FHTJEE

I NI 1 E

ALL INDIA TEST SERIES

JEE(Main), 2014

PART TEST - II

(7 December,2013)

PHYSICS ' CHEMISTRY & MATHEMATICS

(OBJECTIVE)

QUESTIONS
/

ANSWERS & SOLUTIONS

 1 AITS-PT-11-PCM(S)-,JEE(Main)/14

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AITS-PT-11-PCM(S)-JEE(Main)/14

Physics PART - I

SECTION - A
Single Correct Choice Type

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (0)
out of which ONLY ONE is correct.

Four point charges +q, +q, -q and -q are placed on the corners of a a
+q +q
square of side length 'a' as shown in the figure. The magnitude of
electric field at a point which is at a distance x (z>a) from the centre
along a fine perpendicular to the plane of the square and passing a
through the centre, is
,nqa qa -q
(A) (B) -q
4E60x3 27m0 x3
-nqa qa
(C) (D)
2neQ x3 4ne x3

Sol. B
The given configuration of charges is combination of two dipoles and the point where is electric
field is required is on their equatorial line
Kp r- 1 q Vaa _ qa
3 4nri0 x3
X 27T80 X3

A monoatomic ideal gas is used in a carnot engine as the working substance. If during the
adiabatic compression the volume of the gas decreases from v to v/8, the efficiency of the engine
is
(A) 0.50 (B) 0.25
(C) 0.75 (D) 0.40

Sol. C
Let the temperature of Ow gas increases from T1 and T2 during adiabatic compression
Tyr = T2Vr

_ ( V, I = (g)2!3 4
T, V2
T, 1
Efficiency i = 1- — = 1- - = 0.75
T2 4

Two adiabatic containers have volume V1 and V2 respectively. The first container has mono
atomic gas at pressure PIand temperature T1. The second container has another mono atomic
gas at pressure P2 and temperature.T2. When the two containers are connected by a narrow
tube, the final temperature and pressure of the gases.in the containers are P and T respectively.
Then
P2 V2T, (B) T PIVIT2 +.1p2 V2 T1
(A) T -
P,V, + P2 V2 PiV2 +1,32 V,
(C) PIV2 + P2 V1
(D) P - P "V+P2 V2
+ V2 + V2

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Sol. D
As there will be no loss in internal energy of the gas
+ n2C,T2 = (n1 + n2)CvT

RT, RT2 RT, RT2

(R,V, +P2V2)T,T2
PIV1T2 +P2V2T,
As number of moles of the gas will be constant
ni + n2 = n
r P,V, p2v, (PV, PV2
+
RT, RT2 ) kRT RI ) •
,V1T2 +P2V2T1 x (P,V, + P2V2)T,T2 _ +P2V2
= 1-•
1,T2 (V, + V2 ) P,V1T2 +P2V2T, V, + V2

4. A capacitor is charged by a battery. Then it is disconnected from the battery and connected to an
inductor of inductance L. The minimum time in which the charge on the capacitor becomes half of
its initial value is
(A) ;ICE (B)
4
(C) iE ,fi7
,6 (D)
6 3

Sol. D
q = qocos cot
= 9 .q0 coscot
2
t
= ot =-1—
3
n n T n c
=- vLC
3w 271 6 3
3x—
T

A uniform metallic disc of radius r and mass m is spinning with angular speed mo about an axis
passing through its centre and perpendicular to its plane. If its temperature is increased (slightly)
by AT without disturbing the disc, its new angular speed is (The coefficient of linear expansion of
the metal isia)
(A) coo (1+20.AT) (B) 00 (1 + aAT)
(C) coo (1— 2aAT) (D) 0)0 (1— 3ri.L1T)

Sol. C
From conservation of angular momentum
mR2c0 AR Aco
— cons tan t = 2 —+ — = 0
2 R
AR
aw = -2o — = -2oaAT

= + = co, - 2o0aAT
= wo (1- 2a AT)

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A current carrying circular !bop of radius r is placed in the x-y plane with centre at the origin. Half
of the loop with x>0 is now bent so that it now lies in the y-z plane.
The magnitude of the magnetic moment now decreases
The magnitude of magnetic moment does not change
The magnitude of magnetic field at (0, 0, z) increases (given z>> r)
The magnitude of magnetic field at (0, 0, z) is unchanged (given z>> r)

$ol. A

A paramagnetic sample shows a net magnetisation of 8 Am-1, when placed in an external

magnetic field of 0.6 T at a temperature of 4K. When the same sample is placed in an external
magnetic field of 0.21 'at a temperature of 16 K, the magnetisation will be
2
(A) -31Am-I (B) — Am-1
3 3
(C) 6Am-I (D) 2.4Am-1
I
Sol. B I

A complex current wave is given by i = 5 + 5 sin(1007d) A. Its root mean square value over one
time period is given as
(A) 5 A (B) 542 A

(C) 5 —A (D) 10 A
2

Sol. C

I2dt
O T (a + bsinot)2 dt
T

dt
j
O

(a2 + )T
2
= /52
2y 2

A magnet is taken towards .a conducting ring in such a way that a constant current of 10 mA is
,
induced in it. The total resistance of the ring is 0.5 0..In 5 seconds, the magnetic flux through the
ring changes by
(A) 0.25 mWb (B) 25 mWb
(C) 50 mWb (D) 15 mWb

