Steam Genarator
Steam Genarator
Steam Genarator
1.1 Introduction…………………………………………………………………….
2.1 Introduction……………………………………………………………………
2.3 Steam………………………………………………………………………….
2.4 Fuel……………………………………………………………………………..
3.0 FURNACE
3.1 Introduction……………………………………………………………………
4.0 SUPERHEATER
4.1 Introduction…………………………………………………………………..
5.0 DRUMS
5.1 Introduction…………………………………………………………………….
6.1 Introduction……………………………………………………………………….
7.0 AIRHEATER
7.1 Introduction……………………………………………………………………….
Bag filter
9.1 Introduction…………………………………………………………………….
10.1 Introduction……………………………………………………………………
1.1 INTRODUCTION
Indian power demand is met mainly from thermal, hydro and nuclear power. Non-conventional energy power
production is very much negligible. Out of the main power producing sources thermal plant produces 48215 MW
(69%), hydro plant produces 19300 MW (28%), nuclear plant produces 2033 MW (3%) as on 31st March 1992. In
the above power plants 72% of the generation is from thermal and nuclear, where steam generation is one of the
main activity. In the years to come, the demand of electricity is going on increasing and already most of water
resources suitable for power generation is in service. Except from gas turbines power the most of new electric
capacity has to be met by utilizing steam.
Steam boiler today range in size from those to dry the process material 500 kg/hr to large electric power station
utility boilers. In these large units pressure range from 100 kg/cm² to near critical pressures and steam is usually
superheated to 550°C. In India BHARAT HEAVY ELECTRICALS LTD (BHEL) is the pioneer in developing the
technology for combustion of high ash coal efficiently in atmospheric bubbling fluidized bed. From where lot of
industries in boiler manufacturing starts. Only after the year 1990, India’s foreign policy was changed, various
foreign steam generator manufacture entered into Indian power market bringing various configuration and
competitiveness in the market.
The most common source of steam at the beginning of the 18th century was the shell boiler. Little more than a kettle
filled with water and heated from the bottom. Olden day boiler construction were very much thicker shell plate and
riveted constructions. These boilers utilize huge amount of steel for smaller capacity. Followed this shell and tube
type boilers have been used and due to direct heating of the shell by flames leads severe explosion causing major
damages to life and property. For safety need, after the Indian independence India framed Indian boiler regulations
in 1950, similar to various other standards like ASME, BS, DIN, JIS followed world wide. Till date IBR 1950 is
governing the manufacturing and operation of boilers with amendments then and there. Indian sugar industry uses
very low pressure (15 kg/cm²) inefficient boilers during independence now developed to an operating pressure of 65
kg/cm² and more of combined cycle power plant. If we analysis most of the boilers erected in pre-independence
period were imported boilers only and now steam generators were manufactured in India to the world standards on
budget, delivery and performance. In power industry India made a break through in the year 1972, India’s first
nuclear power plant was commissioned at Tarapore. This plant was an pilot plant meant for both power and
research work. This was made in collaboration with then soviet republic of Russia. Now India has its own nuclear
technology for designing nuclear power plant. Even though there is a development, Indian industry has to go a long
way in power sectors.
In early days, as individual electric generating stations increased in capacity, the practice was merely to increase the
number of boilers. This procedure eventually proved to be uneconomical and larger maintenance. Afterwards,
individual boilers were build larger and larger size, however the size became such that furnace floor area occupation
was more. Therefore further research work have been developed in this area and technologies such as pulverized
coal fired furnace, circulated fluidized bed furnace, pressurized circulated fluidized furnace (still under research
stage) were developed. These modern technologies have higher heat transfer coefficient in furnace and allow higher
volumetric combustion rates.
TECHNOLOGY
This is the oldest method of firing fuel. Fuel will be spread over the grate, where the fuel is burnt. Fuel feeding will
be done manually or mechanically to have a sustained flame. In this type burning will be done at higher excess air.
Incoming air will be used for cooling the grate.
Types of grate
Common types of grate that are used for fuel are fixed grate, pulsating grate, dumping grate, travelling grate. Each
type of grate differ slightly in their construction and arrangement. However the combustion phenomenon remains
same.
Travelling grate
The travelling type is a continuous grate which slowly convey the burning fuel through the furnace and discharge
the ash to an ash pit. Grate speed is regulated by the amount of ash discharging to ash pit ( 0 to 7m/hr)
Pulsating grate
The pulsating grate is non- continuous grate. The grate surface extends from the rear of furnace to ash pit. Here the
grate will be given a racking motion at pre determined frequency depending on the fuel/ash bed depth.
Dumping grate
Dumping grates are also a non-continuous type grate. The grate is split into longitudinal sections, one for each
feeder. Fuel is distributed on the grate and burns. When ash depth gets to a depth where air can not diffuse it , the
grates are tilted or ash is dumped into the hopper in the following manner.
Alternating fuel feeding is stopped and grate is tilted by lever arrangement, the actuation can be done either
manually or pneumatic cylinder.
In dumping grate the grate sections should be designed in such a way that, while dumping the ash part of grate
surface not available for burning. In poorly designed dumping grate there may be steam pressure. Therefore while
sizing grate sections care should be taken such that while dumping part of the grate, other fuel feeder and remaining
sections should able to take the full load.
Dumping grate is similar to fixed grates, it is best suitable for bagasse where the fuel is of low calorific value and
having high moisture content. Therefore air alone can acts as a cooling medium. If we use coal the grate bar may
not with stand higher temperature and additional cooling by water tube is necessary. Travelling grate is suitable for
burning coal and lignite. As the grate rotates, the grate bar gets heated and cooled by incoming air for the half of the
cycle and remaining half of the cycle grate bar cooled by the incoming air.
