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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Pre-Feasibility Report

For

Proposed Expansion of Synthetic Organic Chemicals


Manufacturing unit

By

PRASOL CHEMICALS PRIVATE LIMITED

Project under – Activity 5(f)

Category - A

Prepared By

M/s Prasol Chemicals Private Limited


Survey No. 8,13,15,16,25,75,
Tal : Khalapur, Dist: Raigad
Maharashtra, India
Web: prasolchem.com

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Table of Contents

1 EXECUTIVE SUMMARY ............................................................................................................................. 4


2 INTRODUCTION OF THE PROJECT ............................................................................................................. 7
IDENTIFICATION OF THE PROJECT AND PROJECT PROPONENT ........................................................................ 7
BRIEF DESCRIPTION OF NATURE OF THE PROJECT ......................................................................................... 7
NEED OF THE PROJECT AND ITS IMPORTANCE TO THE COUNTRY AND/OR REGION ............................................ 9
DEMAND – SUPPLY GAP ................................................................................................................................ 9
IMPORTS VS INDIGENOUS PRODUCTION ............................................................................................................ 9
EXPORT POSSIBILITY ..................................................................................................................................... 9
DOMESTIC / EXPORT MARKET ........................................................................................................................ 9
EMPLOYMENT GENERATION (DIRECT AND INDIRECT) DUE TO THE PROJECT ............................................................ 10
3 PROJECT DESCRIPTION ........................................................................................................................... 11
TYPE OF PROJECT ....................................................................................................................................... 11
LOCATION ................................................................................................................................................ 12
DETAILS OF ALTERNATIVE SITES..................................................................................................................... 14
SIZE OR MAGNITUDE OF OPERATION .............................................................................................................. 14
PROJECT DESCRIPTION WITH PROJECT DETAILS ................................................................................................. 15
RAW MATERIAL REQUIRED ........................................................................................................................... 15
RESOURCE OPTIMIZATION ............................................................................................................................ 18
WATER, ENERGY / POWER AVAILABILITY AND SOURCE ...................................................................................... 18
Water ..................................................................................................................................................19
Energy .................................................................................................................................................19
Power ..................................................................................................................................................20
WASTE GENERATION, MANAGEMENT AND DISPOSAL ........................................................................................ 20
Waste water .......................................................................................... Error! Bookmark not defined.
Non-Hazardous waste –......................................................................................................................21
Hazardous waste - ..............................................................................................................................21
AIR EMISSIONS:..................................................................................................................................................... 21
MANPOWER ............................................................................................................................................. 22
SCHEMATIC OF EIA PURPOSE ....................................................................................................................... 22
4 SITE ANALYSIS ........................................................................................................................................ 24
CONNECTIVITY .......................................................................................................................................... 24
LAND FORM, LAND USE AND LAND OWNERSHIP................................................................................................ 24
TOPOGRAPHY (ALONG WITH MAP) ................................................................................................................ 24
EXISTING LAND USE PATTERN........................................................................................................................ 24
EXISTING INFRASTRUCTURE .......................................................................................................................... 24
GEOLOGY AND SOIL CHARACTERISTICS............................................................................................................ 24
CLIMATE DATA FROM SECONDARY SOURCES .................................................................................................... 28
SOCIAL INFRASTRUCTURE AVAILABLE .............................................................................................................. 29
5 PLANNING BRIEF .................................................................................................................................... 30
PLANNING CONCEPT................................................................................................................................... 30
POPULATION PROJECTION ........................................................................................................................... 30
LAND USE PLANNING .................................................................................................................................. 30
ASSESSMENT OF INFRASTRUCTURE DEMAND (PHYSICAL AND SOCIAL)................................................................... 30
AMENITIES / FACILITIES ............................................................................................................................... 30
6 PROPOSED INFRASTRUCTURE ................................................................................................................ 31
INDUSTRIAL AREA (PROCESSING AREA)........................................................................................................... 31
RESIDENTIAL AREA (NON-PROCESSING AREA) ................................................................................................... 31
GREEN BELT ............................................................................................................................................. 31

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

SOCIAL INFRASTRUCTURE ............................................................................................................................ 31


CONNECTIVITY .......................................................................................................................................... 31
DRINKING WATER MANAGEMENT .................................................................................................................. 31
SEWERAGE SYSTEM .................................................................................................................................... 31
INDUSTRIAL WASTE MANAGEMENT ................................................................................................................ 32
SOLID WASTE MANAGEMENT........................................................................................................................ 32
POWER REQUIREMENT AND SUPPLY / SOURCE ................................................................................................. 32
7 REHABILITATION & RESETTLEMENT PLAN .............................................................................................. 33
8 PROJECT SCHEDULE AND COST ESTIMATES ............................................................................................ 34
LIKELY DATE OF START OF CONSTRUCTION AND LIKELY DATE OF COMPLETION ......................................................... 34
ESTIMATED PROJECT COST ........................................................................................................................... 34
9 ANALYSIS OF THE PROPOSAL (FINAL RECOMMENDATION) .................................................................... 35

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

1 EXEC UT IV E SU MMA RY

Prasol Chemicals Private Limited (Prasol), form an integral part of the global chemical
industry. Prasol is an ISO 9001:2008, ISO 14001:2004 and an OHSAS
18001:2007 certified company that is well aligned with its vision "To become a premier
manufacturer of Specialty Chemicals and to provide Technical Services globally." Prasol
is also A credit rated by SMERA.

Prasol has its own Research and Development and Manufacturing unit, with production
facilities for Phosphorous Based, Acetone Based and Hydrogenated products, situated at
Khopoli in Raigad district, Maharashtra state.

Prasol is prevalent in various sectors spanning Paints, Coatings, Thinners, Flavors &
Fragrances, Agrochemicals, Lubricant Additives, Surfactants, Cosmetics and
Pharmaceutical Industries.

Prasol’s global reach spans 45 countries along with local presence through multiple
dedicated distribution channels across India.

With a team strength of over 400 employees, Prasol enforces the belief of "Customer
first, Reputation first", through technical support and after sales service.

Prasol has established aggressive growth plans for its business with a well-defined
pathway for the next several years. Lead by a strong and enthusiastic team of
technocrats, the company is well underway in executing plans for organic growth in the
near & medium term.

A few areas were considered in and around Maharashtra and found the existing plot
most suitable due to its availability and proximity from the company’s existing
manufacturing facility.

The site has obtained Prior Environment Clearance in past in the year 2014 for its
expansion.

Plot area for the site is 68,644 m2.

Total cost of the expansion project will be approx. Rs. 50.0 Crores (based on present
rates).

The total design capacity of the plant for various products will be 153,000 MTA (~ 510
TPD) on the basis of running the plant for 24 hrs., a day, seven days a week and 300
days / annum. The balance 65 days will be utilized for product change-over preparation
and annual maintenance shutdown.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

It is proposed to manufacture various inorganic and synthetic organic products.

The 7/12 or Land ownership document is attached at Annexure I

The Google image of the plot site is presented at Annexure – II

Proposed Layout Plan for new establishment is attached as Annexure–III.

Prior Environmental Clearance is mandated by Ministry of Environment and Forests, as


vide EIA Notification SO 1533, dated September 14, 2006 and its amendments. This
project falls under Project activity 5 (f) and Category A.

The project brief is summarized in the table below Project summary at a glance

Table : Brief Project summary


Sr No Particulars Details
1 Name of Company Prasol Chemicals Private Limited
2 Products Refer section 2 (Introduction of the project)
3 Location Survey No. 8,13,15,16,25,75 Tal. Khalapur,
Dist Raigad.
4 Name of the project Expansion of Synthetic Organic Chemicals
Manufacturing Facility
5 Total land area of the plot 68,644 sq m
6 Raw material Refer section 3.6
7 Water (estimate / Source) Existing – 710 cmd
Proposed additional – 430 cmd
Total – 1140 cmd
Source of supply: Patalganga River Water
(Permit Obtained)
8 Power Requirement / Existing – 2900 KVA
Source Proposed additional – 2000 KVA
Total – 4900 KVA
Source : MSEDCL and captive generation
9 Manpower Existing - (Permanent + Contract) = 400 Nos
Proposed: (Permanent + Contract) = 110 Nos
Total (Permanent + Contract) = 510 Nos
10 Wastewater generation Total wastewater generation post expansion n
(estimate) 391 cmd. (Domestic + trade effluent)
Wastewater will be treated at site and will be
totally recycled.
11 Air emissions Refer section 3.9 below
12 Solid Waste Refer section 3.9 below
13 Project cost (estimate) Estimate – 5,000 Lakhs

The Land shall be used as “Industrial” land thus there shall be no change in land use.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Existing Unit has all basic infrastructure like Electrical Power, water supply, the internal
road network, external approach road and networking with CHWSTDF (Common
Hazardous Waste Storage Treatment and Disposal Facility).

There is no sensitive establishment in the vicinity such as health resort, hospital,


archaeological monuments, sanctuaries, etc.

The land and infrastructure is available for the existing unit and the raw material is
easily available through the easy transport via road connectivity by local suppliers as
well as imported one.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

2 INT RODUCT IO N OF TH E PROJ ECT

Identification of the Project and Project Proponent


Prasol Chemicals Private Limited (PCPL) is one of the leading & fastest growing
chemical manufacturing companies in India. Incorporated in 1992, the manufacturing of
unsaturated polyester resins was commissioned. In the year 1995, Prasol Chemicals
became a deemed public limited company and set up a manufacturing unit at Khopoli
near Mumbai, India.

