(Carl L. Yaws) Handbook of Vapor Pressure Volume (BookFi)
(Carl L. Yaws) Handbook of Vapor Pressure Volume (BookFi)
(Carl L. Yaws) Handbook of Vapor Pressure Volume (BookFi)
VOLUME 4
INORGANIC COMPOUNDS
AND ELEMENTS
LIBRARY OF PHYSICO-CHEMICAL PROPERTY DATA
Handbook of Viscosity
Volume 1:C1 to C4 Compounds (Product #5362)
Volume 2:C5 to C7 Compounds (product #5364)
Volume 3:C8 to C28 Compounds (Product #5368)
Carl L. Yaws
Each of the above series contains data for more than 1,000 organic compounds, including
hydrocarbons, oxygenates, halogenates, nitrogenates, sulfur compounds, and silicon compounds.
The data are presented in graphs for vapor pressure, viscosity, or thermal conductivity as a func-
tion of temperature and are arranged by carbon number and chemical formula to enable the engi-
neer to quickly determine values at the desired temperatures.
4
VOLUME
INORGANICCOMPOUNDS
AND ELEMENTS
Carl L, Yaws
Gulf Publishing Company
Houston, London, Paris, Zurich, Tokyo
Handbook of Vapor Pressure, Volume 4
I S B N 0-88415-394-0
10 9 8 7 6 5 4 3 2 1
iv
PREFACE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . vii
REFERENCES . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 344
APPENDIX A: COMPOUND LIST BY FORMULA . . . . . . . . . . . . .346
APPENDIX B: COMPOUND LIST BY NAME . . . . . . . . . . . . . . . . .349
ACKNOWLEDGMENTS
Many colleagues and students have made contributions and helpful comments over the years.
The author is grateful to each: Jack R. Hopper, Joe W. Miller, Jr., C.S. Fang, K.Y. Li, Keith C.
Hansen, Daniel H. Chen, P.Y. Chiang, H.C. Yang, Xiang Pan, Xiaoyan Lin, Li Bu, and Sachin
Nijhawan.
The author wishes to extend special appreciation to his wife (Annette) and family (Kent,
Michele, Chelsea, and Brandon; Lindsay and Rebecca; and Matthew and Sarah).
The author wishes to acknowledge that the Gulf Coast Hazardous Substance Research Center
provided partial support to this work.
DISCLAIMER
This handbook presents a variety of thermodynamic and
physical property data. It is incumbent upon the user to exercise judg-
ment in the use of the data. The author and publisher do not provide
any guarantee, express or implied, with regard to the general or spe-
cific applicability of the data, the range of errors that may be associat-
ed with any of the data, or the appropriateness of using any of the data
in any subsequent calculation, design, or decision process. The author
and publisher accept no responsibility for damages, if any, suffered by
any reader or user of this handbook as a result of decisions made or
actions taken on information contained herein.
vi
PREFACE
Vapor Pressure data are important in many engineering applications in the chemical process-
ing and petroleum refining industries. The objective of this book is to provide the engineer with
such vapor pressure data. The data are presented in graphs covering a wide temperature range to
enable the engineer to quickly determine values at the temperatures of interest.
The contents of the book are arranged in the following order:
1 Graphs
1 References
1 List of compounds
1 Coefficients for vapor pressure equation
1 Critical properties and acentric factor
The graphs for vapor pressure as a function of temperature are arranged by chemical formula
to provide ease of use. Many of the graphs cover the full liquid range from melting point to boil-
ing point to critical point. English units are used, but for those involved in metric and SI usage,
each graph displays a conversion factor to provide SI units.
The coverage of inorganics is comprehensive and encompasses 343 compounds, including
carbon oxides such as carbon monoxide and carbon dioxide; nitrogen oxides such as nitric oxide
and nitrous oxide; sulfur oxides such as sulfur dioxide and sulfur trioxide; hydrogen oxides such
as water and hydrogen peroxide; ammonias such as ammonia and ammonium hydroxide; hydro-
gen halides such as hydrogen chloride and hydrogen fluoride; sulfur acids such as sulfuric acid
and hydrogen sulfide; hydroxides such as sodium hydroxide and potassium hydroxide; silicon
halides such as trichlorosilane and silicon tetrachloride; ureas such as urea and thiourea;
cyanides such as hydrogen cyanide and cyanogen chloride; hydrides such as silane and diborane;
sodium derivatives such as sodium chloride and sodium fluoride; aluminum derivatives such as
aluminum borohydride and aluminum fluoride; and many other compound types. A total of 82
elements are covered, including hydrogen, nitrogen, oxygen, helium, argon, neon, chlorine,
bromine, iodine, fluorine, sulfur, phosphorous, aluminum, lead, tin, mercury, sodium, magne-
sium, silicon, antimony, boron, iron, chromium, cobalt, titanium, tantalum, silver, gold, plat-
inum, radon, uranium, and many others.
The literature has been carefully searched. The following primary references were used exten-
sively in construction of the graphs:
vii
Additional references are given in the section near the end of this book. These primary and
additional references provide full documentation for the original sources used in regression of
the data.
A list of compounds is given near the end of the book to aid the user in quickly locating the
compound of interest from the chemical formula or name.
Coefficients for the vapor pressure equation are provided near the end of the book. Critical
properties and acentric factor are given in the last section of the book. The tabulated values are
especially arranged for quick usage with hand calculator or computer. Computer programs, con-
taining data for all compounds, are available for a nominal fee. The programs are in ASCII which
can be accessed by other software. Contact Carl L. Yaws, P.O. Box 10053, Lamar University,
Beaumont, TX 77710, phone/FAX 409-880-8787.
viii
HANDBOOK OF
VOLUME 4
INORGANIC COMPOUNDS
AND ELEMENTS
This Page Intentionally Left Blank
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Temperature, F
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Temperature, F
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Temperature, F
10
100::::::::::::::::::::::::::::::::::::::::: i --i !
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1 psia = 6.895 kPa
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1 O5O 11 O0 1150 1200 1250 1300 1350 1400 1450
Temperature, F
11
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Temperature, F
13
1O0
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Temperature, F
14
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i i i 1 psia = 51.71 mm Hg
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Temperature, F
15
100
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Temperature, F
16
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1 psia = 51.71 mm Hg
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0.1.L I I I
-200 -150 -1 O0 -50 0 5O 1 O0 150 200 250
Temperature, F
18
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Temperature, F
19
1004 , . ,. .: . ,. ~. ~ .
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/ J ! ! ! i / i i i !
o .,.,,,
"~ . . . . . . . . . t ................................ t ................................... t ..................................... t ..................................... ! ....... ~ ...... ".T ........................................
13. J ~ i i t-i, i i i i
:3
O3
o3 :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
1
::::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
1 1
12122211121212121222112111112112211122222
9 /I i i t ~ i i i
! / i i i ~ ! i i !
, ! ! i i
i i i ~ i i
I i i : i
i
0.01 I I I I
400 450 500 550 600 650 700 750 800 850 900
Temperature, F
20
00 ~ : ! :::::::::::- :::::: : : ....... : ...............................................; . . . . . . . . . . . . . . . .
............:r::----;...........-::.-.-:
.......--+ ................... ~ ....................................
:::::::::::::::::::::
1 I I HI .......................................
iiiiii i_ ! ..................
S ~ ................. _.'.
.................
==========================================
...................
;-- ..,./,i i,~ ....i i . . . . . . . . . . . . .
' i + i t
:.- : t
c~
c~ 0.01= I i ! !
- i i - - - -
t f
G) _
... ._.
i i
l
0.001 = ' ~ . . . . . . . . . . . . . . . . . . . .
G) ~, !_,
-----------~
_-
_ I - - T 9 ! }
{-- ................................. ? ............................................. .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0
c~ o.oom - i i + i
c~
> t .............................
...........................
~ .......................................
9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
4 ..................
4 .............
F-- . . . . . . 4.
i i
.
. .}
.............................. j +
! i
!
+ i
1 E-06
! t ........ :+.........................................................
i
i t +
T i
i i 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
..., ; + +
:9 ! . {
! | - .:
+ ,;., ,.,
E i i
i t ;
1 E-08 I I I I I
100 200 300 400 500 600 700
Temperature, F
21
0 0 ~ :_ ::___:___ ::: .... : : : : : : : : :::~ : . : : : : ::: :: .......... : :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: . . . . . . . . . . . . . . . . . . . . . = = = = = = = = = = = = = = = = = = = = = = = = = = = = ............................... ,~
0 ~ .,,
I I*,. .i ......... I .....................................
1 i ~- ................................
; ......... .. :.:. F : " T " ~ ' i ' :~:::-,~::-~:t?:::"::-:-~_'~ . . . . . . . . . . . . j
i " l .............. - --:-..: --.~: :~:::::::::::::::::..-.... ::::::::::::::::::::::::____._ _-=~.,~176176
;::::::,,: [ . . . . ==============================================================
[ .,I i
0,1~ :~.
: . . . . . . . . . .
.,=,.=
Q. 0,01
(D . . . . . . . . . . . . . . . . ~, . . . . . . . : 9. . . . . . . . . . . . . . . . . . . . . . . ...... _ • . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~....~ . . . . . . . . . . . . . . . . . . . . . . . . 9
; .............
.... ..
. /
! .... :
~- . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
_- ........ 1 ......... , .. ~ .............................. J
O
-- " ". . . . " / ~ ~ . . . . . . . . . . . . . . . . . . -- ............... I. . . . . . . . . . . . . . . . . . . . . . 3
l .
, ........
LI._:_:,_: . . . . . w'--'------~ ~ - - - - - ; . . . . - ' ~ ~ ~ : , ~ ' Z ~ -_': .......................... ~- .....................................
!!!! !!:?
:::::i
1:
IE 07--....... I
- "~ :'::' ~::: L : i
f:: :: _~ ::: : ................. :. . . . . . . . . . . . . . . . . . . . . . . . . . . ~-~-=-= 1 psia = 51.71 mm Hg
-- ! z
! !
. . ..................................
1E-08 I
1500
1
2000 2500
L 3000 3500 4000
I
22
100-, ++,,,,+++,++++~++++,++++,,+~,+,+,~,+++~. . . . .
........
=============================================================================================: :
9 .................. ,
+: _: :::::::::::::::::::::::::::::::
........ 9 . . . . . . . . . . . . . . . . . . . . . . . . . .. -.-.' -.- . . . _ _ ' " ~ . . "
:::::: L ~ ::::::::::::::::::::::::::::::::::::::: ...... .:LL:
,
"
.7. . . . . . . . . . . . . . . . . . . . . . . . . .]. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . [. . .
B BORON I~iiiii+i+iiiiiiiiii+i+~+_.'~__--~.__. _I~T_~--_----~2;::ZTY_-Z--]
, ............................................. , .............................................. ; . . . . . . . . . . . . . . . . . +~ .!
1 o J .........................
I_.= .... _.......+ _ [ . - - = ~ i = ~ . . . . . . _ i _ ................ t...................... ~ .......................
= ~ ~ . - . . . . . . . . . . . . .
-,..-=-=-====+,+++~+-.--=-++,+--=
++~. . . . . . . . . . . . . . . . . . . . . . [ ......................................................
~I .......... T-_..=====.F=:=====..-.-_~+--_-_+:.-=_=-+
-+ : +--. . . . . . . . . . . . . . . . . . . . . .
+'
~l++i~i++ +++!+++++++++++++++~+:!!!!!!!!:!!!!!!!!!!!!!!+~+~' _ _ + ..~ +
~
O. O. 01 =. _ _ ~ +i +- - -
:;~--:-~• I+ i ~ : ~ - i - - N ~ N i - i i ~ ; - 2 . : - ~,-.:.~.2.~..- .g.i -.~...i.................................................................
......................
t ......................... ~....................................
(1) - --+--------.i. i-!"..........
.............. .+ ,.~
9 1........................ 4..............................
. . . . . . . . . ,r.. . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . -,
s,.__ ~t. ______+~t.. l t + +
t'3 - + {" i".................................. ~.............................................................
]7---_ ................... +...... ! i I i. i. +
I---7--I ! i i
,..__
o 0.0001
7'IITI i
+.___ +--
> -
+ 7 - .............................................. + ...........
L~
~--'T"~--um~
i
.,.-7 ~ . . . .
i : - - - -
~
it
i
,'! i! i i!
1E-05~ !
__--~--+-=---~
.+.
9
...... ,+.............. 4
++
.+
*
+
1
i! i: i i! i! I
1 E-06
I + .t
, +..
, .+ r L... ; i +
f iiiiiiiiiiiii
............+
+.
+'
..............................................
'"--
.+". . . .
------'-:!
z' .....................
t:ii+-' +
t:::: I 1 psia
~"I
1 psia = 6.895
= 51.71
kPa
mm Hg
1 E-08/ + i +
,, ,i ,, ,, I
I I
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000
T e m p e r a t u r e , F
23
1 O0
fl
.
,.=
J
10- m
................................ ............................................................
>
1-
............................... t .............................................................
t 11 psia
................................ psia == 51.71
61.895mm
kPaHg ................................
I
0.1- T [
20 40 60 80 1 O0 120 140 160 180 200
Temperature, F
24
1000 .................................
~ii~_~:i:::~;~i~i~iiiiii~iiii::::~.::::::::::~~E~. .......................................................... :,[................................................ ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . :~ZE'TT...'~:Z:T"..C..'.:---_'Z.:E-Z.Z.-..
I ................................ '.. . . . . .~
zl ...................................
i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...................................................................................
~. . . . . . . . . . . . . . . . . . . . . . . . . " ............................................. .i:'..................................
4
3,....................................
! BCI3 B O R O N TRICHLORIDE ---§ .............................. ,'...................................- : : ~ J : ~ ' ............ ]1
t' r t
i
!
| !
l i
to
= ,,.=B
c~
I,,..
0r)
(D
13_
O
C~
t0
>
0.1
0.01
i
0.001 I
-200 -100 100 200 300 400
Temperature, F
25
1000 ] .....................................
1 !
! i ....................................... j
!
. . . . . .
1 O0
,m
Z.
(D
or)
(1)
13_
0
c')
>
10
/
...................................... i ................................................................... i
l
1
-200 - 150 - 1 O0 -50 50
Temperature, F
26
100j ........................................ _~
I ! i ...................................
[ .............................
i'
T
3111111111:ii:11111:iiiiiiii
: iI
BORINE CARBONYL i i
................................. .................................... "i.'
!
| !
9 |
i9 !
/
I
il i
i
illml
........................................
9 "I ..................................... I,
Q.
d
i i i
(B
4".................................. 9............................................... q
I
I 9 =
I
! i, t ..........................
|
t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4'
:
!.__ ! i
Ji
I .
0 !
ii i.
c~ . ............................................
.
,b................................................... 4
> i~ ~r....
/7............................. ~ 1 i
r "~" i i! i
i i
' t'
i i
i i
,i / i, i, iI ii
/ ! t ! i
i I i i ;
,I I
i,......................................i,.........................................................................
.
,
1 psia = 6.895 kPa
'.
,} . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
i .......................................
i
+ .............................................
i
~ ..........................................
i ! i i 1 psia = 51.71 mm Hg
i ! '
, i ......................................... 4............................................. .~.........................................
' i i i
i i I ~ i
I 'i i i'
0.01
i i ! ! i
I I I I
-220 -200 -180 -160 -140 -120 -1 O 0 -80
Temperature, F
27
8E
.:1 'eJn],eJadLu81
OOg Os OOg 0s I. O0 I. 0s
I, I I I I~0" 0
!
|
i
............................ j 6HLUU~ L Z ' L s I. I
i s ed)t= e!sd L
I '
Ji
....................................................................................................................................................
i
7Z2:ZZZI-I:ZZiT~::Z-~::Z:7_-..Z:I-:T-J
L'O
<
"13
0
"13
(1)
o~
(-
wi
(1)
13
m , i
/ . . . . . . . . . . . . . . .
CllOV Off:lOB 80erie
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiFI
i " t, I OL
1 vvu ...................... 1 ....................... |. ,, ................. |. . : ._ .............................
J,_L_ZZZZZZ]I
] .......I B2D6 DEUTERODIBORANE ...........................
]IIIIIIY IIZIII .........................................................................................................................................................
lO!_.................... I , t
! ........................ i ..................................... T. . . . . . . . . . . . . .
. . . . . . . . . . . . l l I
I ! T , ,
1 ................. , , , ................... l ............................. ~ .......
I. i, ,i i/ I' J' i
4J I ! !
I ~Z~Zi~i~iiiiiiiiltiiiiiiltttttT'Tiiiiiiiiiiltti-"1,--~--T
. . . . . . . . . . . . . .
J .................................
.................. I............
~ ..................................................... ~ . . . . . . . . . . . . . ~. . . . . . . -1',.,. . . . . . . . . . . . . . .
if_ 9 ........................................i..-..- - - - - - - - - - - - 1 . . . . . . . . . . 1
I I
/ i
/ i
! i
/ 1
/ i
9 i / i i i i i
" d - i !
/
, i i i i ,
O. I -I-------- ::_-----_____-~::m-,-':-: .................... :................................. - ...................
/ i
-
........................................................................
,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
t -,4
~ , i
] ..... / i ! i
J__ . iiii ! .............................................. ii ............................................................ '~........................................... ~. ,!
] ....... i
1 psia = 6.895 kPa
I
1 psia = 51.71 mm Hg
i
i
i
9
!
i
! i
|
'
I!
i.
0.01 I i i I I
-260 -24O -220 -200 -180 -160 -140 20
Temperature, F
29
OZ:
3 'oJn:leJaduJa/
O0 I. 09 0 09- O0 I.- 09 l.-
I I
I i. 1.0"0
6 H uJuJ LZ" L9 = e!sd L
ed)l $ 6 9 ' 9 = e!sd I.
...-.-.-i.........--i
i,l.i, ......11__ ............... i ................ i . . . . . . . . . . .
i i
' T ~_iilLiiiiiiill iiiii' 1'i'111
;/
[/
- -/ I.'0
= ..... i'
<
. . . . . . . . L 0
. . . . . . . . L
9 [ii .............~ii'i ........... .... : , _ ....... L
"13
{n
o~
c-
Gg
i i
r/ m Q
i
= . . . . . . . . . . . . . . . . . . . . . . li . . . . . . . . . . L
........ 01.
TF ..............................................................................................
3ClIIAIOI=IBOIdGAH 3NVEIOBICl JIBSHEIB
.!
...............~" ' ~ -00
1000 q ..................~............. ~, ~............................................. i, -.: {,
::I:: ::::::::::::::::::::::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::
:1:
]
...........................
i...............
" f ~...... ........
~-;Z]
[
, r ..........
i..............................I....................... T ....................
i.......
========.......... ===========[==
===l==i::::i
==.......................
...... ~ _
] ....I.........
T i ~ i !
.................................................
.................................
l ~ ~ 9
I00~---........................
!......................!'
............... [ ~ - - ~ - ~ - ............i.........................
.... ii
em
f~
Z~
13_
i I
0 '! I
: --,}
>
i i
i- ........................................i [ [
: f .......................... . ............................. i
I I , , ,
,I i '
i
' i i
I. i i ~.9..........................................i.I.......................................4.'
! i i
i i i 1 i
i ! i ~ i
0.1 I !!...............,!........................
J..........................................
L..........................................
i
i i
;
i, it ..............................!
i I
-'-~- ......... 4 ......... |
I
1 psia = 6.895 kPa
I F ......
1 p s i a = 51.71 m m H g
[ i........
, i ! i
i i
! i i;
I 9 ! , i ! i
o.oll I
i
I I I I
i
I I
-300 -25O -200 - 150 - 1 O0 -50 0 50 I O0
Temperature, F
31
100_.
J
10-
f
,L
!iiiiii~i............ii.i ................i ~ il
, f
. , i
CL
e,,
J
(D
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(D j I 84
13..
7
0 /
Q.
/
>
/
0.1 _- z ...............................................................
I
i
/
/
/ 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 mm Hg
0.01 -
-1 O 0 -50 0 50 1 O0 150
Temperature, F
32
100~
!
J ........................
I B4H10 TETRABORANE 1
~ T Y Z ! .............................................., ....................................................................
I O ~::::::::::::::::::::::::::::::::::::::::
. . . . . . . . . . . . . . . . . . . . . . ...............
. . . . . . . .~. . . . . ......................
.............................................. ....................................... q r .............
.........
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I .................................................................... I .....................................................
i i i ...........................i ..................................................................................
o,,~, . . . . . . . . . . . . . . . . . ~i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ii . . . . . . . . . . . . . . . . . . . . . . . . . . . . . §, ................................................................ ~i ..................................................................
Q.
i !
i l i i
O ................ i .................................... r ........ -Y- ....... f .............................................. f ...............................................................
i i / i i
L _
I= I~711111111111?IIIIIIIIIIIIIIIIIIIIIII~~~-Z'I.~~Z~'~I:Z{LT~III.__.__4_
I ~
J ......./ :-~~--~'~-'~'--'i--'~---ZZ3--~:7;ZZI:7~-:7-ZZ'z-:~Z:Z'Z:ZZZZZZLTLZZ
h i .....-ZZ:
o
!,__
.- . . . . . . - - ~ ~L . .-. . .~. . . .-. . .-. . .~. : : : . L T - ~ I-Z Z]Z;- ................................. -:r ...................................................................
. . . . . . . . . . . . ................................. .. . . . . . :! .............................................................................
..................................................
O
Q.
. . . . . . . . i.................
_ 7 ........ i............................................ t ..................................................................
i.............................................................. !
>
. . . . . . . . . I .............. . t ......................... --t ...................................................... ~J..................................................................
i / ! ! i
. . . . . . . . ~. . . . . . . . . . -/ i ....................................... ~,................................................................ ~.................................................................
oi .
-
. . . . . .
~
/
~.
i
:iT_L_--=---
~
!...........................................
;
i...................................................... ,.....................................................
!
Z:i: ~. . . . . . ~ r....................................................
- 7--r i ......... r................................................. t ...................................................
]............................................
...............................................
/--i
. .9~ ~ - . t , .
!.4... ..... ... ..... - ti....................................................... i ..........................................................
........................................................ .i.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
/ ! i i i
. . . . -/~-~[ ~ . !. ~
4 . . . . . . . . L. . . . . . . . . . . . . . . . . . . ,' ............................
i I i
- ------7 z i .......................................... t ................................... t ...................... I psia = 6.895 kPa ......................................
/ j i i 1 psia = 51.71 mm Hg
............ / "+ .............................................. {'.................................. - ................. -i::. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
' I
0.01
I I
-150 -~00 -5o 0 5o ~00
Temperature, F
33
1000 + {
--I1 I i ~:~§
! !
B5H9 PENTABORANE
100
f
l
J':i
o3
u)
1:3. 10
/
r/
Q~ /
s
Q) /
I J....
I
/
IL._
s 1
!
O i
1:3.
> /
!
/ i
1
]i
i....................................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0.1~
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
J
i
0.01
!
I I
-100 100 200 300 4O0 5O0 600
Temperature, F
34
100 ,
......................................
ILL ....... 1 [ [ ..........................................................................................
lm i I i ....XI ..................................................................
i
7 ............. F ........................... T - .............................. i .................. 7 .............!.........................................................
i............................................................
J__ l
i= i, / i: i9
7 ............................................... -r . . . . . . . . . . . . . . . . . . . I- . . . . . . . . . . . . . . . . . . r. . . . . . . ~ ....................... ~ ............l .............................................
L / ii i~ i /
i
ii ii
/ i i i/ i i
1 _~. . . . . . . . . . . . . ................................ ~............................... ~ ..........,:...............................................................
t ~ . . w / _ } ! }-= ~-=
n
L_ . . . . . . . . . .
............ "1".,..................................
...........................
,..".......................
.............................. t .................................... t ................................................................ " .........................................................
====================================================================================================== .............................................
L
4 ............... 1.............................. b ................ ~ ...... { ......................................................
0
c~
...................... T,........................................ ?~.............................................
i~il-.-_-Jll i,~iiii~-i~iiiiiiii~iiiiiiiiiiiiiiilJiJiiill
....................................................... "s.................................................................
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii,.................................................................
ii........................................................
J E i i i
> ~- ........... ~.................................. r / - ........................... F .................................... l .......................................................i ..........................................
l
1 i
i
. . . . . i7" ............ F ...................... r,................................. F I ..... i
. . . . . . ~ ................................... { . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................................... tl 1 p~!~ -- 6.89s kP~ ..................
/i i i i 11 psia = 51.71 mm Hg
. . . . . . l .................................. i .......................................... t .................................................. !1 .................................
i i i i
J i i ~ i
! , i i !
0.01 i i
-1 O0 -50 0 50 1 O0 150 200
Temperature, F
35
10
B10H14 DECABORANE
i
.......................................... i
I r a .
.u
Q.
(D
r Z
(D
13_
O
Q.
>
0.1
, [.......................................
1 psia = 6 . 8 9 5 k P a
..................... 1 psia = 51.71 m m Hg .........................
i
i
l
0.01 i I J i
100 150 200 25O 30O 350
Temperature, F
36
1 O0 ~:::::i::
...........................................................
::::::::::::::: ::::: :...........................................................................................................................................................................................................................
......................... _ | , . ............. ~ m,.~, ................................................... ~ ...............~ _ ~ ........................................
3-:::::::i:--::11111:111::i::11111111
]:: :- :_::::: ::1 B a BARIU~ .....................................................
i 2::::::2::222:2222::22:::::::::::2:::::::::::::::22::2::
= t : ~ ! !==
...........
---.
t
]iii iii:i-i---i::i:iii:iiiiiiiiiiii::iii::iiiii:iii iiiii i ii --.-:i:i .......................................................................
0.1
'
I i
tO
m i i ~-/
i
'
t .............................................
'
"
,t,
Q. 0.01
i !/ i i
(D
! =7:~
(~ 0.001
(p
13_
I ........... 7
0 t..../ I............................. :
1
Q- 0.0001
tO
>
P f. l t .....................................................
',t" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "," . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4,
i i
1 E-05
| ! . .
p . . . . . . . . . . . . . . . . . . . . . . . . ~................................ ~.....................................................................
4
I t. . . . . . . . . . . . . . . . . . . . . . . . . . . . '~" .............................................................. "I.."
, I i
. I
1 E-06
tz r .................................................. 4
t f
t F ....................
9 L...............
,,I !i i
I..... . . . . . . . . . . . . . . . .
1 psia = 6.895 kPa
,p . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................... 1 psia = 51.71 mm Hg
~ ~. . . . . . . . . . . .
! |
l i t
i ii I! ii
1E-08 I
i
I I I I
500 1000 1500 2000 250O 3000
Temperature, F
37
1 O0~c!!!::!::~!~!~t!::::i:~::::::i::::::il ::::::::::::::::::::::::::::::::::::::::::::
............= = - - - - ; = = = - : : : : - ~ : ~ : : " = ~ - - : ' - ............................................................................................................. , ................................................. ::::,
~ ! ~ ! ~ ~ - _ ~ _ ........................
, : _ - = - . ) ~ ......... i ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...............................
#l .................................
f f ~ ............ : - _ . . . . . . . . ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,_ .................................
J / j
, , m . . . . . . . . . . . . . . . . . . . . . . . . . . . i ........... [ . . . . . . . . . . . . .
(D Z.-':ZZZZZ'L':ZZ:;..-.".ZZZ;:Z!Z";":----.;T.~Z::Z;::Z'ZZ::ZZ:::
....................................... ,I...................................................
Z~
I--..
13_
.... . I .... ~ . . . . . . . . . . . . . .
.... ~ .... ,/ . . . . .
_ .. . . . . . . . . ~#" ......
0 #
0.0001 . . . . . . .
_~_ - _ ._ . . . . . . . . . . . . . . l
:::::::::::::::::::::::::::::::::::::::::::::::: ........ ................ .
/
>
- ! ........ - : .......... ..::.: ..............................x,:::::::::::::,
-- . / . . . . . . . . . . . . . . . . . . . . . . . . ". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-- ...-/ . . . . . . . . . . . . . . . . . . . . . . 9 ...................
-- .............. Y . . . . . . . . . . . . . - ..........................................
1 E-05- ~ ~ ~ - ~ ~ - . - = - = = - - - - - = ' , :i
T I ~ .................................................
/ Z}-..-.-_.T.Z~ZZ.-.Z..-.Z[S.ZZZ-}-.:ZZT-[Z
1E- 06-_---_
....................
i _-......
}----/;------;
............-----~::::::..:..:.:..........::-:--:--T:~='-:
/ .......................... ....... - - .....:-::-:::::::::::::::::::::::::::::=:::
................~..-.._...- _ . _ ~
- 9 : ..........................
? . . . . :................................................
]
/
'"" 1 psia = 6.895 kPa .............................
1E 0 7 - / Ei 1 psia = 51.71 mm Hg ii~.-~--E~.~Z-:--"iEEi
~:."-': :._-TZ Z Z " E "_-_Z'T.:Z."_" Z " ',
Y
_/
i ...
~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ............................................
t
1E-08 I i i i I
1500 2000 2500 300O 3500 4000 4500
Temperature, F
38
I O0_]~:::::::::y::::::::
.4I !! ..................L!........................
L ~...............................II !
i
] IYZ21111 , . . . . . ,...... , [
]YY YTYIII ............................... ~ ......................... :
-]iii-iiiiiiiiiiiiiiiiiiiiiiiiiiiiii! BeB2H8 BERYLLIUM BOROHYDRIDE ......................................................................
T-
7111111111 ii.......I i...........................
] ..............................................
i "
i I
I
I
!
,! ~
I 0 ............................................i ~ l i ..................... t .....................................-i-.:-....................... ~ ~ ...................
............................................. - - ....... t " i ......................... ~ .................... ...".......................................... t . . . . . . . . . . . . . . . . . . . ~ .... --'-T-i_,__,-_ ~
................................... ~ . . . . . . . . . 4 "; (.-------- ....... " ............... .~................................ ,:. . . . . . . . . . . . . . . . . . . . . . . 2 - - - . . - . . . . . . . . . . . . . . . . . .
[ i I i i i i i J i
................................ " . . . . . . . " ~" |. . . . . . ,. . . . . . . . . . . . . . . -' ..................... I" . . . . . . . . . . . . . . . . . . . . . . . . . . . . I " . . . . . . . . . . . . . . . . . . .
............................
.............................................. TI. . . . . . . . . . . . -!-! [i ~!. . . . . . . . . . . . . . . . . !i......................... I:........................................... - :i :~7 :_: :_: : :L: :_: : _: - :_: :_:..................................
.~i...................................
:::::::::::
____i
.............................................. i . . . . . . " i. . . . . . . . i ............... "t.. . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...................... -I. .................
-I ~ l F i ~ [ ....~ ................... -i, ............
7 ' ~ I ' t. . . . . . . . . ] ti" 1I . . . . . . . . . . . --t i ................... i' . . . . . . . . . . . . . . . .-. ". .7.-. ]. I. . . . . . ......................... ]]. . . . . . . . . . . . . . . . . .
c~ / l i I i i I / I i
=m
(/) -i-......................................... ~ . . . . . . . . . . . . . . . . . . 1" f I" . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . ..'....... ~ ................
I , I ! i ' i/ J i
i I I ! i
c1. , i i , ! -.~ i i
.............................................
". . . . . . . . . . . f ] ................... T ............................ "....................................t ....................................! .............................
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I i I , , i ......~ t i
I Ii I ! iI ,
i
/ iI !
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oo / t i ! , i / i i i
1 j . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . ~ ~... .,}. . . . . .. . .. . . . . . i . . . . .. . . . . . . . . . . . . . ~ . . . . . . ... . . . . . . . . . . . . . . ... . +-
. . . ... . . . .. . . . . . . . . . . . . . . . § ..................
(D
I,.. 9 . . . . . . . . . . . . . . . . . . . . . . . . . . |. . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ............................... - - 1 " . . . . . . . I" .............................. I '"i . . . . . . . . . . . . . . . . . . . . . . 41". . . . . . .. . .. . . . .. .
(3_ -i ............................................... ,, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . d
i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i-.9. . . . . . . . . . . . . . . . . . . . . . . .
, ,
! .........................
.............
:. . . . . .
!,_.
] . . . . . . . . . . . . . . .t. . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . .i . . . . . .~. . . . . . . .i . . . . J - ...............
- ~ "1,. . . . . . . . . . . . . T
0
Q.
I
- , i ~ - - ~
J . . . . . . . ~~ . . . . .
I
§. . . . . . . . i. . . . . . . .
{tl l i i i
l I ! ,
>
i
.......... ',....... !
-',.I .................
-7 T-'! ......... i....................... i..............................i ............................1'
I ! I :
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~ /, i i i ! i
' I ; i i i ": i
i ! ; z z 9
~ ,
!
~
-I771111711171777~i:i........... - - , , . . . . . . . . . 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............ -.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ; ........................................... , ........................................... , ........................................
___L
' I
......................... ~, ..................... i~............................ i: ............................. 'i.,....................................~i .............................................
4i .............................................
~i ...........................................
................................................................................................. .LC7
~ ......... t- ........
! .........
.................................... ! -
I
x/
I
i
!
I,
I
.
1
' !'
I
il
i I
I 1 psia = 5 1 . 7 1 m m Hg
i ...............................
" ..........i ~ i ~ i i i I ,
I I i i I ' ~ ! t
i ' ~ , i i i
I i' i ! ! ,I ,
i
,i
O.Ol / i ' i ' i
20 40 60 80 1 O0 120 140 160 180 200
Temperature, F
39
_______
10-
tm
7 ~ ...................................
.,.
L_
L_
1
0
>
0,1-"
i ............................
!
0.011 ]
550 600 650 700 750 800 850 900
Temperature, F
40
100,
~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiI I ..... I ............................................... i '
. . . . . . ' ................................. J, ....................... i
~ITTYZZZZZIIYI
],iiiiiiiiiiiiiiiiiiiiiiiiiii BeCl2 BERYLLIUM CHLORIDE ........................ i |
!I Ii
I " i !
|' 1
] !
!
' I
!
,~.
ii |
I
I {,
i
t t
I
i|
e ~
c)
13_
0
c~
>
I
0.1
....... -/:::::z-i
,/
I i :
i
t ',
i i
1 psia = 6.895 kPa
j I I i
! i
i 1 psia = 51.71 mm Hg
!
! i i
i
! I
! i! i
i
i
!
i
! !
t ! i
0.01 I I I
550 6O0 650 700 750 800 850 900 950
Temperature, F
41
10
J
i
BeF2 BERYLLIUM FLUORIDE
l--
om
7 b
F
03
(Q.
ID
t.__
03
03 I .......... . . . . i ..................
(D
L_.
13_ i................ _--_- --~-~_- ............................................................... l............................
L_
O
O.
>
I !
t-" I
I 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.1 I I I
1600 1650 1700 1750 1800 1850 1900 1950 2000 2050
Temperature, F
42
100, " , " _...... , . . . . . . . . . . , ............ ,_ .__ '
T
il ...................... m m
J i
I
! .......................... i
i i '
i I I
i { t---2 ...................... ..
--; .................................. t .............................................. I ........ 7
i "
f_-........-.........._....~ : L. ........................... -i--
..... , ..................................... L _ _ _ _ _ _ ~ .................................. i-
............................ i. ................................... "i ................................... .i...
i ! : i
i i i i . . . . . . . i
t...................................~........f......................"~...................................... +"
I i ! i i" .......................................
/ i
T, j
i i t, ....................... !' .......................... ~-.................................... !""
Q. I i i I i
i t
t i ! L ............l . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .' ...................................
L_
t '
i/ i
t
i I I _4...................................,....................................
J........................................
L
..... { . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~..................................... ~..
r ...................... t : | -
.... t ..................................... * ........................................ 'I ......................................... 4...
n ...... i .............................................................................................................. j.
i ! i
I,__ ..... i ....................... ~ ...................................... .l{.............................................. T'}
Q.
, I,! i
I i i ', i
> T
i
--.4
9 ......................
i
~ ...............................
'
4 ..................................
I
4.-
i
i i I i i
o,J
............................ ft .............................. t ...................................... .!..,
i i i i i'!
i! : i !
...........................................
!
i
!
LI ......................... 4................................. i-
- T r ........................
l. . . . . . . . . . . . .
...........................
9
i,. ..........................
" .................................
4 ...............................
i"
~.-
- ? r w I l
i ....................
i
; ................................. -r, .................................. T
i
i t [
i t i
1
!,........................
.......................t,'i1 ~ Ho
!
1 /"'~ '~ .......
i
I
l
i
1
!
i 1 i i iI
i 1' I1
0.01 i i" ' I I I I
500 550 600 65O 700 750 80O 850 900 950
Temperature, F
43
100_---- F...... '..........................................................~.............................................................
Bi BISMUTH
10-
:-!
0.1
[ f _ . . . . . . . . . . . . . . ~ .....................
o m
03
Q. 0.01~
(P
t . _
I
u~ .................................................. I
oo 0.001 -
(P
t__
13_
L _
0
Q. 0.0001
>
1 E-06=
1E-08 I I I
500 1000 1500 2000 2500 3000
Temperature, F
44
I
100,
! i
! !
...................................... to. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 . . . . . . . . . . . . . . . . . . . . . . . . . .
I
I
i i
i i
!i
i i
O.
l---
(p
L_
i i
13_ t !
0
O.
i
t. . . . . . . . . . . . .
> ..............................
I
i ".-"E-2-2"~:72T-.I.-:T~2T_--_'--_ET;2T'ITCI2~21~EZ2T;E2~
! i................................. ~ .................................. ~...........................
i
,j
~~.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
+ .......................
I
,.". . . . . . . . . . . . . . . . . . . . . .
0.01
l i
i. E
:
1 i
9 !
I I I I
500 550 600 650 700 750 800 850 9( )0
Temperature, F
45
1 O0 ; ; ; i~
_
[; .
1
I
mm
! 9
/
10
................... f
7
o.,m,
c}
J
(D
/
1 ,
(D ,, ii:i ~i~i;i ~
.J
J
n
f
0
r~ /
>
/
..~#
/
0.1
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
0.01 I
400 450 500 550 600 650 700 750 800 850
Temperature, F
46
100, ......... ,........................................................................
,
.......................
3111111111,ii ~i i iiI
][ .....iiiiiiiiiiiii I BrF5 BROMINE PENTAFLUORIDE I
11111................
i1 ..... I !
j i
] ........ ! i
r.....................................................
i
- ! !
- t
- 1
=,,m,
, !
r~
_ , !
(1) s i
i i
,I !!
- ,~ -~
(D
13_
i
0
c~ l
9 / ,i I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
|
I
i E
I
> .p ...............................................
i
!
i i
ii i
0.1
!
4 .......................................
4 ................................................ .$
.-~- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
I i
{ .................................. {
|
i i !
! 1 psia = 6.895 kPa
i i
! i 1 psia = 51.71 mm Hg
i
I
I
! ! i!
o.ol I I I I
-1 O 0 -50 50 1 O0 150
Temperature, F
4?
-1 'eJn},eJedwel
009 OOCj 0017 00~ 00~ O0 I. 0
I
L'O
6 H W W L / _ ' L s = e ! s d L .-
ed>l 969"9 = e!sd L
/
/
/
....
/
<
....
~01. "13
0.=~
==~
i /:: i
-0
..... / I 0
oo
oo
e-
.=~
/
J
/
0
!oo~ "13
m =
/ oo
/
!
L f
................................... .I v
000 L
=INIIAIOEI8 ~J8
4
0000
100] ......................................
t
i I
T'
]iiiiiiiiiiiiiiiiiiiiiiiiiiiii~iiii] C CARBON
~111111111 l L
i .......................................................
i
] i
i
i
i
i'
I
t
I
10~m
ffl
. m
EL.
0
>
!
i
/I
,m,} .....
i
I! 1 psia = 6.895 kPa
! i 1 psia = 51.71 mm Hg ...............................
I
II i
0.1
!
!
I
i
I
5OOO 5500 6000 6500 7000 7500
Temperature, F
49
1000-1 l , ..............................................................................................................
, ............................................................
~: ..................................
:-:---...-~-~. ,T :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ......~.~::::-::--:':'::'
: ::: ::::::-:::-:::::::::::::: . . . . . . . . . . . . . . . . . . . . . . . . t .................................: : : : : : : : : : : : : : : : : : : : : .............:'::
:::::::::::::::::::::::::::: C C I 2 0 PHOSGENE :•--=---=•••••••••••••=••••••••••••••••••=:====•••••••••••••••••••••••••-••••••••
q Z---- m _ _ _................~..,,,,,~.____.,..,...T,_.... ......__..._____.,,.,..,..,
I ........ ............ ................. 7 ....................... , ......... ---.-...---....~.._..._._...____...]_____.___....._____.,
I I . ~~I, !
~ i i i : : ::~: ~ : : : : I ~ : .....................................................
:i~z~~-:..:.~iiiiiiiiiii!iiI!z!i~ii!!!iiiiiiiiiii~ii~i-iz~:iiiK....ii~.~iii~!iiii~i!ii!!!!:...:.:~.~i~ii
]::z::::::::::::::::::::::::::: :::: ':i : --!.----,,,--,-~:____~IZ_T_T_:::,~~------ 7 ............................................... f .................................................................] ................................................
]] . . . . . . . .j . . . . . . -- : ...... : , / " -. . : . .~ . . . . ... . . !l ............................
.............................. ..................................
.........................
-/
l. . . . . . . . . . . . . . . . .::Z. . . .ill. .iiiiiiiiiii
. . . .ii:i:iiiiiii
...
n /
0 0.1 ................................ 4................................................
13.
................................................ p. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
................................................... 4 .................................................
> i
/
0.01 ---__~....~..~::.~ :::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
~ - ~ 1 :.T_:'::.'ZZ::.-Z::::::.-:.":::..-:::":I:_":::::: ..".-:::::::::::~-.:...::::::::::::::::i::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::.::::::"::
| !
i .i
0.001 :::-~-"--:.~.-.~.'.:.--:.:T.:::Z::::::~ :::: :::::::::::::::::::::::::::::::::::::::::
t
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
1 1
1
! !
0.00011 I I
-200 -100 0 100 200 300 400
Temperature, F
50
l ODD,1 .... I _ Z Z L .
i ! i............................................................................................
] ...............
........................... ! ; f..~..
~...i
......................................... T:.............................................................
~ i .
I cg20 CARBONYL FLUORIDE ~..-----_-.--~I~IZZ.-.]I~I}I~ZIZ~_--~I ..................
........................... i. . . . . i i
J__.__L ....................., ................................................................................................................................
L~ .............................................; .............................................
- ~ - - i ..................................................
~ I 1 1 i / i
+ - - - - .....................i .................................................I.....................................................T............................................................
i.......................~ ..........................
!...........................................................
'9 i i i / E
I . : .
I i
............ 4. . . . . . . . . . . . . . . . . . !-. . . . . . . . . . . . . . . . . . . . . . . . ..................
9 ~ ...................................
i t i J i i
i i i /
!
i
'
i
;
9 i i ! l
i t ' i i
00
3-------__
.............. I .............................................................
.......... ,.............................. [...................... ZZZ]:ZZ72-ZZZZZZ]ZZZZZZZZZZiZ-:.ZZT.I......................
t ....................................................... ~ ................................................................. I .....................................................
J i ! " -'.
Q.
+ - - r..................
..............~ ........................... / ...............i................................................
....... J..........,.................................i................................
(1) i i i i i
..... i ! ~ E i
i i i i !
00
(1)
I,..,
13.. i
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i
I
1
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i i
i
.................... "+ .......................... f ................................... t ............................................... ."............................................................... " ..................................................
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i i 9 i i
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',."............................................................
.................................................................... ...............................................................
I i i .'. i
. . . . . . . . . . . . . . ~,....................................... i- ..................................................... ~ ............................................................. :.".................................................................... ~..................................................................
_.-72-_"-:::::::::7 :2:::::::::::::::::::::::::-:Z-ZZ:i::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::i:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~i~~~~i~~~~?~
i i i !
. . . . . . . . . . . . . . . ~ .......................................... - ........................................... ~ .................................................... } .................................................................. ,.,...................................................................
i ~ i ~ ;
i i ' i
i i i i"
1 1 ! i ~
l i i i -'
I i , i i
I i
-200 -150 -100 -50 0 50 100
Temperature, F
51
0.001
t ..................................
I CH4N20 UREA I--
]IIZIIZIII iiiiiii!.................., ...........................................r_-
't .........................................................................................................
i m
Q.
(D
!,__
(D 0.0001 -
n
0
Q.
>
i 1 psia= 6.895kPa
1psia=51.71mmHg
1 E-05
160
I .....
170
!
i
!
180 1 90
i
'
200
i
I
2"
150
Temperature, F
52
10000. ............................... ,. , ,
i .........................................................
t
! i
liiiiiiiiiiiiiiiiiii1 ............................................................................................... ....................... d .............................................. .I.-...................................... .......................
9
,. . . . . . . . . . . . . . . . . . . . . . . . .
I
i
I I ................................ ! ..........~ - -
if)
ffl
,8
' i
I
I
!.___
! i
0 i .J.
>
i
....... T ....
I
!
i
I i!
i
i
I i
i II
i
11 I I I
i
I
300 400 5OO 600 700 8OO 900 1000 1100
Temperature, F
53
1oj .................................................
! i, !
i I
!
....................................... f"........................ t .................................
CNBr CYANOGEN BROMIDE ~i
I
7 iiiiiii_-
[ iiiiii
4
]
Ay
...................................................................
,,m
i
i
(D
t
(/,j
............................................. l .............................................................................................. i
i
.......................................... i ............................................................................
i i
i ...............................................................
c~
J
, ............................. I .......................................... } ......................................... [ ....................................................
II r
i
I j
54
1000
i I
!
i .........................................
....................................................................................... i
!
I i I
ii
!
,~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ? ................................................... ,
I 7-"', !
(B
omm
i
Q.
i
(D
'/ i 1!
|
1/ i i !
l i = ! :
(1) i i i! i
n !
F ............................. ...........................
t..
!
0 i! i! 1
i i
!
! I
> 1 i
ii i,
i i, ~ ........................... 'tT.......................................
........................................
1 i ! i,
i i i i
.
t --/
. . .
................................ ~ ~ w ~ . . . -
I
i
]..... - ..................... ~ ]
!
, i
--.J ~--- . . . . . . . . . . -i- ................................. { ....................................... ~ ...................................
I9 i i' i :
i i
l .........................................
i |
..........
..................... - ................................
r T
.9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
:
S
ii
i 1 psia = 6.895 kPa
!
i i! i ...........................
i
;'- ..........................
i
1 psia = 51.71 mm Hg ..............................
i
! !
_
! !
i ii 9
'
i
'!
i, :
!i!
I I I I I
0 50 1 O0 50 200 250 300 350
Temperature, F
55
100 ...................................... i
r ................................................... ,..................................................
m...,m
0t)
(D
$.,..
(D 10
i
13_
O
c~
>
j
l
f
J
J
!
11 I I
-110 -100 -90 -80 -70 -60 -50
Temperature, F
56
1000
! i
CO CARBON MONOXIDE
,,, . , , , , ~
5...
L_
0
c)..
>
i i i i
1 I I I
-340 -320 -300 -280 -260 -240 -220
Temperature, F
57
Vapor Pressure, psia
0
0 0 ..L 0
o b P --,. o o
-'~ -" '-" 0 0 0
t~ I I li I I I I I I I II I I i I i Iil
i ................
~9 , "........................................................... I ........................ "
i !
!
I !
i
............................... r ............................... [r ! .._
i I
I +L
i n
(/3
o.
(D
I...
:3
03
03
(D
t__
EL
t.__
0
El.
>
0.1
I
.... ,},
T ............................... .t.,..,~ . . . . . . . . . .
!
I! i i
b ..................... i .... 1 psia = 6.895 kPa
i ! i 1 psia = 51.71 mm Hg
i
{ i ........................ ~ ....
!
t 9 i
i I i 84 i
i! i i
i i i
0.01
! ! I ! ! !
i .... I I i
-180 -160 -140 -120 -1 O0 -80 -60 -4O -2O
Temperature, F
59
10000 i I i i i I
. . . . .
] ,r ! F ................... |............................i ............................................
m . "| ....................
.i ~ .............................. ~ ......................
CO2 CARBON DIOXIDE [ i ......................
................ i i
b
~ -
i ...... . . . . . . . .
I
~r
t
t I
! .................... t ~, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~. . . . . . . . . . . . . . . . . . . . . . , ..........................
........................ 1
, t
]
1 000 ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 ....................................................
! !!!i !!!!!!!!!
e .....m
Q.
(D
r~
O
C).
>
100 f
....................................... p. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
L !
r , ,i i
L
101 I I I I I
-80 -60 -40 -20 0 20 40 60 80 100
Temperature, F
60
10000-~ ~
................................................. ! ~ ........... ==:-= ........... = .........................
~l::~:~:i !!!!!!!!!!!!!i!!Yiii iiii~iii: ::~ ::::::::::::::::::::::::::::::::: ........................ ~ .................. ~" ~---..-'_".'..-'..-..:::::_-z..::
~::ii:::::::t::
Z~I::ZZ] .....................