Sol. B

q = TR-
=+
- = qR = ItR = 10-3 x 5 x 0.57 = 25 mWb

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10. Two parallel long straight conductors lies on a smooth plane surface.
Two other long parallel conductors rest on them at right angles so as to
form a square of side a. A uniform magnetic field B exists at right angle to
the plane containing the conductors. Now conductors start moving 4- 0B
outward with a constant velocity vo at t = 0. Then induced current in the V0
loop at any time t is (?. is resistance per unit length of Conductors)
aB v /2 . aBvo
(A) (B)
X. (a + vot) 2X.
13 v By°
(C) ° (D)
X 2X

C
4BCv o
I- - (C is the side length of the square loop at a certain instant)
R 4Xt
Bvo
X

A conductor of length I' is placed perpendicular to a horizontal uniform magnetic field B. Suddenly
a certain amount of charge is passed through it, when it is found to jump to a height h. The
amount of charge that passes through the conductor is
2ma
(A) ma (B)
BE 3BC
liFt (D) none of the above
(C) m
BC

Sal. C
The sudden flow of the charge will exert an impulsive magnetic force Let vo be the velocity of
conductor just after the impulse
mvo = Fdt =f1CBdt =JCBdq = CBq
= iBq
m
q = —v2gh
tB

Consider a capacitor-charging circuit. Let Q lbe the charge given to the capacitor in a time
interval of 10 ms and 02 be the charge given in the next time interval of 10 ms. Let 10 pC charge
be deposited in a time interval t1 and the next 10 'AC charge is deposited in the next time interval
t2.
(A) Qi > 02,11> t2 (B) Q, > Q2, ti < t2
(C) 01 <02, t1 > t2 (D) Q1 CQ2, t1 < t2

801. B
during charging of a capacitor rate of flow of charge (i.e. current) decreases with time

A positively charged disc is placed on a horizontal plane. A charged particle is released from a
certain height along its axis. The particle just reaches (with zero velocity) the centre of the disc.
Select the correct alternative
Particle has negative charge on it
Total potential energy (gravitational + electrostatic) of the particle first increases then
decreases
Total potential energy of the particle first decreases then increases
Total potential energy of the particle continuously decreases

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Sol. C

14. Variation of internal energy with density of one mole of

monatomic gas is depicted in the adjoining figure,
corresponding variation of pressure with volume can be
depicted as (Assuming the curve is rectangular hyperbola)

(A) (13)

V V
(C) (D) P

•
V V

Sol. D
1
V oc —

Vp = constant
V = constant
P = constant

15. A gas undergoes A to B through three different processes 1, 2 and

3 as shown in the figure. The heat supplied to the gas are Q1, 02
. and Q3 respectively, then
01 -" Q2 = Q3
01< 02 < 03
Q1 > Q2 > 03
(D)01=Q2>Q3
V
Sol. C

16. 600 J of heat is Wdded to a monaiomic gas in a process in which the gas performs a work of 150
J. The molar heat capacity of the gas for the process is
(A) 3R (8) 4R
(C) 2R (D) 6R
Sol. C
AQ = nCAT = 600
AU = nCviAT = 450

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4 4 3R
= C = — Cv =- x — =2R
Cv 3 3 3 2

Two identical small conducting spheres having unequal positive charges qland 42 separated by
distance r. If they are made to touch each other and then separated again to the same distance,
the electrostatic force-between them in this case will be
(A) less than before (B) same as before
(C) more than before (D) zero

Sol. C

A capacitor of capacitance 2 p.tF is charged to a potential

difference of 5V. Now the charging battery is disconnected
and the capacitor is connected in parallel to a resistor of 5
and another resistor of unknown resistance R as shown in
5n".
figure. If the total heat produced in 5 0 resistance is 10 µJ
'VVVVV
then the unknown resistance R is equal to
10 0
150
(10/3) 0
7.5

Sol. C

A particle of specific charge q/m = It C/kg is projected from the origin toward positive x-axis with a
velocity of 10 m/s in a uniform magnetic field a = —2k T. The velocity C./. of the particle after time
= 1/6 sec will be
(A) (51+ 5/31) m/s (B) 10] m/s

(C)- (5-shi — 5]) m/s (D) —10] m/s

Sol. .A
A solid conducting sphere .of radius R and total charge q rotates about its diametric axis with
constant angular speed co. The magnetic moment of the sphere is
1 2 2
(A) — qR2co (B) — qR (0
3 3
1 2
(C) — qR2co (D) — qR2e.)
5 5-

Sol. A
Magnetic dipole moment of a charge conducting sphere will be same as a uniformly charged
spherical shell of same radius R and charge q rotating with same angular velocity O.

21. Two concentric conducting spherical shells of radii R and 2R are carrying charges +Q and —2Q
respectively. Now consider the two statement(s)
Statement I: When the charge on outer shell is doubled the potential difference between the
surfaces of the two shells will remain same
Statement II: When the charge on the inner shell is doubled the potential difference between thr
surface of the two shell will become twice of its initial value.
Statement I is correct but statement II is incorrect
Statement II is correct but statement I is correct
Both the statements are correct
Both the statements are incorrect.