PCPL is an ISO 9001: 2008, ISO 14001: 2004 and an OSHAS 18001:2007 certified
company. PCPL has an in-house R&D and manufacturing facility, with production plants
for Phosphorous based, Acetone based and hydrogenated products, situated at Khopoli,
with their own warehouse for storage and distribution of specialty chemicals.
The total occupied area at Khopoli is 16.96 Acres (around 68,644 sq. meters) with
production plants for Phosphorous Pentasulphide, Diacetone Alcohol, Isophorone,
Mesityl Oxide, Lubricant Additives, Phenol – Acetone and various Hydrogenated
Products.

PCPL is prevalent in various sectors spanning Paints, Coatings, Thinners, Flavours &
Fragrances, Agrochemicals, Lubricant Additives, Surfactants, Cosmetics, and
Pharmaceutical Industries.

PCPL’s global reach spreads over 45 countries along with local presence in India
through multiple dedicated distribution channels.

PCPL has established aggressive growth plans for its business with a well-defined
pathway for the next several years. Lead by a strong and enthusiastic team of
technocrats, the company is well underway in executing plans for organic growth in the
near & medium term.

Brief Description of nature of the Project


Proposed project is a Expansion project consisting of manufacturing of Synthetic
Organic Chemicals which will be widely used in several different applications.

List of Proposed Products and Production Capacity


Existing Proposed
Total
(*) Additional
S. No. Products / By Products Capacity
Capacity Capacity
(MT/Year)
(MT/Year) (MT/Year)
Products
1 Diacetone Alcohol 9,000 23,000 32,000
2 Nonyl Phenol 720 30 750
3 Phosphorous Pentasulphide 6,000 4,000 10,000

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

4 Phosphorous Acid Food Grade 600 0 600


5 Phosphorous Pentoxide 500 0 500
6 Dil. Phosphorous Acid 624 26 650
7 Isophorone 3,600 8,400 12,000
8 Phenol 20,000 0 20,000
9 Acetone 12,000 3,000 15,000
10 Zinc Diorgano Dithiophosphate 1,500 2,000 3,500
11 Mesityl Oxide 750 2,250 3,000
Hexylene Glycol, Trimethyl 1,800 13,200 15,000
12 Cyclohexanol, Trimethyl
Cyclohexanone,
13 Methyl Isobutyl Ketone 0 5,000 5,000
14 Methyl Isobutyl Carbinol 0 3,000 3,000
15 Di-isobutyl Ketone 0 1,500 1,500
16 Di-isobutyl Carbinol 0 1,000 1,000
17 Cumene Hydroperoxide 0 5,000 5,000
18 3,5 Dimethyl Phenol 0 3,000 3,000
19 Methyl Pentadiene 0 2,000 2,000
20 Bisphenol-S 0 3,000 3,000
Lubricant Additives (Hydraulic
21 0 500 500
Packages/ Gear Oil Packages etc.)
22 Sodium Dithiophosphate 0 500 500
23 Sodium Dialkyl Dithiophosphate 0 500 500
24 Benzylidene Acetone 0 800 800
25 Benzyl Acetone 0 500 500
26 Dialkyl Dithiophosphoric Acid 0 500 500
27 PIBSA 0 1,500 1,500
28 PIBSI 0 750 750
29 Phosphate Esters 0 500 500
30 Amine Phosphates 0 300 300
31 Carbazole Esters 0 1,500 1,500
32 Ashless Lubricant Additive 0 300 300
33 Resorcinol 0 3,000 3,000
34 Dicumyl Peroxide 0 500 500
35 Cumyl Alcohol 0 250 250
Research and Development
36 - - -
activities with Pilot Plant
Sub Total (Products) 57,094 91,306 148,400
By-Products
1 Di-Nonyl Phenol 60 0 60

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

2 Alpha Methyl Styreme (AMS) 1,500 0 1,500


3 Acetophenone (ACP) 800 0 800
Sodium Hydrogen Sulphide
4 0 2000 2,000
(NaHS)
5 Dicarbinol 0 240 240
Sub Total (By Products) 2,360 2,240 4,600
Grand Total (Products + By
59,454 93,546 153,000
products)
* As per existing consent to operate order no. Format 1.0/BO/CAC-cell/UAN No 0000016852/R/8th CAC –
1903001491 dated 26.03.2019 valid till 30.06.2021.

Need of the Project and Its Importance to the country and/or


Region
All the products proposed above are imported to India on a regular basis. The quantum
of imports varies from product to product, but the manufactured goods will be import
substitutes.

Amongst the products proposed, hydrogenated products, Phosphorus Pentasulphide


and ZDDP are already being manufactured at the company’s current facility near
Khopoli, Dist: Raigad, Maharashtra.

The additional products proposed are forward integration of the company’s current
products and have a great demand both global and domestic. The demand is envisaged
to increase rapidly in the domestic market.

Demand – Supply gap


All the products Manufactured and proposed to be manufactured are being imported in
the country and have a high demand in the domestic markets

Imports vs indigenous production


Currently India is a net importer of all the products proposed and thus the proposed
expansion can lead to reduced foreign exchange and open opportunities in the domestic
markets for other downstream products

Export Possibility
The products can be exported thus leading to forex revenues for the country

Domestic / Export market


All the products Manufactured and proposed to be manufactured are being imported in
the country and have a high demand in the domestic markets. The demand is also high
in the export market and can be catered to with the proposed expansion

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Employment Generation (Direct and indirect) due to the project


During the construction phase around 60 workers and during the operational phase
around 110 workers including contractors will be required. Local skilled and semi-
skilled workers will be engaged during construction phase. The positives impact
includes enhanced direct employment for technical/ administrative works and indirect
employment opportunities for transporters of raw materials and finished goods and
downstream industries.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

3 PROJ ECT DESC RIPT ION

Type of Project
(Including interlinked and interdependent projects, if any)

The project is for manufacture of Prosperous based Chemicals as follows,

Existing Proposed
Total
Capacity Additional
S. No. Products / By Products Capacity
(*) Capacity
(MT/Year)
(MT/Year) (MT/Year)
Products
1 Diacetone Alcohol 9,000 23,000 32,000
2 Nonyl Phenol 720 30 750
3 Phosphorous Pentasulphide 6,000 4,000 10,000
4 Phosphorous Acid Food Grade 600 0 600
5 Phosphorous Pentoxide 500 0 500
6 Dil. Phosphorous Acid 624 26 650
7 Isophorone 3,600 8,400 12,000
8 Phenol 20,000 0 20,000
9 Acetone 12,000 3,000 15,000
10 Zinc Diorgano Dithiophosphate 1,500 2,000 3,500
11 Mesityl Oxide 750 2,250 3,000
Hexylene Glycol, Trimethyl 1,800 13,200 15,000
12 Cyclohexanol, Trimethyl
Cyclohexanone,
13 Methyl Isobutyl Ketone 0 5,000 5,000
14 Methyl Isobutyl Carbinol 0 3,000 3,000
15 Di-isobutyl Ketone 0 1,500 1,500
16 Di-isobutyl Carbinol 0 1,000 1,000
17 Cumene Hydroperoxide 0 5,000 5,000
18 3,5 Dimethyl Phenol 0 3,000 3,000
19 Methyl Pentadiene 0 2,000 2,000
20 Bisphenol-S 0 3,000 3,000
Lubricant Additives (Hydraulic
21 0 500 500
Packages/ Gear Oil Packages etc.)
22 Sodium Dithiophosphate 0 500 500
23 Sodium Dialkyl Dithiophosphate 0 500 500
24 Benzylidene Acetone 0 800 800

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

25 Benzyl Acetone 0 500 500


26 Dialkyl Dithiophosphoric Acid 0 500 500
27 PIBSA 0 1,500 1,500
28 PIBSI 0 750 750
29 Phosphate Esters 0 500 500
30 Amine Phosphates 0 300 300
31 Carbazole Esters 0 1,500 1,500
32 Ashless Lubricant Additive 0 300 300
33 Resorcinol 0 3,000 3,000
34 Dicumyl Peroxide 0 500 500
35 Cumyl Alcohol 0 250 250
Research and Development
36 - - -
activities with Pilot Plant
Sub Total (Products) 57,094 91,306 148,400
By-Products
1 Di-Nonyl Phenol 60 0 60
2 Alpha Methyl Styreme (AMS) 1,500 0 1,500
3 Acetophenone (ACP) 800 0 800
4 Sodium Hydrogen Sulphide (NaHS) 0 2000 2,000
5 Dicarbinol 0 240 240
Sub Total (By Products) 2,360 2,240 4,600
Grand Total (Products + By
59,454 93,546 153,000
products)
* As per existing consent to operate order no. Format 1.0/BO/CAC-cell/UAN No 0000016852/R/8th CAC –
1903001491 dated 26.03.2019 valid till 30.06.2021.

Location
(Map showing general location, specific location, and project boundary and
project site layout) with co ordinates

The proposed project site is at Honad, Chinchawli Gohe, Thanenhave, Dheku,


Tembhewadi Group Grampanchayat, Taluka Khalapur, Dist Raigad.

Raigad District map showing proposed expansion project site location.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Raigad District

Prasol Chemicals
Private Limited
Location

Details of Nearest Infrastructure Facilities


Sr. No. Particulars Details
1. Group Gram Panchayat Honad, Chinchawli Gohe, Thanenhave, Dheku,
Tembhewadi
2. Taluka Khalapur
3. District Raigad
4. Latitude Latitude: 180 46’ 34.90” N
5. Longitude Longitude: 730 18’10.60" E
6. Nearest water bodies Patalganga River
7. Nearest Highway Mumbai Pune Expressway
8. Nearest Railway station Khopoli
9. Nearest Airport/ Airbase Mumbai

The project expansion is proposed at Survey No. 8,13,15,16,25 and 75, Tal. Khalapur,
Dist Raigad.