Spreader stoker
Mechanical spreader
The spreader stoker feeder takes fuel from the feeder hopper by either a small ram or a rotating drum and delivers it
into a spinning rotor. An adjustable trajectory plate is located between the feed mechanism and the rotor. Adjusting
the trajectory plate fuel can be feed through out the entire length of the furnace.
Pneumatic spreader
In this rotor is replaced by high pressure air lines from Secondary air fan is used to spread the fuel into the furnace.
The fuel is carried into the furnace by means of pneumatic system and the air flow adjustment makes the fuel to flow
near or farther of the furnace.
TECHNOLOGY
Flame has a tendency to burn upward only. This forms the basic concept of burner. Whenever fresh fuel enters into
the ignition zone it starts burning upwards and the flame will not come downwards to the incoming fuel, by this
property combustion can be controlled easily. Hence it is always better to bring the oil or gas train from bottom of
the burner.
A liquid or gas fuel has flowable property by nature and it has a lower ignition temperature. When the fuel is forced
to flow through the nozzle it will spread though an predetermined length and burn completely from the point of
entry to the firing zone estimated. The fuel flow can be controlled by means of control valves.
CHARACTERISTICS OF OIL
In today’s climate of fluctuating international fuel prices and quality, the emphasis on the ability of the boiler on low
quality fuel oils has become more greater. In the international market, the quality of the residual fuel oils is
constantly getting poorer due to the development of more sophisticated cracking methods and also our indigenous
crude production falls short of our requirements, about 15 million tons of crude is imported from outside sources.
These outside sources are many, our refineries handle a variety of crude. Since the inherent properties of the
finished petroleum products are directly dependent on the parent crude, one can imagine the petroleum involved in
producing residual fuel oil within narrow limits of specifications, especially with respect to specified characteristics
like carbon residue, asphaltenes and metallic constituents is not possible.
Flash point
Flash point is important primarily from a fuel handling stand point. Too low a flash point will cause fuel to be a fire
hazard subject to flashing and possible continued ignition and explosion. Petroleum products are classified as
dangerous or non dangerous for handling purposes based on flash point as given below.
Petrol
Solvent 1425
Hexane
HSD
Furnace oil
LSHS
Pour Point
The pour point of the fuel gave an indication of the lowest temperature, above which the fuel can be pumped.
Additives may be used to lower the freezing temperature of fuels. Such additives usually work by modifying the
wax crystals so that they are less likely to form a rigid structure. It is advisable to store and handle fuels around
10°C above the expected pour point.
Viscosity
Viscosity is one of the most important heavy fuel oil characteristics for industrial and commercial use, it is
indicative of the rate at which the oil will flow in fuel systems and the ease with which it can be atomized in a given
type of burner. When the temperature increases viscosity of fuel will reduce.
The viscosity needed at burner tip for satisfactory atomization for various types of burners are as follows.
In centi stokes
Steam jet 29 to 37
Sodium, Potassium, Vanadium, Magnesium, Iron, Silica etc. are some of the metallic constituents present in fuel oil.
Of the above metals, sodium and vanadium are the most troublesome metals causing high temperature corrosion in
boiler super heater tubes and gas turbine blades. Much of the sodium is removed from the crude oil in the desalting
operation, which is normally applied in the refinery and additional sodium can be removed from the finished fuel oil
by water washing and centrifuging.
Vanadium is found in certain crude oils and is largely concentrated in fuel oil prepared from these crude. No
economical means for removal of vanadium from the residual fuel oil is available. However certain additives like
magnesium are available to minimize the effect of vanadium.
Asphaltenes are high molecular weight asphaltic material and it requires more residence time for complete
combustion. Asphaltenes as finely divided coke may be discharged from the stack. Residual fuel oils may contain
as much as 4% asphaltenes.
Petroleum fuels have a tendency to form carbonaceous deposits. Carbon residue figures for residual fuel oils from 1
to 16% by weight. This property is totally dependent on the type of crude, refining techniques and the blending
operations in refinery.
Fuels with high carbon residue and asphaltenes requires large combustion chamber and hence while designing the
boiler for such fuel the volumetric loading has to be of the order of 2 lakhs Kcal/m3hr
TECHNOLOGY
When coal is powdered to micron size it can be conveyed easily by air in pipelines and the pulverized coal behaves
as if that of oil and hence the same can be easily burnt in pulverized fuel burners. The heat release by the burners in
very high and un-burnt carbon is almost equal to zero. Hence efficiency achieved by pulverized burners is much
more than any type of coal combustion.
There are two systems of pulverized firing 1.0 direct firing 2.0 indirect firing.
In the direct firing system, raw coal from the storage area is loaded on a conveyor and fed to a coal crusher. A
second conveyor system loads coal into the coal storage bunker located over the coal pulverization system. Coal via
gravity feed is delivered through a down spout pipe to the coal feeder. A coal shutoff gate is provided prior to the
coal feeder inlet to allow emptying the system down stream. The coal feeder meters the coal to the crusher dryer
located directly below the feeder discharge. A primary air fan delivers a controlled mixture of hot and cold air to the
crusher dryer to drive moisture in the coal facilitating pulverization the primary air and crushed coal mixture is then
fed to the coal pulverizer located below the crusher dryer discharge. Selection of pulverizer has to be analyzed
critically, since it is one of the important equipment where the wear and tear is more. For the soft lignite Beter
wheel is preferable and for hard lignite, coal like fuels heavy pulveriser of ball and hammer mill is preferable. The
coal is pulverized to a fine powder and conveyed through coal pipes to the burners. Primary air is the coal pipe
transportation medium.
The indirect firing system utilizes basically the same coal flow path to the pulverizer. After the classification of
pulverized coal, it is delivered to a coal storage bin. When needed to fire the boiler the pulverized coal is then
conveyed to the burners by an exhaust fan. This method requires very special provisions to minimize risk of fire or
explosion. Of the two systems, the direct firing is more common.
