:iiii ill


RHODIUM
! I
] _:::ii::::iii
Rh . . . . .

~ol . . . . . . . . . . . . . I ~ ........

- 1

0.1- ............... ~ . . . . . ~ = : = . = .........- = ~


=

, m

A !
0.01~.

,/~i~iiiiiiiiii~ii~i
I. :iiii:i ]........
ffl 0.001 -
_
i ~ , ! 1
n_ ' [IIIY ii 9 IIIIYI i t' -- - -
I ! / ! '~ . . . . . . . . . . . . . . . . . . {= | i"
o [ ! i .....................................................................................................................
i...........................................
1............................................
i...............................................
0.0001 _

>
/ I

iiii ii ii ii iii iiiii/iii[ii iiiiiiiiiiiii iiiiiiiii


..... iiiiiiiiii ;~!...............
..... 1111 i ..... I i ............................
I.....................................................................................

1 E-05~
! } ! .... [ .......... r
9 :i: i:;: ::i ! ~ ! | i| i |
L / | . . . . . . . . . . .
/ t ! .
' . .
! . . .
1 .
i
i
m _ _ l

. . . . . . . . . . . . . ..L- . . . . . . . . . .

,, f t

|-
i lpsia= 6.895kPa
|~1 1 psia = 51.71 mm Hg

.............
...................................t.:~.:~.:.::.~.::.::.:.::.:.::.::.:.::.:.:::!::::::::::::::::::::::::::::i'"'l
i ........................................................................... ::::::::::::::::::::::::::::::::::::::::::::::: ,_ . . . . ,
!
__:Ji:...... ii i

I I I I

1 1 ! i
i
1 iI
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000
Temperature, F

245
1 O0

l ! ! ! ! !!!i
. . . . i i i _

Rn RADON , ~
i
....................................
i .....

i j P

10 ,i
v9
r i

.m
/
C~. /

/! J
CD
tm

(1)
.........

13.
/
. . . . . .

0
CL
/
>

y
0.1~
/
/
/

// /

1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

0.01 I I 1 I
-240 -220 -200 -180 -160 -140 -120 -100 -80 -60
Temperature, F

246
1007- .... ; :=-=== .......................... ~ ......................................:.i.........................................
; ~. . . . . ;....... ---,

9 ............ t .t ." . .

] Ru R U T H E N I U M i. '
] ~~ t+ '
j

] J ! ..... i ! ..............

3771-7T .i ! ............ . I . . . . . 1 ............. !IIIIIIIIII;IIITIII


........I t L . . I I I I ..............iii~..... ! . . . . . . . . . . . . . . . . i ........... / _~. . . . . . . . . . . . . . .

qiiiiiiiiii:ii:;il,
/
,i, , !:
:~ ::~:: .................. tI . i ................ , ............................... !- ...... ~
" ~ "
....... ~: . . . . ,: _ _ _ _ _ _ . _ _ _ _ + "
.........
9 'i . . . . . . . . . . . . . . . . . . i .................. i ..................................i - - - - ~ ~ ' ~ 7 " ........ ~. . . . . -I, . . . . . . !..........

]........................................ / i,,
- - .......................................
~ ~ ~ , - - - - - - - - - - - i . . . . . . . . [. . . . . . . . . . . . . . . . . . . . "',~t ........................ § ................................. § . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . .
I 9 ! 9

i .I ) i !
,

i I: . . . . . . . . . . . . 9. . . . . . . . . . . . . . . . . . . . . ~ ..............................~ ..................................
+ ................. ~ .................

.........................................t ! _ ._,___ .......... ~. . . . . . . . --~ , '9 ~,.'.. . . . . . . . . . . . . . . . . . . . . . . . ii .................................


i i ! ......................... i~...................................... ~...................................
i .................. -i ....... ~ .....i ................
9

.m... .... ! , r ............................ r ........................... I ............... i ....................


i):
t ! / I ! , I I
. . . . . . . . . . . . . . . . . , ..............................., ...............................~ ..........................................................................
, ................................
., ...............................
0.01 = " ' '~ : - : = ' + .~' / ~-
" _-.
' ' "

;;;; :: ; '
:i;- .I.. l i,
' ....................................
~_----_-7_;___---_; t - - - - i: +
,i .V."?" . .
(D
I,.,.
~'-7 7;; ;_ I .
........................ . . L J
. . . . . . . .
,--------+-----.. . . . . .
7z_~
. . . .
..it.'......................
...................
-.:i,-.................
...................
t~' ..............................
................................ i'
~, ,i . . . . . . . . . . . . . . . . . . . . . . . . .

O9
o.oo~ ~,.iii~77!7!~ii!!!iii17!--i!!i!iii,~:_4 ! '
~ -,~ ,,,.,,,,,,,--,-.~:.,.:~-.~:~-.,.-T--~.~:.~-.~ .~-..~-.---::..:,~.I:----~:.~:::::~:::L~
~::: ======================= ::=:::::,.::::::.~::
[~:::."~
,.'::::
..-:::
::::1::.~:::-:::L,:.~:::~:..~::::1
~.-~:,:::.~,.:
~ ,.~:,,~-:::.::::::::::::::::::::::::::
+~ - - - - . ~ " ~ ~.~ ~ .--..~--__-7:i,..':L--"_--:- 7..--"---"_7" "...+.,:'7:7"-"..".."-"..".:::::.".~::::::~::~:::."-:."-.--.. "."--..::~ .-..-.':~,:<~~7:_-:.~:"_"E"...~.~:T-:: ~ 7..-::::::~ ..-;----".-.-" ."Z:::
(D ---- .... 4 - ~ .............................~....................... 4 . . . . . . . . . . . . . . . . . . . ~ ......................
.................... - ::=--=- :-: ......c" ................. . . . . i ;i t ............................ -" ....................... "~..................... "i'.........................
' L ~ '- . . . . . . . . . . . . . . . . . i, . . . . . . . . . . . . . . . i'-. . . . . . . . . . . . . . . . . . . . . . . . . ~, . . . . . . . . . . . . . . . . . . -i ,i . . . . . . . . . . . . . . . . . . . .
13_
-- ~ : i I , t I
i-............................. ~"............................... -!-. . . . . . . . . . . . . . . . . . .
!
~. . . . . . . . . . . . . . . . . . . . . . . .
0 i i I i ~
i
,
i
0.0001
.i . +..--, ................... " ......................... +..., ............ .-.-=~ .......................
- :: i"=---~--~F=-~::i'-- ................ :i:":"----" "::::='--='':'::: " = - " - ' " = ~ - ~ ! [ ! . ~ E ~ E ! E ~ . ~ : ~ E ! F ~ - ~ ! E E : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : - - - - ~ = .............. : = . . . . . . . . . . . . . . . . .
t'l:l _3 :-:::-:~=-::~;~;;;~;;~;~;;;;;;ii;_-:::;;;;;;;;;;........ ~ t _ . ~ - z ~ . : ,, ~.................... ~..........................................................................~ ................................
> - - " " ............. ....... i' ' '~.......................... ~.................... ; . . . . . . . . . . . . . . . . ~........................
I . I

i i i [ .........................
~! i

- ' i ~ ,, . . . . . . . . . . . . . . . . . . . . . i,. . . . . . . . . . . . . . . . . . . . . . . ; ............................. ~. . . . . . . . . . . . . . . . . . .-z-:..-i, ........ =:===.--=-.=.--.


1 E-05 .r.::::;" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ====================================================================================================== ....
~.-----------I-.:.~,~ -4 ............. 4 ~. ....................................................... ~. . . . . . . . . . . . . . . . . . . . . . . . . .
-_ ,----z: .-7.------$
......................................
~-----.
. _ '; . . . . . . . . . . . . . . . . . . . . . . i i
- ~ q .................... i
,
+
,
' + ............................ ,
i,..
- I----'-'-) i 'I " i ........................ ~. . . . . . . . . . . . . . ~ ........................
........................... i ........................ --q ~ i ~
- ti"- ~- / .................................................
i 9 I, ,i !"I ................... ~",~...................... II [::..................

4 .....................................~ - - - - " t ~ ..................... i ....................................) . . . . . . t ;.............


i ..................................................................................................................
........ M. .... ,,,..................
--i! ] +i......................................
, ,>,,, = ,,>.
1 E - 0 7 =~~.---=-.-==:=i.:.~=:_-i,' ..................... =-i'-"::=:~'.'EL--.'F-: 1 psia = 51,71 mm Hg :::::::::::::::::::::::::::::::::
~t.:::::=::::::::~----~.~-"--" .~"-- ."~ i: .;. . . . . --,7 ................. ~ : ~ . : . " ~ " : . ~ ......... : ::::::::::::::::::::::::::
9 ;;:; ;: ; ;- # ~ .......................... J I, i .
~!--- 7 -71 - / I ........ ; ;.................. i'. - ' - - ~ - - - 4 . r - ............... T ........................ i ................... J ..............................
q ...............-# i i i 1 i i .............................. ' ........................ ~'......................... ~............................
.................. " .................. i ..................... ~ ......................... i .................................. 7 , i I ) i
i
1E-O8/
I I I i i ' " "
i i i ..... i , ..... i i ........... I ' .......
3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000

Temperature, F

247
10::L__.___J _|

"1 P----- !L------ l , 4


RuF5 RUTHENIUM PENTAFLUORIDE J__. . . . . . . .

................

...... ..

I j
I "

/
. L

tO
(/]
13. .I
/
:::]
(/]
/
0.1 ./
r./
13_
//
0
13. /
;/
t~
>

/
7

0.01 u 9

- / I

_ / _

c v

1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m Hg

0.001-
120 140 160 180 200 220 240 260 280 300 320
Temperature, F

248
1~176176176 i ----I
SULFU _...--.

1000

100=
u
m

; T
I
u m ~

t1 '
I
.

(/)
m 10=
't
C). ! t
(D
IL_ ! .
I
O9 1
r 1=
(D
I,..

n ,.~
t ! :
I..,

0 [ j, '
CL
". ~ ' 2 ~ i !
> 0.1=
'7
_-~._::.~.'::.~.-.'..':::::::~2::.~Z:::::.'::Z::":.-.~:::::::::.':.'2::~:::~ Z~ ~
.~....................................
~ ~:
~ ...................... t ........................
j: . . . . . . . . . . . . . . . . . . . . .
It....................................
~.,
j

I
,i.......................... |

. . , m

0.01
i t ,

t [ .......................... F ............................................i

I
[
!
I

0.001

]
t .................................... ' t 1 psia = 6.895 kPa
---------------4 - = ........

I t 1 psia = 51.71 mm Hg

, $ ! 9
!
i

0.0001 1!
[ l
i l
!
1
200 400 600 800 1000 1200 1400 1600 1800 2000
Temperature, F

249
10 i ] ................. ]
! 1 ] ........ ~. . . . . . . . . . . , ................ .. ............

SF4 SULFUR TETRAFLUORIDE

o3 .................. i,....................................../ .....


Q.. ., .......................................

&-,
c}
o3
o3
(D
K.. ..................................................... I ............................................................................

I
K.,
O
13.
>

0.1 iii!i iiiiii i . . . . .

. . . . . . . . . . . . . . . .
i/
i
................................................. / .....................................................................................................

.....................................................
T.......................................................
i.....................................

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg .......................

, ! .
0.01 I I I t I i I
-1 8 0 -160 -140 -120 -100 -80 -60 -40

Temperature, F

250
1 o00 I I ,, i i.
, ...... ~.......... ! ...................................................

......................... 9......................................~ ............................... 4 ..............................

................................................ ; .......................................... -f" ................. f ....................... -i . . . . . . . . . . . . . . . . . . . . . . .

] I , ! i
, z t'~
,
]| . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~i : . . . . . . . . . . . qt 9. . . . . . . . . . . . . . . . . . . ,z
$ .............................. ~ i
:. . . . . . . . . . . . . . . .
~ !...........................
9

I I i
!i !i /
~ i
il
i i E i i
--

__l. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ------+' ........... *' ...................... ;.....~ ............!'............................. i'...................................


I
I: i! A/i !l il
i J /i i i
i I ~ ! i i
, l I~ i I i
- ~i ...............................
~i..............~ i
............................
!i............................................
4!........................................
ii .....................................

i i i " i I
E i i i ! !
! i i i i
I i ; :. ". i

, i i z i !
i ~ i i i i i
if) i l i i i i i i
100- ~ t. . . . . . . . . . . . . . . . . . . . .

::: ::::::::::::::::::
~ ~ ::::::::::::::::::::::: ~ ` ` ` ..............

f l
I,.__
0 - i------

i
............................... ~ .......................

i
: ................................................................................................

i
-.............................................

!
-.......................................

i
i ., i i i
- i, ................................ ~ .............................. i .................................... , .......................................... : ............................................ 4 ............................................... ~. ..........................................

> ! ~ i i i i i i
.!./_ .................................................. i .......................... 4 ................................. ~........................................... i .............................................- ............................................ ! .............................................

-7,/. ......................... ,, i', "


i ................................ i_~.~..._..___...__....,

. . . . . . . . . . . . . . . . . . . . . . . . . . . . ~' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ................................
i I
9 i
!

I
ii
|
i
9 . '- ..........................

i
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

'........... - .................'i
i
i
i
i
t
i !i ! !
10 i I I
-60 -4O -20 2O 4O 60 8O 100 120
Temperature, F

251
100: IBm
ellm
;m

i
SOBr2 THIONYL BROMIDE
. . . . . LI, . . . . .

10

/
.m

Q.

f
(1)

CO
CD
/
.. /

n I I I

0
Q.

>

0.1

/
/

,/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01-
o 50 1 O0 150 200 250 300
Temperature, F

252
SOCI2 THIONYL CHLORIDE

,,I
09
0.1
(D
l_.
rn
rn
(1)
!._

13.
0 0.01 ...................................T ....

>
i I

0.001

0.0001 - ..........--.--------.--,...----

H ~ I P~ia
I ~ 51~
] mm g

! ......................................

1 E-05- i ! ]
-200 -150 -1 O0 -50 0 50 1 O0 15O 2OO 250
Temperature, F

253
t ....I . . . . . I..... s i......................................
J
.......................... ' .....................................
' ......................................
J ..................................

. . . . . ]" . . "~L- ~ . . . . . . . . ] ...........

SOF2 SULFUROUS OXYFLUORIDE I ......................................


J....................................
i
I

I
i
. . . . . . . . . i ................

1
!

...................

........ - ~ ~
. . . . . . . . . . . . . . . . . . . .

. m
ffl
.......

.... / " 1
ID ,/ -I.................
/
J i

i
L _

J
0
I
> I
/' . . . . . ................
_
/"

/i ......................................................................................... -1

ml
/ [
/
/
L

1 psia = 6 . 8 9 5 k P a
!
i

!
1 psia = 51.71 m m H g !
I
I
! i

!
I

0.1 I I
i
I I
-150 -140 -130 -120 -110 -1 O 0 -90 -80 -70 -60 -50 -40

Temperature, F

254
10000_, .................. , 9 ,
-T:I ........... Z-I ......... I ......... --!. ........................................ i
J i I
311ZZZIIIIIIIII I
illiiiii:ii:iil;ill I SO2 SULFUR DIOXIDE
................... L

J
! ...................... |

~ZZII~II i / ..... iiii~i . . . . . . . . . . . . . . . . . . . . .


.t

i l
, i
|
l
. m
i
................ !
1O0 _ _ !
. . . . . . . . . . . . . . . . . . . . . .

J_.........ILIIIII ZZ ZLI::{...............................{
(D ' / !
J

ffl i1 {" i
L_
iI [! !

O_
|' !i
ii ii
!,___

0
10
>
s /__~ l i
!

~, t i-- i
i/__ i l
i i i; i
/ 9 ! i
t : t
I
t ~ "! ' !
, ..........................I_L ...................
l.......
. " i

l|
[ l I 1 psia = 6.895 kPa

! r '
i 1psia=51.71mmHg i

. . . . . . . . ! ........ i .i . . . . . . . . . .i . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . .~ . . . . .
: i i i
! s
i
! ! i i ! ~
0.1 i I I I I I
-15o -1 oo -50 50 1 O0 150 200 250 300 350

Temperature, F

255
1000 {
!

! /
S02CI2 SULFURYL CHLORIDE

1 O0
/
J
i

/
/
/
. i

U9
Q. 10~
/
....

CD
t.._
f [

03
I
09
/
/
(D
13_
t._
O
/
/
> /
/
/
/

0.1 "'"
/
i
/
9 /
J /
,,,

i ...............................................

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01
-100 0 1 O0 200 300 400 500 600
Temperature, F

256
loooo~ L_
~03SULFUR TRIOXIDE

1000-

t i -----~----~,'~~--
(If
,,, m , , , ,

Q.

'i L
(I)
Ii,,..

100- T [ . . . . . . -::::- . . . . . - - = - = - = - - = - : - , - - , ~

13_
i

II,,..
0 !
C}.
>

10- ,=

______--ff
i
. .
,.t
==

1 psia = 6.895 kPa


1 p s i a = 51.71 m m H g

1 T l [
50 1 O0 150 200 250 300 350 400 450
Temperature, F

257
100 4
............
!.........................................................
"i'
{ i i........................................
i
~ i
..............................................
,
, .. . . . . . . . . . . . . . . . . . , ........................................... ::::::::::::::::::::::::::::::::::::::::

$2CI2 SULFUR MONOCHLORIDE iI.......................................t[..............................................


...........................................

..... ,~

i ............................................................................................... i ...................................................................................................
........................................................ ~ L.................................................. i...................................................
I

F
10
............. : : ....................................................
_ t ..................................~ ' ~ - - ~ . ...................................
J.........: . . . . 7 .......................................
[.......................................................
i............................................................

ffl L_ ....................
. . . . . ... .. . . . . . . }" . . . . . . . .. . . . . . . ... . . . . . . . . . . . . . . . . . . . . ~. . . " i ! --i ~-" ........................................
......................... p,

/ .................................... ,

Q
//
7 .~............................

!,___ ................................... e ....................................................

/
9 .. /
0 A .......................... ~ ....................................... ,

>

i..................................................
i....................................i

0,1 :--:::Z':'Z;Z.';'Z"Z:Z:"...........
I..............................................................
'

. . . . .

--t;;-;;..............................................................................................

- / i1 psia 6.895kPa
. . . .

r
I i 1psia=51.71mmHg
! I

0.01~ I
0 50 1 oo 150 200 250 300
Temperature, F

258
100 .================================
. . . . . . . ::::::::::::::::::::::::::::::::::
. . . . . . . :::::7 . :::
. ::: I:::::::::::::: : :-: : : : 7 :.:.:.- . . . ::11 :: =========================
:: . . . . . ........................................... i ~ . . . . . . . . . . . . . :: ........ = : = = = = : ......... : : : : : : : : : : : : : : : : : : : : : : ........... = =

]17!!:!-i--i-i
---;~ iiiii,
..... ......... ' i
21:::::::::::::::::::::::::::::::::::::
Sb ANTIMONY I

10 ..................... ~ ~......................................................4:.......................= - : = = : : :
~!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!:::::::::::::::~:I: .............. :::::::::::::::::::::::::::::::::
======================
:77:: 1__ :::: :1::i::::::71 : :i ====================================
!--7
................................. ' .............................................................................. }--
J :::: ::::::::::::::::::::::::::::::::: _ :: :::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::: . . . . . . . . . . . . !
!
]
!

| +

I
0.1 I.-=:..~:.-...-m.~_.-
~ .-..-T.::==.~= ~..m.=:::..--.::.---.::::=.Tm..-..-=:~

. .....

09
Q. 0.01

(D
:21

09 0.001
(D
I,..
13_
L_

O
ID. 0.0001
>

1 i I
1 E-05 ....... | ........................... 4 .....................

.i,l i' '."

t
{ I :'
I t
! ! i
1 E-06 ~::..-".-'.'~
..-':~..~--. = = .-...--...~."-=:~:::..n'_.--~.:-~:::...-'~--:=.-.z= .T.:%-:=..-:z...-.~-...-::..---'T_-::::
.~::.':.::::
:::::::::::::.-..
~ .m.::::::::.:=
"7.::.~:::::=::= :::::--~:::= .':.::::::
z::::.':::::.':::::
::::"::
:9 ~
. : .- :
9 |
T t
p ...............
i| I 1 psia = 6.895 kPa
t
1 E-07 1 psia = 51.71 mm Hg
i . . . .

,
]::Z:i:Z/:il ..................................
-i !.......................................................... i
I I I
500 1000 1500 2000 2500 3000

Temperature, F

2 5 9
1 O0 ,,, . ; - . . . . . .
!
=_ . . . . . . . . . . . . . . . . .

I
SbBr3 ANTIMONY TRIBROMIDE ...................................

Im

10 _::_ .: ;ii;. ;;; : ;;; i t"


S .......

Lf

S
z
,,m Z

O3
O3 /
E
L r
1 ,
L
0 /
> /
.............

0.1
/
;s
J
l

/
i . . . . . . . . . . . . . . X

/ 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01
200 250 300 350 400 450 500 550
Temperature, F

260
lO00j . . . . . :_ , ..................... , ............. , ', ............, ............ : ............. , ................................... ,
]
i I J. . 7::i :Z II :I!- :F- :F ill..... ii.......... 17Iii .... ii.............. IIIZTZ',TTT-:7-~.....:ZZI .... !Z .......... :FZ777 IW! .... 7:2:2_-_-_-_-_-_-.:_-_::_-::_-_-_-]
1 , ' ...... ' : ,ii i1 iiii i ii iii iii ] i IFIIIIZIIIIZIIIIZIIZIII77711111 ........... iii I17 IIIIIIIIIZIIIIZIZIIII]
311111111
iiiiiiiiILl
iiii I iiii i IIIIIZII iii ii ii ]iiiiii i iii171111711117111]1711111 ..... 7,7717 i] ........ /ii17 Z1
] ........... I SbCI3 ANTIMONY TRICHLORIDE ] 1 t ............... ] ............................ ~ ...............

/ ............ ! _ .... .............


I ....................................
I .....................................
!......................... 1.................~....................................................
..............................................

I i - I .......... i. . . . . . . . . . . .'...... . . . . . . . . . . . . . . . . .
. . . . . i . . . . . t .... I ._ i I / I ....................... ! ................... Z]
I I .....I ........................ t / I [
............................
. m L __ ___........ .......[_i. _::_ii/ii_ I.... I 7-IIIIII--IIIII---IIII--I:Z
:-: ii ii i .........:::::::::::I
13. 1 ...........................................
I...............................
1........................
__~i_!.......................
/i! ............................................
tl)
!,__

lk.,

13.
!,__

0
c'~
>

1 .....................................i.................."..................
i7711;7ZI ii_ IIL 11111177
Zt i
qt
,
:-- !::L:/::__ :ZL:_:::I i , ............... j
................................. ,/iiiiiiiiiiiii:i:iii :i:::: i ,,,i, ,_
" ,' '9
!/
n .... i, ............ i.............................. 1..................................................................... I._ '1 1 psia = 6.895 kPa
/ ........................ ! ................................! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LI 1 psia = 1.71 mm Hg

0.1 1 /
1 O0 200 300
I . . . . .
400
.
500 600
i"
700
i' I
800
1' I
900
' 1000

Temperature, F

261
10 I l J i ..........................
[
J . ! I

SbCI5 ANTIMONY PENTACHLORIDE 1 .......................... ! .........................

Q.

(1)
:3

(1)
I,...
13_
O / .................. i ...........
r~

>

0.1
! / _ J
_iiiiiiii...... i !.....
i i i..... i/ii ......i~i~iiiiiiiiiiiiiiiiiiiiiiii~i
.......
ii.....i

/ I psia = 6.895 kPa

i
1 p s i a = 51.71 m m H g .........................

r ! r
0.01 I I I i i i i i
60 80 100 120 140 160 180 200 220 240
Temperature, F

262
10000, .... , ................ ,. ,. . . . ,
7 ]]]]] ] ]] .... ] ........ | ]]]]]:] ]:]]]]]] |.:::::]: ;]]]]]: '" :[_ :i '_:] _ i::__ -_ ]1 1111.]] : __1____-1 ] ........... 11]] ...... I .......... ] __1........... I
t
l:]]:::: ::::::::::::::::::::: ' ! -- - i 9
i
SbH3 STI ,,~a Ii .............................................. ! .................................,

i ........................................................... , . . . . . _, r
__ i ..............Y .....LI .............i.... i::i .....I:L:,: ...........21 ..........................
211111
.......L_ ....... I '
I
1 oo- 0 . . . . . IIIIIIIL : ] i i i i i ii ...... i l: :: ,
. _l ....................................... ' i~ ~ ~
. . . . . . I i 1 ,- ................................ ; ............................ ~ ." 9 - "~"- ..........................
........................... ~. . . . . . . . . . . . . . . . ', ............ I T.................................... i - - ' - - - - - - - ~ ........................ i". . . . . . . . . . . . . . . ! ....... .777, ................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .t. . . _i -t ~ ~ i ....................................... ~ ............................. r, . . . . . . . . . ,, r '- - -- / - - ~- - I
] ...........:_:_-:............:........ !:-:: _::__:::: ___-_:
.... i--_:_::_:_:]:]::::_
:_--:]...... ]]_:__:]__:::]_::::::_:: :]][:::::::::::::::::::::::::: .......:::::::::::::::::::::::::::::::::::::::::::::::EL::::: ......... "I"

==================]::J:
=========::::::
=== : ::::: [ ::::.......:::: : :: i ...................--7 . . . . . . . ~............. ~ .......... !

. n
ffl
1 O 0 ...................................................................... i , - - ~ ............... 9 "

0L _ -----Z.:[:_::]:_]i:]:]:][:][[:]::]]]]E~L][[I][I:]]:~:~2_~_: r~-----_-.'---.___Z:
i
]
i
".Z.:.--_t'..: -_Z..-~
|
-__2

; ~ ~ ~ i i

0
1 ,.,J__ ~. ..... /_i ........... ! ............. ! i
=========================================::::::::::::::::::: ::::::::::: ::: ::::: :::::::::::::::::::::::::::::::: ::::::::::::::::::::::: ::::::::::: :::::::::_._!::::::::::__:::::::::::::::: ::: ::::_._I_L_ ....
> - ] ................................. i . . . . . . . . . . . . . . . . . . . . . . ! _ _ _ i . . . . . . . . . . . . . . .~ .............. ! ................. F
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
. . . . . . r::::::::::::::mT ......................
7 .................. I . . . . 71 ....... , . . . . . ,---------r
9 I , ' I I
7 : ........................................ r - - - - ' - - - - / " - - i . . . . ~ . . . . "7 . . . . 7"
/ i / i I i i ]
J ...................................! ................Z ............ i ' L__.__I. i

:::::::::::::
- :::: L_:: :::: :::::: Y :::::: ....... :: :::: .... : _ i___: ...... L_ : : ......... ::::: __i ....................... :: __Ls ............ : ........ :_i i 9
:::::::::::::::::::::/i11:1: __ _1111111 __1::11111111]:: ........ 111111 ...... 11111111111_! ............ 11 ___1111111:.... I ..... ::::__::::___L___:::::::__.,J ........................ !
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :]11111111111:. . . . I - [ - ! .., !
] . . . . l ! i ......... ! ......................... [ .............................. I ............................ Z~ . . . . . !.

!.
l ]:II:IIiL:I iiii {..........iiiiiiiiiiiiiiiiiiiiii,................................
{
1 psia = 6.895 kPa
........................ ! . . . . . . l
-I .......... Z .................................... ! ....................................................................... ~ t 1 psia = 51.71 mm Hg

]iii
I
i
......T i i
/ ! i i i .... i, i i !
0.1/ i I . . . . i I I I
-150 -100 -50 0 50 100 150 200 250 300 350

Temperature, F

263
100
..... / ,.
f
i ,
[

1
Sbl3 ANTIMONY TRIIODIDE

!
10 / 1

............................................ / .............. i .........

i . _ _ L L [ ................./
,J I L "

GI
/
. m

C~. /

o9 /
(D
t,...
13_
= /

O
Q.
/
-- x

t~
> /

/
. . . . . . . . . . .

0.1 iilJ r
. , =

/
/
7
!i
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01
300 350 400 450 500 550 600 650 700 750 8OO
Temperature, F

264
1 O0
t ]
b203 ANTIMONY TRIOXIDE

10-
i ~ | .....................................................

4
I
. i

09
(D.
(D
L_

09
03 ..

(D
t._

D_
t._
]
0
(D. ........... .................................
> -i...................................

|
i
..

0.1
................................... ~___

i
' 'i
I
II , , !

. . . . . . . 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

i
0.011 f
t
]
!
!
1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F

265
100=
=

,t "1," I' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I
I . . . . . . . . ,'_ ....... !

Sc SCANDIUM l ......................... i._ !

10=

iiiiii i i i i 111111
i 84184184184184
i i ii i i i i iiii i iiiiiiiiiii iiii iiiiiii iiiiIIIIIIIIIIIIIILIIIIIIIIIIIIIIZJI-II
. . . . . . . . . . . . . . . . . . . . . . . {:!!!,.....~.-..-,-~,----------,
9 _ r

0.1=- . . . . . . . . . . . . . . . . .

. i

ffl
O.. 0.01~
,,~
(D
K..

::3
fn 0.001 ................................... I .~.--- -''.....=.......-.~
"- -..~-.~..'-::'-::'-'.-:'-:'-~.= -:n -= :::

(D
&,.,,
,L
-~
-,-
]

O 1
o. 0.0001 . . . . . . . . . . r-

>

/
1 E-05 r
................................. ::!!/.... ~-=,,=:- ....... __=:=,__,=::__, ................................. § ............................. _=_::::_....... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

I
,--::=-,-=:_,=.

s
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

[
i / ......

1E-06 ..........iiiii.........iii / ..........i L. . . . . . . . . . . . . . . . . . . ~................................................................................................................... ~ ..................................................................

. . . . . . . . ./

i i iii-iiii-iii
~' i
r .... I

iiiill / ii i
t 1 psia = 6.895 kPa
.:=_.:=_==_=.====.___==:::t::::: 1 psia = 51.71 mm Hg E-Eiiii":"iiET:EEEi
] ........... :: ::::: .
1
9 VI
II
II ...... i ........................... 1 [

i t
1 E-08-' I i
1500 20O0 2500 3000 3500 4000 4500
Temperature, F

266
100

Se SELENIUM

10

i i......... i..........§...........f
- - T ............T............T .........
,r.......... --,?
i ~ I i
0.1 i: ............................,...............................
~ ........................................................
9
,..................................
,.............
~-:..!!---~
~....... .Z/..'::::..":.:-".:."i
..................... ~ ................... ~ ..........
............... " ........................ :.".............. --~." ""~:--.~.'.:'C~:

............... !" ................... 1"............... --"-:;,['.. ...................... ;


t.............. -i" ................ ".............
.: - T / 7 ............... i
i i !/ i I
,,.i,

O9
Q. 0.01
.~.'-~--- -~-V-~---------~
(D . ,...........
'---------r . . . . . . . . . .2. .....
"P-- .... 7 ........
4,
i
&,.,
I /
:D . . . . . . . . . . . _ + .......

O9 i --/ I
o9 0.001 ::::::::::::::::::::::::::::::: :::::::::::::::::::::
,',.. . . . . . . . . . . . . . . . . . . . . . . . . . . ...

(D
,,. 9. . . . . . . . . . . . . . . . .,

'~===::==:=':~i
,!. . . . . . . . . . . . . .!
13_ ......... ~. . . . . . . . 7'-[ ............ ~......... ---
. . . . . . . . . r - - - - / - - r ......... , . . . . . . . . . . . . . . . . . . . . . .I". ..............
....... "I
K I
T ...................... i
O i . . . . . . . . . . . . . :
I i i i
Q- 0.0001 ...................................... :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
9 :

............
.......... .................. .~.....:"~:" "..::::_--._: "::-. :r.:-:
~.......................
.~ .
:::: ::::" "-'-:: "..':::::'.-.::.--:::::::"
.
"-'. "c'..::::::: "-".""..:"-- .~:':.:: ::--'_-'-'-:: .-.:::::::- ,':

> ~ ~ tr.E.:.C..~"~E -_".'T_"E:." '


!
'----'--"~" ......... ,.7 ............... .'I'"
:.'-................ r........................................ t
~9 . . . . . . . . -;~" . . . . . . . . . ...............

,4. ........................................
. . . . . . . . . .
!
~ ............
l
~. .................
i
~ .................
!'

i'
i'
.............. -i i i i i I
............... I- ~ . . .........i,
./__[................... ....................
I
_..,. .................... ,.
I
......... "--" . . . . . "~./::::Z.~ Z.~:Z::.?..-..~--"~::-.
~.~ ....... ."--"."
Z.T.Z'.~ Z.'/::~ ::::.T.:'.%T---/."-":::::.~--~
~C/Z::..'2~::~ = Z ::= ~ ~
.__.____~.___~.___.__~:::-'-----------'---='.=---=~_-:,----~4=_~.=:---=,=_.., ...... ::===~. ....................