~: .......::::::::::::::::::]
CS2 CARBON DISULFIDE ----i i. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
,ooo 7 ...............::::::::::::::::::::::::: :: :: !
! -:: -
! ,,
'........................ ~iI
t...............
i
i=-"---'.~'-'=.'-'.".'='-..--'-~ . . . . . . . . . . . . . . . . ~ . . ~.='G.=~..._-=~--=.._--_-=-_-
::::::::::::::::::::::::::::::::::
3 ~ .........................
| I'. J .,.
i .........
........ iiiiiiiiiill i !i.......... -!! s T i
! l i ........................
ij t! h"
;--': =q .................................................................... ,
9 § ..........................................................................................................................
- i t....................... t
..................... t .......................... .." ................................................. t ................................................. ".-
k ............... ...........................
9 -'-............................................ ~................................................4
- ! i
i-- ............................... t ........................................F........................................
..........................................I I _/_ ............ ~............................. " ................................................
L.............................................
i
,2
~ m ,o_
- ........................
i
!
iFz.~=:--~
:F--_7!~-__-=__!~
. . . . . . . . . . . . . . . . . .
i
oo
! /_
..} :~'.~"~-~..~".E~"~Z~ZZE~7"1:"".:~Z"~"~"Z~"~.-.~Z~[~Z~E2~ZZZZ~:::Z:~::~
(D
I,...
n $
i..~9. . . . . . . . . . . . . . . . . . . .~ . . . . . . . . . . . . . . . . . . .
F~ . -. . -. . . ........................................................................................................
................ ., ......................................... ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
! . .~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........................................... ,- ...............................................
0.01
t ~ t ' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .9. i
t t. . . . . . . . . . . . . . . . . . . . . . . . . f ....................................................................................................................... I
, ~ {
. . . . . . . . . . . . . . . L-- . . . . . . . . . J. . . . . . . . . . . . . . . . . ~...............
, - ............. 1 p s i a = 51.71 mm Hg
i i 1 " i
Temperature, F
61
1 O0
i i ..................................................
! t!"...........................................
CSeS C A R B ON S E LE NOSUL F IDE
E.....................................................................................
......................................................................................
j
10 ............. iiiiiiiiiiiiiiiiiiiiiiii~iiiiiiiii ~ i ! il ~ .
u)
(D
13_ ~iiiiiiiiiiiiiiiiiiiiiiiii........ i iiiiiiiii--i~ii~ii-iiiiii~ii~
//
t,,...
0
Q. 9 ~ / ! .... iiiiii _
> ' !
1
I
i i ..................................................
1 i
0.1
0.01 I i i i I
-1 O0 -50 0 50 1 O0 150 200
Temperature, F
62
1 O0 , , ..................., .......................................... , ..................................................................................... }
l ........................ . I .:..:...::...,.
:...:. iii ii ii ii i iiiii_i_ __[_iiiiiiii12111111111111111111111111111111111] . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . IIIIL_
.
i i
' _._~.__
,
lo- ......................................
~! t I, I.............. q ......................................................
::::::::::::::::::::::::::::::::::::: :::~E-!Z- ............
~:::::::::::::::::::::::::~::::
..................
i............................
i ~ ..................i.........................................
T .........
~ ..........................
13. / I ! ii I" / ii ii
_~ . . . . . . . . . . ! . . . . . . . . . . i . . . . . . . . . . . . . . . . . . ~ ..........................
t ~ i i / ! i l
g ! i i i i i
i i i i i i i
1 -_-:::-=:==::~: i : ::::::::::: :::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
~ ~ - - . ' . ......................... ~-, " '. ............................ 4............................................ .';-................................................ -.".........................................
3 _L i -'..
............................................ i ............... ~" i ....... i ........................... i ........................................... i .............................................. i .......................................
....................... i~. . . . . . . . . . . . . . . . . . . . . ~F.
/ ~t~ t !
-+---------~ . . ./ . . i. . . . . . .! . . . . . . i . . . . .
]___
_+, ........
~: ....................................... ~I........... i
~_...Z ...... iI ................. Ji.....................................ii .............................................
ii......................................
I ~ i
> 1 ............................. il -I . . . .!. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . l
'..........................................
;
i i i
/ i :
i
i I / I! ii i' i ' i'
J ~..---Zi ............. ii ................. !I ......................... ~i ............................... "ii .................... 1 psia = 6.895 kPa ...............................
, I i i . ..
I i i i i i i
/-- ~ i ! i i. "
i I ! ~ i i i
i ~ ~ ~ i
Temperature, F
63
10
! t ...................................................... i ....................................... i
.................................................. ~ ................................................. i~
C3S2 CARBON SUBSULFIDE ........................................
i J ......
eu
r~
~-TI T~] ~......................................;
Y i~-~[:i : i~iiiii:iT~ii i~il
.z............................................... !
(D
13_
!--- ....... !............ / -
0
Q.
>
0.1 =. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4.................................................... i
! .........................................
!
!
S ....................I i !
I
! i
J! 1 psia = 6.895 kPa
i' ........................ ~ 1psia=51.71mmHg ......................................
i ,
I e
0.01~ i j i i
50 1 O0 150 200 250 300
Temperature, F
64
1 O0 ---~.................t ....................................................................................................................
~Z~:~::~!~!~:!!~!~!~!!~!!!E!!!~z!!!:~!!!!~:!~-!~!~]~:~-~:~:-~!E~!!!~:!-!!z55!E!~=~a!:
~.ZZ..Z::-:-Z::::Z-Z:-...Z::-::T.ZZ:Z:J.:::Z::-..:;Z::-.---:T
~ , ..... t ~Ts
Ca C A LCIU M
tO
,,,~m
13. 0.01
.L.9 t
iI
(D 0.001
13_
0
Q- 0.0001
to
>
!
1 psia = 6.895 kPa
! i S
1 psia = 51.71 mm Hg
z !
i t ................................. i
! ........... i,....................................... T,.....
1E-08 I I I I
50O 1000 1500 2000 2500 3000
Temperature, F
65
100.. ~ ............................................. 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~TTTTTT-",TTTTTTTTTT"-~TITT'T-T,--TTTTTT-"--T"~,",-T-,, ..... " - , . . . . . m ' , , ' - " T - " ......
i
~. 1
CaF2 CALCIUM FLUORIDE
. . . . . . i
.... i . . . . . . . . . .
10 ..............................................................................................................................................
/ " /
i. . . . . . . .. . . . . . .. . . . .. . . . . . ~'~
j- .......
/ . . . . . . . i
f
1
. m
Q. L z i
CD
/ L
t _
0.1 J
/
z
J : '
13.. /
O r,
/
>
0.01 Z
/ F
/ i,
/
/
0.001 - Z
0.0001
!
i I
25(}0 3000 3500 4000 4500 5000
Temperature, F
66
100~ ............................... [
1 i,
! i-
CbF5 COLUMBIUM FLUORIDE | ~.~
!
i
!
........................... I.
!
,i !t ~.
i
i
i
10 T ........................................................ L::Z:ZZZ::L-Z:Z Z:7
311111111111111111111111ZI
. I.III~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~............................... .............................
=====================================
03
i =...=,
00 ] ....................................................................... 't....................~ .... i.........................
o.
(D
t__
] - - - - - - ii
~
~
. . . . -~ ......................... 4..................
i J
~
i i
.......................
(D
t,.=, 5-- ' .........
. . . .
~
I ' .~- i
................................... t................................... t ......................................................T..................................................
J - i
t__ .......... ~........................................... , .......................................... ~.......................................................... ..:..............................................
0 .... i ..... i i i
>03 ~ I /i i !
I ..............................................
. . . . . . . . .
::::::::::::::::::::::::::::::::::::::::
::=:=-, !
,'
S i
'i........................................................................................................................
~, - ~ . . . .. .. . . .. . ,L . . . .......... . . . . .......... .
1
~J ...............................
............................... ~s ........................
................................
1
-F . . . . . . . . i. . . . . . . . . . . . . . .
J_ ............................................. .,~ ...........
I z
i i : '" "
J 9 .../___" ............................... l ............................................ ! ..................................................................
! .............................................
- ~.-I ........................ --4 .................................. '.,............................................. ~..................................................................,..".............................................................
! :: i ! .-"
i
9 1 ..,
0.1 ~
150 200 250 300 350 400 450
Temperature, F
67
89
.4 'eJn],eJedLtJel
009 I. 0017 I. 00~ L 000 L 008 009 0017 00~
! ! !
I i i i 180-~ i-
..................................................... t' ....................................................... ~ ................................................... t'
:::::::::...'--"'-.....--'-.::":.':.'::::-':.:
:.- ......................................4,
iiiiiiiiiiiiiiiiiiiiiiiiiiii;,/iiiiiiiiiiil:
tI
.........................
!i!']!!:'-"!:']E.:.-i!!!!!'-.--!:'-ii! 6 H LULU LZ" Ls = e ! s d L iiiiiiiiiiiiiii~ii::i~::--i!~i~ iiE~--::.-Ei--~--'.:'-"-~-~-..
/
ecl>l s = e!sd L
......................................
~ ;............................. 4 J ~ ~ II/ZZZZZZ[-
T.Z."IZZZZ:Z~. ..............i .................................................
i ................................................
~.............................
I-
...... ~...........................
..................... "r~- s I.
1.000"0 "13
i i 0
'='1
-13
='I
(I)
1.00"0 f./)
f./)
r...
" I
(I)
"c..=:::::::-.._."-::_'~:'-'--_.-.~. . . . . . . . . . . . . . . . . . . . . . . . . ~-___-='_=-~
1.0"0
m =
J ~- [2_
1.......................
/ /~'o
. . . . . . . . I-
.......~ ...............i .... L .l ................
~__.._~_ . . . . . . . . . . . . . . . . . . . . . .
~...-- .................................... :-: .... F
============================================================================================
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :: : :: ::::::: .... z
ZZ-2ZZd z
..................................... :............................ IAInlIAICIVO PO
........................... -4 ,~
O0 L
1 0 0 ~ l .....i ............ ,
1 ......................... t
i ................. , ...........................................................................................
4! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
' i
1 ................................................................................. i .........................................
t
1 0 J ..................................................
! .9 .................................. T.............................. ". . . . . . . . . . . . . . . . . . . . . . . . . . . .
.......................................................... t ..................... i- . . . . . . . . . . . -'.'.T_~_-Z.'---EZEZ .......
.
J .............................................
~ '
,
t
, .................................
' ...................................................................
. . . .
l ., i i i
. . . . . . . " . . . . . . . . . . . . . . . . . . . . . . . . . T..........................................".................................... ~ ............................................i .........................................................
~ .......................................................
i , i i i i
i i ............. ! ......................................... i ......................................................
i+..................................................~ ! ~ ..............
c~ i i i i i !
. . . . . . . . . . . . . . 4- .................................... i ...................................................... i ................................................. ~,.......................................................... .',........................................................... ~+........................................................
i i i i " i
i i i e ~ i
I i ! ....
1 ~ . . . . . . ..'. . . . . . . . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(!,) - ~ - - - - - - - - - t
~~-----------------Z__4-- ................. i . . . . . . . . . . . . . . . . .
......................... ~~Z-----T__-I-, -----i-.
+ _- .E. .-. . .Z. . Z. . .Z. . .-. . C. . .-. . .:. .:. . .:. ~ Z T"i,.:.........................................
: Z Z : - Z L Z Z Z - Z : : $"i.;Z...........................................
ZZZZ;ZZZ ........
J ........................... I !
13_
~ - ~ - - - - - ' ~ - - " - - - ~ - - i "~ . . . . . . . . i................ t ................................ i ............................................i ......................................
0
......................................... ~ - ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ---'+ ....................... "i"......................................... I .................................................... ~ .........................................
>
t . . . . . t. . .
-Sv . . . . . .
d ' . . . . .
i' . . . . .
i' .
'.................
I I
!
i t
- . . . . . . . . 4.. ..............
! i i i i
X i i i i i
i ! i i i i
O . 1 ................................. i ........................... l .............................. ~................................. ~ .............................................~...................................................
~................................................
................................. T ...................................... T .................................................... ; ........................................................ : ...................................................
- ': ,.". i-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . "~......................................... ; ...................................................... j ..............................................
i
...................................
l ............................... ! ....................................... .i"............................................................................................................................................................
l .................................................
i i i i
t i .....................................................
!
t ............................ o. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ...............................................
.....................................................
i
t i '
t .............................................................. 1 psia = 6.895 kPa
i
i 1 psia = 51.71 mm Hg
i i. . . . . . . . . . . . . . . . . . . . . . . . .
! i i
i
i !
!
i
!
i
i i
i I
0.01 I I i
1100 1200 1300 1400 1500 1600 1700 1800
Temperature, F
69
1 00 t t t I --
! I
--
'
CdF2 CADMIUM FLUORIDE
10
.-a
cn
Q
!E
3
cn
cn 1
2 I ......
..
L / .
/
5
Q
....... . ...
3 ...........
/ -.
0.1 ---UP- 4 .
.
. -....
...........................
- - ............ ! .................................................
'El
' - .
-- . ...... ......
/ I
......
, psia = 6,895 kPa
/ +. j 1 psia = 51.71 mrn Hg
I .
I
0.01 I
2000 2200 2400 2600 2800 3000 3:
Temperature, F
100~ ......... ,
] i i i
..._~
.... ,, ,~
...................................... | {
]yyi~.yyyT-y7 .......................................... i
i
i !I
!
.................................... ~. ........................ lrt
.... 1 ......... l I
..................... i i iI
----~-~--ff
r. . . . . .............
1' - l - -................................................ .........
i
~.
~.................... if .........................................
................................]~.............................
r ........................ ......................... ~
~ ~
................................. i .............................
. . . . . . . . . . . ,.:........................ . . . . . . . . . . . . . .
/ ! ! i i ! ~ i i
Q,II
~, ~ - - - - - , ................... i ..................... . ............................. i ....................................... i .........~ ....................... i, ................................................ |, ...........................................
Q. 9 | | i " i i
I ...........................................
L ............. ~ ................ L..................... i.............................~ . .......................................
.[........................................i ..........................................
Ii l i
'
I t
i i
i
i
7i i
i
i
i
i
CD I i ! ,
i
i
,i / ii i
i
!i
1 ~ _ . _ _ _ ".F.-_::-_--~_~---_-.q-----_--:-_-:--::-::~--_ i ..... ....
!../-..
....................
i i i
=======================================================================================================================================================~
............................................. t ........................................... i: . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(D
i.__
i i i i
i i
O. 1 ~ - , -. + ~. ~..................................................................
-i ....... i i i , ,
0 . 0 1 I I I I I
700 800 900 1000 11 O0 1200 1300 1400 1500
Temperature, F
71
100 1 I -_/...
I I I- -.*--..I-------
i - - -1
I
3-.--
t--
-
.
----- \
I
10 ..
a
--
--
I ...
w.............. ..............
.-(d
V)
... . ...
Q .
@
3
V)
ul 1 /
2
a. ----"
.-
......
5
Q
I
3 -
0.1 .......
-
--a
-
-- ........ ....
...... .
0.01 i I !
1800 2000 2200 2400 2600 2800 3000
Temperature, F
100. , z . . . .
,,,1 .......
J u 7 ....................................
,. . . . . . . . .
t j ,. . . . .
i
r. . . . . "--I . . . . . . . . .
I t. . . . . . . . . . . . . . . . .
i
"i . . . . . . . . . . . . . . . . . . . . . . . . . "+----7"
+ J ~ l ......... ! ...................
" I ~
~ - - '~ ~ + ...............
................ - +t .. ... .. . .. ... .. . .. ... .. . .. .. +......................... .............................
+.,. . . . . . . . . . . . 9. . . . . . . . . . . . - . ~ .....................
~................................ +~.............................
...........................................~
~ ~ .........
..... ~~ ....................................
.......................
L . . . . . . . . ~. "~ .................. l. . . . . . . . . . . . . . . . . . . . .
".:. it . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t-'......................................... l~........................................ l~......................................
t.. ............................................
. . . . . .
9.................
" ....................
, ===============================================================================================================================
~. . . . . . . . . . . . . . . . . . . . . . . . .
........
"~.................................. i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ............................................" .............................................~.......................................... ': . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
s - ~ " .................... ~....................... ~.................................. +................................... ".;......................................... .';.............................................. -: ............................................. 4 ...........................................
0 1 i i 1 i i 1 i
. . . . ~ . . . . . . . . . . . . . . . . . . . . . *.. . . . . . . . . . . . . . . . . . . . . T............................. ";,.................................. t ............................................
f ..............................................
+.............................................
.:. i ............................................
I ~ i i i i i i
>
. ............ ~ ..........................
/i i
i
i
i
"
i
"
i
i ':
i
i
i
i
- I ~I i ~+ .......... :+ ..............i+...............................
i
!
i
!
:
~
i
:
i i
-'..
i I i i i
0.01
I I I I I
-230 -220 -210 -200 -190 -180 -170 -160 -150 -140
Temperature, F
73
Vapor Pressure, psia
o __._1.
b o o
o b .o o o
0 o
IIII
I I I
oI
fJ"l I I I I I IIIII I I I I I
rb
0 I I Iiiii i ~
o
I 1 1 0
t Ii i ,,, ! ~o
0.)
g- i
l, liiii
ii.iiiil. .!!,*i. .!ii..II
'i '
Ii I I i
"-t~- i i.i
~ o
l!i!!il i i,,il!iil i lI,,i,,i iill
[]]iii' "i i!"
~o-
' Ii! i'i ..... !ii
c_,
mP~- ..... it
41,,,, ............... i
, 11
,,-- i:i 'i
!+''''!
, i i
il
i i... +',i! +i ' '
i '+ +' ....
ii
-i-~-l-i, "1-ITi.;I
ititi
it+if
i iIii Ii' I li i+I J :i'! ~I ,. ,~,i,i ii' 1 ii!il
,, , , , , , ,
,. . I t I ~ +i, :iii+i+i+
, , ,
, ~i , , ,i., '-i ,i
. . . . ' + , +,~,
! , , , 1! i I,e ,i ~9 I :. . . , . . I!i,I I ., . . I . .I, . . '-'.,,
, , I , ,IIi. i. , . i +
g- I . . . . . li I+ I , I t,.I + ' "
-" "" +, +........... - ' - + ...........+ - " , - P - P ~ , - ++.. . . . . i .......... , -,.~,. + - - - 4 ..... ++.H ......i : J : : + . ~ ! ......................-+'.............l .......i ......I + : H H ! ...............-+.:- .h-+.-
.-o-.o la, + + i ++! i+ , I ! lilt+ + + +J~s~+z i z +~+i+i ............-T~-I [ ....FH4.
+ iiit
-.-. Ii + i +ill ++ + ' ~1 i i i i i++l,+ i I Ii'!++ ' " !
m + i+ + + i "l+ I+ , i i ' i'ili i ; [~ + l , it ++it
,. , ,.,+, 9 " " "
i+. ! i i-I+-I, ' ' ' : I "1!,i, ,, , , i
II II "" ' i " ' :' ++ Il + ,il ++ , ; + I :''" I i' ~ ! l~'["l llill
u.z'.o', +, ~ + +++, +, l+~si+ + ~ I I,illi ~ I i i ' i iitll
I l k ....+-r.!J.l
ril!l/
: : |
+'"+++~r ' .m----p--lllll,
l ,l i!' l+! illllll
i:: l + ill" ...... . . . . . . li ....i, ,,+iN:,: i:l i l:,l ,,l,i
' 9 .............l+'l '- i,,:,llll,
l l !,,l' l lli,ll,.
. i, liI l ! ,!'i 'l ....................
+'i ll'!ll k
ii' , I , i,! I: I ll:iI'' i i , i ' I i i !I I' '
g_
o !I i+..."iii
i +! i ............. i -i+
i i~il, i
I,' ii ill
i ii Ii
+i l--l-i!li!!
i i I !iiii i
Ii I, !+!ii
ii..-+i
l' I-!---!-ii-ili
i ' i iili' + J :
l, :i ii:-'li!
i : i i ;i ii !i "i i",i .'.,"
i! !' "! '' i" :+i
ii,ii +: i" ii i'i,'l:
i i+iii I." i9 i ii ;i
i!!,i li i' ii ,I
-,'-+~+I
! ~ liiii ! ! i I -': i: i i i i'-iii I + i iii,i I i "i' i ' i i iii
! iiii' i i i , ili II , i i ;i',!' i I i ii~!! ' i ,!i i , .
, ,, ,i, ' ; , ,,, ,, J i , ,i,,~ , : ,,,+~ i ! ,i,,i,
It !~ili~iit=,.:
+i ii i+
+l ii ii i!.!! ii i 9 ~i i!iiiii
it!i.. iI ii i+li~i
i itli: I: !l i~
: t !iii
!.i-'i i
01 ii/
0
Vapor Pressure, psia
O
O ,,,,.i,
O 0
O CI
2~ 'I
0
0 iii!
!
i
i,ii i:, " I !- T
ili! ' I -r
i ii
t----i ....-+-+,-i m
0 ii
I ~!
<>i-- 84
I
ii ,
s : l m i
'
i
iii
i i ~i ~! !
i 9 : : : : :
i i i
0 !
~ i
!
i
1
i i, i'i"i'i
i!,! i
~ii i I i i~i o
--I 'i i
'' ii i
iiil
i !
I i
~..,_~,_.,,.,......,
ii E2
9 o . |
i..... __i .... _.i .__i__i.'....,~...i
i i I'I'1 I
i i ' I i i. . .i. "i i "'"iii
i 9 i ill, i i ! , i i Iii
i Ii!i c-' I
~ ~I ~I i~ ili
i i i i,-
,i!!i i\ i i i I i I~i
l-" , ! \ ~ i i !iii!
i....'~..~......".--~-~...-:.-.'.'...-i'.
'i
§....
,i...... "..i
i
L.!_.LIi,
ilili
i i iii
i ! i! ~i i!i
i i i ii.' i i IX i i i ili
"Ti t ! ::
,i! i I\i i i ~ii
i i\i ii !ii
iiili i i X,.' i! !~
! i ! !i i i i\ i! !i! i i
' i
t ....... ~i........i i " i " i! , ] i i " " ! i
.
~i !i i ii ii ! ~i \ i ~ i! i ii ' iI ii ii ,", !"l "
-o"o ~ i i il i\! i iil I i s
_~.__. .... i ,.. : il i~i !!i I i I i
lit ii)
II II
iilii ! i\iiii i , !
iiili i . i i ~ i l i 9
m ..................i._i....i...i-...................~ .....................
+ ........
: .....+......L-..~..-I-.,:
.......................
,:...........~..........
4m-i.--~.-~- 4.-I-i .......................
~ ....
i
i--
~ i
__.ii,.--4. ....
I
~
i llii , ~ : , i lxi,~, ~ , ! i ,
Z i i Zii Z i Zili i ! S i ~\ii t i i i i
lit
i i i iii i ,,I', , , , ' , ,,.', , , , ' ,
E i i ! iii .- i i l i i i i i i i ! i H \ i I i i I
...........i........ I......I...."-....L..I. ....................... ~ .......... i .......... i ................. "~..... ' ..... !...-i.4 .................... ............. 4 ........ 4--~ ..... ~4.4-.'-..~ ........... ~. i .,. .! i.... .
i , ii i
!
ii9 | i
:
i: I: !: ~'i , i~iI! ! !
\ %. i! i~ i| i:
i i i i! i' .t, . . . I i "' ii ii Iiiii '~ I \ ,i ,i ! ',
!
' ' -'- ' i '-~ iI--- ,: i
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,i , , i ! , i! , i ! i i \ ,i , , ,
t
i i
: '
i i , ii , ,i!i ~i i, ,I ~t iii i iii \ !
i
! i
!' | i ~ ~, , ~ ! l !~!! i , 1 ! I,
' i
O
1 O0 == i ................................. i i i i [ i
m ' ~ . 9 , [...........................I.............................t................... r...............................................................................
1.........................................
i......................................
....................~......................................................................1............................! ..........................
- . . . . -I.. .................................................................. .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4- . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . .................................................. i. . . . . . . . . . . . . . . . .
10
, , m
{/)
. ...........................................................................................................................................................
(D L I
5.. l
............................ !
0~
i
(D
I,==
a_
L _
0
Q.
>
.............................. !
................................. i ........................................................................ b. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
iii iiii Z
/ ..............................!..............................i ...........................................................
t
iI "l ~
'I [
;
[
i i
0.1 I I I I I I
-120 -1 O0 -80 -60 -40 -20 0 20 40 60 80
Temperature, F
?6
10000 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
....
F . . . . ~ i
1 O0
I~-'=.-:Z--:_-_-~_~__.,
t - - - - - ' t - - - - P . . . . . . . t - - - - 7 ~ t
..~_.-_-~_--'-..-..-..I'-':'I - ......
-=9
4 .........................
!
~. ................................
l
.+. . . . . . . . . . . . . . . . . . . . . . .
I
..........................
i
, .... +
. . . . . . . . . + ....... t
i i +
10
=•=L--------_4_
. . . .
I
.; . . . . . . . . . . . .
! I
-~:~:~::~:~~~-~:i~~:~i~:~::i::::~::::::::::::::::::::::::::::::::::::::::!!iiiii!ii~!iiiii~
-L.J.. .......... 4 9 -- $ " "
|/ ............ ~. . . . . . . . . . . . . +. . . . . . . . . . . . . . . . . . . . . . . . T .................................. i ................................. i
"
F I r;. [ i9
. . . . -'----t- . . . . . . . . . . . . . . . ". . . . . . . . . . . ". . . . . . . . . . . . . . .i . . . . . . . . . . . . . . . . .i ................................ +:. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~,
| I '
-~ :
.... " l
,
!
+: +;
................................................... / J + ! +
. m
1 ................ !
t
......... 1............... t.............. Ii............... ~,
! ! ..... ]
s~_ T
n 0.01
! I I i ,
.L. . . . . . . . . . . + . . . . . . . ,i,
O ,L . . . . . . . . . . . . . .
_=
~. .................
! :
c~ +... . . . . . . . . . .
|
+ ..................
!
4
i
i.."
9. . . . . . . . . . . . ~ .................... 4.
>
0.001
,
i
i
! | t r ~ ! 9 ' "~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~ ~ i + L
. i, :, +. . . . . . . . . . . . + '
0.0001
i ....
2 ...................., ,i..................................
it................ '+ +, i i 1
+t + .......................:;--,_..;------__:--_.=:--.u===::+..
~,. . . . . . . . . . . . ~ .................. ::::::::::::::::::::::::::::
I
9
:
.
l |
9 :
i
{.............................+.......................... +
+. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4 ............................... 4
i I ~ l
l ! i !
1 E-05
I E-06 ................................................................
:===== .............~.................... + ...........................,L...............................j ................ I p s i a = 51.71 m m Hg
Temperature, F
77
1000
1O0
i~i~iii~ii~i ill_L______ !
10 ~.!
./
/
/
/
/ f
-- L:::
-- zi..
Q. J
/
(D
I,=.
............................... I i................. --.
0.1
(D ,j
13. | 1
/
......................................... i .......................................... l ........................................
0
Q.
> 0.01
/ ..........................
i
:t' ......................................................................
!
I
~.:-:" ................................
0.001
/ ii12-:! .............................................
i ...................1....................................
9 .'j
/
1 . . . . . . . . . . . . . . . . . . . . . . .
1 I
0.0001
/ 7
.. i
,
- -...--.--.---4-c--
!
! .......
...........
..........
=~:=-----==.===---::==:::t;il!' 1 psia = 6.895 kPa
/ 'i r .....
i iiiiil1, ..... :
1 !
1 E-05 i I I I
-200 -1 O0 0 1 O0 200 300 400 500 600 700
Temperature, F
78
10000~ 7
......................,
II::77777-:Z__LZZI_J'i .....................
,
] ..........................
,
r
i i i i i i i i i i i i i i i i _i i ti __i-
! I !
i "
'I
i f
! i |
[ !
i i
i l
i............ ; .' ! i
1
I i
, l i ,. ............................. .,.! ., ...................................... .,
z t
i i ! i Ji
I i li i
i
. . . . t
c~
!
................ t
1
.
L_
...................... 4......................
.... T [ i 1
n
i t .................................... ,
o i
, /I ! 9
c~
10 t.............. ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . a . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............................. 4 .
>
,r . . . . . . . . ~ ........................ ,. ......................... 4 ................................... .,..
..................... , ................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . ~
i i
[. . . . . . . . . . . . . . . . . . . . . . . z. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -T' .................... '
t !
i
,s........................ 4
i i
.i
:L ...................... =_-i .................... ::::::::::::::::::::::::::::::::::::::::
i !..........................
i
J:_
I" ! f k .......................+.........................f ............... f ....
T ! ~ ~ . . . . . . . . . . . . . . . . . ",..................... T. . . . . . . . . . . . - r ....
I i
t-- ..................................... ..............................................................
9 1 psia = 6.895 kPa
i
i [ ............................................ 1 psia = 51.71 mm Hg
i ti!!!!!
I I l i i
E 9 } "
! i z ! i !
0.1 'I I I I I I
-1 O0 -50 0 50 1 O0 150 200 250 300 350 400
Temperature, F
79
10000-
t I i T
!
!
CI2 CHLORINE .....
1000 f
J
fJ
J
=,,~=
oo
lb. 1 O0 -~
x
(D J
L_ f
/
. . . . . . . . . . .
03
03
(D
!,-- /
J
13_
t._
0
lb. 10
> /
/
7
L Z
/
I
i
/
.......................... , ........................................... ! ...............................................................
111111111111111111111111111111111 iiiiii ii
"~ I IIIIIIIIIIIIIIIIIIIIZIIIII iii i
f
0,1- I
J
I I
-150 -1 O0 -50 0 50 1 O0 1 50 200 250 300
Temperature, F
80
I.- .................. t ........................ t L
.m. I
..................................................................... "r . . . . . . . . . . . . . . . . . .
........................ 4. .......................... ..!-. . . . . . . . . . . . . . . . . . . .
/ ........; ;;Z;Z ; ;I F--~
_1 ........iiiiiiiiiiiiiiiiiii CI20 CHLORINE MONOXIDE ]
1 ii 1 i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
..........................................
I
_ ______!
|
....................... I. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
............................ T
J- fl
J
t
i
i !
!!!1!!!!!
10- ) ~ ~
!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!!i
I ................................ t ..................... "!. . . . . . . . . . . . .
i F ............................. ..i. . . . . . . . . . . . . . . . . . . . . . . . . . .!.". . . . . . . . . . . . . . . . . . . . . . . . . ..e. . . . . . . . . . . . . . . . . . . . .
i / i
a:I
.m,i
!
I=l.
................... ..................... ~ .~ ............................. ; ................ ..~.
(D i ! i ! ' 7 i .......................................
i.................................................................................
I
! , i i 1
4_ . ' ,) : . i i .
I" .......................... ? ........................... ~'................................... ) ...............................
(1) - ) ....................:::::::::::::::::::::::::::::::::::::::::::::::::::::::
%--
~ ! ~ L .... ~..
13_
O
........................................ . . . . . . . r
> ,t"
i ': / i
- i
~. I i rI !
!
! ~
. . . . . . . . . . . . . . . . . . . . . . . . . .
1
/ t
i i !
/ i
i i i
~,-~
- ............ ......................... )............................, ...............................t ........................................
~ .9. . . . . . . . . . . . . . . . . . . .
~.....................................
~.......................
i ..........................................
+..................................
}" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................. .~...................................... 'i ....................................... .i . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- ....................................,I...............
, 4 L~............................ T...............................
t " " i
1 i ii
i ...................... i- .................................
, i '
i ! i '
0.01
, ) ! , 'i ! !
i I I I
-160 -140 -120 -100 -80 -60 -40 -20 0 20 40
Temperature, F
81
1 O0
.... i .................................................................................................
II
lo
............................................................................................
m i
(D
:3
(/)
(D
IL_
s
I,.., .........7i~ .....~7 - - ~ !.............................................
0 ]
Q. .....1,1.,21
>
i
t i
1 I
0.1 ..................................................................
_IIIIIIIIIIIZIII
...................................................................... i ....................................................................
z ~
.................................................. + ..............................
- i
.
! i ,
!
i i
0.01 I
~ .
i I I
-50 0 50 1 O0 1 50 200
Temperature, F
82
...... ~ ................................... ~'_ . . . . . . . . . . . . . . . . . . . . .
u:: . . . . ;::::
. .::::~. .
. . . . . . . . . . . . .
::::::::::::::::::::::::::::::::::::::
:;;;;;;;;;;;;;;;;;;:
Co
. . . . .
COBALT
. . . . . .
-__---__Z~[
........... "~
!ZZ_C_-Z_-_--_;-ZZ;[ZZ;Z;ZZZZZZ;-Z-~ZZZ;ZZZZ;_Z~-~;
i, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~:TZZE:Z::Z:Z"::'::::::'.'.;..~-T...-7.-.'.'.
10 ...................................................... i=============== :: = = = - = = = - - i = : = = = = = = = = = - - = = =
l:--c::..~--~=-:--:---::::::::i::::::::::::::::::::::::::::::..--~::....:::::..--~:..-~...---~!~..~.-x~..-......-:::-.....-c...-::.---.-.-----~.-:
~
~! .................................................... t "...................................................
i
i
........................................... [ :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
2.
| !
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....................... ~....................................... .+ :-_-===-:=::-==: ..... =.=.-_:t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . !:-~:,_-_: : !! !!!!!!!!!!!!7!!!~!7777777-:!~
........................................................................................................................................................................................................................... + ...................................................... +-". . . . . . . . . . . . . . . . . . . . . . . . . . . . . ............ 1301.
100 , ............................ , .................... ,_ _ _ ~ ........ ~ . . . . . . . , ........... ......................... +. . . . . . . . . . . . . . + ................................................
10
. . . . . . . . . . . . . . . . . .
. m
co i ~.............................................................................................. ?i ...................................."
Q.
t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
t,... i
i
t~ _ _ - ................. ::::::::::::::::::::::::::::::::::::::::::::::
! / ...........................................................................
I...........................
13_
...............
i.................... .......................
/ -~....................:......................~..................
................ I....... i....................
0
0.. ...................................................... ~ i i !ZZZZ:IZZZZ I.s
>
~
0 . 1 ~ ZTZZ2: __, ......
222Z:;Z;;II;IIZ21;
; :: ;;12;1111222
+
.... ,=; ; Z2 /_222......I::IZ- 222Z:222Z22;Z=222Z;22~
.................................... II-22"21.-2212ZITs
l ] . ,
I i ] i i : i :
................................
i- i ! i ~ " " i
....... : ............... i....................... ........................................................
,'. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,..................................
Temperature, F
90
100,
-Ii3111111i i iiiiiiii~ii iiillli..........
i i i!i !illi,...... J i i
. i ..................................................... i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- - - ~ ....................................................................................................i .......................................................
] iiiii.........
iiiiiiiiiiiiiiiiiii_i......................" i
!
................................................... ,
!
....................
$ ....................................................... ;
i
= m
!
t ................................................................
i
~
c~ !
~ ................................................. .
B~
i !
(1) 1 9
i i
i:
a.
0
c~
>
1 i
!
_1 i
olt .................. i . . . .
'i . . . .
!
0.01 I
1200 1400 1600 18OO 2000 2200 2400
Temperature, F
91
1 O0 , , ,t ........................... ~ + +
l I !~iiiii~::iiiiiiiiiii~iiiii iiii! .~
i i
10
Iill
~.............
ii i ~ iii :~:i
4 ................... ~.........................
L-_E_--_-_-_-~:iZZ-T--C:
rl -iiiiii .....iiii -ii/i ~iii-iiiiii --/i
A
0
Q.
> i" ............................................... 1 ...............................
/
.......................... "+ .................................... l ......................................................................................................
+ + + + . . . . . . . . . .
1 ,
i i
0.1
............................:.................................!"t.....................................
............................................................................... +....................................... i .........................................
................................................................................................................
::::::::::::::::::::::::::::::::::::
t
............................ T ......................................................................................................
................................................... :::::::::::::::::::::::::::::::::::::::::::::::::::::
........................... I ...........................................
i i + :
9 i
0.011 ' I i ' I t i
1300 1400 1500 1600 1700 1800 1 900 2000 21 O0 2200 2300
Temperature, F
92
Temperature, F
176
cl ' a J n i < e J a d w a /
00~ 000~ 00~i' 00017 00~8 0008 O0~IE 000~ 00~; I.
I I I 1 80-::1I.
, , ~'- ......... !
8H uJuJ L/_"L~I = e ! s d I. 31.
ed)l ~6g'9 = e!~Id i i 1
...............................
'r__::::_:: ..... - ........ i
- L ...... -
- /
_ _ ,- ,/
i
<
Ill
1.000"0 "0
0
"--ll
/ J LJ "0
=-,I
(D
/ : ':'-'--:.... '::" . . . . . . . . . . . . . . . . - ~00"0 f./1
/ C/'i
/
="'ll
/
f . . . .
(O
"D
................... t ..~ ~ ~
~ 1.0"0 f.#l
.,mi
Ill
7 ....... ~......... ,- ,,~,,. i: , ~ t ...... : :,- ,. , 7
.......................................... i ..... r ......................r j i ........... r .............................................. I.'o
...... = !
- -- - , .... , , ~ ~ .............. ,,, . . . . . . ....... l . . . . .. . . . ....... i ....
,'," ~ ' ,/-,,, ~ ..... ~ ..... ~ ,,,,,,,,,,, :, ..... : ,,,,,, . . . . -i,i,; ;',:', ', '~. .
- - _,,, . . . . . . . . = . . . . . . .
l , -. . . . . . . . . . . . . . . . . . . . . . . . -OL
"- i ~ " ~ I:l=:lddO0 no
. . . . . . . . . . . . . .
L ,I . . . . . . . . . . . .
-~ . .
...... - ,. O0 L
1 O0
.... !. 1 ,.
I I ,,
1 ..........
10- I ..... !
............................ [ .....................~ i i i ii----ii-]
i
tO
n
J i
cz. t
m,
r~
co
13_ E !
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....................................q
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to ,[..................................................
i
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iiiiiiiiiiiiii::~
ii
i. i
I
71
_ ! 9 .!
t i
- ! !
i I
1 psia = 6.895 k P a ~
1 psia = 51.71 m m H g l
f
1
1 i
0.01 - i I
1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F
95
1 O0 I
, f
CuCI C U P R O U S CHLORIDE
. . . . . . , .............. ,w._~ . . . . . ,
I I IIII
I IIIII III I1 IIIIIIIII . . . . . . . m
I I1 I I II IIIIIIII. . . . IIIIII IIIIIIIm
~ f
IIIIIIIII IIII " i
II IIII II I III IIIII1.111111_]1 IIII m
:!
llllll Ilill llllllllllll liB ~ l lll
. . . . y
= m
03
1
Q~ J
L _
' l
//
r~
~ . J . .
r~
Q~
L_
13_
t.__
0
Q. 0.1
> /
I
. . . . . . . .
I
i
I
/
i
/
... ........................ . _
u.ul ~ ~ 9 . . . . . . . = . . . . . . . . . . . . . . . . . . . . ,
-! 9
, i iii_ 9
- / . . . . . . . . . . . . . . . , .......
. . . . . . . . . . . I
l
i
/
-! ] I . . . . . . =l
/
,=
0.001 I I
800 1000 1200 14OO 1600 1800 2000 2200 2400 2600 2800
Temperature, F
96
1 O0 . . . . . . . . ! ................... i ....
_: . . . . . . . i , ; .............
10 ~
mm
(D
c~
(D
(D
G.
0
O. ..... L ~ ! /
>
9 I~ i
dv ~, [
, LI
i I
i i !
! ! i
i i
1 i ,
!, !
0.01 1 l t I I I I
550 600 650 700 750 800 850 900 950 1000
Temperature, F
97
B6
..I 'eJnJ, e J a d L u e l
009~ 00~ 00~ 000;~ 0 0 8 I. 0 0 9 I. 0017 L 00~ L 0 0 0 I.
I ! ! ! I. I
'i
'~o'o
L i
6 H uJuJ LZ" LcJ = g!sd I.
gd)l ~6g'9 = g!sd L
9 i
/
<
/ "0
0
/
J .
"0
Y c-.
/. (D
"0
--i ":
o~
m m
iiiiiiiiiiii~. . . . i i i ./
.......................... iiiiiii / !iiiii . . . .
01.
i
L
3CIICi01 1::13ddO0 InO
.............. 1,
i ................l
i ...... ,.......................
i
i ~ t I I
O0 L
100-
!!
10
. B
(1)
L.,
:3
(D
0..
0
Q.
>
0.1
T T i
ii
!
i
1 I
o.oii I l t
-I O0 -80 -(~0 lO -20 20 40 60 80
Temperature, F
99
1000 I t i
D2 DEUTERIUM
j/
/
1 O0
/
, m
Q.
(1)
::3
/
Z . ~ , ..
(D
n
0
Q.
>
1 mF,
/
,21
/
/
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
1 I
-4'}0 -425 -420 -415 -410 -405 -400 -395 -390
Temperature, F
i00
1 0 0 0 0 ~
1000=
100=_
i
(/) 1
i m
C).
F.
(D
i
(/)
If) 10= ;
0 !"
C).
> [ i
1
' i
I |
..... t" . . . . . . . . . . . . . . . -,--!. . . . . . . . . . . . . . .
0.1
i i
0.01
t[ T
i
0 1 O0 200 300 400 500 600 700
Temperature, F
101
| :=~_- | ........................................................................................
] - _ Eu EUROPIUM
10~ ...........
| . . . . . . | . . . . . . . . . . . . . . . . . . . --
i .....
t !
0.1~
....... , ............... ....... ...., ~ - - ~ !-~-7-:.-..---.!-7Z:~---777~!~-E-!--!.:2!!7!!2!7-:.:!!77!777!!7:!!!!~:!-~..~7-!!!~:!!
--I ..... t - ~ ' . ~ / .........................................................................................................................................
1 ........ I / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
03
. m
Q. 0.01 -
(D
t__
03
03 0.001
(D
L__
n _
t__
O
Q. 0.0001 :::'--._:'.'~--"_-2~.
"..-.'._..---
z:,T-::.-::::::'-:.--...~::.-::::::::.~:::
>
...............................................
..............................................
1E-06- ~.-...:~::::..::~'~:`~:`~.:~..-~.:::::::::::::::::~.-.:.-~.:z::::::~.~T.~-.-~.::::.-:~-..-..~...-.~..:z:::~:..-.:.....---~:~:.~:..-:~::::::::~".~:::~.~:.~..-.:::::::::::
1 psia = 6 . 8 9 5 k P a
1E-07~ 1 psia = 51.71 m m H g . . . . . . . . . . . . . . . . . . . . . . . .
iiiiiiiiiiiiiiiiiiiiiiiiiiii
I I
500 1000 1500 2000 2500 3000
Temperature, F
102
1 O0 .................................
. . . . .
',......................4.......................~...........
I
...............................................................
i
Ii
,o!
1
i ! . <
- i ==================================
:::::::::::::::
::::::::::::::::::::
- - = . . . . . . - ...... ' ................... ,............................... i ........................ i ........................... i ................................ :
(I)
iiiiii
i-- ii]iiiiiiiii-
ii-_liiiiiiiiiiiii
9 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
(I)
13_
>
0.1 / _
iii~i~iii:iiiiiii ii i~ii~iiiiii,,~
ilJi~is L!/
s I LII~I Z ......
! /L
.............................................................................. i..............................
t
I
.................. ~ ......................................
9 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg i
............................ I .............................................. .... t .................................
I I
j J I i
i
t , i J
0.01 i i
!
t 1 I I I
-330 -320 -310 -300 -290 -280 -270 -260 -250 -240 -230 -220
Temperature, F
104
~OI
_.4 'eJnleJeduJej.
0 0 ( )cj OOCj~, 000~ 00s 0008 O0s
1i 'i I ~000"0
.............................. edH 969'9 = emd ~ ............................ $ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . | _..i . . . . . . . I-
T''___~_-----.T--LT".' .......................... J....................................... :'_:":. . . . . . . . . . . . . . . . . . ..-r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
...................................................... ~............................................................ r ....................................... 7- ......................................
: ~ooo
! , i
..................................................................... ........................................................................i .................. . L
i 1 ............................... 7 ................................. , . . . . . . . . . . .
! i i l
.................................................................... ~ ..................................................................... 4 ......................................................... L ................................................ ~ . . . . . . . . . . . . . . . . . . . . . .
................................................................... ~,........................................................................ ~ .............................................. i ............................... ,. . . . . . . . . . . . . . .
............................................................. ~ .............................................................
1 ..................................... i................................................................ =
................................................................
F ..................................................................... ~ ........................................... i..................................... i. . . . . . . . . . . . . -
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: .....= _ - ~ ~ _ - - f ~ z = m - ~ L - - - - - - ; ~0.0
' ' ' ~ i <
................................................
9 L............................................................ t ................................. !. . . . . ~_. . . . ~ _ _
~
!. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
: ........................................................
i
..........................................
i /
@. . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
ib. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "O
L i i z i O
I.................................. i~.......................................... ~ .................... ,,___/ . . . . - - --------L
L -O
-"ll
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~ 9........................................... . . . . . . . . . . . . .
i ....... ....... ....... ..... .. ..... .. ..... .. ..... .. ..... .. ..... .. ..... .. .... . . . . . . "~ ................................................... J ~ . . . . . . . . . . . . . . .. . . ... . . - - . . . . i:. . . .. . . . . _ _ _=============================================
L
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
, 0
'
:
'
i
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i
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............ i ................................................................................ i ........................................................................ T .......................................................... t .........................
i i i i 0
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...................................................................................... -.ii.......................................................................
.................................................................................. il...............................................................................
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.............................................................................! ............................................................................~.:....ZL1..Z.-::L-.Z...~1Z::-.ZZZ:Z:Z:::..7Z~ZZZZ:::--2.-2..-21T2-~Z:L-.-..2L~:27I-ZZ.------2..--..2 ...........................__2-
iiiiiiiiiEiiii~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::~:::::~!~.:::::::::.--==~=:=::::=::=:F:: = : : : : : = : : ..... ----- ..... : i = - - = - = - ' ~ "
........................................................... ~.. ............ :::::::::::::::::::::::::::::::::::::::::::::::::::::::: ........ ~'. ........................................... 7i; ................................ :....-~..~.-~--~:~'" . - " 7 " - - - ' ~ "
j L
L 1 i I
............................
s _..~.. _
, ...................................................
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t ......................................................
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..................................... :! ......................................................... ;
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...............................................
....................... ii~iiiiiiiiiiiiii~iiiiiii~!iiii~
............................................................... .i il i~~~~~_..................... _ ................
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....................... ~ ....................................... 4 ! -" _L
7_..---"" _.--L.T.,. ......................... ~ ....................................................... 4 i .~. ....................................... ] ] I ] I ] 7 1 T ~ T ~ I ~ L - _ ~ Z I ] : : L
i
i ! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!
................................................. ~.....................................................................~.................................... []]]]]]]]]- =
T......................................................... NOldl e_.-I ILZ]]7]TLLZE
, i 11111111111111][[11117111111;11[[i[[11_
i_ 9 [, . . . . . . . . . . ::::::::::::::::::::::::::::::::::::::
..... l '; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T ........ --7"- :::: .................... :::::: :: i--
................. ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .I . . . . . . . . . = = : : ...........F O 0 I.
100_
, E
|
. . . . . . . . . . l". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
FeC505 IRON P E N T A C A R B O N Y L
,i
............................................................... 1 ...............................................
10
J
.
m3
m
co
Q.
(D
K..
co 1
(D
&,.,
. fwiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill
5.--
O
c~ Z
>
/
i .....................................................................I ..............................................................
i ".......................................................... '!.............................................
i
1
0.01 I I I I
0 50 100 150 200 250
Temperature, F
106
100] "
............... ,t................................ ,j' +, '"
========================================
~1+ ___________ I
10 i....................................................i
..........................................
rn
13.
(D
i.__
c}
co
co
(D
Ik..,
0
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>
i i i i i
==================================================
2 4 il;~T"- - ~ ~ ~ i i i i ~ i ~~~i~~~~i~~~~~~~~~~i~i~~~~~~~~~i[~~~~~~~~~~~~~i~i~~i~~~2~~~
/ ..........
.................................................
4/
i7 i................................
+ !
[i ................................1""'-
[ .........................................................................= = = ~ = "
+"
.........................................
.......................
! 9 i i
, ! !
0.1 i i . ; ,
I I I I
1200 1300 1400 1500 1600 1700 1800 1900
Temperature, F
107
100_
i; ................................. -'{ i....................................................................
{ ........................................... ~..................................
................... } ................................................. {. ............................................................................................
- ..................................t I |
I FeCI3 FERRIC C H L O R I D E l i
................. { t
9 i 1 ................................ i
................................... | i
f ~
1
i
10
IT!'_E~222222C
~22-~C2~2
!I~- -~I2;2~222112;2111~22~-~I~2
tO
oo / .........t.................................................
f ......................................................