Neyveli lignite power corporation has pulverized boiler of direct firing system.
TECHNOLOGY
When air or gas is passed through an inert bed of solid particles such as sand supported on a fine mesh or grid. The
air initially will seek a path of least resistance and pass upwards through the sand. With further increase in the
velocity, the air starts bubbling through the bed and particles attain a state of high turbulence. Under such
conditions bed assumes the appearance of a fluid and exhibits the properties associated with a fluid and hence the
name fluidized bed.
If the sand, in a fluidized state is heated to the ignition temperature of the fuel and fuel is injected continuously into
the bed, the fuel will burn rapidly and attains a uniform temperature due to effective mixing. This , in short is
fluidized bed combustion.
While it is essential that the temperature of bed should be equal to the ignition temperature of fuel and it should
never be allowed to approach ash fusion temperature (1050° to 1150°C ) to avoid melting of ash. This is achieved
by extraction of heat from the bed by conductive and convective heat transfer through tubes immersed in the bed.
If the velocity is too low fluidization will not occur, and if the gas velocity becomes too high, the particles will be
entrained in the gas stream and lost. Hence to sustain stable operation of the bed, it must be ensured that gas
velocity is maintained between minimum fluidization and particle entrainment velocity.
Advantages of FBC.
1.0 Considerable reduction in boiler size is possible due to high heat transfer rate over a small heat transfer area
immersed in the bed.
2.0 Low combustion temperature of the order of 800 to 950°C facilitates burning of fuel with low ash fusion
temperature. Prevents Nox formation, reduces high temperature corrosion and erosion and minimize accumulation
of harmful deposits due to low volatilization of alkali components.
3.0 High sulphur coals can be burnt efficiently without generation of Sox by feeding lime stone continuously with
fuel.
4.0 The units can be designed to burn a variety of fuels including low grade coals like floatation slimes and
washery rejects.
5.0 High turbulence of the bed facilitates quick start up and shut down.
6.0 Full automation of start up and operation using simple reliable equipment is possible.
7.0 Inherent high thermal storage characteristics can easily absorb fluctuation in fuel feed rate.
TECHNOLOGY
Atmospheric circulating fluidized bed (ACFB) boiler is a devise used to generate steam by burning solid fuels in a
furnace operated under a velocity exceeding the terminal velocity of bed material. I.e., solid particles are
transported through the furnace and gets collected in the cyclone at the end of furnace and again recycled into
furnace by means of pressure difference between fluidized bed and return particle.
The mechanism is similar to AFBC. However in AFBC the fluidization velocity is just to make the particles in
suspended condition. In ACFB boiler, special combination of velocity by primary air and secondary air, re-
circulation rate, size of solids, and geometry of furnace, give rise a special hydrodynamic condition known as fast
bed.
Furnace below secondary air injection is characteristic by bubbling fluidized bed and furnace above the secondary
air injection is characteristic by Fast fluidized bed. Most of the combustion and sulphur capture reaction takes place
in the furnace above secondary air level. This zone operates under fast fluidization. In CFB boiler number of
important features such as fuel flexibility, low Nox emission, high combustion efficiency, effective lime stone
utilization for sulphur capture and fewer fuel feed points are mainly due to the result of this fast fluidization.
In fast fluidization heavier particles are drag down known as slip velocity between gas and solid, formation and
disintegration of particles agglomeration, excellent mixing are major phenomenon of this regime.
2.0 The boiler is required to fire a low grade fuel or highly fluctuating fuel quality.
The advantage of operating fluidized combustion at the elevated pressure ( about 20 bar) is, reduction in steam
generator size can be achieved and make possible the development of a coal fired combined cycle power plant. The
development of pressurized fluidized bed combustion is still in research stage only. With help of pressurized hot
gas coming out of the furnace is cleaned primarily by a cyclone like CFBC boiler and the gas is expanded in a
turbine and the exhaust gas from turbine is further cooled by the heat exchanger. The aim behind the development
of pressurized fluidized bed are:
1.0 To develop steam generator of smaller size for the higher capacity.
3.0 To develop turbines which make use of solid fuels such as coal, lignite etc.,
As explained earlier HRSG can be classified into two types, one is for maintaining process parameter such as
temperature and other is in the point of economic point of view.
The process steam generator are generally referred by the term called waste heat recovery boiler ( WHRB) where
the gas contains heat in excess, this excess waste heat has to be recovered or removed by any means so that the
process parameter can be maintained. ( e.g. Sulphuric acid plant, hydrogen plant, sponge iron plant, Kiln exhaust
etc.,)
The steam generator stands behind the gas turbine are usually referred as Heat recovery steam generator.
The HRSG or WHRB the design greatly vary with respect to the size of the plant, the gas flow, gas volumetric
analysis, dust concentration and sulphur di oxide concentration. In HRSG the gas quantity and inlet temperature is
fixed and for different load the variation of heat will not be proportional and hence at part loads the heat absorbed at
different zones will vary widely and hence for different loads the performance of the HRSG to be done.
2.0 STEAM,GAS and AIR
2.1 INTRODUCTION
In steam generator water, steam, gas and air are the working fluids in this air and gas have similar properties.
Understanding the properties of gas and air are almost one and the same. I have grouped steam and gas as one unit
and water as a separate unit just because understanding the behavior of steam and gas is more important in design
point of view where as knowledge of water is more important in operational point of view.
Heat
Heat is defined as the form of energy that is transferred across a boundary by virtue of a temperature difference.
The temperature difference is the potential and heat transfer is the flux. In other words heat is the cause and
temperature is the effect.
Energy
Energy of a body is its capacity to do work and is measured by the amount of the work that it can perform.
