Kapasitas Aseton Prasol Chem
Kapasitas Aseton Prasol Chem
Kapasitas Aseton Prasol Chem
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Table of Contents
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
1 EXEC UT IV E SU MMA RY
Prasol Chemicals Private Limited (Prasol), form an integral part of the global chemical
industry. Prasol is an ISO 9001:2008, ISO 14001:2004 and an OHSAS
18001:2007 certified company that is well aligned with its vision "To become a premier
manufacturer of Specialty Chemicals and to provide Technical Services globally." Prasol
is also A credit rated by SMERA.
Prasol has its own Research and Development and Manufacturing unit, with production
facilities for Phosphorous Based, Acetone Based and Hydrogenated products, situated at
Khopoli in Raigad district, Maharashtra state.
Prasol is prevalent in various sectors spanning Paints, Coatings, Thinners, Flavors &
Fragrances, Agrochemicals, Lubricant Additives, Surfactants, Cosmetics and
Pharmaceutical Industries.
Prasol’s global reach spans 45 countries along with local presence through multiple
dedicated distribution channels across India.
With a team strength of over 400 employees, Prasol enforces the belief of "Customer
first, Reputation first", through technical support and after sales service.
Prasol has established aggressive growth plans for its business with a well-defined
pathway for the next several years. Lead by a strong and enthusiastic team of
technocrats, the company is well underway in executing plans for organic growth in the
near & medium term.
A few areas were considered in and around Maharashtra and found the existing plot
most suitable due to its availability and proximity from the company’s existing
manufacturing facility.
The site has obtained Prior Environment Clearance in past in the year 2014 for its
expansion.
Total cost of the expansion project will be approx. Rs. 50.0 Crores (based on present
rates).
The total design capacity of the plant for various products will be 153,000 MTA (~ 510
TPD) on the basis of running the plant for 24 hrs., a day, seven days a week and 300
days / annum. The balance 65 days will be utilized for product change-over preparation
and annual maintenance shutdown.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
The project brief is summarized in the table below Project summary at a glance
The Land shall be used as “Industrial” land thus there shall be no change in land use.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Existing Unit has all basic infrastructure like Electrical Power, water supply, the internal
road network, external approach road and networking with CHWSTDF (Common
Hazardous Waste Storage Treatment and Disposal Facility).
The land and infrastructure is available for the existing unit and the raw material is
easily available through the easy transport via road connectivity by local suppliers as
well as imported one.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
PCPL is an ISO 9001: 2008, ISO 14001: 2004 and an OSHAS 18001:2007 certified
company. PCPL has an in-house R&D and manufacturing facility, with production plants
for Phosphorous based, Acetone based and hydrogenated products, situated at Khopoli,
with their own warehouse for storage and distribution of specialty chemicals.
The total occupied area at Khopoli is 16.96 Acres (around 68,644 sq. meters) with
production plants for Phosphorous Pentasulphide, Diacetone Alcohol, Isophorone,
Mesityl Oxide, Lubricant Additives, Phenol – Acetone and various Hydrogenated
Products.
PCPL is prevalent in various sectors spanning Paints, Coatings, Thinners, Flavours &
Fragrances, Agrochemicals, Lubricant Additives, Surfactants, Cosmetics, and
Pharmaceutical Industries.
PCPL’s global reach spreads over 45 countries along with local presence in India
through multiple dedicated distribution channels.
PCPL has established aggressive growth plans for its business with a well-defined
pathway for the next several years. Lead by a strong and enthusiastic team of
technocrats, the company is well underway in executing plans for organic growth in the
near & medium term.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
The additional products proposed are forward integration of the company’s current
products and have a great demand both global and domestic. The demand is envisaged
to increase rapidly in the domestic market.