Q.
~Z_ .................
............!........................................................
!
! .........................................................
........
9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
(1)
I,..
oO
oO
(D
a_ ......... iiiiiiiiiiiiill / : '
I,--
0
C1.
tO
>
~!~ [....................................................
Tk.. p,,osa osa
o ! ~, 7, mm.g .........................................
. . . . . . t" ....................................... } ...... ............................
I I i
I i i
I I ! !
0.01 I 1 I I I I I
350 400 450 500 550 600 650
Temperature, F
108
60I
-I 'eJn],eJeduJ81
00~ L 0 0 0 I. 008 009 00~ 00~
I I I I
I i 80-:1 I.
! I i
........... ~............ . . . . . . .~
i
i i
6 H Lu~ LL' I.cj = e!sd L ...............................................
I
LO-3 I.
edM 968'9 = e!sd L
..... , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
t
.................................................................... !,
t ................................................................... ?'
i I
<
1.000"0 "0
i .......................................................
i , .................................. J, /_[ , 0
"D
(1)
LO0"O o~
[i w i i _,Z__ ,i o~
.................................................................. ~.............................................. ~ ....................................... -4. . . . . . . . . . . . . . . . . . . . .
9
..,................................................................. J. .......... I_L_.....,Z______.
]. ............................................................................................ [
....................................................... .'.,.9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ i--.-. ~.Z. ' "~
I'
".,........................................................... -.". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ................................... -!.: . . . . 7 . . . . . . . . . . . . . . . . . . . i.
i I 1.0"0 "C}
! . , - , . ,,
f,/)
i i
.................................:'~---:-:---:-:-:::: .--:'::':.".'::'::---I
i i ...... ~ i......................................... i:i::i::iii:iiiiii::~_
............................................... ~.................................................~ ...... ,} F--...------------------~---'~.
. . . . . . . . . . . . . . . . . . . . . . . . .
::::::::::::::::::::::::::::::::::::::::::::::::::::. . . . . . . .
............................... , ........................................ .i . . . . . . . . . . . . 7.. .................... !
.................................... ~ .......................................... ..}. . . . .
....................................... ~..~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,.-. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!....................... -':L_ ...............~ ~
............................
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,I F---I .........................~ = ~ - - - i~;~
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1E - 07 .-!I !! : - =~=- ............... ~................ 1 psia = 51.71 mm Hg "i.-]EilEiiEE~-'E::.ii:"
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2000 2500 3000 3500 4000 4500 5000 5500
T e m p e r a t u r e , F
113
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Temperature, F
115
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1 psia = 6.895 kPa
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Temperature, F
116
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119
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r
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Temperature, F
120
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121
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Temperature, F
122
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t ! !
Q. 0.1
>
i i
! !
!
;
i
i
i! i
! !
0.01 .... - 94 .
i
. . . . . . . . . . . . I
I.! !i
! r . ............................................................. j ..............................................
I[
i 84 ~ ....
-- .....................
' ................................ !- 1 psia = 6,895 kPa
!
t
!
! i i
I i i
0.001 i i I I
-50 0 50 1 O0 15O 2OO 250
Temperature, F
125
1000
u J
1
L. . . . . . . . .
H2 HYDROGEN ! t
i
i
J
/
1 O0 /
........... -
.m /
C~.
cg 7
/
/ .......
u~
(D
13_
/
t,,...
0
Q.
>
10
/
r,
/
/ i
/
/
.......................................................................................... I ...............................................
9 ]
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
/
_
126
] iii IIYII .......ii t
iii:::: ........I H20 WATER
|
]iiiiiiiiiiiiiiiiiiiiiiiii
l i .....................................i
] i i .....i i i ' ................
!
t ,
i
/
co
. i
ID. I i
(D
I,---
i i
i i
(D I
!
!
I
~n 10 ! i
ID
K I
,
-..&. . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ...........................
i
~........................
ID. i
i
!_./_. ................. ! 'i
> '/ ! ..... 4.
9 ............................
i
.}............................... 4 .................
i
i
}
i
.i ..........
i " i
1 r ..............
.l 1!
0.1 4
i .
i ....................
.............. ~,----L-.2_-3..2-2:--~:13--233
!
1 psia = 6.895 kPa ...........................
Jiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill
................[
i". . . . . . . . . . . . . . . . . . . . . . . ~ .............................. . ..................
i
t , 1 psia = 51.71 mm Hg
i 9 ~i. . . . . . . . . . .
l i }
I ...................... ~ ..................................... ~................................. 4 ..................................
i I
i
I
i i
i
i
i
i! i i i i
0.01 i
i ~. i
I I
9
Temperature, F
127
10000
. . . . ; ! {i
; I t i .....................................
H202 HYDROGEN PEROXIDE
J ,
1000
]
100
~Jc_.
.............. !................. i ii:i: 1 !
. . . . . . . . . . ...........
!
/ i i
I
(D . . . . . . . . . . . . . . . . ! ~,..............................
13_ r
O IW
....... , ': ...........................
t
t
!
::::::::::::::::::::::::::
............................
c~
/
II i
> /
...................... ~..............................
/ ........ i.
0.1~ :
/
j-r
!
/
i 't
t i'
]
! t l
oo,7
:~ :...............
,__, ,, .',
,.....] 1 psia = 6.895 kPa
..[...................... :,~::::~ I:
-- ___Z[-I i- 9 [~ii[[[[[
_il i ZI .r.
, , , 1 psia = 51.71 m m Hg i
:::::::::: ..... zi : ................... :: ::::::::::::::::::::::::::::::::::::: .........................................
I i j
i i
i
[ T T
Ji i t
0.001 I I I I
0 1 O0 200 300 400 500 600 700 800 900
Temperature, F
128
10000., .............. , , , , :
q- 71;;777771;;;;;;;............. - - 1 ................. i ................... l .................................................... i .................................... i ....................
3 ......7 77771-77771T17771111 ' + ............. ~} "
.
i
j
[ t
t
..............i ............................ ,................................. ! i
3---7...... 777 _1 H 2 S HYDROGEN SULFIDE
---i ii.................................... "J...................................... 'i ...................................
-I77117111171111111111111t
............................................................................................ ..... 4 "- !
i i,...........................................[,.......................................i,
+............... " ............................................. I. ............................................. 4 ...........................................
i t i i
i
,1 !
i............................... L" , i9
i i i i
i i
i ! i
i i 1
I
i ................... J~:='L::'I.:'2E.'_T.;2::'..E2".:IilE'L:-2-.'..-'~EL...:EEIi:::E=:E:ZL~::I !
' " i!
-111111111117;1111111111111111.............
111111111i
I
I
I
'i 7 ~
i !
I=l. ! :
1
=3
cD i
~0 l o o 5 ...................................
j
!
13_ l
0
I=l.
>
i I
, !
i
I
i I
| _ i i !
10;{ .... i
............................ ~.................................................
I"................................................
i ...................................
: ................................... ..,-................................. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . .
Temperature, F
129
100_~ ~ i
10=
/ [
. . . . .
. . . . . . . . . .
/ ! ..........................
0.1
/
~!!!! i~! / ~ ~! !!i ! !~!~:~!~~!!-!!~! i~~~ ......................!.......
. i
09
/ ................................. i .....................................................................................
0.001 I
7:/
0
> /
0.0001
/
L ~i ....... i~:::/: ~i ~ii::i:ii:i~i~Si~ ~iiiii:i~ .........
/!
t
1 E-05 ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
! i
[ ,,,
!
i
1 psia = 6.895 kPa
1 E-06
, ,, ,
~- . . . . . . . . . . . . . . . . . . . . . . 1 psia = 51.71 mm Hg
l
/
1 E-07-
! !
I I I
0 1 O0 200 300 400 500 600 700
Temperature, F
130
100~ , ,
a i; ............. i :;;_ :C " - 3 - ~ ~- i Z:Z;~ZZ-ZZ::."_Z--_ZZZZTZZ.-----/_
..... ' '~, .......
4.........................................
] ...........................J H2S2 HYDROGEN DISULFIDE li .......
[.....................................................
] .................
I J"t
I ..........
il...........................................................
9 ....................................................................................................................................................................
,..~...........................................................................
.~.................................................................................
] ,r..........................................................
i i
................................................................
1 !.............................................................!.....................................................
10~ i i
I
i i
. u
--J. ~
(D
L_
i ........................................ i
0
i
> i .......... i
i
,/ i
: i
0.1
!i
-..i ....................................... :..................................................... ,.~..........................................
.........................................................................
...................................................
i
;t..........................................................
.~.................................................
i
i '
........................................................................ i ..................................................... 1 psia = 6.895 kPa
I i 1 psia = 51.71 mm Hg
131
100: I i I i
, ~ .,
................ F.ZZ..-.ZZ::::::::::::::::::::::::::::::::::Z:Z-Z:::ZZZl~:::~Z~::~ZZ...~..-TZZ
H2Se HYDROGEN SELENIDE
, I
~ f
10 [ i ~
................. : ........ ! ...........................................
~ .....................................................
. I
(D
.,_
13_ I
0.1 --~ /
J
- j . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . :::::::::::::::::::::::: I ..........................................
/ [ i
L / / i ..........................................................
i.................................................
i ...............................................
1 psia = 6 . 8 9 5 k P a
_.7
.u . . . . . .
1 psia - 51.71 m m H g
0.01- I I
I I
-40
-180 -160 -140 - 120 - 100 -80 -60
Temperature, F
132
Vapor Pressure, psia
0 ..,.i,
0 0
0
0 0
i i
" i
0 -l"
,iiii
--I
iJJ! ltl
,ili
I
0 i i 0
0
0 m
0 .... i .... ' ..... ','......'ii ........i-, z
i i i i i
ii ! m
i ! | ! r-
f-.
i i ; i
. . . . . . . . . . . .
.~..-i ..... i...-~...4-, c
--,I &~ ! i " i 9 !
t'D o i ~ l iii
i " ! : , ! ! i
! i !t !'i
i i ! i i o
i! iiii m
j''' ii II i i"
('D i 1 : . I
........ . ........... .i .......... i. ....... i ..... i......i....i.-.i,
. . . .
e-,@ i
E
i iii ii ,iI i
i i i !i i
tl) I i i
i 1 i!ili "!i I
................... -i- ......... ~:.......... ~..........~,.......i ......i-.-.++..i i..........i........i--4.-+...~......................
-rl o I i . . .
I
I i
i
!
, i i I ., i i.,I !
i i i i i i ! i
i ! ... ._k
i
!i i! ii!~ii i i
ii
! i .
--" -" ] ..................... ! ................ .i--.i......i-d...l -..i...-i.....i....L.I........................l ..........
o .......................
[ l........
i i .......i i ~"l .. . . :
: : .. : :
: : .. : : ~..~
9 i iii
l : - : 9
! ~i iil
i!i!
~ "" i ii i ~'' " ' i "
' ,i 'Xii
o-- --,oi i JJi ; i i i j j!j z i t ; w,ii i i
3~
,~ ~
iiii
| 1 | :"
i~ : l
J| |i iilii . : i
i" i
!. il J.:. ~i
" " i\"
i| 1i
Ill i .~ " : i l i i .-" i "i i i : 9 i i i~i i ,
i !'..i ~ i i i I : i.'. i ! I i i !i,%, i
..l.. i iii " ": ~ ." i " I." i i i ! i ii.-' i E
r ~ . . . . . . . . ~ ...........~.............. t ..... i....4-i....~ ........................... ~ .................... .~. . . . i.-.4..-~.....f.-.!...i ................................ i ................................ i ..... 4.........i . . . . . . H 4 , . - i . . - - - ~ . . . . . . . . . . . ~ - - ~
0 i 1 I i i I ! " I i i "" i .~ i I i i i i i !
I I
i i. i, i9 ~i i
,
~
I
i, i~ ~
"
iI i' "iii!i
" ''I
'
i : t i : : i i i : i : : ~ ! i i .
i ; i i i ., I i i ,. i i ! i i i i i
0
0.001
! t !
H3N03S S U L F A M I C ACID
. ,..,,,,.
u)
c~
(D
L_
u)
u')
(1)
J
L_
13..
/
/
0 I
c~
> i
0.0001 I J
! t9
I I
60 80 1 O0 120 140 160 1 80 200 220
Temperature, F
134
Vapor Pressure, psia
O 0
.k" O O
I
0:}
"i-
01
i I
t i -1-"
i i I'rl
i i ! r-"
! t i C
U1
"-4 !
i
!
0"1 i i
. . . . . .
"-4 i.......!._.i ! b,l , 1i
---t
~n i !
I............i........i..... i.
ii i
I!
c ~ ii!
I i 9 I
| I
I
T...............i.........i.........r i
-rl
ii i i
-'
I! i
9 i i: i !
i ii ii,!i i
U1 I i
U1 i I
i
"o-o
'........i"-i,. t' I
__..~_. !
. ii
i i i ! i J
II II
i .........! .......i !"...........
9 ~ +, 4 l ..... 4,
U1
i i i ii i
!
z
i i i
s i i i I I
I ! i i
i . i
"1- i i
ii I i
'- i ! ii
t ......... 6
............... ".............
9 i
i
i i i i i i i !
i ! i i
i ' i i ti i i | i i : i
i I i !!i
i! i i ii
, i
,~ ii i i i
i
l
i
i : I ! ' i
i i . , i
i! i! i
ii
I i i i i I i ,! !~!~ , i
! i i !
100
He HELIUM-4
'7 i
10 E IIZI-ZI~IIIIIIIZ.-_Z~IZ.21~I
..m
O.
F............... i ..................................................
F
ID
...............................................
r7 ~
:3
(D
(D
(D
I..
13_
I,...
!
O
O.
>
:/ ........
/
/ I
I !
I
i i
i
' i I
1 t
0.1 I
., i 1
i i i I
-457 -456 -455 -454 -453 -452 -451 -450
Temperature, F
136
100=j:========================================
.............................. ,...........................................
i:= ..........===~-F--~!!--~---!~:-~!~!!!!-:~-<e!-:e1!!!-!-!!!~::!!!!!!!!!:!!-~:!!~!!!~!~!!!!!!!!::!!~!!::!!z!z!!zI!zzz~z
= , T ...................................
~ .......................................
"................................................
~ ..............................................
~.................................
. ~ . . . . . . . . . . . . . . ~.................................t~............................ ,".............................................. .~.............................................
~ ...................................
- ~ ,.~. . . . . . . . . . . . . . . . . .....................................
9 ~...................................... ~.
t T t
,' { 9
}.
T| ::::::::::::::::::::::::
!
; l ! i i !
:::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
I,i
............................ " ............................... ",,............................................... i
::} l i
i i i
9
,." .,.
0.001
I,i
13...
.......................................
i'.....................................
i
I,i .....................................................
i-................................................
0
Q- 0.0001
>
" L ................................... i
t~ . ~ _7__ i i
l J-f i i
1 E-05
1 E-O6
! -.:
"l"
9 ......~....................................
t .....
1 E-08 I I
9 10 11
Temperature, F
(Thousands)
137
-I
---- ................... :,:.................... 1~ :~z :7/.T..T---=--:::.': :: .':2:: :..~.~'~'-.T.:: =:::~::::: .'..'2Z'..T.'.2=: .':'1 ::::: ::.:= ::: :: :'.: :"=----:::1:::: :.'.':" :::: ..:.:.:-.=:. ~ :::::::::::::::::::::. :::::~::::::: .: :::::::: :::::: :..:::::::::::: :::: ::::::::: ::::::::::::::::::::: :: ::::: .: :::: :::::::: =..:::::: L':::::::: .::
. , . ~ ..................... t tt ' - - ..+....................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . +. ...........................................
............................. ,
+ ~; + .............................. ~................................
j ......... 9 _ _+ ,
Hg MERCURY
10000
1 0 0 0 _ - +++++++++++++++++++++++++++++++++++=.-_=
-. ,. ======================================================
I ........................ !..............................................
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
,
: ==========================================
..............
100-_-
10:
~~---==~~=~-s I!E":Z:!~EE!!!::'!E!!!EE!'E!!!
:LZZZ:IZ s163iJs Z 2}:/----:}Z:::2Z:Z:[Z:ZIZ:Z::-~~I! Z:::'27::::::.'.::L":
......-::Z'.'.'~:.-'/2".'::::::":..'::::ZT::Z:
,r. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1-
. m
[ ZI ~ J !
:: ::::::::::::J + . . . . . . . .ZT-:ZZ:::Z:..... :Z:,
Z3 0.1~:
0 .....~,,`,,+`~,,,~.,,~:`+:~2-::-::::::::::::::::::::::::::::~:~:::~:::~-=:~-=~-=~-~--~%.-:~-----::~--~~-1!~-----=--~.~-=.~-a~:..:~..-:..~.~.~:..~..~-:-.-~.:.:-..:~.,.~:~:~=
~:~.~.~--~=~..~.~.:.~:z..~.~.~..:.~
00
0 ======================............
=====~===-==- t - +---":::::::: •::::::::::::::::::::•::::::F:••--••-:::::::::::::::•:::::::::::•::::::::!::•:•--•••-:::::::::::::::::•:::•::::::::::::
0.01
1
0
0.001
>
0.0001~
1E-05+ ............................................................ .
1E-08 I I
-500 0 500 1000 1500 2000 2500 3000
Temperature, F
138
100, l I ~ ........................... "8. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
'
t ............................................
'
I ........................
3----_~iiiiiiii;iiii;i iii/ii iiiii Z I _ _ i i .................................... t ......................................
...... ~................... 4...................................... ~..................................... .}."
............................................t .................................. !
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . L........................................ I
] ........ i f.
1 0fl ~ ~ 1, --:::::::::::::::::::-:::::::::::::-::::::-::'::::::::
1
. , , . ~ ....._oliiiiiiiii.i ......f_
. . . . . . . . . . . . . . . . . . . .
~I i . . . . . .
I . . . .
J . . . . . . . ,i ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
i J i .....
: ! | ! / | ! i
,-- I i ~ I A i i i
9 , s , / ! i ! !
09 i i ' '
o~ 1 3 ......................................t - ............. ~ . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
tD Zl ........................................
---'- ....... --' . . . . i" . . . . . . . . . . . . . . . . . . . . . . . .
K___ ] ..............................................................
--~--' I " .............. ~i ./ . . . . . . . !. . . . . . . . . i . . . . . . . . .l . . . . . . . . ! . .
H . ~ I . . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i i I
i
i
i
~....................................................
:,........................................J .........................................
i i i
,.,., j ............. i
U . I __7 . . . . . . . . . . . . . . . . . . . . t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~. . . . . ,. . . . ._. . . . ._. . . . ._. . . . .z. . . . .:. . . .,. . . .~. . , , Fl . . .~. . . . ._. . . . .:. . . ... . . .-. . . .-. _ : . :I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...... : : :t:.:. :. .:. .:.:. .:.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. : : : : : : : : : : ".t: :.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. .:. :. .:. :. .:. .:.:. .:.:. .: : : : : : : T: :...........................................
::::::::::::::::::::::::::: t ................................................. " ............................................... ............................
! i i ~ i "
i i J i i ;sia = 5i_7i mm- H9
-! . . . . . o!.............................. i .............................. ~................................... ~............................ ~ ...........................................
I i i i i i
1 j i } J j I
_.../ ~ i ! i J !
Temperature, F
139
1 O0
......................................... i
'!............................
1
f
10
.m
Ch
(D
K..
E
(n
............................... }-.EZ21XZEE".2ZITZ2Z "~IZ.Z2Z2"II~'~Z2.
(D
fi~ii i i i i i ~5-2--2-~!i!i i!!i!i!-i~i i !!!
L__
13_
K..
0
CL
>
..................................... I ..........................................................................................
i
1
I r
0.1 ...............
~-....................................... ~ .......................................................
4 ....................................................
!!!!!!i!!!i!!!!!!!i!! !!!!
1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g
0.01 1 i I I
250 300 350 400 450 500 550 600
Temperature, F
140
100, !
J
]IIIIZIII i-ii-i__ii I
] iiiiiiiiiiiiiiiii ........ I Hgl2 MERCURIC IODIDE
, . _ _ : i ' ]
] i i i ........i i I !
!
................................ ,- ............................... ? ..................................
I
!
.............................. ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . T .........................
10~ ................................ ~ [
i .7~.
..........................................~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
/ ! I
~---------~ . . . . . . . . . . . . . . . . . . . -i . . . . . . . . . . . . . . . . . . . . . . . . . . . .
J ..................................... i ............ .----.4. . . . . . . . . . . . . . ~ . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . . ~ .......................... ' ................ "~........................................ 4 ..................................
> ~ , , -/ ..... i ......... i ......................... ~...........................................i ........................................i ...............
Temperature, F
141
1 O0 , ............... ~. . . . . . . . . , ............................... J
-- ~' ~ ~ i __i______i_j ~. ....... I~Z .............L:I ..............iI.., ,~ s ............. ,-LL .......--.4 .......................................................................
-- '. . . . . ' ..........--4 ,~..........................i. . . . . . . . . . . --4 .....................
ZZJlL ..... i~ I IF7 I O D I N E H E P T A F L U O R I D E F T--]..............[............. i ................................. -I ......................
...........................................................
, , [. . . . I ......................... I . . . . . . . ~ ............................... i.........................T~.............................
1............................ r . . . . . . . . . . . . . . . . .................
1.............................
f I I t / I i i,
1.............. I.....................
I ..... I . . . . . . .I.........................
...............................................
. l-- . . . .l.........................
. ................!....................
l ............ , ...................................................... ~ ........................... T ...................... ; ...............................
. m
r~
1 '...... , 'I ............................
1........ I ..................................
i ....................... _!.............................
(1)
:3
(D
i ', ! ! .............
13_
IL_
0
Q.
>
1 .... i .......... [ / Ii .......................................
Z_-22~iiii:22211 -i~212211~721112~.T.212271
i 1
O, 1
1!2
l
. . . .
'S~~:;!--'-----
. . . . . .
..... - .....................
L..__.L__ZL._Z...TT.Z7...ZZZZZZ:::LTZZT:ZL-Z.':I:IZZ.'ZZ"L"..'..-.'L'Z-Z
! ..............................
I ]'
[ .............................................i ............................................. l ..........................................
,
t
I
i i
0.01 1 I I I
-140 -120 -1 O0 -80 -60 -40 -20 0 20 40
Temperature, F
142
i~"...-= "" ~---2." " = ":" .-.71"--""-::"2.:~:,~:::::::::::.~:::'--:"
..'7":::::"
".=":::,".:-__-.
""i:::~-" "=:.'.----T..---::::
= .':.
" : ~ ,~E:7=--72:=:../=.:;
============================================
................. i___;;;; ......... ;_;____;_;:_;;_ _;.......... ;_ _;; ; ;;'.
- - . : i . . . .....................................
. _____it ,#........................................ ..". . . . . . . . . . . . . . . . . . . . .
!~~------"
]]11;77777777777777;77777777777771711 I ~ ..............................................................................
................................................... i ................................... @ ...................
I ...... I , I t l-- . . . . . . . . . . . . . . [ - ~ - = . . - - = . - - . - . ~ . . . . . . . . .
==========================
J .......... t ......................................: ;: ~ : .............. ---m---i ......................
9 7 ......... ; i ; 1 ..... ;;;i ;1;;;;;;; ;;;;_dZt;Z; .....................
.....................................2 . . . . Ii
I
1 O0~!!!!!!~-~!!!!!!!!!~-!!!7!!!!!!!!!!;i!~>.~!!iiTzii' - - .~=_,=_. . . . . . . . . . . . . . . . . . . . . . . . . . .
_ _ _
r ...............................
. . . . . ...~.
9
!
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , ............................................... .......................................
~ 4 i ~i.:: :_5~ :"i.--~ E:2 .:":E:i.~i!iiiE'i 71:i:I!ii!iii!:.'~i".'i!!:!':"Fii-:,'i- :?i Z i.iZ.-"ZZZ i.i 21ZZ;',
. i !ZZZZZZ'Z.ZZZiZZZZZZ-ZZ-ZZ" .................................
Z.Z..~ ! .............................. , ......................................... .~.......................
. . . . . . . . . . . . . ~ ............................................
.~ ........................................................
~ ...........................................................
~ ......................................................
P,
l
1 = - - .................. ]:;:,_'=~.-;= = = T=:L-.. = =7.';=';:~;;;...~..:;
......... ,8.. . . . . . . . . . . . . . . . . . . . . .
.~;::7.;== ."::7":7:'.':.:: "=:=IZ:;;;:;::-~:.':':;::;::;:;:;::::: ~:::::::..'T::';:;.-..': 7.;".~=;..~ .~~;"=': 7.2;:.':."='::::: ~=;l 7..T".'-'_--22,~;; =:.'.;:
~ ............................................. ~ .......................................................
~ ............................................
............ ~ ............................. ~ .................................................
~ .......................................................
~ ............................................
f .............................. ~................................................... ~ ........................................................ 4. ...................................................
i' {" ..................................................................................
9 i
t .......................................... , .................................................... ., ....................................
I -- ................... ~........................................... ' .................................................. ! ........................................
13_
L 0.1 ~--ZIII-II--71.... 7 -i . . . . . . . . . . . . .
......... ~
..........................
........................ ~ ...................................... . ..................................................
. .....................................
~-"-".."~E"~E."...~.~.~E~.~"~E~E~"~"~Z~EZ~."~.".:7..-."/::"~"~."~EEL---~EE~"-"~,
.............. ~.. . . . . . . . . . . . . . . . . . . . . . . . . . . ~............................................ +.................................................... ~............................................
0 {, i.--
! ................................ , .............................................. "4...............................
...................~ .................................... ~.....................................................
~ ............................................................
~ ....................................................
" ~ ' i ...............
..................~ ...................................................
~-......................................................
~ ...........................................................
|......................................................
Cl:l
> i
...................! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I ! i
i! i!
I"......................................................................................................
~".....................................
',
0.01 ~~~-~7 ................ ~-........................................e ..........................
..................~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
".2"...................
~ ...............................................
~ ........................................................
9.............................................
. .......................................... ........................................
] .............. ~1 [ [
n m n m 4 _ 1 ............................ ].. , I ....... ! .................. 1 psia = 6.895 kPa ....................
%.#, % . J % . # % J I ~ ; ~ ~ ' . . . - - . . . T ~ ":::"............................. ~................................. ~.:~ .~.
---'/".~= : ".:::..... T./.=:.~.~::=::.T_~'.~::.~:= . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
n ~ ~ , ............... ---'[ ...............-- ........~::.... :::--::::-:."--:=---:---';
-"c---:::::--c::--::::z:z::zz:I p s i a = 5 1 . 7 1 mm Hg ::::::::::=:-::-c=.--:::::
~17~iiii~ii~i~i~iiiiiiiiiiiiiiiiiiiiiiiiiiiiii17~--~ : i, i ~:E._--_"IIT..IZ.--..CII..~".-"_E."~'2.'.:Z'~-.~'Z.T..Z;T.I:Z" "-.E.-TCZ~~
J .................................................... ~ . 9 : .................... .4 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
] .......f~ t r , . . . . .
] ...........................................--/~"i " [ " F-" ................ ; .......................... " .................................. t"......................
- ~ ! I I ! !
1 E-05/ i ' i i i i
-200 0 200 400 600 800 1000 1200
Temperature, F
143
1 0 0 ..................................
_ ........~
,.Z-__q--7-~jZT&-.,-1.:-_:.T---I~-E-
~ ~ ......................................................................................................................................................... : f : = = : : = = = ....... = = :, : = = = = = = - - = = = : ,
. ' ~ ~ ~ ~," . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.,= - - __ ilZIZZZZII;T"ZZZZZ-'-1
I=
.=
,=
0.1= "-:'-----.'~.T.T':"--"::"::,
.-Z:,'..---
--'.----~--
""..:"-~: ---T-".'.
.'/:" --_.T.~:'C ~:::3:::'~::~'~ :::::
. m
03
(D. 0.01= .................................... ....T. .......................................
(D
t,..
03
03 0.001 =
(D
t__ .. ,.,--.--.
13_
!,_
O
(D. 0.0001=
>
1E-05= .....................................
:~-.:-T.-:.-.:.-::::::::3:::3:::3-..C:3.~.--.--
Z- ........................................
1 E-06-
.=
144
100~ :.-!!!!!!!!!!!!!!!!!!f!!!!:!::!!:::::i:::::::::::~ZT'_~ttZt
..................... ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
-[TTIIZIZZIZZZ]I
! r i- . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!". . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
~..............................
~ ......................
9. . . . . . . . . . . . . . . . . . . .
,I. . . . . . . . . . . . . . . . . . . . . . . .
:~ ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: .....
-I!E!!!!!!!!!!!]]!!!!!!!:]~
................... l f ...................... ~s . . . . . . . . . . . . . t
!.............. i .......... i:::::::::::::::::::::::::::::::::::::::::::::::::::::::::i:::::::::::::::::::::::::::::::::~::::::::
" ..........................
~................................
P - - ..........................
4 .~
I ! i
!' i
. u
(/) t i .t
i , !
Q_ 0.01
! , f .................. i ......................... f
(1)
l,--
| i t._...:...-.!.--.::..f~L.::..IZ:..:iiLZiZ_Z..q..::::::.,:
i i t /_................ ~i ..................... ,:
I .................. I-
(n ! i -[7 !
(/) 0.001
i i i
::::::::::::::::::::::::::::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
i
(1) i ,,i ............ =====================================
4,
~.....~ ........................... $ .......................
I,..
,L:=t_- i ,i.,.
i. i
!..__
0
c). 0.0001
[-7
>
i / '. . . . . L
F, - - 7 /
-i ! !
::::::::::::::::::::::::::::::::::::::::::
! ! !
9i , . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .,
i t
.l. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.i, . . . . . . . . . . . . . . . . . . . . . . . . § ...................................................................... ~ ................................... 4
"
T i , ,~....................... ~ .......................
I !
i
4,'
i| i, ': '
il~].i~i.._:.._,.g~:._._i~i::i~::.:~F._:~i~i~i] 1 p s i a
1 psia
9 I = 6.895
= 51.71
kPa
mm Hg
li
.~------"---':~--------'4 i
t } ~
""-"----'-I' j t
4.................................................................
-------i s I i i ...................................................................
............i . . . . . . . ~. . . . . . . . . . . t. . . . . . . . . . . . t
4 ................................................... ~ ............................. ~ .................................... ~ ...........................
I i i s
1 E-08 I i i i i I I I
3000 3500 4000 4500 5000 5500 6000 6500 7000 7500 8000
Temperature, F
145
1 ~~~~~::=~"~===~===:=~==F~:~=:~=i~~5::::=:==:==::::=:=:::::=:~5~:~~i~5~E~5~i~iii~::~:~5~:E~5E~:~:~i~~:~: I
,9 ~
../~--- ~ = : ' ~ ' = ~ - : ~ = ~ "
~.............................
====--~~
.....: ~ : Z : I Z Z ~ : I : Z C ~ . . . . . . . . ~ _ _
,
f
!- ................................... * ........................... ~................................. ,
4.......................................~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . " ................................. 9
~ _ _ ,' I, .{.............................
K POTASSIUM ...........................
~ 1 t- ........................... ~...... ---.~,
J 1 I....................... ~ ...... L.
. . . . . ~ ," g ~ . 5 . - - - - , -!::=::=-==::::=:-=-:-.-=
; ::::::::::::::::::::::::: :========================
..... ~ .......................................... !: ii .......;~......... ~ ......................... ~ ' ..................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
!7 .......::::::ii::::iI........................................
_ / ................ r ....................................................~................................... ~ .......................................................................... !
(1:1 ......................
................................... h .......................................................................
. i
(#) / i .............................................
/
13.
0.1 ..................... 2 ~~-~ ~ :"_=!2"
":E~":!!:::"Ti!
~22!2!-"2~-=2!:2".-'2:":2!":'-."::':
2.'I,!T.':":!!!!!!!!!!!!!!!!!:21!
!2!!"!! :""2-"
2:.!2
(D
............................. ~7.~.-:"L~::::"-..".%.:::::::::":::::::::::2::::.~:::::::::::::::7.:::2::::::::2::::2::~::::."2:~:~:~::::::~::::::::::::::::::::::::::::::::::::
~~ . ......... .~
.................................... 3" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ .........................................
i,.,,
/ ...............
:3
............................. T ..............................................T ...................................................
! ..............................................
:======--.:=-:=-:...=::: ::::::::::::::::::::: !~":~.~.E~:i~.5~:e"5..'~!=.::"~E"!~!!"~"~!!!!!!!i!!!!!!!!~!5!!!!!~!!i!!!!~!!!~ ~~5!!~5~!!!!!~!!5~!~!!--!!5!!!!!-!~!!~!!!!!!!!.~--!...-..:!.::-!-!!!!~!
0I i " ' ~ ~ " " ~ ' : !i ===================================================================================================
i,i
o oo, .......... !
I
0
l:i.
.......................................................... ::::::::::::::::::::::::::::::::::
cl:I
> !
[ ...... ..
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
-. _. . . ......... i..........L _ / [ ....................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I
!!2.~E.-..-~.:E5-!E-`..E!!!!Z!!!!!!!!!!!!!!!!!-!~!!!!!?!!.......!!!!i!!!!!E!!!~E!{!.....!!!!!!!!!!!!E!:s163
/
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii;iiiiiiii ............. mZI:I:II::::I:::I:I:::I~I~:~-Z.Z~'~-~_Z~-.:Z~. ....... ZZZZ:tl Z- ......... 1 psia= 6.895kPa [................. ] .............
~- ,~--, l [ i ! 1 psia = 51.71 mm Hg
-- - - ~;,r;;~;r--~;;;~;::;-;:/:.7~T.:; :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::
.............................. ~..............................................................
[~
::
Temperature, F
146
100,
~i:::::ii::iiiiiiiiiiiiii:ii:i:il
......................
-i .................................................. [ ~........................................................................... "i
-I YIII~ ~IYY1
. . . . . . . . . . . . . . ~ ..... i.........................................Z:::::::::::::Z::ZZZ:ZZZZ~Z:IFE:ZZL-Z:-Z:-L-C_--:
....... , ......................................................................................................... ~.........................................
liiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill KBr POTASSIUM BROMIDE ..........i ..................................................................................................................
j .........................................................
i
i i
"r . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
!
i
!
t i
: 1 1
. i
I i !
i t............................................
i
Q. i !
I i i
(D i r....................................................
i
1 !
I
'
'
(D
I,...
! i ::=z:: : ::,
T ..................
i * ............... -,,;2
O_
i i " .......................
0
c~ !, ,./
L./_ ....................
i j..~_. .................................... ,
i|
i
0.1 t .......
T ......
--_.~ .........
........... ............
i
!
!
!
i i
i
i i
i i!
0.01 l
I I I
1400 1600 1800 2000 22OO 2400 2600
Temperature, F
147
1 oo0o.=. !
_|
i ! ,l !
i I .... ::
KCI POTASSIUM CHLORIDE
| . _ . . . . . . . . . . . _
7 9 . ,~~~ -
1
i i :
i
1000 ' i I
. . . .
,I
j i i i ,, ! l I t i ' 1
I I I ! I i
I 1 I 1 i I I
,il i i i i
I I l I I I ~ I i
I I I I I f- !
loo, _i
'
1
i
'
i
i
i- ..,,..-.
J r
i" //ii
II
I
t
,
I i,
,
,,,,
- /
_1 I ! I ! , ,
u)
..=,.
i I , ~ 9
CL
10i i i , , i i I ,' : :,
(1)
i..
! '
l i I I I
t
t
I
,
,
, ,
j I I I I . , 9
I I i I I I , 9 ......... 9
u) .
(D
IL_
n
I
1' ,
L._
i
l I
o ,
r
t
O.
I |
I I t
I , 1 i ! i
> i
!
!
I
!
0.1J i'
: i ' } !
I , ,, !
t |
__1 , i 1
' i
I I , i
i
_1.
i! ' t . . . . . . . . l
0.01 '
i . . /! . . : :
_1 , , ' I i , , i ' ,
; , 1 psia = 6.895 kPa
. . . . .
'
!
I
i
'
I
'
I i
i i t lpsia 51.71mmHg ;l
._ ,
.... "i
0.001 i i i , , I i I I
1000 1500 2000 2500 3000 3500 4000 4500 5000 5500 6000
Temperature, F
148
100
,,,I ~ ,, , ' ;,, ,
........ ,_,,,,
KF POTASSIUM FLUORIDE
10-
,
J
I I
,,m
o0
Q..
(D
L_
o0
i
(D
t__
i ,,,
13_ /
t.__
/"
O
O..
r
/.
>
0.1 _ ,/
!
i /
0.01 -
1600 1800 2000 2200 2400 2600 2~300
Temperature, F
149
OST
-.I 'eJn],eJedLuel
0098 OOtT~ I
0088 0008 008 L 009 L 0017 L 00;~
LO'O
814 muJ LL" Ls = e!sd k /
ed)l s = e!sd L
I m /
. . . . . . . . . . . . . . . i ....
/
/ -
~- -1 f , , ' ...... ~
/
9 L'O
/
/
13
. . . .
0
, L
-g
"/
l _
J
o~
r
/
/ 1
I i
. . . . . . . . . .
. . . .
/
/
I
I
=!(]1(]01 ~ N I $ $ Y I O d I>1
..... L
. . . . 1 _
. . . . . . . . . . . . . . I L ii
00 L
-~::::ii:::ii
~:: .... I : :: :!.!.!!.::i:.!::!ii....
~, .... ~ ~ : : : ::: : "' : , '...... , :~ ..: .::, , i...... ~.................
l..........
i:: ...... :]i : : ::::x:::X]
]::::::
9 :: ~ KOH POTASSIUM HYDROXIDE I ......................................
! ! ............ !. . . . . . . . . . . . . . . . ...................... - 1
] I I t ................................................................................
~ t 1 J
lo ! 'I I I I i ..............................................
....!... ! I
]!!!i:!i!:::i..... ::.....i i ' : "-'-'-'-
'~ I~ " ....... ' ~::' "~ .....~ ' : :::: ..........
:I:. .r.,;,, :,,.......... , ::::::: ....
, i ii/ i.....................................
~. . . . . .
i / ! L_
. . . .
. . . . . . . . . . . . . . . . I
I
. i
.
O.I ~..........
. .
~,,,,:~,~_:::
. .
...............
~......
. .
:_.ii....-~:~!:!~--.+!l:~!!!!!=
........
:~,-------~i:
iii~ ~
i .... ::::~::_~_:_t~:-_=:
/i .....iii:_iiii!
...................~-
'
[
co
I i/ ...i..
YY"'II I ,",'",, iiii ........ / I ...... . '............ " _ ". . . . . . . 14 .............................
0
o9
i ,
:~2~:t~::::::~::::
......
:iiiii~::! :::::::::::::::::::::::::::::
.......
;....................
-X-~2@2~S~?~Y:::~tl;I~::~:?:IT::= ' IIIIT~---~~-----~ ................_.------C~.~":::: : T
0
13=
L__
- l ./ I /I i ...........................................
t ,
0 - - :... ! ....................
I.I.I-iYI.......
:.......
/ I ...... I ...... i I : _:....LL[ l
ooo,..............! I / ! ! ! I l
O=
>
~I .......... : :::::::::::::::::::::::::::::::::::::::::::::::
.......
:J- ..........................
| .... :: .....:..i.:..,::::::'.'-
::::: :: ::::::iiiiii:iZ:::::__;~~ .........~ C ~ L ' - ~ . - - ~ ' = = _ ~ . . ~.
_~ .: ...... i :::::_:::____:
.........
,: ~ .....
ii.......... i i. : I : :: : i ~- :::::::::::::::::::::::::::::::: . . . . . . ~, I
..... ) ....
! ' ~ ...... ! ....... ! .... ~ " ......~::::: : ......... I: :_:::L.--__~__}:~ ..........~ ...................
:::::::::::::::::::::::::::
.......
! z .... [ ii:/J .......
i::::::.::i. . . . . ! ........ ! ............. !............. ! ! .............................
i ~ .......................
] ..... ! /]I]::]Z ....! . . . . . i i ............... I
................ .................
i.....................
-T . . . . . . . . - ~ . . . . . . . . . ~ ..........
I ::::::::::::::::::::::::::::::::
......~-:.- ................. ", ,,:........... ' ............... Y " ! ...............
~ T'~_-~=qi
.................... I psia = 6 895 kPa ).----=-~'
3
3 ......
' '
:~:--:-:-:--I
/,
~................
~ 'i.........................i ................
..........
. . . . . . , .............. ~: ::::::::::::::::
I .......
~ .. : ........:iii
i
.....::t:::
..........i ................................
....::::::::::::::::::::::::::::: J I p s ~ a9 =
..................
"
51.71 mm Hg
i~:~_.--
L- ...............
_ - ...... I I ! I t i i !
1 E-06 i ' I ' i i i ;
600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F
1 5 1
1000 I= i 1
Kr KRYPTON
Y
E /
/
.==m J
O3
Q. i
!.--
(D
/ =
O3
O3 I O0
(1)
L_
Q.
L_
0
> /
/
/
/~ r
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
101 I I
-200 -180 -160 -140
I
J
-120
i
-I O0
I
80
-260 -240 -220
Temperature, F
152
100, ' ':t:!:::! .....................:: ........::""~......... ! T -~. . . . . . r---- ..... T ~ " : - : , - - ' T , - = : T T ! = .........................................................................................................................,
| ............................
9 , . 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................... 4-
] J La LANTHANUM P ........................................
i ~ .........
o] .............
] .............................................................................. ..................... i ......
] I . . . . ............
.... , ............. ,. . . . . . . , .......... r..........................................
~ ~ I ~ ~ - ~ - : : : : : 2 : : : - : ] = - ~ ....."
l I ::-;,
_ I ......... I . . . . I . . ... . ... ... . ... .. . . . . . [. . . . .. ... ... . . I .......................
t -- " ......................... I ........................................
I !.............................................
F - - ~ -:~::::::-:---:
.............................
,
........................ i.....................
i
I _ i ., I .......... " " ,, " ,, I ....................... - ' I ........~.. .............. " T ~"
] . . . . . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I .......... v ..... , ............................. i
................ i .................. [. . . . . . . . i ............................. t ......................
O. I --'.............................
,-,. . . . . ~. . . . . . . . . . . . . . . . . . "~ . . . . . . . . . i............................ ~-. . . . . . . . . . . . . . . . . -x.....................
........ ...... !':::t: . . . . . . . . . ::': ............... ~ ......... i . . . . ' " =======================================
. . . . . . i. ...................... r ............... . ....... i
J ...... t . . . . . . . . . . . . . . . i. . . . . . . . . . . ! . . . . . ! /_ .............. ~ i . . . . . . . . . . . . . . . 1 ........ ,
ool] ! .... / ! ! 9 I i
_ ~ . . . . . . . . r ....................................... ,.-T"----# .................... I ........................... .'!"-" . . . . . . . "... . . . . . . . . . . . "T . . . . . . . . . . . ~ . . . . . . . . . .
9 i ................... i ....................................... I"--E_'I ........................... ! ......................... - - - - - ' T - - . .......... t ..................... "~. . . . . . . . . . . . . . . . . . . . . . "~. . . . . . . . . .
J ........... I . . . . . . . . II' I iiii i ....................................... [ [ ....................... ! ................ ! . . . . ~ . . . . . . . . . ~ . . . . . i+ . . . . . . . . . .
.... ] ! T--TT-- i i i i i
........................................................ i"- . . . . i. . . . . . . . "i' . . . . . . . . . . . . f ................................... i ............................. ,............................
U. U 1,31 ~--i~7.Y!:_:_:_!:_::-:!~-&:-:-_:!_:_v-!
............, ' - - : ~ ~ = = - - " ~ - - ' = ~ ~ ~ . ~ ; .......... ==========================================================================================================
-;2; ......... --- . . . . . . ::::::::::::::::::::::: . . . . . . . . . =========================== --~"~----"--"---'-----:~~-"-~~-------"-----'---.-~-" .......... ;7-'"Z::.'~=::::;Z::"2".:":Z::2".:=~*Z:'-.:Z::.."Z:":=: ..... ~-'."~.~::Z::::::Z:Z"_'-_Z.7.Z"Z::"
~- zz_--:2zz7771 .... _ . . . . . .~-----::-...:--T-'-"-~. - .................. .---- .................. - -- --~- . . . . . . . . . . . . ~.. . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . ......................
9 .................. ! ................... [ ................ 7 " . . . . . . , ~ .... . .......... "I- ................. I . . . . . . . -----"I- ............
9 ...................... ~ ..................................... - i - - - - 7 - .......................... ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i ......................................... - ! . . . . . ".,. . . . . . . . . . . . . . . . -~ ............... I ............
............................................................. -"i- ~. . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . "~ . . . . . . . . . . . . . . . . . .
B
.........
........ -i--
i
i . . . . . . . . . . . . . . . . . . . . . . .
i
,
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
l :. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
J, ~,, i .9. . . . . . . . . . . . . . . .
i ..............................
,9
7 t..................
,
,...........................................................
J - i .#. ............................ [ ......... t : . ; "t
_ i ~. . . . . . . . i ........................... ~.. . . . . . . . . . . . . . . . . . . . .
i
! ! ~ i !
! i i !
1 E-08 i i i t i
2000 2500 3000 3500 4000 4500 5000 5500 6000 6500
Temperature, F
153
#CjT
-4 'eJnleJedwel
O00L 0009 0009 00017 0008: 000;~ 0 0 0 I. 0
I I ! I I 1 I E I.-=I I.
.. '4"..":.:-....- . . . . . :...... ~ - " - -~ . . . . . . . . . ,~ :
:..-----=:::.::..::...-:::: H I.L'I.S = ,~ I. i ~ . - : " . . . : 7 . . . . . . . ~. ~ ' -.. .......................
............................ r . . . . . . . . . . . . . l ; ~ I
..................................................................... ;: .......... [: . . . . . . . . . . . . . . . . . . J! . . . . . . . . . . . . ~L _ - _ ~ --
i,,, -- ,t....,.- . . . . . . . . . . . . . . . . . . . . . ;- . . . . . . . . . . . . . . . . . . . . :--:-: . . . . . . . : - : - - - - : :-:_-: .:_--: - .; ---: ],
~'~..'.-."..'..~~-.-'..'~.-....'.-=._~ .~-~.~=:~-.,.c:.~..".-~-.-'.~::~ !~'.-'.~'~-.',-~"~,:~.~.~.~.--~.::~ ! " - - ................ =~-~---" .....~::--~-::~':=~:
"= 6 O- = i I.
:::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :::::::::::::::::::::::::::::::::::::::::::::::::: r.=.-..~::::::::r..-~..-~.~. ..... .~.~-.:'=:=:.-. ::=.~.~-_.-.~..--a~-.~---_=:l ~ ; , ~ '- . . . . . . . . . ~ - - : : : : _ : _ : / - _-:::-: _ __ L:__ ,,,-
3
.................................. ~............................................................. i=_-=.=-- _ ~- _ _ - - ~ ___ ......................... ~ ................................................. ~ ................ ; . . . . , .....
. . . . . . . . . . . . "i ........... ..................... I i ...... i / ..............
1 t LI=LOI3
..................................................... ; . . . . . . . . . . . . . . . . . . . . . _ . . . . . __ __ j - - _ <
_
'!F!!E-::-.".'F!"~.!!E.":7!!!!!~:'.'F_'.-2.."s ================================ ::::::..':'::.':::::::::-::::::~:::...~-.--=..--~:.---:-;~:Z~--~,i:.~.~.~..~;~;~ 3--.'.'.'.'.'.'.'.~-~. . . . . . . . . . . . . . - " ~
...................... ~;;;;.;;~;:~ L,;;~::;,; ~,.;;;..;.LL;;.;,L....;;....... ......... ~ ........ - ~ . . . . . . . _- - . - . . . . . . . . ;L._.;,_,L';,__';:'_;__"_,.. , ~ ,..
i . . . . . . . . . . . . / .............. s O
.[-- :. ............ : --r . . . . . . . . . . . . . . . . . . =.. : ~i - --
::::::::::::::::::::::::::::::: : ~r-.~=.~.-~r~r..~:~4~`~.T~=:.~:::~:~:~:~:~::::`~::`::::::~::::~`~::::::~:::`~::~:~:`:~:~::;;~;~:`:L`````: :-:;: ::-:=;.L--_- . . . . . - . - - -- . . . . . . . . . . ,,....~.. . . . . . . . . . ::- - ~ - - . . . . . . .
"0
- - I . .: : ................. : : :, :- ~ooo'o O
9 9 _ ~ .... [ : ._- . . . . . . . /_ ........ [~
c
~ ~ - = : ' - - I ........................ t :::~ .... " ' :~ '................... :::: ...... :...........:/ ; " (1)
" - I I . . . . . . . . " " - 1.0"0 13
. . . . . . . . . . . . " " ..... i ...... i - [ / E -
i i
/
_ _ . .................................................. . ...... . . . .