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Sot. C

R1 R2

c't

22. The adjoining figure shows an A.G. circuit with resistance

R, inductance L and source voltage V. Then,
the source voltage Vs = 90 V
the source voltage VA = 72.8 V
the phase angle between current and source voltage
is tan-1(7/2)
the phase angle between current and source voltage
is ir/2

Sol. B

23. In the given situation the resistance of each side of the smaller A •
squares is 100. The equivalent resistance between point A and B is
(A)100
(8)150
(C)200
(D) 5 0

Sol. B

24. Two long wires placed along x and y axis carries equal currents along positive x-axis and positive
y-axis respectively. An electron is projected with some velocity along the line y= x from the origin.
The electron will
(A) be deflected along towards x-axis (B) be deflected towards y-axis
(C) will describe a circle (D) will not deflect at all
Sol. D
25. In the circuit shown. Initially the capacitor is uncharged The switch S 20 411
is closed at time t = 0. Then,
(V, — Vb) is increasing with time
0.5 F
(Va — Vb) is decreasing with time
1-2--WVV1e
(V, Vb) =2 V
(Va — Vb) = zero
1 2

Sot D 20 b 4H
2 e-t/2 NVVV
I1 —(1—
2 e-"2 =

q = 2x 0.5(i— e-t/2 ) ,1— Cl/2

Va —Vb =11 X 2— = 2 (1— e-U2 )- 2 (1 — e 2) = o

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Charge is distributed inside a long cylindrical volume of radius R such that charge density inside
the volume varies as p = aril where a is a constant and r the distance from the axis of the •
cylinder. If the magnitude of electric field inside the cylinder is independent of r, the value of n is
(A) 1 (B) 2
(C) —2 (D) —1

Sol.

Two conducting spheres of radii r and 2r are placed at very long separation. Each sphere
possesses charge Q. These spheres are connected with a conducting wire of resistance R. The
initial current in the wire is
(A) (B)
ReorR 2iicorR

(C) (D)
thrEorR 1371corR

Sol. D

A particle of mass m and charge q is projected in a region where an electric field by E = Eot
exists, with a velocity irjj from the origin. Given m2vg = 2qE0mx0 . The radius of curvature of the
path of the particle when its x-coordinate becomes xo, is
(A) 4V1co (B) 2V-2-x0
(D) x0
(C) -,hx0

Sol. A
2qE0 2qE0 mq, 2
= 2ax x0 — xo — =v
mm 2qE0
Vx = VO
V
2 thmv„2
R— — — 41h0
ax qE0 / lam qE0

The magnitude of electric field for which the volume energy density of this field is the same as
that of the magnetic field with induction B = 2.0 T (both the fields are in vacuum), is
(A) 3 x 106 V/m (B) 6 x 108 V/m
(C) 2 x 106 V/m (D) 9 x 108 V/m

Sol. B

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to

30. A metallic horizontal ring of mass m and radius r falling under gravity in a region having a
magnetic field. If z is the vertical direction, the z-component of magnetic field is 13, =.130(1+ 2.z)
where Bo and ?, are constants. If R is the resistance of the ring, the terminal velocity of the ring is '
(B) mgR
(A) mgR
(Thr2k60 ) (2Thr2 30 )
mgR (D) 2mgR
(C)
(nr2B0 )2 (7ir22.130 )2

Sol. D
When the ring falls with terminal velocity
Rate of heat produced in the ring = rate of loss of gravitation potential energy of the ring .'
I2R = mgv
, 1• clib 1 2 dB Iti2
1= = — = --Do ty
R dt R dt
712i4 2 -42 v2
B(3 R — mgv
R2
mgR
v=
(nd2B 2
o)

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Chemistry PART - UI

SECTION — A

Straight Objective Type -

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE is correct.

Which of the following compounds is not named correctly (not necessarily IUPAC)?
2-methyl-3-heptanone (CH3)2CHC0C1-12CH2CH2CH3
phenylacetaldehyde C6H5CH2CHO
4-hexyn-2-one .CH3C0CH2CsCCH3
para-bromoacetophenone p-BrC6H4CH2C0CH3

Sol. 0
Alkane on heating in a regulated supply of dioxygen or air at high pressure and in the presence of
suitable catalyst gives a variety of oxidation products. Which of the following reaction is incorrect
regarding oxidation of alkanes?
(A) 2CH4 + 02 Cui5231("Ce atm > 2CH3OH
(B) CH4 +02 -'1?-r2I—>HCHO +H20
ico: y4n
(C) 2CH3CH3 +302 tcH >2CH3C0.CH3 +2H20
ManO,
(D) (CH3 )3 CH 0„63353n > (0H3 )3 C —OH

Sol. C
C H3 COO):Mn
2CH3CH3 +302 >2CH3C00H+2H20 •

3. Unlike benzene; anthracene can undergo addition reactions. What will be the major product of the
following reaction?

Sol. A

5 10 4
Anthracene undergoes addition reaction at 9 and 10 positions because resonance energy per
mole of ring increases.

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AITS-PT-II-PCM(S)-JEE(Main)/14

4. Which of the following compounds are aromatic in nature?

(2)
0

(4) I (5)
(A) 1, 3, 5, 6 only (B) 1, 2, 3, 5, 6 only .
(C) 1, 3, 4, 5, 6 only (D) 1; 2, 3, 4, 5, 6 all are aromatic

Sol. A

5. 2-methylbutane is subjected to bromination in presence of sunlight. What is the maximum number'

of monobromo derivatives possible?
(A) 4 only (B) 5 only
(C) 6 only (D) I only
Sol. C

C--C-----C > 2 stereoisomers possible

2 3 4
Br

C—C—C--C Only one possible

Br

2 stereoisomers possible
Br

C—C—C.___C ----)-Only one possible

Br

6. Choose the incorrect statement:

Among dichloro benzenes, para dichloro benzene has highest melting point.
Boiling point of isomeric haloalkanes decreases with increase in branching.
One molecule of DDT contain five atoms of chlorine.
Chloroform is slowly oxidised by air in the presence of light to form methanol.