The Geographical Location of this plot is at Latitude 18° 46’ 34.90” N and 73° 18' 10.60"
E with an elevation of 60 meter above sea level MSL.

Site coordinates are as follows:


Location Latitude Longitude
marked
A 18°46'38.09"N 73°18'7.86"E
B 18°46'36.96"N 73°18'12.79"E
C 18°46'30.97"N 73°18'12.36"E
D 18°46'30.29"N 73°18'7.24"E
E 18°46'24.17"N 73°18'6.51"E
F 18°46'21.60"N 73°18'10.93"E
G 18°46'23.81"N 73°18'11.60"E
H 18°46'22.35"N 73°18'15.38"E
I 18°46'18.30"N 73°18'11.41"E

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

J 18°46'22.80"N 73°18'3.21"E
K 18°46'24.86"N 73°18'5.20"E
L 18°46'31.39"N 73°18'4.28"E
M 18°46'34.86"N 73°18'8.78"E

GPS Location on Google Imagery of the proposed site is attached as Annexure I.

Land Form: Land is on plain contour; it is flat terrain.

Land Ownership: Land ownership is with project proponents (Prasol Chemicals


Private Limited).

Existing Land use Pattern: The Land is for Industrial use & the proposed expansion
project shall be at the same plot.

Existing Infrastructure: Presently there is an existing Infrastructure around the site.

Infrastructure like water, electricity, communication/telephone facility, roads already


available. Other Infrastructure like, hospital, school, housing, entertainment, daily needs
are available easily at nearby Khopoli Town (Which is at distance of about 7 km).

• There is no sensitive establishment in the vicinity such as health resort, hospital, and
archaeological monuments.

Refer Annexure III for the proposed plant site layout plan.

Details of Alternative sites


(Sites considered and the basis of selecting the proposed site, particularly the
environmental considerations gone into should be given)

No alternative site examined as the proposed expansion will be integrated with existing
manufacturing site.

Size or magnitude of operation


Plot area of the project consists of ~ 68,644 m2 area.

The design capacity of the plant as given in the table below will be on the basis of
running the plant for 24 hrs., a day, seven days a week and 300 days / annum. The
balance 65 days will be utilized for product change-over preparation and annual
maintenance shutdown.

It is proposed to manufacture Synthetic Organic Chemicals which will be widely used in


several different applications.

Details of all the proposed products are listed in 3.1 above.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Project description with Project details


(A schematic diagram / flow chart showing the project layout, components of the project etc
should be given)

Proposed products, Brief description, Process Chemistry, Process Block diagram are
given at Annexure V.

Raw material required


(Raw materials along with estimated quantity, likely source, marketing area of final product/s,
mode of transport of raw material and finish products.)

Raw Materials:
The basic raw material for the product capacity is submitted herein below.

Source for Raw Material Procurement: Raw Material is easily available in the local
market.

Mode of Transport of Raw Materials: Few of the raw materials will be transported
locally and few will be imported from the International Market. Mode of transport to
site is by road truck/tankers.

Table: List of Raw Material required

Name of Raw Consumption Physical Means of


S. No. Source
Material (MTPA) State Storage
Imports /
1 Acetone 50,000 L Tanks/Drums
Local
2 Caustic 1,500 S/L Bags/ Tanks Local
3 Phosphorus 3,500 S Tanks/Drums Imports
4 Sulphur 8,000 S/L Bags/ Tanks Local
Imports /
5 Cumene 28,000 L Tanks
Local
6 ZnO 400 S Bags Local
7 Sulphuric Acid 1,500 L Tanks Local
8 Di-isopropyl Benzene 4,500 L Tanks/Drums Local
9 Benzaldehyde 650 L Tanks Local
Cylinder
10 Hydrogen 300 G Local
Banks
11 Polyisobutylene 430 L Tanks Local
12 Maleic Anhydride 120 L Tanks Local
13 Ethyl Acrylate 800 L Tanks Local
14 Phosphorus Pentoxide 500 S Bags Local
15 Methanol 2,000 L Tanks Local
16 Ethanol 2,000 L Tanks Local

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

17 Isopropanol 2,000 Tanks L Local


18 N-Butanol 2,000 Tanks L Local
19 Isobutanol 2,000 Tanks L Local
20 Pentanol 2,000 Tanks L Local
21 Octanol 2,000 Tanks L Local
22 Oleyl Amine 200 Tanks L Local
23 C12 Alcohol 100 Tanks L Local
24 C14 Alcohol 100 Tanks L Local
25 Methyl Acrylate 100 Tanks L Local
26 Carbazole Powder 100 Bags S Local
NOTE: *RM requirement can be on the basis of the grade of ZDDP manufactured, the
figure indicates maximum quantity per annum

Proposed bulk storages at site shall be as follows for finished goods and raw
materials

Finished product storage details,


Bulk
Physical Storage Means of
S. No. Products / By Products
State Capacity Storage
(MT)
Products
1 Diacetone Alcohol Liquid 1,000 Tanks / Drums
2 Nonyl Phenol Liquid 40 Tanks / Drums
Solid/
3 Phosphorous Pentasulphide 300 Silo / Tote Bins
Powder
Phosphorous Acid Food
4 Liquid 40 Tanks / Drums
Grade
Solid/
5 Phosphorous Pentoxide 40 Drums / Bags
Powder
6 Dil. Phosphorous Acid Liquid 40 Tanks / Drums
7 Isophorone Liquid 300 Tanks / Drums
8 Phenol Liquid 300 Tanks / Drums
9 Acetone Liquid 1,000 Tanks / Drums
Zinc Diorgano
10 Liquid 150 Tanks / Drums
Dithiophosphate
11 Mesityl Oxide Liquid 100 Tanks / Drums
Hexylene Glycol, Trimethyl 300 Tanks / Drums
12 Cyclohexanol, Trimethyl Liquid
Cyclohexanone,
13 Methyl Isobutyl Ketone Liquid 100 Tanks / Drums
14 Methyl Isobutyl Carbinol Liquid 40 Tanks / Drums
15 Di-isobutyl Ketone Liquid 40 Tanks / Drums
16 Di-isobutyl Carbinol Liquid 40 Tanks / Drums

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

17 Cumene Hydroperoxide Liquid 40 Tanks / Drums


18 3,5 Dimethyl Phenol Liquid 50 Tanks / Drums
19 Methyl Pentadiene Liquid 40 Tanks / Drums
Solid/
20 Bisphenol-S 40 Silo / Bags
Powder
Lubricant Additives
21 (Hydraulic Packages/ Gear Oil Liquid 40 Tanks / Drums
Packages etc.)
22 Sodium Dithiophosphate Liquid 20 Tanks / Drums
Sodium Dialkyl
23 Liquid 20 Tanks / Drums
Dithiophosphate
24 Benzylidene Acetone Liquid 20 Tanks / Drums
25 Benzyl Acetone Liquid 20 Tanks / Drums
26 Dialkyl Dithiophosphoric Acid Liquid 20 Tanks / Drums
27 PIBSA Liquid 40 Tanks / Drums
28 PIBSI Liquid 40 Tanks / Drums
29 Phosphate Esters Liquid 40 Tanks / Drums
30 Amine Phosphates Liquid 40 Tanks / Drums
31 Carbazole Esters Liquid 40 Tanks / Drums
32 Ashless Lubricant Additive Liquid 40 Tanks / Drums
33 Resorcinol Liquid 100 Tanks / Drums
34 Dicumyl Peroxide Liquid 30 Tanks / Drums
35 Cumyl Alcohol Liquid 10 Tanks / Drums
By-Products
1 Di-Nonyl Phenol Liquid 10 Tanks / Drums
2 Alpha Methyl Styreme (AMS) Liquid 40 Tanks / Drums
3 Acetophenone (ACP) Liquid 20 Tanks / Drums
Sodium Hydrogen Sulphide
4 Liquid 30 Tanks / Drums
(NaHS)
5 Dicarbinol Liquid 10 Tanks / Drums

Raw material storage details,

Bulk Storage
Physical Means of
S. No. Name of Raw Material Capacity
State Storage
(MT)

1 Acetone L 1800 Tanks/Drums


2 Caustic S/L 50 Bags/Tanks
3 Phosphorus S 100 Tanks/Drums
4 Sulphur S/L 200 Bags/Tanks
5 Cumene L 1000 Tanks
6 ZnO S 10 Bags

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

7 Sulphuric Acid L 50 Tanks

8 Di-isopropyl Benzene L 100 Tanks/Drums

9 Benzaldehyde L 30 Tanks
10 Hydrogen G 5000 NM3 Cylinder banks
11 Polyisobutylene L 20 Tanks

12 Maleic Anhydride L 10 Tanks

13 Ethyl Acrylate L 30 Tanks

14 Phosphorus Pentoxide S 40 Bags

15 Methanol L 40 Tanks
16 Ethanol L 40 Tanks
17 Isopropanol L 40 Tanks
18 N-Butanol L 40 Tanks
19 Isobutanol L 40 Tanks
20 Pentanol L 40 Tanks
21 Octanol L 40 Tanks

22 Oleyl Amine L 20 Tanks

23 C12 Alcohol L 20 Tanks


24 C14 Alcohol L 20 Tanks
25 Methyl Acrylate L 10 Tanks
26 Carbazole Powder S 5 Bags

Resource optimization
(Recycling and reuse envisaged in the project, if any, should be briefly outlined)

Prasol Chemicals Private Limited intends to expand the manufacturing capacity of


products. The resource optimization shall be carried out at the site and with other
Prasol sites in order to reduce wastage and minimum transport needs.