Potential energy of a body is the energy it possesses by virtue of its position or state of strain.
Enthalpy
Enthalpy is the quantity of heat that must be added to the fluid at zero degree centigrade to the desired temperature
and pressure. Enthalpy is defined as heat within or heat content of the fluid.
Entropy
The word entropy is derived from a Greek word called ‘tropee’ which means transformation. The unit of entropy is
Joules/kelvin.
Specific heat
Specific heat of a substance is defined as the amount of heat required to raise the temperature of one kilogram of
substance through one degree kelvin. All liquids and solids have one specific heat. However gas have number of
specific heats depends on the condition with which it is heated.
Cp = f(T)
Specific heat of a substance is defined as the amount of heat required at constant pressure to raise the temperature of
one kilogram of substance through one degree kelvin.
Integral constant pressure specificheat
It is the average heat required to rise the temperature between two temperature difference t1 and t2 i.e., Cp = ( H2 –
H1)/(t2 –t1)
H = f(Cp/T)
Specific heat of a substance is defined as the amount of heat required at constant volume to raise the temperature of
one kilogram of substance through one degree kelvin.
NTP condition is at Normal temperature and pressure, i.e., the properties measured at 0°C or 273.15 °K and
pressure 1.01325 bar or 1.03 atm
STP condition is at Standard temperature and pressure i.e., the properties measured at 25°C or 298.15°K and
pressure 1.01325 bar or 1.03 atm.
Viscosity
Viscosity of a liquid is its property, due to the frictional resistance between the fluid particles (cohesion between
particles) or between fluid and the wall. Viscosity of fluid controls the rate of flow.
The shear stress on a layer of a fluid is directly proportional to the rate of shear strain. ( Velocity gradient )
τ α ν/l where τ is shear stress and ν is velocity , l is the distance or gap between layers.
τ = μ ν/l where μ is the constant of proportionality and is known as absolute viscosity or dynamic viscosity.
Thermal conductivity
Thermal conductivity is the property of substance, that its ability to conduct heat and expressed in W/mK.
Kilogram
Kilogram is the mass of one international prototype made of platinum iridium cylinder preserved at the international
bureau of weights and measures at paris.
Meter
Meter is the length between two transverse lines en-grooved in platinum iridium bar at 0°C. or The meter is the
length equal to 1650763.73 vacuum wave length of the orange light. ( λ = 605.8 mm of the Krypton 86 discharge
lamp)
Second
Second is the duration of 9192631770 periods of the radiation corresponding to the transition between two specified
energy level of the Caesium –133 atom. Or 1/86400th part of mean solar day.
Specific volume
For heat and mass transfer calculations, we have to know the above properties.
The properties where mainly depends on the temperature for gases and temperature and pressure for steam. The
required equation for derivation is given at appropriate places.
Cp /R = f(T)
R = Cp – Cv
Cv = Cp - 1
RT ⎠ R
Tn
RT ⎠ R RT
Ts
Specific entropy,
R R⎠ R
Tn
Specific free enthalpy
G = H -S
RT RT R
The temperature dependent specific heat (Cp) can be represented by an equation of 4 th degree polynomial as shown
below
H = a1 + a2T + a3T² + a4T3 + a5T4 + a8/T (for temperature from 273K to 1000K
RT 2 3 4 5
H* = a1 + a2T + a3T² + a4T3 + a5T4 + a6/T (for temperature from 273K to 1000K
RT 2 3 4 5
R 2 3 4
RT 2 6 12 20 T
Thermal conductivity,
kg = kn + P1 XH2O + P2 XCO2
Prandtl number,
2.3 STEAM
We can see in day to day life the process of boiling water to make steam. Steam is water in the vapour or gaseous
state. It is in visible, odorless, non-poisonous and relatively non corrosive to boiler metals. Steam is uniquely
adapted by its advantageous properties for use in industrial process heating and power cycle. Thermodynamically
boiling is the result of heat addition to the water in a constant pressure and constant temperature process. The heat
which must be supplied to change water into steam without raising its temperature is called the heat of evaporation
or vaporization and the boiling point of a liquid may be defined as the temperature at which its vapour
pressure(pressure exerted due to the vapour of the liquid) is equal to the total pressure above its free surface. In
other words temperature at which the partial pressure of vapour increases to make total pressure above the liquid
surface. This temperature is also known as the saturation temperature.
EVAPORATION
Liquid exposed to air evaporate or vapourize. Evaporation is the process takes place at the surface exposed to
atmosphere. If there is any increase in ambient temperature or increase of the liquid temperature evaporation rate
becomes increased. The reduction in pressure above the liquid surfaces accelerate the evaporation rate. Evaporation
will be there at all temperature and pressure, unsaturated surrounding environment also one of the factor increases
the evaporation rate.
BOILING
Boiling is the phenomenon takes place at boiling point of the liquid. Boiling takes place throughout the liquid
column. A liquid will boil, when it’s saturated vapour pressure exceeds the surrounding environment pressure acted
upon the liquid. Hence boiling point of a liquid will change depends on the pressure exerted by the environment
over the surface.
CONDENSATION
Condensation is the change in phase of vapour phase to it’s liquid phase. When water vapour or steam comes in
contact with cooler surfaces, it gives up the heat and condenses to water. The heat released while changing from
vapour phase to liquid phase is called heat of condensation. In factories the steam released out of the main steam
line or process vents where we can see a remarkable phenomenon of indication of dryness of steam. If the steam is
dry, we can not visualize the steam coming out of the vent but after some distance we can see a white cloud. This is
due to the condensation of steam which composed of small particles of water formed when steam cooled in cooler
atmosphere. In other case if the steam is wet, the white smoke cloud is directly released from the vents.