Export Possibility
The products can be exported thus leading to forex revenues for the country
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Type of Project
(Including interlinked and interdependent projects, if any)
Existing Proposed
Total
Capacity Additional
S. No. Products / By Products Capacity
(*) Capacity
(MT/Year)
(MT/Year) (MT/Year)
Products
1 Diacetone Alcohol 9,000 23,000 32,000
2 Nonyl Phenol 720 30 750
3 Phosphorous Pentasulphide 6,000 4,000 10,000
4 Phosphorous Acid Food Grade 600 0 600
5 Phosphorous Pentoxide 500 0 500
6 Dil. Phosphorous Acid 624 26 650
7 Isophorone 3,600 8,400 12,000
8 Phenol 20,000 0 20,000
9 Acetone 12,000 3,000 15,000
10 Zinc Diorgano Dithiophosphate 1,500 2,000 3,500
11 Mesityl Oxide 750 2,250 3,000
Hexylene Glycol, Trimethyl 1,800 13,200 15,000
12 Cyclohexanol, Trimethyl
Cyclohexanone,
13 Methyl Isobutyl Ketone 0 5,000 5,000
14 Methyl Isobutyl Carbinol 0 3,000 3,000
15 Di-isobutyl Ketone 0 1,500 1,500
16 Di-isobutyl Carbinol 0 1,000 1,000
17 Cumene Hydroperoxide 0 5,000 5,000
18 3,5 Dimethyl Phenol 0 3,000 3,000
19 Methyl Pentadiene 0 2,000 2,000
20 Bisphenol-S 0 3,000 3,000
Lubricant Additives (Hydraulic
21 0 500 500
Packages/ Gear Oil Packages etc.)
22 Sodium Dithiophosphate 0 500 500
23 Sodium Dialkyl Dithiophosphate 0 500 500
24 Benzylidene Acetone 0 800 800
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Location
(Map showing general location, specific location, and project boundary and
project site layout) with co ordinates
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Raigad District
Prasol Chemicals
Private Limited
Location
The project expansion is proposed at Survey No. 8,13,15,16,25 and 75, Tal. Khalapur,
Dist Raigad.
The Geographical Location of this plot is at Latitude 18° 46’ 34.90” N and 73° 18' 10.60"
E with an elevation of 60 meter above sea level MSL.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
J 18°46'22.80"N 73°18'3.21"E
K 18°46'24.86"N 73°18'5.20"E
L 18°46'31.39"N 73°18'4.28"E
M 18°46'34.86"N 73°18'8.78"E
Existing Land use Pattern: The Land is for Industrial use & the proposed expansion
project shall be at the same plot.
• There is no sensitive establishment in the vicinity such as health resort, hospital, and
archaeological monuments.
Refer Annexure III for the proposed plant site layout plan.
No alternative site examined as the proposed expansion will be integrated with existing
manufacturing site.
The design capacity of the plant as given in the table below will be on the basis of
running the plant for 24 hrs., a day, seven days a week and 300 days / annum. The
balance 65 days will be utilized for product change-over preparation and annual
maintenance shutdown.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Proposed products, Brief description, Process Chemistry, Process Block diagram are
given at Annexure V.
Raw Materials:
The basic raw material for the product capacity is submitted herein below.
Source for Raw Material Procurement: Raw Material is easily available in the local
market.
Mode of Transport of Raw Materials: Few of the raw materials will be transported
locally and few will be imported from the International Market. Mode of transport to
site is by road truck/tankers.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Proposed bulk storages at site shall be as follows for finished goods and raw
materials
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Bulk Storage
Physical Means of
S. No. Name of Raw Material Capacity
State Storage
(MT)
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
9 Benzaldehyde L 30 Tanks
10 Hydrogen G 5000 NM3 Cylinder banks
11 Polyisobutylene L 20 Tanks
15 Methanol L 40 Tanks
16 Ethanol L 40 Tanks
17 Isopropanol L 40 Tanks
18 N-Butanol L 40 Tanks
19 Isobutanol L 40 Tanks
20 Pentanol L 40 Tanks
21 Octanol L 40 Tanks
Resource optimization
(Recycling and reuse envisaged in the project, if any, should be briefly outlined)
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Water
The total water requirement is for domestic, process, Boiler and cooling and greenery
maintenance purpose.
The source of water shall be from Patalganga River, permit for which has been
obtained by the company. Water requirement for proposed establishment is
tabulated as below:
Energy
Existing and proposed fuel requirement, APC system and stack details are as follows,
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Power
Existing Co-Generation Plant (of capacity 5 MW) shall be sufficient for the Power
requirement of the proposed expansion.