Water, Energy / Power availability and source


(Availability of water, its source, Energy/power and requirement and source should
be given)

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Water

The total water requirement is for domestic, process, Boiler and cooling and greenery
maintenance purpose.

The source of water shall be from Patalganga River, permit for which has been
obtained by the company. Water requirement for proposed establishment is
tabulated as below:

Table : Fresh Water requirement


No Purpose Existing, Proposed additional, Total, cmd
cmd(*) cmd
1 Domestic 27 8 35
2 Industrial
2.1 Industrial cooling / boiler feed 644 380 1018
2.2 Industrial processing 39 24 63
2.3 Gardening 0 18 18
Grand Total 710 430 1140
* As per existing consent to operate order no. Format 1.0/BO/CAC-cell/UAN No 0000016852/R/8th CAC –
1903001491 dated 26.03.2019 valid till 30.06.2021 and Consent to Establish order No Format 1.0/BO/CAC-
cell/UAN No 0000043168/E/5th CAC – 1903000367 dated 07.03.2019 valid till commissioning of the unit or
upto 5 years whichever is earlier.

Energy

Steam/Process heat Requirement: Co-Generation Plant shall be sufficient for the


Steam/Heat energy requirement of the proposed expansions.

Existing and proposed fuel requirement, APC system and stack details are as follows,

Sr Stack attached to APC System Height in Type of Fuel Quantity


No meter and UoM
Existing
1 Boiler – 2 and 3 (3 and 8 TPH) Mechanical dust 25 Imported coal 900 and
collector, bag (common) 2000 kg/hr
filter
2 Boiler 4 (16 TPH) Mechanical dust 35 Imported Coal 3200 kg/hr
collector, bag
filter, Cyclone
separator
3 Boiler 5 (10 TPH) Mechanical dust 35 Imported Coal 2000 kg/hr
collector, bag
filter,
4 Thermic Fluid Heater - 1 Mechanical dust 30 Imported Coal 400 kg/hr
collector, bag
filter,
5 Thermic Fluid Heater – 2 Mechanical dust 35 Imported Coal 687 kg/hr
collector, bag
filter, Cyclone
separator
6 Zinc Di Organo Alkaline 12 - -
Dithiophosphate plant scrubber

19
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

7 Phosphorus Pentasulphide Alkaline 11 - -


plant scrubber
8 DG set (250 KVA) Acoustic 3.6 above HSD 27.5 Lit/hr
enclosure roof
9 DG set (380 KVA) Acoustic 3.6 above HSD 35 Lit/hr
enclosure roof
10 Boiler (38 TPH for power ESP 47 Low ash 5625 kg/hr
generation of 5 MW) (#) Imported Coal
Proposed
11 Boiler 3N (5 TPH) Mechanical dust 35 Furnace Oil 255 Kg/ Hr
collector, bag (Common)
filter
12 Thermic Fluid Heater – 2N Mechanical dust 35 Furnace Oil 320 kg/hr
collector, bag
filter,
13 625 KVA (DG set) Acoustic 3.6 above HSD 125 Lit/hr
enclosure roof
Note: (a) (#) 38 TPH boiler is under construction. Once it is operational. Boilers mentioned in Sr
No. 2 and 3 i.e. 16 TPH and 10 TPH will be standby.
(b) Sr No 1 boiler (3 and 8 TPH- coal fired) operation will be discontinued once Sr No 11 boiler (5
TPH – Oil fired) is installed.
(c) Sr No 5 TFH (coal fired) operation will be discontinued once Sr No 12 TFH (Furnace oil fired)
is installed.

Power

Existing Co-Generation Plant (of capacity 5 MW) shall be sufficient for the Power
requirement of the proposed expansion.

DG Set:

Additional 1 DG sets of 625 KVA capacity is proposed to be installed at this site.

Its fuel requirement (only in case of emergency) shall be as follows:

Sr Capacity Nos Fuel requirement Source


No
1 625 KVA 1 125 lit/hr (HSD) From local depot
(emergency use only) /supplier

Waste generation, Management and disposal


(Quantity of waste to be generated (liquid and solid) and scheme of their management/disposal)

Wastewater

Proposed wastewater generation, treatment and disposal shall be as follows,

N Descriptio Existing, cmd Proposed Total, Treatment and Disposal


o n additional, cmd
cmd
1 Domestic 21.6 5.4 27 Domestic and Trade effluent
effluent shall be treated at site and

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

generation treated water will be


2 Trade 111.0 (Process 253 (Process 364 recycled within site. There
effluent organic 31 Organic (53 (Process will be no discharge outside.
generation cmd + cmd+ Organic (84
inorganic Inorganic 200 cmd+
effluent 80 cmd) Inorganic
cmd) 280 cmd)
Total 132.6 258.4 391
Note : 84 cmd Organic effluent (54 cmd + 30 cmd from IPH Plant).

The quantification of nonhazardous and hazardous waste estimated to be generated


from proposed expansion activities is tabulated as below:

Non-Hazardous waste –
N Waste Type UOM Existing Proposed Total Disposal
o Quantity quantity
1 Ion exchange resin TPA 1 0.5 1.5 Regenerate
2 Sand from water filtration TPA 11 6.5 17.5 CHWTSDF
3 Used cotton hand gloves Pairs per 10,000 2500 12500 CHWTSDF
annum
4 Miscellaneous Kg/annum 500 200 700 CHWTSDF
5 Fly Ash TPD 20 0 20 Sale to Brick
manufacture
r
(*) Note: Above quantities are rough estimate, will be firmed up during EIA study.

Hazardous waste -
No Waste Type Category UOM Existing Proposed Total Disposal
(as per Quantity quantity
HW rules
2016)
1 Used/Spent 5.1 KL/A 6.0 3.0 9.0 Sale to
Oil authorized
reprocessor
2 Filter residue 6.1 TPA 38.0 21.0 59.0 CHWTSDF/
3 Tar 19.1 TPA 1500 - 1500 Sale to
4 Distillation 36.1 TPA 613.2 1225 1838.2 authorized
residue reprocessor
5 Used barrels 33.1 Nos/A 6000 6000 12000 Sale to
authorized
reprocessor
6 ETP sludge 35.3 TPA 80 20 100 CHWTSDF
from WWT
7 Spent 19.2 TPA 5 15 20 CHWTSDF/
catalyst Sale to
authorized
reprocessor
(*) Note: Above quantities are rough estimate, will be firmed up during EIA study.

Air Emissions:
Environmental issues associated with proposed pesticides manufacturing, formulation
and packaging includes:

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

The principal air pollutants will be volatile organic compounds (VOCs) and particulate
matter (PM).

Likely air pollutants from proposed project shall be PM, H2S, NOx, SO2 & HC from
various (~15 m to 35 m) process vents, boiler stack and DG Sets as point source.

Adequate APC equipment like scrubbers’ stacks & vents with adequate height will be
provided. Vehicular Emissions like CO & HC’s will be generated as line source emissions.
Fugitive emissions are also envisaged from proposed project.

Manpower
Manpower: Expected manpower requirement for the establishment (during operation
phase) shall be as follows:

Description Existing, Nos Proposed additional, Nos Total, Nos


Permanent 360 80 440
Contract 40 30 70
Total 400 110 510

Schematic of EIA Purpose


(Schematic representations of the feasibility drawing which give information of EIA purpose)

Figure : Schematic representation of the feasibility drawing which gives EIA


purpose

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Project Concept and


Site identification

Form 1 with
proposed TOR to
MoEF&CC (EAC)

Scoping by EAC

EC – rejected by MoEF&CC on
TOR approved by EAC the recommendation of EAC

Draft EIA report to


SPCB/UTPCC by Summary EIA and Form I –
project proponent. display on SPCB / UTPCC website

Public Consultation
Display on process by
the MoEF&CC SPCB/UTPCC
website

Proceedings of Public Display on the


consultation SPCB/UTPCC website

To proponent for submission of


Appraisal and final EIA report / Supplementary
recommendation by report to draft EIA
EAC
Referred back to EAC under
Approval by MoEF&CC communication to the
project proponent

Rejected Approved
Submission of half Display of compliance
Post EC Monitoring yearly compliance report in MoEF&CC
report to MoEF&CC / website
Ro- MoEF&CC

23
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

4 S IT E A NALYS IS

Connectivity
The proposed expansion of Prasol Chemicals Private Limited shall be located at its
existing facility located at Survey No. 8,13,15,16,25,75, Tal Khalapur Dist Raigad,
Maharashtra. The plant facility is located at 2 km from village Honad, and 3 km from
Mumbai Pune Expressway. There is Khopoli town located on Mumbai-Pune NH4, which
is considerably better developed in terms of infrastructural facilities, education,
transport, hospital etc.

Landform, Land use and land ownership


Landform: Land is on plain contour; it is flat terrain.

Land Ownership: Land ownership is with project proponent (Prasol Chemicals Private
Limited).

Topography (along with map)


The district has three physiographic divisions i.e. (i) Coastal zone in west covers about
20% percent of the district (ii) Central zone covers about 1/3 rd of the district,
consisting of fertile land in low lying area (iii) Hilly zone in the eastern part highly
uneven in altitude and covered with forest. This hill range is characterized by
ruggedness and uneven topography, with Crestline of peaks and saddles forming the
eastern horizon. Ulhas, Panvel and Patalganga are the three main rivers in northern
part. Kundalika River is the main river in central part whereas in the southern part
Savitri River is the main river.
The soils in the district are formed from the Deccan Trap which is predominating rock
formation with small out crops of Laterite at a few places in the Poladpur taluka and
Matheran hill. The soils are grouped as Forest, Varkas, Rice, Khar or Saline, Coastal
Alluvium and Laterite as per the location and topographical situation.