2.4 FUEL
Combustion
Combustion or burning, is a rapid combination of oxygen with a fuel resulting in release of heat. The oxygen comes
from the air, which is about 21% oxygen and 78% nitrogen by volume.
Most fuels contain carbon, hydrogen, and sometimes sulphur as the basic composition of combustion materials.
These three constituents’ reacts with oxygen to produce carbon-di-oxide, water vapour, suphur di oxides gases
respectively and heat.
Carbon, hydrogen and sulphur are found exists in direct form in most of the solid and liquid fuels and in gaseous
fuels the combustion matter is found as hydrocarbons(combination of hydrogen and carbon). When these burn, the
final products are carbon di oxide and water vapour unless there is a shortage of oxygen, in which case the products
may contain carbon mono oxide, unburnt hydrocarbons, and free carbon.
Quantities of heat are measured in BTU, kiloCalories, or joules. A BTU is the quantity of heat required to raise the
temperature of one pound of water one degree fahrenheit. A kilocalorie is the quantity of heat needed to raise one
kilogram of water one degree celsius.
Experimental measurements have been made to determine the heat released by perfect combustion of various fuels.
The heat value is usually determined by calorimeters. When a perfect mixture of a fuel and air originally at 15.6°C
is ignited and then cooled to 15.6°C the total heat released is termed the higher heating value or Gross calorific
value. There is also one more term called lower heating value or the net calorific value it is the quantity of heat
equal to gross calorific value minus the heat absorbed by the latent heat of water moisture( inclusive of moisture
generated due to combustion of hydrogen present in the fuel) at 25°C.
=583.2 kcal/kg
Proximate Analysis
The general procedure for the analysis relating to proximate analysis is describe below as per IS 1350(partI). For full
details, the original standard may be referred to
i) Moisture
The moisture in the coal is determined by drying the known weight of the coal at 108°C±2°C
ii) Volatile matter
The method for the determination of VM consists of heating a weighted quantity of dried sample of coal at a
temperature of 900°±10°C. for a period of seven minutes. Oxidation has to be avoided as far as possible. VM is the
loss in weight less by that due to moisture. VM is the portion of the coal which, when heated in the absense of air
under prescribed conditions, is liberated as gases and vapour.
iii) Ash
In this determination, the coal sample is heated in air up to to 500°C for minutes from 500 to 815°C for a further 30
to 60 minutes and maintained at this temperature until the sample weight becomes constant.
Fixed carbon is determined by deducting the moisture. VM and ash from 100
Ultimate analysis
The ultimate analysis of fuel gives the constituent elements namely carbon, hydrogen,nitrogen, sulphur ,
hydrocarbons, nitrogen etc., For the ultimate analysis of the coal sample is burnt in a current of oxygen. As a result
the carbon, hydrogen, sulphur oxidized to water, carbon di oxide and sulphur di oxide respectively. These
constituent are absorbed solvents to estimate the percentage of C,H2,S,N etc.,
At low pressure and high temperature, all gases have been found to obey three simple laws. These laws relate the
volume of gas to the pressure and temperature. All gases, which obey these laws, are called ideal gases or perfect
gases. These laws are called ideal gas laws. These laws are applicable to gases, which do not undergo changes in
chemical complexity, when the temperature or pressure is varied. I.e., in other words laws applicable to gases which
do not undergo any chemical reaction when subject to change in pressure or temperature.
GAS LAWS
Boyle’s law
Boyle’s law states that the pressure is inversely proportional to volume and the product of pressure and volume is
constant
PV =C
Charles law-I
Charles law states that at constant pressure, volume is directly proportional to temperature.
V/T = C
Charles law-II
Charles law states that at constant volume, pressure is directly proportional to temperature.
P/T = C
Absolute scale of temperature
This scale of temperature is based on Charles law. According to Charles law at constant pressure, volume of given
mass changes by 1/273 of its volume at 0°C for every rise or fall in temperature by 1°C. if the volume of the gas at
0°C is Vo and its volume at t°C,
Vt = Vo + Vo x t = Vo (1 + t/273)
273
If t = -273°C, then volume is zero, the hypothetical temperature of –273°C at which gas will have zero volume is
known as absolute temperature or 0°K.
Avagadra’s Law
Avagadra’ s law state that the volume occupied by any gas at normal temperature and pressure is 22.41383 x 10-3 m3
per mol of gas. I.e., volume occupied by a kg mol of gas is 22.41383 m3/kg mol.
GAS EQUATION
Temperature = 273 K
n = 1 mole
Ro= PV/nT = 1.01325 x 105 x22.41383 x10-3/(1 x273) = 8.314 Nm mol-1 K-1
Daltan’s law
At a constant temperature, the total pressure exerted by a mixture of non- reacting gases is equal to the sum of the
partial pressure of each component gases of the mixture. Thus the total pressure P of a mixture of r gases may be
represented mathematically as
r
Pt = Σ pI where pi is the partial pressure of each components gas of the mixture.
i =1
If P and the molar composition (% volume) of the mixture are known pi can be calculated using the expression pi =
xi P
THEIR SIGNIFICANCE
surface
coefficient determination
friction factor
Where v is velocity
‘ d is characteristic dimension
Cp is specific heat
ρ is density
μ is dynamic viscosity
T is temperature
P is pressure
Ex.01. Estimate the air and flue gas produced per kg of the following coal analysis.
Ultimate analysis: Carbon = 39.9%, Hydrogen = 2.48% , Sulphur = 0.38 %, Nitrogen = 0.67%, Oxygen = 6.76 %,
Moisture =8% and Ash = 42%. The analysis is based on weight basis. Consider 4% carbon loss in combustion of
AFBC system.