! i i
. . . . . . . .! . ----7", . . . . . . . . . . .i ----1'. . . . . . . . . . ti
! i
t ............. t
1 E-06
--_, i i ; i ! !................................i
.....................................
............................
.,
-,
............................ i9
f ............................. i
+"" . . . . "-t

i I i, ..................!i
! i i
1. . . . . . . . . . . . . . . . . . . . . . .,.- . . . . . . . . . . . . . . . . . . . . . . . ,, i I 1 psia = 6.895 kPa

1 p s i a = 5 1 . 7 1 m m H g

.... ~........... q ................ J ......


--1-- . . . . . . . . . . . . . . . . . . . "!"--"
9 i i I !
i
.... ._,_...._ . . . . . . . . . . . ~ ..................... ~ ........

-i, ........................i;........................~j..... ii i! i
1E-08 I I I I I I I i
200 300 400 500 600 700 800 900 1000 1100 1200 1300
Temperature, F

267
1O 0
9
r
;;,
'....................................
7
.... ,I i
................
..... ii
11 171;
:l r9
iiiii .
. . . . . . . . . . . . . . . . i;i'
. .
. . . . . . . . . . . . . .
. .
....J i l
I
.
................................................... "
.

.... ii SeCI4 SELENIUM TETRACHLORIDE l

:I

10- .... t. ..... ' . . . . . . . . . . i i , 1 .. _ . . . . _.................................... j


9 9 . , ' .... J . J ............................................ J

... .. . . . . . . . . ...... /'~

. . . . . . . . . . . . . . . 4 / ' ;
........................................
. . . . . . . . . . . . . . . . 7 I ...... ; III I~;71:;LL;L;;72~L
' ' ' ........... ; ....... i " / ............................................... '
. i
..... ; / ,., 9. . . . . . . _ .... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l

. ., . . . . . . . . . . . . . . . . ii /

l,---

u)
0O ....... .......,,, , '" ".. '.' o' ,. . . . . . . , ................ . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .....................................
(D : i
; I
......... , ---_ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j

Q. i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .,
. . . . . . . . . I f ,. . . . . . . . . . . . . . . . . _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i
' i, , , i / l . . . . . . . . . . . . . . J ................... ....i
O f

C1. __ , ! , i . . ..9 l .......... ~_~ . . . . . . . . . . . j

> -- ' ! ' ~ ,i

....... =

0.1 .~. . . . . . . . . . . ~ / ! ...........................................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J
,i

............................................. J

........................ -__..__._.J

_ - ,,, ,2./;, ; ..............


.. ; 7
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ..i

i ; :::t
/ . . . . . . . : ,,,.., . . . . . . . . . . . . . . . . . . .J

.
~ . . . .
../
. . . .
,i .....
"
[
, !
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 r I I I
150 200 250 300 350 400

Temperature, F

268
100:
,,

SeF6 SELENIUM HEXAFLUORIDE

!
i . . . . . .

10 I [! i
.... ./!
J
iBm I
;Y I
tO
. m

C].

L_

::3
09
09 _

L_

rt r
L_ -i
0
C~. ==

>

t
l
0.1 =

i
- |, !

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01-
-200 -180 -160 -140 -120 -100 -80 -60 -40
Temperature, F

269
OLE
--1 'eJnleJaduJal
0<:38 OOg 0s 00~ 0s oo L 0s
I ! ! I I I I LO"0
r
6 H u.iu.i LL' I.s = e!sd L

i ............... i" ........... ?-


ed)t s = e!~d L i Z .....
7 7 7
i .......................... ]
l r ......
........................................................................... 4
................................................................................................................. j /iiiii r
{'"i ......... 17 77L171 ~ii ...... i ~ 11117.... 7777~: iiiilii177711 i111117iii177 1 iiiiii iiiii.....i ;i i [77777111777777711111~
I ........... 1 ;Z . . . . . . . . . . . . .
"ZL-_~-..-.2;ZTZ72A=-_-.'.-...-; .7;-...-.--'_--Z.L..--.=-.-.Z--Z;I t /
= i i;iiiiiiiii];} ;iiiiiiiii;;;17/~71111:111711 iiiiiiiii ..... iii;;ii ZIIII;~II::: 77:: ;i
...................................................................... i, L'O
. . . . ! . . . . . . . _
...........................
l i
iili._ Z ............. i_il..... i ..... i....... ...... ..... ;iiiiiiiiiiil;i;illiiillii~
0
"I
/] "13
C
tl)
y
"I3
m .
iiiiiii p!oL
j ............................................. 3ClII:IO'IHO,kXO IAIIGIN3"I3S ~lOOeS
i.......................................
9OOL
100~ -4 '
.............................................................................. .},.............................................
~liiiiiiiiiiiiiiiiiiiiiiilliiiiiiiii
]iiiiiiiiiiiii iiii SeO2 SELENIUM DIOXIDE i .................................. i.......................................
................................... ].--
i
i I

1
I it" ............................................................................................
........................................ii ..........................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

i I

Ii i i i i i i i iii ............
iiiiiii
i I
....................................................
t " .......................................................... 4"i .........................................
i i.
i
I i
t .................................................. ,.-
.I....................................... .~
!.- ...................................................... .,:

i !

[ ......................- 7 i
, m
09
Q_ I/ I
(D
:D
00
In
(D
I,...

13_
!---

O
ID.
>

0.1
!
t .. ...........................

,- ...................................... i.
i i
~.................................... "I' 1 psia = 6.895 kPa
i I
I i 1 psia = 51.71 mm Hg
i

i i
!
i i I
0.01 1 ! f i
! . . . . . . . .9 . . . .
I .....I . . . . . . . . . . . . . . . . i I I
300 350 400 450 500 550 600 650

Temperature, F

271
1 O0 !

_' t

-, ..... Si SILICON ...............


,,N , .... = . . . . . . . . . . . . . . .

10
/
II t"

/
O3
./
. m

O3
Q.
(D
L _

O3
U) .

(D
f
/
t..,
r /
13_ . . . . . . . . . . . . . . .
/ ............

0
CL
r
>

//

0.1 /
/ ,

.......

. . . . . . . . . .

/ 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g

0.01 -
3000 3200 3400 3600 3800 4000 4200
Temperature, F

272
10004 ............ " ................ ~ . . . . . ~ :: .............. :~I ............... :'-
.................. I: '

Iiiii iiiiiii~ii~ii............... iiiii T[ .... fillIT ~......... ,77


~qll iii I SiBrOl2F BROMODICHLOROFLUOROSILANE iiiiiiiiiiiiiiiiiii~,iI:LIIIIIIIIIIIIIIIIIIIIIIIIIIIIILIII]L:,Iiiiiiiiiiiiiiiiii~iiii~~iii

lOO ....................
- :.-:..- ~ _ _ - : _ ~ ! ........

--_ - ,,_ ..... L

. m

C). 10
e~
9 [
" __./ --iii __ [
L_ [ ....... /____iiiii i_ ii ............i;
....................Z ......iiii_ii..........ii ...............
/ ........ ..............i
(1) ;'ZII; .........i iiiiiiiiii-iiiiiiii!
13_
0
(3. 1 _L :

> IIIIIIIIIIII-ZI_IL_.IIIIIIIIIIIIIIIII
iiiiiiiii~iiiil/i~ii~iiiiiiiiiiiiiiiiiiiiiiiiiiiii~iiiiiiiiiiiiil......................7".....................................
i i/ __. iiiiiii t
11111111111111111_111111111111111111

/ '
,
i
}
!
i
1
0.1 :T !
,u
......... =-

't'-" 1 p s i a = 6 . 8 9 5 k P a
...... 1 p s i a = 5 1 . 7 1 m m H g ~-
,

.... i,

!
i
1 t ,
0.01 I b I I
-200 -1 O0 1 O0 200 300 400
Temperature, F

273
1000] ! i
I t
]_IIZZIIIILIIZZ;i
] iii~i ZYI~- SiBrF3 TRIFLUOROBROMOSILANE
]
{ - i ............. i

.... I

!. . . . . . . . . . . . . . .i. . . . . . . . . . . . .
I i
1 O(
I l
~..........................................................
9 4..
,,...................................................... ~.
.w Ii...........................................................
I""
i
O9 i t
CL
t............................................... +.
(D
I !
:D
O9
(P
L_
13_

0
13.
>
/ i i , : I
9 i ~ i i

. . . . . . . . . . . . ~
/ ........+~ ............................................................
i i i
~ .........................................................................................................................................
i
~........................................................................
I,
, .......................................................................

. . . . . . . . -7" ................i:....................................................................... i .......................................................................


t .......................................................................
i .......................................................................
i .......................................................................
j
t
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...................................................................... ................................................................... ....................................................................... ....................................................................... ....................................................................... ~

L . /
J i i
................................................................. , ................................................................., .......................................................................
i
i .......................................................................
i
, ........................................................................
!
i 1
i
. . ~ ............................................ 4........................................................
P .............................................................
9.....................................................................
9.......................................................................
! ........................................................................

- i ............................................................................................................................................................................... 1 psia = 51.71 mm Hg ........................................

i
i
i i
I I "
1 I
-1 O0 -50 0 50 1 O0 1 50 200
Temperature, F

274
1000 3~22~ii~i~i~,22~2~1211111111
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
............21111211111......L L 1221111LL2211111111111111111L[
iiiiiiiiiiii
l ........................................
I I I '-I
] iiii - I [ . . . . . . .. . .. .. . .. .. ... .. .. . .. .. . .. .. . .. .. . .. .. . . . . . . . .

] ...... iiiiiiii i iii....... I SiBr2CIF DI B R O M O C H L O R O F L U O R O S I LAN E


7 ..............

] .... . . . . . . . . . . . . .
, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
,1.....................................................................
i i
]illliiiii?iiiiiiiii~iiiiii~tlT:?i ..........i ~ : : : : ] ...........iiiii:21:?...................it:ii .......................t .....................................................................
) ............................./

] ii ii IZZIIIII__ ii
i
]illililliilli i il l l l l l l li~il]=
l C ii= i122 JJ ,7

.m

10
O.
i . . . . . . . . . . . . . . L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,!

(D =_ . . . . . . . . . : : : .......: : : : = : = : ....... I

....................................... I

co
(D
13_

O
O= 1
> t 4 i
i
i
!
)
i

i
| I

,..... . . . . . . . . . . . . . ,!
!
i i
0.1
I i
!
! ~ , ,
:................................................

~-
t
.......................I'.i....................... )I
't..... I 1~ 1 psia = 6.895 kPa
i i 1 psia = 51.71 mm Hg

i
1) 1
i i
] t ,
0.01 ' ! , i
I I I I
-1 O0 1 O0 200 300 400 500

Temperature, F

275
1000 I t:

$iCIF3 TRIFLUOROCHLOROSILANE ..... i


;_ j "

/
f

1 O0 7 !
iiiiiiiii 1
/

/
/

/
................ / J

/
/
. i

ID. 10
/
(D /
/
I,i

/
/
(D
n

0
O. " / "

> /
/
/
/
/

0.1"~ .....
/
......

/
!

i/ 1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

i
!
0.01 I I
-250 -200 " 50 -1 O0 -50 0 50 I O0
Temperature, F

276
1000:., i i + +
~'- . . . . , C ; ! r
. . . . ~:~ i i, ~ : ...... [:::::?'::::::::::::::::::::::::::::::::::
+ Si012F2 DICHLORODIFLUOROSILANE [ l -

i
k

.... ......~ .....................................


-" ; - ..... i ........ ~.............

.......... ! ............. i

. . . . i i " ~ I "

1 O0 . . . . . . . . . . . . . . . . . . . ~ ....... i. . . . . . . . . . . . :. . . . . . . . . _ . ~ ! , ...........

i --+
I.......... :i:ii :ii!. . . . . . . i Z .iii
......[ -ZIIII '/ i ...............
Z~IT"
-" I + " [ / ! -
i ]: ......... ::: ..............C T;
!
................... i ................. _.4_.................... j t
]. . . . . . LS ...... -r............................. t

,m

Q. ,oi ~IZIZIIIIIII iii ZIIIIII: i '; .....


~/
JT
i k 3 ...... ii ........ !

;
9 . . . . . . . . t ................ i ~
__ ......._::::Z::::::::Z::I:::,____T_I3L__ZZ : YI i i rzz-:i .....i-.~z~--
i..............................
i

t,...
z~ / i .... ...... i
u~
u~ ........ ! ................ ! / i ........ ! ......... i iiiiiii
.........................
l..............................................................
i i.........................
(D
ft
i , ] i
0 ! / t
Q. 1 ~+!+~+~!!!!~+:++++:+++~::!++:+++++++:.,+:++++++
+++++++++ +++++: ++++++++++~++
++++++++:+++++++++++++++::v+!
> ................... |
--i~
!-~....................................
| t

.... i ...... ::: .....iIYY::


...................................T ...............................i ....................... i ............................................
! ......................................... t [ ............................... i .................................
I I I l +
,! ................................. ' J.. i +

o.1 ...... I
il 9
.I:........................ .+.+.
!
i
t ................................ i.
I 'i

~ _ _ _ Z ..... Z I / _ _ I IIIZ! l ......................................... t .r-- ...................... | ..........................................'


/ J
| 9 +,

- / ] ..... I

i 1 psia = 6.895 kPa


-~,
i
2 ........! ......... !
-/___ j
7 i
]
! .................. !
T..... 1 psia = 51.71 m m Hg
.....
[
i

J
9 , l
0.01 I .. I i I I I I
-200 -150 -1 oo _,t~0 0 50 1 O0 150 200 250

Temperature, F

277
8LE
-I 'ojn),eJoduJo/
Os 008 098 008 0s L O0 ~ 0s 0 0s O0 t- 0s t-
I I I I !
r 1 1

~" tO'O
4
................................. OH uJuJ tZ" ts = e ! s d t ........11111_:::i::.12i i .............................. ..... ! .J" .....:-
................................. ed)l s = e!sd t
[
: [ -
i
r l
~, I ....... --
; ... . ......... ] [ /
.....
,' i ......... ,::: . . . . i
~" ~t'O
7
l
I
r .................... -......... - r. . . . . ;-- : !..
i ..
/ 9
/
....................... _......... _...........~_. . . . . . . . . . . . . . . . . . . . . . .
r ...................... ; 9 9 -!- / 9 ,. . . . . . . . . . . . . . . . . L
r ............................... i
......................... ~ i
r . . . . . . . . . . . . . . ~ . . . . . . . . . .
:.. ..... /
: / :! :
r........................ ~ ...................... ; ..... [! 9 .~.- :
........... :
..................... ~ --r j,._ i - ;// .:'.::...; . , <
....................................~. . . . . . . . . . . . . . . . +.......................... ~.
"13
I
0
: ................... r ........................ i ............. ; - "13
r ........................ ~ ........... 9 ................ - - ' i ..................... ; ! m
(I)
]
O0
, ..... . . . . . . .
r .................. ! ......~ -- i ...... ; - I,, , 9 f.n
. / .... z . . .
r ................ _I
t ............ i i I ~- L C:
.......................
/-
! m
i ' . . . . . . . i .... 9
....
r ................ 9. . . . . . . . . . . . . . . . . . . . . . . . . . i- ........ ; 0
I . . . . . . . ~ .
I ........... i . . . . . . ;- - - " / i i |
.............. i~ ............. , ..... ; .... , . ,i- _ ! , ,, "13
/ OL
i .
i /
; / " r
!
f .................... -~ ,
t
/ . . . . . . .9
.....................
,i". . . . . . . . . . . . . . . . . . . . . . . . . l[ ..... : ........ -~i ........ . / 9
.. l
I i./
I I
........ / - : ~ . . . . . : .. i ........... : |
! ..... |
I . . . . . . . . . . . . . . ~ . . . . . . . . ~ ..... l, -'f I . . . . . . . . . ;
L L
i . . . . . . .
. . . . . . . O0 t
1
I
i ........i ' ............ i " " ,L L L
i
'--_-:- , ........
i.... : I
i L
3 NV-IISOElOn-1..-IOklO'lHOIkl.I. _-1810!8 I
I
............................... i ,i ........ :! " , I,,
i i l ..... [
:............. ) ................................. 4 ).................... ; ...................... i
000 t
1000 , ,

SiCI4 SILICON TETRACHLORIDE


7

....iii..... ~ ..... i_i

100

. m

O3
Q. 10

(D
L__

(D
L_
13_
t,,,..
0
(D.. 1
>

0.1
i
!

r-" 1 p s i a = 6 . 8 9 5 k P a
I ............................................................ , 1 psia = 51.71 mm Hg
i

,., i!
!
t
i !
0.01 I I I
-1 O0 0 1 O0 2OO 3( )0 400 500
Temperature, F

279
1 0 0 0 ], I ' _ .] i

E
SiF4 SILICON TETRAFLUORIDE L

..... i

. . . .

/
/
W"

,u
/
Q.
(1)
IL_

O9
O3 1 O0
L_
13_ /
IL_
j / j ..............
0
C~. i ......... / .....
tO
>

4
/ .............. - ................. iI ................... i ..........................................................

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

101 I i I
- 140 - 120 - 1 O0 -80 -60 -40 -20 20
Temperature, F

280
l~8E
-I 'eJn~,eJadwal
OOL 009 00~ 0017 OOE OOE O0 O 0 I.-
!
- 1.0"0
6 H tutu I./..' I.g = e!sd I.
i tK
edM g68"9 = e!sd I. - - - - - i
~'0
<
! "0
0
"=I
-13
'='I
('i)
C/)
c/)
c'-
'='=I
0
-0
:0~ f.n
B
m
:oo~
3NV71SOIAIOI:ISII=I1 8JBH!
f m 1 [ 000 k
. . . . . . . . . . . . . . t . . . . . . .
1 0 0 0 - :: I .... :: ! :: i . . . . i i : ............ :: ! ...... .... +iiii!!!!!iii!!!!!!i! 1

.... SiHCI3 TRICHLOROSILANE 1 ..........

100-+ -',, '...... , "


.
,
.
.I:::.:i ....... .......
. . .
.
.~,,
~ _ ~ i, ::,,:: ; ...... ,. . . . . . . . . . .....
.............
... ..... ======================
+ ......................

. . . . . . . . / / ......... Z ,, , ...... i ....... =iiiiiii:i:ii


. . . . . ........ - / t ....... i ....
[ ~
- '

....... i ..... - ....................

10- ,
..... ! . /
. . / "' . ....

.... ..... !
I

..................................

_ , ! / i .... ' II
.
...... . . . . . . . .
/ l i
.............. _ ...........
,, ! . . . . . . . . . ,

, !/
ki" ........ : l .... . .... l _ _ _ j
L
, ~.. . . .
..... ~ . . . . ! .............................. ...+ . . . . . . . . . . . . . . _....... I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J

,I, , , ...... ;

. m 1~ ~I /i" . .

t3'}
C'J ~. ~
,'" } '" I !
" .
,4,, I . . . . . . . .
. . . .
J
I
I=[IILIIIIIIIIIII2;;;;;_I--2;jE.3
............................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I
I
..... / ' " "" "i " '" :

O3
sl,.__
9 : '' ~ -'" 9 + ...... A .................... +. . . . . . . . . . . . . . . _ . J

I , ;.

o)
0.1~ I'"':'1
.....
,. . . . , .... ,
,
1 : ! '" '.. ti " :!

9 i/
! . . . . *_ . . . . . . . . . . I ......................................... I
9' ! ,,, i 1 ..... !I . . . . . . ! ... I .................................. .I

13_
9 " I "' +. .... ; . . . . ! .. I .......................... .+,I
-- ,/I ..t, . . . . . . . . . . . ....... ! . ! . . . . . . . . . ., ,I .......................................... l

i,_ " /
i
. . . . . .
................ . . . .

0 I I I

[
> 001. -~ /
9 .: ,,,,: ,.~
. . . . . .
. . . . .
. . . . .
!
.
. . .

n
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

] I',IY:IL L ' ...........


_ / 4 .....
. . . . .
, . .
........ ,
. . . . . .
;. ...... . . . . . : .......... ~ ............... -~.............. ii:i:ii-iiiiiis

, ..
. . . . . . . . . . . . . . . . . . . . _. . . . . . . . . . . . . . . . . . . . . . . . . . . .

1 i I ' I ! I . . . . . . . ! ..... i ........................................ j

-- /
/ . . . . . ..... . ....................

/ F

0.001 : ; , ........
-- 9 ,9 ..... .... ; . . . . . . . . . . ; ....... ; :
t. . .
.......
. . =
iiii i JT~Z]]III]II~,IL--II_IIIIIIT_,I:~II_I . . . . . . . . . , ; ; I I , ; ; ; I ; Z Z I I I L . + . ~ . I
.:..t ............................................... i
9 ! ,v o ,, 4 .... ;

-- i . . . . . . . . . . . . . . ; . . . . . . . . "~
- / ........................... i !I .......
] / . . . . . . ' . . . . . . . . . . . . . . . . . . . . ' ..................... [ . . . . . . . . . . . .
. . . . . . . . . . l. . . . . . . . . . . . . . . . . . . . . . . . j

_ H
.L-~ . . . . . . . . . . . . . . . . . . . . . ,t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j

o.oool .............. ! ............... ....... :


1 psia = 6.895 kPa
1 psia = 51 71 mm Hg
......................................... i

. . . . . . . . . .

i . . . . . . . . . ; . . . . . . : . . . . . ................ ]1

1E-05 u
-200
I
-1 O 0 0
i i
1 O0 2OO
i
I
300
I
400 5O0
L
Temperature, F

282
~8~
4 'ejn3,eJeduJel
0s 0s O0 L- 0s 00~- OCj;~-
I 10" 0
' 1 1
. - - . 4 . , ....... --~o--~=~,,,,.,-,,,-,,~- ........................... J
t
!6H m m LL" I.s = e!sd I. .....
,i ed)l s = e!sd I. ....
r
-7 L'O
.......................................................
-4 !
:!
L L
0
"13
c::
0
um=
OL
.................................................. --===--= ...... _. . . . . . . . . . ~--~- .................
' Z!i!:~:~~_:~____~i___!~i-_--i~!!!!!! 00[
........ Z
j
3N~qlSOUOAq~IUI s
::-:................. ~ 000 I.
~8~
-I ' B J n ] , e J s d u J 8 1
009 00s 0017 00~ 008 O0 I. O0 L-
I
~0"0
6H uJuJ t L ' t s = e!sd L I I
ed~ s = e!sd t ....... i /:
.._
. . . . . . . I _.
. . . . ! E
. . . . . ~ "0
.../
....... -
. . . . .
13
0
"D
0
" .. / ' " .' . . . . . ,, Oo
O0
.... :: L t-
O
J 13
Oo
im
i'
/
d , r
I
r ~,, '"' , ........ i
::: O 0
J
Z .........
ii
......,, ~ . 3N~qlSOIAIOI:ISIO ;~JB;~H[S
I . . . . . .
I . . . . . I .......
: 000
1000
i __ i
SiH2CI2 DICHLOROSILANE ----

100: -

10: .=

.= 9 ~

.==,=
i ,
03 i
Q.
(D
t__

03
03 , ?

t__
Q.

0 0.1
Q.

>
i z

0.01

|
0.001

i
~'-- 1 p s i a = 6 . 8 9 5 k P a
-I - 1psia=51.71mmHg

t !

0.0001
l
i
it
-200 -1 O0 1 O0 200 300 400
Temperature, F

285
1 0 0 0 ~ I ]

SiH2F2 DIFLUOROSILANE
g

100:

r
. m m

c~ 10:
(1)
rr
!,_._

n
0
Q. 1-
>
m

0.1-

1 psia = 6.895 kPa

0.01 i :
T [
t

-250 -200 -150 -1 O0 -50 0 50 1 O0


Temperature, F

286
1000~_..__._~
I L
~ ~ ~ L ~ iH212 DIIODOSILANE J

100-
.=

.,=.

i i
. m

O3 f
El.
(D
i

U) 10-
(D L._
=..
i

13_
I
/ i
t,..,

0
,,=

13. .=

> I !

I !
1
!

rt
T
, [

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

Ii I
0.1 T i
o 1 O0 200 300 400 500 600 700 800
Temperature, F

287
Vapor Pressure, psia
o o
0 ,.,,I, o o
0
0 0 0

o
o

--I
o
3
0 -,.
"-~ O0

g)

-I1

ID
0
o

II II
01 O)
"6o
--" 01
CO
C) "" "---'-'-"-
o
"1"
QD

.1~
0-
0
68E
4 'eJn},eJeduJel
008 O~E OOE O~lI. O0 I. 09 0 OS- O0 L- OS L- 00i3-
I II ! ! I 1.0"0
. !
!
.. - ----.. i ........ L
~.. 6 H tutu I./_" 1.9 = e ! s d L ......................
i i
. ed)t $69"9 = e!sd L , , i /
] J --
] .... / . -
. l
!-....................................
!
7----: ........... - ................... ~1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ; ........................
/
I
..... - ...... = _ ~ = _ _ ~ . : ................ ~_-: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
J /
_
// .. I,
. . . . . .i. ...................................... I ............................... L <
/ '".i
#_
,.i . . . . . . - ..................... -L
"0
;i 0
"U
(1)
/
/J (/)
C/)
(-.
................................... 1 , ..... / .-_
!
i/
" i/ . . . . . . . . i (D
,---o=-. . . . . . . . . . . . . . . . ............................ i ............................. L_ x . . . . . . i
. . . . J 1 I I! .... i
......... ',-_ ' ,i ..... ! ! ,! "0
i ! 'OL (/)
mm
I 4
i i
I
L
i. - . . . . 9 .................... L
"t' ../. ]. ~ . . . .
.................. _/__ ............ .L; ............ :............ ;ii: "_11 _ 1171- ~ ........... ~.. i ........ ;;;;i. ,:
- - i ::::::::::::::::Z:; i _! ........ ! ..... ._ ................
:~ OOL
J L.. [ .. L ,,, J
/
I
l
/ j ' -
g NV-IISOI:IO'IHOONOIAI IOgH!S
!
., l., '. [ .l,. ~.' .... ''~
i ...... t ...... I t. i i ii --ii i ---__
, i I l { 7
' 000 L
1 000
! ..... . . . . i +
J~
SiH3F MONOFLUOROSILANE
j r /
. . /
/
/
I
1 ' 1 i

100 ~. , ,. f /
, / J : ' ::i
~/ i,,,, ... ....:
.

/ .

,,=,m

03 : ........:.:, .... :
EL 10' / , ......... ,
i
P, i

CD
tk=., i
::}
03
03 l

(D
L_

13_
t__

0
(D. 1
>

0.1 . . .. . . . .. . . ~ . . .
,,:,+ ....... i i i . . . . ..... ',...........
. .
....... . , ; n

. . . . . . . . . . . . . . ~ . . . . . . . . . I . . . . . . . . . . . . . i ................. -~+~-~--~- ......... ~+-


. . . . ~ ............. t ..................... ~ .................... ~ - i

+ . . . . . . . . ' . . . . . ' . . . . i .............. i ....................

1 psia = 6 . 8 9 5 k P a
lpsia=51.71mmHg

i
E
E

0.01 I I I I I I 'i
-250 -200 -150 -~00 -50 0 5o ~00
Temperature, F

290
1000
.... j . . . . . . . . . . . . . . . . . . . . . .

Sill31 IODOSILANE .............iiiiii;iiiiii.... iiiiiiiiiiiiiiiiiiiiiii11111;i ~ .........T II;;I........i


tlJU , i i

i . . . . . . . . . . . . . . . . . . . . '-'
J i i li i i i i i iiiii i iill iiiiiiiii.... i
i

1 O0

. m
Y~~~~~~:~~~:~:~!~~````~f
................ iiiiiiiiiiiiiiiiiiiiiiiii
Q.
(1)
I,,=.
::3
10
(1)
13_
0
C)...
>

t_.

I i '
. . . . . . . . . .
i

t-- 1 psia = 6.895 kPa


1 psia = 51.71 m m Hg
!
,,

i
i!
0.11 I I
-100 0 100 200 300 400 500
Temperature, F

291
1000. _ ~ ..... ~ ~ ~________:__: ........ _. . . . . . . : ......... ____::_:_:, ........ _. . . . . . . . . . . . . . . . . . . . . . . . . . t ......................................... ..I

I I ! [
" ' , I [ .................. i_~i~iii.......... ~iii....... [-----~i~:i .......... i:ii .................... i . . . . . . . . . . . . . . . . .
L !

Sill4 SILANE I

100 ' 7~" '. . . . . . : ........ : .......................

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . .

10 /
/ S

...

. m /

CL /
...

n I_/
[7
O
/
/ . . . .

CI.
>

0.1
/
,/
I
/

/
/

0.01

1 psia = 6.895 kPa


1 psia = 51.71 mm H
i

0.001 I a I I I
-350 -300 -250 -200 -150 -100 -50 0 50

Temperature, F

292
1 O0
J

I
!
Si02 SILICON DIOXIDE

10

. m
i !
(1)
!__

03
09 ; .......................................................... ~ . . . . . . ............................. == ...........

(1)
L_

O_ / 1
t__
......... / I
0 I
Q. !
I=
> . . . . . .

. . . . . . . . ~///]

!
0.1.

....................................... t ...........................................

i ! =
1 psia = 6.895 kPa
i

L
1 psia = 51.71 m m Hg
i
i !
|

i i
i !
0.01 I i i i I i I
2800 3000 3200 3400 3600 3800 4000 4200
Temperature, F

293
100 !

Si2CI6 HEXACHLORODISILANE

10 . . . . . . . . . . . . . . - , ..~, . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . , . . l

03
. m
/
U3
13.

f
. . . .

(D
L_
:D
00
03
(D
L_
Q. /
L_

|
......

O
EL
r /
>
/
/
f

0.1
/
/
/
/
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01
50 1 O0 150 200 250 300

Temperature, F

294
100
Ii ............. [

Si2F6 HEXAFLUORODISILANE

10

,,m
cO
c~
![...................................................
_ . ~
(D
&..,

(n
co

n
(D
~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii.............1~,"
t .... [

0
c~
>
.......... Ji, !. . . . . . . . . . . . . _

0.1

i,IIIIZIIIIIIII ...... iiiiiiiiiii--i-----ii]-iii-ii--ii--iii-iii~

-- 1 psia = 6.895 kPa


~ 1 p s i a = 5 1 . 7 1 m m Hg

L,
1
il ........" , !
0.01
-120 -1 O0 -80 -60 -40 -20
Temperature, F

295
10
t ! 1 J

Si2H5CI DISILANYL CHLORIDE


ii
....

03
u3
(D.
(1)
t..__

U3
03 ....

/
,

(D
!.__

13_

/
t,.,.

O
EL
03
>
E

1 psia = 6.895 kPa


1 psia = 51.71 m m Hg

0.1 I i I
-60 -40 -20 0 20 40 60 80
Temperature, F

296
1000 ..............
iiiiiiii i:i:i::::~ iiiiiiiii:ii :: :iiiiiiiiiiiiiiii :i~i::::iii~iiii i i:i ::: i~iiiiiiii ii ~iii iiiii ~ :: ~ii~iiiiiiiiiiiiii :~i~i~iiiiiiii iiii ,
. . . . . . . . . . . . . . . !
~ill i . . . . . .

Si2H6 DISILANE -I . . . . . I .......

....... . . . . . . . . ! . . . .

! I.............. I

100
!
I

10-
! ' I :

(B
, i

Q.

~ . . . . J
L _

(~ ;~::::::::::ii~ii
iii;~:::::::::::::::::::::::::
.......
i

n
f i
0
Q. !

(If
> . . . . . . . . . . . . . . i

l
!

0.1
i

i i i
| ............................................................ 1 ........................................................... --
i i !
i i !
:!i i t

t
t
i I
t t
0.01
iiiill .... ~iiiiiiiiiiiiiiii~iiii~i~iiiiiiiii -i
1 psia = 6.895 k P a
,] iii i i i iiill iiiiiiii i ii ili i
1 psia = 51.71 m m Hg
4 ,iiiiiiiii ....... iiiiiiii LIII ........... iii ......... i ................... ii........ !

! I i
!
0.001 i I I I I I
-300 -200 -100 0 1oo 2OO 300 400

Temperature, F

297
100'
L ............. i ............................
i I .................................................... , .............................................
i
~! .... ..... i

Si20CI3F3 TRICHLOROTRIFLUORODISILOXANE tiiil]]iiiiiiiii_,


iiii]iiiii]iiii]iiiii i i ~! .... i ~ .......-Z-]']-~_

!
. . . . . . : . . . . . . . . . ; . . . . . . . . . . i . . . . . . . . . . . . . . , .....