Existing land use pattern


Existing land use is for industrial use owned by Prasol Chemicals Private Limited.

Existing infrastructure
Operating plant at the site.

Geology and Soil characteristics


GEOLOGY:

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

The rock of the district is trap. In the plains it is found in tabular masses a few feet
below the soil and sometimes standing out from the surface. In the hills it is tabular and
is also found in irregular masses and shapeless boulders varying from a few inches to
several feet in diameter. In many places the surface of the trap has a rusty hue showing
the presence of iron. Nala on West of the plant site is the main line of drainage which on
going further meets Patalganga river near Mumbai Pune Highway (NH – 4). This nala
has flowing water from Month of June to February. This helps in replenishment of
ground water table.
Soil Characteristics

There are four chief varieties of soil: Alluvial and Alluvia, Powdered Laterite and trap,
clayey mould resting on trap, and soil containing marine deposits with, much sand and
other matter in concretion. Of these the first, which is composed of various
disintegrated rocks of the overlying trap formation, with a varying proportion of
calcareous substances, is at once the richest and the most widespread. The soil in the
vicinity of manufacturing plant is either black soil or red soil (rich in iron). As per the
periodic soil analysis in year 2010, for area of village Honad and Khopoli, done by
Agricultural department of Govt. of Maharashtra, soil has following characteristics;
presented in table below.

Sr. No. Characteristic Observation Inference


1 pH 6.5 - 7.5 Slightly alkaline
2 Salinity (E.C) (mS/cm) 0.18 – 0.20 Average
Sr. No. Characteristic Observation Inference
3 Organic Matter (%) 1.509 – 1.51 Very High
4 Nitrogen (kg/hector) -- --
5 Sulphur (kg/ hector) 18.923 – 19.00 Below Average
6 Potassium 215.04 – 220 Average
(Source: Agricultural Dept., Govt. Maharashtra)

The district is the second largest producer of rice in the Maharashtra State. The
region is peculiarly terraced and, though the small strips in between the two terraces
are levelled, it is difficult to get even a few gunthas of land in one piece in a levelled
condition. The depth varies between two and six feet. They are loamy in texture,
yellowish or reddish grey in color, neutral in reaction and almost devoid of lime. They
are formed from the trap rock from the Sahyadri ranges under heavy rainfall and
humid climatic conditions. The linear response of rice to the application of
nitrogenous, phosphatic and potassic fertilizers is observed in these soils. Addition of
bulky manures in these soils is also found to be advantageous from the point of view

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

of yield. There are some patches of manat soils in Mangaon taluka which are rich in
clay and silt and which become stiff and hard when dry.

Khar soils.

These soils are situated on the flat, levelled land near the sea at the point of creeks
formed due to the rivers. They are flat clay to clay loam in texture and reddish or
yellowish grey in colour. These soils contain hardly more than one per cent of soluble
salts. These soils are formed due to the deposition of salts by the sea or from lands
reclaimed from the sea. Large tracts of land are going out of cultivation due to the
ingress of the sea and, in order to reclaim these lands, the Government have formed
the Khar Land Development Board which has undertaken ambitious projects of the
reclamation of khar lands.

Coastal alluvium soils.

These soils are found all along the coast and at places where there are no creeks.
They are deep soils developed on flat land and loamy in texture with reddish grey
colour. They are devoid of clay fraction or humus and are open in nature. The profile
is difficult to differentiate and is excessively drained. Calcium carbonate is found in
abundance throughout the profile but calcium has not entered the clay complex. The
sub-soil water level is only from ten to fifteen feet deep. The salt contents of the well
water are higher in the proximity of the sea; but due to excellent drainage, its use has
not produced any deleterious effects. The soils are almost neutral or slightly on the
alkaline side of neutrality. Good garden crops like coconut, areca-nut, plantain, etc.,
are grown in these soils, depending upon the availability of water.

Laterite soils.

Out-crops of laterite rock are observed amongst the Sahyadri ranges amidst the trap
rock mainly at Matheran and in the Poladpur taluka. These soils mostly occur on the
mountain peaks. They are coarser in texture, wherever there are no forests. They are
yellowish-red in colour and shallow in depth and yield coarse millets and niger. The
heavy rains in the mountainous regions thoroughly leach the soils turning them acidic
in reaction and devoid of calcium carbonate. They are rich in sesquioxides, the ratio of
silica to sesquioxides being less than two. But they are generally poor in exchangeable
bases or in fertility constituents. However, the soils from the forest region are well-
supplied with nitrogen and organic matter.
Typical soil analysis is as follows

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Description of Soils
Chemical
Coastal Salt land or
Analysis Loamy Varkas Laterite
Alluvial Khar land
(1) (2) (3) (4) (5) (6)
Yellowish Yellowish red Reddish or
Reddish
Colour to reddish to yellowish Yellowish red yellowish
grey
grey. grey. grey.
Depth 1'—3' 1' - 2' 3' — 5' 5' — 10' 5' — 10'
Per cent on
drv matter
oven
Organic matter 0.7 — 1.8 0.5 — 1.0 2.0 — 3.0 0.7 — 1.5 0.5 — 1.5
Calcium
Nil — 0.01 Trace Trace 5.0 — 10.0 0.05 — 2.00
Carbonate
Sand (Coarse
5.0 — 10.0 60.0 — 70.0 8.0 — 10.0 20.0 — 35.0 20.0 — 30.0
and fine)
Silt 30.0 — 35.0 10.0 — 15.0 40.0 — 60.0 30.0 — 40.0 25.0 — 30.0
Clay 30.0 — 40.0 10.0 — 20.0 30.0 — 40.0 15.0 — 30.0 10.0 — 20.0
Clay to Clay
Textural class Loam Sandy Sandy loam Clay loam
loam
Total soluble
0.04 — 0.05 Trace 0.02 — 0.04 Trace 1.0 — 3.0
salts
Organic carbon 0.4 — 0.9 0.27 — 0.67 1.5 — 3.0 0.4 — 1.6 0.5 — 1.05
Total Nitrogen 0.04 — 0.06 0.02 — 0.05 0.15 — 0.20 0.06 — 0.10 0.05 — 0.07
C/N 10—16 10—16 10—15 10—16 10—15
PH value 6.7 — 7.2 6.0 — 7.5 4.5 — 6.0 7.0 — 8.0 7.0 — 8.0
Mgm. per cent
drv matter
on oven
Available P205 8—10 5.10 Trace—5 10—15 10—15
Available K20 12—20 10—20 5—10 20—25 10—15
millie
equivalent
dry matter
per cent on
oven.
Exchangeable
20—25 18—25 5—10 30—35 20—30
Ca
Exchangeable
7—8 7—10 1—2 5—7 10—11
Mg
Exchangeable
0.08 — 2.0 2—3 0.01 — 0.02 2.3 7.5 — 12.0
Na
Exchangeable
0.82 — 1.0 0.44 — 0.8 1—2 0.4 — 0.6 1.2
K
Exchangeable
-- -- 4—6 -- --
H
Total
Exchangeable 30—35 40—43 15—18 35—40 20 — 35
bases
Base Exchange
20—35 40—45 19—24 35—40 30—35
Capacity

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Climate data from secondary sources


Climate and rainfall profile:

Village Honad (Raigad) being in region of Konkan the climate is warm and humid. The
relative humidity levels in this region are high throughout the year. The relative
humidity levels observed are in range of minimum 66% (Dec) to maximum 85% (July,
August, September).
The area receives rainfall for more than four months of the year, which provides main
climatic variations. Out of total rainfall 90% is experienced during Monsoon season of
months June to September. The details of monthly precipitation observed in Raigad
district are given in Table below,
Annual Rainfall Profile for Raigad District

Jan Feb Mar Apr May Jun Jul Aug Sept Oct Nov Dec
Month
Rainfall
2.5 0.8 0.5 1.8 18.8 558.5 699.5 394.7 312.2 69.6 20.1 1.8
(mm)

(Source: Raigad Gazetteer, Government of Maharashtra)

Being a coastal district the diurnal (daily) and seasonal variations of temperature are
not large. The period from March to May is one of increasing temperatures. May is the
hottest month with a mean daily maximum temperature at 31.7°C (89.1°F) and the
mean daily minimum temperature at 26.4°C (79.5°F). Fresh breezes from the sea
relieve the oppressive heat particularly in the coastal regions in the afternoons. The
onset of the south-west monsoon early in June brings down the temperatures
slightly. After the withdrawal of the south-west monsoon by the end of September
the day temperatures increase slightly and the weather in October and November is
almost like the summer months. In the period from December to February the
weather is cooler than in the post-monsoon months.
Humidity:
The air is humid throughout the year. Relative humidity is on an average over 80 per
cent during the south-west monsoon season. In the rest of the year the relative
humidity is between 65 per cent and 75 per cent.
Cloudiness:
During the south-west monsoon season skies are heavily clouded to overcast. In May
and October, the clouding is moderate. Clear or very lightly clouded skies are
common in the rest of the year.
Winds:

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Winds are very strong and blow from west or south-west during monsoon season.
During the period from October to December winds are generally moderate but
sometimes strong in October and blow from directions between north-east and
south-east. In the three months from January to March the winds continue to be
moderate and are predominantly from directions between north and east. In April
while there is a slight strengthening of wind, the direction is variable. In May there is
a further strengthening of winds and the directions are between south-west and
north-west.
Special weather phenomena:
In association with cyclonic storms in the Arabian sea in the post-monsoon months
and to a lesser extent in May, the district experiences very strong winds, sometimes
reaching gale force, particularly very near the coast and also heavy widespread rain.
Occasionally these storms may cross the coast in the northern part of the district and
cause heavy damage. Thunderstorms occur in April and May and just before the onset
of the monsoon and in the late September to the middle of November.