C + O2 Æ CO2 + heat
12 kg of carbon react with 32 kg of oxygen to produce 44 kg of carbon di oxide. I.e., one kg of carbon required
32/12 = 2.666 kg of oxygen and produce 44/12 = 3.666kg of carbon dioxide.
2 kg of hydrogen react with 16 kg of oxygen to produce 18 kg of moisture. I.e., one kg of hydrogen requires 16/2 =
8 kg of oxygen and produce 18/2 = 9 kg of moisture.
S + O2 Æ SO2 + heat
32 kg of sulphur require 32 kg of oxygen to produce 64 kg of sulphur di oxide. I.e., one kg of sulphur require one kg
of oxygen and produce 64/32 = 2 kg of sulphur di oxide.
the other composition like nitrogen, argon(if present) is inert gas and it will not react with oxygen. Moisture is in
saturated form and it does not require oxygen.
Air contains 23.15 % oxygen by weight and hence the air required for 1.1986 kg of oxygen is = 1.1986/0.2315 =
5.176 kg of dry air.
Amount of wet air required considering 60% Relative humidity = 5.176 x 1.013 = 5.244 kg.
Coal requires 20% excess air for combustion in AFBC system hence wet air required for burning per kg of fuel =
5.244 x 1.2 = 6.292 kg.
Ex.02 Find the weight of water present in atmospheric air at 60% relative humidity and temperature 40°C.
For 40°C, the saturation pressure of water is = 0.075226 atm (from steam tables)
=0.045135 atm
= 0.622 x 0.045135
(1.035 – 0.045135)
= 0.02836 kg/kg.
Ex03. Estimate the efficiency of a boiler firing with coal as a fuel having GCV of 3200 kcal/kg. Furnace is
Fluidized bed boiler. Apply ASME PTC 4.1 indirect method to calculate the efficiency. Flue gas temperature
leaving the boiler is140°C and ambient air temperature is 40°C. Ash content of the fuel is 42.3% and 20% of total
ash is collected in bed and 80% ash is carried in fly ash. As per lab report the loss on ignition of ash samples
collected in bed zone and fly ash zone is 0.1% by weight and 4.4%by weight. The boiler is operating at 20% Excess
air and the dry kg/kg of gas produced =5.91 and dry kg/kg of air required = 5.696. The moisture and hydrogen
present in the fuel is 6% and 2.7% respectively.
=0.233%
Bed ash
= 0.2x0.423x0.22(900-40)100/3200
=0.5%
= kg/kg of moist in air x kg/kg of dry air( Enthalpy of steam at Tgo in 0.013ata –
=0.1043%
Note: The above implies that the water vapour at ambient temperature at partial pressure exists in steam form and
gets superheated at 140°C
= 5.824%
Note: The above implies that the water moisture present in fuel is in liquid form, during combustion it will absorb
latent heat and superheat from combustion. The hydrogen present in the fuel react with oxygen to form water. From
combustion equation of hydrogen it is found that 1 kg of hydrogen form 8.94 kg of water.
= kg/kg of dry flue gas x (Enthalpy of gas at Tgo –Air enthalpy at Tamb)x100/3200
Radiation loss,
Ex07 Estimate the FD and ID fan flow and power required for a bagasse fired dumping grate boiler, whose bagasse
consumption at 100% MCR capacity is 31000 kg/hr and the boiler is operating at 35% excess air. The fuel air
requirement is 3.909 kg/kg of fuel and gas generation is 4.873 kg/kg.
FD fan
= 34.31 m3/sec
FD fan head
Pressure head required for air flow sections like airheater, air ducts and grate are to be calculated. Now in most of
the practical applications the pressure drop works out to be 165 mm WC and the same can be assumed for this
calculation.
= 84.09 KW
Motor selected = 84.09 x 1.1 = 92.5 KW (next nearest motor standard is 110 KW)
ID fan
Fan design flow with 25% margin = 151063 x 1.25 x (273 +140)/(3600 x1.295x273)
= 61.27 m3/sec
ID fan head
Pressure head required for gas flow sections like Furnace, Bank, Economiser, air heater, gas ducts and dust
collectors are to be calculated. Now in most of the practical applications the pressure drop works out to be 230 mm
WC and the same can be assumed for this calculation.
= 225 KW
Motor selected = 225 x 1.1 = 247.7 KW (next nearest motor standard is 250 KW)
Table showing percentage margin on flow and head required for different boiler application.
fired
3.0 FURNACE
3.1 INTRODUCTION:
The design of furnace is considered as the vital part in the boiler. The furnace is the zone experiencing a high
temperature in boiler. The performance of the furnace reflects or has an impact over other parts behind it such as
super heater, evaporator, and air heaters. For instant, how the furnace design affects super heater can be illustrated
with following. If furnace outlet temperature (FOT) is high, then the next zone is super heater it gets high amount of
heat input naturally the metal temperature is high and the steam temperature also increased, which in turn reflects in
the performance and cost of material. On the other hand if the furnace is over sized the FOT will be lesser, to get
the required steam temperature the super heater heat transfer area to be increased. If the heat transfer area is
increased it calls for larger space and cost wise it becomes uneconomical.
The type of fuel, form of fuel, heat content and the properties of the fuel such as ash fusion temperature are also
form as constraint over the furnace design. The type of fuel whether solid or liquid or gas and quantity decides how
efficiently we can burn. Whether we can have a burner (for liquid & gases), solids bubbling bed or dumping or
travelling grate. When the fuel is some thing like bagasse (fibrous and long strand structure) it can be burnt well in
dumping or travelling grate.
A gaseous fuel offers fewer problems since it is clean. Fuel oil brings its own problems like high or low temperature
corrosion and additives have to be used. For coal ash fusion is the problem, since ash slag down deposits on the
wall hindering heat transfer to steam water mixture. Depends on property of coal, whether it can be crushable to
powdered form, pulverized firing or bubbling bed or cyclone furnace can be decided.