1 i -

10= ...... |
......i

........ ; ; ~iiiiii 'iiiiii


~. . . . . . . . . . . ;,~

oO I,

Q. ~j ..... i,,

: ....... 1

i/
L_
, L,! ........... = . . . . . . . . .... . . . . . . . . ... . . . . . . . . . . .

03
..... = . . . . . . . . . . . . ! . . . . . . . . . . ! ........ ~ . . . .
, i
CD
t__ i

13_
t__.
. . . . . . . . . . . . . .

0
Q.
>
,_i . . . .
i =i
]
_I
. . . . . . . . ! i . . . . . . . . . . . i ............... ~ ....................................... 1
r

_i . . . . . . .

i : i

." . . . . . . . . . . . . . . . . . . . i~ ........... ~. . . . . . . - . . . . . - ~ - . . . . . ~ " t -

i ! }
i i

i i :
! 1 psia = 6.895 kPa
t 1 psia = 51.71 mm Hg

I
0.1 I , i I I I
-40 -20 0 20 40 60 8O 1 O0 120
Temperature, F

298
100
i
Si20CI6 HEXACHLORODISILOXANE

/
/
t
10

---I--.-.....................
.................................. ,
............................ ;.....................
cU

Q.

(D

/
/
cO 1 /
/ J

1t,.,., L /
13_ i I .....
/ --
0
c~
CU il .......................
>
L .................... / _ ]

0.1

i...../i

E
~ .................iiiiiiiiiiiiiiiiiiiiil;iii!!ii~iiiiiiiiiii!i 1 psia = 6.895 kPa

i:::: / ..i.... '1 1 psia = 51.71 mm Hg

i
0.011 i I
0 50 1 O0 150 200 250 300

Temperature, F

299
Vapor Pressure, psia
o
o __L
o o
! __L
0 o

o3
o

"--I --
o o~
3
"0
(D ,

t-

O
,w
!

"-n~

Ii II
!
ol 0~
."" b~
(2) ---" 01

7"

(:2)
I!~!~!~~ii~ii!i~!:~!i~: !~ii~ii!!!!l
1 O0 -
I ...... .... ! ........ !
:Si3CI8 OCTACHLOROTRISILANE
. . . . . .

i f/
0 ~ ~ ................
i . '~i ~ _ ....... .. _:i _.:::::i_i_.??illllll ........ 2~2~2iii-!:::::::;;-...::~::::~.::::::::::??~:;!??~::::~:~:~222~::i~2222i22222222;222~22222
,~ ......
"' i . . . . . . . . . . ............... : ............................................. ~- _. 2 _ _ / . j i i 2 ...................... , .......................................................

,,, i

.......... 9 i t

i [
.......... . "-----" I I
Ii,i

u~
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . ~ 9 . . . . .................
. . . . I...................................................
,, ,-. . . . . . . . . . . . . i
- ................................................
,
t,,i
.,4'r.................................................... i 4
13.. 'i' ................
t,i / ............ 1 !
0 ....................................
jI i i
ID. ........... I .......... ~ ...... / i
i, !
> .......... ~! ....................
i~/ ................ | !

....... ! .............. / .............. : ..............................................


i
/ I I

: I l
0.1 ! I '
"i ..........................
. . . . . . . i /. '
i
l

. . . . . . . . . i ............ 4
/ , ..... i~ .........
/ i
~,................................................
~ ................................
I psia = 6.895 kPa
i 1 psia = 51.71 mm Hg

- i

0.01 '1
! 1
~ ~ ~ I
1 O0 150 200 250 300 350 400 450
Temperature, F

301
100

Si3H8 TRISILANE

~
f

../-
J

/
/
. . . . . . . . . . . . . . . . . . . . . . . . . .

u)
u m

CL
....

(1)
t,.-

u')
u)

/
(D . . . . . . . . '"

t,,..
13_
L_

O
CL
GI
> ....

....

0.1 , ,

/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01
-100 -50 0 5O I O0 150
Temperature, F

302
100~ !

.................................
I
.... ~;~iii1Si3H9N TRISILAZANE IF' ...... .......... ................ '. . . . . . . . . . t;'

I
lu i ,, ..............

............. i

............................;i
......... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iiii .......................
j ...........................

10- ,, ' I

.m
03
CI.
(D
t._

03
03
(D ~x::: :~iii:.... ~ :i: ~~;~::~?~:~:::::x~--
L_
i~
ii ........ ; i i ....... i ...................
13.. - . . . . . . . . . . . . . . . . . . ; ....................... /_ ..... ];i ...... i ...... -,
,.--_._.__._,__1

t---
O
CI. { ......... ....... i ............. / ..... ! ....................................
t0
> ................... .J9

. . . . . . . . . . . . . . . . .

0.1--- ........................ / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

_,___~__: . . . . . . ~:::_.. : /- .................................... ] " , .... ,JI

- .................. / ........................................ ]..............

. . . . . . . . . . . . . . . . . . . /

[_i ~ 'ii"~';~ ......; 711;-Y---ii'i


I
1

/
z

i ................................... 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
--- . ............ L . . . . . . . . . . . . . . . . . .

........................ r ............................. | . , . . . .

i
! t=

0.01 i ..... . . . . . . . . . . . . _ . . . . . . . . . . . . . .

-100 -50 50 100 150


Temperature, F

303
100
!

Si4H10 TETRASILANE t
.......... =

/
10 f
.............! . . . . . . . . ~ / i ~
. . . . . . . . . .

/
e,=,~

03
Q.
CD /
CO
G0
/
CD
t_..

13_
L _ |
o ,/
>
lb.
/
/

0.1

I
/
/
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 -
-50 50 100 150 200 250
Temperature, F

304
100~ ;:_ . . . . . ; ::::;.........::::::: ...........:--:............- - - - - - - : i - : : c - - ....... - - - - ~ : - - - : : ~ - ~ : : ; - : - " ............................................................................................................ ,

..... ! 8m SAMARIUM I .......... I

1 0"-; I ._ 89 I .....
.iJ.
..........................................
........................................................... , ~~..."..'-:'-~..:.~--'~
~ : : : - - . - _ _
. ,,. - ........ | . . . . . . . . . . . . . . . ~. - .... . ................... . .................. : ....... :] ...... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _ _ _ _ = . . . ~. ~.- - =. ~. = =. , ~. ; ;. ~ ;. ; ;.; : :.: ~. ? : _ : : - - _ - _ - - ~ - ~ : ~ -

- t ......... I' ............... i .........................................................................


1 ~-- ..... :~-::;~ ............ .:i: ;: ....' ::::. . . . . . . ~ ............... :................................... ; ..................... - -

0.1- 1
't9......................................... ... 'i- ::::::::::::::::::::::::::::::::::::: ...................
................................ i;;; .... ............... ,.

- ......... ............ .r ..................... ;.................... ~, ~, J-

= m
-. . . . . . . . . . . . . . . . . ...... I ..........................................2" .~---"~ .................... '

ID. 0.01=

_
'
~ _ ~ ~
i.......................................... -,

! i
0.001 -
| ~

O , i
c~ 0.0001- = ~ ~ .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...---,
> .
~__________~
L
.......... , ..........................................................................
|

1 E-05-
t'--"--'/~
,I.. __ -_=___- . .~ ............ ~,
= ....................... ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~

--I -; ............................... ~ 'i

1 E-06= - - ~ ~ _ : T . % ~ . ~ r .
t../_.
. ~ . ~
. . . .
~ ~ ~ ~.~
~
;_-~: ......... : ............ -----= ...........................................
L....................................................
..t~""~,::~:"~::~
_! 't ............................................
,=.
~; ", , ~ - - - - - - 7
......... -___;;___- ......... __ " -~ ! . . . . . .-. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . . . . $
--
~ _ ........ ~ ................ 9 . . . . . 9 .. , .:
....
-- ... _. . . . . . . . . . . . . . ------~ --~ ......................................................
i=

i .... i
= 6.895 kPa
1 E-07- . . . . . ~ ! ! - ~ i - ~ : : i ~ ! ~ ~ ' ~ = 51.71 mm a g
.=
~ L,III~;;;[IL'L;: ;/i??;;;;;;:??;: :' LI;:?;: .......iil;"i ............... _-iii;; ......... 7:'_ ........... i:i:i':~-iiiiii14~
/ i i .............................. i ................ ,_L_
................ i t [ .... i ~
i I ! i
1E-08 I i i i i I
500 1000 1500 2000 2500 3000

Temperature, F

3 0 5
~. ...... ; ~ ....... ] ............. i ~. . . . . '--t ' , _ :___-:_:;;;-_::;:: ................ ;_ i.

Sn -I-IN ................................................................... :-

............... i i... : ....... /i/i ,+ '


i ..... 9 ........... : .... : ......... ~ _ 9 -- . . . . . . . 1

9 . . . . . . _I .. ; : . . . . : . . . . . . . . . . . 7 , ............................. -, .... -- I

1
......... : ..... . .... : ~ : . . . . . . ~ ,

- - ' - - - " i .......... '" :" : / ...... 9 ++ !

.- " . . . . . . .
;
.. . . . ;7 ...:
/ , i " ....... +, , ............................................... ..,

,~i li _- . . . . . . . . . : ' ' ~,..- ~ ......... ~ .......................... I

0.1 . .
~,+-".:'. . . . . . ., . ......... : ...... : :-::-::
+ . . .: .: ; ; / .... , - ...... : ! ............ ..... ::::: + :::: ! ............... _+-=.;
_ 9 .... I ..... : - -- - - - q P , I
9 ! . . . . . . . . # ...... . . :/..;, . . ...... t " ' . 1
~J -" ; . . . . . . . . . . - 9 i[ .... , , 1
i ~, , i ; ........... ~ , ; .............................. .IP i 1

9 ....... _, . . . . . . . . . . . . . ! / . . . . . . . . . . . ; , l+ 1
. m

ID. 0.01 -
_, .
' ... ..... i, ..
... ......... " ..... i_ ............. ,i .......
. .......
:+, . . . . I..:L:.S::. "
.+ ....... i-: :-:++~::--+~--++++++:-+=:::-::::-
......
............. +, .............................
_ ....... l,
. . . . . . . . ; ...... ]:- . . . . . . . . . . . : , 9 ................. [ , - . . . . . . . . . I
m,
_1 .... i .' ]" ; . . . . . ; ........... ! - " + . . . . . . . . 1

l,_._
_. _, . . ; ~2" .. l . . . . . ; ........... ,-i i 1
. /

i i i .... , / . . . . . + ........ : . . . . . . . . . . . . . . ; ..... , ............ - . . . . . . . . . . 1

/
Ir

- . . z..'.. ! ; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , .. . . . . . . . . . . . . . . . ;
- . .........
_ ", " / .... i ....... .! . 1. .... . :.. ', ......... . . . . . . .

~__ . - : : . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . 1

13_ i - ....... " " 2 - ; . . ; .................. :! .................. 1

L _ J. .............. : ; . . . . . . . . . . . . . . . . . . . . . . . . 9 ........... 1
/
0
..........
9 / ........... ~ ...... :.... ...............
+,
I:::). 0.0001 .~ . . . . . . '
..........._ ,

(1:1 _--7,- ..... . i ..... : / ................. 9 ....... . . . . . . . . . + :!' . . . . . . . . . . . . . . . . . , I


'-9 / ' ' I . . . "
. . . ~ , ' ......... ~ ' ..... ' ", . . . . . . . . 1
i
i I ' ' ....... : ........ " '
_1 _9 + ......... . . . . . . . . . .9. . . . . . . . . . . . ~ ............. - - ................ 1

- / 9 _" : ......... ; . 1
/

IE-05~"~ ......... /+ ::::..... +-: ..........:::: ........... : : : : ~ : ' + ............ i ...................... ;

9 ' .... ~, ; . . . . . . . + . . . . . + .......... . ..... ~ -_:i_;_;_:-- ,_................................... ,


_. ]' _, ..... : . . . . . . . . . ,[ ............

...

1 E-06 ~,. . . . . . . . . . . . . . . . . . . . . . . . . . .=. . . . . . . . . . . . . . . . . . . . . . . . . . . . . f- :'----.-::- ...................... - - : . . - i . . . . . . . . . . . . . "-- ...... - .... = ' : ~ - . . . . . . . . . . . :'---:"-":::
? 9 .......... . : . . :---:. ....... . ..... : ............... :_::_::::_~: . . . . . . _........................... ,

- / ...... . .9. . . . . . . . . . . . . . . . . . . . . . . . . . i .................... '

/ 1 psia = 6.895 kPa

1 E-07 9 " : -- :_~, ... - ...... [


1 psia = 51.71 mm Hg ......................
: ......... :
: ............ . . . . .

~ : I .... . . . . . .

% l ; ............. ___.+
- - . /

_ .
,r

1 E-08 1 I I i i i i I

1500 2OOO 25OO 3000 3500 4000 4500 5000

Temperature, F

306
1 O0
9 , , - |

i
SnBr4 STANNIC BROMIDE 1 ...........................................
i
9 , .

. . . . . . . . . . i . . . . . . . . . . . . . . , . . . . . . J . . . . . . .

10
P-

I
i
I i

tO --T T

i i
,,m
(/)
CL i
1
(1)
!-_
!

O9 {
!

(1)
1 :i

i
- - - - I

13_
I,-
0
CL
i i i--
4
tO i
!
i
,| i
>
i i
i
J
i

i
I

!
i
! !
0.1 9 ! | 1'
qp

................................................... t ............................. | %

! T

.............................. ................................................. !. . . . . . . . . . . . . . . . . . . . . . . }

i l
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
................. I . . . . . . . . . . . . . . |z - --

0.01 I .......... i .....................


i!
!

I I I
1 O0 150 200 250 300 350 400 450

Temperature, F

307
100~ _J . . . . . . . . . . . . . . . . i . . . . . . .
IF
LIII? ;IIIL LI IIILL i ~;il i il il I,II~T==IIII ~ ....... iiiiiii ....... i"~i=ii .......

8nCI2 $TANNOUS CHLORIDE i . . . . . . . . . . . . . . . .

10
......
, ~ - ~ - - ~~ii
".......ii~'
. . . . . . . J

f
I i

/
ffl /
r
,/
L_
....... I " / '
13_ /
. . . . . X
0 /
/
>
/ _

/J
0.1 LJ

~ / J

-r
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

0.01 I I
600 700 800 900 1000 1100 1200

Temperature, F

308
100
IL l

ii iiiiii:ii:ii...... iiiiiiiiiiiiii!iiiii. . . . . ==i~iiiiiiiiiiiiiii..............i i


SnCI4 STANNIC CHLORIDE I . . . . . . . . . . . . . . . . .
[ iiii ................. ii ii~
I . . . . . . . . . : . . . . . . . . . . . . . . . 4

10
V ii i iii.iii_

03
C}.

(D
t=,,

03
03 , i~/.....
i, iiiiiiiiiiiiiiiiii~i
......... ! ................. ii ......................
(1)
t__

n
. . . . . .

/ " iiiiii
t.._ / 1
0 l
Q.
.! iilvvvi i . . . . . iv
>

0.1"

/
.... i ~ / ......... iii.......i ..... :

. . . . . . . . ,,,

.... i ...... 1 psia = 6 . 8 9 5 k P a


1 psia = 51.71 mm Hg

i
J i
0.01 I I I i
-50 0 50 1 oo 150 200 250

Temperature, F

309
1 O0
,. . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . .

SnH4 S T A N N I C HYDRIDE

10
7
p ~
J
/

. m

t~
Q.
fY
CD /
u~
u~ _ . . . . . . . .

(D
!,-

13_ J

/
t=..

0
Q. . ........ / '. . . . . . . . . . .

/
>
/

0.1-
W,

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01
-240 -220 -200 -180 -160 -140 -120 - 1 O0 -80 -60
Temperature, F

310
1 O0
............... , i.... IIII................................. IIIii iiiiiiiii ............... Ji ...........................
_ iii ...........................................

$nl4 STANNICIODIDE

0- , !i~7 ....................
t ~

u}
i
. . . . . . i. . . . . . . . . . . . .
~
i - i
~iill
...........
i
CL l

O)

U)
..
o9
(1)
L _

13_
f
L _

0
CL - / 7 i
>
/ I
i
' i i!
i

0,11 ~ ! .
!

! ................... 1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
r .

I I i

I ii !1
0.01- i i
300 350 400 450 500 550 600 650 700
Temperature, F

311
1 O O ~i~i~ ~
' ~ ii ~: i i .... :::::: :] :::::: :: :: ~i~ii ii~ iiii

r n . . . . . . . . . . . . . . . . . . .

Sr STRONTIUM
I
10~ .....
n i! |
II :lll .............1 !L'll I ll::ll::::
:l " l l l l l l ~ ~

~_._-_ii~ix~_i - illi_L -ii_ii_i=_ -i~illli__ -L_-- y;_21_: i-Ti}Li . ~ 7 1 7 _ 7 . ~ ~

.... [ __ _ /

-/ .......

JE_
- _. . . . . ~ . . . . . . . . . . . ~ z _

. . . . . . . . . ' ... I
/

/
. . . . . .

. m

c~ 0.01__ ..... : .... /


/ _
/ _ _
J,,

9 =
(D
. . . . . . .

L_
/

(D
I,... i _

n 9 . -

f
. . . . . . . , , ,

0
c~ 0.0001 / ~ -- _

> I
I ! ........ ...... - .. ::: ....... : ..
. . . . . . . . . . . . . . . .

I . . . .

1 E-05 j J/

1 E-06
./
i
_ i
!
!
/
1 psia = 6 . 8 9 5 kPa
1 E-07 - / 1 psia = 51.71 mm Hg

" !

1 _
[
I
1E-08 I i i I
500 1000 15oo 2000 2500
Temperature, F

312
11 1 . . . . . . I __ t _ _ I ................................... ! ....

I ' ' i! ........ 211__illl111221......il]L2 .................................................... ! ...................


I SrO STRONTIUM OXIDE l[ .................. l ............................................... 1.............._------------/ ............

1 ..... .... iiiiiiii i iiiiiiiiiiiiiii LLI iii .....iiiiii ii I XIIIIII ..........

7 ...............................................

!
. m

09
T
Q.

(D
L _

09
Q I / '
..... iiii i iiiiiiI ~ iiiiiiii iiii1 __ Z___itli iiiiiiiiiiiiii
L _

13_ !
_ ii
!
L _
ii ......... i ___i_I ...... ........ .........1 __/_ ........ I ...........................
0 !~ I'
El. IIZLLIIIIIIIIIIIIIL .........!LIIIIII ii................ii .......I___i__/_ .......
>
...........__ .......1..... i............. Z .................i......... , =

! /_I ............................... t

i . . . . . . . . . . . . . . . . . . . . . i/ "
I

1-iiiiiiiiiiiiiiiiiii-iiiiiiiiiiiiii
iiiiiiiiiiiii_i_
_i_iii_iiiiiiiiiiiiiiiii
. .i._.i_ii.i.i.i.i.i.l.i._.............
_i..i.i :
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

i i
0.01
i!
I
!I iI
3700 3800 3900 4000 41 O0 4200 4300 4400

Temperature, F

313
100=
i I
. . . . . . il '

1-a T A N T A L U M
/
..... :::~ ii:::: :::i::i ....... : ........... ! ...... ~ : .... ~ ...... c ~ ~; ...... ........ ;;:i:;;i ...... ;ii!!!!!;!:;:!i!!!!;;;~:!!-!~!:::.~i;!; !!!!!!!!;;~;~;;ii!!!!;; ~---~..... :~

i ~--./-
/

..

, /
0.1 -"- .......................... i .................... ~-~!~;~ : i ~ i~i!~!iiiii,i~i!!:_iii,ii~;_!:_ii,iii!~!;_!!iiii~i!~!]iiiiii!~!!!]i......... :................... ::::,::_c:_.::..................... ::::

_- ~ . . . . . ,.f" .i:i iiii iii iii ........ L.,:,II ~i .......... i i~ ! ........................ i~


. . . . . . . . . . . / . . . . . . ..................
. m

/ .
n O.Ol
9

(1) -_ ~ : / " ii~ i~i i i /iiii ://'iii iii'"'i ii/" 'ii//::ii/!i:iiiiiii:iiiiiiiiii'.:iiiiiiii.': iiiiiii/:::iiiii .... :iii

/,
/ . . . .

0.OOl :_. /ill / iii i iii. . 9 9 .. . :.

:~ ,, ~:~,:,;~:~:" ~ ;' ~;.... ~::: i ,/i :~ii i ~I ] . . . . . . . .


n 9 . . . . . . . . . . . . . . . . . . . . . . ,, . . . . . . . . . .
- . /

0
/ '

c~ 0.0o01 k

> i

m . . . . . . . . . . . . . . m . . . . . . . . . . . . . . . . .

/
1 E-05 ..... ~ /

/ -

1E-06 i!i ~/
Pd
|
iiii i/
1 psia = 6.895 kPa
1 E-07: / 1 psia = 51.71 mm Hg

:/
1
4000 5000 6000 7000 8000 9000 10000
Temperature, F

314
:
,!
I

10
m

0.1

O. 01 _= ,,m,~r~~mi~T--~-..-.-~.~--!!! ................................
- t " i i -------~.-_-.,,
0.001 -= = =L=== F ~~ZIZI~________
- - - - - ~ - ~ ~ ~ " ! ! - ~ - ~ ~ . . " = = ~ r ~ ~ ~ = ~ ! ! ~ " ~ - ~ - ~ - ~ ! ~ - ! " - ! ~
, , m

O9 "= .

ID.
O. 0001 = ~.----.-~.'.=-~,'-~---~'---~---
ID
:D
In
1 E-05 ' ' ', ----------
ID
______1~ It
I,.,.
13_ -- ,.____
K--
O
E-06 = -~ ................................................... i
=_ ! ................. :
ID.
- t ~ ' i

_ ____~..------=_~ .~
~{~!~:=:::~==:===.-..--::=::::::::::::z:=:
!~ .............................. ~=:-"=.====:

- r----r t , , ; I

1 E - 0 8 _- ~=..~--F.!!:!=~__.==..._.__.;:_._::~__-_:=!_,=~_====_~-~====:__...._~_
4 ~
t .............. :::::::::::::::::::::::::::::::::::
, ......................................
~ , _ ___
, ..................
.................: ~ =::~-="=:="====--==
, ...........

E-09- , ~ ~ ~ ........I

-- !. Lri ................................... i, .................................. i,


1E-10

1E-11
- ====~ ............... ~ ~ i - -

- t
1E-12- |........................................ ~.......................... f
2000 3000 4000 5000 6000 7000 8000 9000

Temperature, F

315
100============= . . . . . . . . -] . . . . . . . . . . . . . . . i ................. i....................................i ...............................................
:f===:=:-~:~==---==== .......=l
i ~ I ,
Te TELLURIUM
r r ~
0 _~ ~ -,, ,~

i ~ f ..................... 2' . j ~ '

- ~ J - 5 9 9 ...................... 9

_ _ .

9 ~ z . . . . . . . . .

O, 1 ........... ~ 9, , ~.

] /1 ........... i -i
,m

0.01
- ~- -/I : ,.~ .........
Q. - ~ ~

/
/
t.._
. . . . . . . . . . . . . . . . . . . .
i t
O3
Q)
0.001 . . . . . . /

/ :
i._ ,/: , i
13_
L_
0
cl. 0.0001
.

-
/
;_

r
>
L /
[/
/
1 E-05
~, .......
/ . . . . . . . - . . . . . . . . !

9 /
1 E-06-
...~. ..... l

/ !.......... ! ' ! i ..................... i _ ' "


J,,, /

,E o7;, J
1 psia = 6 . 8 9 5 kPa
1 psia = 51.71 mm Hg

.... jlr ....


/

1E-08 I i i i i i t i i
400 600 800 1000 1200 1400 1600 1800 2000
Temperature, F

316
1 O0
i !
I

TeCI4 TELLURIUM TETRACHLORIDE

...... :_. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j

10
. . . . . . . . . . . . . . . !

, , m

r~

(D
!,---

:3
iiiiiiiiiii~
(D
n
!,-- i . . . . . . . . . . . .
/
0 i
13. , !

>

....... ! ................ / ii~III J


.......................... j ............................ ~. . . . . . . . . . . . . . . . . . . . . . . . . . .
!i! ii I i . . . . . . . . . .
..................... i ................. 1...........................................
: : - t i

!
........... I
!

z 1 psia = 6 . 8 9 5 k P a
- /
........ , 1 p s i a = 5 1 . 7 1 m m Hg

o.lL
1

i i
i.
! , 1
I I
450 500 550 600 650 700 750

Temperature, F

317
100 ,. ~ ,
9 , ' ' " ' ....... ]i-i;;; "7 ..... i ......... ..,, '

TeF6 TELLURIUM HEXAFLUORIDE ~ ,i

!
i r

10 .......... : ~ i
i !
; i
J ~ L."
"G . . . . . . . . . . . . . i i .....................

!
f

L ! t. . . . . . . . i ..... / ,

. u

O3
Q.
/,; ...................................
J
(D
t__

09
O3 <. -: '. . . . . . . . . . . . . . . . . . . . . . .

(D /

Q. ;;i/ ; ....i 84I;,IL;;I .... ;' iiiiii ..... ;iiii i.;i i,


t.__
l
O t
O. . . . . . . . . . . L L _ . . . . . . . . . . . . . . . . ~. . . . . .

>

/ IF
!
0.1
_i/17111111111111
/,i ......
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

i i
0.01 I i i i I
-180 -160 -140 -120 -1 O0 -80 -60 -40 -20

Temperature, F

318
loo ............ ~!~ ! ! ~

1- - ~ -_ ~ ~. ~ ~ - - , , ~ - ~ - z - -.~--------

] 4-.........................................................................
, , m

ID.. 0.01
!
t--'7 ------T

-I t
(1)
:3 ........................................ '-, .....................
In
(/'j 0.001
!
~------..~.
~
9
~.:~ ~ ~ : : ~ ~ ~..~
[
~
~.-_.~..-::...-=_.--::=.=
i
~ . . . ~
r
~ ~ ==:_.~------------~
:
s
(D
!.-

13.. i t ~[ .........
.............................................. .!}

0
ID.. 0.0001
>

1 E-05 , !

' F-----
! i
1 E-06 [ ......
,1.
--!.----------
............... " i . ~ i . . . ~ i . . ; i ~ ; ; ~ ; =
,l-.-. . . . . .

t
m
I----

1 E-07=
1
!. . . . . .
1 psia = 6 . 8 9 5 k P a
1 psia = 51,71 m m H
l....--re.,

, !
1 E-08-
2000
t
2500 3000 3500 4000 4500
I
5000
I
5500 6000
Temperature, F

319
-! ' a J n ] , e J a d U J a l
OOZ oog oo~ oo17 ooc oo~ ooL O0 I.-
I - LO0"O
......................
6 H uJus LZ" Lg = e!sd L
edit ~ 6 g ' 9 = e!sd L
........
9 L
. . . . . . . . . . . . . . . . . . .
1.0"0
i
/
/
I
.......
L
J I
I
L'O
<
,/ 0
, /
/,, ....
..... ..,/ :L
(1)
f~
Or)
/ I=:
/ (1)
/ w i
"O
m , ,
.......... , .: , : .: . / : ............... l
E
........ / , . .
i / l ,,
01.
. . . . . . . . . .
i. . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . .
..... ~ / . . . . . .
.......... ~'i .
.~. . . . . . . . . i. . . . . ~. . . . . . . .
,,
~.~" . . . . . . . . . .
/ ' i. . . . . ':',": . . . . . . '"
O0 I.
. . . . . . . . . . . . . . i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1111111111111111111111111111// 9 .
3CilklO-IHOVkI.L3.1. ~nlNVJ.IJ. tlO!J.
/
f !
I ..... ,,i ~ ,. . . . . . . . . . . . . . . . " ............ , !
0 0 0 I.
100-
A::: !ii!!!i LL L:!:!'::_,
-J i iiiii-- ii 31

LI'IIIIIILIILL _1TI THALLIUM

1- ....... ~ G-~----====-~ =----

0.1-
i i !i! !i ! ! : ':!!;!!: :!:: i::~Z:i !:: ! ! ii !!: ! : Li:~ ~iiiiii:::::: i : {i :: !:i:L::::;::: iiii ~ ....... ===================================================================
I

..... ! / [
ZK , [~ ...............
. i

r
0.01
--A-
(D ..................................... !

L_

09 ....... i .................... i, i9
0.001
(D
n
L _
iiiiiiii!!!!!i!!i!!~!!!!!!!!i!!!!~:J!:~ii~iii!i!!iiii!!!!!:::~:~
....................
!I!!!~~-~---2L~.--.----~~_'~-~_~_.~.,
! ......................................................................... ! . . . . . . . . . . . . . . . . !. . . . . . . . . . . . . .
:!
t.._
0
Q. 0.0001
>
iiiiiiiii iiiii}iii ii iiii i~iiiiii;i;iiiiii iiiiiiiiii LIIIIIIIIIIIIIIIIII ~
...... t ...................... i
1 E-05-

! '.

1 E-06 ! L
1 psia = 6.895 kPa
1 E-07: 1 psia = 51.71 mm Hg

[
| . . . . . . . . . . . . . . . . . . . . . . . . . | .............. 'i'"

! ....................... !
! ! I!
1 E-08 I I I I
500 1000 15o0 2ooo 2500 3000

Temperature, F

321
100 ! ! !

TIBr THALLOUS BROMIDE


I

/
/
10 /

cU
o9
Cl.
/

J
CD

CD /
i 9 iiii ii ii
!,__ /
0
Q.
/
cU
> /
/ 7
/

0.1-~
9 J ,

- I

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
I r

0.01
900 1000 1100 1200 1300 1400 1500 1600
Temperature, F

322
1 O0
9 . . . . . . . ~ ~ ! .....

r 1
fil THALLOUS IODIDE i
7
| II

J
4
i
i

10 r.--"~

i -7

r-7!
= m

Q.
(D T7 i ......... :'
z~
I,...

A" ! I
........... i / ~ d ~ .......... !............................ I ........................
L_
/ IZIIIII
f~ ............. iiiii I ..........
~_ __ ZI .................iiiiiI__iiiiii
....................
IIIIIIZIII][

0
/ ! . . . . . . . .

ctl .....................................................................
z_______:::::: ............
:--:--:::::::
............
,......................
........ ::
:--" ..................................
4 ...............................
>

0.1 iiiiiii~ i ,- - - ~ - ......... ~,i


i .................................................................................................... i

/z i 1, '!
. --Y ........ i
\84184184184184184184184184184184184184184184184184184184184184184184184184184184184184
i
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i ........................

I i
0.01 I i
II II I
800 900 1000 11 O0 1200 1300 1400 1500 1600
Temperature, F

323
0.01 ~:: :: -::::::: : -:: ::::: : :: :::::::: _ ::::::: : :~ : ::::: _ :::_::: ::: _::::::::::::::_: . . . . . ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ................... -. .......... .-_: ......... ---- ......... --: ........

i: : : : : : : : :: :I:::::_ : :::::___ ::::::: . . . . : ::: ........ ::: . . . . . . :: :_:.


] : ~ : . . . . . : : _ :. _ : :: . . . . ~ ................................................

Tm THULIUM
0.001 9 ~:::
L

0.0001 . . . .

:: ' : ::! :
:

:!:: ::: : , ::: :::


:

!:ii:::!::::: ::
:

::::::::::::::::::::::::::::::
:

::::::::::::::::::::::::
.... :,..-

.,t:____":_ ::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::: :::::::::


:

:::::::::::::
= ::, . . . . . . . . . . . . _

j-

1 E-05 . . . . . . . ....................... . . . . . ,
:::::::::::::::::::::::::::::::::::::::::::::::::: :::___:_:::::::___ :::::: ...... :::::::::::::::::::::::

. m

09
EL
1 E-06 ,,, : : :::: : ,z
L/
i::: ::: _::
:::_ :::
_
:
: 12 : _

(D
. . . . . .

/
:0
O3 /
09 1 E-07__ ;
,
. .': : :::::: ;7!!.'. ..... - :::: ! !!!!!
(1)
L _
' : ...... . . . . . .
/
/"

13_ . . . . . . . . . . . . . . . . . . . . . . . . ~ ~ . . . . . . . . . . . . .

/
L_

0
, /
EL 1 E-O8 , i

~: : " : :. . . . . . . . . ,,,'.i
> ~::: .......... :. . . . . . . /:L: ........ . . . . .
.,,/ . . . . . . . . . . . .

. . . . . . Z . . . . . .

1 E-09:- . . . . : . . . .

..... / . . . . . . . . . _.,,.

/ , r
/

1E-10--,
/ : . . . . . . . . . .
:1 . . . . . . . . . .

..,~ ,~ ] t/ . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i L
1 psia = 6 . 8 9 5 k P a
IE-11 ~;: iiiii :::i: . . . . . . . . . . ........ ............ .......... ~...........................~....................................... - - 1 psia = 51.71 mm Hg
. . . . . .