_. . . . . . . . . ._. ..... ... .. ... ... .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -. . . . . . . . . . ... ..... ... .. ... ... .. ... ..... ... .. ... ... . . . . ! ..... I ....... 7-;, . . . . . ._ . _ L_
................................................ ;- . . . . . . . . . . . ~ ......................... -----::--:--~-:----:----:::--:-:::-:--::=--==--:==:::- ............ ~ ............................................. .';......=_ . . . . --_- _ '. . . . . . . . . . . . . -_-_-_
. . /
. . . . . . . . . . : ............ .: ....................... ,,!:':.'.'. ".i : -
: .......... : , ~ / ..... ':':":", ..... :.... , , , , , : . . . . . , .... ":
: i ......... . . . . . . . . . . . . . . . IAInlH• . . . . 00001.
' '~ 4 ~ - :..~
~.~L----..i~!!!"~!!!!!.".'7!RT..--.!"~!! i ! ! . . + . . - . . . ! . . . - . ~ ! ! ~ . " - . . . ~ E . ~ : ~ . ~ ! ! ! ~ E . ! ! i i ! ! ! ! ~ ! ! ! ! t! 7 ! ! ! ! ! ! ! . . - . . . " . - . . . . 7 . . " . . ! ~ ! ! ! - . . 7 ! E " ~ . ~ ! q ~ r 9 ............ 7...": ........................ E ~.--------.~----7.--.'.----..~:.--:~."~:~:.:.:.~::.:.~m::~:.~. 0 0 0 0 0
100
10
..J,~
ID.
(D
&..
(D
(D
I,...
13_
Ik.,,,
O
ID.
> 1 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i
0.1
IIIIIII.~IIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIIII.I~II~IIIIZ~IIIIIIIIIIII ........ l 't t - -
......-|i . . .i. . . . i. . . ...... . . iiiiii/
. . . . . . . . .. .. .
____/ . ... .. .. .. .. ... .. .. .
. ... .. .. .. .. ... .. . . . . . . . iiiiiiiiii
!
,8
Z i
.
-.
1 psia = 51.71 mm Hg
. . . .
i
j
i
fE i
0.01 I
1I . . . . .
i
I . . . . I
1200 1 4O0 1 600 1800 2000 2200 2400
Temperature, F
155
1 O0
m ...... ~ ...............
,_ ! ........................ i .... /iiii,i
I i ii .
LiCI LITHIUM CHLORIDE ......... i ~ ~ j
. . . . . . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . J
,.. : : ;~ . . . . . . . . . . . . . . . . . . . . . .i. _ _ : . . . . . . . . . . . 9
|
9 . , ! ~
. . . . . . . . ~! . . . . . . . . . . . . . ,,._ ......................... 9
0 ~ ................ - . . . . . . . . . . . -,
. . . . . . . . . . . . . . . . . 1 . . . . . ..:::::. . . . . J ............................. ..i
!........... ,. . . . . . . . . . . .
!'; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . "J
j" .
t,... !, . / ,...! L
L ........................ 9
13. ill;;.....................
:iiiii--"i........
L _
0
Q..
> . / ..................... ; ;;_-
0.1 ! M J
,6 .......
......... ~ ....................................................... J m m ~
,,L, "' ........ L/ - .......
/ ; .........
/
i l 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
t
0.01 i i i i I
1400 1600 1800 2000 2200 2400 2600
Temperature, F
156
1 O0
|
... ,,
10
, ~ ~ ~............. ~ ...... ~,!..........~ ............. ~ i ! ~............................
~,~..........~ ........ !~! ~!~i~!~:
_ --;i ..... i ....... i-ii ............... 1-71 ..................................... 7~ ......................... i..................!-'-i...........
ID.
(D
I,---
:D
lD
(D
(D t ' t t -7"
//I }
i ,
'
I
i
i
,
i
r
13_
~qI.............................................................................................................................
t / !!.......................................................
. il .....................................................
. 11 ................
0 I
!
i
I
,
O.
> ,, ! I
. . . . . . . 1 ,,
0.1
i
ii . . . . . . . . . . . . . . . . . . . . . .
!
i
t
0.01- i ,, !
I
1800 2000 2200 2400 2600 2800 3000 3200
Temperature, F
157
1 O0
Bill
m ~
LU LITHIUM IODIDE
'I . . . . . . . . . . . . . . . J,
/
/
10 l
/
f ~ f --
,,m
Q.
/
U~ . . . . . . . ~ E i,i ' ~ "~iiii ........ ii ....... iiiii~ ..... iii'i iii'i iiiiii! iiii ..........................
CD ,/
13_
j/
t,.. Z
0
Q.
>
/
/
0.1 J /
/
ii...... /
/
. . . . . .
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 -
1300 1400 1500 1600 1700 1800 1900 2000 21 O0 2200
Temperature, F
158
6ST
3 'eJn],eJadwel
00s 000~ 00s 0008 00s 000E 0 0 s I. 000 I.
I , ! I ! ! l !
i I 80-31.
...................i! ................. i,!--- ..........................
i............................................
[..................................
i ..................... I
............... ii, i:21_i i.... ii........:2111........ [ iiiiii ...... Z I _iliii i___iiii.....i_i i:i ii
-- : I ...........
2 ..........
Z,2L22:2 ........
1_2111 ......
: : Y 2 : ..............
:i: ......... 22___:_222~
212:/Y:2__:II ........... I::::
....... : f : : : - : ~ S : : : : ~ S S - - - S : : : . ~ : S : : : : ` ~ : : S 7 S : : ~ 7 S . - - Z : : : : . ` . : : : S : : : : : ~ : ~ 7 [ : : : ~ ? 7 ~ 7 S ` . ~ : : S : : ` T ` 2 ? : : 2 : : ~ 2 ~ 2 ~ : ~ ] ~'
:J Z:ZZZ2_.J2Z: L:: LZ:LZE_-
~ :Z:::2 2::: 7:7::::: 22 1:L1 ZZZZ ZZ 2777:1272-Z:777:7727Z__:22:2ZELLL2ZZZZLZ:7777:77:]
6H uJuJ I.L" I.s = e ! s d L
i ~ ~ /~
/..o-=! I.
ed)t s = e!sd I.
................. i ............................................................. ! ............................................................ ! ...............................................
_/.,:
............ ~ ............... i. . . . . . ! .... L I
...............................................
- ........:L .............................: ....... __i., ........................ I ......... :: ::: _ _7:::, .............. 22 :_ _/.__: : :: ___:7:77::7:__::_: : .......... 2::: ..... :::::~::::::: 777:7:7::__:::_:: ........ ::::2:: :::::::::::::::::::::::
' .................... T; ............................... i ................... = 9 0 - 3 I.
i !
_._i ............................................... t
L i ! .............. :I]711:::YTI::7:::II771Z77- .......................................................... ii ...... i_"_21:
i ! -s I.
I i
i 1 ]717
l!
" i#
<
.... ! I ...... 1 .... looo'o "13
..... = ..............
i 0
"'I
-T .......
............ 222._I .......
21_1.......
:22: .........22_:_!12222::Z_II_II .......
/ 2_::Z]2Y::IY 7O
........ 7____:L.I .......] _/121 .......iii_:,__iiii:~i. I__11121Z_ _ ii I iiii
. . . . . . . . . :::::::_::_:.___ ~ ........ : ::: ...... :::::: ............... :::_::: :_:_____~::: ======================== . ============================================
9 = --- 9 -- = .......
:7::
_s 0
~ [00"0
........................ !
O0
I i L
C
,,,-%
I ..................... :i L-
0
~ 1.0"0 "0
i i 1 oo
llm=
,, i ............................... A__J ............................................... 1....
L ........ IIIIIL]____Z .............. iliii. 21111 ......... 12] .... :]ii-
= . .= : = _ -- . == = = _-= . .== : :== = _-_ - _-= = --= . =:= : === | ::= = --- 7 =:- - ~=7 ~ :=~ = =~i ~ ~~- ..............=",._ - ---~_==~_---._-_=
~ VO
........................................... | ~ i ....22_L~ : / 2 : ..... : _:_:::i
7 ~ . . . . . . . . . . _7_7.. . . . ~:ZZ]2:Z22::I :I/2ZZ:__: .........: __:_::::::: ..... ~.:
. . . . . . . . . . . . . . . . . . . l ..............................__./'1 ........................... i . . . . . . . . . . . . . . . l . _ ]
~I~7_::::72Z~_]:22.-_7_:2_TT-_7~I iii -::7 - __ i :i i: ::L_: :.... 2_:: T:::: i: 2: i_: Y2: :7:17
. -. . . . . 7172:177722'i:22:77711277~ ...... _-_7__:]~:_2_ i .......... 2 s ......... 2 _ 1 2 ] ..... 21 ...... 2 Z 2 ' ........... 2__"_TI21L _i 22 22 ....... i i~
..... OL
: ! . . . . . . . j ................ ' ,
1
|
IAINII~IN7 n7
O0
" " - - - - ' - - L ' ~ - - - - T " ~ T ................................
_. ; I -
- " ~ - - - E ,
- . . . . . : I ............ .............................
_~I__~I-----Z_7---_Z----_~....._L_-_---L_/---__-_-----___~----__
:---~_Z---__~7---___------__T----__~;~
Z-~ ....
- - - - ~ - -" . . . . . . . . . . . . . . . . . . . . '~ r " ~ . . . . . . . . . I
0.1 ..... : ....... . . . . i ~ : ..... : ..... ~.... T : ~ ~ . . . . ~ / - : : .......... ........ : : : - : - - - - - = - - ~ ' - ~ - - = ' ~ . . . . . . . ~ = ................ "-~'=~;
9 - ~ ]--/ . . . . . _ .- ._ __ _ . . . . . . . . . . . . . :
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i J" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- F I / !
o')
, , i
Q. 0.01 --
_
---
__ -
- ---
_ . . . . . .
L~2-
. . . . . .
Z
. . .
__L_Z~---
-
:
_ .
- -- - ~ -.~
I- . .
_4
. . . . .
.
-
. . . . . . . . .
. . . . . - .. . . . I . ~ . . . .
(D
&...
.. .
o')
09 0.001 - .............. .............. /
0L _
- - -___--__ --L -__ -_ --_ . . . . . -2Z_ _'_:.-: ...... - - _ " ' " " - . . . . :-- I" ..... " "
_
. . . . . . . . z -- 9 . . . . . . . .
13_
. . . . . . . . . . . . . . . . . J ...... T 1
- ...!... 9 ~
- - _ .... [ / ~
0
0.0001 / /~/
>
~ . . . . . . . ~ . . . . . . . -:- ......... :..... ' ........ I i. . . . . . . . . . . . . . . . . . . . . . . . . . . .
- /_ _
. . . . . J
/
1 E-06 .................................
............ .
1 E-0811 I I i I I I ' I
400 600 800 1000 1200 1400 1600 1800 2000 2200
Temperature, F
160
1 O0
(D
. m
c~
, !
Y
1
!
I
! i
I I j i
(D
I,... , i
(D i !
!
(D F[ !
n
I,...
0 tt I
Q.
i i
> i i
0.1
I
!/
i
i
f ! t
i ! !
I
1I
. . . . . . . .
oo11
I
i
t
i
!
t
I
[
1400 1600 1800 2OOO 2200 2400 2600
Temperature, F
161
1000
J
100- . . . . . . . |
/
/ r
-,,i . . . . . .
/
/
. m . . . . . . .
C2. /
/
/
L _
r~
r~
O~
r
13_
O
C2.
tO
>
10 L
.... . . . . .
/
J
/
......
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
10 11
Temperature, F
(Thousands)
162
1
........................~ - _ _ : }
~~176
l ~
!
0.1
03
EL 0.01
_._ _._ _. / . . . . . . . . . . . . . . . . . | |
~ i / [ ,
03 1.................................................,P--~
/, ...............................................
0.001 '!r . . = = . ~ " ~ . ~ . ' = = . - - . - - = = . - . " ~ : i: ~ = - . ' . . = . - : = ~ : ~ = ~ " = = = = : ! i
~
03
(1)
t,..,
13_
~----~----~
!._. ---~ ........ --i
0 i : . . . . . F ........... --7
i / I I ~ !
0.. 0.0001 ~_'=.~-.=__--_.~===:=::==f.::"_"='=:'.':::=:".'.:==:-=:=-====:}! ...............................
>
9 , m ~ i t'
- - i ]
!
1 E-06=
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _. . . . . . . ==_. . . . . . . . . . . . . .
b ,:.
!
!
i
1 E-08- t r [ [
1000 1500 2000 2500 3000 3500 4000
Temperature, F
163
100 . . . . L . . . . . . . !
1
- |
MnCI2
MANGANESE
MnCI2 M A N G A N ECHLORIDE
S E CHLORIDE
I . . . . .
/
/
10 L
......... | f
I 7
/
/ . . . . . . . . . . . . . . . . . . . . .
. . . . .
I:L
f
O9
(D
1 .jj/
J. . . . . . . . i ..... i iii! .... iii ....... i ~
I..., I
CL. J
L_ /
0
Q.
cO
/
>
/
/
0.01
1300 1400 1500 1600 1700 1800 1900 2000 21 O0 2200
Temperature, F
164
Mo MOLYBDENUM [-----1 ! ! 1
0.1
I
0.01 ! .................................... ],
0.001 ~'-.-----------3-~
.==-'.""
-.-..==.
...... .--=.:-=::""-:::!~.."-.!~--~F-:.-~.---:..:.=.=--===:{!!|!H~=======:=:::=:====~:
,m i if ::=:::"-':'-:---'::'!~:":!~'.=-'!!'~"!!::::::~F~:-~-59-"~'~!~E~!~!:I
09
Q.
i
0.0001 9 1 ........... ,L . . . . . . . . . . . . . . . . . . . . . . . . .
(D
~L__
co . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . i i! i
. ......
i
(D
K.. :~ -* :I
n
i __, I i '!
&.-- ...........
I i i i
O
CZ.
>
1 E-0'
i9 i
.
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
'-
i
1 E-08
! !
!I ~ t, tt
! i i i
I/ I ! i i I
:"!:.::=::: ."-.~= = =::=::::::=::-"::.".::::::--.:::::::::::
~ ::::::::
= ::::::::::::::::::::::= r.::.T.=::.~:::~.i=.-..%.--.::
.-u:::::::.-:=::.-.T.:::.~.T...':=
..-:::::::::::1
1E-1
- - - ;
[-~.= } i
-i--
'
t
,
,
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
1
1E-11 !. . . . . . ==~: .~. . . . . . . . . . . . . . . .
{ 4
1 T
t ]|
-- t
1E-1 I i [ i i !
2000 3000 4000 5000 6000 7000 8000 9000
Temperature, F
165
99I
-I 'aJn),eJedwal
O0 08 09 O~ O~ 0 OE- 0~- 09- 08- O0 r-
1 LL0"O
/
6HWW LZ'Lg=e!sd L /
edM ~68'9 = e!sd L . . . .
/
....
/
/
,,,
VO
"tJ
0
/ 73
/ 0
r oo
oo
0
o0
m =
./
7
/
....................... L
........ . . . . . . . . . . . j
ki , .... . ....... " ' " . . . . . . . . --01.
. . . . . . . . . . . .
J
._
I
~ 3alHOn7..-I la17N3as,~70~ 9_-IO~ .
1
I
! ,,
' :---00
1 O0
::. ...... :: ~:::: ............ ! I 84 i }i:........... ii .
m i
.........................
|
[
10
i i ~-5,"-.................. [ .....................
4
.g
c~
1'
j ......... .
~ ' - ~" _
...............
|i !"
i !/ I
t / r " i i
u~
_- z ........... ~___ 121221221112221
............ [i./i/-_- _~
(D
tkm
/ ........................!......................... ! . . . . . . _j
13_ ,! /
&=. it"
0 /!
C~.
>
/ I
I - - [
i / .........!.... !
t
II II
i
! !
OI I ~_L i iii/ : i !
!
r I psia = 6.895 kPa
[_
!
I psia=51.71 m m H g
!
! i
0.01 I
l !1
I I i I I i i I
1300 1400 15OO 1600 1700 1800 1900 2000 21 O0 2200
Temperature, F
167
1 O0
NCI3 N I T R O G E N TRICHLORIDE
10
/
. . . . . . . . . . . .
u) ./
.,n,,,
(1) /
u)
u)
/
Z
(D
/
13_
0
CL
r
>
/
/
I
/
/
/
/
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.1
-50 50 1 O0 150 200 250
Temperature, F
168
100 1 1..... t t i
!
| ! l
! i ! .... . . . .
l .........11..................................................................
........ ,,
...................................................................................................... I - 'l' ,
1i ...............................................................
'
i !
[....................... I
O9
i .
F
i
l
+ /
L_
, ' ' I j
L_
] ......................... ! --T---JJI ' ~ ! i, ]:.7 ~ ..... 1:
', ............... .................
i ..................
13.
-I ..............................................
i.............................................
i .......................................
i i .........................i ..r " i
0
] ...........................t ......... i .......... I................. i........................ +,i-~ ]
>
l+++++illlliillil ++ ++illi i i+i+ i .... _-T .... i !
1 84184184184184
- i
.......... ...... ...... ......! .................. ,
/ i i !
i
' ! I
1 I ,
I
I
-110 -1 O0 -90 -80 -70 -60 -50 -40 -30 -20
Temperature, F
169
1000 l ,]
L _ _ _ : : L L L :L____:::LL: L:_____:LLL . . . . . . . . . . . : : : : i
t t t
100! .......................... - - - - - - - - - - - - - . - - - - - - - - .
~ . . . .
/
/
10 .
1
~ . . . . . . . . . . . . . . . . . . . . .
/
1
. . . . . . . . J
03
..,m, L . . . . . . . / z
CL /
/ ]
/
:::}
/
t__
o3
0.1- l . . . . . .
(D
t__
_
13_
/
O
Q.
/
> 0.01~
/
/
/
/
0.001 /
!
I
_ I
_ !
0.0001 .... ~
i: :~: ~i!J1ps'a--6895kPa 1 psia = 51.71 mm Hg
[ ......................!
1E-05 1 i
I I
r
-350 -300 -250 -200 -150 -100 -50
Temperature, F
170
TLT
-I 'aJnlejaduJel
OOg Os OOg OCj I. O0 I. 09 0 09- O0 L- 09 L-
I I = !
I I.'0
!
i i i
! !
6H u.luJ LL" Ls = e ! s d L .....
ed)1968"9 = e!sd L ....4
I , i
::::::::::::::::::::::::::
;;;i~,17~ii'171111111-i
]17]i]i]]]]i'i]i]]]i]
{7] ]]]]i177{]77]7]71117~
i'!'7{7117]]1]]]]]]]
71]]1111'77777{]
]]'7]i!']];7]]]]
............................................................................................................................................
I "
I
.............i .......
[ .......... r ............... 3 - ~ . . . . . "-
I i ' / _ _
................... i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ ........................................ i ...... , . _ _ . __
............. T ............... ] -
! ..................I ................................ ! . . . . . . . . . . . . . . . . . . . . .
iiiiiiii17711111111111771177~.................
iiiiii~iii i #......iiiiiiiiiiiii 7..................[i:::::::::::::::::::::::::::::::::::::::::::::::::: _- <
1........................... ~' .........................................
ll)
..................... ;7.__]__.]]7]]]]]]]];7;;]_-]]_777]]777]] ........ L-_];;;];;]]L_LZT]7;]];];];]];]Z777-Z ]]Li;]]71717]]]]];];];L]L_;777];;];]]];]]_ ZTT]]7]]]];
01. "13
0
'==II
. . . . . . . . . . . . . . . .
..................... 7 1 "13
"==i
l i'D
......................... i I
......................
(#)
! '==I
. . . . . . . . . . i, . . . . . . . . . . . . . I---/-- . . . . . . ! .................. ! ................ t ..................................
.......................... ,i i'D
O0
~ a
l:i)
l " :' ; :-: ; ~ - ..." - - i
000 L
::::::::::::::::::::::::::::::::::::::: ! ...........................................
z_; ::::::: :;;i iiiill V I N O I A I I A I V s ::::::::::::::::::::::::::::
I -
, ~ .... r .............. I..... : - 0000 I.
ELI
3 'eJn},eJedLuel
OtTE OEE 00~ 0 8 I. 0 9 I. 017 I. O~L 001. Og
L i L L LO'O
. . . . . . .
uJuJ L L' l.Cj= e ! s d L
ed)t cJ69"9 = e ! s d L
i
Z
L'O
<
"(3
0
-0
/ CD
(/)
(/)
(-
(1)
r . : ,.
"0
I .
,,; . . . . . . . . . . ;
I
i
! ...... i
~j./- .... ; .- .
OL
/
i
.....
!i i
_ _ _ _ _ . ,F :INIIAIV-IAXOhlCIAH OE:HN
i
.,, [ .................
1_........i_i...................................... ii t li .......
-00 L
1 O0
] ]
H4Br AMMONIUM BROMIDE
10-
,=
. m
] ........ "i t
Q. i
(1)
'F/ ii
L_ l
i /
.A I, !i!
U3
03 _
(D
T
!._
n
L_ i I ,
O
Q. I
--i !
r ........................... t
03 i!
> !
1 i
!
I!
!
0,1- L. . . . . . . ,-!--- ........
=.
=..
i
i ......................... i
!
i............................... i 7"
I
!
........ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g
! i i
........................................ i ...............
!
I t
! i
0.01 -
350 400 450 500 550
i
600 650
t
700
i
750
Temperature, F
173
looo:l[ ] [ t
NH4CI AMMONIUM CHLORIDE
~
100-
. m
or)
Q.
L_
ffl
ID
>
10-
.=
.=
.= J
___/
~
I
111psia=51.71mmHg
psia = 6.895 kPa
1
500 550 600 650 700 750 800 850 900 950 1000
Temperature, F
174
100: ,., ........ I I
i
[
. . . . I i i
CD
li.
O
ID.
> ! / ii......iiiiiil/iii'i'iilJ
..........................................
i ............. i
. . . . . . . i ....................
t .............................
i Ii
I |
0.1 -
"=- _
,iiiiiiiiii;;;;.___.iii;iI/7111171;7;77--ii
~ ~
........................ i ...................................
I
I.........................................
"i&
/
i
i . . . . . . . . . .
175
1000
/ J
100
......................
/
J
/
/
.I
Q. /
(D
o3 10:, I m
IIw,~i
13_ ~m
O /
Q.
/
>
/
,/
/
7, 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0,1"
-100 -50 50 100 150 200
Temperature, F
176
100] ...........:::::::: .........JI ........ ~ iiiii:iiiiiiiiiiiiiiiii~!
I
........ ~~iiiilLiii ~):::
I
~iiiiii~ii::i:::: ! I . . . . . . . . . . . }.
!!!!!!!!i
,o- !
1 .............. ______i.....___i.... ,
2 i ........................................ : ....................................'
)
........................................... "F.i 212 ,, :,,,
, m ............................ z ......... ,
if) 'I I
c~ i , i !
!..__
,1 ' it /
i i
i
O9 I
I
i
t
!
i
L_
i............................ !
) t
I !
0 I
i I
> z !
i j
I i
i I
I i
i i
! I
0.1 ! +
I ............... . .t" r[ T!
i ....................................................i ............................................! ' '
. . . . . . . . . . . . . . 9
! !
| ..................................................................................... i
i !
)!................................................... i'
6
1 psia = 6.895 kPa
I ,
1 psia = 51.71 mm Hg
! i
ii i
l! !
o.o11
! !
I I I
-60 -40 -20 20 40 60 80 100
Temperature, F
177
1000 I ....... ~ f
I 1 I ! /]
NO NITRIC OXIDE i J
Il /
i ......................!.............................
/
/,
1 O0 i iiiiiiiiiiiiiiiiiiill iiiilZiiiiiiiii
i iii III/ZZIZI]
to
. m I /ZI .......
iiiili
rJ)
C~.
-7
/
Q~
/
7.
r~
O~
l/
13_
/
L_
0
C].
tO
>
10
/iiiiiiii iiiii
/
Z
/
11 1 I i i i
-280 -260 -240 -220 -200 -180 -160 -140 -120
Temperature, F
178
Vapor Pressure, psia
----L
--~ 0
,.,,.,IM 0 0
0 0 0 0
, -,. -" 0 0 0 0
I I I II I I I I I IIII I I I I I I I I III I I I I I I III
0
~
...........
_o
Z
r~
01
-4
G)
o
-!---iliii i
G)
r-@
,ii!!I
i !ii ,it irlii
! i
I ' iii I I9 I~
i
i
"11 , !
! ' , I
jl !~I ,
' ill , i ..- I i
!J! i
" ''! i
.......... ~"- 9 iI
IX)
44.." ........................... i
i,ii i
0
0 i !i~ i I I i ii
i''." i
iI iz i: :i
9 . I i
-- iii i i i
~~ iii
i,I 'i i I i ''
II II i ~ i
i i i !
~I! l i
01 (:~ -'t"H', ............. ,...... "-'!' .....4 ....+-"-!
i:::m If! i
',,I
9 r I
0 i
--'- r
i!i i
ill i
! i
i I
! i I i
9 i!i I
0
0 ! I
i I iiii
i i i iJii
i , i
I
ii i! ! '
U1
0
I iii,
1 O0 . . . . , ............... ~ ............ ,
I
NOF NITROSYL FLUORIDE
................ i
.................. i
11:1
.m
I:1
. . . . . . .
! k
.,,
i '
!,.._
1~ E .......... ./,,
(D
13_ /
i._. y ,
0
I:1
/ J ! .......................... i
!
>
/ ,i
0.1
!.............................
J~
/
/ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g
i
0.01 I I I I
-220 -200 -180 -160 -140 -120 -1 O0 -80 -60
Temperature, F
180
10000 ......... I ....... ! ........... | , !
J:i . . . . . . . . J .... I:ZII ii ......... I
- ................................................. t ......................
I ! .....................-1--
.i.................... !
J /
I ........... I...............
i i .............................................
............... I i .....................
~ .................. i. . . . . . . . . . . . . . . . . . . . . .
.......... : - + ~ ................I
. I
.................................................. I
I
i
i
i
!
t / i + i
9i YYIA: ....... iii.......................... T - - 1 _..._+ ....................................... l ...........................................................
J. . . . ! I :/:i i
s,__
fl
J .... ~: ........... i:..... x / : ......i'
................. .......
.....
::.....:..'..- - .....................
--7' i__
0
J_............................. / 1 ~ l
>
o l ...........
I vn: :: :+:+--+........ : ................ :
i/ t ~
i
_
i
+.........................l . . . . . . . . . . . . . . . . . . . . . . . . -.,--
i
.......................
~
f. . . . . . . . . . . . .
I
~.--
J ..................... ~ : i : ............. i ............. ! ................... ~ . . . . . . . . . . . . . . ~ ......... ---r--
I / i. . . . . . . . + ............. + . . . . . . ~. . . . . . . . . . ---r--
---r . . . . . . . -t--- . . . . . T ....................... +................... - + -
" F - - - F - - I - . . . . . . . q - - - - ............ .................................
9 + ............... 4---
~_~.._~J/_. , , , i
...................... i .......................
---+ - ' . . . .
'i_ :'.." .__i ....... - -- l " l 1 psia= 6.895kPa
J ............................ J l + I psia = 51.71 mm Hg
............ + I
i i t i
9 i
. i '! !
:
1 I I I I I
0 50 1 O0 150 200 250 300 350
Temperature, F
181
1000
N2 NITROGEN
. . . . . . . . . . . . . . .
. . . . . . . . . . . .
J
. . . .
y
./
/
1 O0 ~ i/
/
, , n ii /
,,F/
ID.. /
(D /
/
/
I----
(/}
ID
13.. /
O /
/
O..
>
1
|
!
/
/
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 m m Hg
1 I I
-360 -340 -320 -300 -280 -260 -240 -220
Temperature, F
182
1000.~
t
~ N 2 F 4 TETRAFLUOROHYDRAZlNE
1 OO=
u~
. i
Q.
|
(/)
(/)
(1)
L__
n
o
Q.
>
0.1
................... !
0.01 ,i
4 1 psia = 6.895 kPa !
[
1
i 1 psia = 51.71 mm Hg
i
t---"--'-'-"
0.001 -
1
!
T !
r l
i
-300 -250 -200 -150 -1 O0 -50 0 5O 100
Temperature, F
183
10000
........... . ..................... +. . . . . . . . . . . . . . . . . . . . . . ... . . .=.. .... ... .. . . . . . . . . . . . . ! ............. ,. ..................... 7Y~, ..................... i
N2H4 HYDRAZlNE
!
.....!' ...................... ..........
1000,
100-~
; ......... ; - ,, i:, / .... :i: '"::::::':............. !
.t'~__ ~ ~ ~ . . . . . . . . . . . . . . i /. .... i i IZ ii -'
~
m
/
I~
10, ~ ~ ,+/
,:,
.......... ,,:,, ,,: ............................
.. . . . . . . . . . . . . . . . . . . . . . .
m.. .,.:,, :
- : : ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
/.' .............
E / : : : ................ i
0 r ,/ !
>
' / - p +
--_ - ..... = . . _. .: . . . . . . . . . . . . . . . . . . - ............
o.o17 i 1 t t t ] 1
0 1 O0 200 300 4oo 5oo 600 700 800
Temperature, F
184
I O0 9
............................................ "I
i / /
10- I t
oo
Q.
..................................... |
(D - t 1
I,i
13_ ! I
IL_
i t
0
i i
>
1 i
i
I................................ T
I
I
J i i i
I I
0.1 L ..___~ i i
......... [ :i
_- Z' ' ...... m J- i
_ L ....... I ............................... i. |
9 / ! I
!
__ / i !
1 psia = 6 . 8 9 5 k P a
i .......................... i ...........................i 1 psia = 51.71 m m H g
i i
!
,
', !I
0.01 1 !
i
i
i l
.
i I
-60 -40 -20 20 40 60 80 I O0
Temperature, F
185
100
1 i/
LIL::L:: i: / ~ ..............................................
7 ~
/
J
,,m
y
ID.
(D
1.-
In
(/'j /
(D
l.-- 1
/
l.. . . / ..
O /
/
O. /
>
/
0.1
/
/
F,
/
/
/
0.01 I
-20 20 40 60 80 100 12O 140
Temperature, F
186
1 0 0 0 0 . . . . . . { ....... , ! ..........................
+ . . . . x o + ~ ,,,,,,_+
i
i
.: . . . . ; . . . . , ...................
L++++ii+..................
+i _iii iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii~-i ...... ~ ~ ....................
ID
o9
13_
O
>
100-
!!!
t i
i .'.
..................... !/
i ii + ................... ~ -
9
L 1 psia = 6.895 kPa
=...........+ 1 psia = 51.71 mm Hg "
lol i i i , ,
-150 -1 O0 -50 0 50 1 O0
Temperature, F
187
1 0 0 0 0 C...... ,,~,..................... ,,, [i
i~ '
lee ......
y , iiiii?;ii,
2"
. i
f.t)
c~
_
(D . . . . . . , , .... ' ,
::l
I
(/)
(l) I /
13_
B nm '
0
m m
~' ,, / " r.
c~
>
V . . . . . . . . . |
" ,"/..
0.1- i ii/
/
0.01 /
........ 1 psia = 6.895 kPa
,,
..... 1 psia = 51.71 mm Hg
0.001
-200 -1 O0 1 O0 200 300 400
Temperature, F
188
100-
.mt~
r~
c~ 84
Q~
10-
O~
13..
0
Q.
tO ........ ~........t ............................................
>
/ ii
""'~""-'- "='~"~'-'~"'- ml 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i !
20 40 60 80 1 O0 120
Temperature, F
189
1 O0
10
......... f
J
ii.... i ..... 1. . . . Z / ..................
. m
O3
Q.
/
/
t._
O3 /
O3
(D
t__ /
Q. / L ,
/
t._
0
Q.
> Z . . . . . . . . . . . . ~. . . .
, , . . . . . . . . . . . . .
0.1 /
, / , 1
p -
/
/
/
n 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 I
-40 -20 20 40 60 8O 100
Temperature, F
190
10000~ .......................
~........~.........~.....=_.: ......................................................................
i ....................... ]
1000
i .............. i
1000~ . !
, .....
I i
..i
-~
i:.:-:~:..:-:.:m::.:::..:-:::..:.:-:-::::::.:..:-:.:...=::....~..-....--.::..-::.=i
f-- ...........................]
.m
c/) 0.1
r~ 2
e~
(1)
!.__ I I !
0.01
c/)
i
T.................................. ?4,
c/) 9
(2) !
T
!
n 0.001
!.__
f ! i--
o [: i'f.....................................i:
r~
I i '
0.0001 ,L.
>
i 1 1
|~--~---:..............
:=:~...~-~:::~:::..-::~::..-::."~=::~:=='.T.::::.--m:::x:::::r.::.':.-_..::==
,8
.z:..::=::::=.~~
L. . . . .
t . . . . . . . . . . . J:.................................
t ........................ ? r
i t i
1 E-06
~ m
i ; {'
I i I
1 E-07
:, mm.o
i---------i !
! i !
I i I
0 500 1000 1500 2000 2500 3000 3500 4000 4500
Temperature, F
191
1 O0
10 /,d'
/
.......... 7
/
lj 7
,m
O9
CL 1 /
/i
/
/ . . . .
/ 9
(1)
L_
cO
L_
13_
0
Q. 0.1 /
> /
/
|
/
0.01
/
]
0.001
1200 1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F
192
]
NaCN SODIUM CYANIDE
i r
!
tO
t I
. u
t
C}. i !
0.1 ................................... J
(1)
m,
::3
t~
13_
0.01 -
0
C~.
I
j 9
cO
>
i
0.001 - -
__,
_~ ...................
====:~ , .,
..................... I :;
"." 4
I !
0.0001
i
' ! ! t
t,
t,m
:E'
i :1'-: 1psia=51.71mmHg
i ' ! T
i
!
t
1 E-05 ! T
1000 1200 1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F
193
1 O0
,o 1 I I
,,m
..
ID... u
(1)
l..
(1)
I,.,.
l&..
O
ID. 0.1-
>
0.01
:i:- 6.8,5.Pa - - - -
= 51.71 mm Hg ................
...,,,...-
0.001
1400 1600 1800 2000 2200 2400 2600 2800
Temperature, F
194
1 O0 ....... ;' I;.,.,F :ii . . . . . . . .
10 . . . . . . .
J ._.
. _ i l
, t /
t
...................
.
J
IllZIIi ~
, .................. / [
......................... / i I
i
. m
Q.
III
ml _IZ ~ 9
I
P
/ ii
/ ! ...........................
! ............
i i !
L . . . . . . . .
9
(D X
/'
/
I
(D
D_
i
0
Q.
I
0.1
!
> / !
i
!
.......................................... i .................................................
:
',_ ..............................
I ...............
:Z
! .........................
1.........................................i ....
i ! ..............................................., ...................................... !
i
/ ! ... I
i 1
/ 1
I........
t
!
0.01 . !
! t | ..........................................................................................
! 1 | t
~" ..................... i ................................... ,
| "- i
L
|
!
..........
.................
..........
I~.........
........ I psia = 6.895 kPa
! ...........................................J - 1psia=51.71mmHg
1 !
I 1
i I i
0.001 i i i
1800 2000 2200 2400 26OO 28OO 3000 3200 3400
Temperature, F
195
1 O0 I ,.
I
,,
/
f
10
J
/
/
/
ltl
. m
c~
J
e,,
(1)
/
/
(D /- j
13_
0 /
CL /
>
/
/
0.1 /
/
Y
/
/
/ 1 psia = 6.895 kPa
1 p s i a = 51.71 m m H g
0.01 - I
1400 15OO 1600 1700 1800 1900 2000 21 O0 2200 2300 2400
Temperature, F
196
100~
10-
1-
, m
co
0.1-
7 ,
1'!'
=.,
.,,
I
I
i
o.oi~ i.
cO .,.,,
ffJ
0.001-
0
>
0.0001=
=. i
I
1E-05- t.
=
l !
I i
! i
. . . . . . . . . . . . . . . . . . . . . .
1E_071 ! i
500 1000 15O0 2OOO 2500 3000
Temperature, F
197
1 E-06
1 .... J................. !
Na2SO4 SODIUM SULFATE
.m
09
E).
e~
Q)
t,,.,,
J
u) _ / _ "
u) 1 E-07
/ i ~ ' _. ......... .. .......... ........
13_ i 9
L_ 5i- -
y,,d,~,
0
C).
> . j f
/
f
1E-08 I i I i I I
1650 1660 1670 1680 1690 1700 1710 1720 1730 1740 1750
Temperature, F
198
I00~ .................~ . . . . . . . . . . . . . , .... ............... i ...... .. . . . . . . . i,, ~.............................. _. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . ~ .....................
~g....~___:_:_:_:;_:;::_::_::;:[:::;;:~;; ..... :: 1l - ...... ~-:~7
~-_-:--_
_i . . . . i
. . . . . . . . j ..... I
i t I......... '
9 _ .... !
, . , . . . . . . . . . . . . -. . _. . .1 .
!
!
.... ' ..... i ....
: _1 N b NIOBIUI~ M
] ! i .......... ........................
i .........
I
10! ..............
_~. . . . . . . . . . . . . . . . .
' ..... :
". .......... :':. !' ...' i:ii: , " I
i ....
: ' :':]- 1 ,
i
i
1 ~.: ..... -.......... ;--]
| ..... I
I .... !
i
t ,
0.1 ~,...................................
JJ ................... i
. . . . _ .... T . . . ~ ~ . ~ -=:-4 F
I . ,
,,, - ....... " I
.G:I J
03
lz 0.01 ..... ~ ........ ~__+
J
|
: ::: ...... : ..... ' i T
I.__ JJ ........... i. . . . . .
9 ' ' i
i I
::3 j ,
O9
1
!
i
0.001
9
....... , ..... | T . . . . . . . . . . . . . .
11,..
i
r
L__
0
0.o001 i
- - i .......................................
i.......................
i
i *
i
1 E-05
I / ......
..... A.. . . . . i
i
! ............... - ...... t
i i
!
1 E - 0 6 .................................................. ~/
,:
,
..........
, ....
/
./
i
....... : ,, ,-, ,.....
................................................
-III:Ii:I::T=
.................................. T-'!
i ...........................................................
i.... 1 psia = 6.895 kPa
- / -~ |
' /, E !
u __ ============================ . . . . . . . . . . . . . . . : ; ; q _ ......... :::-~:-'::;~;;~;:~!'~!!;!::: ;::4 .................... :::..:' ~'::: :~ . . . . . . . .
;~!:-=i~!iii~!::-- ~.~ 1 psia = 51.71 mm Hg ~.......................................
~ ~ ;
". ' :~:~::i ........... : i . -' : ........................... ::[::::::
-- - : ! l . . . . . . . . I ....................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
! .................. 1..................
! ....................
,
1
1 E-08 I I i i i
3000 4000 5000 6000 7000 8000 9000
Temperature, F
199
3- - I It t | ; ; J
,j .......! ! ! ! _
......
] 1 1 I I / 1 1 "
_1 l I [
9 ' ir[ '~ . . . . . . . .
-- l | I J" I . . . . . . . . . . . . . . .
~ ~ ~ , i ~ I . . . . . . . . . . . . . . .
1 l ..... l___ ! / 1 I ' ",.... " I . . . . I ....... "
-9
~
s 0.01
] J l . . }/ . l9 . .
"... ~ -
.
..........4
t 1
........... [ " r - ~ ........................... --:..:::-:--L.:.:.- .......................
] i ..... ]_ _ ,,,i I ' i .....
m 0.001 . . . . . . . . . . . . . . . . . . . . .
: ; .... -_ : _:_ :~ / i
'
i .......
,. . . . . . .
:::::::=.:--- ,. . . .
(D
I,..
I I l ~ '
I i .............. ]/ i I [ , ,,l ......
13_ ~ ...... _ ~. . . . . v ~ 1 [......... :..:..........
[. . . . . . . . . . . -.
_9 l~ _ I _ _ A t I I ..... I . 1 -_,
o ~ I /1 I I' ! ] ! :
~ . . . . . i ! I [ l - I .....
- ,
_-:l l . . . . . . . . . " ~ _ _ _ .
[
r-
......
.. . . . .
: .......... .t::-:l
:[~.'_._-_. .L ....................
.t l . . ! .... I.
1E-08
Ii Ii !I
1500 2000 2500 3000 3500 4000 4500 5000 5500 6000
Temperature, F
200
1000
IZII~I~I'II
...-]ii
.....
I
f
L ~ . . . . . . . . . . . . .
1 O0 i .....4
i ~ i~i ............IZIIIIIII'ZZZZIIZZZZZZZZZ]ZII --I
. i
u~
...... i
-
]..
i
! t i i
.............. i ........... i- !
(D i
i9
I
!
ix -
(D
L_
>
IOE . Zi IIII!ILL2"~~:TI .........i
IIL2L]IZZ~Z21ZZI ...........V.......................................... 1
]IIIV ii--ii_ ]i ', ............... 1
I
/ i ........................ i
9................................ ! - - - . . . . . . . . . .
!
!
!
f
i 1
1
t ,
z
t
I ' 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
i ' l i
!
t
I I
i
i i
11 i
-415 -410
I I
-385
I i
-420 -405 -400 -395 -390 -380 -375
Temperature, F
201
1 O0
: ...... t :
Ni NICKEL r ]
:
L.
=,.
i ;' . . . , :-, /......~ . ~,--"~
;. . . . . . . ......
.. ,I
i'
]
0.1--
~ ~L~ ~ iii ii;ii iii .........C........;ii ii~....... i; ii :'"'~ZI.....
~ ~ / i i i : .......:iii..... :ii i:iiiii:iiiiiii iiiiiiiiii ii iii iii i '
i / iiiiiiii ii iil Liiiii iiiiiii ................. '....
= m '/
O3
(D.. 0.01
(D
03
03 0.001
(D
t._,.
13. . . . . .
t,,.._
O
ID,. 0.0001 - ~
>
1 E-05
1 E-06
1 E-07
.............!.iI 1 psia
1 psia
= 6.895
= 51.71
kPa
mm Hg
1E-08 I
1000 1500 2000 250O 3000 3500 4000
Temperature, F
202
1 O0
!
!
i .
10 .......... ] ................................. ]
............i ................................i ..............................
-~__C~ _ _
i m
_.__._____~_~_~~ ____._
Q.. .
1 , !
L _ i ] i
/ --
(D
13_
o
Q.
9 i
I
>
............................................................
!................................
!
-! .............................................................. i .................... .~
t ~ ~ t
i i , ,
I i : t
I |
i ...................... .--4
i i
t! i!
O.lt i i i ' i i
-20 0 20 40 60 80 1 O0 120
Temperature, F
203
10~ I I !
!
!,ii ......iiiiiii.......7 ~;
ltl . . . . . . Z
. . . . . . . . . . . . . . . . . . . . . . . . .
i m
CL
(D
IB
/
j
J
L_
13..
/
L._
>
0.1 t
7
7
..... . . . .
0.01 I
1950 2000 2050 21 O0 215O 22OO 2250 2300 2350
Temperature, F
204
0.0001-,
,.I
!
Np NEPIUNIUM
1 E-05 , ,
,.
I
..........................
i
Zl.
i
S ....................
.
ell
n
i--- i
el. ,x ! !
(D
:D
7i i I
1 E-06
!
i
(D / , f
/ /
!.__
r 1
L_
li
/
i. . . . . . . . . . . . . . . . . . . . . . . . . .
...........
O !
Cl.
/ ! I
. . . . . . . . . . . . . . . . . . . . . .
> I
i
I i I
i
! ....................
i 1
1 E-07-
/
/
.... ~" .............. ,
/ I
-
......
,,, , /
P"
,ii ! ....... !
- /
i"-'~i 1 psia = 6.895 kPa
i 1 psia = 51.71 mm Hg
I i
! i
1 E-08 I I
II
2400 2500 2600 2700 2800 2900 3000 3100 3200 3300
Temperature, F
205
1000
02 OXYGEN
100-
==
..=
u)
Q. 10:
(1)
:3
(D
L_
13_
L_
0
EL ...,
>
,m
0.1-
,==
~ ~ kPa
mm Hg
0.01 - [
-380 -360 -340 -320 -300 -280 -260 -240 -220 -200 -180
Temperature, F
206
1 0 0 0 ~
OZONE
100=
10=
z l
!
_
I
. m
i
!
i
! T'
!
4,
ffl i
0.1= . . . . . . ! ................................
13_
0
F 'i
i
I
> 0.01=
r i 9
i |
0.001 =
-_ q;
~ .....
!
0.0001
! !
1 E_05t 1 [ i t
-350 -300 -250 -200 -150 -1 O0 -50 0 50
Temperature, F
207
1 O0
0.1
e m
03
CL 0.01
(1)
t__
::3
03
03 0.001
t__
rl
t.__
0
Q. 0.0001
>
1 E-05
1 E-06-
w
1 E-08- ]
3500 4000 4500 5000 5500 6000 6500 7000 7500 8000 8500
Temperature, F
208
10
|mm
..... 1 2
i
ill
I
e3
. a
J
(o
O.
0
J
00
00
0!---
O_
/
/
&,..
!" ]
0
O.
>
ii . . . . . , , , !
Temperature, F
209
1 O0
...... t
~ . . . . . 11".'"i.i . . . . . . . . . . . . . . . . . . . . . . . . . . i
10
./
. m ...........
co
Q.
(D
(D
!,--
/
13_ i ~ii iiiii ii i i
t,.,.
0
ZI / ..................... i
Q. , .... q
>
/
0.1 Z
E
/
/ . . . .
/
Z
/
i 1 psia = 6.895 kPa !. . . . . . . . . . . . . . . . . . . .
1 psia - 51.71 mm Hg !
f""l
i
0.01 i i I
f
I
o 50 1 O0 150 2OO 250 300
Temperature, F
210
1%,/%,./_I I _ I
3-III+~11111U11~III11]
_I_ZIIZ_ZIiiiiiZJ Os04 OSMIUM TETROXIDE-WHITE
]iiiiiillliiiiilllliiiiiiiiiii+iiill.........i:..... !+ II==:::::ILIL::I::III::_+__:I21:/221L
+++:+......+:+::+++++++++:
:++..............
++++ i++F~ ..................................
{ .........
. , m ] i+i++++iiiiiiiiii+i+iiiiiiiiiiiill;il
illl iiiiiiilill..........................................................
c')
]iiiiiii2111____i
iiii___ili21li_~-
_i___i.12 !!!i!!!!i-..................................
s,__
t
,! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . -,
I,__
13_
'L_..
--"i .................... i
0 ] ..........................................................i............................................... 1 7 .................................................. ..... ~ .............................. t
t"J
> _-I IZIII iii11- 111111111]
..................................
i i
i i
!
.... " ~ .................................... ~. . . . . . . . . . . . . . . . . . . . . . . . . .
1 i
.+++++++_
. ........ . . .+++++i
. .. . . +. . . . .
' I
0.1-- ! 1
[ i
........................................................
i ................. i ...........................................................T....................................
! 1
i...................................... i
~ . . . . . . . . .
1 psia = 51.71 mm Hg
I'--I'....
! I
i'
i 19
0.01 t I I
0 5O 1 O0 150 200 250 300
Temperature, F
211
l~176 - i
,
! ~ I
! .........
i
i ....
l F
P PHOSPHORUS-WHITE ~. . . . . . . . . . . . . . . . . . . . . . i .......
10
(1I
c')
1
i /
:3
n
J
L..
>
-:::A
/I
. . . . . . . .
............. i
~;ZZZ-_.-Z;
........................... i
!......................................................... F ...................................... I
E
i...............................
r J
!
0.1 I I
250 300 350 400 450 500 550 600 650
Temperature, F
212
1 O0
i
[
i i
9 ~ ,
10"
, t
1 i / .... l +
cO
. m L
c} !
CD
L._
+! : ..........> l 1 '
u)
co i i
(D ............ iiiiiii ill' . .
. . . . . .
. .
9r
. . t ......................
t 1
+......................................................
13_ J
Ij
0 ---S 1 !
>
cO i i
I
i
i!
0.1 t
--r---- t t
i + t
!
t
+ .
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
i i i
i! !!
0.01 1 I I I I
0 50 100 150 2OO 25O 300 350
Temperature, F
213
10
i i i
I
. . . . . . . . . . . . . . . . .
................ I
7
J
I . . . . . . . . . . . . I,, ! .......... i
, ! ...... i_ . . . . . . . . . . 1 /
/
............................................
,
/
03
. m
03
EL
t.__
03
03
I
-| . . . . . . . ,ll . . . . . . . . . I
LG)
_ ]"+ ........... ,_
Q. I . . . . 9. i .................... l
L_
0 , / i ,
EL I ........ i
03 . . . .
>
! . , ............................