Social infrastructure available


Nearest town is Khopoli which is about 5 km from site towards east. Social
infrastructure such as schools, Hospitals, market place and other amenities are easily
available. Transport facilities by road are available.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

5 PL A NNING B RIEF

Planning Concept
• Existing operational unit in a well-established industrial area.
• Water supply from Patalganga River.
• Well-developed roads and connectivity.
• Integration with the existing manufacturing facility.

Population Projection
In 2011, Raigad district had population of 2,634,200 of which male and female were
1,344,345 and 1,289,855 respectively. In 2001 census, Raigad had a population of
2,207,929 of which males were 1,117,628 and remaining 1,090,301 were females.
Raigad District population constituted 2.34 percent of total Maharashtra population.

In 2001 census, this figure for Raigad District was at 2.28 percent of Maharashtra
population.

There was change of 19.31 percent in the population compared to population as per
2001. In the previous census of India 2001, Raigad District recorded increase of 20.99
percent to its population compared to 1991.

The initial provisional data released by census India 2011, shows that density of Raigad
district for 2011 is 368 people per sq. km. In 2001, Raigad district density was at 309
people per sq. km. Raigad district administers 7,152 square kilometers of areas.

Land use planning


For Industrial use

Assessment of Infrastructure Demand (Physical and social)


No major infrastructure demand is envisaged as the proposed site is in well-developed
area.

Amenities / Facilities
No major amenities / facilities demand is envisaged as the proposed site is in well-
developed area and has good site connectivity.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

6 PROPOS ED INF RASTRU CTU RE


Since the expansion is planned at existing plant site, no special/specific development is
anticipated. Company will have to do site development only. Company has not planned
any residential area.

Industrial Area (Processing area)


Prasol Chemicals Private limited, Survey No. 8,13,15,16,25,75, Tal: Khalapur, Dist:
Raigad Maharashtra, proposes to expand its existing facility for manufacture of
Synthetic Organic Chemicals manufacturing based on demand and market projection.

Residential area (non-processing area)


No Residential area is proposed within the plant site.

Green Belt
Green belt of adequate area within and around the project site shall be carried out as
per industries norms and requirement.

Social Infrastructure
Local people will be given preference wherever found suitable for all the jobs in the
plant, direct as well as indirect. Thus, the project shall have a positive impact on the
employment pattern of the region. Economic status of the local population will
improve due to increased ancillary/business opportunities, thereby making positive
impact. Educational, medical & housing facilities will improve due to the proposed
project.

Connectivity

This proposed expansion project facility shall be located at company’s existing


manufacturing area located at village Honad, in Raigad district, Maharashtra. The Site is
7 km from Khopoli town and 10 km from nearest railway Station, Khopoli. The land and
infrastructure is available and the raw material is easily available through the easy
transport via road connectivity.

Drinking water management

The total water requirement is about 1140 cmd for Domestic, boiler/cooling, Greenery
and process. The source of water shall be from Patalganga river.

Sewerage System
Refer Annexure IV for trade effluent and sewerage water treatment scheme.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Industrial waste management


Refer 3.9 above

Solid waste management


No specific infrastructure is required for the proposed expansion for solid waste
management. Refer 3.9 above for additional waste generation and its disposal
management.

Power requirement and supply / source


Power requirement shall be sourced from MSEDCL and by captive power
generation (Cogen plant of 5 MW).

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

7 REHAB IL ITAT ION & RES ET TL EMENT


PL A N
(Policy to be adopted (center/state) in respect of project affected persons including home oustees,
land oustees and landless labors (a brief outline to be given)

The proposed expansion shall be within the plot owned of the company. It does not
require acquisition of Land and the Infrastructure so there is no any kind of activity of
Rehabilitation and Resettlement to be carried out.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

8 PROJ ECT SCH ED UL E A ND COST


EST IMAT ES

Likely date of start of construction and likely date of


completion
(Time schedule of the project to be given)

It is expected that the expansion project shall be completed within 9 to 12 months from
date of grant of Environmental clearance.

Estimated project cost


(Along with analysis in terms of economic viability of the project)

Total estimated project cost is around Rs. 5000 Lacs

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

9 A NA LYS IS OF TH E PRO P O SAL (FINAL


RECOMMENDAT IO N)
(Financial and social benefits with special emphasis on the benefit to the local people including
tribal population, if any, in the area)

The proposed expansion project envisages

o For the growing domestic market and as Import substitution.

o Direct employment to locals and will prompt ancillary businesses.

o Export benefits.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Annexure – I

Attached as Additional file

Annexure – II

36
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Location of Prasol Site

Goggle image of site

Goggle image of site with 1 km radius

Goggle image of site with 10 km radius

37
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

38
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Annexure – III

Proposed Plant site layout

AREA STATEMENT
Sr No Description Area in sq m
1 Total Built up area 18,958
2 Total Green belt area 22,864
3 Total area for roads 14,215
4 Open land area 9,407
5 Total Co gen area 3,200
Total Plot area 68,644

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Annexure - IV

Proposed Effluent treatment scheme

Post expansion following quantities of effluent are expected.

• Domestic effluent – 27 cmd


• Trade effluent – 30 cmd from IPH Plant
- 54 cmd Organic effluent
- 280 inorganic effluent
Total – 391 cmd

The brief process of treatment of effluent will be as follow.

The proposed ETP will be designed to achieve “Zero Liquid Discharge”.


Treatment scheme is as below:
• Effluent will be segregate as per Low COD/ TDS & High COD/ TDS.
• High COD/TDS effluent streams will be sent to Flotation tank after
Neutralization. Sludge from filtration will be send to CHWTSDF for disposal.
• After filtration, effluent will be sent to MEE & ATFD. Permeate from MEE &
ATFD treatment will be send for Aerobic treatment. Sludge/ residue from
reject stream of MEE & ATFD will be send to CHWTSDF for disposal.
• Domestic effluent will be added in Aeration tank along with permeate stream
of MEE & ATFD for biological treatment. After Biological treatment effluent
will be send to clarifier. Active biological sludge from clarifier is send back to
aeration tank to maintain MLSS & excess will be disposed of to CHWTSDF
facility.
• After secondary clarifier effluent passed through chlorination tank followed
by Pressure sand filter/ Activated carbon filter.
• Low COD/ TDS effluent will be treated in separate mixing tank with addition
of Na2CO3 & Alum. Effluent will be passed through Multi grade sand filter to
remove suspended solids from effluent.
• The filtered effluent will be sent to RO plant to remove dissolved solids. RO
reject stream will be sent back to MEE.
• Treated effluent will be stored in Final storage tank & recycle back for
gardening/cooling tower makeup.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

PROPOSED ETP SCHEME


Effluent 1 Effluent 2 Effluent 3 In
From IPH Plant Organic organic
effluent effluent

Na2CO3
Neutralisation Neutralisation
Mixing Alum

Bottom Residue
Filtration Settling Multi grade
sand filter

Sludge to
CHWTSDF Back wash to
Clarifier
Filter press
RO reject
MEE + ATFD

Domestic Effluent Sludge to


CHWTSDF

Sludge to Biological Treatment


CHWTSDF
UF/ RO

Chlorination Secondary Clarifier Sludge to CHWTSDF


PSF/ACF

RO permeate
Final storage
Treated eff. for recycle
3

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Annexure - V

Proposed products, Brief description, Process Chemistry, Process Block diagram

1 Diacetone Alcohol

Diacetone Alcohol is produced by the Aldol Condensation of Acetone. The reaction is conducted
in the reactive distillation mode. Acetone is passed over anionic catalyst to form diacetone
alcohol after reaction. The reaction mass containing acetone and Diacetone alcohol is subjected
to distillative separation to a) recover and recycle the unreacted acetone and b) recover
diacetone alcohol in desired purities.
The product will be stored in storage vessel prior to drumming

Diacetone Alcohol

(CH3)2CO
Alcoholic Caustic Catalyst
Acetone Diacetone Alcohol

FEED ACETONE (kg) CAUSTIC + CATALYST R (KG)


106.00 0.26

REACTION RECYCLE ACETONE


742.18
848.44

CATALYST
NEUTRALIZATION
REMOVAL
0.26 848.18

FLASHER
334.13
514.05

DISTILLATION 1
385.54
128.51

DISTILLATION 2
3.01
125.50

OFF-SPEC ACETONE(KG) DISTILLATION 3 RECOVERY


22.00 25.01
3.50 100.00

DAA PRODUCT ORGANICS


2.50
100.00

2) Phosphorus Pentasulphide (PPS)

Manufacturing Process
In PPS plant, the manufacturing is done in 5 steps:

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Feed Preparation;
Reaction;
Distillation;
Flaking;
Grinding & Packaging.

Step 1: Feed Preparation

The solid Sulphur is sent to the melting tank for melting. After melting, the sulphur is sent to the
Sulphur Feed Tank for reaction. The Phosphorus is molten and stored under water in the
Phosphorus Feed Tank.
Step 2: Reaction
From feed tanks the liquid sulphur and phosphorus are fed to the reactor which is operated
under Nitrogen blanket. In the reactor a simple addition reaction takes place at high
temperatures to form Phosphorus Pentasulphide (PPS) product and then it is drained to the
intermediate tank maintained at the desired temperature to be fed to the distillation furnace.
The vapours formed (if any, during abnormal conditions) in the reactor and the intermediate
tanks are sent to the H2S scrubber attached to the ZDDP plant / DATC Plant.
Step 3: Distillation
The reaction mass is heated and the vapours are collected in the distillation pot. The vapours
are cooled in the pot and liquid PPS of 99.5% purity is obtained. Periodic maintenance shall be
done, during which sludge will be removed.
Step 4: Flaking
The distillate mass is sent to the flaker. In flaker the distillate mass is solidified over a drum
cooled with chilled water to form a thin solid layer which is scraped by a blade arrangement and
collected in the form of flakes.
Step 5: Grinding & Packaging
These flakes are then conveyed through a pin mill arrangement to obtain the product in the
required size of granules or powder. This product is then stored in Silos and packed in drums or
Tote bins as per the requirement.