DG Set:
Wastewater
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Non-Hazardous waste –
N Waste Type UOM Existing Proposed Total Disposal
o Quantity quantity
1 Ion exchange resin TPA 1 0.5 1.5 Regenerate
2 Sand from water filtration TPA 11 6.5 17.5 CHWTSDF
3 Used cotton hand gloves Pairs per 10,000 2500 12500 CHWTSDF
annum
4 Miscellaneous Kg/annum 500 200 700 CHWTSDF
5 Fly Ash TPD 20 0 20 Sale to Brick
manufacture
r
(*) Note: Above quantities are rough estimate, will be firmed up during EIA study.
Hazardous waste -
No Waste Type Category UOM Existing Proposed Total Disposal
(as per Quantity quantity
HW rules
2016)
1 Used/Spent 5.1 KL/A 6.0 3.0 9.0 Sale to
Oil authorized
reprocessor
2 Filter residue 6.1 TPA 38.0 21.0 59.0 CHWTSDF/
3 Tar 19.1 TPA 1500 - 1500 Sale to
4 Distillation 36.1 TPA 613.2 1225 1838.2 authorized
residue reprocessor
5 Used barrels 33.1 Nos/A 6000 6000 12000 Sale to
authorized
reprocessor
6 ETP sludge 35.3 TPA 80 20 100 CHWTSDF
from WWT
7 Spent 19.2 TPA 5 15 20 CHWTSDF/
catalyst Sale to
authorized
reprocessor
(*) Note: Above quantities are rough estimate, will be firmed up during EIA study.
Air Emissions:
Environmental issues associated with proposed pesticides manufacturing, formulation
and packaging includes:
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
The principal air pollutants will be volatile organic compounds (VOCs) and particulate
matter (PM).
Likely air pollutants from proposed project shall be PM, H2S, NOx, SO2 & HC from
various (~15 m to 35 m) process vents, boiler stack and DG Sets as point source.
Adequate APC equipment like scrubbers’ stacks & vents with adequate height will be
provided. Vehicular Emissions like CO & HC’s will be generated as line source emissions.
Fugitive emissions are also envisaged from proposed project.
Manpower
Manpower: Expected manpower requirement for the establishment (during operation
phase) shall be as follows:
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Form 1 with
proposed TOR to
MoEF&CC (EAC)
Scoping by EAC
EC – rejected by MoEF&CC on
TOR approved by EAC the recommendation of EAC
Public Consultation
Display on process by
the MoEF&CC SPCB/UTPCC
website
Rejected Approved
Submission of half Display of compliance
Post EC Monitoring yearly compliance report in MoEF&CC
report to MoEF&CC / website
Ro- MoEF&CC
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
4 S IT E A NALYS IS
Connectivity
The proposed expansion of Prasol Chemicals Private Limited shall be located at its
existing facility located at Survey No. 8,13,15,16,25,75, Tal Khalapur Dist Raigad,
Maharashtra. The plant facility is located at 2 km from village Honad, and 3 km from
Mumbai Pune Expressway. There is Khopoli town located on Mumbai-Pune NH4, which
is considerably better developed in terms of infrastructural facilities, education,
transport, hospital etc.
Land Ownership: Land ownership is with project proponent (Prasol Chemicals Private
Limited).
Existing infrastructure
Operating plant at the site.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
The rock of the district is trap. In the plains it is found in tabular masses a few feet
below the soil and sometimes standing out from the surface. In the hills it is tabular and
is also found in irregular masses and shapeless boulders varying from a few inches to
several feet in diameter. In many places the surface of the trap has a rusty hue showing
the presence of iron. Nala on West of the plant site is the main line of drainage which on
going further meets Patalganga river near Mumbai Pune Highway (NH – 4). This nala
has flowing water from Month of June to February. This helps in replenishment of
ground water table.
Soil Characteristics
There are four chief varieties of soil: Alluvial and Alluvia, Powdered Laterite and trap,
clayey mould resting on trap, and soil containing marine deposits with, much sand and
other matter in concretion. Of these the first, which is composed of various
disintegrated rocks of the overlying trap formation, with a varying proportion of
calcareous substances, is at once the richest and the most widespread. The soil in the
vicinity of manufacturing plant is either black soil or red soil (rich in iron). As per the
periodic soil analysis in year 2010, for area of village Honad and Khopoli, done by
Agricultural department of Govt. of Maharashtra, soil has following characteristics;
presented in table below.