Sol. D
Para dichlorobenzene has highest mp due to its symmetry.
Due to increase in branching, surface area decreases and BP decreases.

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(C) Cl

Cl
Cl
Cl
(D) 2CHCI3 +02 2C0C12 +2HCI
(Phosgene)

7. What is the correct order of SNIreactivity of the following -alkyl halide?

CoH5CH2Br, C6H,CH(C,115 )Br, C,H,CH(CH,)Br, C6H5C(CH3 )(C6H5 )Br
(1) (2) (3) (4)

(A) 4 > 2> 3> 1 (B) 4> 3 > 2> 1

(C) 4 > 2> 1 > 3 (D) 2> 3 > 4 > 1

Sol, A
Sal reactivity depends upon stability of carbocation.

8.
+CH, —CH = CH c'tH3P°4 >, X
Major

X+02
Y HI:40 >Phenol+ Q(organic product)
Find the correct statement about Q.
(A) Q gives silver mirror test (B) Q gives red ppt. with Fehling's solution
(C) Q gives red ppt. with Benedict's solution (D) Q gives yellow ppt. with 12/NaOH.

Sol. D

Q is CH, -C-CH,, it gives CHI3 with 12 in NaOH.

9 Which of the following ethers are cleaved by HI?

(1) Ph - 0 -CH, (2) Ph-0 -Ph
CH3 0
(3) H3C—C-0—CH2—CH3 (4)
1
CH3
0

(5)
0
(A) 1, 3, 5 only (B) 1, 3, 5, 6 only
(C) 1, 3, 4 only (D) 1, 3, 4, 5, 6 only

Sol. C

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10. Choose the incorrect statement:

When phenol reacts with Br2 in CS2 at 273 K para bromo phenol is obtained as major product
When phenol is treated with Br2 in H20 a white ppt. is obtained.
During Reimer-Tiemann reaction, dichloro carbene is reactive intermediate
Phenol reacts with Zn dust to form diphenyl ether.

Sol. D
OH OH OH
Br

Br (Major)
OH OH
H3C

Br (White ppt)

CHCI3 +KOH—>CCI, +H20 +IC

CC13 -->C1' +: CCI

2
clichloroCagbene

OH

+ ZnO

11. Which of the following reaction is not correct?

PhCOCI pd: so, >PhCHO

(B) CH, —CH = CH—CH, —CH, —CN A1Fi110so2 >CH —CH r- CH—CH, —CH, —CHO
,0
O 0
II II
(C) CH, —CH, — C— OC,H, A IH,
(18
04)' CH,CH, — C— H

CH, —CH, —C-0C2H5 An„(60")2 >CH, —CH, —CH, —OH

2

Sol. D

12. In which of the following reaction a colour change does not take place?
CH,CHO+Ag(NH,);

CH,CHO+R —NH2
CH3CHO + Cut2 +Sod. pot. tartarate +Na0H-->
CH3CHO+Na01 >

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Sol. B
(A) Ag is precipitated
(B) No colour change
Cu2O (red ppt.) obtained
CHI3 (yellow ppt.) obtained.

13. What will be the major cross product of the following condensation reaction?
CH, - CHO + CH3 -COCH3 - 'Dd r

(A) OH (B) H3C—C=CH—CHO

H3C—C—CH2—CHO CH3
CH3
(C) H3C—CH=CH—COCH3 (D) OH
H3C—CH=CH2-C-CH3
8
Sol. C
In the slow step of the reaction Nu" attacks at less hindered aldehyde group.

What is the rate determining step of the following reaction?

PhCHO c411":" >PhCOO- +PhCH,OH
Os.

Ph—C—H
(A) transfer of H' from PhCOOH to PhCH20" (B) transfer of Fr from OH to PhCHO
os
Ph—C—H
(C) attack of OH' on PhCHO (ID) attack of OH on PhCHO

Sol. B
Hydride transfer step is rate determining step of Cannizzaro reaction.

Choose the correct statement with respect to the following reactions.

(a) (b)

(c) (d)

CO2 will be one of the product in every reaction.

CO2 will be evolved only in a, b only
In 'a' reaction, dicarboxylic acid is the only product
'b', 'c' and 'd' give a keto acid as a product

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 AITS-PT-11-PCM(S)-JEE(Main)/14 16

Sol. B
(A) (B)

+ 2CO2
CO2

(C) (D)
o, COOH
0, > I 0 H26,6
H204 COOH
COOH

16. Which of the following amide will give primary amine as a product when treated with Br2 in conc.
KO}-l?
(A) 0 (B) 0
CH3CH2 —C—NHCH, Ph— C—NHPh
(C) 0 (D) 0
PhCH2 — C— NH2 PhCH2 —C—N(CH3 )2

Sol. C

Amide of the type R -C-NH2 which do not have substitution on 'N' atom undergo Hoffmann
bromamide degradation reaction in presence Br2 in conc. KOH to give 10 amines only.