Reaction involved and process flow diagram is shown below:

4P4 + 5S8 4P4S10


Phosphorus Sulphur Phosphorus
Pentasulphide (PPS)

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Phosphorus Sulphur

Figure : Block Diagram for PPS Manufacturing

Reactor

Furnace for
Distillation

Sludg
Distillation Receiver
e
Pot

Flaker

Grinding by Pin Mill

Packing of P2S5
Product

44
Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

3) Phosphoric Acid (Food Grade) / Dil. Phosphoric acid

Phosphoric Acid is prepared by addition of water (dilution) of Polyphosphoric Acid in an Agitated


Reactor. On further or excess Dilution, we get a dilute phosphorous Acid product

Phosphoric Acid

Polyphosphoric Acid Water


MIXING
85.00 15.00
100.00

PHOSPHORIC ACID
PRODUCT
100.00

Phosphoric Acid Water


MIXING
85.00 15.00
100.00

DIL. PHOSPHORIC
ACID PRODUCT
100.00

4) Isophorone
Process:

Isophorone is produced by Aldol Condensation of Acetone.

Acetone with a catalyst mixture is fed in a continuous manner to a reactive distillation column
system. The condensation reaction takes place in these reactors forming a mixture of
Isophorone, Acetone, water and other organics. The Acetone is recovered and recycled back in
the reaction section itself and is further sent for neutralization. The reaction mass, after
neutralization, is washed & and then subjected to separation by distillation process to extract
Isophorone in desired purities.

Isophorone

3 (CH3)2CO + 2H2O
Caustic Catalyst
Acetone Isophorone Water

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

0.069
CAUSTIC

155.88
ACETONE +
REACTION WATER TO ETP
WATER 110
70.16 323.44

195.726 85.726
WASHING AQ. DISTILLATION WATER FOR RECYCLE

127.7182

0.069
DISTILLATION 1 CAUSTIC RECOVERY
11.61075
116.1075

DISTILLATION 2 IPH PRODUCT


100
17.72
1.61252

RECOVERY

HEAVIES
85.726 16.10748 16.10748

5) Phenol / Acetone / Cumene Hydroperoxide (CHP) / Cumyl Alcohol (PDMC) / Dicumyl


Peroxide / Alkyl Phenols
Manufacturing of Phenol and Acetone is a two stage Cumene Peroxidation Process.
First stage is oxidation of Cumene to Cumene Hydro Peroxide (CHP) followed by
acid catalyzed decomposition (cleavage) of CHP to Phenol, Acetone, AMS,
Acetophenone, and Tar etc. Second stage consists of series of distillation operations
to separate Acetone, Phenol & other by products in stages. Firstly Acetone is
separated followed by Phenol, Final stage separates out byproducts Acetophenone
and Tar.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Phenol – Acetone (Overall reaction):

+ O2 + (CH3)2CO

Cumene Oxygen Phenol Acetone

Reaction 1:

+ O2
o
(80–110 C)
Cumene Oxygen Cumene Hydroperoxide (CHP)

Reaction 2:

H2SO4 catalyst + (CH3)2CO


o
(80–85 C)
CHP Phenol Acetone

PA Plant

CARBONATE VENT AIR (INERT)


0.30 157.47

CUMENE AIR
OXIDATION
140.00 188.50
694.10

RECYCLE CUMENE CHP CHP PRODUCT optional draw


513.82 CONCENTRATION
180.29 PDMC PRODUCT optional draw

CATALYST WATER 5
CLEAVAGE
0.42
184.13 TO ETP 1.58

ACETONE PRODUCT ACETONE PHENOL PHENOL PRODUCT 100.00


60.00 60.00 DISTILLATION 109.13 DISTILLATION 100.00
15.00 9.13

ALKYL PHENOL OLEFIN


AMS RECOVERY ACP RECOVERY
8.96 PROCESSING#
6.04 2.88

AMS PRODUCT ACP PRODUCT ALKYL PHENOL^


6.042 2.88
TAR
6.25

ALL NUMBERS IN KGS EXCEPT MENTIONED OTHERWISE


*CHP & PDMC Products can be drawn at a desirable quantity from the concentration stage as they are intermediates formed in the Oxidation reaction
#
All Alkyl Phenols will be manufactured from a Phenol Distillation stream to the desired quantity of the product mix
^Alkyl Phenols Include:
Nonyl Phenol
DiNonyl Phenol
3,5 Dimethyl Phenol

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

6) Zinc Diorgano Dithiophosphate (ZDDP) / Dialkyl Dithiophosphoric Acid

Manufacturing Process
Zinc Diorgano-DithioPhosphate (ZDDP) is manufactured in two major steps.
Step 1: Synthesis Step:
The synthesis of Oxo-Alcohols and Phosphorus Pentasulphide takes place to form a
Di-Alkyl Dithiophosphoric Acid with release of Hydrogen Sulphide gas. In this step,
the oxo-alcohols are charged into the reactor, stirred and heated. Phosphorus
Pentasulphide is added to this mass with continuous stirring which results in the
evolving of gases which are to be absorbed in the 2 stage caustic scrubber.

Step 2: Neutralization Step:


The neutralization of the acid is carried out with zinc oxide. Once neutralization is
complete, the product mass is dried. Filter aid is added and the batch is filtered to
obtain the product of desired quality. The residue is then removed from the filter in
the form of solid cakes. The ZDDP product is then stored, packed and dispatched as
required.

ZDDP Reactions:

Reaction 1:
SH
o
(95–100 C)
4 R-OH + P2S5 2(RO)2-P=S + H2S

Oxo-alcohols Phosphorus Diorganodithiophosphate


Pentasulphide Acid

Reaction 2:

SH S S

2(RO)2-P=S + ZnO (RO)2-P=S-Zn-S=P-(OR)2 + H2O

Diorganodithiophosphate Zinc Zinc Diorganodithiophosphate


Acid Oxide

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

5.12 NaOH (10%)


28.04
PPS

4.39
H2S Scrubber NaHS (30%)
9.47
Optional Draw
DDP ACID PRODUCT Reaction
Alcohol 47.06
71.70 48.06 To Flare
0.0439
11.00 16.00
ZnO Neutralization Base Oil
98.70

1.00
Drying Alcohol (Recovered)

97.70
Base Oil 3.00
Filter Aid 0.60
Mixing

101.30

Filtration Filter Cake


1.30
100.00

ZDDP Product
100.00

7) Mesityl Oxide
Mesityl Oxide is manufactured by the dehydration of Di Acetone Alcohol (DAA) in presence of an
acid catalyst followed by distillation to obtain the pure product. The raw material DAA is
charged into an agitated reactor and the acid catalyst is added. The reaction is maintained at a
constant temperature by use of steam for heating. The vapors are then passed through a
distillation column to collect Crude MO at the top. The bottoms containing acetone & Di-
acetone Alcohol (DAA) are recycled back into the reactor.
The top product which is collected in a decanter is the fed to a distillation column where a Pure
MO product is extracted from a mixture of MO, water and other lighter hydrocarbons. The pure
MO is then stored in a product tank or packed as per requirements.

Mesityl Oxide
(CH3)2C(OH)(C0)CH3 CH3(CO)CH=C(CH3)2 + H2O
Catalyst

Diacetone Alcohol Mesityl Oxide Water

DAA REACTION ACID

160.25 161.25 1.00

TO ETP WASHING
166.88
52.50 210.00 65.625

OFF SPEC DISTILLATION H2O


75.00
35 100.00 26.25

MO PRODUCT

100

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

8) Hydrogenated Products (Hexylene Glycol, Trimethyl Cyclohexanol, Trimethyl


Cyclohexanone, Methyl Isobutyl Ketone , Methyl Isobutyl Carbinol, Di-isobutyl Ketone, Di-
isobutyl Carbinol, Benzyl Acetone)

Initially the raw material is pumped from the feed tank into the loop reactor which operates at a
preset temperature and pressure. The catalyst is fed into the reactor before the batch is
initiated. The hydrogen gas in then introduced into the Loop reactor where the hydrogenation
reaction takes place. The contents of the loop reactor are thoroughly mixed using a pump
circulation system. After the reaction is completed, the reaction mass is emptied into a storage
tank and a new batch is charged into the loop reactor.

The reaction mass from the tank is then passed through a filter system where the catalyst
entrained in the product is removed / recycled. For some of the products a purification system
based on distillation and special filtration is used. The product is then pumped into a tank from
where the purified product can be packed and shipped.