~I

1E-12
................................. i

I
600 800 000 200 400 1600 1800
Temperature, F

324
c_;zE
-! ' a J n : l ~ J o d w a l
O00L 0099 0009 0099 0009 009~' 00017 OOCJ8 00013 OOSE 000;~
I I I I ! ! 1 80-=I ~
I
!
......... i ....................i / ......................
................ 7 ........... -it ....... ...... ....
i .... ~ ._ - ir _ - -___ _
i . . . . --: ................................. #~, --- ---- --
~ H UJLU I.Z" 1.9 = e ! s d I.
e d ) l $ 6 9 " 9 = e! ~Id I.
. . . . . . . . . . . -.................... ; . . . . . . - ............ _ - ...... ,- ...... - __ ...................... .................. i ...................... /-__i ...................... 7-: ...... __
,I i_ / I
........................ ___~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I . . . . # I . . . .
......... I ..... I...;..--~ ............ _ -
i- - ..... ! ..... : .......
,.~- ................................... -t_......... :---:--
17ZZZU_-ZZ-;_ZZi ..............
|. i
i t ] ; : ] 3r [ ] : ]
<
1.000"0 "~
0
""I
i ~ i ~/ii .... i ?,,,, . . . . . .
~ZI=ZZ:ZZ--~ZZ~.[ZZ7
................................... ====.................
/= .,-I--.................................
iY:::YI::TZIZIYZI:7:71iI7YYZYZ:TZTI 71 :::::/ i ~ii]177ii :,,:,:,:1117 ii : ,,;:::i ~i i ......... i i,,
"D
~-~`~~!L~``!!!!!~!~!!!7~:!!!!!!!!!!~`~~~~::::::::~!::::!:!!-~!!>:~!`:::::!!:~`!~!!!!!>>1~!~:~!:!~!!~!
............................................ i- .................................................................... _. i_ .............. ~

!!!! ~ ::::::::::::::::::::::::
.....

: : :::k! !!!!!!i !!! ! ......: : -


::_: . . . . . . . . . . . . . . . . . . . : : :____::::::::: . . . . . . . : : :::. . . . . . . . . . . . . :___:: _:_:::::::::::::: ....
Q
!='====--i . . . . ~F--~i' i i : : : : : ~ ~ . i. . . LO0"O u)
(/)
L ................................................................... t
c:
!.
E)
: IIZZ~Z~U---2-Z-_~SZIZ:::iZZZZ::::ZiZi::::Zi:iZiZ::~ IZZZZZZ:ZZ!ZZZ:ZIZ:hI~Z2:Z22ZZZZZiLZZZZ:51111Z~ZZ:ZZ:Z!ZZZ5515111115Z-_-_:: Z
"0 "1:3
fJ)
i' " f:
--7zj
! i
i / " i ..... !................
i
-_...................................
::L.................................... [ ..... : I:Y: / ~' J,
-- .................................~ ..........:................ ~ -z ' ;~ ::; _ i ~! " ..........
. . . . . . . . . . . . . . . , . . . . . . . . ~ . . . . . . . . . . . . .
i ...............
~__: ............ ...... ] ....... r . . . . . . iii .....
~L'__--=..--='....~
...................................... "................................................................................................................................................
:L_~i........
-.........................................
~...............
~ ...........
~......
~:~ .....................
i::'--O I"
~~ i :: ' ~ '""'
I
t 1 ,,, ~ IAlnlNvldn A i
-.............................. ~
l . . . . . . . . . . i . . . . . . . . . ~ . . . .. . . .. . . .. . . . . . . . i. I
i. . . . . :. . . ~. . .~ . " . . ....... ..; ......
~ ',~7::: ~ .......
. . . . ~ .....
. ,i ;,
, : . . . . . . . . . . , .... I , '"
; ..................................... ~00
100_~
, ! I ............... ........... i .... ii ...................
,, 1 J
~ ......... t! ; ........... ! ......................... J

UF6 URANIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,.....


9 , i ....................... ------~ ....... _. . . . . . . . . _ ..... , ................. ,._.__..j

. . . . . . . . . . . . . . . . . _ .........................

0 ....
~., H i
J
............ i . iiiiiiiiiiiiiiii
/

.... .....................................

J
. u

Cl.

(D /
li..

::3
tn . . . . . . j
.. . . _ .........................................

(D , , , / '" [

1i,..
. . . .
n
L__

0 /
/
GI
> ..</

. . . . . . . . . . . . / ....... i
L
i

i/ ..... ~ :

. . . . . . i/ ................................ /

/
:: ............. L. . . . . . . . . . . . . . . . . . . . . . . : ...... .............................

Z
! ....................
i ................... ! ............... i

/ l
i

1 psia = 6.895 kPa


1 psia = 51.71 mm Hg
i ..... :. . . . . . . . . II .....

0.01, I i I I i I I I I
-40 -20 0 2O 40 60 80 1 O0 120 140

Temperature, F

326
1 O0 ...................................................................................... . . . . . . ~, ,

10~-------

0.1~ i

. i

O3
O.01s i

, i

ffl
0.001 = i
i

n_ ==

L_ ..=
iI -
0 !
0.0001= i

>
i

,i,

1 E-05- =.
.....................................

.=

1 E-06=
f
=..

~
t
i

I
[-!
1 psia = 6.895 kPa
1 E-07= 1 psia = 51.71 m m Hg
..=

! ! .
t i .............................................. + ...........

E-08- i I i
2000 2500 3000 3500 4000 4500 5000 5500 6000 6500
Temperature, F

327
8;~;
-.! ' e J n l e J s d L u s /
008 OOL 009 00s 00~ 008 00~ O0 I. 0 O0 I.-
I_ LO0"O
6H LULU LZ" Ls = e!sd L I,
ed)l s = e!sd L
mi
If&IIIIiII
,,,,,,,,m~ i t - . . = = . - .
mvAIllmmmle
LO'O
!......... //
/
/
,,,
I
L'O
"1:3
...... ,/
0

/
"13
, .,/ , (I:)
-I. Or)
Or)
E:
0
/
i

/
/
'13
/ ,,m,~ e
....i.... L ~ ....../ .............
/ " ' -01.
.....
,, . . . . . . .
9 /
mm
,/
i
...
J ..,
jr ..... ,
11 :00 L
Z ..~.
3ClII:IO"IHOVI:I.I.31 IAInlGNVA ~IOA "
. . . .
I ~ ~ :,.,,.,,.,
mUU U I.
! i !
VOCI3 VANADIUM OXYTRICHLORIDE

.=.l

09
(D.
0.1
(1)
L._

:3
09
(~
t__
rl
t.._

0 0.01
(3.
>

0.001 L
i
{
?
!
- ~ ~ |

0.0001
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg

i !

1E-05 ! [ f t
-,so -,oo -so o so ,oo ,,o 2OO 25O 300
Temperature, F

329
............................... i ........

!
I I ....................
I W TUNGSTEN !
lo I I .......
f . . . . . . . . . . . _-___=__:_= . . . . . . . . . . - ....

- -~ , , --1 i
~ L ...... ;;--- =======================
F ' .... J..............117
J
F; ~ - -
~ ~,~, . . . . . . . . . . .

] J _ , .... - <,

: . . . . . . . . . . . .

0.1 _ ........ .........: ~ ~. . . . . . . . . . . . ,: . . . . ; :: . . . . . = :,.:~i~_-:--~,~ --:


. . . . . . . . . . . . . . . '~i~,,, r-- ..................................
/ ......... /iiii~iiiiiiiiii iiii~iiiiii IIIIIIZ~IIIi iiiiiiiii~iiiiiiii
(#')
= m

C1. 0.01 . . . . . . . . -'/ ~ ~ --


--_ _ _ -

/
I !

~
-
, .
' '~.....:: 17
. . .
'; ,,,,',L---'l
. . .

9~ :, , " ;, / " "i": .... ' ....... : . . . . . . . . . . . . . . . .


i/) 9 / ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

(/}
. . . . . . _-
. . . . . . . . . . . . . . .

13., -- / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-- ~ _

~ - ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ . . . . . . . .

0 /
0.0001
,,,~. ..

>
, , , / , , 9

-- / it" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . .

1 E-05 _
. . . . . . .
.
. . . . . . . .
. #
;;,- . . . . . . . . . . . . ~ . . . . . . . . ~ ,,, , ...... ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

- / . . . . . . . . . . . . . . . . . . . . . . . . . . ,,

_ / _- . . . . . . . . t~ . . . . . . ... ' ..... . .. " . . ' ....

__- .... -/ / ..
,
J

1 E-06 ..... / _ - _
,,
/ . . . . .

'i!.,, ~~__it 1 psia = 6.895 kPa


1 E - 0-". - ~-__--_-i / . . . . . . !1 ' : 1 psia = 51.71 mm Hg
# . . . . . . . . . . . . . . . . . . . . . . . .

1E-08 ~ i I i I
4000 5000 6000 7000 8000 9000 10000
Temperature, F

330
~
100:]
t [ ]
WF6 TUNGSTEN FLUORIDE

10-=.

.m ..= "i I
O3 ....
!
T
i
Q. ! t
i t!
..=

(1)
t__

i i
03
09 1- --i T
(1)
L_
I
!
1

tl =.,

t_..

O
Q. L ..........

03
>
i
t
i
I
i I
i i
! i
0.1-.................... ~ ~ --i
i I

....................... t
t i
| !

{ i
l
. . . . . . . . . . . . . .

i-i 1 psia = 6.895 kPa


~t 1psia=51.71mmHg
! ! I i
, L
i l
0.01 4
-100 -80
~
-60
I!
-40 -20
,
0 20
[
40
i
60 80
Temperature, F

331
1000

Xe XENON j/

/
/

/
. . . . . / L
. . . . . . . . . . . . .

.
t~
m

C~.
(D
:3
r~
o~ 1 O0
Q~ I
I
IL--
rl

/
I,..,
0
CL
>
tO
/
/
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i

10
-200 -150 -1 O0 -50 50 1 O0
Temperature, F

332
1 O0 ......................................

Yb YTTERBIUM
10

1, i. ! - -

t t !

0.1 i.

-------I
f--------i
-------i--~-~--
O3 [ ] .
~. 0.01 i. :t
---~ ............................ |

...... r ............ i 84
u}
m 0.001
i..............................
i
(D
..................... 4=-'::::=',~:=.~:=--"=:-'--::=:~ ~ ....................

i ~____q
i
13_

0
Q- 0.0001 I

>
! I
i. ![ ..................................
1 E-05 L ..........! ..................... &

; ......... ! .........................

I I I I

J ..........................
I~......................
i..........................
l
1 E-06 L-. .................
9
~ ......................
..
i
:,
'
9

I --" .... .= .....

~ T r------
' i i 1 psia = 6.895 kPa
1 E-07: 1 psia = 51.71 mm Hg
--------t
- - F - - ~ ]
b"-'--------'-----F ............... ~
i J !
i i i
1E-08-1
! !

t l t ! ! T
6OO 800 1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F

333
ioo~ L
YTTRIUM I
10
m

1=

0.1_===
.=

.=

Q. 0.01- u

(D
L_

O3 0.001= ..
L_

13.
L_

0
Q. 0.0001=
> m

1 E-05-

1 E-06-

1 E-07- ~ 1 psia = 6.895 kPa


1 psia = 51.71 mm H

1 E_08i
1500 2000 2500 3000 3500 4000 4500 5000 5500
Temperature, F

334
lOOOOO~
[ i t
Zn ZINC r-----1

=i
03

(D i +
L_
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill+l
!.......................................
i
L_

13..
t.._

0 t
El.
>
! t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

0.1
I_ ........ + _ . . . . . . . . ~ ...... i + ............. + .......................................................

i ...................................
i~ ...............
"!t i ..........................................
! !
0.01 'T
1 psia = 6.895 kPa IL------
1 psia = 51.71 mm Hg
!
']'

+ j

o.ool -I-
ii' I
!
50O 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500
Temperature, F

335
100-: , i

I1

ZnCI2 ZINC CHLORIDE

10-
J
9 j r
/

/
/
J
. m

co

(1)
u)
cO
(1)
13_
/
0
Q.
/
/
> ,//

0.1
/
il
/ J
/

, , . .

/ 1 psia = 6.895 kPa


1 psia = 51.71 m m H g

0.01 -
800 900 1000 11 O0 1200 1300 1400
Temperature, F

336
1 O0

F-
1 I i i ! 1.
ZnF2 ZINC FLUORIDE
.................... :-- .... t

10
+....................................
! !.
|

! 1

, 1

03
13.
t
i ....................................
i r i
(D i
V i i i
t._
t !
i i
03 i "
03
(D ............... ~ ........................~. . . . . . , . . . . . . . . . . . . . . k - ......................4
Ill

Q_
.....- - - - t = - ~ t -
t
=
.m__.~-i
.................

~ ~ i
i
................. -r.
i ...........
i
! . . . . . . . . . .
1
" i - - - - ~ - - ' t . . . . .
!._
' i i i i
0 i ..................i i [ .,
i / ! i i 9 i
! t iI
I i i
> ........................T. . . . . . , 4...................."...................T
i ,/ !
i
i
!
i
:
i
. t
I ' t ...................

, /i i i Ii ! i I I
, i ! i i
t i t

t I i' I i
I ' i t
0.1 i t ..................+................................
~..............................h..............................
-!..,
..................................... ~ ....................... ---:----i:. ....................... t-'-----------f . . . . . . 4..
. . . . . . . . . s ...... _.,__....~, . . . . . . :_ _. . . . . . . . . . . :~__ ........... :
' I 1............. -l', ....
! L ' :i".....................
!
.................................... i ...........................
!
t" . . . . . . !........
!
t - - - ~
i
L___ i , I -
i i
! !
i 1 psia = 6.895 kPa -~
1 psia = 51.71 mm Hg
/ ................................. =......................... :. = ~. . . . . . . .

' i i

'
|

1 i ! i
i
9
,
!
I ,'
i
0.01 I I I I I I I I
1700 1800 1900 2000 2100 2200 2300 2400 2500 2600 2700 2800
Temperature, F

337
8E~
..4 'a.Jn;eJaduJel
0098 00s 00178 0088 00~8 00 ~.C 0008 006~ OOBE 00/..~3
I I I !
I ' I.l." 0
J
, _j
, , 8HWW LZ'L~=~!sd L
" " 7 . . . . . . . . . . ~ -
!
~d~l ~68"9 = e!sd L I
r 7

t- .. , ,, .,~ : .....

/
, .
/
.... . . . . . . . . . . . . . . . . . . . . . . .
r T _
'r T -; .... : ,,, ,.'. . . . . '.

/r z , L
.i"
9 | / . . . . . ! .. 9
r 9 - ". . . . . . . i
; ....... .., / ! . n
/
It . . . . . . . . . . . . . . . . ........... 9 ........... r ,t . . . . . . . . . ; . . . . . ; 2. ; ........... m
a r
r'- ~ - .................... I- I ; ....... I ,, 4 / ! . . . . 1 ,, 9
[ ......... --- . . . . . . 9 - i
' '....... ; / / . . . . . . . . . . L
<
"0
0
'
~ i

f ''
-0
__~ .......... 9. . . . ; ..... _, (I)
C/)
C/)
9 ! ........... in
C~
.... x ........ n
i -- . . . . . . . . . . . . . -7
0
"0
9 ~ ,,, I c/)
m o
'r...............
r !iiiiiill i- iiiii ..... i : . . . . . _L
r ....... !
r I " ~ T
L. . . . . . .........i i~~ ,,ut-= ........... ; .n
: "OL
/
; ..... ; ...... : .... : ' 7 : ........ C
.............. ; .-: . . . . . . . . . . . . . . : . . ....... 9 ........... | ,
r , ~ "
J
r
............................................ ' .................
:v
[, ............. iiiiii
, i ...... ~ ............. I I
................. ::IGIXO ONIZ OUZ I
i '
.i . . . . . . . . . . . . . . . . . . . . . . . i
..... ' ......... I i ...... t ,4 ' lk_
'
............ ; r. . . . . . . . " i ' O 0
I00[ I
, ............ i i ....... '
'" I 9 " ..................................

I
i i
[ , I

ZnS04 ZINC SULFATE


tl

10
- - . . . . . . . . . . ~ - - ...... - - - ~- - " i .... " ......................................... ; ................................. ~ . ~. . . i . . , . . .. . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.,.,m,

_: I I . v ., i

l,=,,
............... i................ ~ ....... i ........... i ..........
/ ..........I t.................. t '

13_
0
. / 1 !
>
j i .
' 1
.................................................. - ......... i --- ~ ---- -- - ........ : ............................................. 'i ~|

..... .....!... 7 .........


!............................... ! . . . . . . , ,

I.........................

,
' i
i 1 psia = 6.895 kPa
. . . . . . . . . . . . . . . 1 p s i a = 51.71 m m H g

i ; I t
! .
!'
!
i
!
J
t
0.1 1
60 80 1 O0 120 140 160 180 200 220 240
Temperature, F

339
O#E
-! ' e J n l e J e d L u e l
0008 OOSL O00l 0099999 0009 0099999999 0 0 0 9 00cj17 00017 0098 000~ ,
l
-80-3 L
/
/
tO-3 L
edM 9 6 9 ' 9 = e ! s d
t ~mw =90-3 I.
.m
=s L
f
/___
Z <
- LO00"O "0
ZE 0
.m
.L l "13
= 1.00"0 or)
m
ror)
(I)
- 1.0"0 "tJ
Or)
i . ,
-" I.'0
I
"r------frO I.
IhlnlNOOl=llZ J Z ~
i L . _ . m _ _ ~
i
!
.........."~-"
......~ i ~ 0 0 I.
1 O0
. . . . . . . . . . .................. I ..................................................................................................

. . . . . i ........... I ............ I.......................................... ii~i~i ........... i ........ i ....... i-ii--i ......... iiiii-it ............. i ................ iiiiii-i ............................ i

ZrBr4

i
E

10 84 i . f ........
i r.......................................................~ * | ............................

, ~_.L,C,
~F ..... _

r
u)
.u
F

El.
(D
09
u)
(D
L_
13..
L_
0

> / J !/ ................................................
T.............
21~i
........i~=~ii:i~',-,.i
........ i /.,, ,,,, [,ii ..... ..... . ,

0.1 . . . . il/ ,,
I
illlllllliillliiiiiilZ
_ ililll Z i. .................i ...................
i/211__ii.

----------i -11 psia = 6.895 kPa


1 psia = 51.71 mm Hg

0.01 I
400 450 500 550 600 650 700
Temperature, F

341
1 O0 . . . . . . . . . . .

. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

ZrCI4 ZIRCONIUM CHLORIDE

0 .... tT /
.... J.

W.4B

.,, - , ~ ........... /

.
(0
m

09
CL

J
(D

U)
U)
G)
L _
/
a.
L__

O
CL
>
/

0.1 /
/
/ [ . . . .

....... / l

iiiii Z '~........
/ ...... 1 psia = 6 . 8 9 5 k P a

- .....
1 psia = 51.71 m m Hg

0.01
350 400 450 500 550 600 650
Temperature, F

342
1 o0 _
t

. . . .

/
Zrl4 ZIRCONIUM IODIDE

.......
0- ' '
,
I i i! __
_:::. . . . . . ::;___;___;__;____________i'.__'
.......
_ L- . . . . . . .,.i. . . . . . . . . .

!
I

................................................ / _ . . i i

u'l
, i

Q. ........................................ i

l..,.

t ,
O3
. . . . . . . . . !" ..................... 1! .......
.......

- - - - ! i - - t
ll.. ! l ! [ !
13_ ./ i ................................... 1. . . . . . . . . . . . . . . . . . . . . . . .
1
, _ . _ ~ i

/ i
! i
I..,,
0
Q. i

> i, // ' ! I

/
/ ......................................... : . . . . . . . . ~,, 4

1 l, '!
0.1 ........ .,, !
....
/ ! i

' ~ / '
- /
-- . 4 . . . . : :i
-- " i "'
/

/
.. i

........... 1 psia = 6.895 kPa


-/ 1 psia = 51.71 mm Hg
_

i
--i ....
t
iI !
I i!
I i i
0.01 i I I I
500 550 600 650 700 750 8O0 850
Temperature, F

343
REFERENCES

SELECTED VALUES OF PROPERTIES OF HYDROCARBONS AND RELATED COMPOUNDS,


Thermodynamics Research Center, TAMU, College Station, TX (1977, 1984).
0 SELECTED VALUES OF PROPERTIES OF CHEMICAL COMPOUNDS, Thermodynamics Research
Center, TAMU, College Station, TX (1977, 1987).
0 Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS,
Parts 1, 2, 3 and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).
0 Nesmeyanov, A. N., VAPOR PRESSURE OF THE CHEMICAL ELEMENTS, Elsevier, New York, NY
(1963).
11 Ambrose, D., VAPOUR-LIQUID CRITICAL PROPERTIES, National Physical Laboratory, Teddington,
England, NPL Report Chem 107 (Feb., 1980).
0 Simmrock, K. H., R. Janowsky and A. Ohnsorge, C R I T I C A L DATA OF PURE SUBSTANCES, Vol.
II, Parts 1 and 2, Dechema Chemistry Data Series, 6000 Frankfurt/Main, Germany (1986).
" INTERNATIONAL CRITICAL TABLES, McGraw-Hill, New York, NY (1926).
8. Braker, W. and A. L. Mossman, MATHESON GAS DATA BOOK, 6th ed., Matheson Gas Products,
Secaucaus, NJ (1980).
0 CRC HANDBOOK OF CHEMISTRY AND PHYSICS, 66th- 75th eds., CRC Press, Inc., Boca Raton,
FL (1985-1994).
10. LANGE'S HANDBOOK OF CHEMISTRY, 13th and 14th eds., McGraw-Hill, New York, NY (1985,
1992).
11. PERRY'S CHEMICAL ENGINEERING HANDBOOK, 6th ed., McGraw-Hill, New York, NY (1984).
12. Kaye, G. W. C. and T. H. Laby, TABLES OF PHYSICAL AND CHEMICAL CONSTANTS, Longman
Group Limited, London, England (1973).
13. Raznjevic, Kuzman, HANDBOOK OF THERMODYNAMIC TABLES AND CHARTS, Hemisphere
Publishing Corporation, New York, NY (1976).
14. Vargaftik, N. B., TABLES ON THE THERMOPHYSICAL PROPERTIES OF LIQUIDS AND GASES,
2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983).
15. Lyman, W. J., W. F. Reehl and D. H. Roserblatt, HANDBOOK OF CHEMICAL PROPERTY
ESTIMATION METHODS, McGraw-Hill, New York, NY (1982).
16. Reid, R. C., J. M. Prausnitz and B. E. Poling, THE PROPERTIES OF GASES AND LIQUIDS, 3rd ed.
(R. C. Reid and T. K. Sherwood), 4th ed., McGraw-Hill, New York, NY (1977, 1987).
17. Kirk, R. E. and D. F. Othmer, editors, .ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY, 3rd ed.,
Vols. 1-24, John Wiley and Sons, Inc., New York, NY (1978-1984).
18. CONDENSED CHEMICAL DICTIONARY, 10th (G. G. Hawley) and l lth eds. (N. I. Sax and R. J.
Lewis, Jr.), Van Nostrand Reinhold Co., New York, NY (1981,1987).
19. Boublick, T., V. Fried and E. Hala, THE VAPOUR PRESSURES OF PURE SUBSTANCES, 1st and 2nd
eds., Elsevier, New York, NY (1975, 1984).
20. Ohe, S., COMPUTER AIDED DATA BOOK OF VAPOR PRESSURE, Data Book Publishing Company,
Tokyo, Japan (1976).
21. Hultgren, R., P. D. Desai, D. T. Hawkins, M. Gleiser, K. K. Kelley and D. D. Wagman, SELECTED
VALUES OF THE THERMODYNAMIC PROPERTIES OF THE ELEMENTS, American Society for
Metals, Metals Park, OH (1973).
22. Simmrock, K. H., R. Janowsky and A. Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES, Vol.
II, Parts 1 and 2, Dechema Chemistry Data Series, 6000 Frankfurt/Main, Germany (1986).
23. Yaws, C. L. and others, Solid State Technology, 16, No. 1, 39 (1973).
24. Yaws, C. L. and others, Solid State Technology, 17, No. 1, 47 (1974).

344
25. Yaws, C. L. and others, Solid State Technology, 17, No. 11, 31 (1974).
26. Yaws, C. L. and others, Solid State Technology, 18, No. 1, 35 (1975).
27. Yaws, C. L. and others, Solid State Technology, 21, No. 1, 43 (1978).
28. Yaws, C. L. and others, Solid State Technology, 24, No. 1, 87 (1981).
29. Yaws, C. L. and others, J. Ch. I. Ch. E., 12, 33 (1981).
30. Yaws, C. L. and others, J. Ch. I. Ch.E., 14, 205 (1983).
31. Yaws, C. L. and others, Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984).
32. Yaws, C. L., pHySICAL PROPERTIES, McGraw-Hill, New York, NY (1977).
33. Yaws, C. L., THERMODYNAMIC AND PHYSICAL PROPERTY DATA, Gulf Publishing Co.,
Houston, TX (1992).
34. Yaws, C. L. and R. W. Gallant, pHYSICAL PROPERTIES OF HYDROCARBONS, Vols. 1 (2nd ed.),
Vol 2, (3rd ed.) and Vol 3 (lst ed.), Gulf Publishing Co., Houston, TX (1992, 1993, 1993).

345
Appendix A

COMPOUND LIST BY FORMULA

Ag SILVER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 CdF2 CADMIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . 70


AgCt SILVER CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 2 CdI2 CADMIUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 71
Agl SILVER IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 CdO CADMIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 72
At ALUMINUM . . . . . . . . . . . . . . . ................. 4 CLF CHLORINE MONOFLUORIDE. . . . . . . . . . . . . . . . . . . 73
AtB3H12 ALUMINUM BOROHYDRIDE . . . . . . . . . . . . . . . . . . . . 5 CtF03 PERCHLORYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . 74
ALBr3 ALUMINUN BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 6 CtF3 CHLORINE TRIFLUORIDE . . . . . . . . . . . . . . . . . . . . 75
A[C[3 ALUMINUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 7 CtF5 CHLORINE PENTAFLUORIDE . . . . . . . . . . . . . . . . . . 76
AtF3 ALUMINUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 8 CLH03S CHLOROSULFONIC ACID . . . . . . . . . . . . . . . . . . . . . 77
A[13 ALUMINUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . 9 CIH04 PERCHLORIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . 78
At203 ALUMINUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 10 Ct02 CHLORINE DIOXIDE . . . . . . . . . . . . . . . . . . . . . . . . 79
A[2S3012 ALUMINUM SULFATE . . . . . . . . . . . . . . . . . . . . . . . . 11 Ct2 CHLORINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
Ar ARGON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 Ct20 CHLORINE MONOXIDE . . . . . . . . . . . . . . . . . . . . . . . 81
As ARSENIC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 Ct207 CHLORINE HEPTOXIDE . . . . . . . . . . . . . . . . . . . . . . 82
AsBr3 ARSENIC TRIBROHIDE . . . . . . . . . . . . . . . . . . . . . . 14 Co COBALT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
AsC[3 ARSENIC TRICHLORIDE . . . . . . . . . . . . . . . . . . . . . 15 CoCt2 COBALT CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 84
AsF3 ARSENIC TRIFLUORIDE . . . . . . . . . . . . . . . . . . . . . 16 CONC304 COBALT NITROSYL TRICARBONYL . . . . . . . . . . . . . 85
AsF5 ARSENIC PENTAFLUORIDE . . . . . . . . . . . . . . . . . . . 17 Cr CHROMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
AsH3 ARSINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 CRC606 CHROMIUM CARBONYL . . . . . . . . . . . . . . . . . . . . . . . 87
AsI3 ARSENIC TRIIODIDE . . . . . . . . . . . . . . . . . . . . . . . 19 CrO2Cl2 CHROMIUM OXYCHLORIDE . . . . . . . . . . . . . . . . . . . . 88
As203 ARSENIC TRIOXIDE . . . . . . . . . . . . . . . . . . . . . . . . 20 Cs CESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
At ASTATINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 CsBr CESIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 90
Au GOLD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22 CsCt CESIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 91
B BORON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 CsF CESIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 92
BBr3 BORON TRIBRONIDE . . . . . . . . . . . . . . . . . . . . . . . . 24 Csl CESIUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
BCt3 BORON TRICHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 25 Cu COPPER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
BF3 BORON TRIFLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 26 CuBr CUPROUS BRONIDE . . . . . . . . . . . . . . . . . . . . . . . . . 95
BH2CO BORINE CARBONYL . . . . . . . . . . . . . . . . . . . . . . . . . 27 CuCt CUPROUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 96
BH303 BORIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 CuCt2 CUPRIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 97
B2D6 DEUTERODIBORANE . . . . . . . . . . . . . . . . . . . . . . . . . 29 Cul COPPER IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
B2H5Br DIBORANE HYDROBROHIDE . . . . . . . . . . . . . . . . . . . 30 DCN DEUTERIUM CYANIDE . . . . . . . . . . . . . . . . . . . . . . . 99
B2H6 DIBORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 D2 DEUTERIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
B3N3H6 BORINE TRIAMINE . . . . . . . . . . . . . . . . . . . . . . . . . 32 D20 DEUTERIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 101
B4HIO TETRABORANE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33 Eu EUROPIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
BSH9 PENTABORANE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 F2 FLUORINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
B5H11 TETRAHYDROPENTABORANE. . . . . . . . . . . . . . . . . . . 35 F20 FLUORINE OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 104
B10H14 DECABORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36 Fe IRON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
Ba BARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 Fee505 IRON PENTACARBONYL . . . . . . . . . . . . . . . . . . . . . . 106
Be BERYLLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 FeCt2 FERROUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 107
BeB2H8 BERYLLIUM BOROHYDRIDE . . . . . . . . . . . . . . . . . . . 39 Feel3 FERRIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 108
BeBr2 BERYLLIUM BROMIDE ....................... 40 Fr FRANCIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
BeCt2 BERYLLIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 41 Ga GALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110
BeF2 BERYLLIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . 42 GaCL3 GALLIUM TRICHLORIDE . . . . . . . . . . . . . . . . . . . . . 111
BeI2 BERYLLIUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . 43 Gd GADOLINIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
Bi BISMUTH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 Ge GERMANIUM. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
BiBr3 BISMUTH TRIBRONIDE . . . . . . . . . . . . . . . . . . . . . . 45 GeBr4 GERMANIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . 114
BiC[3 BISMUTH TRICHLORIDE . . . . . . . . . . . . . . . . . . . . . 46 GeC [ 4 GERMANIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 115
BrF5 BROMINE PENTAFLUORIDE . . . . . . . . . . . . . . . . . . . 47 GeHC[3 TRICHLORO GERMANE. . . . . . . . . . . . . . . . . . . . . . . 116
Br2 BROMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 GeH4 GERMANE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
C CARBON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 Ge2H6 DIGERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118
CCt20 PHOSGENE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50 Ge3H8 TRIGERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
CF20 CARBONYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 51 HBr HYDROGEN BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 120
CH4N20 UREA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52 HCN HYDROGEN CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . 121
CH4N2S THIOUREA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53 HCt HYDROGEN CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 122
CNBr CYANOGEN BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 54 HF HYDROGEN FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 123
CNC[ CYANOGEN CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 55 HI HYDROGEN IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . 124
CNF CYANOGEN FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 56 HN03 NITRIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
CO CARBON MONOXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 57 H2 HYDROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
COS CARBONYL SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . 58 H20 WATER. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
COSe CARBON OXYSELENIDE . . . . . . . . . . . . . . . . . . . . . . 59 H202 HYDROGEN PEROXIDE . . . . . . . . . . . . . . . . . . . . . . . 128
C02 CARBON D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . . . 60 H2S HYDROGEN SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . 129
CS2 CARBON D I S U L F I D E . . . . . . . . . . . . . . . . . . . . . . . . 61 H2S04 SULFURIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
CSeS CARBON SELENOSULFIDE . . . . . . . . . . . . . . . . . . . . 62 H2S2 HYDROGEN D I S U L F I D E . . . . . . . . . . . . . . . . . . . . . . 131
C2N2 CYANOGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63 H2Se HYDROGEN SELENIDE . . . . . . . . . . . . . . . . . . . . . . . 132
C3S2 CARBON SUBSULFIDE . . . . . . . . . . . . . . . . . . . . . . . 64 H2Te HYDROGEN TELLURIDE . . . . . . . . . . . . . . . . . . . . . . 133
Ca CALCIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 H3N03S SULFAMIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
CaF2 CALCIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . 66 He HELIUM-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
CbF5 COLUMBIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . 67 He HELIUM-4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 156
Cd CADMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 Hf HAFNIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
CdC[2 CADMIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 69 Hg MERCURY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138