Which of the following natural amino acids contain aromatic ring in the side Chain?
(A) Valine (B) Lysine
(C) Aspartic acid (D) Histidine

Sol. D

Histidine contains

Choose the incorrect statement regarding the reaction of diazonium salt?

Diazonium salt (Ar1(12 Cr) reacts with ethanol to give phenol and acetaldehyde as the

organic product
Diazonium salt (ArN2CI- ) react with phenol in basic medium to form orange dye

Diazonium salt ( ArN2CI- reacts with aniline in acidic medium to form yellow dye

When Diazonium fluoroborate is heated with aq. NaNO2 in Cu, nitrobenzene is formed

Sol. A
ArN2C1- +Et0H Qpc >Ph H + CH,CHO +HCI + N2

ArN2 CI- + PhOH--+;°—›

Ic Ar N — N — C61-14 — OH+ CI- +H20
(Orange)

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 17 AITS-PT-11-PCM(S)-JEE(Main)/14

ArN2C1- + PhNH2 Ar N - N C6H4 - NH2 + HCI

ArN2C1- +HBF, N2 BF; 2 PhNO2 + N2 + NaBF,

19. Choose the incorrect option regarding examples of polymers:

Elastomers : Buna-S, Buna-N, Neoprene, Melamine
Fibers : Nylon(6,6), Polyester
Thermoplastic: Polythene, Polystyrene
Thermosetting : Bakelite, Urea formaldehyde resin

Sol. A
Melamine is thermosetting plastic.

20. D-glucose and D-fructose can be distinguised by which of the following reagent?
(A) Fehling's solution (B) Br2 in H20 or I-10Br
(C) Benedict's solution (D) Osazone formation

Sol. B
D-fructose being a keto sugar is not oxidised HOBr.

21. Which of the following carbohydrate will not produce red pot of Cu2O on reaction with Fehling's
solution?

(A) CH2OH (B) HOH2C

CH2OH
H

OH

OH OH OH H
(C) CH2OH (D) cH2oH cH2oH
Ch1/20H H
0 NCH3 H 0
° H
/H H \
/
\OH 02 CH2OH \OH H OH H
OH
OH H • OH
H OH H. OH H OH

Sol C
C is sucrose where reducing groups of a-glucose and 0-fructose are involved in glycoside bond
formation, so sucrose is non reducing sugar.

22. Which of the following dimethylcycloputanes is chiral?

(A) trans-1,2-dimethylcyclobutane (B) cis-1,2-dimethylcyclobutane
(C) trans-1,3-dimethylcyclobulane (D) cis-1,3-dimethylcyclobutane

Sol. A

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18

23. What is the product of following reaction?

0 0
c_oc,„
6c,_,2_ 1, ,,i3,
,4

(A)
6 OH 0

c5
.0H

CH2—CH2-0H

o
(C) OH
cH2L-CHO CH2—CH2OH

Sol. A
NaBK4 reduces only ketonic group in this case not ester group.

24. Treatment of 1-methylcyclohexene with an ether solution of diborane (B2H6), followed by reaction
with alkaline H202 produces what product?
(A) 1-methylcyclohexanol (B) cis-1-methylcyclohexane-1,2-diol
(C) cis-2-methylcyclohexanol (D) trans-2-methylcyclohexanol

Sol. D

25. Arrange the following phenols in order of their acidic strength

OH OH OH OH
NO2 NO2 NO2 0 N NO2

NO2 NO2
(1) (2) (3) (4)
NO2 NO2 NO2
(A) 1 > 2> 3> 4 (B) 4> 3> 2> 1
(C) 4> 1 > 3> 2 (D) 4> 3> 1 > 2

Sol. D
More the number of electron withdrawing groups present at ortho and para w.r.t. OH group, more
be the acidic strength.

26. Two C5H8 isomers undergo catalytic (Pt) hydrogenation to form the same C5H10 Product. On
ozonolysis followpd by oxidative workup (11202), one isomer gave a C511804 diacid, while the other
isomer gave a 1 05H803 ketoacid. Which of the following isomeric pairs correspond to this
evidence?
cyclopentene and 1-pentyne
cyclopentene and 1-methylcyclobutene
1-methylcyclobutene and 3-methylcyclobutene
cyclopentene and 3-methylcyclobutene

Sol. C

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 19 AITS-PT-11-PCM(S)-JEE(Main)114

27. Choose the correct statement regarding decarboxylation of following carboxylic acids:
COOH

'(>K' eN
I
C H3 C H3
(b)
rate of decarboxylation — a > c-> b
rate of decarboxylation — b> a > c
rate of decarboxylation —ä> b> c
rate of decarboxylation— c> a> b

Sol. C
Rate of decarboxylation depends upon the stability of intermediate carbanion. Acid that forms
stable carbanion will decarboxylate readily.
8,

> (Stability of carbanion)

>
/8
oN
CH3 CH3
CH3

28. You have two (C6H100) ketones, I and II. Both are optically active, but I is racemized by treatment
with base and II is not.
Wolff-Kishner reduction of both ketones gives the same achiral hydrocarbon, formula 06H What
reasonable structures may be assigned to I and II?
I is 3-methyl-4-penten-2-one; II is 4-methyl-1-penten-3-one
I is 2-methylcyclopentanone; II is 3-methylcyclopentanone
I is 3-methylcyclopentanone; II is 2-methylcyclopentanone
I is 2-ethylcyclobutanone; II is 3-ethylcyclobutanone

Sol. B

29. DNA contains four bases-adenine, guanine, cytosine and thymine Out of these four, which base
is not present in RNA?
(A) Thymine . ,..(B) Adenine
(C) Cytosine (D) Guanine

Sol. A

30. Which of the following amines will give a foul or bad odour compound on treatment with. CHCI3 in
conc. KOH?

(A)
H3C NHCH3

(C)
CH30- NH2

Sol. C
Only 10 amine give carbylamines reaction on reaction with CHCI3 in KOH, which gives bad odour
of isocyanides.