When we go for oil or gas firing, we can have higher heat flux in the furnace because of the higher emissivity of oil
flame and relative cleanliness of walls compared to coal firing. There by size of furnace will be smaller for oil or
gas fired steam generators. The volume of the furnace for oil fired boilers will be 60 to 65 percentage of pulverized
fuel firing. However, if a furnace designed for both coal and oil it is normally designed for coal and performance for
oil firing in that furnace will be carried out. When a furnace designed for coal operated with oil, the higher furnace
absorption results in a lower furnace outlet temperature. Lower FOT means super heater pick up in super heater will
be less and steam outlet temperature will be less. This is avoided by several techniques out of which, when oil is
fired FOT will be increased by gas recirculation, otherwise when coal is fired FOT will be reduced by some means
of bed absorption (This is used in FLUIDISED BED COMBUSTION techniques). Furnace size also governed by
length of flame in gas or oil fired boiler since the flame should not impinge on the water walls and cause
overheating. Likewise in coal fired boilers flue gas velocity should be optimized to prevent higher rate of erosion
due to carry over particles in flue gas. Normally a flue gas velocity of 6 to 8 meters per sec was allowed for coal
fired boilers and 12 to 15 meters per sec was allowed for bagasse fired boilers.
Water wall is receiving radiation from flames and are exposed to high heat flux and there is a possibility of over
heating. The boiling is the phenomenon, which governs the rate of heat transfer from combustion to steam water
mixture inside the tube. In boiling when bubbles formed at tube wall hinders the heat transfer which cause tubes
over heating and tube failure. This sort of boiling occurs at nucleate boiling stage. Therefore proper circulation
must be ensured to cool all tube. Circulation ratio (CR) is the ratio between mass of water circulated inside the
boiler to rate of steam generation. Hence CR is also directly related to dryness fraction of steam by the expression
CR = 1/x. which implies in one circulation 1/CR quantity of dry steam was produced. Circulation number will be
higher when the difference in density between steam and water is more (i.e.) due to higher difference in density;
steam water mixture velocity will be more thereby overheating will be prevented. If the proper circulation is not
there, circulation in the boiler circuit is effected by means of external agency (normally a circulation pump will be
used). This type of circulation is called Forced or controlled circulation.
Boiling phenomenon can be represented by a log-log plot of heat flux Vs surface temp-bulk temperature as shown
Q max.
A B C D
SURFACE TEMP
The different regimes of boiling indicated by the letters A, B, C, D. Absence of bubble formation and the influence
of natural convection on the heat transfer process is predominant in the region A (pool boiling). Formation of
vapour bubbles at the nuclei with resulting agitation of liquid by the bubble characteristics at the region B (nucleate
boiling). The most important perhaps the critical region with respect to the heat flux is C. In this region the
unstable film boiling manifests with an eventual transition to a continuous vapour film. In the final region D film
boiling becomes stabilized. This phenomenon of stable film boiling is referred as “ LEINDENFROST EFFECT”
In the regime of boiling the maximum wall heat flux is observed in region C. Many experimentalists refer this state
of maximum wall heat flux as “BURN OUT FLUX’. The reason being when the wall is heated electrically, the
heating element frequently burn out when the wall heat flux reaches Q maximum. Hence the design engineers
should have an idea of average heat flux to the tubes, how they vary around periphery and fin tip temperature in case
of membrane wall construction. Calculation of fin temperature was discussed in latter part of this chapter.
1.0 Optimal heat transfer area to reduce the gas temperature to a temperature required from the point of super
heater.
3.0 Fins in the wall to be properly cooled, accordingly the pitch of water wall to be selected.
7.0 Sufficient residence time inside the furnace for complete combustion
a) Dry bottom: It consists of water walls or refractory walls enclosing the flame. Ash shall be removed dry
from bottom. The fuel used has low heat flux and high ash fusion temperature.
b) Wet bottom: Ash removed from bottom is of molten form. The fuel having high heat flux low ash fusion
temperature is used. The flue gas generated here or clean and free from fly ash and hence erosion, fouling
problems are minimized.
a)Conventional firing
1) Travelling grate
2) Dumping grate
3) Pulsating grate
4) Step grate
5) Fixed grate
e) Cyclone furnace.
a) Balance draft: In balanced draft both Forced draft and Induced draft fans are used so to maintain vacuum
or zero pressure in furnace. There is no leakage of combustion product in the atmosphere. In the
atmospheric pressure air leaks into furnace. This type of draft system is widely adapted in industries.
b) Forced draft or pressurized draft: Considering economic aspect in oil or gas fired boilers Forced draft fan
alone used. The furnace pressure will be of the order of 100 to 150 mm a water column. The furnace has to
be designed to without leakage. Otherwise combustion product will leak into atmosphere.
c) Induced draft: Induced draft fan is used for sucking the flue gas generated. The furnace pressure will be
maintained below atmospheric pressure.
d) Natural draft: There is no draft fan will be provided for this system. Natural draft generated due to
chimney itself used for the boiler draft. Very small capacity steam generators will be of this type.
In general heat transfer from higher temperature to lower temperature is carried out in three modes.
1.0 Conduction
2.0 Convection
3.0 Radiation
Conduction
Conduction refers to the transfer of heat between two bodies or two parts of the same body through molecules,
which are more or less stationary. Fourier law of heat conduction states rate of heat flux is linearly proportional to
temperature gradient.
Q = --K dt/dx
Where,
Negative sign indicates heat flows from high temperature to low temperature.
A area of plate
‘r cylinder radius
‘t temperature of surfaces
Convection
Convection is a process involving mass movement of fluids. When a temperature difference produces a density
difference which results in a mass movement. Newton’s law of cooling governs convection. In convection there is
always a film immediately adjacent to wall where temperature varies.