The district is the second largest producer of rice in the Maharashtra State. The
region is peculiarly terraced and, though the small strips in between the two terraces
are levelled, it is difficult to get even a few gunthas of land in one piece in a levelled
condition. The depth varies between two and six feet. They are loamy in texture,
yellowish or reddish grey in color, neutral in reaction and almost devoid of lime. They
are formed from the trap rock from the Sahyadri ranges under heavy rainfall and
humid climatic conditions. The linear response of rice to the application of
nitrogenous, phosphatic and potassic fertilizers is observed in these soils. Addition of
bulky manures in these soils is also found to be advantageous from the point of view
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
of yield. There are some patches of manat soils in Mangaon taluka which are rich in
clay and silt and which become stiff and hard when dry.
Khar soils.
These soils are situated on the flat, levelled land near the sea at the point of creeks
formed due to the rivers. They are flat clay to clay loam in texture and reddish or
yellowish grey in colour. These soils contain hardly more than one per cent of soluble
salts. These soils are formed due to the deposition of salts by the sea or from lands
reclaimed from the sea. Large tracts of land are going out of cultivation due to the
ingress of the sea and, in order to reclaim these lands, the Government have formed
the Khar Land Development Board which has undertaken ambitious projects of the
reclamation of khar lands.
These soils are found all along the coast and at places where there are no creeks.
They are deep soils developed on flat land and loamy in texture with reddish grey
colour. They are devoid of clay fraction or humus and are open in nature. The profile
is difficult to differentiate and is excessively drained. Calcium carbonate is found in
abundance throughout the profile but calcium has not entered the clay complex. The
sub-soil water level is only from ten to fifteen feet deep. The salt contents of the well
water are higher in the proximity of the sea; but due to excellent drainage, its use has
not produced any deleterious effects. The soils are almost neutral or slightly on the
alkaline side of neutrality. Good garden crops like coconut, areca-nut, plantain, etc.,
are grown in these soils, depending upon the availability of water.
Laterite soils.
Out-crops of laterite rock are observed amongst the Sahyadri ranges amidst the trap
rock mainly at Matheran and in the Poladpur taluka. These soils mostly occur on the
mountain peaks. They are coarser in texture, wherever there are no forests. They are
yellowish-red in colour and shallow in depth and yield coarse millets and niger. The
heavy rains in the mountainous regions thoroughly leach the soils turning them acidic
in reaction and devoid of calcium carbonate. They are rich in sesquioxides, the ratio of
silica to sesquioxides being less than two. But they are generally poor in exchangeable
bases or in fertility constituents. However, the soils from the forest region are well-
supplied with nitrogen and organic matter.
Typical soil analysis is as follows
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Description of Soils
Chemical
Coastal Salt land or
Analysis Loamy Varkas Laterite
Alluvial Khar land
(1) (2) (3) (4) (5) (6)
Yellowish Yellowish red Reddish or
Reddish
Colour to reddish to yellowish Yellowish red yellowish
grey
grey. grey. grey.
Depth 1'—3' 1' - 2' 3' — 5' 5' — 10' 5' — 10'
Per cent on
drv matter
oven
Organic matter 0.7 — 1.8 0.5 — 1.0 2.0 — 3.0 0.7 — 1.5 0.5 — 1.5
Calcium
Nil — 0.01 Trace Trace 5.0 — 10.0 0.05 — 2.00
Carbonate
Sand (Coarse
5.0 — 10.0 60.0 — 70.0 8.0 — 10.0 20.0 — 35.0 20.0 — 30.0
and fine)
Silt 30.0 — 35.0 10.0 — 15.0 40.0 — 60.0 30.0 — 40.0 25.0 — 30.0
Clay 30.0 — 40.0 10.0 — 20.0 30.0 — 40.0 15.0 — 30.0 10.0 — 20.0
Clay to Clay
Textural class Loam Sandy Sandy loam Clay loam
loam
Total soluble
0.04 — 0.05 Trace 0.02 — 0.04 Trace 1.0 — 3.0
salts
Organic carbon 0.4 — 0.9 0.27 — 0.67 1.5 — 3.0 0.4 — 1.6 0.5 — 1.05
Total Nitrogen 0.04 — 0.06 0.02 — 0.05 0.15 — 0.20 0.06 — 0.10 0.05 — 0.07
C/N 10—16 10—16 10—15 10—16 10—15
PH value 6.7 — 7.2 6.0 — 7.5 4.5 — 6.0 7.0 — 8.0 7.0 — 8.0
Mgm. per cent
drv matter
on oven
Available P205 8—10 5.10 Trace—5 10—15 10—15
Available K20 12—20 10—20 5—10 20—25 10—15
millie
equivalent
dry matter
per cent on
oven.