Reactions

Hexylene Glycol

CH2COCH2C(CH3)2OH + H2 Ni Catalyst

DAA Hexylene Glycol (HG)

3,3,5 - Trimethyl Cyclohexanol

Catalyst
C9H14O + 2 H2 C9H18O

IPH Trimethyl Cyclohexanol (TMCHnol)

3,3,5 - Trimethyl Cyclohexanone

Catalyst
C9H14O + H2 C9H16O

IPH Trimethyl Cyclohexanone (TMCHnone)

MIBK
Catalyst
CH3(CO)CH=C(CH3)2 + H2 CH3(CO)CH2CH(CH3)2

Mesityl Oxide Methyl Isobutyl


Ketone (MIBK)

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Note: DIBK is a By-Product in MIBK manufacture

MIBC

Catalyst
CH3(CO)CH2CH(CH3)2 + H2 CH3CHOHCH2CH(CH3)2

Methyl Isobutyl Methyl Isobutyl


Ketone (MIBK) Carbinol (MIBC)

DIBC

Catalyst
(CH3)2CHCH2(CO)CH2CH(CH3)2 + H2 (CH3)2CHCH2CHOHCH2CH(CH3)2

Di Isobutyl Ketone (DIBK) Di Isobutyl Carbinol (DIBC)

Benzyl Acetone

C10H10O + H2 C10H12O

Benzylidene Acetone Benzyl Acetone

VENT GAS

RM HYDROGEN GAS
REACTION
CATALYST

CATALYST RECYCLE
FILTRATION
0.00

DISTILLATION
HBs (HW) OFF SPEC PRODUCT

HYDROGENATED
PRODUCT

9) 3,5 Dimethyl Phenol

3,5 Dimethyl Phenol is prepared by thermal cracking of Isophorone. The process is carried out in
4 steps. Step 1 includes the thermal cracking of Isophorone in presence of a metallic catalyst.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Step 2 involves distillation to remove the Impurities formed during cracking. Step 3 involves
extraction of the product from the crude mass. Step 4 consists of final product purification to
meet the quality requirements

O OH

CH3
+ CH4
H3C CH3 H3C CH3

isophorone 3,5-dimethylphenol

ISOPHORONE REACTION RECYCLE ISOPHORONE

IMPURITY REMOVAL DISTILLATION 1

EXTRACTION

DISTILLATION 2

DISTILLATION 3

3,5 DMP PRODUCT

10) Methyl Pentadiene

Methyl Pentadiene is manufactured by the dehydration of Hexylene Glycol (HG) in presence of


an acid catalyst followed by distillation to obtain the pure product. The raw material HG is
charged into an agitated reactor and the acid catalyst is added. The reaction is maintained at a
constant temperature by use of steam for heating. The vapors are then passed through a
distillation column to collect Crude MPD at the top.
The product which is collected in a decanter is washed and then fed to a distillation column
where a Pure MPD product is extracted from a mixture of MPD, water and other impurities. The
pure MPD is then stored in a product tank or packed as per requirements.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

HO OH H3C CH2 CH CH2

H3C CH C CH3 CH CH CH
CH2 CH3
+ 2H2O
CH3

2-methylpentane-2,4-diol
4-methyl1,3-pentadiene

MPD Plant

HG REACTION ACID

TO ETP WASHING

OFF SPEC DISTILLATION H2O

MPD PRODUCT

11) Bisphenol-S
Bisphenol-S is prepared by the reaction of phenol with Sulphuric Acid. Phenol is reacted with
Sulphuric Acid in presence of a catalyst to form Bisphenol-S. The product is then distilled from
the crude mass after washing.

OH
HO OH

2 + H2SO4 O

phenol O
Bisphenol-S

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

CATALYST

PHENOL REACTION SULPHURIC ACID

TO ETP WASHING

OFF SPEC DISTILLATION H2O

BISPHENOL-S

12) Lubricant Additives (Hydraulic Packages/ Gear Oil Packages etc.)

Lubricant Additives used in Hydraulic & Gear Oil Packages are generally prepared by mixing of
multiple grades of additives (ZDDP & Ashless additives). It is simply a blending process with
addition of base oils and other additives to form packages for Hydralic Oil & Gear Oil
applications
13) Sodium Dithiophosphate

Sodium Dithiophosphate is prepared by a reaction of Sodium Hydroxide with Phosphorus


Pentasulphide. The process involves evolution of H2S gas in the reaction. This H2S gas is then
scrubbed with Caustic soda to form Sodium Hydrogen Sulphide (NaHS). Sodium Dithiophosphate
is often used in the hydrated form.

P2S5 + 6 NaOH → 2 Na3PO2S2 + H2S + 2 H2O

14) Sodium Dialkyl Dithiophosphate


Manufacturing Process
Sodium Diorgano-DithioPhosphate (SDDP) is manufactured in two major steps.
Step 1: Synthesis Step:
The synthesis of Oxo-Alcohols and Phosphorus Pentasulphide takes place to form a Di-Alkyl
Dithiophosphoric Acid with release of Hydrogen Sulphide gas. In this step, the oxo-alcohols are
charged into the reactor, stirred and heated. Phosphorus Pentasulphide is added to this mass
with continuous stirring which results in the evolving of gases which are to be absorbed in the 2
stage caustic scrubber.

Step 2: Neutralization Step:


The neutralization of the acid is carried out with Caustic Soda. Once neutralization is complete,
the product mass is dried. Filter aid is added and the batch is filtered to obtain the product of
desired quality. The residue is then removed from the filter in the form of solid cakes. The SDDP
product is then stored, packed and dispatched as required.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

SDDP Reactions:

Reaction 1:
SH
o
(95–100 C)
4 R-OH + P2S5 2(RO)2-P=S + H2S

Oxo-alcohols Phosphorus Alkyldithiophosphate


Pentasulphide Acid

Reaction 2:

SH S-Na

(RO)2-P=S + NaOH (RO)2-P=S + H2O

Alkyldithiophosphate Caustic Sodium Alkyl


Acid Dithiophosphate

4.51 NaOH (10%)


23.74
PPS

3.87
H2S Scrubber NaHS (30%)
8.35
Optional Draw
DDP ACID PRODUCT Reaction
Alcohol 39.85
60.71 To Flare
0.0387
21.99 16.00
NaOH Neutralization Base Oil
98.70

1.00
Drying Alcohol (Recovered)

97.70
Base Oil 3.00
Filter Aid 0.60
Mixing

101.30

Filtration Filter Cake


1.30
100.00

SDDP Product
100.00

15) Benzylidene Acetone

Benzylidene Acetone is manufactured by Aldol condensation of Benzaldehyde & Acetone.


Benzaldehyde & Acetone are fed to a reaction system along with a catalyst to form Benzylidene
Acetone along with some impurities. The reaction mass is then washed and purified to form
Benzylidene Acetone product

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

Benzylidene Acetone

CH3C(O)CH3 + C6H5CHO C6H5CH=CHC(O)CH3 + H2O

Acetone Benzaldehyde Benzylidene Acetone Water

1.00
CATALYST

BENZALDEHYDE REACTION ACETONE


94.00 153.75 58.75

TO ETP WASHING
166.88
52.50 202.50 65.625

OFF SPEC DISTILLATION H2O


75.00
27.5 100.00 26.25

BENZYLIDENE
ACETONE
100.00

16) PIBSA

PIBSA is manufactured by the reaction of PolyIsobutylene & Maleic Anhydride. Polyisobutylene


in presence of catalyst reacts with Maleic Anhydride forms Polyisobutylene Succinic Acid.

17) PIBSI
PIBSA on further reaction with a polyamine forms Polyisobutylene succinimide (PIBSI)

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

18) Phosphate Esters


Phosphate Esters are produced by a synthesis of Alcohols with Phosphorus Pentoxide.
Phosphorus Pentoxide is added to a Alcohol mixture where reaction takes place at
predetermined temperature & pressure conditions to form Phosphate Esters with liberation or
water. Different grades of Phosphate Esters can be manufactured by varying the alcohols in the
Alcohol mixture of the feed.

19) Amine Phosphates


Phosphate Esters when reacted with and alkyl amine form amine phosphates. It is a simple
addition reaction taking place at predetermined temperature & Pressure conditions.

20) Carbazole Esters


Carbazole Esters are manufactured by a reaction of Ethyl Acrylate with Carbazole. Ethyl Acrylate
and Carbazole at given temperature & pressure conditions in presence of catalyst form Carbzole
Esters

21) Ashless Lubricant Additive


Ashless Lubricant additive is manufactured in a manner similar to ZDDP. Alcohol (e.g Ethanol)
reacts with Phosphorus Pentasulphide (PPS) to form the corresponding Dithiophosphoric Acid
(Dirthyl Thiophosphoric Acid). H2S gas is evolved in the process. The Acid is the reacted with
Ethyl Acrylate to form a Dithiophosphate Ester. This Dithiophosphate ester on refinement and
addition of base oil act as an Ashless Lubricant Additive

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

NaOH (10%)

PPS

H2S Scrubber NaHS (30%)

Optional Draw
DDP ACID PRODUCT Reaction
Alcohol
To Flare

Ethyl Acrylate Synthesis Base Oil

Drying Alcohol (Recovered)

Base Oil
Mixing

Ashless Additive

22) Resorcinol
Resorcinol can be manufactured by various routes. We have selected the manufacture of
Resorcinol by Hydroperoxidation of m-Diisopropylbenzene (m-DIPB). M-DIPB is oxidized in a
bubble column reactor to form the hydroperoxide mixture containing Dihydroiperoxide (DHP,
Ketohydroperxide (KHP) & Hydroxyhydroperoxide (HHP). The mixture undergoes extraction to
maximize the DHP concentration. This DHP then undergoes Cleavage to form Resorcinol &
Acetone. The reaction mass is then distilled to obtain pure Resorcinol & Acetone in a series of
distillation columns.

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Prefeasibility Report Prasol Chemicals Private limited, Village Honad, Dist Raigad, Maharashtra

CARBONATE VENT AIR (INERT)

DIPB AIR
OXIDATION

RECYCLE DIPB DHP


CONCENTRATION

WATER
CLEAVAGE

TO ETP

ACETONE PRODUCT ACETONE RESORCINOL RESORCINOL PRODUCT


DISTILLATION DISTILLATION

59

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