346
HgBr2 MERCURIC BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 139 PC[3 PHOSPHORUS TRICHLORIDE. . . . . . . . . . . . . . . . . . 215
HgC[2 MERCURIC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 140 PC[5 PHOSPHORUS PENTACHLORIDE . . . . . . . . . . . . . . . . 216
HgI2 MERCURIC IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 141 PH3 PHOSPHINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
IF7 IODINE HEPTAFLUORIDE . . . . . . . . . . . . . . . . . . . . 142 PH4Br PHOSPHONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . 218
12 IODINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 PH4C[ PHOSPHONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . 219
In INDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 PH4I PHOSPHONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . 220
Ir IRIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 POCt3 PHOSPHORUS OXYCHLORIDE. . . . . . . . . . . . . . . . . . 221
K POTASSIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 PSBr3 PHOSPHORUS THIOBROMIDE. . . . . . . . . . . . . . . . . . 222
KBr POTASSIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 147 PSC[3 PHOSPHORUS THIOCHLORIDE. . . . . . . . . . . . . . . . . 223
KCI POTASSIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 148 P406 PHOSPHORUS TRIOXIDE. . . . . . . . . . . . . . . . . . . . . 224
KF POTASSIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . 149 P4010 PHOSPHORUS PENTOXIDE. . . . . . . . . . . . . . . . . . . . 225
KI POTASSIUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . 150 P4SIO PHOSPHORUS PENTASULFIDE . . . . . . . . . . . . . . . . . 226
KOH POTASSIUM HYDROXIDE. . . . . . . . . . . . . . . . . . . . . 151 Pb LEAD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
Kr KRYPTON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 PbBr2 LEAD BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 228
La LANTHANUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 PbC[2 LEAD CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 229
Li LITHIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 PbF2 LEAD FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 230
LiBr LITHIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . 155 PbI2 LEAD IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
LiCl LITHIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . 156 PbO LEAD OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232
LiF LITHIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 157 PbS LEAD SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
LII LITHIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 158 Pcl PALLADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
Lu LUTETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Po POLONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
Mg MAGNESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 Pt PLATINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
MgCI2 MAGNESIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 161 Ra RADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
MgO MAGNESIUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 162 Rb RUBIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
Mn MANGANESE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 RbBr RUBIDIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 239
MnCt 2 MANGANESE CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 164 RbC[ RUBIDIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 240
Mo MOLYBDENUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 RbF RUBIDIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 241
MoF6 MOLYBDENUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . 166 Rbl RUBIDIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 242
MoO3 MOLYBDENUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . 167 Re RHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
NC[3 NITROGEN TRICHLORIDE. . . . . . . . . . . . . . . . . . . . 168 Re207 RHENIUM HEPTOXIDE. . . . . . . . . . . . . . . . . . . . . . . 244
ND3 HEAVY AMMONIA. . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Rh RHODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245
NF3 NITROGEN TRIFLUORIDE. . . . . . . . . . . . . . . . . . . . 170 Rn RADON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
NH3 AMMONIA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 Ru RUTHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247
NH30 HYDROXYLAMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . 172 RuF5 RUTHENIUM PENTAFLUORIDE . . . . . . . . . . . . . . . . . 248
NH4Br AMMONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 173 S SULFUR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249
NH4C[ AMMONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 174 SF4 SULFUR TETRAFLUORIDE. . . . . . . . . . . . . . . . . . . . 250
NH41 AMMONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 175 SF6 SULFUR HEXAFLUORIDE. . . . . . . . . . . . . . . . . . . . . 251
NH50 AMMONIUM HYDROXIDE. . . . . . . . . . . . . . . . . . . . . . 176 SOBr2 THIONYL BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . 252
NHSS AMMONIUM HYDROGENSULFIDE . . . . . . . . . . . . . . . . 177 SOCt2 THIONYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . 253
NO NITRIC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 SOF2 SULFUROUS OXYFLUORIDE. . . . . . . . . . . . . . . . . . . 254
NOCt NITROSYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 179 SO2 SULFUR DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 255
NOF NITROSYL FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 180 S02C[2 SULFURYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 256
NO2 NITROGEN DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . 181 SO3 SULFUR TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 257
N2 NITROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 $2CL2 SULFUR MONOCHLORIDE . . . . . . . . . . . . . . . . . . . . . 258
N2F4 TETRAFLUOROHYDRAZINE . . . . . . . . . . . . . . . . . . . . 183 Sb ANTIMONY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
N2H4 HYDRAZINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 SbBr3 ANTIMONY TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . 260
N2H4C AMMONIUM CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . 185 SbC[3 ANTIMONY TRICHLORIDE. . . . . . . . . . . . . . . . . . . . 261
N2H6C02 AMMONIUM CARBAMATE. . . . . . . . . . . . . . . . . . . . . . 186 SbCt5 ANTIMONY PENTACHLORIDE . . . . . . . . . . . . . . . . . . 262
N20 NITROUS OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 SbH3 STIBINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
N203 NITROGEN TRIOXIDE . . . . . . . . . . . . . . . . . . . . . . . 188 SbI3 ANTIMONY TRIIODIDE . . . . . . . . . . . . . . . . . . . . . . 264
N204 NITROGEN TETRAOXIDE . . . . . . . . . . . . . . . . . . . . . 189 Sb203 ANTIMONY TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . 265
N205 NITROGEN PENTOXIDE. . . . . . . . . . . . . . . . . . . . . . 190 Sc SCANDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
Na SODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Se SELENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
NaBr S O D I U M BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 192 SeCt4 SELENIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 268
NaCN S O D I U M CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 193 SeF6 SELENIUM HEXAFLUORIDE. . . . . . . . . . . . . . . . . . . 269
NaCL SODIUM CHLORIDE ......................... 194 SeOC [ 2 SELENIUM OXYCHLORIDE. . . . . . . . . . . . . . . . . . . . 270
NaF S O D I U M FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 195 Se02 SELENIUM DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . 271
Nal S O D I U M IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Si SILICON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 272
NaOH SODIUM HYDROXIDE ........................ 197 SIBrCt2F BROMODICHLOROFLUOROSILANE . . . . . . . . . . . . . . . 273
Na2S04 S O D I U M SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . 198 SiBrF3 TRIFLUOROBROMOSILANE . . . . . . . . . . . . . . . . . . . . 274
Nb NIOBIUM ................................. 199 SiBr2CLF DIBROMOCHLOROFLUOROSILANE . . . . . . . . . . . . . . . 275
Nd NEODYMIUM ............................... 200 SiCtF3 TRIFLUOROCHLOROSILANE . . . . . . . . . . . . . . . . . . . 276
Ne NEON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 SiCt2F2 DICHLORODIFLUOROSILANE . . . . . . . . . . . . . . . . . . 277
Ni NICKEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 SiCt3F TRICHLOROFLUOROSILANE . . . . . . . . . . . . . . . . . . . 278
N iC404 NICKEL C A R B O N Y L . . . . . . . . . . . . . . . . . . . . . . . . . 203 SiCt4 SILICON TETRACHLORIDE. . . . . . . . . . . . . . . . . . . 279
NiF2 NICKEL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 204 SiF4 SILICON TETRAFLUORIDE. . . . . . . . . . . . . . . . . . . 280
Np NEPTUNIUM ............................... 205 SIHBr3 TRIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 281
02 OXYGEN .................................. 206 SiHCt3 TRICHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 282
03 OZONE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 SIHF3 TRIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 283
Os OSMIUM .................................. 208 SIH2Br2 DIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . 284
OsOF5 O S M I U M OXIDE P E N T A F L U O R I D E .............. 209 SIH2C[2 DICHLOROSILANE . . . . . . . . . . . . . . . . . . ........ 285
Os04 O S M I U M T E T R O X I D E - Y E L L O W ............... 210 SIH2F2 DIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 286
Os04 OSMIUM TETROXIDE WHITE ................
- 211 SiH212 DIIODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287
P P H O S P H O R U S - WHITE . . . . . . . . . . . . . . . . . . . . . . 212 SiH3Br MONOBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 288
PBr3 PHOSPHORUS TRIBROMIDE ................... 213 S i H3C t MONOCHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 289
PCt2F3 P H O S P H O R U S D I C H L O R I D E T R I F L U O R I D E ....... 214 SIH3F MONOFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 290

347
SiH31 IODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
SiH4 SILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
Si02 SILICON DIOXIDE ......................... 293
Si2Ct6 HEXACHLORODISILANE . . . . . . . . . . . . . . . . . . . . . . 294
Si2F6 HEXAFLUORODISILANE . . . . . . . . . . . . . . . . . . . . . . 295
Si2H5Cl D I S I L A N Y L CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 296
Si2H6 DISILANE ................................ 297
Si2OCl3F3 TRICHLOROTRIFLUORODISILOXANE . . . . . . . . . . . . 298
Si20Cl6 HEXACHLORODISILOXANE . . . . . . . . . . . . . . . . . . . . 299
S i20H6 DISILOXANE .............................. 300
Si3Cl8 OCTACHLOROTRISILANE . . . . . . . . . . . . . . . . . . . . . 301
Si3H8 TRISILANE ............................... 302
Si3H9N TRISILAZANE ............................. 303
Si4H10 TETRASILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304
Sm SAMARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
Sn TIN ..................................... 306
SnBr4 STANNIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 307
SnCl2 STANNOUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 308
SnCt4 STANNIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 309
SnH4 STANNIC HYDRIDE . . . . . . . . . . . . . . . . . . . . . . . . . 310
SnI4 STANNIC I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . . 311
Sr STRONTIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312
SrO STRONTIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 313
Ta TANTALUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314
Tc TECHNETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
Te TELLURIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 316
TeC[4 TELLURIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 317
TeF6 TELLURIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . 318
Ti TITANIUM ................................ 319
TiC[4 T I T A N I U M TETRACHLORIDE . . . . . . . . . . . . . . . . . . 320
T[ THALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
TIBr THALLOUS BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 322
Tll THALLOUS I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 323
Tm THULIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324
U URANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
UF6 URANIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 326
V VANADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
VCt4 VANADIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 328
VOCt3 VANADIUM OXYTRICHLORIDE. . . . . . . . . . . . . . . . . 329
W TUNGSTEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
WF6 TUNGSTEN FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 331
Xe XENON. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 332
Yb YTTERBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333
Yt YTTRIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334
Zn ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
ZnCt2 ZINC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 336
ZnF2 ZINC FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 337
ZnO ZINC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338
ZnS04 ZINC SULFATE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 339
Zr ZIRCONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340
ZrBr4 ZIRCONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 341
ZrC[4 ZIRCONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 342
ZrI4 ZIRCONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . 343

348
Appendix B

COMPOUND LIST BY NAME

ALUMINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 CESIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 90


ALUMINUM BOROHYDRIDE. . . . . . . . . . . . . . . . . . . . 5 CESIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 91
ALUMINUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 6 CESIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 92
ALUMINUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 7 CESIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
ALUMINUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 8 CHLORINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 80
ALUMINUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 9 CHLORINE D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . 79
ALUMINUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 10 CHLORINE HEPTOXIDE . . . . . . . . . . . . . . . . . . . . . . 82
ALUMINUM SULFATE. . . . . . . . . . . . . . . . . . . . . . . . 11 CHLORINE MONOFLUORIDE . . . . . . . . . . . . . . . . . . . 7"5
AMMONIA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 CHLORINE MONOXIDE . . . . . . . . . . . . . . . . . . . . . . . 81
AMMONIUM BROMIDE. . . . . . . . . . . . . . . , ........ 173 CHLORINE PENTAFLUORIDE . . . . . . . . . . . . . . . . . . 76
AMMONIUM CARBAMATE. . . . . . . . . . . . . . . . . . . . . . 186 CHLORINE T R I F L U O R I D E . . . . . . . . . . . . . . . . . . . . 75
AMMONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 174 CHLOROSULFONIC A C I D . . . . . . . . . . . . . . . . . . . . . 77
AMMONIUM CYANIDE. . . . . . . . . . . . . . . . . . . . . . . . 185 CHROMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
AMMONIUM HYDROGENSULFIDE . . . . . . . . . . . . . . . . 177 CHROMIUM CARBONYL. . . . . . . . . . . . . . . . . . . . . . . 87
AMMONIUM HYDROXIDE. . . . . . . . . . . . . . . . . . . . . . 176 CHROMIUM OXYCHLORIDE. . . . . . . . . . . . . . . . . . . . 88
AMMONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 175 COBALT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 83
ANTIMONY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259 COBALT CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . 84
ANTIMONY PENTACHLORIDE. . . . . . . . . . . . . . . . . . 262 COBALT NITROSYL TRICARBONYL. . . . . . . . . . . . . 85
ANTIMONY TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . 260 COLUMBIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . 67
ANTIMONY TRICHLORIDE. . . . . . . . . . . . . . . . . . . . 261 COPPER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 94
ANTIMONY TRIIODIDE . . . . . . . . . . . . . . . . . . . . . . 264 COPPER IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 98
ANTIMONY TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . 265 CUPRIC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . 97
ARGON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12 CUPROUS BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . 95
ARSENIC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 CUPROUS.CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 96
ARSENIC PENTAFLUORIDE. . . . . . . . . . . . . . . . . . . 17 CYANOGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
ARSENIC TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . . 14 CYANOGEN BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 54
ARSENIC TRICHLORIDE. . . . . . . . . . . . . . . . . . . . . 15 CYANOGEN CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 55
ARSENIC TRIFLUORIDE. . . . . . . .9. . . . . . . . . . . . . 16 CYANOGEN FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 56
ARSENIC TRIIODIDE . . . . . . . . . . . . . . . . . . . . . . . 19 DECABORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
ARSENIC TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . 20 DEUTERIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
ARSINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 DEUTERIUM CYANIDE. . . . . . . . . . . . . . . . . . . . . . . 99
ASTATINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21 DEUTERIUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 101
BARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37 DEUTERODIBORANE . . . . . . . . . . . . . . . . . . . . . . . . . 29
BERYLLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 38 DIBORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
BERYLLIUM BOROHYDRIDE. . . . . . . . . . . . . . . . . . . 39 DIBORANE HYDROBROMIDE. . . . . . . . . . . . . . . . . . . 30
BERYLLIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 40 DIBROMOCHLOROFLUOROSILANE . . . . . . . . . . . . . . . 275
BERYLLIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 41 DIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . 284
BERYLLIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . 42 DICHLORODIFLUOROSILANE . . . . . . . . . . . . . . . . . . 277
BERYLLIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . 43 DICHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 285
BISMUTH . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 44 DIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 286
BISMUTH TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . . 45 DIGERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 118
BISMUTH TRICHLORIDE. . . . . . . . . . . . . . . . . . . . . 46 DIIODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287
BORIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 DISILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 297
BORINE CARBONYL. . . . . . . . . . . . . . . . . . . . . . . . . 27 DISILANYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 296
BORINE TRIAMINE. . . . . . . . . . . . . . . . . . . . . . . . . 32 DISILOXANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 300
BORON. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 EUROPIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 102
BORON TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 24 FERRIC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . 108
BORON TRICHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 25 FERROUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 107
BORON TRIFLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 26 FLUORINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
BROMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 48 FLUORINE OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 104
BROMINE PENTAFLUORIDE. . . . . . . . . . . . . . . . . . . 47 FRANCIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
BROMODICHLOROFLUOROSILANE . . . . . . . . . . . . . . . 27] GADOLINIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 112
CALCIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 GALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 110
CALCIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 66 GALLIUM TRICHLORIDE. . . . . . . . . . . . . . . . . . . . . 111
CADMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 68 GERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
CADMIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . 69 GERMANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
CADMIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 70 GERMANIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 114
CADMIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 71 GERMANIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 115
CADMIUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 72 GOLD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 22
CARBON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 -HAFNIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
CARBON DIOXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 60 HEAVY AMMONIA. . . . . . . . . . . . . . . . . . . . . . . . . . . 169
CARBON DISULFIDE . . . . . . . . . . . . . . . , ....... . . . . 61 HELIUM-3 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 135
CARBON MONOXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 57 HELIUM-4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
CARBON OXYSELENIDE. . . . . . . . . . . . . . . . . . . . . . 59 HEXACHLORODISILANE . . . . . . . . . . . . . . . . . . . . . . 294
CARBON SELENOSULFIDE. . . . . . . . . . . . . . . . . . . . 62 HEXACHLORODISILOxANE . . . . . . . . . . . . . . . . . . . . 299
CARBON SUBSULFIDE. . . . . . . . . . . . . . . . . . . . . . . 64 HEXAFLUORODISILANE . . . . . . . . . . . . . . . . . . . . . . 295
CARBONYL FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 51 HYDRAZINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
CARBONYL SULFIDE. . . . . . . . . . . . . . . . . . . . . ... 58 HYDROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 126
CESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89 HYDROGEN BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 120

349
HYDROGEN CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 122 PERCHLORYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . 74
HYDROGEN CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . 121 PHOSGENE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
HYDROGEN D I S U L F I D E . . . . . . . . . . . . . . . . . . . . . . 131 PHOSPHINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
HYDROGEN FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 123 PHOSPHONIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . 218
HYDROGEN I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 124 PHOSPHONIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . 219
HYDROGEN PEROXIDE . . . . . . . . . . . . . . . . . . . . . . . 128 PHOSPHONIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . 220
HYDROGEN SELENIDE . . . . . . . . . . . . . . . . . . . . . . . 132 PHOSPHORUS - WHITE . . . . . . . . . . . . . . . . . . . . . . 212
HYDROGEN SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . 129 PHOSPHORUS DICHLORIDE T R IF L U O R ID E . . . . . . . 214
HYDROGEN TELLURIDE . . . . . . . . . . . . . . . . . . . . . . 133 PHOSPHORUS OXYCHLORIDE . . . . . . . . . . . . . . . . . . 221
HYDROXYLAMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . 172 PHOSPHORUS PENTACHLORIDE . . . . . . . . . . . . . . . . 216
INDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 PHOSPHORUS PENTASULFIDE . . . . . . . . . . . . . . . . . 226
IODINE .................................. 143 PHOSPHORUS PENTOXIDE . . . . . . . . . . . . . . . . . . . . 225
I O D I N E HEPTAFLUORIDE . . . . . . . . . . . . . . . . . . . . 142 PHOSPHORUS THIOBROMIDE . . . . . . . . . . . . . . . . . . 222
IODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291 PHOSPHORUS THIOCHLORIDE . . . . . . . . . . . . . . . . . 223
IRIDIUM ................................. 145 PHOSPHORUS TRIBRONIDE . . . . . . . . . . . . . . . . . . . 213
IRON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 PHOSPHORUS TRICHLORIDE . . . . . . . . . . . . . . . . . . 215
IRON PENTACARBONYL . . . . . . . . . . . . . . . . . . . . . . 106 PHOSPHORUS T R I O X I D E . . . . . . . . . . . . . . . . . . . . . 224
KRYPTON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 PLATINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
LANTHANUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 POLONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
LEAD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 POTASSIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
LEAD BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 POTASSIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . 147
LEAD CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 POTASSIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 148
LEAD FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 POTASSIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . 149
LEAD I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 POTASSIUM HYDROXIDE . . . . . . . . . . . . . . . . . . . . . 151
LEAD OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232 POTASSIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . 150
LEAD SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 RADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
LITHIUM ................................. 154 RADON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
L I T H I U M BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 155 RHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
L I T H I U M CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 156 RHENIUM HEPTOXIDE . . . . . . . . . . . . . . . . . . . . . . . 244
L I T H I U M FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . 157 RHODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245
LITHIUM IODIDE .......................... 158 RUBIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
LUTETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 RUBIDIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 239
MAGNESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 RUBIDIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 240
MAGNESIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 161 RUBIDIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 241
MAGNESIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 162 RUBIDIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 242
MANGANESE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 RUTHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247
MANGANESE CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 164 RUTHENIUM PENTAFLUORIDE . . . . . . . . . . . . . . . . . 248
MERCURIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 139 SAMARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
MERCURIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 140 SCANDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
MERCURIC I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 141 SELENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
MERCURY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 SELENIUM D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . 271
MOLYBDENUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 SELENIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . . 269
MOLYBDENUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . 166 SELENIUM OXYCHLORIDE . . . . . . . . . . . . . . . . . . . . 270
MOLYBDENUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . 167 SELENIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 268
MONOBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 288 SILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
MONOCHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 289 SILICON ................................. 272
NONOFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 290 SILICON DIOXIDE ......................... 293
NEODYMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 S I L I C O N TETRACHLORIDE . . . . . . . . . . . . . . . . . . . 279
NEON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 S I L I C O N TETRAFLUORIDE . . . . . . . . . . . . . . . . . . . 280
NEPTUNIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 SILVER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
NICKEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 SILVER CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 2
NICKEL CARBONYL . . . . . . . . . . . . . . . . . . . . . . . . . 203 SILVER IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
NICKEL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 204 SODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
NIOBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 SODIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 192
N I T R I C ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 SODIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 194
N I T R I C OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 SODIUM CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 193
NITROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 SODIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 195
NITROGEN D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . 181 SODIUM HYDROXIDE . . . . . . . . . . . . . . . . . . . . . . . . 197
NITROGEN PENTOXIDE . . . . . . . . . . . . . . . . . . . . . . 190 SODIUM IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . . 196
NITROGEN TETRAOXIDE . . . . . . . . . . . . . . . . . . . . . 189 SODIUM SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . 198
NITROGEN TRICHLORIDE . . . . . . . . . . . . . . . . . . . . 168 STANNIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 307
NITROGEN T R I F L U O R I D E . . . . . . . . . . . . . . . . . . . . 170 STANNIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 309
NITROGEN T R I O X I D E . . . . . . . . . . . . . . . . . . . . . . . 188 STANNIC HYDRIDE . . . . . . . . . . . . . . . . . . . . . . . . . 310
NITROSYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 179 STANNIC IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . 311
NITROSYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 180 STANNOUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 308
NITROUS OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 STIBINE ................................. 263
OCTACHLOROTRISILANE . . . . . . . . . . . . . . . . . . . . . 301 STRONTIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312
OSMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 STRONTIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 313
OSMIUM OXIDE PENTAFLUORIDE . . . . . . . . . . . . . . 209 SULFAMIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
OSMIUM TETROXIDE - WHITE . . . . . . . . . . . . . . . . 211 SULFUR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249
OSMIUM TETROXIDE - YELLOW . . . . . . . . . . . . . . . 210 SULFUR D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . . . 255
OXYGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206 SULFUR HEXAFLUORIDE . . . . . . . . . . . . . . . . . . . . . 251
OZONE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 SULFUR MONOCHLORIDE . . . . . . . . . . . . . . . . . . . . . 258
PALLADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234 SULFUR TETRAFLUORIDE . . . . . . . . . . . . . . . . . . . . 250
PENTABoRANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 SULFUR T R I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . . 257
PERCHLORIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . 78 SULFURIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 130

350
SULFUROUS OXYFLUORIDE . . . . . . . . . . . . . . . . . . . 254
SULFURYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 256
TANTALUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314
TECHNETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
TELLURIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 316
TELLURIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . 318
TELLURIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . 317
TETRABORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
TETRAFLUOROHYDRAZINE . . . . . . . . . . . . . . . . . . . . 183
TETRAHYDROPENTABORANE . . . . . . . . . . . . . . . . . . . 35
TETRASILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304
THALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
THALLOUS BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 322
THALLOUS I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 323
THIONYL BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 252
THIONYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 253
THIOUREA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
THULIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324
TIN ..................................... 306
TITANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
TITANIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 320
TRIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 281
TRICHLORO GERMANE. . . . . . . . . . . . . . . . . . . . . . . 116
TRICHLOROFLUOROSILANE . . . . . . . . . . . . . . . . . . . 278
TRICHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 282
TRICHLOROTRIFLUORODISILOXANE . . . . . . . . . . . . 298
TRIFLUOROBROMOSILANE . . . . . . . . . . . . . . . . . . . . 274
TRIFLUOROCHLOROSILANE . . . . . . . . . . . . . . . . . . . 276
TRIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 283
TRIGERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
TRISILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302
TRISILAZANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303
TUNGSTEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
TUNGSTEN FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 331
URANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
URANIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 326
UREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
VANADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
VANADIUM OXYTRICHLORIDE. . . . . . . . . . . . . . . . . 329
VANADIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 328
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
XENON. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 332
YTTERBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333
YTTRIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334
ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
ZINC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 336
ZINC FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 337
ZINC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338
ZINC SULFATE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 339
ZIRCONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340
ZIRCONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 341
ZIRCONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 342
ZIRCONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . 343

351
Appendix C

COEFFICIENTS FOR VAPOR PRESSURE EQUATION*


Carl L. Y a w s , Sachin N i j h a w a n and Li Bu
Lamar University, Beaumont, Texas

t Og,o P = A + B I T + C t Og,o T + D T + E T 2 (P - mm Hg, T - K)

NO FORMULA NAME A B C D E TM I N TMAX

1 Ag SILVER 23.6822 -1.6026E+04 -4.5239E+00 4.0517E-04 1.0895E-16 1234.00 6410.00


2 Age t SILVER CHLORIDE 35.4158 -1.2320E+04 -8.7445E+00 1.7514E-03 -1.4905E-07 1185.15 1837.15
3 Agl SILVER IODIDE 69.1111 -1.3908E+04 -1.9966E+01 4.3499E-03 -3.9755E-07 1093.15 1779.15
4At ALUMINUM 9.9884 -1.3837E+04 -3.4595E-01 1.1361E-11 -1.2182E-15 933.00 2329.10
5 AtB3H12 ALUMINUM BOROHYDRIDE 65.4884 -2.8974E+03 -2.4421E+01 2.8261E-02 -1.3715E-05 220.95 319.05
6 AIBr3 ALUMINUN BROMIDE 5597.9805 -1.5335E+05 -2.2913E+03 2.1944E+00 -8.0708E-04 354.45 529.45
7 ALCL3 ALUMINUM CHLORIDE 27.8613 -6.7364E+03 -3.8080E+00 -1.3181E-05 5.2521E-09 373.15 465.75
8 AIF3 ALUMINUM FLUORIDE 4703.8748 -4.6135E+05 -1.5238E+03 3.4062E-01 -3.0079E-05 1511.15 1810.15
9 At 13 ALUMINUM IODIDE 585.1783 -2.6198E+04 -2.1938E+02 1.3820E-01 -3.5008E-05 451.15 658.65
10 At203 ALUMINUM OXIDE 14.1611 -2.8238E+04 -7.3843E-01 -3.7413E-07 2.2086E-11 2421.10 3253.10
11 At2S3012 ALUMINUM SULFATE -464.7417 4.9953E+04 1.3895E+02 5.7398E-04 -1.0158E-07 845.15 1043.20
12 Ar ARGON 14.9138 -4.5675E+02 -3.5895E+00 3.5490E-08 2.1907E-05 83.78 150.86
13 As ARSENIC 70.7356 -9.6421E+03 -2.2451E+01 1.3810E-02 -3.8579E-06 420.00 885.00
14 AsBr3 ARSENIC TRIBROMIDE 69.8773 -4.4831E+03 -2.4415E+01 1.8936E-02 -6.1554E-06 314.95 493.15
15 AsC[3 ARSENIC TRICHLORIDE 93.9840 -4.4550E+03 -3.5080E+01 3.3505E-02 -1.3338E-05 261.75 403.55
16 AsF3 ARSENIC TRIFLUORIDE 27.7465 -2.4305E+03 -7.8250E+00 7.8140E-03 -3.3333E-06 270.65 329.45
17 AsF5 ARSENIC PENTAFLUORIDE 1944.5157 -3.0430E+04 -9.1148E+02 1.8231E+00 -1.4325E-03 155.25 220.35
18 AsH3 ARSINE -10.3462 -7.7134E+02 9.1086E+00 -2.4654E-02 2.0673E-05 156.23 373.00
19 AsI3 ARSENIC TRIIODIDE 96.0056 -6.8120E+03 -3.3239E+01 2.0112E-02 -5.0888E-06 437.15 602.65
20 As203 ARSENIC TRIOXIDE -2811.4735 7.9643E+04 1.1255E+03 -9.0385E-01 2.6735E-04 485.65 730.35
21 At ASTATINE -17.3579 -4.5040E+03 1.3457E+01 -2.2096E-02 9.7987E-06 279.00 607.00
22 Au GOLD 126.1594 -2.9160E+04 -3.7975E+01 8.0922E-03 -6.6670E-07 1226.00 3120.00
23 B BORON 38.5877 -3.6230E+04 -7.5640E+00 -1.1450E-04 5.1894E-08 1821.00 4133.00
24 BBr3 BORON TRIBROMIDE 104.0215 -4.2744E+03 -3.9717E+01 3.9970E-02 -1.6726E-05 273.15 361.05
25 BCI3 BORON TRICHLORIDE 35.3538 -2.3048E+03 -I.0108E+01 5.5834E-I0 5.1455E-06 166.15 451.95
26 BF3 BORON TRIFLUORIDE 75.2534 -2.4715E+03 -2.6531E+01 8.5366E-08 4.2709E-05 144.78 260.90
27 BH2CO BORINE CARBONYL 433.1860 -6.8163E+03 -2.0499E+02 4.5121E-01 -3.7515E-04 133.95 209.15
28 BH303 BORIC ACID -81.1257 2.1815E+03 2.9986E+01 -2.2693E-05 1.0956E-08 293.15 401.15
29 B2D6 DEUTERODIBORANE 120.8038 -2.4092E+03 -5.4329E+01 1.1943E-01 -I.0820E-04 118.25 179.25
30 B2H5Br DIBORANE HYDROBROMIDE 488.4916 -8.8892E+03 -2.2351E+02 4.1313E-01 -2.9011E-04 179.85 289.45
31 B2H6 DIBORANE 11.5597 -9.4549E+02 -1.3754E+00 -2.3575E-03 2.6782E-06 107.65 289.80
32 B3N3H6 BORINE TRIAMINE 58.7997 -2.8667E+03 -2.1466E+01 2.5002E-02 -1.2241E-05 210.15 323.75
33 B4HIO TETRABORANE 23.0730 -1.7369E+03 -6.6041E+00 8.4552E-03 -4.6056E-06 182.25 289.25
34 B5H9 PENTABORANE -163.4159 1.4743E+03 7.5896E+01 -I.0578E-01 5.0905E-05 232.75 568.45
35 B5H11 TETRAHYDROPENTABORANE 7.6486 -1.8417E+03 2.8719E-01 -3.0007E-04 1.3472E-07 222.95 340.15
36 B10H14 DECABORANE 4813.9118 -1.2837E+05 -1.9845E+03 1.9935E+00 -7.8068E-04 333.15 436.95
37 Ba BARIUM -18.1369 -8.1603E+03 1.0107E+01 -5.9955E-03 9.8349E-07 638.00 1907.00
38 Be BERYLLIUM -4.7459 -1.6799E+04 5.4503E+00 -2.6044E-03 2.8638E-07 1097.00 2744.00
39 BeB2H8 BERYLLIUM BOROHYDRIDE -94.5732 2.2630E+02 4.1281E+01 -2.7627E-02 8.9618E-06 274.15 363.15
40 BeBr2 BERYLLIUM BROMIDE 2669.4633 -9.8679E+04 -I.0326E+03 7.2331E-01 -1.9329E-04 562.15 747.15
41 BeC[2 BERYLLIUM CHLORIDE -289.7317 1.0348E+04 1.0311E+02 -1.6198E-02 -9.9081E-06 564.15 760.15
42 BeF2 BERYLLIUM FLUORIDE 224.7647 -2.8762E+04 -7.0897E+01 1.7991E-02 -1.8955E-06 1145.55 1372.15
43 BeI2 BERYLLIUM IODIDE 3417.9820 -1.2770E+05 -1.3156E+03 8.8819E-01 -2.2863E-04 556.15 760.15
44 Bi BISMUTH 1449.1712 -8.3717E+04 -5.1359E+02 2.0492E-01 -2.9858E-05 569.00 1700.00
45 BiBr3 BISMUTH TRIBROMIDE 216.7751 -1.3734E+04 -7.6683E+01 3.9665E-02 -8.4421E-06 534.15 734.15
46 BiC[3 BISMUTH TRICHLORIDE -6.1334 -3.1936E+03 5.2620E+00 -2.4866E-03 5.0977E-07 503.65 710.55
47 BrF5 BROMINE PENTAFLUORIDE 51.1403 -2.6286E+03 -1.8290E+01 2.1840E-02 -I.0991E-05 203.85 313.55
48 Br2 BROMINE 23.7200 -2.2840E+03 -5.6145E+00 2.2602E-09 1.7888E-06 265.85 584.15
49 C CARBON -2.0686 -2.5987E+04 3.5504E+00 -5.3440E-04 2.9310E-08 3259.10 4399.10
50 CCl20 PHOSGENE 46.6551 -2.4657E+03 -1.5351E+01 9.2288E-03 -4.9658E-14 145.37 455.00
51 CF20 CARBONYL FLUORIDE -70.1866 -3.8315E+02 4.1225E+01 -1.2049E-01 1.1291E-04 161.89 297.00
52 CH4N20 UREA 6.7305 -4.4855E+03 1.5588E+00 -1.7855E-03 8.4006E-07 340.65 368.05
53 CH4N2S THIOUREA -35.4224 -2.3772E+03 1.9025E+01 -2.0819E-02 6.8609E-06 454.15 854.00
54 CNBr CYANOGEN BROMIDE 2302.7452 -4.9937E+04 -9.9806E+02 1.3391E+00 -7.0662E-04 273.01 313.09
55 CNCI CYANOGEN CHLORIDE -9.0018 -1.2842E+03 8.2222E+00 -1.6105E-02 9.5986E-06 266.65 449.00

* A computer program, c o n t a i n i n g c o e f f i c i e n t s f o r vapor pressure f o r a l l compounds , is a v a i t a b t e f o r a nominat fee (Carl L.


Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other so f tw a r e .

352
t oglo P = A + B / T + C t oglo T + D T + E T 2 (P - mm Hg, T - K)

NO FORMULA NAME A B C D E TMI N TMAX

56 CNF CYANOGENFLUORIDE 179.8136 -4.3677E+03 -7.6561E+01 1.1639E-01 -7.2513E-05 196.75 226.35


57 CO CARBON MONOXIDE 51.8145 -7.8824E+02 -2.2734E+01 5.1225E-02 4.6603E-11 68.15 132.92
58 COS CARBONYLSULFIDE 36.8556 -1.7187E+03 -1.2036E+01 8.9612E-03 2.0283E-13 134.30 378.80
59 COSe CARBON OXYSELENIDE 525.5520 -9.1072E+03 -2.4172E+02 4.5341E-01 -3.1974E-04 156.05 251.25
60 C02 CARBON DIOXIDE 35.0187 -1.5119E+03 -1.1335E+01 9.3383E-03 7.7626E-10 216.58 304.19
61 CS2 CARBON DISULFIDE 25.1475 -2.0439E+03 -6.7794E+00 3.4828E-03 3.4373E-15 161.11 552.00
62 CSeS CARBON SELENOSULFIDE -101.6898 -4.5082E+02 5.2520E+01 -1.0400E-01 6.9601E-05 225.85 358.75
63 C2N2 CYANOGEN 4016.4115 -5.9887E+04 -1.9008E+03 3.9066E+00 -3.0816E-03 177.35 252.15
64 C3S2 CARBON SUBSULFIDE -243.5223 3.1498E+03 1.0795E+02 -1.3131E-01 5.9581E-05 287.15 403.95
65 Ca CALCIUM -75.9862 -4.9573E+03 3.0625E+01 -1.3574E-02 1.9938E-06 625.00 1762.00
66 C a F 2 CALCIUMFLUORIDE 49.0700 -2.7912E+04 -1.0510E+01 1.4288E-08 -1.0745E-12 1691.00 2806.50
67 C b F 5 COLUMBIUMFLUORIDE -42.2353 -1.1915E+03 2.0862E+01 -2.2002E-02 8.8506E-06 359.45 498.15
68 Cd CADMIUM -145.3985 -8.3891E+02 6.0509E+01 -4.3639E-02 1.1003E-05 393.00 1043.00
69 CdC[2 CADMIUM CHLORIDE -4189.3798 2.2619E+05 1.4896E+03 -5.9464E-01 9.0541E-05 891.15 1240.15
70 CdF2 CADMIUM FLUORIDE -1738.0052 1.5268E+05 5.6319E+02 -1.1301E-01 7.8517E-06 1385.15 2024.15
71 CdI2 CADMIUM IODIDE -899.5410 3.5567E+04 3.3430E+02 -1.6865E-01 3.2257E-05 689.15 1069.15
72 CdO CADMIUM OXIDE 42.8498 -1.5443E+04 -1.0651E+01 2.0649E-03 -1.7038E-07 1273.15 1832.15
73 CLF CHLORINEMONOFLUORIDE 44.9140 -1.6526E+03 -1.6727E+01 3.3592E-02 -2.8601E-05 129.75 172.65
74 C L F 0 3 PERCHLORYLFLUORIDE 40.5028 -1.8544E+03 -1.3458E+01 9.9792E-03 3.8242E-13 125.41 368.40
75 CLF3 CHLORINETRIFLUORIDE 25.4578 -1.6807E+03 -7.7581E+00 9.8092E-03 -5.2739E-06 192.75 284.65
76 CLF5 CHLORINEPENTAFLUORIDE 131.4931 -3.7893E+03 -5.3872E+01 7.2145E-02 -3.9712E-05 193.95 297.95
77 ClH03S CHLOROSULFONIC ACID -5.6040 -2.7604E+03 8.4466E+00 -2.2029E-02 1.1699E-05 193.15 700.00
78 CLH04 PERCHLORICACID 7.5448 -2.0352E+03 1.0732E+00 -7.2499E-03 4.2925E-06 171.95 631.00
79 C t 0 2 CHLORINEDIOXIDE 121.9791 -5.2893E+03 -4.1838E+01 -2.0950E-08 2.6848E-05 213.55 465.00
80 Cl2 CHLORINE 28.8659 -1.6745E+03 -8.5216E+00 5.3792E-03 -7.7867E-13 172.12 417.15
81 Ct20 CHLORINEMONOXIDE 20.7506 -1.6377E+03 -5.5984E+00 7.4816E-03 -4.2600E-06 174.65 275.35
82 Ct207 CHLORINEHEPTOXIDE 5.5051 -1.7898E+03 1.0930E+00 -1.1071E-03 4.8227E-07 227.85 351.95
83 Co COBALT 16.7750 -1.8953E+04 -1.7830E+00 2.8243E-05 -6.2846E-08 1095.00 2528.00
84 C o C l 2 COBALTCHLORIDE 90.9544 -1.2963E+04 -2.7733E+01 7.3497E-03 -8.1551E-07 1043.15 1323.15
85 CONC304 COBALT NITROSYL TRICARBONYL -2295.1356 4.3067E+04 1.0148E+03 -1.4317E+00 7.7031E-04 271.85 353.15
86 Cr CHROMIUM -80.3456 -1.2221E+04 2.9746E+01 -6.8400E-03 5.2454E-07 1229.00 2840.00
87 CRC606 CHROMIUM CARBONYL -3135.3223 6.6813E+04 1.3443E+03 -1.6151E+00 7.4196E-04 309.15 424.15
88 CrO2Ct2 CHROMIUM OXYCHLORIDE 226.3675 -7.6454E+03 -9.0472E+01 9.3809E-02 -3.9753E-05 254.75 390.25
89 Cs CESIUM -2.9708 -3.6286E+03 4.1641E+00 -3.6632E-03 7.9575E-07 295.00 959.00
90 CsBr CESIUM BROMIDE 1537.6463 -I.0591E+05 -5.2949E+02 1.7992E-01 -2.3362E-05 1021.15 1573.15
91CsCL CESIUM CHLORIDE 438.8475 -3.4903E+04 -1.5008E+02 5.3499E-02 -7.3394E-06 1017.15 1573.15
92 CsF CESIUM FLUORIDE 1768.1436 -1.1822E+05 -6.1137E+02 2.1264E-01 -2.8322E-05 985.15 1524.15
93 Csl CESIUM IODIDE 276.4031 -2.6150E+04 -9.2366E+01 3.0791E-02 -4.0411E-06 1011.15 1553.15
94 Cu COPPER -82.6254 -1.1231E+04 3.1336E+01 -8.9074E-03 7.5663E-07 1130.00 3150.00
95 CuBr CUPROUS BROMIDE 208.6672 -2.0301E+04 -6.8060E+01 1.9026E-02 -2.1495E-06 845.15 1628.15
96 C u e [ CUPROUS CHLORIDE 27.2556 -7.5654E+03 -6.1858E+00 1.2376E-I0 -1.7508E-14 703.00 1763.10
97 CuC[2 CUPRIC CHLORIDE -238.6809 1.7213E+04 7.5807E+01 2.5333E-05 -6.1652E-09 582.85 794.15
98 Cul COPPER IODIDE 855.8840 -5.7746E+04 -2.9506E+02 1.0189E-01 -1.3492E-05 883.15 1609.15
99 DCN DEUTERIUM CYANIDE 798.8279 -1.7354E+04 -3.4780E+02 4.9610E-01 -2.8192E-04 204.25 299.35
100 D2 DEUTERIUM 6.1037 -6.7085E+01 -5.7226E-01 1.6894E-02 -I.7612E-11 18.73 38.35
101D20 DEUTERIUM OXIDE -12.8257 -2.1886E+03 1.0645E+01 -1.9029E-02 9.1375E-06 276.97 643.89
102 Eu EUROPIUM -55.5456 -6.4880E+03 2.3529E+01 -I.0970E-02 1.6487E-06 640.00 1742.00
103 F2 FLUORINE 27.1409 -5.7201E+02 -I.0015E+01 2.1078E-02 8.9567E-13 53.48 144.31
104 F20 FLUORINE OXIDE -24.8186 -1.9007E+02 1.5985E+01 -4.1421E-02 4.8042E-05 77.05 128.55
105 Fe IRON 11.5549 -1.9538E+04 -6.2549E-01 -2.7182E-09 1.9086E-13 1808.15 3008.20
106 FeC505 IRON PENTACARBONYL 317.6618 -9.3157E+03 -1.2965E+02 1.3467E-01 -4.8175E-05 266.65 378.15
107 FeC[2 FERROUS CHLORIDE -1350.9354 6.2772E+04 4.8764E+02 -2.0598E-01 3.2434E-05 973.15 1299.15
108 FeCL3 FERRIC CHLORIDE 64969.7167 -I.9169E+06 -2.6114E+04 2.2347E+01 -7.3076E-03 467.15 592.15
109 Fr FRANCIUM -38.3826 -2.2043E +03 1.8322E+01 -1.5441E-02 4.4042E-06 267.00 879.00
110 Ga GALLIUM -4.4968 -1.2924E+04 4.3403E+00 -9.5226E-04 2.3443E-08 954.00 2517.00
111 G a O l 3 GALLIUMTRICHLORIDE 54.9805 -4.8102E+03 -1.6009E+01 -8.4664E-09 3.9331E-06 350.90 694.00
112 Gd GADOLINIUM 9.6612 -I.0909E+04 -4.7131E-01 1.2082E-03 -3.9062E-07 728.00 1770.00
113 Ge GERMANIUM 24.3265 -1.9756E+04 -4.9583E+00 9.5753E-04 -8.0668E-08 1230.00 3125.00
114 G e B r 4 GERMANIUMBROMIDE 151.2941 -6.5181E+03 -5.7438E+01 4.8303E-02 -1.6731E-05 316.45 462.15
115 GeCL4 GERMANIUMCHLORIDE 207.3749 -6.4745E+03 -8.4232E+01 9.6332E-02 -4.5015E-05 228.15 357.15
116 GeHC[3 TRICHLOROGERMANE 175.3633 -5.9201E+03 -7.0301E+01 7.9543E-02 -3.7043E-05 231.85 348.15
117 G e H 4 GERMANE 32.2743 -1.3704E+03 -9.9425E+00 5.1455E-I0 1.6203E-05 107.26 308.00
118 Ge2H6 DIGERMANE 45.6425 -2.1567E+03 -1.6528E+01 2.1047E-02 -1.1265E-05 184.45 304.65
119 Ge3H8 TRIGERMANE 36.7997 -2.5324E+03 -1.2064E+01 1.1954E-02 -5.0050E-06 236.25 383.95
120 HBr HYDROGEN BROMIDE 34.4939 -1.6379E+03 -I.0909E+01 7.5732E-03 -2.5521E-12 185.15 363.15
121HCN HYDROGEN CYANIDE -57.0540 -3.6256E+02 2.9415E+01 -4.7528E-02 2.8406E-05 259.83 456.65

* A computer program, containing c o e f f i c i e n t s f o r vapor pressure f o r a t [ compounds 9is a v a i t a b t e f o r a nominal fee (Cart L.
Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710 9phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other software.

353
tog,o P = A + B/T + C loglo T + D T + E T2 (P - nan Hg, T - K)

NO FORMULA NAME A B C D E TM[ N TMAX

122 HCL HYDROGEN CHLORIDE 43.5455 -I .6279E+03 -1.5214E+01 1.3783E-02 -1.4984E-11 158.97 324.65
123 HF HYDROGEN FLUORIDE 23.7347 -I. 7996E+03 -6.1764E+00 -5.0046E-10 6.1500E-06 189.79 461.15
124 HI HYDROGEN IODIDE 21.4282 -1.4515E+03 -5.5756E+00 3.3878E-03 -8.9335E-12 222.38 423.85
125 HN03 NITRIC ACID 71.7653 -4.3768E+03 -2.2769E+01 -4.5988E-07 1.1856E-05 231.55 376.10
126 H2 HYDROGEN 3.4132 -4.1316E+01 1.0947E+00 -6.6896E-10 1.4589E-04 13.95 33.18
127 H20 WATER 29.8605 -3.1522E+03 -7.3037E+00 2.4247E-09 1.8090E-06 273.16 647.13
128 H 2 0 2 HYDROGENPEROXIDE 33.3222 -3.7350E+03 -8.3458E+00 -1.2351E-10 1.6917E-06 272.74 730.15
129 H2S HYDROGEN SULFIDE 18.6383 -1.3446E+03 -4.1034E+00 3.1815E-09 2.4664E-06 187.68 373.53
130 H2S04 SULFURICACID 2.0582 -4.1924E+03 3.2578E+00 -1.1224E-03 5.5371E-07 283.15 603.15
131 H 2 S 2 HYDROGENDISULFIDE 22.3747 -2.4043E+03 -5.5539E+00 5.8402E-03 -2.6241E-06 229.95 337.15
132 H 2 S e HYDROGENSELENIDE 573.9933 -I.0568E+04 -2.6071E+02 4.7258E-01 -3.4316E-04 157.85 232.05
133 H 2 T e HYDROGENTELLURIDE 532.0079 -I.0876E+04 -2.3540E+02 3.7306E-01 -2.3649E-04 176.75 271.15
134 H3N03S SULFAMICACID 0.1130 -6.8449E+02 5.2613E-05 -6.8934E-08 3.4587E-11 293.15 373.15
135 He HELIUM-3 2.1239 -1.1769E+00 2.0493E+00 -1.7652E-10 9.4980E-03 1.01 3.31
136 He HELIUM-4 2.8838 -3.9043E+00 6.7240E-01 1.1913E-01 -2.1010E-11 1.76 5.20
137 Hf HAFNIUM -187.3128 -4.7256E+03 5.9397E+01 -7.1673E-03 2.6648E-07 2117.00 5960.00
138 Hg MERCURY 11.3169 -3.3515E+03 -1.1296E+00 -2.9698E-13 1.1699E-07 234.31 1735.00
139 HgBr2 MERCURIC BROMIDE -6001.9471 1.6586E+05 2.4352E+03 -2.1646E+00 7.2767E-04 409.65 592.15
140 HgCL2 MERCURIC CHLORIDE 8091.0938 -2.3113E+05 -3.2811E+03 2.9716E+00 -1.0294E-03 409.35 577.15
141HgI2 MERCURIC IODIDE -9817.2743 2.9088E+05 3.9308E+03 -3.2560E+00 1.0229E-03 430.65 627.15
142 IF7 IODINE HEPTAFLUORIDE 2.2894 -1.4949E+03 2.7875E+00 -3.5044E-03 1.9005E-06 186.15 277.15
143 12 IODINE 46.9335 -5.1763E+03 -1.1170E+01 -1.0130E-02 7.7500E-06 242.00 819.15
144 In INDIUM 112.3721 -1.8894E+04 -3.5777E+01 1.1333E-02 -1.3444E-06 850.00 2323.00
145 Ir IRIDIUM "197.4829 -6.5755E+03 6.4387E+01 -9.6603E-03 5.0122E-07 1944.00 4450.00
146 K POTASSIUM 10.8410 -4.6934E+03 -1.1916E+00 1.5875E-04 1.7454E-17 336.35 2223.00
147 KBr POTASSIUM BROMIDE 86.7862 -1.5677E+04 -2.5680E+01 5.9097E-03 -5.6987E-07 1068.15 1656.15
148 KCt POTASSIUM CHLORIDE -8.0224 -9.3722E+03 6.4641E+00 -3.1639E-03 3.2745E-07 1044.00 3470.00
149 KF POTASSIUM FLUORIDE 86.1553 -1.7030E+04 -2.5138E+01 5.3564E-03 -4.7879E-07 1158.15 1775.15
150 KI POTASSIUM IODIDE 88.6708 -1.5026E+04 -2.6513E+01 6.3780E-03 -6.4206E-07 1018.15 1597.15
151KOH POTASSIUM HYDROXIDE 20.9787 -9.5262E+03 -3.8001E+00 -2.9030E-10 1.2312E-08 679.00 1600.00
152 Kr KRYPTON -12.6883 -3.1111E+02 1.0610E+01 -3.8518E-02 5.0870E-05 115.78 209.35
153 La LANTHANUM 190.2107 -4.1131E+04 -5.7186E+01 9.9276E-03 -6.4353E-07 1441.50 3643.00
154 Li LITHIUM 12.1182 -8.4301E+03 -1.3510E+00 2.2909E-04 -6.2641E-18 453.69 4085.00
155 LiBr L I T H I U MBROMIDE 65.3934 -1.3245E+04 -1.8782E+01 4.4647E-03 -4.4694E-07 1021.15 1583.15
156 LiCL L I T H I U MCHLORIDE 1659.2051 -1.1514E+05 -5.7029E+02 1.9064E-01 -2.4324E-05 1056.15 1655.15
157 LiF LITHIUM FLUORIDE 69.3367 -1.8147E+04 -1.9178E+01 3.6011E-03 -2.8544E-07 1320.15 1954.15
158 L i l LITHIUM IODIDE 72.2997 -1.4450E+04 -2.0834E+01 5.2464E-03 -5.5773E-07 996.15 1444.15
159 Lu LUTETIUM -47.6746 -1.1929E+04 1.8989E+01 -4.5961E-03 3.5367E-07 1057.00 2535.00
160 Mg MAGNESIUM -72.6513 -4.2014E+03 3.0264E+01 -1.5558E-02 2.6429E-06 517.00 1376.00
161MgCL2 MAGNESIUMCHLORIDE 1239.2680 -9.0236E+04 -4.2304E+02 1.3654E-01 -1.6884E-05 1051.15 1691.15
162 MgO MAGNESIUMOXIDE -41.2727 -1.4025E+04 1.5392E+01 -2.3614E-03 1.1265E-07 3105.00 5950.00
163 Mn MANGANESE "123.9176 -5.9845E+03 4.6074E+01 -1.4659E-02 1.5195E-06 924.00 2392.00
164 MnCl2 MANGANESE CHLORIDE 1275.0362 -8.8381E+04 -4.3842E+02 1.4858E-01 -1.9347E-05 1009.15 1463.15
165 Mo MOLYBDENUM 74.9735 -4.1955E+04 -2.0072E+01 3.2166E-03 -2.2507E-07 1677.00 5100.00
166 MoF6 MOLYBDENUM FLUORIDE 300.7229 -7.9655E+03 -1.2644E+02 1.6582E-01 -8.8423E-05 207.65 309.15
167 MoO3 MOLYBDENUM OXIDE 3015.8551 -2.1859E+05 -1.0259E+03 3.1920E-01 -3.8938E-05 1007.15 1424.15
168 N C L 3 NITROGENTRXCHLORIDE 88.8600 -4.2008E+03 -3.1565E+01 1.8305E-02 -6.0409E-11 246.15 367.15
169 ND3 HEAVY AMMONIA 125.5395 -3.5614E+03 -5.1766E+01 7.4954E-02 -4.4958E-05 199.15 239.75
170 NF3 NITROGEN TRXFLUORIDE 8.4514 -7.4300E+02 3.9105E-01 -1.1295E-02 1.7758E-05 66.36 233.85
171NH3 AMMONIA 37.1575 -2.0277E+03 -1.1601E+01 7.4625E-03 -9.5811E-12 195.41 405.65
172 NH30 HYDROXYLAMINE 2.4590 -4.0142E+03 6.3297E+00 -1.8547E-02 1.1266E-05 306.25 383.00
173 NH4Br AMMONIUM BROMIDE 23.7261 -5.2014E+03 -5.1721E+00 2.6919E-03 -5.9955E-07 471.45 669.15
174 NH4CL AMMONIUM CHLORIDE -893.5430 1.9484E+04 3.6716E+02 -3.2056E-01 1.0034E-04 553.15 793.15
175 N H 4 1 AMMONIUM IODIDE 0.4097 -4.4032E+03 3.5216E+00 -1.7562E-03 3.7842E-07 484.05 678.05
176 NH50 AMMONIUM HYDROXIDE 42.3381 -2.3577E+03 -1.3597E+01 8.5486E-03 4.7298E-11 203.15 353.15
177 N H 5 S AMMONIUMHYDROGENSULFIDE 178.9587 -6.0657E+03 -7.2004E+01 8.7809E-02 -4.4365E-05 222.05 306.45
178 NO NITRIC OXIDE 61.2046 -1.5365E+03 -2.3621E+01 2.9377E-02 -1.3066E-09 109.50 180.15
179 NOCL NITROSYLCHLORIDE 24.1469 -1.8469E+03 -6.0513E+00 9.2881E-09 4.5319E-06 213.55 440.65
180 NOF NITROSYLFLUORIDE 478.8331 -7.7441E+03 -2.2562E+02 4.9213E-01 -4.2279E-04 141.15 217.15
181 NO2 NITROGENDIOXIDE 32.1203 -2.2563E+03 -9.7702E+00 8.6560E-03 -5.1036E-11 261.95 431.35
182 N2 NITROGEN 23.8572 -4.7668E+02 -8.6689E+00 2.0128E-02 -2.4139E-11 63.15 126.10
183 N 2 F 4 TETRAFLUOROHYDRAZINE 16.4473 -9.6387E+02 -4.3123E+00 5.9876E-03 2.2680E-13 111.65 309.35
184 N 2 H 4 HYDRAZINE 31.2541 -3.1466E+03 -8.2200E+00 2.6734E-03 4.6004E-13 274.68 653.15
185 N2H4C AMMONIUMCYANIDE 179.6608 -6.1294E+03 -7.2215E+01 8.8090E-02 -4.4545E-05 222.55 304.85
186 N2H6C02 AMMONIUMCARBAMATE 93.9638 -4.8160E+03 -3.4502E+01 3.6858E-02 -1.6578E-05 247.05 331.45
187 N20 NITROUS OXIDE 61.5168 -2.1016E+03 -2.2337E+01 1.8232E-02 -1.1348E-10 182.30 309.57

* A computer program, containing c o e f f i c i e n t s f o r vapor pressure f o r a l l compounds , is a v a i t a b t e f o r a nominal fee (Carl L.


Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other software.

354
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

log,o P = A + B / T + C t o g , o T + D T + E T 2 (P - mm Hg, T - K)

NO FORMULA NAME A B C D E TM I N TMAX


. . .

188 N 2 0 3 NITROGENTRIOXIDE -2.5932 -1.8582E+03 7.4627E+00 -2.7402E-02 2.0570E-05 170.00 425.00


189 N 2 0 4 NITROGENTETRAOXIDE -197.7926 7.7599E+02 9.9702E+01 -2.0780E-01 1.4907E-04 261.90 320.65
190 N 2 0 5 NITROGENPENTOXIDE -270.4814 4.6851E+02 1.3740E+02 -2.9833E-01 2.3064E-04 236.35 305.55
191Na SODIUM 7.2828 -5.4249E+03 1.5358E-01 -2.0200E-04 3.7007E-08 370.97 257"5.00
192 NaBr SODIUM BROMIDE 18.4164 -1.0501E+04 -2.8637E+00 8.9249E-10 -1.1019E-13 1020.00 1720.00
193 NaCN SODIUM CYANIDE -2.2303 -8.2019E+03 3.8990E+00 -2.3458E-03 3.9325E-07 836.85 1769.10
194 NaCt SODIUM CHLORIDE 22.4317 -1.1358E+04 -4.2035E+00 3.4674E-04 -3.9472E-12 1073.90 1738.10
195 NaF SODIUM FLUORIDE 11.6744 -1.1663E+04 -9.6084E-01 1.2957E-04 -1.1232E-14 1269.00 2060.00
196 Nal SODIUM IODIDE 69.6407 -1.4137E+04 -2.0041E+01 4.7338E-03 -4.7106E-07 1040.15 1577.15
197 NaOH SODIUM HYDROXIDE -48.2774 -1.9340E+03 1.7000E+01 2.9640E-11 -8.7510E-07 596.00 1830.00
198 Na2S04 SODIUMSULFATE -2.2687 -1.5051E+04 3.5005E+00 -1.2712E-03 1.7716E-07 1173.10 1223.10
199 Nb NIOBIUM -64.3485 -2.9438E+04 2.3622E+01 -3.9155E-03 2.0660E-07 2250.00 5115.00
200 Nd NEODYMIUM 130.3312 -2.6812E+04 -3.9789E+01 8.4714E-03 -6.7800E-07 1144.00 3384.00
201Ne NEON 0.0175 -5.9863E+01 3.6341E+00 -8.8025E-09 -1.8115E-04 24.56 44.40
202 Ni NICKEL -57.4301 -1.3533E+04 2.3611E+01 -7.6670E-03 7.8143E-07 1061.00 2415.00
203 NiC404 NICKEL CARBONYL 24.7530 -1.9573E+03 -7.0802E+00 7.4594E-03 -3.3536E-06 250.15 315.65
204 NiF2 NICKEL FLUORIDE 634.6103 -7.2704E+04 -2.0233E+02 4.4627E-02 -3.9862E-06 1350,15 1556.15
205 Np NEPTUNIUM 88.3172 -3.1522E+04 -2.5083E+01 4.1165E-03 -2.8679E-07 1617.99 2073.99
206 02 OXYGEN 20.6695 -5.2697E+02 -6.7062E+00 1.2926E-02 -9.8832E-13 54.35 154.58
207 O3 OZONE 38.6910 -1.4144E+03 -1.2543E+01 -1.3045E-10 2.4393E-05 80.15 261.00
208 Os OSMIUM -252.0332 -6.3868E+03 8.1758E+01 -1.2735E-02 7.0592E-07 2234.00 4880.00
209 OsOF5 OSMIUMOXIDE PENTAFLUORIDE 18125.3278 -4.6581E+05 -7.4493E+03 6.8812E+00 -2.0309E-03 304.80 330.90
210 Os04 OSMIUM TETROXIDE - YELLOW -6976.1921 1.3882E+05 3.0478E+03 -4.0659E+00 2.0494E-03 276.35 403.15
2110s04 OSMIUM TETROXIDE - WHITE -1362.6815 2.3640E+04 6.0656E+02 -8.6236E-01 4.5669E-04 267.55 403.15
212 P PHOSPHORUS - WHITE 37.5747 -4.5200E+03 -9.8304E+00 -1.4385E-06 1.4357E-06 404.15 590.15
213 PBr3 PHOSPHORUSTRIBROMIDE 75.1763 -4.1298E+03 -2.7120E+01 2.3495E-02 -8.5043E-06 280.95 448.45
214 PCL2F3 PHOSPHORUSDICHLORIDE TRIFLUORIDE 41.7838 -2.0432E+03 -1.4841E+01 2.0345E-02 -1.1817E-05 193.35 250.35
215 PCt3 PHOSPHORUSTRICHLORIDE 56.7046 -3.2295E+03 -1.8915E+01 1.0097E-02 -7.5546E-13 181.15 374.15
216 PCt5 PHOSPHORUSPENTACHLORIDE 30.0396 -6.2579E+03 -7.4964E-01 -2.9515E-02 1.0957E-05 433.15 465.00
217 PH3 PHOSPHINE 17.6034 -1.0512E+03 -4.0706E+00 -1.5186E-09 5.1920E-06 139.37 324.75
218 P H 4 B r PHOSPHONIUMBROMIDE 79.2715 -4.0989E+03 -2.8848E+01 3.2807E-02 -1.5741E-05 229.45 311.45
219 PH4CL PHOSPHONIUMCHLORIDE 255.9276 -6.5388E+03 -1.0929E+02 1.6761E-01 -1.0572E-04 182.15 246.15
220 P H 4 I PHOSPHONIUMIODIDE 90.3833 -4.6958E+03 -3.3063E+01 3.5026E-02 -1.5625E-05 247.95 335.45
221POCt3 PHOSPHORUSOXYCHLORIDE 89.5904 -4.4038E+03 -3.1847E+01 1.8570E-02 1.2780E-08 274.33 378.65
222 P S B r 3 PHOSPHORUSTHIOBROMIDE 100.8066 -6.1441E+03 -3.5921E+01 2.9018E-02 -9.8408E-06 323.15 448.15
223 PSCL3 PHOSPHORUSTHIOCHLORIDE 30.9267 -2.9337E+03 -8.3323E+00 2.4967E-03 -3.2735E-11 236.95 398.15
224 P 4 0 6 PHOSPHORUSTRIOXIDE -9.1727 -1.7181E+03 6.7269E+00 -5.0441E-03 1.6463E-06 312.85 446.25
225 P 4 0 1 0 PHOSPHORUSPENTOXIDE -55.9316 -2.8529E+03 2.7900E+01 -2.9138E-02 9.4669E-06 693.15 758.15
226 P 4 S 1 0 PHOSPHORUSPENTASULFIDE 18.3195 -5.1772E+03 -3.3346E+00 1.0110E-03 -6.7993E-14 561.15 1291.00
227 Pb LEAD -17.6204 -8.5777E+03 9.2106E+00 -3.9318E-03 5.4789E-07 708.00 2024.00
228 PbBr2 LEAD BROMIDE -392.9133 9.8716E+03 1.4928E+02 -7.7340E-02 1.4423E-05 786.15 1187.15
229 PbCt2 LEAD CHLORIDE 178.2156 -1.8711E+04 -5.7943E+01 1.8346E-02 -2.4020E-06 820.15 1227.15
230 PbF2 LEAD FLUORIDE 797.7308 -6.5142E+04 -2.6816E+02 8.0837E-02 -9.4270E-06 1134.15 1566.15
231 PbI2 LEAD IODIDE 1790.0196 -9.5547E+04 -6.4509E+02 2.9522E-01 -5.2262E-05 752.15 1145.15
232 PbO LEAD OXIDE -357.2600 1.4278E+04 1.2467E+02 -3.7266E-02 4.2118E-06 1216.15 1745.15
233 PbS LEAD SULFIDE -2243.0170 1.5079E+05 7.6189E+02 -2.1739E-01 2.2835E-05 1125.15 1554.15
234 Pd PALLADIUM 90.8138 -2.9630E+04 -2.5363E+01 3.7450E-03 -2.0394E-07 1336.00 3385.00
235 Po POLONIUM 220.5827 -1.5775E+04 -7.8208E+01 3.8994E-02 -7.4047E-06 448.00 1235.00
236 Pt PLATINUM 87.6383 -4.0548E+04 -2.2701E+01 1.8600E-03 -1.5887E-08 1744.00 3980.00
237 Ra RADIUM 31.4507 -I.0221E+04 -7.3958E+00 4.1178E-04 1.3090E-07 593.00 1809.00
238 Rb RUBIDIUM 13.7111 -4.4634E+03 -2.1307E+00 -7.2787E-05 1.8422E-07 310.00 978.00
239 RbBr RUBIDIUM BROMIDE 78.4584 -1.4856E+04 -2.2965E+01 5.3426E-03 -5.2198E-07 1054.15 1625.15
240 R b C t RUBIDIUM CHLORIDE 95.4464 -1.6358E+04 -2.8542E+01 6.6137E-03 -6.4090E-07 1065.15 1654.15
241RbF RUBIDIUM FLUORIDE 4858.3696 -3.9369E+05 -1.6193E+03 4.3432E-01 -4.5433E-05 1194.15 1681.15
242 Rbl RUBIDIUMIODIDE 87.3359 -1.5106E+04 -2.6017E+01 6.2775E-03 -6.3467E-07 1021.15 1577.15
243 Re RHENIUM -31.5392 -3.2254E+04 1.2215E+01 -1.2695E-03 3.7363E-08 2480.00 5915.00
244 Re207 RHENIUM HEPTOXIDE -50918.9674 1.6274E+06 2.0103E+04 -1.5444E+01 4.5207E-03 485.65 635.55
245 Rh RHODIUM -83.3270 -2.3619E+04 3.2126E+01 -8.8651E-03 7.4827E-07 1735.00 3940.00
246 Rn RADON 168.4046 -3.3600E+03 -7.5618E+01 1.4923E-01 -1.2016E-04 128.95 211.75
247 Ru RUTHENIUM 3.1324 -3.5567E+04 3.0770E+00 -1.1098E-03 6.9449E-08 2051.00 4500.00
248 RuF5 RUTHENIUMPENTAFLUORIDE 253.0895 -I.0396E+04 -9.8031E+01 8.5375E-02 -3.0601E-05 322.75 429.95
249 S SULFUR 86.7925 -7.8894E+03 -2.7433E+01 7.5706E-03 5.7656E-15 388.36 1313.00
250 SF4 SULFUR TETRAFLUORIDE 340.1740 -6.8405E+03 -1.5222E+02 2.6997E-01 -1.9417E-04 160.85 223.95
251 SF6 SULFUR HEXAFLUORIDE 10.5389 -I.0352E+03 -1.1341E+00 -I.8565E-07 1.1504E-I0 223.15 318.69
252 SOBr2 THIONYLBROMIDE 1.5135 -1.9716E+03 2.6530E+00 -2.2814E-03 8.4571E-07 266.45 412.65
253 S O C t 2 THIONYLCHLORIDE 66.4546 -3.3385E+03 -2.3318E+01 1.5153E-02 -8.4247E-12 172.00 372.15
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , . . . ,

* A computer program, c o n t a i n i n g c o e f f i c i e n t s f o r vapor pressure f o r a l l compounds, is a v a i t a b t e f o r a nominat fee (Cart L.


Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other software.

355
l og,o P = A + B / T + C l Og,o T + D T + E T 2 (P - mm Hg, T - K)

NO FORMULA NAME A B C D E TM IN TMAX

254 SOF2 SULFUROUS OXYFLUORIDE 238.2631 -5.2181E+03 -I.0431E+02 1.7358E-01 -1.1781E-04 174.42 229.05
255 SO2 SULFUR DIOXIDE 19.7418 -1.8132E+03 -4.1458E+00 -4.4284E-09 8.4918E-07 197.67 430.75
256 S02C[2 SULFURYL CHLORIDE 5.9028 -2.0407E+03 2.2796E+00 -I.0358E-02 6.0161E-06 222.00 545.00
257 S03 SULFUR TRIOXIDE 114.0529 -6.4619E+03 -3.6784E+01 -1.7530E-07 1.1919E-05 289.95 490.85
258 S2CI2 SULFUR MONOCHLORIDE 162.6274 -6.2944E+03 -6.3327E+01 6.1401E-02 -2.4506E-05 265.75 411.15
259 Sb ANTIMONY -14.9322 -1.3754E+04 1.5738E+01 -2.3835E-02 5.1947E-06 617.00 1898.00
260 SbBr3 ANTIMONY TRIBROMIDE -68.4797 -6.2413E+02 3.0034E+01 -2.0378E-02 4.6884E-06 367.05 548.15
261SbCl3 ANTIMONY TRICHLORIDE 68.0484 -5.1047E+03 -2.1724E+01 7.4742E-03 5.7270E-13 346.55 794.00
262 SbCl5 ANTIMONY PENTACHLORIDE 73.6650 -4.3530E+03 -2.6389E+01 2.3832E-02 -9.0652E-06 295.85 387.25
263 SbH3 STIBINE 65.7241 -2.2895E+03 -2.5586E+01 3.4766E-02 -1.7809E-05 177.87 440.35
264 SbI3 ANTIMONY TRIIODIDE -1834.2309 5.3081E+04 7.3328E+02 -5.9001E-01 1.8014E-04 436.75 674.15
265 Sb203 ANTIMONY TRIOXIDE 3557.6905 -2.2934E+05 -1.2298E+03 4.1528E-01 -5.3009E-05 847.15 1698.15
266 Sc SCANDIUM -410.3222 1.5184E+04 1.4020E+02 -3.6544E-02 3.4523E-06 1110.00 2700.00
267 Se SELENIUM 994.5705 -4.3994E+04 -3.7357E+02 2.2452E-01 -5.1145E-05 397.00 930.00
268 SeCt4 SELENIUM TETRACHLORIDE 62.7934 -5.6601E+03 -2.0127E+01 1.5021E-02 -4.7573E-06 347.15 464.65
269 SeF6 SELENIUM HEXAFLUORIDE -13.7376 -9.6701E+02 1.0083E+01 -1.4935E-02 9.6551E-06 154.55 227.35
270 SeOC[2 SELENIUM OXYCHLORIDE -31.1449 -1.5960E+03 1.5901E+01 -1.1690E-02 3.7904E-06 307.95 441.15
271Se02 SELENIUM DIOXIDE -26.7091 -2.9884E+03 1.3896E+01 -7.6193E-03 1.8305E-06 430.15 590.15
272 Si SILICON 315.0687 -7.1384E+04 -8.9680E+01 8.3445E-03 -2.5806E-09 1997.10 2560. I0
273 SiBrCI2F BROMODICHLOROFLUOROSILANE 221.2325 -5.5951E+03 -9.3501E+01 1.2431E-01 -6.0950E-05 186.65 474.30
274 SiBrF3 TRIFLUOROBROMOSILANE -316.1829 5.0196E+03 1.4386E+02 -2.1246E-01 1.1958E-04 203.35 354.90
275 SiBr2CIF DIBROMOCHLOROFLUOROSILANE 114.7880 -3.9867E+03 -4.5478E+01 5.1723E-02 -2.2118E-05 207.95 515.92
276 SiClF3 TRIFLUOROCHLOROSILANE 102.6712 -2.5416E+03 -4.3347E+01 7.1921E-02 -4.5231E-05 129.15 308.83
277 SiCl2F2 DICHLORODIFLUOROSILANE 65.5754 -2.0450E+03 -2.6643E+01 4.5134E-02 -2.8299E-05 148.45 367.35
278 SiCl3F TRICHLOROFLUOROSILANE 106.0275 -3.4770E+03 -4.2166E+01 5.0626E-02 -2.3053E-05 180.55 434.85
279 SiC[4 SILICON TETRACHLORIDE 28.4503 -2.3911E+03 -7.3965E+00 -9.3193E-I0 2.7569E-06 204.30 507.00
280 SiF4 SILICON TETRAFLUORIDE 250.9551 -6.9843E+03 -9.4613E+01 -5.3053E-05 1.3121E-04 186.35 259.00
281SiHBr3 TRIBROMOSILANE 29.8264 -2.6956E+03 -8.0772E+00 2.0334E-03 1.0063E-06 242.65 617.50
282 SiHCl3 TRICHLOROSILANE 8.8008 -1.6896E+03 5.0043E-01 -6.9024E-03 5.1631E-06 144.95 479.00
283 SIHF3 TRIFLUOROSILANE -122.7759 5.7853E+01 6.9914E+01 -2.1980E-01 2.2343E-04 121.15 276.65
284 SiH2Br2 DIBROMOSILANE 63.8405 -2.9308E+03 -2.3568E+01 2.4715E-02 -9.7683E-06 212.25 559.24
285 SiH2Cl2 DICHLOROSILANE 30.1827 -2.0844E+03 -8.2717E+00 -3.7469E-I0 4.5636E-06 151.15 449.00
286 SiH2F2 DIFLUOROSILANE 23.8427 -1.5675E+03 -4.4921E+00 -1.9742E-02 3.1144E-05 126.45 310.75
287 SiH212 DIIODOSILANE -132.4973 2.1632E+03 5.6398E+01 -4.9010E-02 1.6020E-05 276.95 683.81
288 SiH3Br MONOBROMOSILANE 48.9247 -2.1416E+03 -1.7831E+01 2.1780E-02 -I.0087E-05 187.45 455.15
289 SIH3CI MONOCHLOROSILANE 97.0716 -3.0578E+03 -3.8232E+01 4.4033E-02 -1.8687E-05 155.35 396.79
290 SiH3F MONOFLUOROSILANE 262.3858 -5.0922E+03 -1.1579E+02 1.8678E-01 -1.1081E-04 120.15 285.87
291SiH31 IODOSILANE 81.5431 -3.3034E+03 -3.0771E+01 3.1175E-02 -1.1973E-05 220.15 524.59
292 SiH4 SILANE 49.8037 -1.3946E+03 -1.8981E+01 2.2497E-02 3.0530E-13 88.48 269.70
293 Si02 SILICON DIOXIDE -378.5210 6.5473E+03 1.3150E+02 -3.ST/4E-02 3.4220E-06 I883.00 2503.20
294 Si2Cl6 HEXACHLORODISILANE 28.0093 -2.9842E+03 -7.7427E+00 6.7458E-03 -2.5044E-06 277.15 412.15
295 Si2F6 HEXAFLUORODISILANE -3.5918 -1.9401E+03 6.6355E+00 -8.5356E-03 4.7603E-06 192.15 254.25
296 Si2H5Cl DISILANYL CHLORIDE 50.2854 -2.4890E+03 -1.8081E+01 2.1374E-02 -I.0671E-05 226.95 291.15
297 Si2H6 DISILANE 19.4083 -1.5000E+03 -4.5432E+00 -2.0804E-I0 3.3390E-06 143.85 432.00
298 Si2OCl3F3 TRICHLOROTRIFLUORODISILOXANE -39.7219 -2.7322E+02 1.9305E+01 -1.7428E-02 7.2191E-06 235.15 316.35
299 Si20Cl6 HEXACHLORODISILOXANE 173.0145 -6.6562E+03 -6.7483E+01 6.5445E-02 -2.6121E-05 268.15 408.75
300 Si20H6 DISILOXANE 23.4097 -1.5324E+03 -6.9541E+00 1.0056E-02 -6.1820E-06 160.65 257.75
301Si3Cl8 OCTACHLOROTRISILANE 0.9548 -2.4388E+03 2.9120E+00 -2.1105E-03 6.5985E-07 319.45 484.55
302 Si3H8 TRISILANE 61.7030 -2.7796E+03 -2.2974E+01 2.7178E-02 -1.3469E-05 204.25 326.25
303 Si3H9N TRISILAZANE 77.8169 -3.1701E+03 -2.9814E+01 3.5861E-02 -1.8007E-05 204.45 321.85
304 Si4H10 TETRASILANE 72.5811 -3.7126E+03 -2.6507E+01 2.6806E-02 -1.1367E-05 245.45 373.15
305 Sm SAMARIUM -63.3814 -6.9759E+03 2.5576E+01 -9.5945E-03 1.2128E-06 733.00 1874.00
306 Sn TIN -11.8452 -1.3744E+04 6.4004E+00 -9.7861E-04 -4.2795E-I0 1096.00 2995.00
307 SnBr4 STANNIC BROMIDE 62.0925 -4.1212E+03 -2.1351E+01 1.6385E-02 -5.2861E-06 331.45 477.85
308 SnCl2 STANNOUS CHLORIDE 430.9683 -2.2551E+04 -1.5874E+02 9.2347E-02 -2.1208E-05 589.15 896.15
309 SnCl4 STANNIC CHLORIDE 146.4762 -5.5847E+03 -5.7244E+01 5.8634E-02 -2.4782E-05 250.45 386.15
310 SnH4 STANNIC HYDRIDE 7.8482 -9.7474E+02 -2.7435E-01 4.6026E-04 -3.3081E-07 133.15 220.85
311SnI4 STANNIC IODIDE -5.9850 -2.4424E+03 5.1095E+00 -2.7912E-03 6.6165E-07 429.15 621.15
312 Sr STRONTIUM -111.2297 -2.8962E+03 4.3785E+01 -2.0560E-02 3.2941E-06 582.00 1630.00
313 SrO STRONTIUM OXIDE 2848.9447 -4.0303E+05 -8.7252E+02 1.3051E-01 -7.7456E-06 2341.15 2683.15
314 Ta TANTALUM 90.4608 -5.3107E+04 -2.4076E+01 2.9553E-03 -1.3908E-07 2511.00 5565.00
315 Tc TECHNETIUM -240.5191 -5.7928E+03 7.8794E+01 -1.3112E-02 7.4635E-07 1660.00 5000.00
316 Te TELLURIUM -130.9948 -5.2810E+03 5.7873E+01 -4.6486E-02 1.0781E-05 497.00 1285.00
317 TeCl4 TELLURIUM TETRACHLORIDE 225.5681 -1.3194E+04 -8.0899E+01 4.5316E-02 -I.0441E-05 506.15 665.15
318 TeF6 TELLURIUM HEXAFLUORIDE 103.1152 -3.1620E+03 -4.2245E+01 6.7520E-02 -4.5015E-05 161.85 234.55
319 Ti TITANIUM -194.8742 -8.2733E+03 6.8261E+01 -1.7329E-02 1.5517E-06 1508.00 3442.00

* A computer program, containing c o e f f i c i e n t s f o r vapor pressure f o r a l l compounds, is a v a i t a b l e f o r a nominat fee (Carl L.


Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII whi ch can be
accessed by other software.

356
tog,o P = A + BIT + C tog,o T + D T + E T 2 (P - mm Hg, T - K)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

NO FORMULA NAME A B C D E TMI N TMAX

320 TiCt4 TITANIUMTETRACHLORIDE 65.9073 -4.0187E+03 -2.2002E+01 1.0422E-02 -8.7715E-13 249.05 638.00
321TL THALLIUM 149.2845 -1.7175E+04 -4.9494E+01 1.8084E-02 -2.5186E-06 636.00 1745.00
322 TtBr THALLOUSBROMIDE 65.7795 -9.3154E+03 -1.9913E+01 6.6371E-03 -9.3147E-07 763.15 1092.15
323 TtI THALLOUSIODIDE 107.4718 -1.2047E+04 -3.4449E+01 1.2081E-02 -1.7669E-06 713.15 1096.15
324 Tm THULIUM 581.9203 -4.0634E+04 -2.0847E+02 9.8996E-02 -1.8204E-05 661.00 1237.00
325 U URANIUM 5.1916 -2.3655E+04 1.4051E+00 -6.7084E-04 6.4472E-08 1600.00 4135.00
326 UF6 URANIUM FLUORIDE 141.7284 -5.4522E+03 -5.5519E+01 6.2879E-02 -2.9623E-05 234.35 328.85
327 V VANADIUM 52.0677 -3.1989E+04 -1.2620E+01 1.6179E-03 -1.0505E-07 1604.00 3665.00
328 VCt4 VANADIUMTETRACHLORIDE 12.7215 -2.2338E+03 -1.7693E+00 -9.8525E-11 3.4861E-07 247.45 697.00
329 V O C [ 3 VANADIUMOXYTRICHLORIDE 31.8135 -2.8585E+03 -8.5879E+00 3.9375E-09 3.4924E-06 193.65 400.00
330 W TUNGSTEN -19.5111 -3.8683E+04 8.6887E+00 -7.1355E-04 2.1195E-08 2667.00 5645.00
331 WF6 TUNGSTEN FLUORIDE 354.8192 -8.8753E+03 -1.5107E+02 2.0875E-01 -1.1715E-04 201.55 290.45
332 Xe XENON 15.6530 -8.1035E+02 -3.9013E+00 4.7985E-03 -1.7020E-11 161.36 289.74
333 Yb YTTERBIUM -61.8092 -5.3349E+03 2.5566E+01 -1.1528E-02 1.7104E-06 599.00 1660.00
334 Yt YTTRIUM -198.7054 -2.2991E+03 6.8766E+01 -1.6442E-02 1.3848E-06 1246.00 3055.00
335 Zn ZINC -20.3143 -4.6362E+03 1.0073E+01 -3.8085E-03 4.8860E-07 692.70 3170.00
336 ZnCt2 ZINC CHLORIDE 256.5500 -1.7845E+04 -9.1583E+01 4.9680E-02 -1.0787E-05 701.15 1005.15
337 ZnF2 ZINC FLUORIDE -17799.4171 1.2561E+06 6.0444E+03 -1.7915E+00 2.0155E-04 1243.15 1770.15
338 ZnO ZINC OXIDE 10.0724 -1.5790E+04 -3.0065E-02 6.5659E-06 -5.4927E-10 1773.10 2223.10
339 ZnS04 ZINC SULFATE 8.7415 -2.2158E+03 -5.1178E-04 6.6577E-07 -3.3159E-10 293.15 378.15
340 Zr ZIRCONIUM 95.1134 -4.3264E+04 -2.5683E+01 2.9830E-03 -1.1696E-07 1975.00 4598.00
341ZrBr4 ZIRCONIUM BROMIDE 35.8920 -6.9028E+03 -8.7767E+00 4.6821E-03 -I.0688E-06 480.15 630.15
342 ZrC[4 ZIRCONIUM CHLORIDE 80.7853 -8.5643E+03 -2.5618E+01 1.4577E-02 -3.5146E-06 463.15 604.15
343 ZrI4 ZIRCONIUM IODIDE 95.3927 -I.0449E+04 -3.0444E+01 1.5025E-02 -3.1340E-06 537.15 704.15

* A computer program, c o n t a i n i n g c o e f f i c i e n t s f o r vapor pressure f o r a l l compounds, is a v a i t a b t e f o r a nominal fee (Cart I .


Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other software.

357
Appendix D

CRITICAL PROPERTIES AND ACENTRIC FACTOR*


Carl L. Yaws, Sachin Nijhawan and Li Bu
Lamar University, Beaumont, Texas

MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/m0t K K K bar cm3/mo t g/cm 3 Zc ~ SOURCE

1Ag SILVER 107.868 1234.00 2485.00 7480.00 5066.0 58.20 1.8534 0.474 0.150 1,6
2 AgCt SILVER CHLORIDE 143.321 728.15 1837.15 . . . . . . . . . . . . . . . "'" 2

3 AgI SILVER IODIDE 234.773 825.15 1779.15 . . . . . . . . . . . . . . . --- 2

4 At ALUMINUM 26.982 933.00 2329.15 7151.00 5458.0 39.00 0.6918 0.358 --- 1
5 ALB3H12 ALUMINUM BOROHYDRIDE 71.510 209.15 319.05 . . . . . . . . . . . . . . . "'" 2

6 AtBr3 ALUMINUN BROMIDE 266.694 390.15 529.45 763.00 --- 124.20 2.1473 --- --- 3,6
7 ALCL3 ALUMINUM CHLORIDE 133.340 465.70 453.15 629.00 26.35 261.45 0.5100 0.132 --- 1
8 AtF3 ALUMINUM FLUORIDE 83.977 1313.15 1810.15 . . . . . . . . . . . . . . . . . .

9 ALl3 ALUMINUM IODIDE 407.695 464.15 658.65 . . . . . . . . . . . . . . . . . . 2,10


101.961 2325.00 3253.15 5335.00 --- . . . . . . . . . . . .
10 At203 ALUMINUM OXIDE
342.154 1043.20 . . . . . . . . . . . . . . . . . . . . .
11 At2S3012 ALUMINUM SULFATE
12 Ar ARGON 39.948 83.80 87.28 150.86 48.98 74.59 0.5356 0.291 0.000 1
13 As ARSENIC 74.922 1090.15 885.00 1673.15 --- . . . . . . . . . . . . 4,5
14 AsBr3 A R S E N I CTRIBROMIDE 314.634 306.15 493.15 . . . . . . . . . . . . . . . . . . 2,10
15 AsC[3 A R S E N I CTRICHLORIDE 181.280 255.15 403.55 . . . . . . . . . . . . . . . . . .

. . . . . . . . . . . .
16 AsF3 ARSENIC TRIFLUORIDE 131.917 267.25 329.45 . . . . . .
. . . . . . . . . . . .
17 AsF5 ARSENIC PENTAFLUORIDE 169.914 193.35 220.35 . . . . . .
18 AsH3 ARSINE 77.945 156.28 210.67 373.00 65.50 97.80 0.7970 0.207 0.006 1
19 AsI3 ARSENIC TRIIODIDE 455.635 419.15 676.15 . . . . . . . . . . . . . . . . . . 2,5
. . . . . . . . . . . .
20 As203 A R S E N I CTRIOXIDE 197.841 585.95 730.35 . . . . . .
21 At ASTATINE 210.000 575.15 607.00 . . . . . . . . . . . . . . . . . . 4,5
22 Au GOLD 196.967 1337.33 3120.00 4398.00 --- 50.30 3.9158 ...... 4,5,6
23 B BORON 10.811 2348.15 4133.00 . . . . . . . . . . . . . . . . . . 4,5
24 BBr3 BORON TRIBROMIDE 250.523 228.15 364.85 . . . . . . . . . . . . . . . . . .

25 BC[3 BORON TRICHLORIDE 117.169 166.15 285.65 451.95 38.71 148.34 0.7899 0.153 0.151 1
26 BF3 BORON TRIFLUORIDE 67.806 146.05 173.35 260.90 49.85 123.61 0.5485 0.284 0.430 1
27 BH2CO BORINE CARBONYL 40.837 136.15 209.15 . . . . . . "'" 3

28 BH303 BORIC ACID 61.833 458.15 . . . . . . . . . --- I

29 B 2 D 6 DEUTERODIBORANE 33.718 --- 179.87 . . . . . . --- 2

30 B2H5Br DIBORANEHYDROBROMIDE 106.566 168.95 289.45 . . . . . . --- 3

31B2H6 DIBORANE 27.670 107.65 180.65 289.80 40.53 1 7 3 . 1 0 0 . 1 5 9 8 0.291 0.125 1


32 B3N3H6 B O R I N E TRIAMINE 80.501 214.95 323.75 . . . . . . "'" 2

33 B4HIO TETRABORANE 53.323 153.25 289.25 . . . . . . --- 2

34 B S H 9 PENTABORANE 63.126 226.35 331.55 568.45 46.41 285.1 0 . 2 2 1 4 0 . 2 8 0 --- 2,8


. . . . . .
35 B 5 H 1 1 TETRAHYDROPENTABORANE 65.142 --- 340.15 . . . . . .
36 B10H14 DECABORANE 122.221 372.75 486.15 . . . . . . ...... 2,10
37 Ba BARIUM 137.327 1000.15 1907.00 . . . . . . ...... 2,4,5
38 Be BERYLLIUM 9.012 1560.15 2744.00 . . . . . . ...... 4,5
. . . . . .
39 B e B 2 H 8 BERYLLIUMBOROHYDRIDE 38.698 396.15 363.15 . . . . . .
. . . . . .
40 BeBr2 BERYLLIUMBROMIDE 168.820 763.15 747.15 . . . . . .
41 Beet2 BERYLLIUMCHLORIDE 79.918 678.15 760.15 ...... . . . . . .

42 BeF2 B E R Y L L I U MFLUORIDE 47.009 1073.15 . . . . . . . . . ...... 2,10


43 BeI2 B E R Y L L I U MIODIDE 262.821 761.15 760.15 . . . . . . . . . . . .

44 Bi BISMUTH 208.980 544.15 1698.15 4620.00 --- 79.40 2.6320 ...... 3,6
45 BiBr3 B I S M U T HTRIBROMIDE 448.692 491.15 734.15 1220.00 --- 302.00 1 . 4 8 5 7 ...... 2,6
46 BiCt3 B I S M U T HTRICHLORIDE 315.338 503.15 714.15 1178.00 --- 2 6 1 . 7 0 1.2050 ...... 2,6
47 BrF5 BROMINE PENTAFLUORIDE 174.896 211.75 313.55 470.00 --- . . . . . . . . . . . . 2,6
48 Br2 BROMINE 159.808 265.90 331.90 584.15 103.35 135.00 1.1838 0.287 0.119 1
49 C CARBON 12.011 4247.00 4203.00 6810.00 2230.0 18.80 0.6389 0.074 1.566 1
50 CC[20 PHOSGENE 98.916 145.37 280.71 455.00 56.74 190.22 0.5200 0.285 0.201 I
51 CF20 CARBONYLFLUORIDE 66.007 161.89 188.58 297.00 57.60 1 4 1 . 0 0 0.4681 0 . 3 2 9 0 . 2 8 3 1
52 CH4N20 UREA 60.056 405.85 465.00 705.00 90.50 218.00 0.2755 0.337 --- 1
53 CH4N2S THIOUREA 76.122 454.15 536.00 854.00 82.30 248.00 0.3069 0.287 0.359 1
54 C N B r CYANOGENBROMIDE 105.922 331.15 334.65 . . . . . . . . . . . . . . . . . . 2
55 C N C [ CYANOGENCHLORIDE 61.470 266.65 286.00 449.00 59.90 1 6 3 . 0 0 0.3771 0 . 2 6 2 0 . 3 2 0 1
56 CNF CYANOGEN FLUORIDE 45.016 --- 227.17 . . . . . . . . . . . . . . . . . . 2
57 CO CARBON MONOXIDE 28.010 68.15 81.70 132.92 34.99 93.10 0.3009 0.295 0.066 1
58 COS CARBONYL SULFIDE 60.076 134.35 223.00 378.80 63.49 135.10 0.4447 0.272 0.097 1

* A computer program, c o n t a i n i n g d a t a f o r a l l compounds, i s a v a i t a b t e f o r a nominal f e e ( C a r l L. Yaws, Box 10053, Lamar U n i v e r s i t y ,


Beaumont, TX 77710, phone/FAX 4 0 9 - 8 8 0 - 8 7 8 7 ) . The computer program i s i n ASCII which can be accessed by o t h e r s o f t w a r e .

358
MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc ~ SOURCE

59 COSe CARBON OXYSELENIDE 106.970 --- 251.25 ...... . . . . . . . . . . . .

60 C02 CARBON DIOXIDE 44.010 216.58 194.70 304.19 73.82 94.00 0.4682 0.274 0.228 1
61CS2 CARBON DISULFIDE 76.143 161.58 319.37 552.00 79.03 160.00 0.4759 0.276 0.108 1
62 CSeS CARBON SELENOSULFIDE 123.037 197.95 358.75 ...... . . . . . . . . . . . .

63 C 2 N 2 CYANOGEN 52.035 238.75 252.15 399.90 60.60 . . . . . . . . . --- 3,6


64 C3S2 CARBON SUBSULFIDE 100.165 273.55 . . . . . . . . . . . . . . . . . . "'" 3

65 Ca CALCIUM 40.078 1115.15 1762.00 . . . . . . . . . . . . . . . --- 4,5


66 OaF2 CALCIUM FLUORIDE 78.075 1691.00 2806.50 . . . . . . . . . . . . . . . --- 1
67 C b F 5 COLUMBIUMFLUORIDE 187.898 348.65 498.15 . . . . . . . . . . . . . . . "~ 3
68 Cd CADMIUM 112.411 594.05 1043.15 2291.00 --- 37.90 2.9660 --- --- 3,6
69 C d C L 2 CADMIUMCHLORIDE 183.316 841.15 1240.15 . . . . . . . . . . . . . . . "'" 3
70 CdF2 CADMIUM FLUORIDE 150.408 793.15 2024.15 . . . . . . . . . . . . . . . ~176 3

71 CdI2 CADMIUM IODIDE 366.220 658.15 1069.15 . . . . . . . . . . . . . . . --- 3


72 CdO CADMIUM OXIDE 128.410 --- 1832.15 . . . . . . . . . . . . . . . --- 2
73 CIF CHLORINE MONOFLUORIDE 54.451 128.15 172.65 . . . . . . . . . . . . . . . --- 2
74 ClF03 PERCHLORYLFLUORIDE 102.449 125.41 226.49 368.40 53.70 161.00 0.6363 0.282 0.173 1
75 CIF3 CHLORINETRIFLUORIDE 92.448 190.15 284.65 ...... . . . . . . . . . . . .

76 CIF5 CHLORINEPENTAFLUORIDE 130.445 --- 260.05 415.90 52.60 2 3 0 . 4 0 0 . 5 6 6 2 0 . 3 5 0 --- 2,6


77 C I H O 3 S CHLOROSULFONICACID 116.525 193.15 427.00 700.00 85.00 195.00 0.5976 0.285 0.301 1
78 CtH04 PERCHLORICACID 100.458 171.95 385.00 631.00 38.60 168.00 0.5980 0.124 0.050 1
79 CI02 CHLORINEDIOXIDE 67.452 213.55 284.05 465.00 86.13 . . . . . . . . . 0.356 1
80 C[2 CHLORINE 70.905 172.12 239.12 417.15 77.11 123.75 0.5730 0.275 0.069 1
81CI20 CHLORINEMONOXIDE 86.905 157.15 275.35 . . . . . . . . . . . . . . . ''" 2

82 Ct207 CHLORINEHEPTOXIDE 182.901 182.15 351.95 . . . . . . . . . . . . . . . --- 2

83 Co COBALT 58.933 1768.15 2528.00 . . . . . . . . . . . . . . . ~ 4,5


84 CoCl2 COBALT CHLORIDE 129.839 1008.15 1323.15 . . . . . . . . . . . . . . . "'" 2

85 CONC304 COBALTNITROSYL TRICARBONYL 172.971 262.15 353.15 . . . . . . . . . . . . . . . --- 3

86 Cr CHROMIUM 51.996 2180.15 2840.00 . . . . . . . . . . . . . . . --- 2,4,5


87 CRC606 CHROMIUMCARBONYL 220.059 423.65 424.15 . . . . . . . . . . . . . . . --- 3,10
88 CrO2Ct2 CHROMIUMOXYCHLORIDE 154.900 176.65 390.25 . . . . . . . . . . . . . . . -'- 2,10
89 Cs CESIUM 132.905 301.65 963.15 2048.10 116.50 316.40 0.4201 0.216 -'- 2,6
90 CsBr CESIUM BROMIDE 212.809 909.15 1573.15 ...... . . . . . . . . . . . .

91CsCl CESIUM CHLORIDE 168.358 919.15 1573.15 ...... . . . . . . . . . . -- 3

92 CsF CESIUM FLUORIDE 151.904 956.15 1524.15 ...... --- . . . . . . . . . 3

93 Csl CESIUM IODIDE 259.810 894.15 1553.15 ...... . . . . . . . . . . . .

94 Cu COPPER 63.546 1 3 5 7 . 7 7 3 1 5 0 . 0 0 5123.00 --- 61.00 1.0417 ...... 4,5,6


95 CuBr CUPROUS BROMIDE 143.450 777.15 1628.15 ...... . . . . . . . . . . . .

96 CuC[ CUPROUS CHLORIDE 98.999 703.00 1763.15 2435.00 --- . . . . . . . . . . . . I

97 CuCl2 CUPRIC CHLORIDE 134.451 906.15 1266.15 2010.00 --- . . . . . . . . . . . . I

98 CuI COPPER IODIDE 190.450 878.15 1609.15 ...... --- . . . . . . . . . 3

99 DCN DEUTERIUM CYANIDE 28.034 261.15 299.35 ...... . . . . . . . . . . . .

100 D2 DEUTERIUM 4.032 18.73 23.65 38.35 16.64 60.26 0.0669 0.314 -0.145 1
101D20 DEUTERIUM OXIDE 20.031 276.96 374.55 643.89 219.41 56.30 0.3558 0.231 0.368 1
102 Eu EUROPIUM 151.965 1095.15 1742.00 5150.00 --- . . . . . . . . . . . . 4,5,6
103 F2 FLUORINE 37.997 53.53 84.95 144.31 52.15 66.20 0.5740 0.288 0.059 1
104 F20 FLUORINE OXIDE 53.996 49.25 128.55 215.10 49.50 97.60 0.5532 0.270 --- 2,6
105 Fe IRON 55.847 1808.15 3000.00 9340.00 10150 28.00 1.9945 0.366 -0.298 1
106 FeCS05 IRON PENTACARBONYL 195.899 252.15 378.15 ...... . . . . . . . . . . . .

