Tufftride - Qpq-Process: Technical Information
Tufftride - Qpq-Process: Technical Information
Tufftride - Qpq-Process: Technical Information
Technical Information
TUFFTRIDE® - QPQ - Process
Salt bath nitrocarburizing by the TUFFTRIDE process has
been applied in a wide range of industries throughout the
world for many decades. It is used to improve the wear
resistance, the fatigue strength and – in particular when
combined with the oxidative cooling – the corrosion
resistance of components made from steel, cast iron and
sintered iron materials. In many cases the TUFFTRIDE
process is used as an alternative to other surface
engineering processes such as case hardening, galvanic
(e.g. hard chrome plating), and other coating processes
(plastic coating, painting, laser coating etc.), also plasma
or gas nitrocarburizing with equally good or improved
quality and greater economy.
1
As the regeneration takes place without any change in
the volume of the nitrocarburizing bath, part of the melt
does not have to be bailed out. Drag-out losses which
occur when the parts are removed from the bath are
supplemented with TF 1 replenisher salt. Unlike gas
nitriding or gas nitrocarburizing, the substances – TF 1
and REG 1 - needed for the TUFFTRIDE QPQ process,
do not contain constituents classified as toxic or harmful
to the environment.
2
This complete process sequence is shown in Fig. 2 and
is in fact the TUFFTRIDE QPQ process. QPQ means
Quench Polish Quench and comprises TUFFTRIDE
treatment with oxidative cooling, mechanical processing
and oxidative post treatment in a salt melt.
Composition and
thickness of the
nitride layer
$
&" '()*+ - , ,
Compound layer
, ,
During salt bath nitrocarburizing by
"
"#
Fig. 3
3
In the metallographic analysis of salt bath nitrocarburized
components, that part of the total layer known as the
compound layer is defined clearly from the diffusion layer
thereunder as a slightly etched zone. During the diffusion
of atomic nitrogen the compound layer is formed. The
growing level of nitrogen results in the limit of solubility in
the surface zone being exceeded, which causes the
nitrides to precipitate and form a closed compound layer.
4
But the actual nitrogen penetration
is also considerably deeper than the
darker etched area visible metallo-
graphically.
sind Richtwerte der Kernfestigkeit und Oberflchen-
!!"#$%
& ' () * () * () +
Ck15 1.1141 600 550 350 300 200
C45W3 1.1730 750 - 850 700 - 800 450 350 250
Ck60 1.1221 750 - 900 700 - 800 450 350 250
20MnCr5 1.7147 800 - 950 800 - 900 600 450 400
53MnSi4 1.5141 850 - 950 800 - 900 450 400 350
90MnV8 1.2842 1000 - 1200 900 - 1100 550 450 400
42CrMo4 1.7225 900 - 1200 900 - 1100 650 500 450
X19NiCrMo4 1.2764 900 - 1100 900 - 1000 600 500 450
55NiCrMoV6 1.2713 1200 - 1400 1150 - 1300 650 550 500
56NiCrMoV7 1.2714 1300 - 1500 1250 - 1400 650 550 500
50NiCr13 1.2721 1200 - 1350 1100 - 1200 600 500 450
X20Cr13 1.2082 1000 - 1200 1000 - 1200 > 900 600 450
X35CrMo17 1.4122 1000 - 1200 1000 - 1200 > 900 700 550
X210Cr12 1.2080 1500 - 1700 1400 - 1600 > 800 600 450
X210CrW12 1.2436 1500 - 1800 1400 - 1650 > 800 600 500
X165CrMoV12 1.2601 1400 - 1900 1400 - 1700 > 800 650 500
45CrMoW58 1.2603 1500 - 1800 1400 - 1700 800 700 600
X32CrMoV33 1.2365 1700 - 1800 1600 - 1750 > 900 850 700
X38CrMoV51 1.2343 1700 - 1900 1500 - 1700 > 900 850 700
X37CrMoW51 1.2606 1700 - 1900 1600 - 1800 > 900 800 700
X30WCrV53 1.2567 1700 - 1900 1600 - 1800 > 900 850 750
X30WCrV93 1.2581 1500 - 1800 1500 - 1700 > 900 850 800
Fig. 6
5
Changes in component
properties through the
QPQ treatment
Corrosion resistance
rust.
Fig. 8
6
In the ground condition, corrosion
occurred after only a short time.
After 90 minutes salt bath nitro-
carburizing followed by oxidation
in the cooling bath the corrosion
resistance was over 200 hours.
Lapping does not change the
resistance of the samples. After
Surface roughness Rm in µm
oxidative post treatment in the
cooling bath (25 mins. at 370°C),
figures of over 400 hours will be
obtained.
7
Fig. 11 shows the results obtained on samples made
from C45 treated by different surface engineering
processes after a total immersion test lasting 2 weeks
and carried out in accordance with the Standard.
With a weight loss of 0.34 g/m2,
this sample is much better than
the galvanic or chemically coated
ones.
In the case of 12 µm hard chrome !"