Exchangeable
20—25 18—25 5—10 30—35 20—30
Ca
Exchangeable
7—8 7—10 1—2 5—7 10—11
Mg
Exchangeable
0.08 — 2.0 2—3 0.01 — 0.02 2.3 7.5 — 12.0
Na
Exchangeable
0.82 — 1.0 0.44 — 0.8 1—2 0.4 — 0.6 1.2
K
Exchangeable
-- -- 4—6 -- --
H
Total
Exchangeable 30—35 40—43 15—18 35—40 20 — 35
bases
Base Exchange
20—35 40—45 19—24 35—40 30—35
Capacity
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Village Honad (Raigad) being in region of Konkan the climate is warm and humid. The
relative humidity levels in this region are high throughout the year. The relative
humidity levels observed are in range of minimum 66% (Dec) to maximum 85% (July,
August, September).
The area receives rainfall for more than four months of the year, which provides main
climatic variations. Out of total rainfall 90% is experienced during Monsoon season of
months June to September. The details of monthly precipitation observed in Raigad
district are given in Table below,
Annual Rainfall Profile for Raigad District
Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec
Month
Rainfall
2.5 0.8 0.5 1.8 18.8 558.5 699.5 394.7 312.2 69.6 20.1 1.8
(mm)
Being a coastal district the diurnal (daily) and seasonal variations of temperature are
not large. The period from March to May is one of increasing temperatures. May is the
hottest month with a mean daily maximum temperature at 31.7°C (89.1°F) and the
mean daily minimum temperature at 26.4°C (79.5°F). Fresh breezes from the sea
relieve the oppressive heat particularly in the coastal regions in the afternoons. The
onset of the south-west monsoon early in June brings down the temperatures
slightly. After the withdrawal of the south-west monsoon by the end of September
the day temperatures increase slightly and the weather in October and November is
almost like the summer months. In the period from December to February the
weather is cooler than in the post-monsoon months.
Humidity:
The air is humid throughout the year. Relative humidity is on an average over 80 per
cent during the south-west monsoon season. In the rest of the year the relative
humidity is between 65 per cent and 75 per cent.
Cloudiness:
During the south-west monsoon season skies are heavily clouded to overcast. In May
and October, the clouding is moderate. Clear or very lightly clouded skies are
common in the rest of the year.
Winds:
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Winds are very strong and blow from west or south-west during monsoon season.
During the period from October to December winds are generally moderate but
sometimes strong in October and blow from directions between north-east and
south-east. In the three months from January to March the winds continue to be
moderate and are predominantly from directions between north and east. In April
while there is a slight strengthening of wind, the direction is variable. In May there is
a further strengthening of winds and the directions are between south-west and
north-west.
Special weather phenomena:
In association with cyclonic storms in the Arabian sea in the post-monsoon months
and to a lesser extent in May, the district experiences very strong winds, sometimes
reaching gale force, particularly very near the coast and also heavy widespread rain.
Occasionally these storms may cross the coast in the northern part of the district and
cause heavy damage. Thunderstorms occur in April and May and just before the onset
of the monsoon and in the late September to the middle of November.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
5 PL A NNING B RIEF
Planning Concept
• Existing operational unit in a well-established industrial area.
• Water supply from Patalganga River.
• Well-developed roads and connectivity.
• Integration with the existing manufacturing facility.
Population Projection
In 2011, Raigad district had population of 2,634,200 of which male and female were
1,344,345 and 1,289,855 respectively. In 2001 census, Raigad had a population of
2,207,929 of which males were 1,117,628 and remaining 1,090,301 were females.
Raigad District population constituted 2.34 percent of total Maharashtra population.
In 2001 census, this figure for Raigad District was at 2.28 percent of Maharashtra
population.
There was change of 19.31 percent in the population compared to population as per
2001. In the previous census of India 2001, Raigad District recorded increase of 20.99
percent to its population compared to 1991.
The initial provisional data released by census India 2011, shows that density of Raigad
district for 2011 is 368 people per sq. km. In 2001, Raigad district density was at 309
people per sq. km. Raigad district administers 7,152 square kilometers of areas.