107 FeCt2 FERROUSCHLORIDE 126.752 945.15 1299.15 . . . . . . . . . . . . . . . . . . 3,10


108 FeCl3 FERRIC CHLORIDE 162.205 577.15 592.15 . . . . . . . . . . . . . . . . . .

109 Fr FRANCIUM 223.000 300.15 879.00 . . . . . . . . . . . . . . . . . . 4,5


110 Ga GALLIUM 69.723 302.91 2517.00 7620.00 --- 75.30 0.9259 ...... 4,5,6
111GaCI3 G A L L I U MTRICHLORIDE 176.081 350.90 474.15 694.00 38.20 263.00 0.6695 0.174 0.458 1
112 Gd GADOLINIUM 157.250 1587.15 1770.00 . . . . . . . . . . . . . . . . . . 4,5
113 Ge GERMANIUM 72.610 1211.40 3125.00 8400.00 . . . . . . . . . . . . . . . 4,5,6
114 GeBr4 GERMANIUMBROMIDE 392.226 299.25 462.15 . . . . . . . . . . . . . . . . . . 2
115 GeCI4 GERMANIUMCHLORIDE 214.421 223.65 357.15 . . . . . . . . . . . . . . . . . . 2
116 G e H C [ 3 TRICHLOROGERMANE 179.976 202.05 348.15 . . . . . . . . . . . . . . . . . . 2
117 GeH4 GERMANE 76.642 107.26 185.00 308.00 55.50 140.00 0.5474 0.303 0.151 1
118 Ge2H6 DIGERMANE 151.268 164.15 304.65 . . . . . . . . . . . . . . . . . . 2
119 Ge3H8 TRIGERMANE 225.894 167.55 383.95 . . . . . . . . . . . . . . . . . . 2
120 HBr HYDROGEN BROMIDE 80.912 186.34 206.45 363.15 85.52 100.26 0.8070 0.284 0.069 1
121HCN HYDROGEN CYANIDE 27.026 259.91 298.85 456.65 53.91 138.59 0.1950 0.197 0.410 1
122 HCI HYDROGEN CHLORIDE 36.461 158.97 188.15 324.65 83.09 81.02 0.4500 0.249 0.132 1
123 HF HYDROGEN FLUORIDE 20.006 189.79 292.67 461.15 64.85 69.00 0.2899 0.117 0.383 1
124 HI HYDROGEN IODIDE 127.912 222.38 237.55 423.85 83.10 121.94 1.0490 0.288 0.038 1
125 HN03 NITRIC ACID 63.013 231.55 356.15 520.00 68.90 145.00 0.4346 0.231 0.714 1
126 H2 HYDROGEN 2.016 13.95 20.39 33.18 13.13 64.15 0.0314 0.305 -0.215 1
127 H20 WATER 18.015 273.15 373.15 647.13 220.55 55.95 0.3220 0.229 0.345 1

* A computer program, c o n t a i n i n g data f o r a l l compounds, i s a v a i l a b l e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s i n ASCII which can be accessed by o t h e r s o f t w a r e .

359
MW TF Te Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc c0 SOURCE

128 H 2 0 2 HYDROGEN PEROXIDE 34.015 272.72 423.35 730.15 216.84 77.70 0.4378 0.278 0.360 1
129 H2S HYDROGEN SULFIDE 34.082 187.68 212.80 373.53 89.63 98.49 0.3460 0.284 0.083 1
130 H 2 S 0 4 SULFURICACID 98.079 283.46 610.00 925.00 64.00 177.03 0.5540 0.147 --- 1
131 H 2 S 2 HYDROGEN DISULFIDE 66.148 183.45 337.15 ...... . . . . . . . . . . . .

132 H 2 S e HYDROGENSELENIDE 80.976 209.15 232.05 411.10 90.30 . . . . . . . . . . . . 2,6


133 H2Te HYDROGEN TELLURIDE 129.616 224.15 271.15 ...... . . . . . . . . . . . .

134 H3N03S SULFAMICACID 97.095 478.00 . . . . . . . . . 225.00 0.4315 ...... I


135 He HELIUM-3 3.016 1.01 3.20 3.31 1.17 72.50 0.0416 0.308 -0.472 1
136 He HELIUM-4 4.003 I. 76 4.22 5.20 2.28 57.30 0.0699 0.302 -0.390 1
137 Hf HAFNIUM 178.490 25 06.15 5960. O0 ...... . . . . . . . . . . . . 4,5
138 HB MERCURY 200.590 234.29 629.73 1735.00 1608.0 56.35 3.5597 0.628 -0.164 1
139 HgBr2 MERCURICBROMIDE 360.398 510.15 592.15 ...... . . . . . . . . . . . .

140 HgCt2 MERCURICCHLORIDE 271.495 550.15 577.15 ...... . . . . . . . . . . . .

141HgI2 MERCURICIODIDE 454.399 532.15 627.15 1078.10 100.00 . . . . . . . . . . . . 3,6


142 IF7 IODINE HEPTAFLUORIDE 259.893 278.65 277.15 ...... . . . . . . . . . . . .

143 12 IODINE 253.809 386.75 458.39 819.15 116.54 155.00 1.6375 0.265 0.117 1
144 In INDIUM 114.818 429.75 2323.00 6730.00 2432.0 82.60 1.3900 0.359 --- 4,5,6
145 Iv IRIDIUM 192.220 2719.15 4450.00 ...... . . . . . . . . . . . . 4,5
146 K POTASSIUM 39.098 336.35 1037.00 2223.00 162.12 209.00 0.1871 0.183 -0.183 1
147 KBr POTASSIUM BROMIDE 119.002 1003.15 1656.15 . . . . . . . . . . . . . . . . . . 2
148 KCI POTASSIUM CHLORIDE 74.551 1044.00 1688.87 3470.00 180.00 625.00 0.1193 0.390 -0.121 1
149 KF POTASSIUM FLUORIDE 58.097 1153.15 1775.15 ...... . . . . . . . . . . . .

150 KI POTASSIUM IODIDE 166.003 996.15 1597.15 ...... . . . . . . . . . . . .

151KOH POTASSIUMHYDROXIDE 56.106 679.00 1600.00 ...... . . . . . . . . . . . . I

152 Kr KRYPTON 83.800 115.78 119.80 209.35 55.02 91.20 0.9189 0.288 0.000 1
153 La LANTHANUM 138.906 1193.15 3643.00 9511.00 5460.0 36.50 3.8056 0.252 --- 4,5,6
154 Li LITHIUM 6.941 453.69 1597.00 4085.00 1722.5 47.00 0.1477 0.238 -0.045 1
155 L i B r LITHIUM BROMIDE 86.845 820.15 1583.15 . . . . . . . . . . . . . . . . . .

156 LiCl LITHIUM CHLORIDE 42.394 887.15 1655.15 . . . . . . . . . . . . . . . . . .

157 LiF LITHIUM FLUORIDE 25.939 1143.15 1954.15 . . . . . . . . . . . . . . . . . .

158 L i l LITHIUM IODIDE 133.845 719.15 1444.15 . . . . . . . . . . . . . . . . . .

159 Lu LUTECIUM 174.967 1936.15 2535.00 . . . . . . . . . . . . . . . . . . 4,5


160 Mg MAGNESIUM 24.305 923.15 1376.00 . . . . . . . . . . . . . . . . . . 4,5
161MgCl2 MAGNESIUMCHLORIDE 95.210 985.15 1691.15 . . . . . . . . . . . . . . . . . .

162 MgO MAGNESIUM OXIDE 40.304 3105.00 3873.20 5950.00 33.91 209.50 0.1924 0.014 0.214 1
163 Mn MANGANESE 54.938 1519.15 2392.00 . . . . . . . . . . . . . . . . . . 4,5
164 MnCl2 MANGANESECHLORIDE 125.843 923.15 1463.15 . . . . . . . . . . . . . . . . . .

165 Mo MOLYBDENUM 95.940 2895.15 5081.15 9620.00 --- 3 8 . 3 0 2.5050 ...... 3,6
166 M o F 6 MOLYBDENUMFLUORIDE 209.930 290.15 309.15 . . . . . . . . . . . . . . . . . .

167 M o O 3 MOLYBDENUMOXIDE 143.938 1068.15 1424.15 . . . . . . . . . . . . . . . . . .

168 NCI3 NITROGENTRICHLORIDE 120.365 246.15 344.15 564.00 104.00 . . . . . . . . . . . .

169 ND3 HEAVY AMMONIA 20.055 199.15 239.75 . . . . . . . . . . . . . . . . . .

170 NF3 NITROGEN TRIFLUORIDE 71.002 66.36 144.09 233.85 45.30 1 1 8 . 7 5 0 . 5 9 7 9 0 . 2 7 7 0 . 1 2 6 1


171NH3 AMMONIA 17.031 195.41 239.72 405.65 112.78 72.47 0 . 2 3 5 0 0 . 2 4 2 0 . 2 5 2 1
172 N H 3 0 HYDROXYLAMINE 33.030 306.25 383.00 574.00 137.00 . . . . . . . . . 0.694 1
173 N H 4 B r AMMONIUMBROMIDE 97. 943 --- 669.15 ...... . . . . . . . . . . . .

174 N H 4 C I AMMONIUMCHLORIDE 53.491 793.20 612.00 882.00 16.40 . . . . . . . . . . . .


175 N H 4 I AMMONIUMIODIDE 144.943 --- 678.05 . . . . . . . . . . . . . . . . . .

176 N H 5 0 AMMONIUMHYDROXIDE 35.046 194.15 . . . . . . . . . . . . . . . . . . . . .


177 N H S S AMMONIUMHYDROGENSULFIDE 51.112 --- 306.45 . . . . . . . . . . . . . . . . . .

178 NO NITRIC OXIDE 30.006 112.15 121.38 180.15 64.85 57.70 0 . 5 2 0 0 0 . 2 5 0 0 . 5 8 5 1


179 N O C I N I T R O S Y LCHLORIDE 65.459 213.55 267.77 440.65 91.19 139.30 0.4699 0.347 0.307 1
180 NOF NITROSYL FLUORIDE 49.005 139.15 217.15 . . . . . . . . . . . . . . . . . .

181 NO2 NITROGEN DIOXIDE 46.006 261.95 294.00 431.35 101.33 82.49 0.5577 0.233 0.849 1
182 N2 NITROGEN 28.013 63.15 77.35 126.10 33.94 90.10 0.3109 0.292 0.040 1
183 N 2 F 4 TETRAFLUOROHYDRAZINE 104.007 111.65 198.95 309.35 37.10 213.00 0.4883 0.307 0.223 1
184 N 2 H 4 HYDRAZINE 32.045 274.69 386.65 653.15 146.92 158.00 0.2028 0.427 0.314 1
185 N 2 H 4 C AMMONIUMCYANIDE 44.056 309.15 304.85 . . . . . . . . . . . . . . . . . . 2
186 N2H6C02 AMMONIUMCARBAMATE 78.071 --- 331.45 . . . . . . . . . . . . . . . . . . 2
187 N20 NITROUS OXIDE 44.013 182.33 184.67 309.57 72.45 97.37 0.4520 0.274 0.142 1
188 N 2 0 3 NITROGENTRIOXIDE 76.012 170.00 275.15 425.00 69.90 195.00 0.3898 0.386 0.431 I
189 N 2 0 4 NITROGENTETRAOXIDE 92.011 261.90 302.22 431.15 101.33 82.49 1.1154 0.233 1.007 I
190 N 2 0 5 NITROGENPENTOXIDE 108.010 . . . . . . . . . . . . . . . . . . . . . . . . I
191Na SODIUM 22.990 370.98 1156.00 2573.00 354.64 116.00 0.1982 0.192 -0.102 I
192 NaBr SODIUM BROMIDE 102.894 1020.00 1663.82 4287.00 192.52 398.00 0.2585 0.215 -0.800 I
193 NaCN SODIUM CYANIDE 49.008 836.85 1769.15 2900.00 . . . . . . . . . . . . . . . I
194 NaCI SODIUM CHLORIDE 58.442 1073.95 1738.15 3400.00 355.00 266.00 0.2197 0.334 0.134 I
195 NaF SODIUM FLUORIDE 41.988 1269.00 1982.72 5530.00 531.96 185.00 0.2270 0.214 -1.115 1
196 Nal SODIUM IODIDE 149.894 924.15 1577.15 . . . . . . . . . . . . . . . . . . 2

* A computer program, c o n t a i n i n g data f o r a l l compounds, i s a v a i l a b l e f o r a nominal fee (Carl L. Yaws, Box 10053, Larnar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be accessed by o t h e r s o f t w a r e .

360
MW TF Ts Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc co SOURCE

197 NaOH SODIUM HYDROXIDE 39.997 596.00 1663.15 2820.00 253.31 200.00 0.2000 0.216 --- I
198 N a 2 S 0 4 SODIUMSULFATE 142.043 1157.00 . . . . . . . . . . . . . . . . . . . . . I

199 Nb NIOBIUM 92.906 2750.15 5115.00 ...... . . . . . . . . . . . . 4,5


200 Nd NEODYMIUM 144.240 1289.15 3384.00 ...... . . . . . . . . . . . . 4,5
201Ne NEON 20.180 24.55 27.09 44.40 26.53 41.70 0.4839 0.300 -0.041 1
202 Ni NICKEL 58.693 1728.15 2415.00 ...... . . . . . . . . . . . . 4,5
203 NiC404 N I C K E LCARBONYL 170.735 248.15 315.65 ...... . . . . . . . . . . . .

204 NiF2 NICKEL FLUORIDE 96.690 . . . . . . . . . . . . . . . . . . . . . . . .

205 Np NEPTUNIUM 237.000 913.15 . . . . . . . . . . . . . . . . . . . . . 2,10


206 02 OXYGEN 31.999 54.36 90.17 154.58 50.43 73.40 0.4360 0.288 0.022 I
207 03 OZONE 47.998 80.15 161.85 261.00 55.73 89.00 0.5393 0.229 0.227 I
208 Os OSMIUM 190.230 3306.15 4880.00 . . . . . . . . . . . . . . . . . . 4,5
209 OsOF5 OSMIUM OXIDE PENTAFLUORIDE 301.221 . . . . . . . . . . . . . . . . . . . . . . . .

210 Os04 OSMIUM TETROXIDE - YELLOW 254.228 329.15 403.15 ...... . . . . . . . . . . . .

2110s04 OSMIUM TETROXIDE - WHITE 254.228 315.15 403.15 ...... . . . . . . . . . . . .

212 P PHOSPHORUS - WHITE 30.974 870.00 553.45 993.75 83.29 . . . . . . . . . . . . I

213 PBr3 PHOSPHORUS TRIBROMIDE 270.686 233.15 448.45 . . . . . . . . . . . . . . . . . .

214 P C L 2 F 3 PHOSPHORUSDICHLORIDE TRIFLUORIDE 158.874 . . . . . . . . . . . . . . . . . . . - . . . . 2

215 PCt3 PHOSPHORUS TRICHLORIDE 137.332 181.15 349.25 563.15 56.70 260.00 0.5282 0.315 0.234 1
216 PC[5 PHOSPHORUS PENTACHLORIDE 208.237 433.15 433.00 646.15 . . . . . . . . . . . . . . . 1
217 PH3 PHOSPHINE 33.998 139.37 185.41 324.75 65.36 113.32 0.3000 0.274 0.036 1
218 P H 4 B r PHOSPHONIUMBROMIDE 114.910 --- 311.45 . . . . . . . . . . . . . . . . . . 2
219 P H 4 C L PHOSPHONIUMCHLORIDE 70.458 244.65 246.15 . . . . . . . . . . . . . . . . . . 2
220 P H 4 I PHOSPHONIUM IODIDE 161.910 291.65 335.45 . . . . . . . . . . . . . . . . . . 2,10
221POCt3 PHOSPHORUSOXYCHLORIDE 153.331 274.33 378.65 602.15 . . . . . . . . . . . . . . . 1
222 PSBr3 PHOSPHORUSTHIOBROMIDE 302.752 311.15 448.15 . . . . . . . . . . . . . . . . . . 2
223 P S C L 3 PHOSPHORUSTHIOCHLORIDE 169.398 236.95 398.15 . . . . . . . . . . . . . . . . . . 1
224 P406 PHOSPHORUS TRIOXIDE 219.891 295.65 446.25 . . . . . . . . . . . . . . . . . . 2
225 P4010 PHOSPHORUSPENTOXIDE 283.889 693.15 . . . . . . . . . . . . . . . . . . . . . I
226 P 4 S I O PHOSPHORUSPENTASULFIDE 444.555 561.15 787.15 1291.00 232.00 . . . . . . . . . 0.594 I
227 Pb LEAD 207.200 600.61 2024.00 5400.00 861.30 93.20 2.2232 0.179 --- 4,5,6
228 PbBr2 LEAD BROMIDE 367.008 646.15 1187.15 . . . . . . . . . . . . . . . . . . 3
229 PbCt2 LEAD CHLORIDE 278.105 774.15 1227.15 . . . . . . . . . . . . . . . . . . 2
230 PbF2 LEAD FLUORIDE 245.197 1128.15 1566.15 . . . . . . . . . . . . . . . . . . 3
231PbI2 LEAD IODIDE 461.009 675.15 1145.15 . . . . . . . . . . . . . . . . . . 3
232 PbO LEAD OXIDE 223.199 1163.15 1745.15 . . . . . . . . . . . . . . . . . . 3
233 PbS LEAD SULFIDE 239.266 1387.15 1554.15 . . . . . . . . . . . . . . . . . . 3
234 Pd PALLADIUM 106.420 1828.05 3385.00 . . . . . . . . . . . . . . . . . . 4,5
235 Po POLONIUM 209.000 527.15 1235.00 . . . . . . . . . . . . . . . . . . 4,5
236 Pt PLATINUM 195.080 2041.55 3980.00 6983.00 --- 759.10 0.2570 ...... 4,5,6
237 Ra RADIUM 226.000 973.15 1809.00 . . . . . . . . . . . . . . . . . . 4,5
238 Rb RUBIDIUM 85.468 312.46 978.00 2111.10 134.00 247.00 0.3460 0.189 --- 4,5,6
239 RbBr R U B I D I U MBROMIDE 165.372 955.15 1625.15 . . . . . . . . . . . . . . . . . . 2
240 R b C L R U B I D I U MCHLORIDE 120.921 988.15 1654.15 . . . . . . . . . . . . . . . . . . 2
241RbF RUBIDIUM FLUORIDE 104.466 1033.15 1681.15 . . . . . . . . . . . . . . . . . . 2
242 RbI RUBIDIUM IODIDE 212.372 915.15 1577.15 . . . . . . . . . . . . . . . . . . 2
243 Re RHENIUM 186.207 3459.15 5915.00 ...... 32.10 5.8008 ...... 4,5,6
244 Re207 RHENIUM HEPTOXIDE 484.410 569.15 635.55 . . . . . . . . . . . . . . . . . . 3
245 Rh RHODIUM 102.906 2237.15 3940.00 . . . . . . . . . . . . . . . . . . 4,5
246 Rn RADON 222.000 202.15 211.35 377.40 63.00 140.00 1.5857 0.281 --- 2,6
247 Ru RUTHENIUM 101.070 2607.15 4500.00 . . . . . . . . . . . . . . . . . . 4,5
248 R u F 5 RUTHENIUM PENTAFLUORIDE 196.062 . . . . . . . . . . . . . . . . . . . . . . . . 2
249 S SULFUR 32.066 388.36 717.82 1313.00 182.08 158.00 0.2029 0.264 0.262 1
250 SF4 SULFUR TETRAFLUORIDE 108.060 149.15 233.15 . . . . . . . . . . . . . . . . . . 2,10
251 SF6 SULFUR HEXAFLUORIDE 146.056 222.45 209.25 318.69 37.60 198.52 0.7357 0.282 0.215 1
252 S O B r 2 T H I O N Y LBROMIDE 207.873 220.95 412.65 . . . . . . . . . . . . . . . . . . 2
253 S O C t 2 T H I O N Y LCHLORIDE 118.971 172.00 348.75 567.00 --- 203.00 0.5861 ...... 1
254 S O F 2 SULFUROUS OXYFLUORIDE 86.062 --- 228.90 . . . . . . . . . . . . . . . . . . 2
255 S02 SULFUR DIOXIDE 64.065 200.00 263.13 430.75 78.84 122.00 0.5251 0.269 0.245 I
256 S02Ct2 SULFURYLCHLORIDE 134.970 222.00 342.55 545.00 46.10 224.00 0.6025 0.228 0.176 I
257 S03 SULFUR TRIOXIDE 80.064 289.95 317.90 490.85 82.07 127.08 0.6300 0.256 0.422 1
258 $2C[2 SULFUR MONOCHLORIDE 135.037 193.15 411.15 . . . . . . . . . . . . . . . . . . 2
259 Sb ANTIMONY 121.757 903.78 1898.00 5070.00 . . . . . . . . . . . . . . . 4,5,6
260 SbBr3 ANTIMONYTRIBROMIDE 361.469 369.75 548.15 . . . . . . . . . . . . . . . . . . 3
261 SbCt3 ANTIMONYTRICHLORIDE 228.115 346.55 493.40 794.00 48.20 270.00 0.8449 0.197 0.171 1
262 SbCt5 ANTIMONYPENTACHLORIDE 299.021 275.95 413.15 . . . . . . . . . . . . . . . . . . 2,11
263 SbH3 STIBINE 124.781 185.15 255.15 440.35 73.06 157.2 0.7938 0.314 --- 7
264 SbI3 ANTIMONYTRIIODIDE 502.470 440.15 674.15 . . . . . . . . . . . . . . . . . . 3
265 Sb203 ANTIMONYTRIOXIDE 291.512 929.15 1698.15 . . . . . . . . . . . . . . . . . . 3

* A computer program, c o n t a i n i n g data f o r a l l compounds, is a v a i t a b t e f o r a nominat fee (Carl L. Yaws, Box 10053, Lamar U n i v e r s i t y
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s in ASCII which can be accessed by o t h e r s o f t w a r e .

361
MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm31mo t glcm 3 Zc SOURCE

266 Sc SCANDIUM 44.956 1814.15 2700.00 . . . . . . . . . . . . . . . --- 4,5


267 Se SELENIUM 78.960 494.15 930.00 1766.00 380.00 62.30 1.2674 0.161 --- 4,5,6
268 SeCt4 SELENIUM TETRACHLORIDE 220.771 --- 464.65 . . . . . . . . . . . . . . . --- 2
269 SeF6 SELENIUM HEXAFLUORIDE 192.950 238.45 227.35 . . . . . . . . . . . . . . . --- 2

270 SeOCt2 SELENIUM OXYCHLORIDE 165.865 281.65 441.15 . . . . . . . . . . . . . . . --- 2


271Se02 SELENIUM DIOXIDE 110.959 613.15 590.15 . . . . . . . . . . . . . . . --- 2

272 Si SILICON 28.086 1685.00 3513.80 5159.00 537.00 233.00 0.1205 0.292 --- I
273 SiBrCL2F BROMODICHLOROFLUOROSILANE 197.893 160.85 308.55 . . . . . . . . . . . . . . . --- 3

274 SiBrF3 TRIFLUOROBROMOSILANE 164.985 202.65 231.45 . . . . . . . . . . . . . . . --- 2


275 SiBr2CtF DIBROMOCHLOROFLUOROSILANE 242.345 173.85 332.65 . . . . . . . . . . . . . . . --- 2
276 SiCLF3 TRIFLUOROCHLOROSILANE 120.533 131.15 203.15 . . . . . . . . . . . . . . . --- 2
277 SiC[2F2 DICHLORODIFLUOROSILANE 136.988 133.45 241.35 . . . . . . . . . . . . . . . --- 2

278 SiC[3F TRICHLOROFLUOROSILANE 153.442 152.35 285.35 . . . . . . . . . . . . . . . --- 2

279 SiCt4 SILICON TETRACHLORIDE 169.896 204.30 330.00 507.00 35.93 326.00 0.5212 0.278 0.232 1
280 SiF4 SILICON TETRAFLUORIDE 104.079 186.35 178.35 259.00 37.19 165.00 0.6308 0.285 0.385 1
281SiHBr3 TRIBROMOSILANE 268.805 199.65 384.95 . . . . . . . . . . . . . . . "'" 2

282 SiHCt3 TRICHLOROSILANE 135.452 144.95 305.00 479.00 41.70 268.00 0.5054 0.281 O. 203 1
283 SiHF3 TRIFLUOROSILANE 86.089 141.75 178.15 . . . . . . . . . . . . . . . "'" 2

284 SiH2Br2 DIBROMOSILANE 189.909 202.95 343.65 . . . . . . . . . . . . . . . "'" 2


285 SiH2C[2 DICHLOROSILANE 101.007 151.15 281.45 449.00 44.30 228.00 0.4430 0.271 0.177 1
286 SiH2F2 DIFLUOROSILANE 68.098 --- 195.35 . . . . . . . . . . . . . . . "'" 2
287 SiH212 DIIODOSILANE 283.910 272.15 422.65 . . . . . . . . . . . . . . . --.. 2
288 SiH3Br MONOBROMOSILANE 111.013 179.25 275.55 ...... . . . . . . . . . . . .

289 SiH3C[ MONOCHLOROSILANE 66.562 155.05 242.75 396.65 48.43 174.00 0.3822 0.256 0.136 3,9
290 SiH3F MONOFLUOROSILANE 50.108 --- 175.15 ...... . . . . . . . . . "'" 2
291SiH3I IODOSILANE 158.014 216.15 318.55 ...... . . . . . . . . . . . .

292 SiH4 SILANE 32.117 88.15 161.00 269.70 48.43 132.70 0.2420 0.287 0.097 1
293 Si02 SILICON DIOXIDE 60.084 1883.00 2503.20 ...... . . . . . . . . . . . . I

294 Si2C[6 HEXACHLORODISILANE 268.687 271.95 412.15 ...... . . . . . . . . . . . .

295 Si2F6 HEXAFLUORODISILANE 170.161 254.55 254.25 ...... . . . . . . . . . . . .

296 Si2H5CL DISILANYL CHLORIDE 96.663 --- 314.70 ...... . . . . . . . . . . . .

297 Si2H6 DISILANE 62.219 140.65 259.00 432.00 51.30 198.00 0.3142 0.283 0.102 I
298 Si20Ct3F3 TRICHLOROTRIFLUORODISILOXANE 235.524 --- 315.89 . . . . . . . . . . . . . . . "'" 2
299 Si20Ct6 HEXACHLORODISILOXANE 284. 887 239.95 408.75 . . . . . . . . . . . . . . . --- 2

300 Si20H6 DISILOXANE 78.218 128.95 257.75 . . . . . . . . . . . . . . . --- 2


301 Si3C[8 OCTACHLOROTRISILANE 367.878 --- 484.55 . . . . . . . . . . . . . . . --- 2
302 Si3H8 TRISILANE 92.320 155.95 326.25 . . . . . . . . . . . . . . . --- 2
303 Si3H9N TRISILAZANE 107.335 167.45 321.85 . . . . . . . . . . . . . . . ...
2
304 Si4HlO TETRASILANE 122.421 179.55 373.15 . . . . . . . . . . . . . . . ...
2
305 Sm SAMARIUM 150.360 1345.15 1874.00 . . . . . . . . . . . . . . . ...
4,5
306 Sn TIN 118.710 505.08 2995.00 7400.00 --- 115.10 1.0314 --- ...
4,5,6
307 SnBr4 STANNICBROMIDE 438.326 304.15 477.85 . . . . . . . . . . . . . . . ...
2
308 SnC[2 STANNOUSCHLORIDE 189.615 519.95 896.15 . . . . . . . . . . . . . . . ...
3
309 SnCt4 STANNICCHLORIDE 260.521 242.95 386.15 . . . . . . . . . . . . . . . ...
2
310 SnH4 STANNIC HYDRIDE 122.742 123.25 220.85 . . . . . . . . . . . . . . . ...
2
311SnI4 STANNIC IODIDE 626.328 417.65 621.15 . . . . . . . . . . . . . . . ...
2
312 Sr STRONTIUM 87.620 1050.15 1630.00 . . . . . . . . . . . . . . . --- 4,5
313 SrO STRONTIUM OXIDE 103.619 2703.15 . . . . . . . . . . . . . . . . . . "'" 2
314 Ta TANTALUM 180.948 3290.15 5565.00 . . . . . . . . . . . . . . . --- 4,5
315 Tc TECNNETIUM 98.000 2430.15 5000.00 . . . . . . . . . . . . . . . --- 4,5
316 Te TELLURIUM 127.600 722.66 1285.00 4840.00 . . . . . . . . . . . . --- 4,5,6
317 TeC[4 TELLURIUMTETRACHLORIDE 269.411 497.15 665.15 . . . . . . . . . . . . . . . ''" 2
318 TeF6 TELLURIUMHEXAFLUORIDE 241.590 235.35 234.55 . . . . . . . . . . . . . . . --- 2
319 Ti TITANIUM 47.880 1941.15 3442.00 6400.00 --- . . . . . . . . . . . . 4,5,6
320 T i e r 4 T I T A N I U MTETRACHLORIDE 189.691 249.05 409.00 638.00 46.61 340.00 0.5579 0.299 0.284 1
321 T[ THALLIUM 204.383 577.15 1745.00 ...... . . . . . . . . . . . . 4,5
322 TtBr THALLOUSBROMIDE 284.287 733.15 1092.15 ...... . . . . . . . . . . . .

323 TLI THALLOUS IODIDE 331.288 713.15 1096.15 ...... . . . . . . . . . . . .

324 Tm THULIUM 168.934 1818.15 2219.15 ...... . . . . . . . . . . . . 4,5


325 U URANIUM 238.029 1408.15 4135.00 ...... . . . . . . . . . . . . 4,5
326 UF6 URANIUM FLUORIDE 352.019 342.35 328.85 ...... . . . . . . . . . . . .

327 V VANADIUM 50.942 2183.15 3665.00 ...... . . . . . . . . . . . . 4,5


328 VC[4 VANADIUM TETRACHLORIDE 192.752 247.45 425.00 697.00 60.30 268.00 0.7192 0.279 0.186 I
329 VOCt3 VANADIUM OXYTRICHLORIDE 173.299 193.65 400.00 636.00 --- 290.00 0.5976 ...... I
330 W TUNGSTEN 183.840 3695.15 5645.00 14756.0 --- 33.90 5.4230 ...... 4,5,6
331WF6 TUNGSTEN FLUORIDE 297.830 272.65 290.45 . . . . . . . . . . . . . . . . . . 2
332 Xe XENON 131.290 161.36 165.03 289.74 58.40 118.00 1.1126 0.286 0.000 1
333 Yb YTTERBIUM 173.040 1097.15 1660.00 . . . . . . . . . . . . . . . . . . 4,5
334 Yt YTTRIUM 88.906 1799.15 3055.00 . . . . . . . . . . . . . . . . . . 4,5

* A computer program, c o n t a i n i n g data f o r a t l confounds, i s a v a i t a b t e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s in ASCII which can be accessed by o t h e r software.

362
MW TF Te Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm3 Zc ~ SOURCE

335 Zn ZINC 65.390 692.70 1181.15 3170.00 2904.0 33.00 1.9815 0.364 0.078 1
336 ZnCt2 ZINC CHLORIDE 136.295 638.15 1005.15 ...... . . . . . . . . . . . .

337 ZnF2 ZINC FLUORIDE 103.387 1145.15 1770.15 ...... . . . . . . . . . . . .

338 ZnO ZINC OXIDE 81.389 2248.20 . . . . . . . . . . . . . . . . . . . . . I

339 ZnS04 ZINC SULFATE 161.454 953.00 . . . . . . . . . . . . . . . . . . . . . I

340 Zr ZIRCONIUM 91.224 2128.15 4598.00 8802.00 --- . . . . . . . . . . . . 4,5,6


341ZrBr4 ZIRCONIUM BROMIDE 410.840 723.15 630.15 ...... . . . . . . . . . . . .

342 ZrCt4 ZIRCONIUM CHLORIDE 233.035 710.15 604.15 ...... . . . . . . . . . . . .

343 ZrI4 ZIRCONIUM IODIDE 598.842 772.15 704.15 ...... . . . . . . . . . . . .

* A con~uter program, containing data f o r a l l compounds, is a v a i l a b l e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The con~uter program is in ASCII which can be accessed by other software.

NOTE:

1. Sources f o r the property data are:

1. Daubert, T. E. and R. P. Danner, RATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2, 3 and 4, Supplements
1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).
2. Ohe, S., COMPUTERAIDED DATA BOOK OF VAPOR PRESSURE, Data Book Publishing CcHnpany, Tokyo, Japan (1976).
3 . PERRY'S CHEMICAL ENGINEER!NG HANDBOOK, 6th ed., McGraw-Hilt, New York, NY (1984).
4. Nesmeyanov, A. N., VAPOR PRESSURE OF THE CHEMICAL ELEMENTS, E l s e v i e r , New York, NY (1963).
5. CRC HANDBOOKOF CHEMISTRY AND PHYSICS, 66th - 75th eds., CRC Press, I n c . , Boca Raton, FL (1985-1994).
6. Simmrock, K. H., R. Janowsky and A, Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES, Vot. I I , Parts 1 and 2, Dechema
Chemistry Data Series, 6000 Frankfurt~Main, Germany (1986).
7. Yaws, C. L. and others, Solid State Technology, 17', No. 1, 47 (1974).
8. Yaws, C. L. and others, Sotid State Technology, 18, No. 1, 35 (1975).
9. Yaws, C. L. and others, Solid State Technology, 16, No. 1, 39 (1973).
10. CONDENSED CHEMICAL DICTIONARY, lOth (G. G. Hawley) and 11th eds. (N. I . Sax and R. J. Lewis, J r . ) , Van Nostrand
Reinhold Co., New York, NY (1981,1987).
11. LANGE'S HANDBOOK OF CHEMISTRY, 13th and 14th eds., McGraw-Hitt, New York, NY (1985, 1992).

2. Very l i m i t e d experimental data f o r c r i t i c a l constants and acentric f a c t o r are a v a i l a b l e f o r inorganic con~ounds and elements
which are sotids at room temperature. Thus, the estimates f o r these substances should be considered rough approximations in the
absence of experimental data.

363
This Page Intentionally Left Blank

You might also like