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 AITS-PT-II-PCM(S)-JEE(Main)/14 20

Mathematics PART — III

SECTION - A

Straight Objective Type

This section contains 30 multiple choice questions. Each question has four choices (A), (B), (C) and (0)
out of which ONLY ONE is correct.

In an equilateral triangle ex-centre opposite vertex A is (2, -4) and equation of side BC is
x + y - 2 = 0, if co-ordinates of vertex A is (a, p) then 2a - p is
(A) 12 (13) 6
(C) (D) 4

Sol. A
Vertex A will be mirror image of ex-centre about x + y -2 = 0
a-2 0+4 —2(2-4-2)
-4
1 1 2
a= 6 andp= 0

The angle of elevation of the top of a hill from each of the vertices A, B. C of a horizontal triangle
ABC with side lengths a, b, c is 60°. Then height of the hill is

(A) bihcosecB (B) T a cosec A

(C) c cosecC (D) None of these

Sol. B

The distance of the foot from each vertex = h c0t60° =—

,r
1/3
The foot is at the circumcentre of the triangle. So R =_
V3
L.
h=
aJ
2 sin A

Locus of centre of circle which cuts the parabola y2 = 4x orthogonally at (1, 2) will pass through
(A) (3, 4) (B) (4, 4)
(C) (3,7) (D) (1,5)
Sol. A
Locus will be the tangent to the parabola y2 = 4x at (1,2)
y=x+ 1

If combined equation of two sides AB and AC of a triangle is x2 - xy - 2y2 + x + y = 0; and (1, 1) is

orthocentre, then circum-radius of AABC is
5-5 10,ri
(A)
Ti- (B)
3
3.k
(C) (D)
5 1042

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 21 AITS-PT-114PCM(S)-JEE(Main)/14

Sol. A
Clearly two sides are x.—.2y + 1 = 0 and x + y = 0
As orthocentre lies on x — 2y + 1= 015 right angled (let at B)
Third side passes through (1, 1) and is perpendicular to x — 2y + 1 =
Third side is 2x + y — 3 = 0
1 5-12
Circum-radius = — AC —
2 3

If the vertices of a triangle ABC are A =(2ji, 1) ; B (4, 3) and C 4JI, 210 then co—
ordinates of orthocentre is
(A) (2(16 +2)+ig, 4 +2/51 (B) (4+ 4+2J) -
(C) (8-16 + VS, 3+2V') (D) (4+2,j, 4(18. +1) + -sig)
Sol. A
(2(-16Vg
+2)+ 4+241
Clearly, co-ordinates of circumcentre are (0, 0) and centroid are
3 3
Since centroid divides the line segment joining orthocentre and circumcentre in the ratio 2: 1;
Hence co—ordinate of orthocentre are (2(Nre +2)+1g, 4 + ZIS")

If OR is chord of contact when two tangents are drawn from origin to the variable circle, with
centre P lying on xy '= 1; then locus of circumcentre of APQR is
1
(A) xy = 4 (B) xy = —
4
3
(C) xy = 1 (D) xy = —
4
Sol. B
Let (h, k) be the centre of circumcircle
(2h, 2k) lies on xy = 1
1
4hk = 1 xy =
4

7
r 8x it
Interval containing x such that c05-1 — +2tan 14x
k1+16x2 2
1
(B)L16
It, 8
1 \
(D) k8 4
1
Sol. C
It .1( 2 x 4x ) it
On solving sin- +2tan-14x
2 1+16x2 ) 2
2(4x) -)
=- 2tan-1 (4x) = it—sin-1 i
‘..1+(4x)2
2x >i
-:2tan 1 X = Tt - sin-1( ;x
1-I- X2
1
=r,As 4x > 1 x— x e (1 ,00)
4 4

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 22
AITS-PT-11-PCM(S)-JEE(Main)114
crt ern., a te ,at • t re.“4“
<

x2 ,2
x y
The straight line -- = 1 intersects the ellipse — =1 at two points P and Q The number
4 3 16 9
of points A on the ellipse such that area of &APO is1 5 sq units; is
(A) 0 (8) 1
(C) 2 (D) 4
Sol. A
Clearly length PQ = 5 units
as PQ is the base and area(AAQP) = 15 sq units
.1
x PQ x h = 15 h = 6
2
but maximum distance of any point on ellipse is less than 6
Hence there is no point on ellipse.