J
/
.... = ... / .
c, I + B B
.......i
0 . 1 'i i I
- 120 - 1 O0 -80 -60 -4O -2O
Temperature, F
214
STE
-I9 ' e J n l . e J e d u J e l
098 008 09 L O0 L 09 0 09- O0 L- 0 9 L-
I ! ! I LO00"O
I
, - .................
i
l
'
l . . . . . . .
.
]! 6H ~uLu L/,'Ls = elsdL
~..~_ ed)l s = e!sd l f i
. . . . . . . . . . . .
77~7771i"?' ~ ..... " : :: :.i ~ ; .... : : : . i ~ i~i, /::: ::::::~::::i
:~c-
f-. . . . . . . .
i,,/, ,,'........ i,i,,,i.... '". ...... /..i..'i .......... ...i:-
.t ............. / . .
i [ / i .................
] ....... ; ...... ; ;; 9 , ,; ..... :' ,, :, - ,_
. . . . . . . [ ........ ]]] 7 __Jill ......... s .............. ;;;;17;;;;7___ ; i;L;i;7;;;;7;;77 .-
'! ..... ;;.; ' .L:;7: l:::C;77777:::::-!./ ...... , 2 , : : :::ii({i{i:i:::::r::::(i:{iiT:Ti.'-- ~0"0
<
. . . . . . . . . . . . . . . . . . . . . . : . . . . . . . . .
lit
........................... i / ............
I
0
I l l
. . . . 1_
. . . .
9 -
"U
9
............. .../
/ ..... ~
:. . . . . ~
i. ., . . . . . ,_
' / ! i ..... i.. ...~ .~ L
............................... ~........ --: ........................................... ,, ..L----;- 77;;;;; , / ....... _= . . . .
r .... - - - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~- ,. (#)
p / ,r
(#)
.i I
. . . . . . ~ ~ .-:.- :. : L
i i/ r ! (I)
....................... _--~- ............ ;. ....................... { . . . . . . . . . . . . . . . . . l . . . . . . . . . . . . . . . . . . . . . .
' /r i i ................ .-
r-"-------- -~................................................... . . . . -,:- . . . . . . . : . . . . . . i ... I . . . . . . . . . . . . . . . . . . i . . . . . . . L 13
. . . . . . . . . . . . . .
(#)
I .
, ~:~- .... ~........................................... 9. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . - 9~ - ..............
.......................... :::::::~ :::::::~: : ~ i ~-
;..i ;;;;.; ;" ....-; . . . . . i, ;;;;;;;;;;; ;;;;;;;;;;;;;;;;E Ill
______,,,,,,_._.,___,, ...... i; i ;71 . . . . . . . I . ; . . . . . . . . . . . . . . :~: ~.~ ~
....................... ; /_. ............. ]] .... ;7 i ! i
=================================== ~_J~c____"~;___::::; ....... : ~ ~ ~. . . . . .=- ..... ; .... ; ~ i;;.:;.;:'. ~_ L
r
L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i ' i
...... f I
.... ; .......... ! . . . . . . . . . . . . . . . . . . . . . . . . . .
!. . . . . . . . . . . . . . . . . . . . . i .................... ~ .....
..... i. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. ..,. ........... ; ..... ! . . . . . .
.... i ................ ! ..... i .......
;;;~:;]~]:]]~]:;~;;;ii]~_;i 711111...... J i .... :. i ::;"_ ....... i .~____ ..... :_:_: . . . . :____:::::. :
. . " . :;;";i. . i . ........
. . . ;. . ; .......
~...........
,;:ilj';,; ..... J.......................
ii J ............ i " .-:"
' - .................... - ......................................... " ............... " . i ~ ..;~ -.. " ....... "i I .... ;~;;::::~i:-;i ;;:;;;;:::::;::L 0
................. ................................................. ............... i ...... , -
1 L
m
[
l ! ............... :IEilI:IO-IHOlI:I/ snI:IOHdSOHd I~lOd ........... -
n ......:............ ..... i1 .... ~:....... i
t~.. .......... . ..... ' ;:;::~~i r ...... ~ :::~; i~ :,~:~:~~ ...... .~ ~,~1 l .... ~ ...... q I ...... --:oo
L
1~176l , ] i~ i
.__p, , ,
03
. m
03
EL
(D
t=..
03
03
i,_
tt / J
!,.- ,J
o J
f
EL J
f
03
> I
J
J
J
J
J
7i
J
/
I
J
J
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
101 t t i t I I
310 320 330 340 350 360 370 38O
Temperature, F
216
1000
I ....
~! ~ .'r! ~ ....
PH3 PHOSPHINE
7
m
1 O0 ~ II |
_f
A, ..........i...........,_ J_ _i .............................................. | ................................................. _.
I /I i ! !
I 7 1 ! i t
. a
/i
K)
L..
09
09 10 i 9 t i I
(D
L_
I/ I I I
| !
|Y
13_ /I
F-I
t__
....../ 1 | I
0
(D. I
> ! i
/ ! i I, !i
/ I
I !
i t
!
t
I
i !
1 L/
v
I
Ii
1 1 |
! . . . . . . . . . .
!!
|
t
I !
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
ii !
i i=
0.1 I
-250 -200 -150 -~ O0 -50 50 1 oo 150
Temperature, F
217
1 O0
I ........ ! . . . . . . . . ! ....................................................................
PH4Br PHOSPHONIUM BROMIDE I
I
............ , ..........
. . . . . . . ~ ..........
...... ~ .................... ~ ~ e _ _
10- /-
/
. .,..
-i . . . . . . . . . . . . . . . . .
/
/
u)
. B
Q.
(D /
u~
/
(D
L. . . . . . L
L /
13_ 1
t=,,,
0 /
> /
/L, ,
0.1
/
/
~ ... 1
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 -
-60 -40 -20 20 40 60 80 1 O0 120
Temperature, F
218
61E
-I 'aJn],eJaduJe/
o, o~- ot,- 099 - 08- O0 I.- 0~1.- Or7 I.-
I "~'~ I I I 1.0"0
' 1 1
....1:.....
BH u~uJ I.Z" Lg = ,~!sd L
!
I
i
z
L'O
I
i
li
<
i .................................
O
i
"13
i (1)
................... t
J
i r--
!
i (1)
w.
I'.........................................
i
OL
f
................................... m....... ~ imnml . . . . . . . .
....i I
I] 3CIlI:IO'IHO IAIfllNOHdSOHd IOt, H d I
......
..................................................................il
I....I...................... Ii IZIIII _F
......
i!
L - ............fILl J
I
' ~ ~ ~ OOL
100-
L
PH41 P H O S P H O N I U M IODIDE
I f
i /
10 r - 9
,=m
o0
c'J
(D /
L _
r
O3
t_.
13..
!,__
O - / ...........:
>
,S
/
0.1 . . . . .
,/ L ..... _~
Z
. . . .
/ E i
,/. 1 psia = 6 . 8 9 5 k P a
; / 1 psia = 51.71 m m H g
I
0.01 I i i J i
-20 20 40 60 80 100 120 140 160
Temperature, F
220
100 i . l . . . . I . . . . a " ~ '
I _ ......i...... ii....iii__
..... I......... I__ _i ....- _ ......... i_
. . . . . . . . . . . . . . . . . . . . . . . . . . . i ............
im
L__
if}
ffl
I /
/
i1 ii_i!_iiiiiii_iiiii . i __
0
Q.
>
t .......
....... ii _iiii -- _ li _/ / - _ _ ii _ --__..... ..... _~_
I-__/I.__ ----
221
1 O0 ........ , ,
i
..... .... ..... ,,
I
....... ....... .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . . .
0 . . . .
.......... ! . . . . . . . . . . i ,, l , l/ .................. J
1 ..... 1 . . . . . . . . . . . . . . . . . / .............................................. ,I
j !
= m
if)
I ,, , / .......................iiii iiiiiiiiiii
1 . . . . . .
if) 1 . . . . . . . . . . . . .
.....
i. . . . . . . . . . . .
! , L i , ! J ........iiiii ~IIIIIIZIIIIIIIIIIIIIIIIIIIIIIIIIZZIZZZIIIIIj
,-.,,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J
! 1 ...................... J
13_
. . . . . . . . . . . . . ! . . . . . , , , /
1 ....
,! ........... i,, , / i
,/
=
l
0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
........... =- .................. .. . . . . . . . . . . . . . . . . . . . . . . . I
> i . . . . . . . . . . . . . . .
=
.
i i
i
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .i
t . . . . i'
i i
0.1--
....... i ..... : i / ii ii i
. . . . . . . ~ ,,.
....... ~ . . . . . . . . . . . . .
...... ,,,
..... ,
0.01. I I I i I
1 O0 150 2OO 25O 300 350
Temperature, F
222
100,_
10-
9 ..... i-iiill' i iiiiiiiiii' iiiiiiiiiiiiil;i ~~ i iiiiiiiii-iil~!!!!iiiiiiii~iiiiiiiiii:!ililTiiiiiiiiiiiiiiil
, ::... ' .... ,. . . . . ~ ,, ~ i ii~~, ,
i~ :: ::: :i~~ ~::::::::::::::::::::::::::::::::::::::::::::::::::::~--~
u) ....... ]i............................................
... ~ ~ [
EL 1
.............................................................. 'I ................................................... }........................................................
(D
t.__
!
!
,I
! t
U3
U)
(D
/
L_
Q.
. . |
/,
L_
0
EL 0.1
cO
> iiili
...... ! ..........,_
.... / !
.......
/
! !
=,.............................................
0.01
._/!
9TiT~IIIIII/-
[
!
{ -,
b ,~i
l
iii/_~iiiiiii~iiiii
_~iiiii~iii:ii~i~i:i~ii_ Ii~ii , i t
| i
~,
- iiiiiiiii
.....
:i/
! ..................................
ii~iiii i ............................................................. i .......................................................... !
......................................
i ..... i.......................... i
1 psia = 6.895 kPa
, i
,r
1 psia = 51.71 mm Hg
0.001 I I
-50 50 1 o0 150 200 250 300
Temperature, F
223
100 ,
i
1
J
/
10,
j ~ f
.,m f
03
E}.
/
Q~
I._
03
03
Q~ .l
m
....
t__
Q. //,,
.... ..........
,,i,,,i.......
L_
O
Q.
/
.....
>
0.1-~_- , ,
. . . . . . . . . . . . . . . . . . . . . I
11 psia
~ | ~
=~ ~6.895
~C
kPa
1 psia = 51.71 mm Hg
0.01 -
1 O0 150 200 25O 300 350
Temperature, F
224
1000-
ii
=
P4010 P H O S P H O R U S PENTOXIDE
03
I
03
EL
(D
L_
03
03
(D
13_
L_
0
EL i !
o3
> i
low
i
=
I I
! I
780 800 820 840 860 880 900 920
Temperature, F
225
10000 - iiiii 84 :iiii'iiiii:;?? ~ ~ ~ ......... j
.... . , , ;: ~ ~ ~:
1 . :
,. . .:.:
~ ~ ......... ! ...................
L.
. m 4
03
Q. ' , .......... J
- -/ +
(D
L_
. . . . . J
03
03 10
L_
13_
t.__
>
ID.
/ T ' r_____2
E.... /
i ,, , 9 . . . . . ' ......
I / L.................. i
4 i
........ I
0.1 . . . . . . . . . . . . . . . . .
0.01 I I
400 600 800 1 ooo 1200 1400 1600 1800 2000
Temperature, F
226
I O0 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
10 ------
0.1~
a:l
.m
Q. 0.01
(I)
L_
09 0.001
(I)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .!.
13_
t,,,=
0
EL 0.0001
>
1 E-05
i . . . . .
T
1 E-06 i
!
I "i
; J
.................................................. t
i i
[ 1
500 1000 1500 2OOO 2500 3000 3500
Temperature, F
227
8EE
4 'aJnleJadwal
OOLk 009 L 009 L 0017 L 008 L 00~ L O0 L L 000 L 006
I I I ! ~ ! I ~Lo'o
6 H ww i l'is = e!sd L /
ed)l s = e!sd L
/
.: ..... A:
rl J . . . .
J: /
. . . . . . . . . . . :
. . . .
<
/ li)
/ 0
i .......................................... / -
::L
i ......... S ... :[
' LIII 73
L-:: ..............................:....... i.,. :::., ,,:7':,.. :,..':::::::::., , ...................... ~ 71 !
(D
L_:::: - - ::: 21:111 :i:i,./
i ' ''- . . . . . . . . . . . . . . . . . . . - : L
i
C
.=.I
s
" ~i f 7
ll)
___::ii:i:i:ii__i_ii__~,,. -~ i,,. 7:::
-~ . ............................ -:
L
f ............. 7.......................... i OL
J
f
T
E
L ,i I J
i
3CII~0E18 CIV37 ~JSqd
:i ~ h O0 L
1 o0 ! !
i
! !
......! .......... !. . . . . . . . !
/
f
10
[
....... i i
!
, i
i i
.... [
i I
, m
Q.
i i
L
CD
!,--
03
J
CD
L_
i
i
!
13.. -TP . . . . . .
t__
!
0 1
13).
!
> §
!
t
i
! !
i
t
e l l 1 ==JLm
...........
i
! :
, i i
l i i
i
I
i ................... 1 psia = 6.895 kPa
l
1 psia = 51.71 mm Hg
' ' !
!
0.01 i I I
1000 1100 1200 1300 1400 150o 1600 1700 1800
Temperature, F
229
Vapor Pressure, psia
0
o o o
0 0
o~
o
__L
o
o
(30
o
o
--I
CD
3
"tJ
(I)
c-
OD
-n
ro
o
o
ro H H
ro 01 o~
o
o
-1-
t~
ro
co
o
ro
o
o
100
~iiii "' "
11
_
Pbl2 LEAD IODIDE : 1
i
. . . . . i ' J ! , , . . . .
i ,
10 . i
[ i ' i . . . .
L I : i i : ........... 2 i: 1211............ -
,,m
u~
Q.
!
I__
!
I__
n
L _
O
Q. ..................! ..............................................
........................................
{ i
>
t I
9 1
! .... / i
i / '
I
T
i !
i L
0.1 ~__i-~___ - ..... .--~ ......... - .... --/i~i_ - .......... ~__i .... - ..... --- ~i _- ......... _ .... " __-~ _i-
' !.. ; i........... I
i .... /! .... !
9 !
I, i
II...
i !
0.01 I
! i . .
i i I I
800 900 1000 1100 1200 1300 1400 1500 1600 1700
Temperature, F
231
1 O0 !
!
!
t
................... I
PbO LEAD OXIDE
10 L
J
Z
. m
EL
/
L_
u)
u')
......... 5 7
(D ./
13,. _ , /
L_
o
Q.
>
/
/
/
0.1
...........
./" '
/
/
/
/
/ . . . . . 1 psia = 6.895 kPa
/ 1 psia = 51.71 mm Hg
0.01 I I I
1700 1800 1900 2000 2100 2200 2300 2400 2500 2600 2700
Temperature, F
232
1 oo ]: tt ~1 !
!
I ...... I
! .... I
]Ti;il;illllllllllll;illlli,l PbS LEAD SULFIDE _____,
......................
1- ...... I .....
t-
o : -= !
] I '
!
I
Ill
L _
if)
(D
t ii
i
!
i
i
i
I
'
L _
i ....................... T! ............ i'!
13.. i .,' ' i '
!,___
i , [
0 " r t
Q.
I I
>
t i
i 1
0.1 I
i
9 '
i
i .....................
!
t !
I
i
i ..................... i ............................. i
-i--------~-/---i r
i--
i
i
i
i:
i-1
,!". . . .
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
!
O.Oll
15oo
i 1600
i
I
1700 1800 1900 2000
i I
21 O0
i
I
2200
I
2300 2400
Temperature, F
233
100 !~p~
Pd
10
,i
1=
0.1-
. i
l/}
Q. 0.01=
(D
L._
m
09 0.001-_
(D
L__
ii
I,..
0
Q. 0.0001=
>
1 E-05=
1 E-06_= .=
,.=
-i
1 E-08-
1500 2000 2500 3000 3500 4000 4500 5000 5500 6000
Temperature, F
234
1 O0 .......................................................
----.------...--..
--.--.....--........
POLONIUM
0.1
" : -V---zz" T "
- ~ :,z T i
- - - - - - - - ' ------ t 1
.m
! i 9
09 0.01 = ' "--~. , I
L_
: ~ '~,
I
r o.oo1-======.~ I ! i
(2)
" | .........................................................................................................
0
O. 0 0 0 1 -
= i . . . . . . . . . . . . . . . . . .
J,
ii T] i 'i i
- - - - - - - - - - T - - 7 - - - ~ T - - - - - I - ~ [. . . . . i ....
1 E-07
Temperature, F
235
1 O 0 ........................................ i ........ ...?.. '...'. '_ .. '__: _-: . . . . . . . ~.
[
] .............................
i "
f
. m /
c~ 0.01 t ............ ...................
_ _- _- : z ~ . . . . . . ._ . . . . . . . .
=9
o.ooi
-: ' . ~" _ i
/ [ r
. . . . . . . . . . / 9 .. , .,
. . . . . . . . . . . . . . . . ..........
n in ~
0
c~
0.0001
/
_ i":- ,...... ~7~,~,/ - ...... ! .... -- _...........~,.~,,- ', ....... i : : ~ : : : . : : : . ..............
~ /~ [ [ [
/
1 E-05-- _
-
:
: .. z
.-
......
~
:i . . . .
~
. . .
~ ,,
. -~ ........ / -- .: . ~ ~ - _ ,~_
1 E-06 _ - :__:::,;;;:~:,~
-/
;, ~ ~- . . . . . _ ' __ _~_
~ _ ,...,:,.:
[ .... : _ -- _ . _ , ......... _ u ~ =
r-
~.-;7;I:;:LZZZZZI;ZZZIi
A
!
: ....... . . . . . . . . . . . . . . . ..................... _,
/
_ ....................,
i i ' i
I i 1 psia = 6.895 kPa
!: 1 psia = 51.71 mm Hg
! "i
" I . - . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I _ _ _
1 E-08 I I I I I i i i I
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000
Temperature, F
236
100=
,oi Ra RADIUM
1=
0.I-
on,m,
u)
!
Q. 0.01-
(1)
l&..
:D t
09
u)
(!)
0.001- L................................................]
I
IL_
n t 1
IL_
0 I 9 |
0.0001 =
1 E-05-
il ................
1 E-06---
4
,-------
1 psia = 6 . 8 9 5 k P a
1 E-07= r ............
1 psia = 51.71 m m H g ........................
I
.... ===
i !
1 E-08- T I l
500 1000 15OO 2OOO 2500 3000
Temperature, F
237
S E E
-I 'oJnTeJeduJa/
0017 L 00~ L 000 L 008 009 OOP 00~ 0
I J J I I I I ~ ,80-=1L
.......................................... .. . . . . . . . J
................................... ............... '....... 1] 1] . . . . . . . . . " /
, I
............. "_ i. ' ..... ' !
............... I . ~ .... ,. . . . . . . . . . . . -" Jr
. . . . . . 9
13 H u J L u I.Z'Lg=e!sd L ' ,.... ' 'i " " .: ........ "
::: ! ....../: I LO-=IL
edM 968"9 = e!sd L
.,. ; ! __
9 ! ...... ; . . . . . . . e
................................................ .. . . . . . . .
... ,,, .... r /
..... -
................. ' _ ............ .... ! .-
.......................................... ... :[ ...... - . . . . . i . . . . . . . . . . . . . .
....
.., ! /
..... .........
/ '-90-=1 I.
........
.i
/, " ..
'_::::_:::::::::::::::--:-::--: ..... i ............... .~ - ........................
........="':-'---izii:z111~:---:-:::-::_ ::_:_ " -.-:--.::::: . . . . . . . . . . . . . . . . . . . . . .
... ' , , / ...
...... .................. i ......... - i : ........... -,,!!!i ..... . . . . . . . . . . . . . . . . , .........
.
7i::::::: i:: ,,
~/ ~;0-:I
I.
_ . . , , _ ................. . . . . . . . . . . . . . . . . . . .
. . . . . . <
. . . . . . . . . = 1.000"0 "0
............ =.._=_ .....
0
........................... .. . . . . . .
9 .
/ ,
-0
zzzzz:'.-.Z.z'_'zz/_z:'_'_'_'_.................._ L :: . . . . . . ,,,, """ , ..... , ,,,,h ....
: ............... . ....... " ' - ..... :---::: .......... ----!--:~!i;::;i~ ........... --:;;-i~ .................. , .......... 9 ' ~ ...-- '
" ,...' ". . . . . . . LO0"O
f~
c-
......................... 9 9 i . . . . . . . . . . . . . " / ....
:::::::::::::::::::::::::::::::::: ... . . . : . . . . . . . . . . . . . . . . . . . .. 9 . /
......................... ~ ............ i, '......... , , , i ..... ]
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . '"v - . . .
J . ....... . .
,,Zi/- - _ ....
"I '
"0
----- / - .......: LO'O
m l
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I #.,...
............:...... - = = - ............................... / '
....................................................:! ........... . . . . . . . '...... .. . . . . . . . . . " . . . . .
. . . . . . . . . . . ~ ..
.............................................................. . .... ~ . ,/.ill ..... . ,
................. ------.. .... . ..... . .. "._.:-.~_.,~._.__.:;.:.;..::_:_::_::_ ........ ~__ :-::~ . ..... .
.... / L'O
.......
f
/ " ,
Z : : : : : : : : : I L . ~ . . . . . . - 9 . . . . . . . . . . . . ....... ~ . . . . . . . I"
.-- . ~ , , ,
. . . . . . . . . . . . . . . . . . . . . . i.:'" i "" 9.,, . . . . .
T
........ ~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ........... _ ......
....................................................... ] NNICilSNI::::I q ff
1
RUBIDIUM BROMIDE
10- ..--.--.----------
, m
(/3
(1)
:3
(D
&=,,
(1.
0
c~
i T
>
i
0.1 T T
0.011
1400 1600 1800 2000 2200 2400 2600
Temperature, F
239
100
I
10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
o m
(D
t._
O3 /
(D
1 ,A
w
L_ /
EL mR,
t__
m
O
Q.
w
/
>
/
0.1 /
/
j
/
/
.....
0.01
1400 1600 1800 2000 2200 2400 2600
Temperature, F
240
100, . , 1 ,,, 1 ............... '1 ............... l .......... ! ........................................................... !
9 . . . . . . . . ! 1 I I iiiii , iiiits 7- I7 ............ iiii-i ................................................................................................................
_iI i ii|' " ....... ' ' CZZZ !i+ii 7 Z I ......... i i ] ................ 7 1 7 . . . . . .
] ........ s ! IC__il iiiiii i ....... " .................................................................................................
_ i 1 i i 171111/I'7111111171
.......iiiI........................Z2111111Ziii,iiiiiiiiiiiiill
In I i i i
: ] ................................... ; : ] . . . . . . . . . . . . . . . . . . . t ........................... +...................................... J r +
.....................................
I----V----
r----~r ...... -r--------t
+
]ZZZZZTZ311:III~i:Z::I::I
~:: C ~ . ' - 7 " I i' ................... ~ ................. "i" ........... i
L__
..................... ! .............................. !_ . . . . . 1 2~'I
. ................... +I . . . . . . . T! ................. i T
0
9
I! l/i
-~i ~ ............~7 ................
........i..... ",, ',, :1........................
/ ......................................................
il,............................
-.
I,.......................
i,
......................
........................... ! Z
i v .................................................
.........................................
! ..................................
~.................................... i
i
_-, . . . .
1 psia = 6.895 kPa
1 psia = 51.71 m m Hg
-I !
i ........... _...........
0.01 I
J
I
i1
I
I
I
I
1600 1700 1800 1900 2000 21 O0 2200 2300 2400 2500 2600
Temperature, F
241
100_~
i~ii~iii:::iiii~iiiiiiiiiii::::i::::i:iii~iiiiiiiiill
ii~iiiiiiiiiiilii iiiiiii:~!iiii
Rbl RUBIDIUM IODIDE
10
i~/-: i,_,_.,::.1
....... L ; ................
_ ,ZI~I iiiiii
(O
,,m
Q.
(D
I,.,..
(o
(o
(D
13_
L_
0
Q.
>
0.1
/
/
/ i
.....
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 i I
1200 1 400 1600 1 800 2000 2200 2400
Temperature, F
242
~.=:::!::?~ ............. =!~!::::~ ..... ?:!:?::1::!?!_~!:?!:!_!__!:_!!_! ..............................
l -! , ! '
I
~IIIYIII i i YI[I IIIIIII:IIIIYIIIIIII]IIIi ii i i i i%::::::i:i:i:::: IIIIIIY:IIi
9 ii ..... --I
, . . . . . . . . i~e RHENIUM
::::::::::::::::::::::
............ .... , ::
i
i .... 1
1- j-
; ........ ..... :iiili i::::i~ :!~i ......... i ; ........ i ;i ..... ,,i .......... :J
I . _ '" ! "
Ii iii.......
LLLLIIII .....i....LLLLI__ _ ii/_!LLL__]ILLI ........................
] ............................. l
I L l~ :L I : ~ ~ ....................................
(B
co 0.001 !......... ~ . . . . . . . .
==-'~ . . . . . . . . ~
i . . . . . . . .
(D l. . . . . . . ! ............................................
:: __l . . . . . . . . . . . .
n
I:]:::]]]:L:::::/_:.......!:::::::iii::
ii i ]_i:i ..... i
0
O. 0.0001
>
1 E-O6 i [ , ,
1 E-07 . . . . . . . . . . . ! . . . . . . . .........................................
'=:::~::: 1 psia = 51.71 mm Hg
::: :::::::: ...... :: ) ,
::::::::::: :::: :: :::::::::::: ::::::: :::::: : : :
:!:::
:) ......
:::::::
:_:.,::::::
:::::::::::::::::::::::::::::::::
:.r::::::::
::::::::::::::::::::::::::::::::::::::
:::.___::
:::.r::::::::_:::
:;::::........
] 1
...........
::::::::::::::::::::::::::::: ,, 9 _........................
_ ] .............
!
i) t
1E-08 I ' i I I I
4 5 6 7 8 9 10 11
Temperature, F
(Thousands)
243
Re207 RHENIUM HEPTOXlDE
/
J
10
f ...........
Q. /
/
/
(D
/
CD ........ ,, .~,
13_
/
0
Q.
/
/
>
/
0.1 /
J
.... / , , . . . . .
.............
/
r
2,/,,, ~L
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01
400 450 500 550 600 650 700
Temperature, F
244
100-~ ............ I
9 i ! :: .......
~ol . . . . . . . . . . . . . I ~ ........
- 1
, m
A !
0.01~.
,/~i~iiiiiiiiii~ii~i
I. :iiii:i ]........
ffl 0.001 -
_
i ~ , ! 1
n_ ' [IIIY ii 9 IIIIYI i t' -- - -
I ! / ! '~ . . . . . . . . . . . . . . . . . . {= | i"
o [ ! i .....................................................................................................................
i...........................................
1............................................
i...............................................
0.0001 _
>
/ I
1 E-05~
! } ! .... [ .......... r
9 :i: i:;: ::i ! ~ ! | i| i |
L / | . . . . . . . . . . .
/ t ! .
' . .
! . . .
1 .
i
i
m _ _ l
. . . . . . . . . . . . . ..L- . . . . . . . . . .
,, f t
|-
i lpsia= 6.895kPa
|~1 1 psia = 51.71 mm Hg
.............
...................................t.:~.:~.:.::.~.::.::.:.::.:.::.::.:.::.:.:::!::::::::::::::::::::::::::::i'"'l
i ........................................................................... ::::::::::::::::::::::::::::::::::::::::::::::: ,_ . . . . ,
!
__:Ji:...... ii i
I I I I
1 1 ! i
i
1 iI
2500 3000 3500 4000 4500 5000 5500 6000 6500 7000
Temperature, F
245
1 O0
l ! ! ! ! !!!i
. . . . i i i _
Rn RADON , ~
i
....................................
i .....
i j P
10 ,i
v9
r i
.m
/
C~. /
/! J
CD
tm
(1)
.........
13.
/
. . . . . .
0
CL
/
>
y
0.1~
/
/
/
// /
0.01 I I 1 I
-240 -220 -200 -180 -160 -140 -120 -100 -80 -60
Temperature, F
246
1007- .... ; :=-=== .......................... ~ ......................................:.i.........................................
; ~. . . . . ;....... ---,
9 ............ t .t ." . .
] Ru R U T H E N I U M i. '
] ~~ t+ '
j
] J ! ..... i ! ..............
qiiiiiiiiii:ii:;il,
/
,i, , !:
:~ ::~:: .................. tI . i ................ , ............................... !- ...... ~
" ~ "
....... ~: . . . . ,: _ _ _ _ _ _ . _ _ _ _ + "
.........
9 'i . . . . . . . . . . . . . . . . . . i .................. i ..................................i - - - - ~ ~ ' ~ 7 " ........ ~. . . . . -I, . . . . . . !..........
]........................................ / i,,
- - .......................................
~ ~ ~ , - - - - - - - - - - - i . . . . . . . . [. . . . . . . . . . . . . . . . . . . . "',~t ........................ § ................................. § . . . . . . . . . . . . . . . . . . . . . . . ~. . . . . . . . . . . . . . . . . . . . . . . . .
I 9 ! 9
i .I ) i !
,
i I: . . . . . . . . . . . . 9. . . . . . . . . . . . . . . . . . . . . ~ ..............................~ ..................................
+ ................. ~ .................
;;;; :: ; '
:i;- .I.. l i,
' ....................................
~_----_-7_;___---_; t - - - - i: +
,i .V."?" . .
(D
I,.,.
~'-7 7;; ;_ I .
........................ . . L J
. . . . . . . .
,--------+-----.. . . . . .
7z_~
. . . .
..it.'......................
...................
-.:i,-.................
...................
t~' ..............................
................................ i'
~, ,i . . . . . . . . . . . . . . . . . . . . . . . . .
O9
o.oo~ ~,.iii~77!7!~ii!!!iii17!--i!!i!iii,~:_4 ! '
~ -,~ ,,,.,,,,,,,--,-.~:.,.:~-.~:~-.,.-T--~.~:.~-.~ .~-..~-.---::..:,~.I:----~:.~:::::~:::L~
~::: ======================= ::=:::::,.::::::.~::
[~:::."~
,.'::::
..-:::
::::1::.~:::-:::L,:.~:::~:..~::::1
~.-~:,:::.~,.:
~ ,.~:,,~-:::.::::::::::::::::::::::::::
+~ - - - - . ~ " ~ ~.~ ~ .--..~--__-7:i,..':L--"_--:- 7..--"---"_7" "...+.,:'7:7"-"..".."-"..".:::::.".~::::::~::~:::."-:."-.--.. "."--..::~ .-..-.':~,:<~~7:_-:.~:"_"E"...~.~:T-:: ~ 7..-::::::~ ..-;----".-.-" ."Z:::
(D ---- .... 4 - ~ .............................~....................... 4 . . . . . . . . . . . . . . . . . . . ~ ......................
.................... - ::=--=- :-: ......c" ................. . . . . i ;i t ............................ -" ....................... "~..................... "i'.........................
' L ~ '- . . . . . . . . . . . . . . . . . i, . . . . . . . . . . . . . . . i'-. . . . . . . . . . . . . . . . . . . . . . . . . ~, . . . . . . . . . . . . . . . . . . -i ,i . . . . . . . . . . . . . . . . . . . .
13_
-- ~ : i I , t I
i-............................. ~"............................... -!-. . . . . . . . . . . . . . . . . . .
!
~. . . . . . . . . . . . . . . . . . . . . . . .
0 i i I i ~
i
,
i
0.0001
.i . +..--, ................... " ......................... +..., ............ .-.-=~ .......................
- :: i"=---~--~F=-~::i'-- ................ :i:":"----" "::::='--='':'::: " = - " - ' " = ~ - ~ ! [ ! . ~ E ~ E ! E ~ . ~ : ~ E ! F ~ - ~ ! E E : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : - - - - ~ = .............. : = . . . . . . . . . . . . . . . . .
t'l:l _3 :-:::-:~=-::~;~;;;~;;~;~;;;;;;ii;_-:::;;;;;;;;;;........ ~ t _ . ~ - z ~ . : ,, ~.................... ~..........................................................................~ ................................
> - - " " ............. ....... i' ' '~.......................... ~.................... ; . . . . . . . . . . . . . . . . ~........................
I . I
i i i [ .........................
~! i
Temperature, F
247
10::L__.___J _|
................
...... ..
I j
I "
/
. L
tO
(/]
13. .I
/
:::]
(/]
/
0.1 ./
r./
13_
//
0
13. /
;/
t~
>
/
7
0.01 u 9
- / I
_ / _
c v
1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m Hg
0.001-
120 140 160 180 200 220 240 260 280 300 320
Temperature, F
248
1~176176176 i ----I
SULFU _...--.
1000
100=
u
m
; T
I
u m ~
t1 '
I
.
(/)
m 10=
't
C). ! t
(D
IL_ ! .
I
O9 1
r 1=
(D
I,..
n ,.~
t ! :
I..,
0 [ j, '
CL
". ~ ' 2 ~ i !
> 0.1=
'7
_-~._::.~.'::.~.-.'..':::::::~2::.~Z:::::.'::Z::":.-.~:::::::::.':.'2::~:::~ Z~ ~
.~....................................
~ ~:
~ ...................... t ........................
j: . . . . . . . . . . . . . . . . . . . . .
It....................................
~.,
j
I
,i.......................... |
. . , m
0.01
i t ,
t [ .......................... F ............................................i
I
[
!
I
0.001
]
t .................................... ' t 1 psia = 6.895 kPa
---------------4 - = ........
I t 1 psia = 51.71 mm Hg
, $ ! 9
!
i
0.0001 1!
[ l
i l
!
1
200 400 600 800 1000 1200 1400 1600 1800 2000
Temperature, F
249
10 i ] ................. ]
! 1 ] ........ ~. . . . . . . . . . . , ................ .. ............
&-,
c}
o3
o3
(D
K.. ..................................................... I ............................................................................
I
K.,
O
13.
>
. . . . . . . . . . . . . . . .
i/
i
................................................. / .....................................................................................................
.....................................................
T.......................................................
i.....................................
, ! .
0.01 I I I t I i I
-1 8 0 -160 -140 -120 -100 -80 -60 -40
Temperature, F
250
1 o00 I I ,, i i.
, ...... ~.......... ! ...................................................
] I , ! i
, z t'~
,
]| . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~i : . . . . . . . . . . . qt 9. . . . . . . . . . . . . . . . . . . ,z
$ .............................. ~ i
:. . . . . . . . . . . . . . . .
~ !...........................
9
I I i
!i !i /
~ i
il
i i E i i
--
i i i " i I
E i i i ! !
! i i i i
I i ; :. ". i
, i i z i !
i ~ i i i i i
if) i l i i i i i i
100- ~ t. . . . . . . . . . . . . . . . . . . . .
::: ::::::::::::::::::
~ ~ ::::::::::::::::::::::: ~ ` ` ` ..............
f l
I,.__
0 - i------
i
............................... ~ .......................
i
: ................................................................................................
i
-.............................................
!
-.......................................
i
i ., i i i
- i, ................................ ~ .............................. i .................................... , .......................................... : ............................................ 4 ............................................... ~. ..........................................
> ! ~ i i i i i i
.!./_ .................................................. i .......................... 4 ................................. ~........................................... i .............................................- ............................................ ! .............................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . ~' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . t ................................
i I
9 i
!
I
ii
|
i
9 . '- ..........................
i
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
'........... - .................'i
i
i
i
i
t
i !i ! !
10 i I I
-60 -4O -20 2O 4O 60 8O 100 120
Temperature, F
251
100: IBm
ellm
;m
i
SOBr2 THIONYL BROMIDE
. . . . . LI, . . . . .
10
/
.m
Q.
f
(1)
CO
CD
/
.. /
n I I I
0
Q.
>
0.1
/
/
,/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01-
o 50 1 O0 150 200 250 300
Temperature, F
252
SOCI2 THIONYL CHLORIDE
,,I
09
0.1
(D
l_.
rn
rn
(1)
!._
13.
0 0.01 ...................................T ....
>
i I
0.001
0.0001 - ..........--.--------.--,...----
H ~ I P~ia
I ~ 51~
] mm g
! ......................................
1 E-05- i ! ]
-200 -150 -1 O0 -50 0 50 1 O0 15O 2OO 250
Temperature, F
253
t ....I . . . . . I..... s i......................................
J
.......................... ' .....................................
' ......................................
J ..................................
I
i
. . . . . . . . . i ................
1
!
...................
........ - ~ ~
. . . . . . . . . . . . . . . . . . . .
. m
ffl
.......
.... / " 1
ID ,/ -I.................
/
J i
i
L _
J
0
I
> I
/' . . . . . ................
_
/"
/i ......................................................................................... -1
ml
/ [
/
/
L
1 psia = 6 . 8 9 5 k P a
!
i
!
1 psia = 51.71 m m H g !
I
I
! i
!
I
0.1 I I
i
I I
-150 -140 -130 -120 -110 -1 O 0 -90 -80 -70 -60 -50 -40
Temperature, F
254
10000_, .................. , 9 ,
-T:I ........... Z-I ......... I ......... --!. ........................................ i
J i I
311ZZZIIIIIIIII I
illiiiii:ii:iil;ill I SO2 SULFUR DIOXIDE
................... L
J
! ...................... |
i l
, i
|
l
. m
i
................ !
1O0 _ _ !
. . . . . . . . . . . . . . . . . . . . . .
J_.........ILIIIII ZZ ZLI::{...............................{
(D ' / !
J
ffl i1 {" i
L_
iI [! !
O_
|' !i
ii ii
!,___
0
10
>
s /__~ l i
!
~, t i-- i
i/__ i l
i i i; i
/ 9 ! i
t : t
I
t ~ "! ' !
, ..........................I_L ...................
l.......
. " i
l|
[ l I 1 psia = 6.895 kPa
! r '
i 1psia=51.71mmHg i
. . . . . . . . ! ........ i .i . . . . . . . . . .i . . . . . . . . . i. . . . . . . . . . . . . . . . . . . . .~ . . . . .
: i i i
! s
i
! ! i i ! ~
0.1 i I I I I I
-15o -1 oo -50 50 1 O0 150 200 250 300 350
Temperature, F
255
1000 {
!
! /
S02CI2 SULFURYL CHLORIDE
1 O0
/
J
i
/
/
/
. i
U9
Q. 10~
/
....
CD
t.._
f [
03
I
09
/
/
(D
13_
t._
O
/
/
> /
/
/
/
0.1 "'"
/
i
/
9 /
J /
,,,
i ...............................................
0.01
-100 0 1 O0 200 300 400 500 600
Temperature, F
256
loooo~ L_
~03SULFUR TRIOXIDE
1000-
t i -----~----~,'~~--
(If
,,, m , , , ,
Q.
'i L
(I)
Ii,,..
100- T [ . . . . . . -::::- . . . . . - - = - = - = - - = - : - , - - , ~
13_
i
II,,..
0 !
C}.
>
10- ,=
______--ff
i
. .
,.t
==
1 T l [
50 1 O0 150 200 250 300 350 400 450
Temperature, F
257
100 4
............
!.........................................................
"i'
{ i i........................................
i
~ i
..............................................
,
, .. . . . . . . . . . . . . . . . . . , ........................................... ::::::::::::::::::::::::::::::::::::::::
..... ,~
i ............................................................................................... i ...................................................................................................
........................................................ ~ L.................................................. i...................................................
I
F
10
............. : : ....................................................
_ t ..................................~ ' ~ - - ~ . ...................................
J.........: . . . . 7 .......................................
[.......................................................
i............................................................
ffl L_ ....................
. . . . . ... .. . . . . . . }" . . . . . . . .. . . . . . . ... . . . . . . . . . . . . . . . . . . . . ~. . . " i ! --i ~-" ........................................
......................... p,
/ .................................... ,
Q
//
7 .~............................
/
9 .. /
0 A .......................... ~ ....................................... ,
>
i..................................................
i....................................i
0,1 :--:::Z':'Z;Z.';'Z"Z:Z:"...........
I..............................................................
'
. . . . .
--t;;-;;..............................................................................................
- / i1 psia 6.895kPa
. . . .
r
I i 1psia=51.71mmHg
! I
0.01~ I
0 50 1 oo 150 200 250 300
Temperature, F
258
100 .================================
. . . . . . . ::::::::::::::::::::::::::::::::::
. . . . . . . :::::7 . :::
. ::: I:::::::::::::: : :-: : : : 7 :.:.:.- . . . ::11 :: =========================
:: . . . . . ........................................... i ~ . . . . . . . . . . . . . :: ........ = : = = = = : ......... : : : : : : : : : : : : : : : : : : : : : : ........... = =
]17!!:!-i--i-i
---;~ iiiii,
..... ......... ' i
21:::::::::::::::::::::::::::::::::::::
Sb ANTIMONY I
10 ..................... ~ ~......................................................4:.......................= - : = = : : :
~!!!!!!!!!!!!!!!!!!!!!!!!!!!~!!!!!!!!!!!!!!!!!!!!!!!!!!!!!:::::::::::::::~:I: .............. :::::::::::::::::::::::::::::::::
======================
:77:: 1__ :::: :1::i::::::71 : :i ====================================
!--7
................................. ' .............................................................................. }--
J :::: ::::::::::::::::::::::::::::::::: _ :: :::::: ::::::::::::::::::::::::::::::::::::::::::::::::::::::: . . . . . . . . . . . . !
!
]
!
| +
I
0.1 I.-=:..~:.-...-m.~_.-
~ .-..-T.::==.~= ~..m.=:::..--.::.---.::::=.Tm..-..-=:~
. .....
09
Q. 0.01
(D
:21
09 0.001
(D
I,..
13_
L_
O
ID. 0.0001
>
1 i I
1 E-05 ....... | ........................... 4 .....................
t
{ I :'
I t
! ! i
1 E-06 ~::..-".-'.'~
..-':~..~--. = = .-...--...~."-=:~:::..n'_.--~.:-~:::...-'~--:=.-.z= .T.:%-:=..-:z...-.~-...-::..---'T_-::::
.~::.':.::::
:::::::::::::.-..
~ .m.::::::::.:=
"7.::.~:::::=::= :::::--~:::= .':.::::::
z::::.':::::.':::::
::::"::
:9 ~
. : .- :
9 |
T t
p ...............
i| I 1 psia = 6.895 kPa
t
1 E-07 1 psia = 51.71 mm Hg
i . . . .
,
]::Z:i:Z/:il ..................................
-i !.......................................................... i
I I I
500 1000 1500 2000 2500 3000
Temperature, F
2 5 9
1 O0 ,,, . ; - . . . . . .
!
=_ . . . . . . . . . . . . . . . . .
I
SbBr3 ANTIMONY TRIBROMIDE ...................................
Im
Lf
S
z
,,m Z
O3
O3 /
E
L r
1 ,
L
0 /
> /
.............
0.1
/
;s
J
l
/
i . . . . . . . . . . . . . . X
0.01
200 250 300 350 400 450 500 550
Temperature, F
260
lO00j . . . . . :_ , ..................... , ............. , ', ............, ............ : ............. , ................................... ,
]
i I J. . 7::i :Z II :I!- :F- :F ill..... ii.......... 17Iii .... ii.............. IIIZTZ',TTT-:7-~.....:ZZI .... !Z .......... :FZ777 IW! .... 7:2:2_-_-_-_-_-_-.:_-_::_-::_-_-_-]
1 , ' ...... ' : ,ii i1 iiii i ii iii iii ] i IFIIIIZIIIIZIIIIZIIZIII77711111 ........... iii I17 IIIIIIIIIZIIIIZIZIIII]
311111111
iiiiiiiiILl
iiii I iiii i IIIIIZII iii ii ii ]iiiiii i iii171111711117111]1711111 ..... 7,7717 i] ........ /ii17 Z1
] ........... I SbCI3 ANTIMONY TRICHLORIDE ] 1 t ............... ] ............................ ~ ...............
I i - I .......... i. . . . . . . . . . . .'...... . . . . . . . . . . . . . . . . .
. . . . . i . . . . . t .... I ._ i I / I ....................... ! ................... Z]
I I .....I ........................ t / I [
............................
. m L __ ___........ .......[_i. _::_ii/ii_ I.... I 7-IIIIII--IIIII---IIII--I:Z
:-: ii ii i .........:::::::::::I
13. 1 ...........................................
I...............................
1........................
__~i_!.......................
/i! ............................................
tl)
!,__
lk.,
13.
!,__
0
c'~
>
1 .....................................i.................."..................
i7711;7ZI ii_ IIL 11111177
Zt i
qt
,
:-- !::L:/::__ :ZL:_:::I i , ............... j
................................. ,/iiiiiiiiiiiii:i:iii :i:::: i ,,,i, ,_
" ,' '9
!/
n .... i, ............ i.............................. 1..................................................................... I._ '1 1 psia = 6.895 kPa
/ ........................ ! ................................! . . . . . . . . . . . . . . . . . . . . . . . . . . . . . LI 1 psia = 1.71 mm Hg
0.1 1 /
1 O0 200 300
I . . . . .
400
.
500 600
i"
700
i' I
800
1' I
900
' 1000
Temperature, F
261
10 I l J i ..........................
[
J . ! I
Q.
(1)
:3
(1)
I,...
13_
O / .................. i ...........
r~
>
0.1
! / _ J
_iiiiiiii...... i !.....
i i i..... i/ii ......i~i~iiiiiiiiiiiiiiiiiiiiiiii~i
.......
ii.....i
i
1 p s i a = 51.71 m m H g .........................
r ! r
0.01 I I I i i i i i
60 80 100 120 140 160 180 200 220 240
Temperature, F
262
10000, .... , ................ ,. ,. . . . ,
7 ]]]]] ] ]] .... ] ........ | ]]]]]:] ]:]]]]]] |.:::::]: ;]]]]]: '" :[_ :i '_:] _ i::__ -_ ]1 1111.]] : __1____-1 ] ........... 11]] ...... I .......... ] __1........... I
t
l:]]:::: ::::::::::::::::::::: ' ! -- - i 9
i
SbH3 STI ,,~a Ii .............................................. ! .................................,
i ........................................................... , . . . . . _, r
__ i ..............Y .....LI .............i.... i::i .....I:L:,: ...........21 ..........................
211111
.......L_ ....... I '
I
1 oo- 0 . . . . . IIIIIIIL : ] i i i i i ii ...... i l: :: ,
. _l ....................................... ' i~ ~ ~
. . . . . . I i 1 ,- ................................ ; ............................ ~ ." 9 - "~"- ..........................
........................... ~. . . . . . . . . . . . . . . . ', ............ I T.................................... i - - ' - - - - - - - ~ ........................ i". . . . . . . . . . . . . . . ! ....... .777, ................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .t. . . _i -t ~ ~ i ....................................... ~ ............................. r, . . . . . . . . . ,, r '- - -- / - - ~- - I
] ...........:_:_-:............:........ !:-:: _::__:::: ___-_:
.... i--_:_::_:_:]:]::::_
:_--:]...... ]]_:__:]__:::]_::::::_:: :]][:::::::::::::::::::::::::: .......:::::::::::::::::::::::::::::::::::::::::::::::EL::::: ......... "I"
==================]::J:
=========::::::
=== : ::::: [ ::::.......:::: : :: i ...................--7 . . . . . . . ~............. ~ .......... !
. n
ffl
1 O 0 ...................................................................... i , - - ~ ............... 9 "
0L _ -----Z.:[:_::]:_]i:]:]:][:][[:]::]]]]E~L][[I][I:]]:~:~2_~_: r~-----_-.'---.___Z:
i
]
i
".Z.:.--_t'..: -_Z..-~
|
-__2
; ~ ~ ~ i i
0
1 ,.,J__ ~. ..... /_i ........... ! ............. ! i
=========================================::::::::::::::::::: ::::::::::: ::: ::::: :::::::::::::::::::::::::::::::: ::::::::::::::::::::::: ::::::::::: :::::::::_._!::::::::::__:::::::::::::::: ::: ::::_._I_L_ ....
> - ] ................................. i . . . . . . . . . . . . . . . . . . . . . . ! _ _ _ i . . . . . . . . . . . . . . .~ .............. ! ................. F
::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
. . . . . . r::::::::::::::mT ......................
7 .................. I . . . . 71 ....... , . . . . . ,---------r
9 I , ' I I
7 : ........................................ r - - - - ' - - - - / " - - i . . . . ~ . . . . "7 . . . . 7"
/ i / i I i i ]
J ...................................! ................Z ............ i ' L__.__I. i
:::::::::::::
- :::: L_:: :::: :::::: Y :::::: ....... :: :::: .... : _ i___: ...... L_ : : ......... ::::: __i ....................... :: __Ls ............ : ........ :_i i 9
:::::::::::::::::::::/i11:1: __ _1111111 __1::11111111]:: ........ 111111 ...... 11111111111_! ............ 11 ___1111111:.... I ..... ::::__::::___L___:::::::__.,J ........................ !
:::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: :]11111111111:. . . . I - [ - ! .., !