# $
and even 45 µm double chrome
%
plating, the weight loss was
around 7 g/m2 and was thereby &'# (
more than 20 times greater than )*# , -
that of the nitrocarburized sam- %, &' %
ples. , -
.!# / &- / 0 .# -%
In the age hardened condition,
the 20 µm nickel layer showed a Fig. 11
weight loss of 2.9 g/m2. Only the
Triplex layer containing 37 µm
copper, 45 µm nickel and 1.3 µm
chrome is comparable with the
TUFFTRIDE QPQ salt bath treat-
ed sample.
8
The question is often raised as to the wear resistance of
the diffusion layer. Fig. 12 shows a comparison of the
wear behaviour of rocker arms treated by two different
heat treatment processes. It shows the wear on the run-
ning surface of the rocker arm
which run against a salt bath
nitrocarburized camshaft made
from chilled cast iron. Although
Influence of the surface treatment on the wear of a rocker arm
the surface hardness of the case
hardened rocker arm was slightly
0,25 reduced by nitrocarburizing, the
Loss of weight in g of the running surface
Case hardened
much improved wear resistance
Case hardened
0,20 and TUFFTRIDE due to the presence of the com-
treated
pound layer, to approximately 80
0,15 hours running time is clearly visi-
Material:
CrMo alloyed case ble.
0,10 hardening steel
Camshaft: chilled
cast iron, After 70-80 hours, the wear pro-
0,05 TUFFTRIDE treated,
r.p.m. 1000
file then runs parallel to that of the
Load =
76-86 kp/mm2 case hardened only rocker arm,
0 20 40 60 80 100 Oil: SAE 10 W 30 which is attributable to the pro-
Running duration in h (80¡C)
tection given by the diffusion
layer. A spontaneous increase in
wear after the loss of the com-
Fig. 12
pound layer was not observed.
9
Another interesting factor in connection with the wear
resistance and running properties is the friction coeffi-
cient of the outer surface layer. The interfacial reactions
which occur during sliding are not so much determined
by the absolute hardness of the running partner but by
the material partnering, their microstructural composi-
tion, surface geometry and the lubricant used.
10
The TUFFTRIDE treatment increases the rotating bend-
ing fatigue strength and the rolling fatigue strength of
components. These are mainly influenced by:
+!
,-..,/01 )*) In this connection we would like to
#!
#
point out that hard chrome plating
reduces the rotating bending
" fatigue strength of the base mater-
σ
#
ial. A similar situation prevails with
α' $ % & $ electro galvanizing. Nitrocarbu-
rizing, however, always increases
(
)*)
the fatigue strength.
x
#!
Fig. 15 shows the results of a
fatigue strength test conducted
on notched samples made from
material C45N. QPQ treatment
increased the fatigue strength by
! more than 50 %. Hard chrome
plating, however, reduced the
fatigue strength by 20 %.
Fig. 15
11
Practical application
of the TUFFTRIDE QPQ process
Fig. 17
12
Fig. 18 shows gas springs and QPQ treated piston
rods. These parts are mainly built into tailgate flaps
and engine bonnets of cars, as well as into the bag-
gage flaps and cabin doors of aeroplanes.
Fig. 19
Fig. 20
13
TUFFTRIDE® plants and
their economics
!"
# $
! %# $ #% $
Fig. 22
14
A comparison of the economics of
this process with other surface
engineering processes also shows
#
$ %&&'( !"! some favourable aspects. Cost
comparisons made by various
users showed that major savings
can be made. As an example,
please see the cost comparison in
Fig. 23
Summary
In addition to the improvements in the properties such as
wear protection, fatigue strength and sliding properties,
the TUFFTRIDE treatment plus oxidative cooling and/or
post treatment produces a major increase in the corro-
sion resistance. Results of tests and practical applica-
tions show that the quality of the treated components is
often superior to that of electro galvanic layers and other
nitrocarburizing processes. This opens a broad field of
application for the TUFFTRIDE process, which can often
be accompanied by expensive materials being replaced
by lower-cost ones.
15
NOTES:
Details we provide on our products and appliances as well as our plants and
process methods are based on comprehensive research work and operational
experience. We provide such data either verbally or in writing to the best of our
knowledge and belief on the understanding that they do not present any
warranty concerning the existence of specific characteristics in our products,
but reserve the right to make technical modifications in the cours of product
development.
This does not, however, relieve the user of his responsibility to check our data
and recommendations for his own application before using them. This also
applies - particularly for shipment abroad - with regard to the maintenace of
protection rights of third parties and to applications and process methods not
expressly declared by ourselves in writing. In the event of loss our liability is limited
to replace goods and services on the same scale as is stipulated for quality
defects in our General Conditions of Scale and Delivery.
11/03 1000 Gr
Durferrit GmbH
Industriestrasse 3
D-68169 Mannheim
Phone + 49 (0) 621 / 3 22 24-0
Fax + 49 (0) 621 / 3 22 24-809
www.durferrit.com E-Mail: [email protected]