In a right-angled triangle, the acute angle a, p are satisfying tan a(1 + tan a) + tan 0(1 + tan (1) =
4. If hypotenuse is of length d, then area of the triangle is

(A) —d2 (B) —d2

4 8
d2
(C) — (D) d2
4
Sol. C
As a + 8 = 90°
tan a + tan2 a + cot + cot2 =
; let tana = x
x2
1 1
As x + - 2 for x > 0 and x + - =2
x=1
It
a=8=
atj
d2
Hence area of isosceles right-angled triangle = —
4

On the curve xy = c2 two points P and Q are taken, if tangents at P and Q cut x-axis at A and B
respectively, then ratio of area of AOPA to area of AOQB (0 origin) is equal to
1 1
(A) - (B)
2 3
(C)1- (D) 1
4
Sol. D
Area of both triangle will be equal

If 0 is origin A is vertex and S is focus of a parabola such that OS = 20A and OA = a. If x - y = 0

is the axis of parabola; then locus of image of focus with respect to any tangent to parabola is
(A) x + y = a (B) x + y - 2/2.a = 0
(C) x + y - 2a = 0 (D) x + y = 0
Sol. D
Locus of image of focus with respect to any tangent is the directrix of parabola.

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General solution of inequality sin 2x> sih2 x + (2— •fi)cos2 x

(A) x E (rin + —
lc (B) x (nit + + Lt)
3
+) 12' 4

(C) x e (nit +I nit + 11) (D) x e (nit + nn + 1

7
'
Sol. C
Dividing both sides by co52 x
We get -fitan2 x — 2tan x + (2 — .5) < 0

= tanx (-.5-1, 1) x e inn + 11 mt.+

81 4

Let a line- L be drawn through focus S of the parabola y2 = 8x and it is parallel to the tangent at
P(a, a), (a # 0) on the parabola y2 — 8x = 0. If line L intersects the line y = 8 at 0, then PQ is
equal to
(A) 10 (B) 11
(C) 12 (D) 14
Sol. A
PQ=a+x= 2 + 8= 10

a 2 b2 c2
If cosec0 — where a, b, c are sides of a triangle ABC, then 0 can never attain the
ab + bc +ca
value
(A) (B)
6 4

(C) (0)
3 2
Sol. A
b2 c2 a•
We have a2 + o bc + ca
za2
2
Ea tab — 1
Eab
And in AABC lb — q< a
b2 + c2 — 2bc < a
similarly c2 + a2 — 2ac < b2
a 2 + b2 - 2ab < c2
Ea2 < 2Zab
la2
— <2
Eab "
(71 71
=, cosece < 2
6 2

If radius of director circle of auxil ary circle of ellipse

(3x + 4y — 1)2 + 5(4x — 3y + 2)2 = 250 is r then In is ([.] is g.i.f)
(A) 1 • (B) 2
(C) 4 (D) 5
Sol. C
a2 = 10, b2 = 2
so radius of director circle = NIF:1
[r] = 4

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16. ABC is right-angled triangle such that D is midpoint of hypotenuse AB and E.is midpoint of AC.
Segment BE and CD intersect at F. If BC = 1 and AC = ./2- and angle CFB = 0 then cost) is

(A) 1 ( 3) 0
2
1
(c) (D)
2 V2
Sol. B
Select 'C' as origin
1
2 I
1 ,h

Slope BE = -Nh
= CD I BE = ZBFC = 90°
= cos 0 = 0

17. In-circle of a triangle ABC, with radii 4 units touches side BC at D such that BD = 8 units and
DC = 6 units, then
MSC is acute with perimeter = 21 units
AABC is right angled with area = 168 sq. units
AABC is obtuse with area = 84 sq. units
AABC is acute with area = 84 sq. units
SW. D
We are given r = 4 and s - b = 8 and s - c = 6
B
as r = (s - b) tan - and r (s - c) tan -
2 2
B 1 C 2
= tan - = - and tan - = -
2 2 2 3
A B A 4
again as tan-tan- 1 = tan- -
2 2 2 7
A
As r = (s - a) ta n - = (s - a) = 7
2
s = (s - a) + (s - b) + (s - c)
= 7 + 8 + 6 = 21 = perimeter = 42 units
A = r.s. =.4 x 21 = 84 sq. units.

18. Two directrices of a hyperbola are 3x + 4y + 10 = 0 and 3x + 4y - 10.= 0, if one of the focii is at
S(6, 8) and C is centre then eccentricity of hyperbola is

(A)4 (B)
2
(C) (D) c/T)
Sol. B
Distance of focus from directrices 3x + 4y + 10 = 0 and 3x + 4y - 10 = 0 are 12 and 8 units
respectively.
= focus is nearer to 3x + 4y -10
a a
ae - - =8 and ae + - =12

e=

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 25 AITS-PT-II-PCM(S)-JEE(Mairi)114

Two circles passing through A(1, 2) and E(2, 1) touch the fine 4x + By -7 = 0 at B and D. The
coordinates of C such that ABCD is a parallelogram is

(A) 5 , - 9)
L- - (8) (0,3)
(2 2
(D) ( 3 3 )

Sol. A
Point C lies on AE such that mid point of AC lies on BD
Equation AE is x + y = 3 C .s (a, 3 - a)
1+a 3 - a +2
Mid point of AC = ( ) lies on 4x + By - 7 = 0
2 2
15 9
"= 7'13=
•
Least positive angle x satisfying the equation •
sin3 x + sins 2x + sin3 3x = (sin x + sin 2x + sin 3x)3 is given by

Sol. D
As (a + b + c)3 = a3 + b3 + c3 (a + b)(b + c)(c + a) = 0
(sin x + sin 2x)(sin 2x + sin 3x)(sin 3x + sin x) = 0
3x x 5x x
.2 sin—cos- or 2 sin — cos -= 0
2 2 2 2
or 2sin2x cosx = 0
271
On solving least positive angle is — .
5