] . . . . l ! i ......... ! ......................... [ .............................. I ............................ Z~ . . . . . !.
!.
l ]:II:IIiL:I iiii {..........iiiiiiiiiiiiiiiiiiiiii,................................
{
1 psia = 6.895 kPa
........................ ! . . . . . . l
-I .......... Z .................................... ! ....................................................................... ~ t 1 psia = 51.71 mm Hg
]iii
I
i
......T i i
/ ! i i i .... i, i i !
0.1/ i I . . . . i I I I
-150 -100 -50 0 50 100 150 200 250 300 350
Temperature, F
263
100
..... / ,.
f
i ,
[
1
Sbl3 ANTIMONY TRIIODIDE
!
10 / 1
i . _ _ L L [ ................./
,J I L "
GI
/
. m
C~. /
o9 /
(D
t,...
13_
= /
O
Q.
/
-- x
t~
> /
/
. . . . . . . . . . .
0.1 iilJ r
. , =
/
/
7
!i
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01
300 350 400 450 500 550 600 650 700 750 8OO
Temperature, F
264
1 O0
t ]
b203 ANTIMONY TRIOXIDE
10-
i ~ | .....................................................
4
I
. i
09
(D.
(D
L_
09
03 ..
(D
t._
D_
t._
]
0
(D. ........... .................................
> -i...................................
|
i
..
0.1
................................... ~___
i
' 'i
I
II , , !
i
0.011 f
t
]
!
!
1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F
265
100=
=
,t "1," I' . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I
I . . . . . . . . ,'_ ....... !
10=
iiiiii i i i i 111111
i 84184184184184
i i ii i i i i iiii i iiiiiiiiiii iiii iiiiiii iiiiIIIIIIIIIIIIIILIIIIIIIIIIIIIIZJI-II
. . . . . . . . . . . . . . . . . . . . . . . {:!!!,.....~.-..-,-~,----------,
9 _ r
0.1=- . . . . . . . . . . . . . . . . .
. i
ffl
O.. 0.01~
,,~
(D
K..
::3
fn 0.001 ................................... I .~.--- -''.....=.......-.~
"- -..~-.~..'-::'-::'-'.-:'-:'-~.= -:n -= :::
(D
&,.,,
,L
-~
-,-
]
O 1
o. 0.0001 . . . . . . . . . . r-
>
/
1 E-05 r
................................. ::!!/.... ~-=,,=:- ....... __=:=,__,=::__, ................................. § ............................. _=_::::_....... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I
,--::=-,-=:_,=.
s
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
[
i / ......
. . . . . . . . ./
i i iii-iiii-iii
~' i
r .... I
iiiill / ii i
t 1 psia = 6.895 kPa
.:=_.:=_==_=.====.___==:::t::::: 1 psia = 51.71 mm Hg E-Eiiii":"iiET:EEEi
] ........... :: ::::: .
1
9 VI
II
II ...... i ........................... 1 [
i t
1 E-08-' I i
1500 20O0 2500 3000 3500 4000 4500
Temperature, F
266
100
Se SELENIUM
10
i i......... i..........§...........f
- - T ............T............T .........
,r.......... --,?
i ~ I i
0.1 i: ............................,...............................
~ ........................................................
9
,..................................
,.............
~-:..!!---~
~....... .Z/..'::::..":.:-".:."i
..................... ~ ................... ~ ..........
............... " ........................ :.".............. --~." ""~:--.~.'.:'C~:
O9
Q. 0.01
.~.'-~--- -~-V-~---------~
(D . ,...........
'---------r . . . . . . . . . .2. .....
"P-- .... 7 ........
4,
i
&,.,
I /
:D . . . . . . . . . . . _ + .......
O9 i --/ I
o9 0.001 ::::::::::::::::::::::::::::::: :::::::::::::::::::::
,',.. . . . . . . . . . . . . . . . . . . . . . . . . . . ...
(D
,,. 9. . . . . . . . . . . . . . . . .,
'~===::==:=':~i
,!. . . . . . . . . . . . . .!
13_ ......... ~. . . . . . . . 7'-[ ............ ~......... ---
. . . . . . . . . r - - - - / - - r ......... , . . . . . . . . . . . . . . . . . . . . . .I". ..............
....... "I
K I
T ...................... i
O i . . . . . . . . . . . . . :
I i i i
Q- 0.0001 ...................................... :::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::
9 :
............
.......... .................. .~.....:"~:" "..::::_--._: "::-. :r.:-:
~.......................
.~ .
:::: ::::" "-'-:: "..':::::'.-.::.--:::::::"
.
"-'. "c'..::::::: "-".""..:"-- .~:':.:: ::--'_-'-'-:: .-.:::::::- ,':
,4. ........................................
. . . . . . . . . .
!
~ ............
l
~. .................
i
~ .................
!'
i'
i'
.............. -i i i i i I
............... I- ~ . . .........i,
./__[................... ....................
I
_..,. .................... ,.
I
......... "--" . . . . . "~./::::Z.~ Z.~:Z::.?..-..~--"~::-.
~.~ ....... ."--"."
Z.T.Z'.~ Z.'/::~ ::::.T.:'.%T---/."-":::::.~--~
~C/Z::..'2~::~ = Z ::= ~ ~
.__.____~.___~.___.__~:::-'-----------'---='.=---=~_-:,----~4=_~.=:---=,=_.., ...... ::===~. ....................
! i i
. . . . . . . .! . ----7", . . . . . . . . . . .i ----1'. . . . . . . . . . ti
! i
t ............. t
1 E-06
--_, i i ; i ! !................................i
.....................................
............................
.,
-,
............................ i9
f ............................. i
+"" . . . . "-t
i I i, ..................!i
! i i
1. . . . . . . . . . . . . . . . . . . . . . .,.- . . . . . . . . . . . . . . . . . . . . . . . ,, i I 1 psia = 6.895 kPa
1 p s i a = 5 1 . 7 1 m m H g
-i, ........................i;........................~j..... ii i! i
1E-08 I I I I I I I i
200 300 400 500 600 700 800 900 1000 1100 1200 1300
Temperature, F
267
1O 0
9
r
;;,
'....................................
7
.... ,I i
................
..... ii
11 171;
:l r9
iiiii .
. . . . . . . . . . . . . . . . i;i'
. .
. . . . . . . . . . . . . .
. .
....J i l
I
.
................................................... "
.
:I
. . . . . . . . . . . . . . . 4 / ' ;
........................................
. . . . . . . . . . . . . . . . 7 I ...... ; III I~;71:;LL;L;;72~L
' ' ' ........... ; ....... i " / ............................................... '
. i
..... ; / ,., 9. . . . . . . _ .... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
. ., . . . . . . . . . . . . . . . . ii /
l,---
u)
0O ....... .......,,, , '" ".. '.' o' ,. . . . . . . , ................ . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . .....................................
(D : i
; I
......... , ---_ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j
Q. i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .,
. . . . . . . . . I f ,. . . . . . . . . . . . . . . . . _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i
' i, , , i / l . . . . . . . . . . . . . . J ................... ....i
O f
....... =
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J
,i
............................................. J
........................ -__..__._.J
i ; :::t
/ . . . . . . . : ,,,.., . . . . . . . . . . . . . . . . . . .J
.
~ . . . .
../
. . . .
,i .....
"
[
, !
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 r I I I
150 200 250 300 350 400
Temperature, F
268
100:
,,
!
i . . . . . .
10 I [! i
.... ./!
J
iBm I
;Y I
tO
. m
C].
L_
::3
09
09 _
L_
rt r
L_ -i
0
C~. ==
>
t
l
0.1 =
i
- |, !
0.01-
-200 -180 -160 -140 -120 -100 -80 -60 -40
Temperature, F
269
OLE
--1 'eJnleJaduJal
0<:38 OOg 0s 00~ 0s oo L 0s
I ! ! I I I I LO"0
r
6 H u.iu.i LL' I.s = e!sd L
1
I it" ............................................................................................
........................................ii ..........................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i I
Ii i i i i i i i iii ............
iiiiiii
i I
....................................................
t " .......................................................... 4"i .........................................
i i.
i
I i
t .................................................. ,.-
.I....................................... .~
!.- ...................................................... .,:
i !
[ ......................- 7 i
, m
09
Q_ I/ I
(D
:D
00
In
(D
I,...
13_
!---
O
ID.
>
0.1
!
t .. ...........................
,- ...................................... i.
i i
~.................................... "I' 1 psia = 6.895 kPa
i I
I i 1 psia = 51.71 mm Hg
i
i i
!
i i I
0.01 1 ! f i
! . . . . . . . .9 . . . .
I .....I . . . . . . . . . . . . . . . . i I I
300 350 400 450 500 550 600 650
Temperature, F
271
1 O0 !
_' t
10
/
II t"
/
O3
./
. m
O3
Q.
(D
L _
O3
U) .
(D
f
/
t..,
r /
13_ . . . . . . . . . . . . . . .
/ ............
0
CL
r
>
//
0.1 /
/ ,
.......
. . . . . . . . . .
/ 1 psia = 6 . 8 9 5 k P a
1 psia = 51.71 m m H g
0.01 -
3000 3200 3400 3600 3800 4000 4200
Temperature, F
272
10004 ............ " ................ ~ . . . . . ~ :: .............. :~I ............... :'-
.................. I: '
lOO ....................
- :.-:..- ~ _ _ - : _ ~ ! ........
. m
C). 10
e~
9 [
" __./ --iii __ [
L_ [ ....... /____iiiii i_ ii ............i;
....................Z ......iiii_ii..........ii ...............
/ ........ ..............i
(1) ;'ZII; .........i iiiiiiiiii-iiiiiiii!
13_
0
(3. 1 _L :
> IIIIIIIIIIII-ZI_IL_.IIIIIIIIIIIIIIIII
iiiiiiiii~iiiil/i~ii~iiiiiiiiiiiiiiiiiiiiiiiiiiiii~iiiiiiiiiiiiil......................7".....................................
i i/ __. iiiiiii t
11111111111111111_111111111111111111
/ '
,
i
}
!
i
1
0.1 :T !
,u
......... =-
't'-" 1 p s i a = 6 . 8 9 5 k P a
...... 1 p s i a = 5 1 . 7 1 m m H g ~-
,
.... i,
!
i
1 t ,
0.01 I b I I
-200 -1 O0 1 O0 200 300 400
Temperature, F
273
1000] ! i
I t
]_IIZZIIIILIIZZ;i
] iii~i ZYI~- SiBrF3 TRIFLUOROBROMOSILANE
]
{ - i ............. i
.... I
!. . . . . . . . . . . . . . .i. . . . . . . . . . . . .
I i
1 O(
I l
~..........................................................
9 4..
,,...................................................... ~.
.w Ii...........................................................
I""
i
O9 i t
CL
t............................................... +.
(D
I !
:D
O9
(P
L_
13_
0
13.
>
/ i i , : I
9 i ~ i i
. . . . . . . . . . . . ~
/ ........+~ ............................................................
i i i
~ .........................................................................................................................................
i
~........................................................................
I,
, .......................................................................
L . /
J i i
................................................................. , ................................................................., .......................................................................
i
i .......................................................................
i
, ........................................................................
!
i 1
i
. . ~ ............................................ 4........................................................
P .............................................................
9.....................................................................
9.......................................................................
! ........................................................................
i
i
i i
I I "
1 I
-1 O0 -50 0 50 1 O0 1 50 200
Temperature, F
274
1000 3~22~ii~i~i~,22~2~1211111111
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
............21111211111......L L 1221111LL2211111111111111111L[
iiiiiiiiiiii
l ........................................
I I I '-I
] iiii - I [ . . . . . . .. . .. .. . .. .. ... .. .. . .. .. . .. .. . .. .. . .. .. . . . . . . . .
] .... . . . . . . . . . . . . .
, . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
,1.....................................................................
i i
]illliiiii?iiiiiiiii~iiiiii~tlT:?i ..........i ~ : : : : ] ...........iiiii:21:?...................it:ii .......................t .....................................................................
) ............................./
] ii ii IZZIIIII__ ii
i
]illililliilli i il l l l l l l li~il]=
l C ii= i122 JJ ,7
.m
10
O.
i . . . . . . . . . . . . . . L. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ,!
(D =_ . . . . . . . . . : : : .......: : : : = : = : ....... I
....................................... I
co
(D
13_
O
O= 1
> t 4 i
i
i
!
)
i
i
| I
,..... . . . . . . . . . . . . . ,!
!
i i
0.1
I i
!
! ~ , ,
:................................................
~-
t
.......................I'.i....................... )I
't..... I 1~ 1 psia = 6.895 kPa
i i 1 psia = 51.71 mm Hg
i
1) 1
i i
] t ,
0.01 ' ! , i
I I I I
-1 O0 1 O0 200 300 400 500
Temperature, F
275
1000 I t:
/
f
1 O0 7 !
iiiiiiiii 1
/
/
/
/
................ / J
/
/
. i
ID. 10
/
(D /
/
I,i
/
/
(D
n
0
O. " / "
> /
/
/
/
/
0.1"~ .....
/
......
/
!
i
!
0.01 I I
-250 -200 " 50 -1 O0 -50 0 50 I O0
Temperature, F
276
1000:., i i + +
~'- . . . . , C ; ! r
. . . . ~:~ i i, ~ : ...... [:::::?'::::::::::::::::::::::::::::::::::
+ Si012F2 DICHLORODIFLUOROSILANE [ l -
i
k
.......... ! ............. i
. . . . i i " ~ I "
1 O0 . . . . . . . . . . . . . . . . . . . ~ ....... i. . . . . . . . . . . . :. . . . . . . . . _ . ~ ! , ...........
i --+
I.......... :i:ii :ii!. . . . . . . i Z .iii
......[ -ZIIII '/ i ...............
Z~IT"
-" I + " [ / ! -
i ]: ......... ::: ..............C T;
!
................... i ................. _.4_.................... j t
]. . . . . . LS ...... -r............................. t
,m
;
9 . . . . . . . . t ................ i ~
__ ......._::::Z::::::::Z::I:::,____T_I3L__ZZ : YI i i rzz-:i .....i-.~z~--
i..............................
i
t,...
z~ / i .... ...... i
u~
u~ ........ ! ................ ! / i ........ ! ......... i iiiiiii
.........................
l..............................................................
i i.........................
(D
ft
i , ] i
0 ! / t
Q. 1 ~+!+~+~!!!!~+:++++:+++~::!++:+++++++:.,+:++++++
+++++++++ +++++: ++++++++++~++
++++++++:+++++++++++++++::v+!
> ................... |
--i~
!-~....................................
| t
o.1 ...... I
il 9
.I:........................ .+.+.
!
i
t ................................ i.
I 'i
- / ] ..... I
J
9 , l
0.01 I .. I i I I I I
-200 -150 -1 oo _,t~0 0 50 1 O0 150 200 250
Temperature, F
277
8LE
-I 'ojn),eJoduJo/
Os 008 098 008 0s L O0 ~ 0s 0 0s O0 t- 0s t-
I I I I !
r 1 1
~" tO'O
4
................................. OH uJuJ tZ" ts = e ! s d t ........11111_:::i::.12i i .............................. ..... ! .J" .....:-
................................. ed)l s = e!sd t
[
: [ -
i
r l
~, I ....... --
; ... . ......... ] [ /
.....
,' i ......... ,::: . . . . i
~" ~t'O
7
l
I
r .................... -......... - r. . . . . ;-- : !..
i ..
/ 9
/
....................... _......... _...........~_. . . . . . . . . . . . . . . . . . . . . . .
r ...................... ; 9 9 -!- / 9 ,. . . . . . . . . . . . . . . . . L
r ............................... i
......................... ~ i
r . . . . . . . . . . . . . . ~ . . . . . . . . . .
:.. ..... /
: / :! :
r........................ ~ ...................... ; ..... [! 9 .~.- :
........... :
..................... ~ --r j,._ i - ;// .:'.::...; . , <
....................................~. . . . . . . . . . . . . . . . +.......................... ~.
"13
I
0
: ................... r ........................ i ............. ; - "13
r ........................ ~ ........... 9 ................ - - ' i ..................... ; ! m
(I)
]
O0
, ..... . . . . . . .
r .................. ! ......~ -- i ...... ; - I,, , 9 f.n
. / .... z . . .
r ................ _I
t ............ i i I ~- L C:
.......................
/-
! m
i ' . . . . . . . i .... 9
....
r ................ 9. . . . . . . . . . . . . . . . . . . . . . . . . . i- ........ ; 0
I . . . . . . . ~ .
I ........... i . . . . . . ;- - - " / i i |
.............. i~ ............. , ..... ; .... , . ,i- _ ! , ,, "13
/ OL
i .
i /
; / " r
!
f .................... -~ ,
t
/ . . . . . . .9
.....................
,i". . . . . . . . . . . . . . . . . . . . . . . . . l[ ..... : ........ -~i ........ . / 9
.. l
I i./
I I
........ / - : ~ . . . . . : .. i ........... : |
! ..... |
I . . . . . . . . . . . . . . ~ . . . . . . . . ~ ..... l, -'f I . . . . . . . . . ;
L L
i . . . . . . .
. . . . . . . O0 t
1
I
i ........i ' ............ i " " ,L L L
i
'--_-:- , ........
i.... : I
i L
3 NV-IISOElOn-1..-IOklO'lHOIkl.I. _-1810!8 I
I
............................... i ,i ........ :! " , I,,
i i l ..... [
:............. ) ................................. 4 ).................... ; ...................... i
000 t
1000 , ,
100
. m
O3
Q. 10
(D
L__
(D
L_
13_
t,,,..
0
(D.. 1
>
0.1
i
!
r-" 1 p s i a = 6 . 8 9 5 k P a
I ............................................................ , 1 psia = 51.71 mm Hg
i
,., i!
!
t
i !
0.01 I I I
-1 O0 0 1 O0 2OO 3( )0 400 500
Temperature, F
279
1 0 0 0 ], I ' _ .] i
E
SiF4 SILICON TETRAFLUORIDE L
..... i
. . . .
/
/
W"
,u
/
Q.
(1)
IL_
O9
O3 1 O0
L_
13_ /
IL_
j / j ..............
0
C~. i ......... / .....
tO
>
4
/ .............. - ................. iI ................... i ..........................................................
101 I i I
- 140 - 120 - 1 O0 -80 -60 -40 -20 20
Temperature, F
280
l~8E
-I 'eJn~,eJadwal
OOL 009 00~ 0017 OOE OOE O0 O 0 I.-
!
- 1.0"0
6 H tutu I./..' I.g = e!sd I.
i tK
edM g68"9 = e!sd I. - - - - - i
~'0
<
! "0
0
"=I
-13
'='I
('i)
C/)
c/)
c'-
'='=I
0
-0
:0~ f.n
B
m
:oo~
3NV71SOIAIOI:ISII=I1 8JBH!
f m 1 [ 000 k
. . . . . . . . . . . . . . t . . . . . . .
1 0 0 0 - :: I .... :: ! :: i . . . . i i : ............ :: ! ...... .... +iiii!!!!!iii!!!!!!i! 1
10- ,
..... ! . /
. . / "' . ....
.... ..... !
I
..................................
_ , ! / i .... ' II
.
...... . . . . . . . .
/ l i
.............. _ ...........
,, ! . . . . . . . . . ,
, !/
ki" ........ : l .... . .... l _ _ _ j
L
, ~.. . . .
..... ~ . . . . ! .............................. ...+ . . . . . . . . . . . . . . _....... I . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . J
,I, , , ...... ;
. m 1~ ~I /i" . .
t3'}
C'J ~. ~
,'" } '" I !
" .
,4,, I . . . . . . . .
. . . .
J
I
I=[IILIIIIIIIIIII2;;;;;_I--2;jE.3
............................................
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
I
I
..... / ' " "" "i " '" :
O3
sl,.__
9 : '' ~ -'" 9 + ...... A .................... +. . . . . . . . . . . . . . . _ . J
I , ;.
o)
0.1~ I'"':'1
.....
,. . . . , .... ,
,
1 : ! '" '.. ti " :!
9 i/
! . . . . *_ . . . . . . . . . . I ......................................... I
9' ! ,,, i 1 ..... !I . . . . . . ! ... I .................................. .I
13_
9 " I "' +. .... ; . . . . ! .. I .......................... .+,I
-- ,/I ..t, . . . . . . . . . . . ....... ! . ! . . . . . . . . . ., ,I .......................................... l
i,_ " /
i
. . . . . .
................ . . . .
0 I I I
[
> 001. -~ /
9 .: ,,,,: ,.~
. . . . . .
. . . . .
. . . . .
!
.
. . .
n
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
, ..
. . . . . . . . . . . . . . . . . . . . _. . . . . . . . . . . . . . . . . . . . . . . . . . . .
-- /
/ . . . . . ..... . ....................
/ F
0.001 : ; , ........
-- 9 ,9 ..... .... ; . . . . . . . . . . ; ....... ; :
t. . .
.......
. . =
iiii i JT~Z]]III]II~,IL--II_IIIIIIT_,I:~II_I . . . . . . . . . , ; ; I I , ; ; ; I ; Z Z I I I L . + . ~ . I
.:..t ............................................... i
9 ! ,v o ,, 4 .... ;
-- i . . . . . . . . . . . . . . ; . . . . . . . . "~
- / ........................... i !I .......
] / . . . . . . ' . . . . . . . . . . . . . . . . . . . . ' ..................... [ . . . . . . . . . . . .
. . . . . . . . . . l. . . . . . . . . . . . . . . . . . . . . . . . j
_ H
.L-~ . . . . . . . . . . . . . . . . . . . . . ,t . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j
. . . . . . . . . .
i . . . . . . . . . ; . . . . . . : . . . . . ................ ]1
1E-05 u
-200
I
-1 O 0 0
i i
1 O0 2OO
i
I
300
I
400 5O0
L
Temperature, F
282
~8~
4 'ejn3,eJeduJel
0s 0s O0 L- 0s 00~- OCj;~-
I 10" 0
' 1 1
. - - . 4 . , ....... --~o--~=~,,,,.,-,,,-,,~- ........................... J
t
!6H m m LL" I.s = e!sd I. .....
,i ed)l s = e!sd I. ....
r
-7 L'O
.......................................................
-4 !
:!
L L
0
"13
c::
0
um=
OL
.................................................. --===--= ...... _. . . . . . . . . . ~--~- .................
' Z!i!:~:~~_:~____~i___!~i-_--i~!!!!!! 00[
........ Z
j
3N~qlSOUOAq~IUI s
::-:................. ~ 000 I.
~8~
-I ' B J n ] , e J s d u J 8 1
009 00s 0017 00~ 008 O0 I. O0 L-
I
~0"0
6H uJuJ t L ' t s = e!sd L I I
ed~ s = e!sd t ....... i /:
.._
. . . . . . . I _.
. . . . ! E
. . . . . ~ "0
.../
....... -
. . . . .
13
0
"D
0
" .. / ' " .' . . . . . ,, Oo
O0
.... :: L t-
O
J 13
Oo
im
i'
/
d , r
I
r ~,, '"' , ........ i
::: O 0
J
Z .........
ii
......,, ~ . 3N~qlSOIAIOI:ISIO ;~JB;~H[S
I . . . . . .
I . . . . . I .......
: 000
1000
i __ i
SiH2CI2 DICHLOROSILANE ----
100: -
10: .=
.= 9 ~
.==,=
i ,
03 i
Q.
(D
t__
03
03 , ?
t__
Q.
0 0.1
Q.
>
i z
0.01
|
0.001
i
~'-- 1 p s i a = 6 . 8 9 5 k P a
-I - 1psia=51.71mmHg
t !
0.0001
l
i
it
-200 -1 O0 1 O0 200 300 400
Temperature, F
285
1 0 0 0 ~ I ]
SiH2F2 DIFLUOROSILANE
g
100:
r
. m m
c~ 10:
(1)
rr
!,_._
n
0
Q. 1-
>
m
0.1-
0.01 i :
T [
t
286
1000~_..__._~
I L
~ ~ ~ L ~ iH212 DIIODOSILANE J
100-
.=
.,=.
i i
. m
O3 f
El.
(D
i
U) 10-
(D L._
=..
i
13_
I
/ i
t,..,
0
,,=
13. .=
> I !
I !
1
!
rt
T
, [
Ii I
0.1 T i
o 1 O0 200 300 400 500 600 700 800
Temperature, F
287
Vapor Pressure, psia
o o
0 ,.,,I, o o
0
0 0 0
o
o
--I
o
3
0 -,.
"-~ O0
g)
-I1
ID
0
o
II II
01 O)
"6o
--" 01
CO
C) "" "---'-'-"-
o
"1"
QD
.1~
0-
0
68E
4 'eJn},eJeduJel
008 O~E OOE O~lI. O0 I. 09 0 OS- O0 L- OS L- 00i3-
I II ! ! I 1.0"0
. !
!
.. - ----.. i ........ L
~.. 6 H tutu I./_" 1.9 = e ! s d L ......................
i i
. ed)t $69"9 = e!sd L , , i /
] J --
] .... / . -
. l
!-....................................
!
7----: ........... - ................... ~1. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ; ........................
/
I
..... - ...... = _ ~ = _ _ ~ . : ................ ~_-: . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . l
J /
_
// .. I,
. . . . . .i. ...................................... I ............................... L <
/ '".i
#_
,.i . . . . . . - ..................... -L
"0
;i 0
"U
(1)
/
/J (/)
C/)
(-.
................................... 1 , ..... / .-_
!
i/
" i/ . . . . . . . . i (D
,---o=-. . . . . . . . . . . . . . . . ............................ i ............................. L_ x . . . . . . i
. . . . J 1 I I! .... i
......... ',-_ ' ,i ..... ! ! ,! "0
i ! 'OL (/)
mm
I 4
i i
I
L
i. - . . . . 9 .................... L
"t' ../. ]. ~ . . . .
.................. _/__ ............ .L; ............ :............ ;ii: "_11 _ 1171- ~ ........... ~.. i ........ ;;;;i. ,:
- - i ::::::::::::::::Z:; i _! ........ ! ..... ._ ................
:~ OOL
J L.. [ .. L ,,, J
/
I
l
/ j ' -
g NV-IISOI:IO'IHOONOIAI IOgH!S
!
., l., '. [ .l,. ~.' .... ''~
i ...... t ...... I t. i i ii --ii i ---__
, i I l { 7
' 000 L
1 000
! ..... . . . . i +
J~
SiH3F MONOFLUOROSILANE
j r /
. . /
/
/
I
1 ' 1 i
100 ~. , ,. f /
, / J : ' ::i
~/ i,,,, ... ....:
.
/ .
,,=,m
03 : ........:.:, .... :
EL 10' / , ......... ,
i
P, i
CD
tk=., i
::}
03
03 l
(D
L_
13_
t__
0
(D. 1
>
0.1 . . .. . . . .. . . ~ . . .
,,:,+ ....... i i i . . . . ..... ',...........
. .
....... . , ; n
1 psia = 6 . 8 9 5 k P a
lpsia=51.71mmHg
i
E
E
0.01 I I I I I I 'i
-250 -200 -150 -~00 -50 0 5o ~00
Temperature, F
290
1000
.... j . . . . . . . . . . . . . . . . . . . . . .
i . . . . . . . . . . . . . . . . . . . . '-'
J i i li i i i i i iiiii i iill iiiiiiiii.... i
i
1 O0
. m
Y~~~~~~:~~~:~:~!~~````~f
................ iiiiiiiiiiiiiiiiiiiiiiiii
Q.
(1)
I,,=.
::3
10
(1)
13_
0
C)...
>
t_.
I i '
. . . . . . . . . .
i
i
i!
0.11 I I
-100 0 100 200 300 400 500
Temperature, F
291
1000. _ ~ ..... ~ ~ ~________:__: ........ _. . . . . . . : ......... ____::_:_:, ........ _. . . . . . . . . . . . . . . . . . . . . . . . . . t ......................................... ..I
I I ! [
" ' , I [ .................. i_~i~iii.......... ~iii....... [-----~i~:i .......... i:ii .................... i . . . . . . . . . . . . . . . . .
L !
Sill4 SILANE I
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . .
10 /
/ S
...
. m /
CL /
...
n I_/
[7
O
/
/ . . . .
CI.
>
0.1
/
,/
I
/
/
/
0.01
0.001 I a I I I
-350 -300 -250 -200 -150 -100 -50 0 50
Temperature, F
292
1 O0
J
I
!
Si02 SILICON DIOXIDE
10
. m
i !
(1)
!__
03
09 ; .......................................................... ~ . . . . . . ............................. == ...........
(1)
L_
O_ / 1
t__
......... / I
0 I
Q. !
I=
> . . . . . .
. . . . . . . . ~///]
!
0.1.
....................................... t ...........................................
i ! =
1 psia = 6.895 kPa
i
L
1 psia = 51.71 m m Hg
i
i !
|
i i
i !
0.01 I i i i I i I
2800 3000 3200 3400 3600 3800 4000 4200
Temperature, F
293
100 !
Si2CI6 HEXACHLORODISILANE
10 . . . . . . . . . . . . . . - , ..~, . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . , . . l
03
. m
/
U3
13.
f
. . . .
(D
L_
:D
00
03
(D
L_
Q. /
L_
|
......
O
EL
r /
>
/
/
f
0.1
/
/
/
/
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01
50 1 O0 150 200 250 300
Temperature, F
294
100
Ii ............. [
Si2F6 HEXAFLUORODISILANE
10
,,m
cO
c~
![...................................................
_ . ~
(D
&..,
(n
co
n
(D
~iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii.............1~,"
t .... [
0
c~
>
.......... Ji, !. . . . . . . . . . . . . _
0.1
L,
1
il ........" , !
0.01
-120 -1 O0 -80 -60 -40 -20
Temperature, F
295
10
t ! 1 J
03
u3
(D.
(1)
t..__
U3
03 ....
/
,
(D
!.__
13_
/
t,.,.
O
EL
03
>
E
0.1 I i I
-60 -40 -20 0 20 40 60 80
Temperature, F
296
1000 ..............
iiiiiiii i:i:i::::~ iiiiiiiii:ii :: :iiiiiiiiiiiiiiii :i~i::::iii~iiii i i:i ::: i~iiiiiiii ii ~iii iiiii ~ :: ~ii~iiiiiiiiiiiiii :~i~i~iiiiiiii iiii ,
. . . . . . . . . . . . . . . !
~ill i . . . . . .
....... . . . . . . . . ! . . . .
! I.............. I
100
!
I
10-
! ' I :
(B
, i
Q.
~ . . . . J
L _
(~ ;~::::::::::ii~ii
iii;~:::::::::::::::::::::::::
.......
i
n
f i
0
Q. !
(If
> . . . . . . . . . . . . . . i
l
!
0.1
i
i i i
| ............................................................ 1 ........................................................... --
i i !
i i !
:!i i t
t
t
i I
t t
0.01
iiiill .... ~iiiiiiiiiiiiiiii~iiii~i~iiiiiiiii -i
1 psia = 6.895 k P a
,] iii i i i iiill iiiiiiii i ii ili i
1 psia = 51.71 m m Hg
4 ,iiiiiiiii ....... iiiiiiii LIII ........... iii ......... i ................... ii........ !
! I i
!
0.001 i I I I I I
-300 -200 -100 0 1oo 2OO 300 400
Temperature, F
297
100'
L ............. i ............................
i I .................................................... , .............................................
i
~! .... ..... i
!
. . . . . . : . . . . . . . . . ; . . . . . . . . . . i . . . . . . . . . . . . . . , .....
1 i -
10= ...... |
......i
oO I,
Q. ~j ..... i,,
: ....... 1
i/
L_
, L,! ........... = . . . . . . . . .... . . . . . . . . ... . . . . . . . . . . .
03
..... = . . . . . . . . . . . . ! . . . . . . . . . . ! ........ ~ . . . .
, i
CD
t__ i
13_
t__.
. . . . . . . . . . . . . .
0
Q.
>
,_i . . . .
i =i
]
_I
. . . . . . . . ! i . . . . . . . . . . . i ............... ~ ....................................... 1
r
_i . . . . . . .
i : i
i ! }
i i
i i :
! 1 psia = 6.895 kPa
t 1 psia = 51.71 mm Hg
I
0.1 I , i I I I
-40 -20 0 20 40 60 8O 1 O0 120
Temperature, F
298
100
i
Si20CI6 HEXACHLORODISILOXANE
/
/
t
10
---I--.-.....................
.................................. ,
............................ ;.....................
cU
Q.
(D
/
/
cO 1 /
/ J
1t,.,., L /
13_ i I .....
/ --
0
c~
CU il .......................
>
L .................... / _ ]
0.1
i...../i
E
~ .................iiiiiiiiiiiiiiiiiiiiil;iii!!ii~iiiiiiiiiii!i 1 psia = 6.895 kPa
i
0.011 i I
0 50 1 O0 150 200 250 300
Temperature, F
299
Vapor Pressure, psia
o
o __L
o o
! __L
0 o
o3
o
"--I --
o o~
3
"0
(D ,
t-
O
,w
!
"-n~
Ii II
!
ol 0~
."" b~
(2) ---" 01
7"
(:2)
I!~!~!~~ii~ii!i~!:~!i~: !~ii~ii!!!!l
1 O0 -
I ...... .... ! ........ !
:Si3CI8 OCTACHLOROTRISILANE
. . . . . .
i f/
0 ~ ~ ................
i . '~i ~ _ ....... .. _:i _.:::::i_i_.??illllll ........ 2~2~2iii-!:::::::;;-...::~::::~.::::::::::??~:;!??~::::~:~:~222~::i~2222i22222222;222~22222
,~ ......
"' i . . . . . . . . . . ............... : ............................................. ~- _. 2 _ _ / . j i i 2 ...................... , .......................................................
,,, i
.......... 9 i t
i [
.......... . "-----" I I
Ii,i
u~
. . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . ~ 9 . . . . .................
. . . . I...................................................
,, ,-. . . . . . . . . . . . . i
- ................................................
,
t,,i
.,4'r.................................................... i 4
13.. 'i' ................
t,i / ............ 1 !
0 ....................................
jI i i
ID. ........... I .......... ~ ...... / i
i, !
> .......... ~! ....................
i~/ ................ | !
: I l
0.1 ! I '
"i ..........................
. . . . . . . i /. '
i
l
. . . . . . . . . i ............ 4
/ , ..... i~ .........
/ i
~,................................................
~ ................................
I psia = 6.895 kPa
i 1 psia = 51.71 mm Hg
- i
0.01 '1
! 1
~ ~ ~ I
1 O0 150 200 250 300 350 400 450
Temperature, F
301
100
Si3H8 TRISILANE
~
f
../-
J
/
/
. . . . . . . . . . . . . . . . . . . . . . . . . .
u)
u m
CL
....
(1)
t,.-
u')
u)
/
(D . . . . . . . . '"
t,,..
13_
L_
O
CL
GI
> ....
....
0.1 , ,
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01
-100 -50 0 5O I O0 150
Temperature, F
302
100~ !
.................................
I
.... ~;~iii1Si3H9N TRISILAZANE IF' ...... .......... ................ '. . . . . . . . . . t;'
I
lu i ,, ..............
............. i
............................;i
......... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . iiii .......................
j ...........................
10- ,, ' I
.m
03
CI.
(D
t._
03
03
(D ~x::: :~iii:.... ~ :i: ~~;~::~?~:~:::::x~--
L_
i~
ii ........ ; i i ....... i ...................
13.. - . . . . . . . . . . . . . . . . . . ; ....................... /_ ..... ];i ...... i ...... -,
,.--_._.__._,__1
t---
O
CI. { ......... ....... i ............. / ..... ! ....................................
t0
> ................... .J9
. . . . . . . . . . . . . . . . .
0.1--- ........................ / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . /
/
z
........................ r ............................. | . , . . . .
i
! t=
0.01 i ..... . . . . . . . . . . . . _ . . . . . . . . . . . . . .
303
100
!
Si4H10 TETRASILANE t
.......... =
/
10 f
.............! . . . . . . . . ~ / i ~
. . . . . . . . . .
/
e,=,~
03
Q.
CD /
CO
G0
/
CD
t_..
13_
L _ |
o ,/
>
lb.
/
/
0.1
I
/
/
/
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 -
-50 50 100 150 200 250
Temperature, F
304
100~ ;:_ . . . . . ; ::::;.........::::::: ...........:--:............- - - - - - - : i - : : c - - ....... - - - - ~ : - - - : : ~ - ~ : : ; - : - " ............................................................................................................ ,
1 0"-; I ._ 89 I .....
.iJ.
..........................................
........................................................... , ~~..."..'-:'-~..:.~--'~
~ : : : - - . - _ _
. ,,. - ........ | . . . . . . . . . . . . . . . ~. - .... . ................... . .................. : ....... :] ...... _. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . _ _ _ _ = . . . ~. ~.- - =. ~. = =. , ~. ; ;. ~ ;. ; ;.; : :.: ~. ? : _ : : - - _ - _ - - ~ - ~ : ~ -
0.1- 1
't9......................................... ... 'i- ::::::::::::::::::::::::::::::::::::: ...................
................................ i;;; .... ............... ,.
= m
-. . . . . . . . . . . . . . . . . ...... I ..........................................2" .~---"~ .................... '
ID. 0.01=
_
'
~ _ ~ ~
i.......................................... -,
! i
0.001 -
| ~
O , i
c~ 0.0001- = ~ ~ .~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ...---,
> .
~__________~
L
.......... , ..........................................................................
|
1 E-05-
t'--"--'/~
,I.. __ -_=___- . .~ ............ ~,
= ....................... ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .~
1 E-06= - - ~ ~ _ : T . % ~ . ~ r .
t../_.
. ~ . ~
. . . .
~ ~ ~ ~.~
~
;_-~: ......... : ............ -----= ...........................................
L....................................................
..t~""~,::~:"~::~
_! 't ............................................
,=.
~; ", , ~ - - - - - - 7
......... -___;;___- ......... __ " -~ ! . . . . . .-. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. .. . . . . . . . . . . . $
--
~ _ ........ ~ ................ 9 . . . . . 9 .. , .:
....
-- ... _. . . . . . . . . . . . . . ------~ --~ ......................................................
i=
i .... i
= 6.895 kPa
1 E-07- . . . . . ~ ! ! - ~ i - ~ : : i ~ ! ~ ~ ' ~ = 51.71 mm a g
.=
~ L,III~;;;[IL'L;: ;/i??;;;;;;:??;: :' LI;:?;: .......iil;"i ............... _-iii;; ......... 7:'_ ........... i:i:i':~-iiiiii14~
/ i i .............................. i ................ ,_L_
................ i t [ .... i ~
i I ! i
1E-08 I i i i i I
500 1000 1500 2000 2500 3000
Temperature, F
3 0 5
~. ...... ; ~ ....... ] ............. i ~. . . . . '--t ' , _ :___-:_:;;;-_::;:: ................ ;_ i.
Sn -I-IN ................................................................... :-
9 . . . . . . _I .. ; : . . . . : . . . . . . . . . . . 7 , ............................. -, .... -- I
1
......... : ..... . .... : ~ : . . . . . . ~ ,
.- " . . . . . . .
;
.. . . . ;7 ...:
/ , i " ....... +, , ............................................... ..,
0.1 . .
~,+-".:'. . . . . . ., . ......... : ...... : :-::-::
+ . . .: .: ; ; / .... , - ...... : ! ............ ..... ::::: + :::: ! ............... _+-=.;
_ 9 .... I ..... : - -- - - - q P , I
9 ! . . . . . . . . # ...... . . :/..;, . . ...... t " ' . 1
~J -" ; . . . . . . . . . . - 9 i[ .... , , 1
i ~, , i ; ........... ~ , ; .............................. .IP i 1
9 ....... _, . . . . . . . . . . . . . ! / . . . . . . . . . . . ; , l+ 1
. m
ID. 0.01 -
_, .
' ... ..... i, ..
... ......... " ..... i_ ............. ,i .......
. .......
:+, . . . . I..:L:.S::. "
.+ ....... i-: :-:++~::--+~--++++++:-+=:::-::::-
......
............. +, .............................
_ ....... l,
. . . . . . . . ; ...... ]:- . . . . . . . . . . . : , 9 ................. [ , - . . . . . . . . . I
m,
_1 .... i .' ]" ; . . . . . ; ........... ! - " + . . . . . . . . 1
l,_._
_. _, . . ; ~2" .. l . . . . . ; ........... ,-i i 1
. /
/
Ir
- . . z..'.. ! ; . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , .. . . . . . . . . . . . . . . . ;
- . .........
_ ", " / .... i ....... .! . 1. .... . :.. ', ......... . . . . . . .
~__ . - : : . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . 1
L _ J. .............. : ; . . . . . . . . . . . . . . . . . . . . . . . . 9 ........... 1
/
0
..........
9 / ........... ~ ...... :.... ...............
+,
I:::). 0.0001 .~ . . . . . . '
..........._ ,
- / 9 _" : ......... ; . 1
/
...
1 E-06 ~,. . . . . . . . . . . . . . . . . . . . . . . . . . .=. . . . . . . . . . . . . . . . . . . . . . . . . . . . . f- :'----.-::- ...................... - - : . . - i . . . . . . . . . . . . . "-- ...... - .... = ' : ~ - . . . . . . . . . . . :'---:"-":::
? 9 .......... . : . . :---:. ....... . ..... : ............... :_::_::::_~: . . . . . . _........................... ,
~ : I .... . . . . . .
% l ; ............. ___.+
- - . /
_ .
,r
1 E-08 1 I I i i i i I
Temperature, F
306
1 O0
9 , , - |
i
SnBr4 STANNIC BROMIDE 1 ...........................................
i
9 , .
. . . . . . . . . . i . . . . . . . . . . . . . . , . . . . . . J . . . . . . .
10
P-
I
i
I i
tO --T T
i i
,,m
(/)
CL i
1
(1)
!-_
!
O9 {
!
(1)
1 :i
i
- - - - I
13_
I,-
0
CL
i i i--
4
tO i
!
i
,| i
>
i i
i
J
i
i
I
!
i
! !
0.1 9 ! | 1'
qp
................................................... t ............................. | %
! T
.............................. ................................................. !. . . . . . . . . . . . . . . . . . . . . . . }
i l
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
................. I . . . . . . . . . . . . . . |z - --
I I I
1 O0 150 200 250 300 350 400 450
Temperature, F
307
100~ _J . . . . . . . . . . . . . . . . i . . . . . . .
IF
LIII? ;IIIL LI IIILL i ~;il i il il I,II~T==IIII ~ ....... iiiiiii ....... i"~i=ii .......
10
......
, ~ - ~ - - ~~ii
".......ii~'
. . . . . . . J
f
I i
/
ffl /
r
,/
L_
....... I " / '
13_ /
. . . . . X
0 /
/
>
/ _
/J
0.1 LJ
~ / J
-r
/ 1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
0.01 I I
600 700 800 900 1000 1100 1200
Temperature, F
308
100
IL l
10
V ii i iii.iii_
03
C}.
(D
t=,,
03
03 , i~/.....
i, iiiiiiiiiiiiiiiiii~i
......... ! ................. ii ......................
(1)
t__
n
. . . . . .
/ " iiiiii
t.._ / 1
0 l
Q.
.! iilvvvi i . . . . . iv
>
0.1"
/
.... i ~ / ......... iii.......i ..... :
. . . . . . . . ,,,
i
J i
0.01 I I I i
-50 0 50 1 oo 150 200 250
Temperature, F
309
1 O0
,. . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . .
SnH4 S T A N N I C HYDRIDE
10
7
p ~
J
/
. m
t~
Q.
fY
CD /
u~
u~ _ . . . . . . . .
(D
!,-
13_ J
/
t=..
0
Q. . ........ / '. . . . . . . . . . .
/
>
/
0.1-
W,
0.01
-240 -220 -200 -180 -160 -140 -120 - 1 O0 -80 -60
Temperature, F
310
1 O0
............... , i.... IIII................................. IIIii iiiiiiiii ............... Ji ...........................
_ iii ...........................................
$nl4 STANNICIODIDE
0- , !i~7 ....................
t ~
u}
i
. . . . . . i. . . . . . . . . . . . .
~
i - i
~iill
...........
i
CL l
O)
U)
..
o9
(1)
L _
13_
f
L _
0
CL - / 7 i
>
/ I
i
' i i!
i
0,11 ~ ! .
!
I I i
I ii !1
0.01- i i
300 350 400 450 500 550 600 650 700
Temperature, F
311
1 O O ~i~i~ ~
' ~ ii ~: i i .... :::::: :] :::::: :: :: ~i~ii ii~ iiii
r n . . . . . . . . . . . . . . . . . . .
Sr STRONTIUM
I
10~ .....
n i! |
II :lll .............1 !L'll I ll::ll::::
:l " l l l l l l ~ ~
.... [ __ _ /
-/ .......
JE_
- _. . . . . ~ . . . . . . . . . . . ~ z _
. . . . . . . . . ' ... I
/
/
. . . . . .
. m
9 =
(D
. . . . . . .
L_
/
(D
I,... i _
n 9 . -
f
. . . . . . . , , ,
0
c~ 0.0001 / ~ -- _
> I
I ! ........ ...... - .. ::: ....... : ..
. . . . . . . . . . . . . . . .
I . . . .
1 E-05 j J/
1 E-06
./
i
_ i
!
!
/
1 psia = 6 . 8 9 5 kPa
1 E-07 - / 1 psia = 51.71 mm Hg
" !
1 _
[
I
1E-08 I i i I
500 1000 15oo 2000 2500
Temperature, F
312
11 1 . . . . . . I __ t _ _ I ................................... ! ....
7 ...............................................
!
. m
09
T
Q.
(D
L _
09
Q I / '
..... iiii i iiiiiiI ~ iiiiiiii iiii1 __ Z___itli iiiiiiiiiiiiii
L _
13_ !
_ ii
!
L _
ii ......... i ___i_I ...... ........ .........1 __/_ ........ I ...........................
0 !~ I'
El. IIZLLIIIIIIIIIIIIIL .........!LIIIIII ii................ii .......I___i__/_ .......
>
...........__ .......1..... i............. Z .................i......... , =
! /_I ............................... t
i . . . . . . . . . . . . . . . . . . . . . i/ "
I
1-iiiiiiiiiiiiiiiiiii-iiiiiiiiiiiiii
iiiiiiiiiiiii_i_
_i_iii_iiiiiiiiiiiiiiiii
. .i._.i_ii.i.i.i.i.i.l.i._.............
_i..i.i :
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i i
0.01
i!
I
!I iI
3700 3800 3900 4000 41 O0 4200 4300 4400
Temperature, F
313
100=
i I
. . . . . . il '
1-a T A N T A L U M
/
..... :::~ ii:::: :::i::i ....... : ........... ! ...... ~ : .... ~ ...... c ~ ~; ...... ........ ;;:i:;;i ...... ;ii!!!!!;!:;:!i!!!!;;;~:!!-!~!:::.~i;!; !!!!!!!!;;~;~;;ii!!!!;; ~---~..... :~
i ~--./-
/
..
, /
0.1 -"- .......................... i .................... ~-~!~;~ : i ~ i~i!~!iiiii,i~i!!:_iii,ii~;_!:_ii,iii!~!;_!!iiii~i!~!]iiiiii!~!!!]i......... :................... ::::,::_c:_.::..................... ::::
/ .
n O.Ol
9
(1) -_ ~ : / " ii~ i~i i i /iiii ://'iii iii'"'i ii/" 'ii//::ii/!i:iiiiiii:iiiiiiiiii'.:iiiiiiii.': iiiiiii/:::iiiii .... :iii
/,
/ . . . .
0
/ '
c~ 0.0o01 k
> i
m . . . . . . . . . . . . . . m . . . . . . . . . . . . . . . . .
/
1 E-05 ..... ~ /
/ -
1E-06 i!i ~/
Pd
|
iiii i/
1 psia = 6.895 kPa
1 E-07: / 1 psia = 51.71 mm Hg
:/
1
4000 5000 6000 7000 8000 9000 10000
Temperature, F
314
:
,!
I
10
m
0.1
O. 01 _= ,,m,~r~~mi~T--~-..-.-~.~--!!! ................................
- t " i i -------~.-_-.,,
0.001 -= = =L=== F ~~ZIZI~________
- - - - - ~ - ~ ~ ~ " ! ! - ~ - ~ ~ . . " = = ~ r ~ ~ ~ = ~ ! ! ~ " ~ - ~ - ~ - ~ ! ~ - ! " - ! ~
, , m
O9 "= .
ID.
O. 0001 = ~.----.-~.'.=-~,'-~---~'---~---
ID
:D
In
1 E-05 ' ' ', ----------
ID
______1~ It
I,.,.
13_ -- ,.____
K--
O
E-06 = -~ ................................................... i
=_ ! ................. :
ID.
- t ~ ' i
_ ____~..------=_~ .~
~{~!~:=:::~==:===.-..--::=::::::::::::z:=:
!~ .............................. ~=:-"=.====:
- r----r t , , ; I
1 E - 0 8 _- ~=..~--F.!!:!=~__.==..._.__.;:_._::~__-_:=!_,=~_====_~-~====:__...._~_
4 ~
t .............. :::::::::::::::::::::::::::::::::::
, ......................................