Amenities / Facilities
No major amenities / facilities demand is envisaged as the proposed site is in well-
developed area and has good site connectivity.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Green Belt
Green belt of adequate area within and around the project site shall be carried out as
per industries norms and requirement.
Social Infrastructure
Local people will be given preference wherever found suitable for all the jobs in the
plant, direct as well as indirect. Thus, the project shall have a positive impact on the
employment pattern of the region. Economic status of the local population will
improve due to increased ancillary/business opportunities, thereby making positive
impact. Educational, medical & housing facilities will improve due to the proposed
project.
Connectivity
The total water requirement is about 1140 cmd for Domestic, boiler/cooling, Greenery
and process. The source of water shall be from Patalganga river.
Sewerage System
Refer Annexure IV for trade effluent and sewerage water treatment scheme.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
The proposed expansion shall be within the plot owned of the company. It does not
require acquisition of Land and the Infrastructure so there is no any kind of activity of
Rehabilitation and Resettlement to be carried out.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
It is expected that the expansion project shall be completed within 9 to 12 months from
date of grant of Environmental clearance.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
o Export benefits.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Annexure – I
Annexure – II
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Annexure – III
AREA STATEMENT
Sr No Description Area in sq m
1 Total Built up area 18,958
2 Total Green belt area 22,864
3 Total area for roads 14,215
4 Open land area 9,407
5 Total Co gen area 3,200
Total Plot area 68,644
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Annexure - IV
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Na2CO3
Neutralisation Neutralisation
Mixing Alum
Bottom Residue
Filtration Settling Multi grade
sand filter
Sludge to
CHWTSDF Back wash to
Clarifier
Filter press
RO reject
MEE + ATFD
RO permeate
Final storage
Treated eff. for recycle
3
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Annexure - V
1 Diacetone Alcohol
Diacetone Alcohol is produced by the Aldol Condensation of Acetone. The reaction is conducted
in the reactive distillation mode. Acetone is passed over anionic catalyst to form diacetone
alcohol after reaction. The reaction mass containing acetone and Diacetone alcohol is subjected
to distillative separation to a) recover and recycle the unreacted acetone and b) recover
diacetone alcohol in desired purities.
The product will be stored in storage vessel prior to drumming
Diacetone Alcohol
(CH3)2CO
Alcoholic Caustic Catalyst
Acetone Diacetone Alcohol
CATALYST
NEUTRALIZATION
REMOVAL
0.26 848.18
FLASHER
334.13
514.05
DISTILLATION 1
385.54
128.51
DISTILLATION 2
3.01
125.50
Manufacturing Process
In PPS plant, the manufacturing is done in 5 steps:
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Feed Preparation;
Reaction;
Distillation;
Flaking;
Grinding & Packaging.
The solid Sulphur is sent to the melting tank for melting. After melting, the sulphur is sent to the
Sulphur Feed Tank for reaction. The Phosphorus is molten and stored under water in the
Phosphorus Feed Tank.
Step 2: Reaction
From feed tanks the liquid sulphur and phosphorus are fed to the reactor which is operated
under Nitrogen blanket. In the reactor a simple addition reaction takes place at high
temperatures to form Phosphorus Pentasulphide (PPS) product and then it is drained to the
intermediate tank maintained at the desired temperature to be fed to the distillation furnace.
The vapours formed (if any, during abnormal conditions) in the reactor and the intermediate
tanks are sent to the H2S scrubber attached to the ZDDP plant / DATC Plant.
Step 3: Distillation
The reaction mass is heated and the vapours are collected in the distillation pot. The vapours
are cooled in the pot and liquid PPS of 99.5% purity is obtained. Periodic maintenance shall be
done, during which sludge will be removed.
Step 4: Flaking
The distillate mass is sent to the flaker. In flaker the distillate mass is solidified over a drum
cooled with chilled water to form a thin solid layer which is scraped by a blade arrangement and
collected in the form of flakes.