Tangent and normal are drawn at any point P on the parabola y2 = 4ax such that tangent
intersects x-axis at Q and normal intersects the curve at R such that chord PR subtends angle
900 at the vertex, then area of triangle PQR is
(A) 18a2 (B) 18-5 a2
(C) 9a2 (D) 9Ja2
Sol. B
2
Let P a- (at, 2ati) and R 7-• (at22, 2a12), then t2 = -t1 - (1)
ti
and t1t2= --4 ...(2) and Q 7- (-ati2, 0)
-at2 0 1
1
then APOR = — at? 2at, 1 Ha2t,
2 -t2)21
2at2 1

using (1) and (2) APQR = 18.5 a2

Point P lies on the curve cosy = sinx; then number of tangents that can be drawn from point P to
the curve x2 + y2 = 1 is
(A) 2 (8) 0
(C) 1 for some positions of P (D) 3
Sol. A
Let (cos0, sine) be any point on x2 + y2 = 1

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If curve intersects cosy = sinx

cos(sin0) = sincos0
cos(sin0) = cos(- - cos0)
2

sine = 2rin + (LIcos0)

2

sin° ± cos° = 2nn -

2
but 'sin° ± cosi no solution
no intersection.=> point P always lies outside.

23. If CI : x2 + y2 - 2ax + c = 0 lies completely inside C2 : X2 + y2 - 2bx + c = 0 (a # b), then

(A) c > ab > 0 (B) ab > 0, c < 0
(C) ab > c > 0 (D)ab<0;c> 0
Sol. C
Using distance between centres <11'1 - r2I
\Aa - b)2 <11a—
2 - c - 41)2 -
squaring and solving we get ab > c> O.
24. Let C1 be a circle with centre 01(0, 0) and radius 1 and C, be the circle with centre 02(t, t2 + 1) ; t
R and radius 2, then
Ci and C2 have no common tangent
CIand C2 have at least one common tangent
C1 and C2 have exactly one common tangent
Ci and C2 have exactly 3 common tangents
Sol. B
For the two circles 0102 - r21 V t E R.

25. If ABC is a triangle such that A E (1,2) and BE (5, 5) with BC = 9 and AC = 12 units, then slope
of altitude CD is (D is a point on BC)
4
(A) (B) ±
3 3
3
4
Sol. A
As common chord is perpendicular to the line joining centres
so, drawing circles with A and B as centre and radius 12 and 9 units respectively, we get circles
as
122
and (x - 5)2 + (y 5)2 = 92
Common chord = 4x + 3y - 54 = 0.

26. Circumradius of an isosceles AABC with A = B; is 4 times its inradius; Then cosA is root of the
equation
(A) x2 - x - 8 = 0 (B) x2 - x - 4 = 0
(C) 4x2 - 4x + 1 = 0 (D) 8x2 - 8x + 1 = 0
Sol. D
A A
As R = 4r = 4 x 4R sin - sin - cosA
2 2
8(1 - cosA) cosA = 1
8cos2A - 8cosA + 1 = 0

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 27 AITS-PT-II-PCM(S)-JEti(Main)114
.. •

Tangent and normal are drawn at the end points of focal chords of parabola y2 = 4ax to form a
rectangle. Then locus of circum-centre of rectangle is
(A) ax = y2 + 2a2 (B) 2ax = y2 + a2
2y2 a2 (D) 2ax = y2 + 2a2
(C) 2ax =

Sol. D
Centre is midpoint of ends of focal chord
= 2h = a(q +1) (1)
and 2k = 2a (ti +t2 ) (2)
with 102 = —1
Eliminating t1 and t2 required locus is 2ax = y2 + 2a2

A point P is 9 units from the centre of a circle of radius 15 units. Then the total number of different
chords of circle containing P and have integral lengths, is
(A) 5 (B) 6
(C) 7 (D) 8

Sol. C
Length of smallest chord .= 23/152 — 92 = 24
Length of biggest chord = diameter = 30
Again length of any chord = 21152 _ x2
= 24 5 24152 — x2 <30
= Length of chord through P with integral
Length are 24, 25, 26, 27, 28, 29, 30
Number of chords = 7.

Let 0 be the circumcentre of acute angled /ABC and let rl, r2 and r3 be the radii of the circles
drawn on the altitudes OD, OE and OF of triangle OBC, OCA and OAB as diameter then
a 2 b2 b2
minimum value of + -T + is
r2
(A) 36 (8) 72
(C) 144 (D) 216

Sol. C
ZBOC = 2ZBAC = 2/SOD
OS a
= ta n A = — = —
OD 4ri
a 2
= 16tan2 A
ri2
a2 %1/3
-T =16Etan2 A 16 x 3(tan2 A tan2 B tant) =144

In a AABC, 1— cosB cosC = sinB sinC sin2A then triangle is

(A) right-angle isosceles
(8) isosceles where equal angles are greater than —
7`
4
equilateral
scalene triangle
Sol. A

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AITS-PT-II-PCM(S)-JEE(Main)/14

As sin2 A 5 1
cos B cos C + sin B sin C sin2 A < cos B cos C + sin B sin C
cos (B —C) 1
cos (B — C) = 1 B = C
2 1 — cos B cos C 1— cos2 B
sin A = =1
sinBsinC sin2 B

A= I
2

•
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•
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