~ , _ ___
, ..................
.................: ~ =::~-="=:="====--==
, ...........
E-09- , ~ ~ ~ ........I
1E-11
- ====~ ............... ~ ~ i - -
- t
1E-12- |........................................ ~.......................... f
2000 3000 4000 5000 6000 7000 8000 9000
Temperature, F
315
100============= . . . . . . . . -] . . . . . . . . . . . . . . . i ................. i....................................i ...............................................
:f===:=:-~:~==---==== .......=l
i ~ I ,
Te TELLURIUM
r r ~
0 _~ ~ -,, ,~
- ~ J - 5 9 9 ...................... 9
_ _ .
9 ~ z . . . . . . . . .
O, 1 ........... ~ 9, , ~.
] /1 ........... i -i
,m
0.01
- ~- -/I : ,.~ .........
Q. - ~ ~
/
/
t.._
. . . . . . . . . . . . . . . . . . . .
i t
O3
Q)
0.001 . . . . . . /
/ :
i._ ,/: , i
13_
L_
0
cl. 0.0001
.
-
/
;_
r
>
L /
[/
/
1 E-05
~, .......
/ . . . . . . . - . . . . . . . . !
9 /
1 E-06-
...~. ..... l
,E o7;, J
1 psia = 6 . 8 9 5 kPa
1 psia = 51.71 mm Hg
1E-08 I i i i i i t i i
400 600 800 1000 1200 1400 1600 1800 2000
Temperature, F
316
1 O0
i !
I
...... :_. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . j
10
. . . . . . . . . . . . . . . !
, , m
r~
(D
!,---
:3
iiiiiiiiiii~
(D
n
!,-- i . . . . . . . . . . . .
/
0 i
13. , !
>
!
........... I
!
z 1 psia = 6 . 8 9 5 k P a
- /
........ , 1 p s i a = 5 1 . 7 1 m m Hg
o.lL
1
i i
i.
! , 1
I I
450 500 550 600 650 700 750
Temperature, F
317
100 ,. ~ ,
9 , ' ' " ' ....... ]i-i;;; "7 ..... i ......... ..,, '
!
i r
10 .......... : ~ i
i !
; i
J ~ L."
"G . . . . . . . . . . . . . i i .....................
!
f
L ! t. . . . . . . . i ..... / ,
. u
O3
Q.
/,; ...................................
J
(D
t__
09
O3 <. -: '. . . . . . . . . . . . . . . . . . . . . . .
(D /
>
/ IF
!
0.1
_i/17111111111111
/,i ......
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i i
0.01 I i i i I
-180 -160 -140 -120 -1 O0 -80 -60 -40 -20
Temperature, F
318
loo ............ ~!~ ! ! ~
1- - ~ -_ ~ ~. ~ ~ - - , , ~ - ~ - z - -.~--------
] 4-.........................................................................
, , m
ID.. 0.01
!
t--'7 ------T
-I t
(1)
:3 ........................................ '-, .....................
In
(/'j 0.001
!
~------..~.
~
9
~.:~ ~ ~ : : ~ ~ ~..~
[
~
~.-_.~..-::...-=_.--::=.=
i
~ . . . ~
r
~ ~ ==:_.~------------~
:
s
(D
!.-
13.. i t ~[ .........
.............................................. .!}
0
ID.. 0.0001
>
1 E-05 , !
' F-----
! i
1 E-06 [ ......
,1.
--!.----------
............... " i . ~ i . . . ~ i . . ; i ~ ; ; ~ ; =
,l-.-. . . . . .
t
m
I----
1 E-07=
1
!. . . . . .
1 psia = 6 . 8 9 5 k P a
1 psia = 51,71 m m H
l....--re.,
, !
1 E-08-
2000
t
2500 3000 3500 4000 4500
I
5000
I
5500 6000
Temperature, F
319
-! ' a J n ] , e J a d U J a l
OOZ oog oo~ oo17 ooc oo~ ooL O0 I.-
I - LO0"O
......................
6 H uJus LZ" Lg = e!sd L
edit ~ 6 g ' 9 = e!sd L
........
9 L
. . . . . . . . . . . . . . . . . . .
1.0"0
i
/
/
I
.......
L
J I
I
L'O
<
,/ 0
, /
/,, ....
..... ..,/ :L
(1)
f~
Or)
/ I=:
/ (1)
/ w i
"O
m , ,
.......... , .: , : .: . / : ............... l
E
........ / , . .
i / l ,,
01.
. . . . . . . . . .
i. . . . . . . . . . . . ~ . . . . . . . . . . . . . . . . .
..... ~ / . . . . . .
.......... ~'i .
.~. . . . . . . . . i. . . . . ~. . . . . . . .
,,
~.~" . . . . . . . . . .
/ ' i. . . . . ':',": . . . . . . '"
O0 I.
. . . . . . . . . . . . . . i . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1111111111111111111111111111// 9 .
3CilklO-IHOVkI.L3.1. ~nlNVJ.IJ. tlO!J.
/
f !
I ..... ,,i ~ ,. . . . . . . . . . . . . . . . " ............ , !
0 0 0 I.
100-
A::: !ii!!!i LL L:!:!'::_,
-J i iiiii-- ii 31
0.1-
i i !i! !i ! ! : ':!!;!!: :!:: i::~Z:i !:: ! ! ii !!: ! : Li:~ ~iiiiii:::::: i : {i :: !:i:L::::;::: iiii ~ ....... ===================================================================
I
..... ! / [
ZK , [~ ...............
. i
r
0.01
--A-
(D ..................................... !
L_
09 ....... i .................... i, i9
0.001
(D
n
L _
iiiiiiii!!!!!i!!i!!~!!!!!!!!i!!!!~:J!:~ii~iii!i!!iiii!!!!!:::~:~
....................
!I!!!~~-~---2L~.--.----~~_'~-~_~_.~.,
! ......................................................................... ! . . . . . . . . . . . . . . . . !. . . . . . . . . . . . . .
:!
t.._
0
Q. 0.0001
>
iiiiiiiii iiiii}iii ii iiii i~iiiiii;i;iiiiii iiiiiiiiii LIIIIIIIIIIIIIIIIII ~
...... t ...................... i
1 E-05-
! '.
1 E-06 ! L
1 psia = 6.895 kPa
1 E-07: 1 psia = 51.71 mm Hg
[
| . . . . . . . . . . . . . . . . . . . . . . . . . | .............. 'i'"
! ....................... !
! ! I!
1 E-08 I I I I
500 1000 15o0 2ooo 2500 3000
Temperature, F
321
100 ! ! !
/
/
10 /
cU
o9
Cl.
/
J
CD
CD /
i 9 iiii ii ii
!,__ /
0
Q.
/
cU
> /
/ 7
/
0.1-~
9 J ,
- I
0.01
900 1000 1100 1200 1300 1400 1500 1600
Temperature, F
322
1 O0
9 . . . . . . . ~ ~ ! .....
r 1
fil THALLOUS IODIDE i
7
| II
J
4
i
i
10 r.--"~
i -7
r-7!
= m
Q.
(D T7 i ......... :'
z~
I,...
A" ! I
........... i / ~ d ~ .......... !............................ I ........................
L_
/ IZIIIII
f~ ............. iiiii I ..........
~_ __ ZI .................iiiiiI__iiiiii
....................
IIIIIIZIII][
0
/ ! . . . . . . . .
ctl .....................................................................
z_______:::::: ............
:--:--:::::::
............
,......................
........ ::
:--" ..................................
4 ...............................
>
/z i 1, '!
. --Y ........ i
\84184184184184184184184184184184184184184184184184184184184184184184184184184184184184
i
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i ........................
I i
0.01 I i
II II I
800 900 1000 11 O0 1200 1300 1400 1500 1600
Temperature, F
323
0.01 ~:: :: -::::::: : -:: ::::: : :: :::::::: _ ::::::: : :~ : ::::: _ :::_::: ::: _::::::::::::::_: . . . . . ::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::::: ................... -. .......... .-_: ......... ---- ......... --: ........
Tm THULIUM
0.001 9 ~:::
L
0.0001 . . . .
:: ' : ::! :
:
!:ii:::!::::: ::
:
::::::::::::::::::::::::::::::
:
::::::::::::::::::::::::
.... :,..-
:::::::::::::
= ::, . . . . . . . . . . . . _
j-
1 E-05 . . . . . . . ....................... . . . . . ,
:::::::::::::::::::::::::::::::::::::::::::::::::: :::___:_:::::::___ :::::: ...... :::::::::::::::::::::::
. m
09
EL
1 E-06 ,,, : : :::: : ,z
L/
i::: ::: _::
:::_ :::
_
:
: 12 : _
(D
. . . . . .
/
:0
O3 /
09 1 E-07__ ;
,
. .': : :::::: ;7!!.'. ..... - :::: ! !!!!!
(1)
L _
' : ...... . . . . . .
/
/"
13_ . . . . . . . . . . . . . . . . . . . . . . . . ~ ~ . . . . . . . . . . . . .
/
L_
0
, /
EL 1 E-O8 , i
~: : " : :. . . . . . . . . ,,,'.i
> ~::: .......... :. . . . . . . /:L: ........ . . . . .
.,,/ . . . . . . . . . . . .
. . . . . . Z . . . . . .
1 E-09:- . . . . : . . . .
..... / . . . . . . . . . _.,,.
/ , r
/
1E-10--,
/ : . . . . . . . . . .
:1 . . . . . . . . . .
..,~ ,~ ] t/ . . . . . . . . . . . . . . . . . . . . . . . . . . . .
i L
1 psia = 6 . 8 9 5 k P a
IE-11 ~;: iiiii :::i: . . . . . . . . . . ........ ............ .......... ~...........................~....................................... - - 1 psia = 51.71 mm Hg
. . . . . .
~I
1E-12
................................. i
I
600 800 000 200 400 1600 1800
Temperature, F
324
c_;zE
-! ' a J n : l ~ J o d w a l
O00L 0099 0009 0099 0009 009~' 00017 OOCJ8 00013 OOSE 000;~
I I I I ! ! 1 80-=I ~
I
!
......... i ....................i / ......................
................ 7 ........... -it ....... ...... ....
i .... ~ ._ - ir _ - -___ _
i . . . . --: ................................. #~, --- ---- --
~ H UJLU I.Z" 1.9 = e ! s d I.
e d ) l $ 6 9 " 9 = e! ~Id I.
. . . . . . . . . . . -.................... ; . . . . . . - ............ _ - ...... ,- ...... - __ ...................... .................. i ...................... /-__i ...................... 7-: ...... __
,I i_ / I
........................ ___~ . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . I . . . . # I . . . .
......... I ..... I...;..--~ ............ _ -
i- - ..... ! ..... : .......
,.~- ................................... -t_......... :---:--
17ZZZU_-ZZ-;_ZZi ..............
|. i
i t ] ; : ] 3r [ ] : ]
<
1.000"0 "~
0
""I
i ~ i ~/ii .... i ?,,,, . . . . . .
~ZI=ZZ:ZZ--~ZZ~.[ZZ7
................................... ====.................
/= .,-I--.................................
iY:::YI::TZIZIYZI:7:71iI7YYZYZ:TZTI 71 :::::/ i ~ii]177ii :,,:,:,:1117 ii : ,,;:::i ~i i ......... i i,,
"D
~-~`~~!L~``!!!!!~!~!!!7~:!!!!!!!!!!~`~~~~::::::::~!::::!:!!-~!!>:~!`:::::!!:~`!~!!!!!>>1~!~:~!:!~!!~!
............................................ i- .................................................................... _. i_ .............. ~
!!!! ~ ::::::::::::::::::::::::
.....
. . . . . . . . . . . . . . . . . _ .........................
0 ....
~., H i
J
............ i . iiiiiiiiiiiiiiii
/
.... .....................................
J
. u
Cl.
(D /
li..
::3
tn . . . . . . j
.. . . _ .........................................
(D , , , / '" [
1i,..
. . . .
n
L__
0 /
/
GI
> ..</
. . . . . . . . . . . . / ....... i
L
i
i/ ..... ~ :
. . . . . . i/ ................................ /
/
:: ............. L. . . . . . . . . . . . . . . . . . . . . . . : ...... .............................
Z
! ....................
i ................... ! ............... i
/ l
i
0.01, I i I I i I I I I
-40 -20 0 2O 40 60 80 1 O0 120 140
Temperature, F
326
1 O0 ...................................................................................... . . . . . . ~, ,
10~-------
0.1~ i
. i
O3
O.01s i
, i
ffl
0.001 = i
i
n_ ==
L_ ..=
iI -
0 !
0.0001= i
>
i
,i,
1 E-05- =.
.....................................
.=
1 E-06=
f
=..
~
t
i
I
[-!
1 psia = 6.895 kPa
1 E-07= 1 psia = 51.71 m m Hg
..=
! ! .
t i .............................................. + ...........
E-08- i I i
2000 2500 3000 3500 4000 4500 5000 5500 6000 6500
Temperature, F
327
8;~;
-.! ' e J n l e J s d L u s /
008 OOL 009 00s 00~ 008 00~ O0 I. 0 O0 I.-
I_ LO0"O
6H LULU LZ" Ls = e!sd L I,
ed)l s = e!sd L
mi
If&IIIIiII
,,,,,,,,m~ i t - . . = = . - .
mvAIllmmmle
LO'O
!......... //
/
/
,,,
I
L'O
"1:3
...... ,/
0
/
"13
, .,/ , (I:)
-I. Or)
Or)
E:
0
/
i
/
/
'13
/ ,,m,~ e
....i.... L ~ ....../ .............
/ " ' -01.
.....
,, . . . . . . .
9 /
mm
,/
i
...
J ..,
jr ..... ,
11 :00 L
Z ..~.
3ClII:IO"IHOVI:I.I.31 IAInlGNVA ~IOA "
. . . .
I ~ ~ :,.,,.,,.,
mUU U I.
! i !
VOCI3 VANADIUM OXYTRICHLORIDE
.=.l
09
(D.
0.1
(1)
L._
:3
09
(~
t__
rl
t.._
0 0.01
(3.
>
0.001 L
i
{
?
!
- ~ ~ |
0.0001
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i !
1E-05 ! [ f t
-,so -,oo -so o so ,oo ,,o 2OO 25O 300
Temperature, F
329
............................... i ........
!
I I ....................
I W TUNGSTEN !
lo I I .......
f . . . . . . . . . . . _-___=__:_= . . . . . . . . . . - ....
- -~ , , --1 i
~ L ...... ;;--- =======================
F ' .... J..............117
J
F; ~ - -
~ ~,~, . . . . . . . . . . .
] J _ , .... - <,
: . . . . . . . . . . . .
/
I !
~
-
, .
' '~.....:: 17
. . .
'; ,,,,',L---'l
. . .
(/}
. . . . . . _-
. . . . . . . . . . . . . . .
13., -- / . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
-- ~ _
~ - ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ~ . . . . . . . .
0 /
0.0001
,,,~. ..
>
, , , / , , 9
-- / it" . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . .
1 E-05 _
. . . . . . .
.
. . . . . . . .
. #
;;,- . . . . . . . . . . . . ~ . . . . . . . . ~ ,,, , ...... ,. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
- / . . . . . . . . . . . . . . . . . . . . . . . . . . ,,
__- .... -/ / ..
,
J
1 E-06 ..... / _ - _
,,
/ . . . . .
1E-08 ~ i I i I
4000 5000 6000 7000 8000 9000 10000
Temperature, F
330
~
100:]
t [ ]
WF6 TUNGSTEN FLUORIDE
10-=.
.m ..= "i I
O3 ....
!
T
i
Q. ! t
i t!
..=
(1)
t__
i i
03
09 1- --i T
(1)
L_
I
!
1
tl =.,
t_..
O
Q. L ..........
03
>
i
t
i
I
i I
i i
! i
0.1-.................... ~ ~ --i
i I
....................... t
t i
| !
{ i
l
. . . . . . . . . . . . . .
331
1000
Xe XENON j/
/
/
/
. . . . . / L
. . . . . . . . . . . . .
.
t~
m
C~.
(D
:3
r~
o~ 1 O0
Q~ I
I
IL--
rl
/
I,..,
0
CL
>
tO
/
/
/
/
1 psia = 6.895 kPa
1 psia = 51.71 mm Hg
i
10
-200 -150 -1 O0 -50 50 1 O0
Temperature, F
332
1 O0 ......................................
Yb YTTERBIUM
10
1, i. ! - -
t t !
0.1 i.
-------I
f--------i
-------i--~-~--
O3 [ ] .
~. 0.01 i. :t
---~ ............................ |
...... r ............ i 84
u}
m 0.001
i..............................
i
(D
..................... 4=-'::::=',~:=.~:=--"=:-'--::=:~ ~ ....................
i ~____q
i
13_
0
Q- 0.0001 I
>
! I
i. ![ ..................................
1 E-05 L ..........! ..................... &
; ......... ! .........................
I I I I
J ..........................
I~......................
i..........................
l
1 E-06 L-. .................
9
~ ......................
..
i
:,
'
9
~ T r------
' i i 1 psia = 6.895 kPa
1 E-07: 1 psia = 51.71 mm Hg
--------t
- - F - - ~ ]
b"-'--------'-----F ............... ~
i J !
i i i
1E-08-1
! !
t l t ! ! T
6OO 800 1000 1200 1400 1600 1800 2000 2200 2400 2600
Temperature, F
333
ioo~ L
YTTRIUM I
10
m
1=
0.1_===
.=
.=
Q. 0.01- u
(D
L_
O3 0.001= ..
L_
13.
L_
0
Q. 0.0001=
> m
1 E-05-
1 E-06-
1 E_08i
1500 2000 2500 3000 3500 4000 4500 5000 5500
Temperature, F
334
lOOOOO~
[ i t
Zn ZINC r-----1
=i
03
(D i +
L_
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiill+l
!.......................................
i
L_
13..
t.._
0 t
El.
>
! t. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0.1
I_ ........ + _ . . . . . . . . ~ ...... i + ............. + .......................................................
i ...................................
i~ ...............
"!t i ..........................................
! !
0.01 'T
1 psia = 6.895 kPa IL------
1 psia = 51.71 mm Hg
!
']'
+ j
o.ool -I-
ii' I
!
50O 1000 1500 2000 2500 3000 3500 4000 4500 5000 5500
Temperature, F
335
100-: , i
I1
10-
J
9 j r
/
/
/
J
. m
co
(1)
u)
cO
(1)
13_
/
0
Q.
/
/
> ,//
0.1
/
il
/ J
/
, , . .
0.01 -
800 900 1000 11 O0 1200 1300 1400
Temperature, F
336
1 O0
F-
1 I i i ! 1.
ZnF2 ZINC FLUORIDE
.................... :-- .... t
10
+....................................
! !.
|
! 1
, 1
03
13.
t
i ....................................
i r i
(D i
V i i i
t._
t !
i i
03 i "
03
(D ............... ~ ........................~. . . . . . , . . . . . . . . . . . . . . k - ......................4
Ill
Q_
.....- - - - t = - ~ t -
t
=
.m__.~-i
.................
~ ~ i
i
................. -r.
i ...........
i
! . . . . . . . . . .
1
" i - - - - ~ - - ' t . . . . .
!._
' i i i i
0 i ..................i i [ .,
i / ! i i 9 i
! t iI
I i i
> ........................T. . . . . . , 4...................."...................T
i ,/ !
i
i
!
i
:
i
. t
I ' t ...................
, /i i i Ii ! i I I
, i ! i i
t i t
t I i' I i
I ' i t
0.1 i t ..................+................................
~..............................h..............................
-!..,
..................................... ~ ....................... ---:----i:. ....................... t-'-----------f . . . . . . 4..
. . . . . . . . . s ...... _.,__....~, . . . . . . :_ _. . . . . . . . . . . :~__ ........... :
' I 1............. -l', ....
! L ' :i".....................
!
.................................... i ...........................
!
t" . . . . . . !........
!
t - - - ~
i
L___ i , I -
i i
! !
i 1 psia = 6.895 kPa -~
1 psia = 51.71 mm Hg
/ ................................. =......................... :. = ~. . . . . . . .
' i i
'
|
1 i ! i
i
9
,
!
I ,'
i
0.01 I I I I I I I I
1700 1800 1900 2000 2100 2200 2300 2400 2500 2600 2700 2800
Temperature, F
337
8E~
..4 'a.Jn;eJaduJel
0098 00s 00178 0088 00~8 00 ~.C 0008 006~ OOBE 00/..~3
I I I !
I ' I.l." 0
J
, _j
, , 8HWW LZ'L~=~!sd L
" " 7 . . . . . . . . . . ~ -
!
~d~l ~68"9 = e!sd L I
r 7
t- .. , ,, .,~ : .....
/
, .
/
.... . . . . . . . . . . . . . . . . . . . . . . .
r T _
'r T -; .... : ,,, ,.'. . . . . '.
/r z , L
.i"
9 | / . . . . . ! .. 9
r 9 - ". . . . . . . i
; ....... .., / ! . n
/
It . . . . . . . . . . . . . . . . ........... 9 ........... r ,t . . . . . . . . . ; . . . . . ; 2. ; ........... m
a r
r'- ~ - .................... I- I ; ....... I ,, 4 / ! . . . . 1 ,, 9
[ ......... --- . . . . . . 9 - i
' '....... ; / / . . . . . . . . . . L
<
"0
0
'
~ i
f ''
-0
__~ .......... 9. . . . ; ..... _, (I)
C/)
C/)
9 ! ........... in
C~
.... x ........ n
i -- . . . . . . . . . . . . . -7
0
"0
9 ~ ,,, I c/)
m o
'r...............
r !iiiiiill i- iiiii ..... i : . . . . . _L
r ....... !
r I " ~ T
L. . . . . . .........i i~~ ,,ut-= ........... ; .n
: "OL
/
; ..... ; ...... : .... : ' 7 : ........ C
.............. ; .-: . . . . . . . . . . . . . . : . . ....... 9 ........... | ,
r , ~ "
J
r
............................................ ' .................
:v
[, ............. iiiiii
, i ...... ~ ............. I I
................. ::IGIXO ONIZ OUZ I
i '
.i . . . . . . . . . . . . . . . . . . . . . . . i
..... ' ......... I i ...... t ,4 ' lk_
'
............ ; r. . . . . . . . " i ' O 0
I00[ I
, ............ i i ....... '
'" I 9 " ..................................
I
i i
[ , I
10
- - . . . . . . . . . . ~ - - ...... - - - ~- - " i .... " ......................................... ; ................................. ~ . ~. . . i . . , . . .. . ~. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
.,.,m,
_: I I . v ., i
l,=,,
............... i................ ~ ....... i ........... i ..........
/ ..........I t.................. t '
13_
0
. / 1 !
>
j i .
' 1
.................................................. - ......... i --- ~ ---- -- - ........ : ............................................. 'i ~|
I.........................
,
' i
i 1 psia = 6.895 kPa
. . . . . . . . . . . . . . . 1 p s i a = 51.71 m m H g
i ; I t
! .
!'
!
i
!
J
t
0.1 1
60 80 1 O0 120 140 160 180 200 220 240
Temperature, F
339
O#E
-! ' e J n l e J e d L u e l
0008 OOSL O00l 0099999 0009 0099999999 0 0 0 9 00cj17 00017 0098 000~ ,
l
-80-3 L
/
/
tO-3 L
edM 9 6 9 ' 9 = e ! s d
t ~mw =90-3 I.
.m
=s L
f
/___
Z <
- LO00"O "0
ZE 0
.m
.L l "13
= 1.00"0 or)
m
ror)
(I)
- 1.0"0 "tJ
Or)
i . ,
-" I.'0
I
"r------frO I.
IhlnlNOOl=llZ J Z ~
i L . _ . m _ _ ~
i
!
.........."~-"
......~ i ~ 0 0 I.
1 O0
. . . . . . . . . . .................. I ..................................................................................................
. . . . . i ........... I ............ I.......................................... ii~i~i ........... i ........ i ....... i-ii--i ......... iiiii-it ............. i ................ iiiiii-i ............................ i
ZrBr4
i
E
10 84 i . f ........
i r.......................................................~ * | ............................
, ~_.L,C,
~F ..... _
r
u)
.u
F
El.
(D
09
u)
(D
L_
13..
L_
0
> / J !/ ................................................
T.............
21~i
........i~=~ii:i~',-,.i
........ i /.,, ,,,, [,ii ..... ..... . ,
0.1 . . . . il/ ,,
I
illlllllliillliiiiiilZ
_ ililll Z i. .................i ...................
i/211__ii.
0.01 I
400 450 500 550 600 650 700
Temperature, F
341
1 O0 . . . . . . . . . . .
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
0 .... tT /
.... J.
W.4B
.,, - , ~ ........... /
.
(0
m
09
CL
J
(D
U)
U)
G)
L _
/
a.
L__
O
CL
>
/
0.1 /
/
/ [ . . . .
....... / l
iiiii Z '~........
/ ...... 1 psia = 6 . 8 9 5 k P a
- .....
1 psia = 51.71 m m Hg
0.01
350 400 450 500 550 600 650
Temperature, F
342
1 o0 _
t
. . . .
/
Zrl4 ZIRCONIUM IODIDE
.......
0- ' '
,
I i i! __
_:::. . . . . . ::;___;___;__;____________i'.__'
.......
_ L- . . . . . . .,.i. . . . . . . . . .
!
I
................................................ / _ . . i i
u'l
, i
Q. ........................................ i
l..,.
t ,
O3
. . . . . . . . . !" ..................... 1! .......
.......
- - - - ! i - - t
ll.. ! l ! [ !
13_ ./ i ................................... 1. . . . . . . . . . . . . . . . . . . . . . . .
1
, _ . _ ~ i
/ i
! i
I..,,
0
Q. i
> i, // ' ! I
/
/ ......................................... : . . . . . . . . ~,, 4
1 l, '!
0.1 ........ .,, !
....
/ ! i
' ~ / '
- /
-- . 4 . . . . : :i
-- " i "'
/
/
.. i
i
--i ....
t
iI !
I i!
I i i
0.01 i I I I
500 550 600 650 700 750 8O0 850
Temperature, F
343
REFERENCES
344
25. Yaws, C. L. and others, Solid State Technology, 17, No. 11, 31 (1974).
26. Yaws, C. L. and others, Solid State Technology, 18, No. 1, 35 (1975).
27. Yaws, C. L. and others, Solid State Technology, 21, No. 1, 43 (1978).
28. Yaws, C. L. and others, Solid State Technology, 24, No. 1, 87 (1981).
29. Yaws, C. L. and others, J. Ch. I. Ch. E., 12, 33 (1981).
30. Yaws, C. L. and others, J. Ch. I. Ch.E., 14, 205 (1983).
31. Yaws, C. L. and others, Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984).
32. Yaws, C. L., pHySICAL PROPERTIES, McGraw-Hill, New York, NY (1977).
33. Yaws, C. L., THERMODYNAMIC AND PHYSICAL PROPERTY DATA, Gulf Publishing Co.,
Houston, TX (1992).
34. Yaws, C. L. and R. W. Gallant, pHYSICAL PROPERTIES OF HYDROCARBONS, Vols. 1 (2nd ed.),
Vol 2, (3rd ed.) and Vol 3 (lst ed.), Gulf Publishing Co., Houston, TX (1992, 1993, 1993).
345
Appendix A
346
HgBr2 MERCURIC BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 139 PC[3 PHOSPHORUS TRICHLORIDE. . . . . . . . . . . . . . . . . . 215
HgC[2 MERCURIC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 140 PC[5 PHOSPHORUS PENTACHLORIDE . . . . . . . . . . . . . . . . 216
HgI2 MERCURIC IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 141 PH3 PHOSPHINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
IF7 IODINE HEPTAFLUORIDE . . . . . . . . . . . . . . . . . . . . 142 PH4Br PHOSPHONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . 218
12 IODINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143 PH4C[ PHOSPHONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . 219
In INDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 PH4I PHOSPHONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . 220
Ir IRIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145 POCt3 PHOSPHORUS OXYCHLORIDE. . . . . . . . . . . . . . . . . . 221
K POTASSIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146 PSBr3 PHOSPHORUS THIOBROMIDE. . . . . . . . . . . . . . . . . . 222
KBr POTASSIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 147 PSC[3 PHOSPHORUS THIOCHLORIDE. . . . . . . . . . . . . . . . . 223
KCI POTASSIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 148 P406 PHOSPHORUS TRIOXIDE. . . . . . . . . . . . . . . . . . . . . 224
KF POTASSIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . 149 P4010 PHOSPHORUS PENTOXIDE. . . . . . . . . . . . . . . . . . . . 225
KI POTASSIUM IODIDE . . . . . . . . . . . . . . . . . . . . . . . . 150 P4SIO PHOSPHORUS PENTASULFIDE . . . . . . . . . . . . . . . . . 226
KOH POTASSIUM HYDROXIDE. . . . . . . . . . . . . . . . . . . . . 151 Pb LEAD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227
Kr KRYPTON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 PbBr2 LEAD BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 228
La LANTHANUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 PbC[2 LEAD CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 229
Li LITHIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 154 PbF2 LEAD FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 230
LiBr LITHIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . 155 PbI2 LEAD IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231
LiCl LITHIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . 156 PbO LEAD OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232
LiF LITHIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 157 PbS LEAD SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233
LII LITHIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 158 Pcl PALLADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234
Lu LUTETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 Po POLONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
Mg MAGNESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 Pt PLATINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
MgCI2 MAGNESIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 161 Ra RADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
MgO MAGNESIUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 162 Rb RUBIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
Mn MANGANESE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 RbBr RUBIDIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 239
MnCt 2 MANGANESE CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 164 RbC[ RUBIDIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 240
Mo MOLYBDENUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 RbF RUBIDIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 241
MoF6 MOLYBDENUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . 166 Rbl RUBIDIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 242
MoO3 MOLYBDENUM OXIDE. . . . . . . . . . . . . . . . . . . . . . . . 167 Re RHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
NC[3 NITROGEN TRICHLORIDE. . . . . . . . . . . . . . . . . . . . 168 Re207 RHENIUM HEPTOXIDE. . . . . . . . . . . . . . . . . . . . . . . 244
ND3 HEAVY AMMONIA. . . . . . . . . . . . . . . . . . . . . . . . . . . 169 Rh RHODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245
NF3 NITROGEN TRIFLUORIDE. . . . . . . . . . . . . . . . . . . . 170 Rn RADON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
NH3 AMMONIA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171 Ru RUTHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247
NH30 HYDROXYLAMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . 172 RuF5 RUTHENIUM PENTAFLUORIDE . . . . . . . . . . . . . . . . . 248
NH4Br AMMONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . 173 S SULFUR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249
NH4C[ AMMONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 174 SF4 SULFUR TETRAFLUORIDE. . . . . . . . . . . . . . . . . . . . 250
NH41 AMMONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . . 175 SF6 SULFUR HEXAFLUORIDE. . . . . . . . . . . . . . . . . . . . . 251
NH50 AMMONIUM HYDROXIDE. . . . . . . . . . . . . . . . . . . . . . 176 SOBr2 THIONYL BROMIDE. . . . . . . . . . . . . . . . . . . . . . . . . 252
NHSS AMMONIUM HYDROGENSULFIDE . . . . . . . . . . . . . . . . 177 SOCt2 THIONYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . 253
NO NITRIC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 SOF2 SULFUROUS OXYFLUORIDE. . . . . . . . . . . . . . . . . . . 254
NOCt NITROSYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 179 SO2 SULFUR DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . 255
NOF NITROSYL FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 180 S02C[2 SULFURYL CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . 256
NO2 NITROGEN DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . 181 SO3 SULFUR TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . . 257
N2 NITROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 $2CL2 SULFUR MONOCHLORIDE . . . . . . . . . . . . . . . . . . . . . 258
N2F4 TETRAFLUOROHYDRAZINE . . . . . . . . . . . . . . . . . . . . 183 Sb ANTIMONY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 259
N2H4 HYDRAZINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184 SbBr3 ANTIMONY TRIBROMIDE. . . . . . . . . . . . . . . . . . . . . 260
N2H4C AMMONIUM CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . 185 SbC[3 ANTIMONY TRICHLORIDE. . . . . . . . . . . . . . . . . . . . 261
N2H6C02 AMMONIUM CARBAMATE. . . . . . . . . . . . . . . . . . . . . . 186 SbCt5 ANTIMONY PENTACHLORIDE . . . . . . . . . . . . . . . . . . 262
N20 NITROUS OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 SbH3 STIBINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263
N203 NITROGEN TRIOXIDE . . . . . . . . . . . . . . . . . . . . . . . 188 SbI3 ANTIMONY TRIIODIDE . . . . . . . . . . . . . . . . . . . . . . 264
N204 NITROGEN TETRAOXIDE . . . . . . . . . . . . . . . . . . . . . 189 Sb203 ANTIMONY TRIOXIDE. . . . . . . . . . . . . . . . . . . . . . . 265
N205 NITROGEN PENTOXIDE. . . . . . . . . . . . . . . . . . . . . . 190 Sc SCANDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
Na SODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191 Se SELENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
NaBr S O D I U M BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 192 SeCt4 SELENIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 268
NaCN S O D I U M CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 193 SeF6 SELENIUM HEXAFLUORIDE. . . . . . . . . . . . . . . . . . . 269
NaCL SODIUM CHLORIDE ......................... 194 SeOC [ 2 SELENIUM OXYCHLORIDE. . . . . . . . . . . . . . . . . . . . 270
NaF S O D I U M FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 195 Se02 SELENIUM DIOXIDE. . . . . . . . . . . . . . . . . . . . . . . . 271
Nal S O D I U M IODIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 196 Si SILICON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 272
NaOH SODIUM HYDROXIDE ........................ 197 SIBrCt2F BROMODICHLOROFLUOROSILANE . . . . . . . . . . . . . . . 273
Na2S04 S O D I U M SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . 198 SiBrF3 TRIFLUOROBROMOSILANE . . . . . . . . . . . . . . . . . . . . 274
Nb NIOBIUM ................................. 199 SiBr2CLF DIBROMOCHLOROFLUOROSILANE . . . . . . . . . . . . . . . 275
Nd NEODYMIUM ............................... 200 SiCtF3 TRIFLUOROCHLOROSILANE . . . . . . . . . . . . . . . . . . . 276
Ne NEON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 SiCt2F2 DICHLORODIFLUOROSILANE . . . . . . . . . . . . . . . . . . 277
Ni NICKEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 SiCt3F TRICHLOROFLUOROSILANE . . . . . . . . . . . . . . . . . . . 278
N iC404 NICKEL C A R B O N Y L . . . . . . . . . . . . . . . . . . . . . . . . . 203 SiCt4 SILICON TETRACHLORIDE. . . . . . . . . . . . . . . . . . . 279
NiF2 NICKEL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 204 SiF4 SILICON TETRAFLUORIDE. . . . . . . . . . . . . . . . . . . 280
Np NEPTUNIUM ............................... 205 SIHBr3 TRIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 281
02 OXYGEN .................................. 206 SiHCt3 TRICHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 282
03 OZONE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 SIHF3 TRIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 283
Os OSMIUM .................................. 208 SIH2Br2 DIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . 284
OsOF5 O S M I U M OXIDE P E N T A F L U O R I D E .............. 209 SIH2C[2 DICHLOROSILANE . . . . . . . . . . . . . . . . . . ........ 285
Os04 O S M I U M T E T R O X I D E - Y E L L O W ............... 210 SIH2F2 DIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 286
Os04 OSMIUM TETROXIDE WHITE ................
- 211 SiH212 DIIODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 287
P P H O S P H O R U S - WHITE . . . . . . . . . . . . . . . . . . . . . . 212 SiH3Br MONOBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 288
PBr3 PHOSPHORUS TRIBROMIDE ................... 213 S i H3C t MONOCHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 289
PCt2F3 P H O S P H O R U S D I C H L O R I D E T R I F L U O R I D E ....... 214 SIH3F MONOFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 290
347
SiH31 IODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291
SiH4 SILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
Si02 SILICON DIOXIDE ......................... 293
Si2Ct6 HEXACHLORODISILANE . . . . . . . . . . . . . . . . . . . . . . 294
Si2F6 HEXAFLUORODISILANE . . . . . . . . . . . . . . . . . . . . . . 295
Si2H5Cl D I S I L A N Y L CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 296
Si2H6 DISILANE ................................ 297
Si2OCl3F3 TRICHLOROTRIFLUORODISILOXANE . . . . . . . . . . . . 298
Si20Cl6 HEXACHLORODISILOXANE . . . . . . . . . . . . . . . . . . . . 299
S i20H6 DISILOXANE .............................. 300
Si3Cl8 OCTACHLOROTRISILANE . . . . . . . . . . . . . . . . . . . . . 301
Si3H8 TRISILANE ............................... 302
Si3H9N TRISILAZANE ............................. 303
Si4H10 TETRASILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304
Sm SAMARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
Sn TIN ..................................... 306
SnBr4 STANNIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 307
SnCl2 STANNOUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 308
SnCt4 STANNIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 309
SnH4 STANNIC HYDRIDE . . . . . . . . . . . . . . . . . . . . . . . . . 310
SnI4 STANNIC I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . . 311
Sr STRONTIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312
SrO STRONTIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 313
Ta TANTALUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314
Tc TECHNETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
Te TELLURIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 316
TeC[4 TELLURIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 317
TeF6 TELLURIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . 318
Ti TITANIUM ................................ 319
TiC[4 T I T A N I U M TETRACHLORIDE . . . . . . . . . . . . . . . . . . 320
T[ THALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
TIBr THALLOUS BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 322
Tll THALLOUS I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 323
Tm THULIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324
U URANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
UF6 URANIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 326
V VANADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
VCt4 VANADIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 328
VOCt3 VANADIUM OXYTRICHLORIDE. . . . . . . . . . . . . . . . . 329
W TUNGSTEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
WF6 TUNGSTEN FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 331
Xe XENON. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 332
Yb YTTERBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333
Yt YTTRIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334
Zn ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
ZnCt2 ZINC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 336
ZnF2 ZINC FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 337
ZnO ZINC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338
ZnS04 ZINC SULFATE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 339
Zr ZIRCONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340
ZrBr4 ZIRCONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 341
ZrC[4 ZIRCONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 342
ZrI4 ZIRCONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . 343
348
Appendix B
349
HYDROGEN CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 122 PERCHLORYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . 74
HYDROGEN CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . 121 PHOSGENE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 50
HYDROGEN D I S U L F I D E . . . . . . . . . . . . . . . . . . . . . . 131 PHOSPHINE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 217
HYDROGEN FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 123 PHOSPHONIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . 218
HYDROGEN I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 124 PHOSPHONIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . 219
HYDROGEN PEROXIDE . . . . . . . . . . . . . . . . . . . . . . . 128 PHOSPHONIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . 220
HYDROGEN SELENIDE . . . . . . . . . . . . . . . . . . . . . . . 132 PHOSPHORUS - WHITE . . . . . . . . . . . . . . . . . . . . . . 212
HYDROGEN SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . 129 PHOSPHORUS DICHLORIDE T R IF L U O R ID E . . . . . . . 214
HYDROGEN TELLURIDE . . . . . . . . . . . . . . . . . . . . . . 133 PHOSPHORUS OXYCHLORIDE . . . . . . . . . . . . . . . . . . 221
HYDROXYLAMINE . . . . . . . . . . . . . . . . . . . . . . . . . . . 172 PHOSPHORUS PENTACHLORIDE . . . . . . . . . . . . . . . . 216
INDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144 PHOSPHORUS PENTASULFIDE . . . . . . . . . . . . . . . . . 226
IODINE .................................. 143 PHOSPHORUS PENTOXIDE . . . . . . . . . . . . . . . . . . . . 225
I O D I N E HEPTAFLUORIDE . . . . . . . . . . . . . . . . . . . . 142 PHOSPHORUS THIOBROMIDE . . . . . . . . . . . . . . . . . . 222
IODOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 291 PHOSPHORUS THIOCHLORIDE . . . . . . . . . . . . . . . . . 223
IRIDIUM ................................. 145 PHOSPHORUS TRIBRONIDE . . . . . . . . . . . . . . . . . . . 213
IRON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 PHOSPHORUS TRICHLORIDE . . . . . . . . . . . . . . . . . . 215
IRON PENTACARBONYL . . . . . . . . . . . . . . . . . . . . . . 106 PHOSPHORUS T R I O X I D E . . . . . . . . . . . . . . . . . . . . . 224
KRYPTON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 152 PLATINUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 236
LANTHANUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153 POLONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 235
LEAD . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 227 POTASSIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 146
LEAD BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 228 POTASSIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . 147
LEAD CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 POTASSIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 148
LEAD FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 230 POTASSIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . 149
LEAD I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 231 POTASSIUM HYDROXIDE . . . . . . . . . . . . . . . . . . . . . 151
LEAD OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 232 POTASSIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . 150
LEAD SULFIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 233 RADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 237
LITHIUM ................................. 154 RADON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 246
L I T H I U M BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 155 RHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 243
L I T H I U M CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 156 RHENIUM HEPTOXIDE . . . . . . . . . . . . . . . . . . . . . . . 244
L I T H I U M FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . 157 RHODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 245
LITHIUM IODIDE .......................... 158 RUBIDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238
LUTETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 159 RUBIDIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 239
MAGNESIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160 RUBIDIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 240
MAGNESIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 161 RUBIDIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 241
MAGNESIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 162 RUBIDIUM I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 242
MANGANESE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163 RUTHENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 247
MANGANESE CHLORIDE . . . . . . . . . . . . . . . . . . . . . . 164 RUTHENIUM PENTAFLUORIDE . . . . . . . . . . . . . . . . . 248
MERCURIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 139 SAMARIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 305
MERCURIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 140 SCANDIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 266
MERCURIC I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 141 SELENIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 267
MERCURY . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138 SELENIUM D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . 271
MOLYBDENUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165 SELENIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . . 269
MOLYBDENUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . 166 SELENIUM OXYCHLORIDE . . . . . . . . . . . . . . . . . . . . 270
MOLYBDENUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . 167 SELENIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . . 268
MONOBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 288 SILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 292
MONOCHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 289 SILICON ................................. 272
NONOFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . 290 SILICON DIOXIDE ......................... 293
NEODYMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200 S I L I C O N TETRACHLORIDE . . . . . . . . . . . . . . . . . . . 279
NEON . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 201 S I L I C O N TETRAFLUORIDE . . . . . . . . . . . . . . . . . . . 280
NEPTUNIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205 SILVER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
NICKEL . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 202 SILVER CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 2
NICKEL CARBONYL . . . . . . . . . . . . . . . . . . . . . . . . . 203 SILVER IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
NICKEL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 204 SODIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
NIOBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199 SODIUM BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 192
N I T R I C ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 SODIUM CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 194
N I T R I C OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . . 178 SODIUM CYANIDE . . . . . . . . . . . . . . . . . . . . . . . . . . 193
NITROGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 182 SODIUM FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . . . 195
NITROGEN D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . 181 SODIUM HYDROXIDE . . . . . . . . . . . . . . . . . . . . . . . . 197
NITROGEN PENTOXIDE . . . . . . . . . . . . . . . . . . . . . . 190 SODIUM IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . . 196
NITROGEN TETRAOXIDE . . . . . . . . . . . . . . . . . . . . . 189 SODIUM SULFATE . . . . . . . . . . . . . . . . . . . . . . . . . . 198
NITROGEN TRICHLORIDE . . . . . . . . . . . . . . . . . . . . 168 STANNIC BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 307
NITROGEN T R I F L U O R I D E . . . . . . . . . . . . . . . . . . . . 170 STANNIC CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 309
NITROGEN T R I O X I D E . . . . . . . . . . . . . . . . . . . . . . . 188 STANNIC HYDRIDE . . . . . . . . . . . . . . . . . . . . . . . . . 310
NITROSYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 179 STANNIC IO D ID E . . . . . . . . . . . . . . . . . . . . . . . . . . 311
NITROSYL FLUORIDE . . . . . . . . . . . . . . . . . . . . . . . 180 STANNOUS CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 308
NITROUS OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . . . 187 STIBINE ................................. 263
OCTACHLOROTRISILANE . . . . . . . . . . . . . . . . . . . . . 301 STRONTIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 312
OSMIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208 STRONTIUM OXIDE . . . . . . . . . . . . . . . . . . . . . . . . . 313
OSMIUM OXIDE PENTAFLUORIDE . . . . . . . . . . . . . . 209 SULFAMIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
OSMIUM TETROXIDE - WHITE . . . . . . . . . . . . . . . . 211 SULFUR . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249
OSMIUM TETROXIDE - YELLOW . . . . . . . . . . . . . . . 210 SULFUR D I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . . . 255
OXYGEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 206 SULFUR HEXAFLUORIDE . . . . . . . . . . . . . . . . . . . . . 251
OZONE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207 SULFUR MONOCHLORIDE . . . . . . . . . . . . . . . . . . . . . 258
PALLADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 234 SULFUR TETRAFLUORIDE . . . . . . . . . . . . . . . . . . . . 250
PENTABoRANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 SULFUR T R I O X I D E . . . . . . . . . . . . . . . . . . . . . . . . . 257
PERCHLORIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . 78 SULFURIC ACID . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
350
SULFUROUS OXYFLUORIDE . . . . . . . . . . . . . . . . . . . 254
SULFURYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . 256
TANTALUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 314
TECHNETIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 315
TELLURIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 316
TELLURIUM HEXAFLUORIDE . . . . . . . . . . . . . . . . . . 318
TELLURIUM TETRACHLORIDE . . . . . . . . . . . . . . . . . 317
TETRABORANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
TETRAFLUOROHYDRAZINE . . . . . . . . . . . . . . . . . . . . 183
TETRAHYDROPENTABORANE . . . . . . . . . . . . . . . . . . . 35
TETRASILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 304
THALLIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 321
THALLOUS BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . 322
THALLOUS I O D I D E . . . . . . . . . . . . . . . . . . . . . . . . . 323
THIONYL BROMIDE . . . . . . . . . . . . . . . . . . . . . . . . . 252
THIONYL CHLORIDE . . . . . . . . . . . . . . . . . . . . . . . . 253
THIOUREA . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
THULIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 324
TIN ..................................... 306
TITANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 319
TITANIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 320
TRIBROMOSILANE . . . . . . . . . . . . . . . . . . . . . . . . . . 281
TRICHLORO GERMANE. . . . . . . . . . . . . . . . . . . . . . . 116
TRICHLOROFLUOROSILANE . . . . . . . . . . . . . . . . . . . 278
TRICHLOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 282
TRICHLOROTRIFLUORODISILOXANE . . . . . . . . . . . . 298
TRIFLUOROBROMOSILANE . . . . . . . . . . . . . . . . . . . . 274
TRIFLUOROCHLOROSILANE . . . . . . . . . . . . . . . . . . . 276
TRIFLUOROSILANE . . . . . . . . . . . . . . . . . . . . . . . . . 283
TRIGERMANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
TRISILANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 302
TRISILAZANE . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303
TUNGSTEN . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 330
TUNGSTEN FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . 331
URANIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 325
URANIUM FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . 326
UREA. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 52
VANADIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 327
VANADIUM OXYTRICHLORIDE. . . . . . . . . . . . . . . . . 329
VANADIUM TETRACHLORIDE. . . . . . . . . . . . . . . . . . 328
WATER . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 127
XENON. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 332
YTTERBIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 333
YTTRIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 334
ZINC . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 335
ZINC CHLORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 336
ZINC FLUORIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . 337
ZINC OXIDE. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 338
ZINC SULFATE. . . . . . . . . . . . . . . . . . . . . . . . . . . . 339
ZIRCONIUM . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 340
ZIRCONIUM BROMIDE. . . . . . . . . . . . . . . . . . . . . . . 341
ZIRCONIUM CHLORIDE. . . . . . . . . . . . . . . . . . . . . . 342
ZIRCONIUM IODIDE. . . . . . . . . . . . . . . . . . . . . . . . 343
351
Appendix C
352
t oglo P = A + B / T + C t oglo T + D T + E T 2 (P - mm Hg, T - K)
* A computer program, containing c o e f f i c i e n t s f o r vapor pressure f o r a t [ compounds 9is a v a i t a b t e f o r a nominal fee (Cart L.
Yaws, Box 10053, Lamar U n i v e r s i t y , Beaumont, TX 77710 9phone/FAX 409-880-8787). The computer program is in ASCII which can be
accessed by other software.