Step 5: Grinding & Packaging
These flakes are then conveyed through a pin mill arrangement to obtain the product in the
required size of granules or powder. This product is then stored in Silos and packed in drums or
Tote bins as per the requirement.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Phosphorus Sulphur
Reactor
Furnace for
Distillation
Sludg
Distillation Receiver
e
Pot
Flaker
Packing of P2S5
Product
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Phosphoric Acid
PHOSPHORIC ACID
PRODUCT
100.00
DIL. PHOSPHORIC
ACID PRODUCT
100.00
4) Isophorone
Process:
Acetone with a catalyst mixture is fed in a continuous manner to a reactive distillation column
system. The condensation reaction takes place in these reactors forming a mixture of
Isophorone, Acetone, water and other organics. The Acetone is recovered and recycled back in
the reaction section itself and is further sent for neutralization. The reaction mass, after
neutralization, is washed & and then subjected to separation by distillation process to extract
Isophorone in desired purities.
Isophorone
3 (CH3)2CO + 2H2O
Caustic Catalyst
Acetone Isophorone Water
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
0.069
CAUSTIC
155.88
ACETONE +
REACTION WATER TO ETP
WATER 110
70.16 323.44
195.726 85.726
WASHING AQ. DISTILLATION WATER FOR RECYCLE
127.7182
0.069
DISTILLATION 1 CAUSTIC RECOVERY
11.61075
116.1075
RECOVERY
HEAVIES
85.726 16.10748 16.10748
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
+ O2 + (CH3)2CO
Reaction 1:
+ O2
o
(80–110 C)
Cumene Oxygen Cumene Hydroperoxide (CHP)
Reaction 2:
PA Plant
CUMENE AIR
OXIDATION
140.00 188.50
694.10
CATALYST WATER 5
CLEAVAGE
0.42
184.13 TO ETP 1.58
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Manufacturing Process
Zinc Diorgano-DithioPhosphate (ZDDP) is manufactured in two major steps.
Step 1: Synthesis Step:
The synthesis of Oxo-Alcohols and Phosphorus Pentasulphide takes place to form a
Di-Alkyl Dithiophosphoric Acid with release of Hydrogen Sulphide gas. In this step,
the oxo-alcohols are charged into the reactor, stirred and heated. Phosphorus
Pentasulphide is added to this mass with continuous stirring which results in the
evolving of gases which are to be absorbed in the 2 stage caustic scrubber.
ZDDP Reactions:
Reaction 1:
SH
o
(95–100 C)
4 R-OH + P2S5 2(RO)2-P=S + H2S
Reaction 2:
SH S S
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
4.39
H2S Scrubber NaHS (30%)
9.47
Optional Draw
DDP ACID PRODUCT Reaction
Alcohol 47.06
71.70 48.06 To Flare
0.0439
11.00 16.00
ZnO Neutralization Base Oil
98.70
1.00
Drying Alcohol (Recovered)
97.70
Base Oil 3.00
Filter Aid 0.60
Mixing
101.30
ZDDP Product
100.00
7) Mesityl Oxide
Mesityl Oxide is manufactured by the dehydration of Di Acetone Alcohol (DAA) in presence of an
acid catalyst followed by distillation to obtain the pure product. The raw material DAA is
charged into an agitated reactor and the acid catalyst is added. The reaction is maintained at a
constant temperature by use of steam for heating. The vapors are then passed through a
distillation column to collect Crude MO at the top. The bottoms containing acetone & Di-
acetone Alcohol (DAA) are recycled back into the reactor.
The top product which is collected in a decanter is the fed to a distillation column where a Pure
MO product is extracted from a mixture of MO, water and other lighter hydrocarbons. The pure
MO is then stored in a product tank or packed as per requirements.
Mesityl Oxide
(CH3)2C(OH)(C0)CH3 CH3(CO)CH=C(CH3)2 + H2O
Catalyst
TO ETP WASHING
166.88
52.50 210.00 65.625
MO PRODUCT
100
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Initially the raw material is pumped from the feed tank into the loop reactor which operates at a
preset temperature and pressure. The catalyst is fed into the reactor before the batch is
initiated. The hydrogen gas in then introduced into the Loop reactor where the hydrogenation
reaction takes place. The contents of the loop reactor are thoroughly mixed using a pump
circulation system. After the reaction is completed, the reaction mass is emptied into a storage
tank and a new batch is charged into the loop reactor.
The reaction mass from the tank is then passed through a filter system where the catalyst
entrained in the product is removed / recycled. For some of the products a purification system
based on distillation and special filtration is used. The product is then pumped into a tank from
where the purified product can be packed and shipped.