353
tog,o P = A + B/T + C loglo T + D T + E T2 (P - nan Hg, T - K)
122 HCL HYDROGEN CHLORIDE 43.5455 -I .6279E+03 -1.5214E+01 1.3783E-02 -1.4984E-11 158.97 324.65
123 HF HYDROGEN FLUORIDE 23.7347 -I. 7996E+03 -6.1764E+00 -5.0046E-10 6.1500E-06 189.79 461.15
124 HI HYDROGEN IODIDE 21.4282 -1.4515E+03 -5.5756E+00 3.3878E-03 -8.9335E-12 222.38 423.85
125 HN03 NITRIC ACID 71.7653 -4.3768E+03 -2.2769E+01 -4.5988E-07 1.1856E-05 231.55 376.10
126 H2 HYDROGEN 3.4132 -4.1316E+01 1.0947E+00 -6.6896E-10 1.4589E-04 13.95 33.18
127 H20 WATER 29.8605 -3.1522E+03 -7.3037E+00 2.4247E-09 1.8090E-06 273.16 647.13
128 H 2 0 2 HYDROGENPEROXIDE 33.3222 -3.7350E+03 -8.3458E+00 -1.2351E-10 1.6917E-06 272.74 730.15
129 H2S HYDROGEN SULFIDE 18.6383 -1.3446E+03 -4.1034E+00 3.1815E-09 2.4664E-06 187.68 373.53
130 H2S04 SULFURICACID 2.0582 -4.1924E+03 3.2578E+00 -1.1224E-03 5.5371E-07 283.15 603.15
131 H 2 S 2 HYDROGENDISULFIDE 22.3747 -2.4043E+03 -5.5539E+00 5.8402E-03 -2.6241E-06 229.95 337.15
132 H 2 S e HYDROGENSELENIDE 573.9933 -I.0568E+04 -2.6071E+02 4.7258E-01 -3.4316E-04 157.85 232.05
133 H 2 T e HYDROGENTELLURIDE 532.0079 -I.0876E+04 -2.3540E+02 3.7306E-01 -2.3649E-04 176.75 271.15
134 H3N03S SULFAMICACID 0.1130 -6.8449E+02 5.2613E-05 -6.8934E-08 3.4587E-11 293.15 373.15
135 He HELIUM-3 2.1239 -1.1769E+00 2.0493E+00 -1.7652E-10 9.4980E-03 1.01 3.31
136 He HELIUM-4 2.8838 -3.9043E+00 6.7240E-01 1.1913E-01 -2.1010E-11 1.76 5.20
137 Hf HAFNIUM -187.3128 -4.7256E+03 5.9397E+01 -7.1673E-03 2.6648E-07 2117.00 5960.00
138 Hg MERCURY 11.3169 -3.3515E+03 -1.1296E+00 -2.9698E-13 1.1699E-07 234.31 1735.00
139 HgBr2 MERCURIC BROMIDE -6001.9471 1.6586E+05 2.4352E+03 -2.1646E+00 7.2767E-04 409.65 592.15
140 HgCL2 MERCURIC CHLORIDE 8091.0938 -2.3113E+05 -3.2811E+03 2.9716E+00 -1.0294E-03 409.35 577.15
141HgI2 MERCURIC IODIDE -9817.2743 2.9088E+05 3.9308E+03 -3.2560E+00 1.0229E-03 430.65 627.15
142 IF7 IODINE HEPTAFLUORIDE 2.2894 -1.4949E+03 2.7875E+00 -3.5044E-03 1.9005E-06 186.15 277.15
143 12 IODINE 46.9335 -5.1763E+03 -1.1170E+01 -1.0130E-02 7.7500E-06 242.00 819.15
144 In INDIUM 112.3721 -1.8894E+04 -3.5777E+01 1.1333E-02 -1.3444E-06 850.00 2323.00
145 Ir IRIDIUM "197.4829 -6.5755E+03 6.4387E+01 -9.6603E-03 5.0122E-07 1944.00 4450.00
146 K POTASSIUM 10.8410 -4.6934E+03 -1.1916E+00 1.5875E-04 1.7454E-17 336.35 2223.00
147 KBr POTASSIUM BROMIDE 86.7862 -1.5677E+04 -2.5680E+01 5.9097E-03 -5.6987E-07 1068.15 1656.15
148 KCt POTASSIUM CHLORIDE -8.0224 -9.3722E+03 6.4641E+00 -3.1639E-03 3.2745E-07 1044.00 3470.00
149 KF POTASSIUM FLUORIDE 86.1553 -1.7030E+04 -2.5138E+01 5.3564E-03 -4.7879E-07 1158.15 1775.15
150 KI POTASSIUM IODIDE 88.6708 -1.5026E+04 -2.6513E+01 6.3780E-03 -6.4206E-07 1018.15 1597.15
151KOH POTASSIUM HYDROXIDE 20.9787 -9.5262E+03 -3.8001E+00 -2.9030E-10 1.2312E-08 679.00 1600.00
152 Kr KRYPTON -12.6883 -3.1111E+02 1.0610E+01 -3.8518E-02 5.0870E-05 115.78 209.35
153 La LANTHANUM 190.2107 -4.1131E+04 -5.7186E+01 9.9276E-03 -6.4353E-07 1441.50 3643.00
154 Li LITHIUM 12.1182 -8.4301E+03 -1.3510E+00 2.2909E-04 -6.2641E-18 453.69 4085.00
155 LiBr L I T H I U MBROMIDE 65.3934 -1.3245E+04 -1.8782E+01 4.4647E-03 -4.4694E-07 1021.15 1583.15
156 LiCL L I T H I U MCHLORIDE 1659.2051 -1.1514E+05 -5.7029E+02 1.9064E-01 -2.4324E-05 1056.15 1655.15
157 LiF LITHIUM FLUORIDE 69.3367 -1.8147E+04 -1.9178E+01 3.6011E-03 -2.8544E-07 1320.15 1954.15
158 L i l LITHIUM IODIDE 72.2997 -1.4450E+04 -2.0834E+01 5.2464E-03 -5.5773E-07 996.15 1444.15
159 Lu LUTETIUM -47.6746 -1.1929E+04 1.8989E+01 -4.5961E-03 3.5367E-07 1057.00 2535.00
160 Mg MAGNESIUM -72.6513 -4.2014E+03 3.0264E+01 -1.5558E-02 2.6429E-06 517.00 1376.00
161MgCL2 MAGNESIUMCHLORIDE 1239.2680 -9.0236E+04 -4.2304E+02 1.3654E-01 -1.6884E-05 1051.15 1691.15
162 MgO MAGNESIUMOXIDE -41.2727 -1.4025E+04 1.5392E+01 -2.3614E-03 1.1265E-07 3105.00 5950.00
163 Mn MANGANESE "123.9176 -5.9845E+03 4.6074E+01 -1.4659E-02 1.5195E-06 924.00 2392.00
164 MnCl2 MANGANESE CHLORIDE 1275.0362 -8.8381E+04 -4.3842E+02 1.4858E-01 -1.9347E-05 1009.15 1463.15
165 Mo MOLYBDENUM 74.9735 -4.1955E+04 -2.0072E+01 3.2166E-03 -2.2507E-07 1677.00 5100.00
166 MoF6 MOLYBDENUM FLUORIDE 300.7229 -7.9655E+03 -1.2644E+02 1.6582E-01 -8.8423E-05 207.65 309.15
167 MoO3 MOLYBDENUM OXIDE 3015.8551 -2.1859E+05 -1.0259E+03 3.1920E-01 -3.8938E-05 1007.15 1424.15
168 N C L 3 NITROGENTRXCHLORIDE 88.8600 -4.2008E+03 -3.1565E+01 1.8305E-02 -6.0409E-11 246.15 367.15
169 ND3 HEAVY AMMONIA 125.5395 -3.5614E+03 -5.1766E+01 7.4954E-02 -4.4958E-05 199.15 239.75
170 NF3 NITROGEN TRXFLUORIDE 8.4514 -7.4300E+02 3.9105E-01 -1.1295E-02 1.7758E-05 66.36 233.85
171NH3 AMMONIA 37.1575 -2.0277E+03 -1.1601E+01 7.4625E-03 -9.5811E-12 195.41 405.65
172 NH30 HYDROXYLAMINE 2.4590 -4.0142E+03 6.3297E+00 -1.8547E-02 1.1266E-05 306.25 383.00
173 NH4Br AMMONIUM BROMIDE 23.7261 -5.2014E+03 -5.1721E+00 2.6919E-03 -5.9955E-07 471.45 669.15
174 NH4CL AMMONIUM CHLORIDE -893.5430 1.9484E+04 3.6716E+02 -3.2056E-01 1.0034E-04 553.15 793.15
175 N H 4 1 AMMONIUM IODIDE 0.4097 -4.4032E+03 3.5216E+00 -1.7562E-03 3.7842E-07 484.05 678.05
176 NH50 AMMONIUM HYDROXIDE 42.3381 -2.3577E+03 -1.3597E+01 8.5486E-03 4.7298E-11 203.15 353.15
177 N H 5 S AMMONIUMHYDROGENSULFIDE 178.9587 -6.0657E+03 -7.2004E+01 8.7809E-02 -4.4365E-05 222.05 306.45
178 NO NITRIC OXIDE 61.2046 -1.5365E+03 -2.3621E+01 2.9377E-02 -1.3066E-09 109.50 180.15
179 NOCL NITROSYLCHLORIDE 24.1469 -1.8469E+03 -6.0513E+00 9.2881E-09 4.5319E-06 213.55 440.65
180 NOF NITROSYLFLUORIDE 478.8331 -7.7441E+03 -2.2562E+02 4.9213E-01 -4.2279E-04 141.15 217.15
181 NO2 NITROGENDIOXIDE 32.1203 -2.2563E+03 -9.7702E+00 8.6560E-03 -5.1036E-11 261.95 431.35
182 N2 NITROGEN 23.8572 -4.7668E+02 -8.6689E+00 2.0128E-02 -2.4139E-11 63.15 126.10
183 N 2 F 4 TETRAFLUOROHYDRAZINE 16.4473 -9.6387E+02 -4.3123E+00 5.9876E-03 2.2680E-13 111.65 309.35
184 N 2 H 4 HYDRAZINE 31.2541 -3.1466E+03 -8.2200E+00 2.6734E-03 4.6004E-13 274.68 653.15
185 N2H4C AMMONIUMCYANIDE 179.6608 -6.1294E+03 -7.2215E+01 8.8090E-02 -4.4545E-05 222.55 304.85
186 N2H6C02 AMMONIUMCARBAMATE 93.9638 -4.8160E+03 -3.4502E+01 3.6858E-02 -1.6578E-05 247.05 331.45
187 N20 NITROUS OXIDE 61.5168 -2.1016E+03 -2.2337E+01 1.8232E-02 -1.1348E-10 182.30 309.57
354
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
log,o P = A + B / T + C t o g , o T + D T + E T 2 (P - mm Hg, T - K)
355
l og,o P = A + B / T + C l Og,o T + D T + E T 2 (P - mm Hg, T - K)
254 SOF2 SULFUROUS OXYFLUORIDE 238.2631 -5.2181E+03 -I.0431E+02 1.7358E-01 -1.1781E-04 174.42 229.05
255 SO2 SULFUR DIOXIDE 19.7418 -1.8132E+03 -4.1458E+00 -4.4284E-09 8.4918E-07 197.67 430.75
256 S02C[2 SULFURYL CHLORIDE 5.9028 -2.0407E+03 2.2796E+00 -I.0358E-02 6.0161E-06 222.00 545.00
257 S03 SULFUR TRIOXIDE 114.0529 -6.4619E+03 -3.6784E+01 -1.7530E-07 1.1919E-05 289.95 490.85
258 S2CI2 SULFUR MONOCHLORIDE 162.6274 -6.2944E+03 -6.3327E+01 6.1401E-02 -2.4506E-05 265.75 411.15
259 Sb ANTIMONY -14.9322 -1.3754E+04 1.5738E+01 -2.3835E-02 5.1947E-06 617.00 1898.00
260 SbBr3 ANTIMONY TRIBROMIDE -68.4797 -6.2413E+02 3.0034E+01 -2.0378E-02 4.6884E-06 367.05 548.15
261SbCl3 ANTIMONY TRICHLORIDE 68.0484 -5.1047E+03 -2.1724E+01 7.4742E-03 5.7270E-13 346.55 794.00
262 SbCl5 ANTIMONY PENTACHLORIDE 73.6650 -4.3530E+03 -2.6389E+01 2.3832E-02 -9.0652E-06 295.85 387.25
263 SbH3 STIBINE 65.7241 -2.2895E+03 -2.5586E+01 3.4766E-02 -1.7809E-05 177.87 440.35
264 SbI3 ANTIMONY TRIIODIDE -1834.2309 5.3081E+04 7.3328E+02 -5.9001E-01 1.8014E-04 436.75 674.15
265 Sb203 ANTIMONY TRIOXIDE 3557.6905 -2.2934E+05 -1.2298E+03 4.1528E-01 -5.3009E-05 847.15 1698.15
266 Sc SCANDIUM -410.3222 1.5184E+04 1.4020E+02 -3.6544E-02 3.4523E-06 1110.00 2700.00
267 Se SELENIUM 994.5705 -4.3994E+04 -3.7357E+02 2.2452E-01 -5.1145E-05 397.00 930.00
268 SeCt4 SELENIUM TETRACHLORIDE 62.7934 -5.6601E+03 -2.0127E+01 1.5021E-02 -4.7573E-06 347.15 464.65
269 SeF6 SELENIUM HEXAFLUORIDE -13.7376 -9.6701E+02 1.0083E+01 -1.4935E-02 9.6551E-06 154.55 227.35
270 SeOC[2 SELENIUM OXYCHLORIDE -31.1449 -1.5960E+03 1.5901E+01 -1.1690E-02 3.7904E-06 307.95 441.15
271Se02 SELENIUM DIOXIDE -26.7091 -2.9884E+03 1.3896E+01 -7.6193E-03 1.8305E-06 430.15 590.15
272 Si SILICON 315.0687 -7.1384E+04 -8.9680E+01 8.3445E-03 -2.5806E-09 1997.10 2560. I0
273 SiBrCI2F BROMODICHLOROFLUOROSILANE 221.2325 -5.5951E+03 -9.3501E+01 1.2431E-01 -6.0950E-05 186.65 474.30
274 SiBrF3 TRIFLUOROBROMOSILANE -316.1829 5.0196E+03 1.4386E+02 -2.1246E-01 1.1958E-04 203.35 354.90
275 SiBr2CIF DIBROMOCHLOROFLUOROSILANE 114.7880 -3.9867E+03 -4.5478E+01 5.1723E-02 -2.2118E-05 207.95 515.92
276 SiClF3 TRIFLUOROCHLOROSILANE 102.6712 -2.5416E+03 -4.3347E+01 7.1921E-02 -4.5231E-05 129.15 308.83
277 SiCl2F2 DICHLORODIFLUOROSILANE 65.5754 -2.0450E+03 -2.6643E+01 4.5134E-02 -2.8299E-05 148.45 367.35
278 SiCl3F TRICHLOROFLUOROSILANE 106.0275 -3.4770E+03 -4.2166E+01 5.0626E-02 -2.3053E-05 180.55 434.85
279 SiC[4 SILICON TETRACHLORIDE 28.4503 -2.3911E+03 -7.3965E+00 -9.3193E-I0 2.7569E-06 204.30 507.00
280 SiF4 SILICON TETRAFLUORIDE 250.9551 -6.9843E+03 -9.4613E+01 -5.3053E-05 1.3121E-04 186.35 259.00
281SiHBr3 TRIBROMOSILANE 29.8264 -2.6956E+03 -8.0772E+00 2.0334E-03 1.0063E-06 242.65 617.50
282 SiHCl3 TRICHLOROSILANE 8.8008 -1.6896E+03 5.0043E-01 -6.9024E-03 5.1631E-06 144.95 479.00
283 SIHF3 TRIFLUOROSILANE -122.7759 5.7853E+01 6.9914E+01 -2.1980E-01 2.2343E-04 121.15 276.65
284 SiH2Br2 DIBROMOSILANE 63.8405 -2.9308E+03 -2.3568E+01 2.4715E-02 -9.7683E-06 212.25 559.24
285 SiH2Cl2 DICHLOROSILANE 30.1827 -2.0844E+03 -8.2717E+00 -3.7469E-I0 4.5636E-06 151.15 449.00
286 SiH2F2 DIFLUOROSILANE 23.8427 -1.5675E+03 -4.4921E+00 -1.9742E-02 3.1144E-05 126.45 310.75
287 SiH212 DIIODOSILANE -132.4973 2.1632E+03 5.6398E+01 -4.9010E-02 1.6020E-05 276.95 683.81
288 SiH3Br MONOBROMOSILANE 48.9247 -2.1416E+03 -1.7831E+01 2.1780E-02 -I.0087E-05 187.45 455.15
289 SIH3CI MONOCHLOROSILANE 97.0716 -3.0578E+03 -3.8232E+01 4.4033E-02 -1.8687E-05 155.35 396.79
290 SiH3F MONOFLUOROSILANE 262.3858 -5.0922E+03 -1.1579E+02 1.8678E-01 -1.1081E-04 120.15 285.87
291SiH31 IODOSILANE 81.5431 -3.3034E+03 -3.0771E+01 3.1175E-02 -1.1973E-05 220.15 524.59
292 SiH4 SILANE 49.8037 -1.3946E+03 -1.8981E+01 2.2497E-02 3.0530E-13 88.48 269.70
293 Si02 SILICON DIOXIDE -378.5210 6.5473E+03 1.3150E+02 -3.ST/4E-02 3.4220E-06 I883.00 2503.20
294 Si2Cl6 HEXACHLORODISILANE 28.0093 -2.9842E+03 -7.7427E+00 6.7458E-03 -2.5044E-06 277.15 412.15
295 Si2F6 HEXAFLUORODISILANE -3.5918 -1.9401E+03 6.6355E+00 -8.5356E-03 4.7603E-06 192.15 254.25
296 Si2H5Cl DISILANYL CHLORIDE 50.2854 -2.4890E+03 -1.8081E+01 2.1374E-02 -I.0671E-05 226.95 291.15
297 Si2H6 DISILANE 19.4083 -1.5000E+03 -4.5432E+00 -2.0804E-I0 3.3390E-06 143.85 432.00
298 Si2OCl3F3 TRICHLOROTRIFLUORODISILOXANE -39.7219 -2.7322E+02 1.9305E+01 -1.7428E-02 7.2191E-06 235.15 316.35
299 Si20Cl6 HEXACHLORODISILOXANE 173.0145 -6.6562E+03 -6.7483E+01 6.5445E-02 -2.6121E-05 268.15 408.75
300 Si20H6 DISILOXANE 23.4097 -1.5324E+03 -6.9541E+00 1.0056E-02 -6.1820E-06 160.65 257.75
301Si3Cl8 OCTACHLOROTRISILANE 0.9548 -2.4388E+03 2.9120E+00 -2.1105E-03 6.5985E-07 319.45 484.55
302 Si3H8 TRISILANE 61.7030 -2.7796E+03 -2.2974E+01 2.7178E-02 -1.3469E-05 204.25 326.25
303 Si3H9N TRISILAZANE 77.8169 -3.1701E+03 -2.9814E+01 3.5861E-02 -1.8007E-05 204.45 321.85
304 Si4H10 TETRASILANE 72.5811 -3.7126E+03 -2.6507E+01 2.6806E-02 -1.1367E-05 245.45 373.15
305 Sm SAMARIUM -63.3814 -6.9759E+03 2.5576E+01 -9.5945E-03 1.2128E-06 733.00 1874.00
306 Sn TIN -11.8452 -1.3744E+04 6.4004E+00 -9.7861E-04 -4.2795E-I0 1096.00 2995.00
307 SnBr4 STANNIC BROMIDE 62.0925 -4.1212E+03 -2.1351E+01 1.6385E-02 -5.2861E-06 331.45 477.85
308 SnCl2 STANNOUS CHLORIDE 430.9683 -2.2551E+04 -1.5874E+02 9.2347E-02 -2.1208E-05 589.15 896.15
309 SnCl4 STANNIC CHLORIDE 146.4762 -5.5847E+03 -5.7244E+01 5.8634E-02 -2.4782E-05 250.45 386.15
310 SnH4 STANNIC HYDRIDE 7.8482 -9.7474E+02 -2.7435E-01 4.6026E-04 -3.3081E-07 133.15 220.85
311SnI4 STANNIC IODIDE -5.9850 -2.4424E+03 5.1095E+00 -2.7912E-03 6.6165E-07 429.15 621.15
312 Sr STRONTIUM -111.2297 -2.8962E+03 4.3785E+01 -2.0560E-02 3.2941E-06 582.00 1630.00
313 SrO STRONTIUM OXIDE 2848.9447 -4.0303E+05 -8.7252E+02 1.3051E-01 -7.7456E-06 2341.15 2683.15
314 Ta TANTALUM 90.4608 -5.3107E+04 -2.4076E+01 2.9553E-03 -1.3908E-07 2511.00 5565.00
315 Tc TECHNETIUM -240.5191 -5.7928E+03 7.8794E+01 -1.3112E-02 7.4635E-07 1660.00 5000.00
316 Te TELLURIUM -130.9948 -5.2810E+03 5.7873E+01 -4.6486E-02 1.0781E-05 497.00 1285.00
317 TeCl4 TELLURIUM TETRACHLORIDE 225.5681 -1.3194E+04 -8.0899E+01 4.5316E-02 -I.0441E-05 506.15 665.15
318 TeF6 TELLURIUM HEXAFLUORIDE 103.1152 -3.1620E+03 -4.2245E+01 6.7520E-02 -4.5015E-05 161.85 234.55
319 Ti TITANIUM -194.8742 -8.2733E+03 6.8261E+01 -1.7329E-02 1.5517E-06 1508.00 3442.00
356
tog,o P = A + BIT + C tog,o T + D T + E T 2 (P - mm Hg, T - K)
. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
320 TiCt4 TITANIUMTETRACHLORIDE 65.9073 -4.0187E+03 -2.2002E+01 1.0422E-02 -8.7715E-13 249.05 638.00
321TL THALLIUM 149.2845 -1.7175E+04 -4.9494E+01 1.8084E-02 -2.5186E-06 636.00 1745.00
322 TtBr THALLOUSBROMIDE 65.7795 -9.3154E+03 -1.9913E+01 6.6371E-03 -9.3147E-07 763.15 1092.15
323 TtI THALLOUSIODIDE 107.4718 -1.2047E+04 -3.4449E+01 1.2081E-02 -1.7669E-06 713.15 1096.15
324 Tm THULIUM 581.9203 -4.0634E+04 -2.0847E+02 9.8996E-02 -1.8204E-05 661.00 1237.00
325 U URANIUM 5.1916 -2.3655E+04 1.4051E+00 -6.7084E-04 6.4472E-08 1600.00 4135.00
326 UF6 URANIUM FLUORIDE 141.7284 -5.4522E+03 -5.5519E+01 6.2879E-02 -2.9623E-05 234.35 328.85
327 V VANADIUM 52.0677 -3.1989E+04 -1.2620E+01 1.6179E-03 -1.0505E-07 1604.00 3665.00
328 VCt4 VANADIUMTETRACHLORIDE 12.7215 -2.2338E+03 -1.7693E+00 -9.8525E-11 3.4861E-07 247.45 697.00
329 V O C [ 3 VANADIUMOXYTRICHLORIDE 31.8135 -2.8585E+03 -8.5879E+00 3.9375E-09 3.4924E-06 193.65 400.00
330 W TUNGSTEN -19.5111 -3.8683E+04 8.6887E+00 -7.1355E-04 2.1195E-08 2667.00 5645.00
331 WF6 TUNGSTEN FLUORIDE 354.8192 -8.8753E+03 -1.5107E+02 2.0875E-01 -1.1715E-04 201.55 290.45
332 Xe XENON 15.6530 -8.1035E+02 -3.9013E+00 4.7985E-03 -1.7020E-11 161.36 289.74
333 Yb YTTERBIUM -61.8092 -5.3349E+03 2.5566E+01 -1.1528E-02 1.7104E-06 599.00 1660.00
334 Yt YTTRIUM -198.7054 -2.2991E+03 6.8766E+01 -1.6442E-02 1.3848E-06 1246.00 3055.00
335 Zn ZINC -20.3143 -4.6362E+03 1.0073E+01 -3.8085E-03 4.8860E-07 692.70 3170.00
336 ZnCt2 ZINC CHLORIDE 256.5500 -1.7845E+04 -9.1583E+01 4.9680E-02 -1.0787E-05 701.15 1005.15
337 ZnF2 ZINC FLUORIDE -17799.4171 1.2561E+06 6.0444E+03 -1.7915E+00 2.0155E-04 1243.15 1770.15
338 ZnO ZINC OXIDE 10.0724 -1.5790E+04 -3.0065E-02 6.5659E-06 -5.4927E-10 1773.10 2223.10
339 ZnS04 ZINC SULFATE 8.7415 -2.2158E+03 -5.1178E-04 6.6577E-07 -3.3159E-10 293.15 378.15
340 Zr ZIRCONIUM 95.1134 -4.3264E+04 -2.5683E+01 2.9830E-03 -1.1696E-07 1975.00 4598.00
341ZrBr4 ZIRCONIUM BROMIDE 35.8920 -6.9028E+03 -8.7767E+00 4.6821E-03 -I.0688E-06 480.15 630.15
342 ZrC[4 ZIRCONIUM CHLORIDE 80.7853 -8.5643E+03 -2.5618E+01 1.4577E-02 -3.5146E-06 463.15 604.15
343 ZrI4 ZIRCONIUM IODIDE 95.3927 -I.0449E+04 -3.0444E+01 1.5025E-02 -3.1340E-06 537.15 704.15
357
Appendix D
MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/m0t K K K bar cm3/mo t g/cm 3 Zc ~ SOURCE
1Ag SILVER 107.868 1234.00 2485.00 7480.00 5066.0 58.20 1.8534 0.474 0.150 1,6
2 AgCt SILVER CHLORIDE 143.321 728.15 1837.15 . . . . . . . . . . . . . . . "'" 2
4 At ALUMINUM 26.982 933.00 2329.15 7151.00 5458.0 39.00 0.6918 0.358 --- 1
5 ALB3H12 ALUMINUM BOROHYDRIDE 71.510 209.15 319.05 . . . . . . . . . . . . . . . "'" 2
6 AtBr3 ALUMINUN BROMIDE 266.694 390.15 529.45 763.00 --- 124.20 2.1473 --- --- 3,6
7 ALCL3 ALUMINUM CHLORIDE 133.340 465.70 453.15 629.00 26.35 261.45 0.5100 0.132 --- 1
8 AtF3 ALUMINUM FLUORIDE 83.977 1313.15 1810.15 . . . . . . . . . . . . . . . . . .
. . . . . . . . . . . .
16 AsF3 ARSENIC TRIFLUORIDE 131.917 267.25 329.45 . . . . . .
. . . . . . . . . . . .
17 AsF5 ARSENIC PENTAFLUORIDE 169.914 193.35 220.35 . . . . . .
18 AsH3 ARSINE 77.945 156.28 210.67 373.00 65.50 97.80 0.7970 0.207 0.006 1
19 AsI3 ARSENIC TRIIODIDE 455.635 419.15 676.15 . . . . . . . . . . . . . . . . . . 2,5
. . . . . . . . . . . .
20 As203 A R S E N I CTRIOXIDE 197.841 585.95 730.35 . . . . . .
21 At ASTATINE 210.000 575.15 607.00 . . . . . . . . . . . . . . . . . . 4,5
22 Au GOLD 196.967 1337.33 3120.00 4398.00 --- 50.30 3.9158 ...... 4,5,6
23 B BORON 10.811 2348.15 4133.00 . . . . . . . . . . . . . . . . . . 4,5
24 BBr3 BORON TRIBROMIDE 250.523 228.15 364.85 . . . . . . . . . . . . . . . . . .
25 BC[3 BORON TRICHLORIDE 117.169 166.15 285.65 451.95 38.71 148.34 0.7899 0.153 0.151 1
26 BF3 BORON TRIFLUORIDE 67.806 146.05 173.35 260.90 49.85 123.61 0.5485 0.284 0.430 1
27 BH2CO BORINE CARBONYL 40.837 136.15 209.15 . . . . . . "'" 3
44 Bi BISMUTH 208.980 544.15 1698.15 4620.00 --- 79.40 2.6320 ...... 3,6
45 BiBr3 B I S M U T HTRIBROMIDE 448.692 491.15 734.15 1220.00 --- 302.00 1 . 4 8 5 7 ...... 2,6
46 BiCt3 B I S M U T HTRICHLORIDE 315.338 503.15 714.15 1178.00 --- 2 6 1 . 7 0 1.2050 ...... 2,6
47 BrF5 BROMINE PENTAFLUORIDE 174.896 211.75 313.55 470.00 --- . . . . . . . . . . . . 2,6
48 Br2 BROMINE 159.808 265.90 331.90 584.15 103.35 135.00 1.1838 0.287 0.119 1
49 C CARBON 12.011 4247.00 4203.00 6810.00 2230.0 18.80 0.6389 0.074 1.566 1
50 CC[20 PHOSGENE 98.916 145.37 280.71 455.00 56.74 190.22 0.5200 0.285 0.201 I
51 CF20 CARBONYLFLUORIDE 66.007 161.89 188.58 297.00 57.60 1 4 1 . 0 0 0.4681 0 . 3 2 9 0 . 2 8 3 1
52 CH4N20 UREA 60.056 405.85 465.00 705.00 90.50 218.00 0.2755 0.337 --- 1
53 CH4N2S THIOUREA 76.122 454.15 536.00 854.00 82.30 248.00 0.3069 0.287 0.359 1
54 C N B r CYANOGENBROMIDE 105.922 331.15 334.65 . . . . . . . . . . . . . . . . . . 2
55 C N C [ CYANOGENCHLORIDE 61.470 266.65 286.00 449.00 59.90 1 6 3 . 0 0 0.3771 0 . 2 6 2 0 . 3 2 0 1
56 CNF CYANOGEN FLUORIDE 45.016 --- 227.17 . . . . . . . . . . . . . . . . . . 2
57 CO CARBON MONOXIDE 28.010 68.15 81.70 132.92 34.99 93.10 0.3009 0.295 0.066 1
58 COS CARBONYL SULFIDE 60.076 134.35 223.00 378.80 63.49 135.10 0.4447 0.272 0.097 1
358
MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc ~ SOURCE
60 C02 CARBON DIOXIDE 44.010 216.58 194.70 304.19 73.82 94.00 0.4682 0.274 0.228 1
61CS2 CARBON DISULFIDE 76.143 161.58 319.37 552.00 79.03 160.00 0.4759 0.276 0.108 1
62 CSeS CARBON SELENOSULFIDE 123.037 197.95 358.75 ...... . . . . . . . . . . . .
100 D2 DEUTERIUM 4.032 18.73 23.65 38.35 16.64 60.26 0.0669 0.314 -0.145 1
101D20 DEUTERIUM OXIDE 20.031 276.96 374.55 643.89 219.41 56.30 0.3558 0.231 0.368 1
102 Eu EUROPIUM 151.965 1095.15 1742.00 5150.00 --- . . . . . . . . . . . . 4,5,6
103 F2 FLUORINE 37.997 53.53 84.95 144.31 52.15 66.20 0.5740 0.288 0.059 1
104 F20 FLUORINE OXIDE 53.996 49.25 128.55 215.10 49.50 97.60 0.5532 0.270 --- 2,6
105 Fe IRON 55.847 1808.15 3000.00 9340.00 10150 28.00 1.9945 0.366 -0.298 1
106 FeCS05 IRON PENTACARBONYL 195.899 252.15 378.15 ...... . . . . . . . . . . . .
* A computer program, c o n t a i n i n g data f o r a l l compounds, i s a v a i l a b l e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s i n ASCII which can be accessed by o t h e r s o f t w a r e .
359
MW TF Te Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc c0 SOURCE
128 H 2 0 2 HYDROGEN PEROXIDE 34.015 272.72 423.35 730.15 216.84 77.70 0.4378 0.278 0.360 1
129 H2S HYDROGEN SULFIDE 34.082 187.68 212.80 373.53 89.63 98.49 0.3460 0.284 0.083 1
130 H 2 S 0 4 SULFURICACID 98.079 283.46 610.00 925.00 64.00 177.03 0.5540 0.147 --- 1
131 H 2 S 2 HYDROGEN DISULFIDE 66.148 183.45 337.15 ...... . . . . . . . . . . . .
143 12 IODINE 253.809 386.75 458.39 819.15 116.54 155.00 1.6375 0.265 0.117 1
144 In INDIUM 114.818 429.75 2323.00 6730.00 2432.0 82.60 1.3900 0.359 --- 4,5,6
145 Iv IRIDIUM 192.220 2719.15 4450.00 ...... . . . . . . . . . . . . 4,5
146 K POTASSIUM 39.098 336.35 1037.00 2223.00 162.12 209.00 0.1871 0.183 -0.183 1
147 KBr POTASSIUM BROMIDE 119.002 1003.15 1656.15 . . . . . . . . . . . . . . . . . . 2
148 KCI POTASSIUM CHLORIDE 74.551 1044.00 1688.87 3470.00 180.00 625.00 0.1193 0.390 -0.121 1
149 KF POTASSIUM FLUORIDE 58.097 1153.15 1775.15 ...... . . . . . . . . . . . .
152 Kr KRYPTON 83.800 115.78 119.80 209.35 55.02 91.20 0.9189 0.288 0.000 1
153 La LANTHANUM 138.906 1193.15 3643.00 9511.00 5460.0 36.50 3.8056 0.252 --- 4,5,6
154 Li LITHIUM 6.941 453.69 1597.00 4085.00 1722.5 47.00 0.1477 0.238 -0.045 1
155 L i B r LITHIUM BROMIDE 86.845 820.15 1583.15 . . . . . . . . . . . . . . . . . .
162 MgO MAGNESIUM OXIDE 40.304 3105.00 3873.20 5950.00 33.91 209.50 0.1924 0.014 0.214 1
163 Mn MANGANESE 54.938 1519.15 2392.00 . . . . . . . . . . . . . . . . . . 4,5
164 MnCl2 MANGANESECHLORIDE 125.843 923.15 1463.15 . . . . . . . . . . . . . . . . . .
165 Mo MOLYBDENUM 95.940 2895.15 5081.15 9620.00 --- 3 8 . 3 0 2.5050 ...... 3,6
166 M o F 6 MOLYBDENUMFLUORIDE 209.930 290.15 309.15 . . . . . . . . . . . . . . . . . .
181 NO2 NITROGEN DIOXIDE 46.006 261.95 294.00 431.35 101.33 82.49 0.5577 0.233 0.849 1
182 N2 NITROGEN 28.013 63.15 77.35 126.10 33.94 90.10 0.3109 0.292 0.040 1
183 N 2 F 4 TETRAFLUOROHYDRAZINE 104.007 111.65 198.95 309.35 37.10 213.00 0.4883 0.307 0.223 1
184 N 2 H 4 HYDRAZINE 32.045 274.69 386.65 653.15 146.92 158.00 0.2028 0.427 0.314 1
185 N 2 H 4 C AMMONIUMCYANIDE 44.056 309.15 304.85 . . . . . . . . . . . . . . . . . . 2
186 N2H6C02 AMMONIUMCARBAMATE 78.071 --- 331.45 . . . . . . . . . . . . . . . . . . 2
187 N20 NITROUS OXIDE 44.013 182.33 184.67 309.57 72.45 97.37 0.4520 0.274 0.142 1
188 N 2 0 3 NITROGENTRIOXIDE 76.012 170.00 275.15 425.00 69.90 195.00 0.3898 0.386 0.431 I
189 N 2 0 4 NITROGENTETRAOXIDE 92.011 261.90 302.22 431.15 101.33 82.49 1.1154 0.233 1.007 I
190 N 2 0 5 NITROGENPENTOXIDE 108.010 . . . . . . . . . . . . . . . . . . . . . . . . I
191Na SODIUM 22.990 370.98 1156.00 2573.00 354.64 116.00 0.1982 0.192 -0.102 I
192 NaBr SODIUM BROMIDE 102.894 1020.00 1663.82 4287.00 192.52 398.00 0.2585 0.215 -0.800 I
193 NaCN SODIUM CYANIDE 49.008 836.85 1769.15 2900.00 . . . . . . . . . . . . . . . I
194 NaCI SODIUM CHLORIDE 58.442 1073.95 1738.15 3400.00 355.00 266.00 0.2197 0.334 0.134 I
195 NaF SODIUM FLUORIDE 41.988 1269.00 1982.72 5530.00 531.96 185.00 0.2270 0.214 -1.115 1
196 Nal SODIUM IODIDE 149.894 924.15 1577.15 . . . . . . . . . . . . . . . . . . 2
* A computer program, c o n t a i n i n g data f o r a l l compounds, i s a v a i l a b l e f o r a nominal fee (Carl L. Yaws, Box 10053, Larnar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be accessed by o t h e r s o f t w a r e .
360
MW TF Ts Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm 3 Zc co SOURCE
197 NaOH SODIUM HYDROXIDE 39.997 596.00 1663.15 2820.00 253.31 200.00 0.2000 0.216 --- I
198 N a 2 S 0 4 SODIUMSULFATE 142.043 1157.00 . . . . . . . . . . . . . . . . . . . . . I
215 PCt3 PHOSPHORUS TRICHLORIDE 137.332 181.15 349.25 563.15 56.70 260.00 0.5282 0.315 0.234 1
216 PC[5 PHOSPHORUS PENTACHLORIDE 208.237 433.15 433.00 646.15 . . . . . . . . . . . . . . . 1
217 PH3 PHOSPHINE 33.998 139.37 185.41 324.75 65.36 113.32 0.3000 0.274 0.036 1
218 P H 4 B r PHOSPHONIUMBROMIDE 114.910 --- 311.45 . . . . . . . . . . . . . . . . . . 2
219 P H 4 C L PHOSPHONIUMCHLORIDE 70.458 244.65 246.15 . . . . . . . . . . . . . . . . . . 2
220 P H 4 I PHOSPHONIUM IODIDE 161.910 291.65 335.45 . . . . . . . . . . . . . . . . . . 2,10
221POCt3 PHOSPHORUSOXYCHLORIDE 153.331 274.33 378.65 602.15 . . . . . . . . . . . . . . . 1
222 PSBr3 PHOSPHORUSTHIOBROMIDE 302.752 311.15 448.15 . . . . . . . . . . . . . . . . . . 2
223 P S C L 3 PHOSPHORUSTHIOCHLORIDE 169.398 236.95 398.15 . . . . . . . . . . . . . . . . . . 1
224 P406 PHOSPHORUS TRIOXIDE 219.891 295.65 446.25 . . . . . . . . . . . . . . . . . . 2
225 P4010 PHOSPHORUSPENTOXIDE 283.889 693.15 . . . . . . . . . . . . . . . . . . . . . I
226 P 4 S I O PHOSPHORUSPENTASULFIDE 444.555 561.15 787.15 1291.00 232.00 . . . . . . . . . 0.594 I
227 Pb LEAD 207.200 600.61 2024.00 5400.00 861.30 93.20 2.2232 0.179 --- 4,5,6
228 PbBr2 LEAD BROMIDE 367.008 646.15 1187.15 . . . . . . . . . . . . . . . . . . 3
229 PbCt2 LEAD CHLORIDE 278.105 774.15 1227.15 . . . . . . . . . . . . . . . . . . 2
230 PbF2 LEAD FLUORIDE 245.197 1128.15 1566.15 . . . . . . . . . . . . . . . . . . 3
231PbI2 LEAD IODIDE 461.009 675.15 1145.15 . . . . . . . . . . . . . . . . . . 3
232 PbO LEAD OXIDE 223.199 1163.15 1745.15 . . . . . . . . . . . . . . . . . . 3
233 PbS LEAD SULFIDE 239.266 1387.15 1554.15 . . . . . . . . . . . . . . . . . . 3
234 Pd PALLADIUM 106.420 1828.05 3385.00 . . . . . . . . . . . . . . . . . . 4,5
235 Po POLONIUM 209.000 527.15 1235.00 . . . . . . . . . . . . . . . . . . 4,5
236 Pt PLATINUM 195.080 2041.55 3980.00 6983.00 --- 759.10 0.2570 ...... 4,5,6
237 Ra RADIUM 226.000 973.15 1809.00 . . . . . . . . . . . . . . . . . . 4,5
238 Rb RUBIDIUM 85.468 312.46 978.00 2111.10 134.00 247.00 0.3460 0.189 --- 4,5,6
239 RbBr R U B I D I U MBROMIDE 165.372 955.15 1625.15 . . . . . . . . . . . . . . . . . . 2
240 R b C L R U B I D I U MCHLORIDE 120.921 988.15 1654.15 . . . . . . . . . . . . . . . . . . 2
241RbF RUBIDIUM FLUORIDE 104.466 1033.15 1681.15 . . . . . . . . . . . . . . . . . . 2
242 RbI RUBIDIUM IODIDE 212.372 915.15 1577.15 . . . . . . . . . . . . . . . . . . 2
243 Re RHENIUM 186.207 3459.15 5915.00 ...... 32.10 5.8008 ...... 4,5,6
244 Re207 RHENIUM HEPTOXIDE 484.410 569.15 635.55 . . . . . . . . . . . . . . . . . . 3
245 Rh RHODIUM 102.906 2237.15 3940.00 . . . . . . . . . . . . . . . . . . 4,5
246 Rn RADON 222.000 202.15 211.35 377.40 63.00 140.00 1.5857 0.281 --- 2,6
247 Ru RUTHENIUM 101.070 2607.15 4500.00 . . . . . . . . . . . . . . . . . . 4,5
248 R u F 5 RUTHENIUM PENTAFLUORIDE 196.062 . . . . . . . . . . . . . . . . . . . . . . . . 2
249 S SULFUR 32.066 388.36 717.82 1313.00 182.08 158.00 0.2029 0.264 0.262 1
250 SF4 SULFUR TETRAFLUORIDE 108.060 149.15 233.15 . . . . . . . . . . . . . . . . . . 2,10
251 SF6 SULFUR HEXAFLUORIDE 146.056 222.45 209.25 318.69 37.60 198.52 0.7357 0.282 0.215 1
252 S O B r 2 T H I O N Y LBROMIDE 207.873 220.95 412.65 . . . . . . . . . . . . . . . . . . 2
253 S O C t 2 T H I O N Y LCHLORIDE 118.971 172.00 348.75 567.00 --- 203.00 0.5861 ...... 1
254 S O F 2 SULFUROUS OXYFLUORIDE 86.062 --- 228.90 . . . . . . . . . . . . . . . . . . 2
255 S02 SULFUR DIOXIDE 64.065 200.00 263.13 430.75 78.84 122.00 0.5251 0.269 0.245 I
256 S02Ct2 SULFURYLCHLORIDE 134.970 222.00 342.55 545.00 46.10 224.00 0.6025 0.228 0.176 I
257 S03 SULFUR TRIOXIDE 80.064 289.95 317.90 490.85 82.07 127.08 0.6300 0.256 0.422 1
258 $2C[2 SULFUR MONOCHLORIDE 135.037 193.15 411.15 . . . . . . . . . . . . . . . . . . 2
259 Sb ANTIMONY 121.757 903.78 1898.00 5070.00 . . . . . . . . . . . . . . . 4,5,6
260 SbBr3 ANTIMONYTRIBROMIDE 361.469 369.75 548.15 . . . . . . . . . . . . . . . . . . 3
261 SbCt3 ANTIMONYTRICHLORIDE 228.115 346.55 493.40 794.00 48.20 270.00 0.8449 0.197 0.171 1
262 SbCt5 ANTIMONYPENTACHLORIDE 299.021 275.95 413.15 . . . . . . . . . . . . . . . . . . 2,11
263 SbH3 STIBINE 124.781 185.15 255.15 440.35 73.06 157.2 0.7938 0.314 --- 7
264 SbI3 ANTIMONYTRIIODIDE 502.470 440.15 674.15 . . . . . . . . . . . . . . . . . . 3
265 Sb203 ANTIMONYTRIOXIDE 291.512 929.15 1698.15 . . . . . . . . . . . . . . . . . . 3
* A computer program, c o n t a i n i n g data f o r a l l compounds, is a v a i t a b t e f o r a nominat fee (Carl L. Yaws, Box 10053, Lamar U n i v e r s i t y
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s in ASCII which can be accessed by o t h e r s o f t w a r e .
361
MW TF TB Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm31mo t glcm 3 Zc SOURCE
272 Si SILICON 28.086 1685.00 3513.80 5159.00 537.00 233.00 0.1205 0.292 --- I
273 SiBrCL2F BROMODICHLOROFLUOROSILANE 197.893 160.85 308.55 . . . . . . . . . . . . . . . --- 3
279 SiCt4 SILICON TETRACHLORIDE 169.896 204.30 330.00 507.00 35.93 326.00 0.5212 0.278 0.232 1
280 SiF4 SILICON TETRAFLUORIDE 104.079 186.35 178.35 259.00 37.19 165.00 0.6308 0.285 0.385 1
281SiHBr3 TRIBROMOSILANE 268.805 199.65 384.95 . . . . . . . . . . . . . . . "'" 2
282 SiHCt3 TRICHLOROSILANE 135.452 144.95 305.00 479.00 41.70 268.00 0.5054 0.281 O. 203 1
283 SiHF3 TRIFLUOROSILANE 86.089 141.75 178.15 . . . . . . . . . . . . . . . "'" 2
289 SiH3C[ MONOCHLOROSILANE 66.562 155.05 242.75 396.65 48.43 174.00 0.3822 0.256 0.136 3,9
290 SiH3F MONOFLUOROSILANE 50.108 --- 175.15 ...... . . . . . . . . . "'" 2
291SiH3I IODOSILANE 158.014 216.15 318.55 ...... . . . . . . . . . . . .
292 SiH4 SILANE 32.117 88.15 161.00 269.70 48.43 132.70 0.2420 0.287 0.097 1
293 Si02 SILICON DIOXIDE 60.084 1883.00 2503.20 ...... . . . . . . . . . . . . I
297 Si2H6 DISILANE 62.219 140.65 259.00 432.00 51.30 198.00 0.3142 0.283 0.102 I
298 Si20Ct3F3 TRICHLOROTRIFLUORODISILOXANE 235.524 --- 315.89 . . . . . . . . . . . . . . . "'" 2
299 Si20Ct6 HEXACHLORODISILOXANE 284. 887 239.95 408.75 . . . . . . . . . . . . . . . --- 2
* A computer program, c o n t a i n i n g data f o r a t l confounds, i s a v a i t a b t e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program i s in ASCII which can be accessed by o t h e r software.
362
MW TF Te Tc Pc Vc Pc
NO FORMULA NAME g/mot K K K bar cm3/mot g/cm3 Zc ~ SOURCE
335 Zn ZINC 65.390 692.70 1181.15 3170.00 2904.0 33.00 1.9815 0.364 0.078 1
336 ZnCt2 ZINC CHLORIDE 136.295 638.15 1005.15 ...... . . . . . . . . . . . .
* A con~uter program, containing data f o r a l l compounds, is a v a i l a b l e f o r a nominal fee (Cart L. Yaws, Box 10053, Lamar U n i v e r s i t y ,
Beaumont, TX 77710, phone/FAX 409-880-8787). The con~uter program is in ASCII which can be accessed by other software.
NOTE:
1. Daubert, T. E. and R. P. Danner, RATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS, Parts 1, 2, 3 and 4, Supplements
1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).
2. Ohe, S., COMPUTERAIDED DATA BOOK OF VAPOR PRESSURE, Data Book Publishing CcHnpany, Tokyo, Japan (1976).
3 . PERRY'S CHEMICAL ENGINEER!NG HANDBOOK, 6th ed., McGraw-Hilt, New York, NY (1984).
4. Nesmeyanov, A. N., VAPOR PRESSURE OF THE CHEMICAL ELEMENTS, E l s e v i e r , New York, NY (1963).
5. CRC HANDBOOKOF CHEMISTRY AND PHYSICS, 66th - 75th eds., CRC Press, I n c . , Boca Raton, FL (1985-1994).
6. Simmrock, K. H., R. Janowsky and A, Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES, Vot. I I , Parts 1 and 2, Dechema
Chemistry Data Series, 6000 Frankfurt~Main, Germany (1986).
7. Yaws, C. L. and others, Solid State Technology, 17', No. 1, 47 (1974).
8. Yaws, C. L. and others, Sotid State Technology, 18, No. 1, 35 (1975).
9. Yaws, C. L. and others, Solid State Technology, 16, No. 1, 39 (1973).
10. CONDENSED CHEMICAL DICTIONARY, lOth (G. G. Hawley) and 11th eds. (N. I . Sax and R. J. Lewis, J r . ) , Van Nostrand
Reinhold Co., New York, NY (1981,1987).
11. LANGE'S HANDBOOK OF CHEMISTRY, 13th and 14th eds., McGraw-Hitt, New York, NY (1985, 1992).
2. Very l i m i t e d experimental data f o r c r i t i c a l constants and acentric f a c t o r are a v a i l a b l e f o r inorganic con~ounds and elements
which are sotids at room temperature. Thus, the estimates f o r these substances should be considered rough approximations in the
absence of experimental data.
363
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