Reactions
Hexylene Glycol
CH2COCH2C(CH3)2OH + H2 Ni Catalyst
Catalyst
C9H14O + 2 H2 C9H18O
Catalyst
C9H14O + H2 C9H16O
MIBK
Catalyst
CH3(CO)CH=C(CH3)2 + H2 CH3(CO)CH2CH(CH3)2
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
MIBC
Catalyst
CH3(CO)CH2CH(CH3)2 + H2 CH3CHOHCH2CH(CH3)2
DIBC
Catalyst
(CH3)2CHCH2(CO)CH2CH(CH3)2 + H2 (CH3)2CHCH2CHOHCH2CH(CH3)2
Benzyl Acetone
C10H10O + H2 C10H12O
VENT GAS
RM HYDROGEN GAS
REACTION
CATALYST
CATALYST RECYCLE
FILTRATION
0.00
DISTILLATION
HBs (HW) OFF SPEC PRODUCT
HYDROGENATED
PRODUCT
3,5 Dimethyl Phenol is prepared by thermal cracking of Isophorone. The process is carried out in
4 steps. Step 1 includes the thermal cracking of Isophorone in presence of a metallic catalyst.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Step 2 involves distillation to remove the Impurities formed during cracking. Step 3 involves
extraction of the product from the crude mass. Step 4 consists of final product purification to
meet the quality requirements
O OH
CH3
+ CH4
H3C CH3 H3C CH3
isophorone 3,5-dimethylphenol
EXTRACTION
DISTILLATION 2
DISTILLATION 3
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
H3C CH C CH3 CH CH CH
CH2 CH3
+ 2H2O
CH3
2-methylpentane-2,4-diol
4-methyl1,3-pentadiene
MPD Plant
HG REACTION ACID
TO ETP WASHING
MPD PRODUCT
11) Bisphenol-S
Bisphenol-S is prepared by the reaction of phenol with Sulphuric Acid. Phenol is reacted with
Sulphuric Acid in presence of a catalyst to form Bisphenol-S. The product is then distilled from
the crude mass after washing.
OH
HO OH
2 + H2SO4 O
phenol O
Bisphenol-S
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
CATALYST
TO ETP WASHING
BISPHENOL-S
Lubricant Additives used in Hydraulic & Gear Oil Packages are generally prepared by mixing of
multiple grades of additives (ZDDP & Ashless additives). It is simply a blending process with
addition of base oils and other additives to form packages for Hydralic Oil & Gear Oil
applications
13) Sodium Dithiophosphate
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
SDDP Reactions:
Reaction 1:
SH
o
(95–100 C)
4 R-OH + P2S5 2(RO)2-P=S + H2S
Reaction 2:
SH S-Na
3.87
H2S Scrubber NaHS (30%)
8.35
Optional Draw
DDP ACID PRODUCT Reaction
Alcohol 39.85
60.71 To Flare
0.0387
21.99 16.00
NaOH Neutralization Base Oil
98.70
1.00
Drying Alcohol (Recovered)
97.70
Base Oil 3.00
Filter Aid 0.60
Mixing
101.30
SDDP Product
100.00
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
Benzylidene Acetone
1.00
CATALYST
TO ETP WASHING
166.88
52.50 202.50 65.625
BENZYLIDENE
ACETONE
100.00
16) PIBSA
17) PIBSI
PIBSA on further reaction with a polyamine forms Polyisobutylene succinimide (PIBSI)
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
NaOH (10%)
PPS
Optional Draw
DDP ACID PRODUCT Reaction
Alcohol
To Flare
Base Oil
Mixing
Ashless Additive
22) Resorcinol
Resorcinol can be manufactured by various routes. We have selected the manufacture of
Resorcinol by Hydroperoxidation of m-Diisopropylbenzene (m-DIPB). M-DIPB is oxidized in a
bubble column reactor to form the hydroperoxide mixture containing Dihydroiperoxide (DHP,
Ketohydroperxide (KHP) & Hydroxyhydroperoxide (HHP). The mixture undergoes extraction to
maximize the DHP concentration. This DHP then undergoes Cleavage to form Resorcinol &
Acetone. The reaction mass is then distilled to obtain pure Resorcinol & Acetone in a series of
distillation columns.
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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra
DIPB AIR
OXIDATION
WATER
CLEAVAGE
TO ETP
59