- kf A (tf - tw)
Q =
Where,
α is film thickness
Radiation
All bodies radiate heat. This phenomenon is identical to emission of light. Radiation requires no medium between
two bodies, irrespective of temperature the radiation heat transfer takes place between each other. However the
cooler body will receive more heat then hot body. The rate at which energy is radiated by a black body at
temperature T( °K) is given by Stefan Boltzmann law.
Q = σ A T4
4.88 x 10 –8 Kcal/sq.m hr K4
3.8 HEAT TRANSFER IN FURNACE
Furnace heat transfer is a complex phenomenon, which can not be calculated by a single formula. It is the
combination of above said three modes of heat transfer. However in a boiler furnace heat transfer is predominantly
due to radiation, partly due to luminous part of the flame and partly due to non-luminous gases. Overall heat
transfer coefficient in furnace is governed by three T’s temperature, turbulence and time and calculated by two parts.
Heat transfer by convection may carry out in turbulent or laminar flow of the fluid. In forced convection turbulence
or laminar flow depends on mean velocity, characteristic length L, density and viscosity. These variables are
grouped together in a dimensionless parameter called Reynolds number. Reynolds number is the ratio between
inertia force to viscous force.
Dynamic viscosity.
< 2100 then flow is laminar. In practical case the flow is most often turbulent only.
In free convection turbulence or laminar flow depends on the buoyancy force and temperature difference, coefficient
of volume of expansion. These variables are grouped to form dimensionless numbers called Grashoff number and
Prandl number. Laminar or turbulence is identified with product of Grashoff number and prandl number
The heat transfer coefficient may be evaluated from correlation developed by dimensional analysis. In this method
all the variables related to the phenomenon is grouped by experience with help of basic fundamental units length,
mass, time and temperature.
FORCED CONVECTION
h = f(L,U, ρ,µ,k,Cp) ,
where,
U velocity (meters/second)
Cp specific heat(watt/kilogram.°kelvin)
0 = a + b –3c –d +e +2f
-3 = -b –d –3e –2f
1 =c+d+e
-1 = -e - f
FREE CONVECTION
Free convection depends on buoyancy force F, which is defined by,
ρo = ρ (1 + ß Δ T)
(ρo/ ρ ) – 1 = ß Δ T
F = ßg Δ T
For an ideal gas ß is inversely proportional to temperature,(i.e. dimensional number for ß is Θ-1 and F is Θ-1 * LT-
2
*Θ ie LT-2)
By dimensional analysis,
h = B.(Fa.Cpb.Lc. ρ d.µe.kf)
= a + 2b + c –3d –e + f
-3 = -2a –2b-e-3f
-1 = -b-f
c = 3a – 1,d = 2a , e = b –2a, f = 1- b
Nu = B. Gra. Prb
By large number of experiments made on fluids it has been found that exponents a and b are of the same value. So
the expression reduce to Nu = B.(Gr.Pr)a
In furnace heat transfer is predominant by luminous and non-luminous radiation. A general approximate expression
may be written for furnace absorption using Stefan boltzman law.
εg = ηc εc + ηw εw - Δ ε
emissivity pattern of tri atomic gases such as carbon di oxide and water vapour are studied by Mr. Hottel and charts
are available to predict gas emissivity as a function of various gas temperature, partial pressure and beam length. I
have also furnished the expression form to find gas emissivity. When εc and εw are found from graph
ηc and ηw can be determined from the following expression or from graph. Otherwise emissivity of gas can be
directly found by the expression given in equation1.
0.222 1 1
ηc = EXP _______________ -
√ Pc *L +0.035 ln2.8 ln(p + 1.8)
1/3
0.23 1 2
ηw = EXP 0.842 -
αg = ηc αc + ηw α w - Δ α
εcw is a function of Pcw .L and wall temperature for this we have to see the emissivity in graph
εww is a function of Pww .L and wall temperature for this we have to see the emissivity in graph
The effect of absorptivty is negligible hence the same can be neglected and a generalized form of Q = A εw εg σ
[Tg4 –TS4] can be used.
εw wall emissivity
εg gas emissivity
TS Furnace wall temperature (If calculated for outside heat transfer coefficient or consider saturation temperature if
calculated for over all heat transfer coefficient, the difference will be of very minor).
Wf Fuel burnt
εf = Ω ( 1- e –k.L )
0.90 for luminous and semi luminous flame of coal .lignite & husk(AFBC )
0.85 for luminous and semi luminous flame of bagasse (conventional firing)
0.72 for luminous and semi luminous sooty flame of liquid fuels
0.62 for luminous and semi luminous flames of refinery gas fuel OR gas/oil
mixture
K attenuation factor, which depends on fuel type and presence of ash and its concentration. For non-luminous
flame
_______
√(Pc +Pw)L
For semi luminous flame, the ash particle size and concentration is taken in calculation
________ + 7µ(1/dm²TM²)1/2
√(Pc +Pw)L
TM – furnace mean temperature °k(Some authors will consider this as outlet temperature, but it is convincing
assumption that in furnace zone temperature will be uniformly spread through out the furnace by radiation effect
(spherical). Hence considering mean temperature for calculating radiation heat transfer coefficient will be more
appropriate. You can appreciate a notable phenomenon of furnace temperature depends on flame location inside the
furnace, in case flame is located at the center of furnace(like oil fired burners (refer example1)) mean temperature
and outlet temperature will be at the most equal and if flame is located at one end of the furnace and radiation beam
travels a larger distance of furnace(like AFBC boilers assuming no free board combustion) the furnace temperature
near flame will be higher and it gradually degrees at the furnace exit.
For luminous oil or gas flame
Above equations give only Theoretical values for flame emissivity. In practical cases a wide variation would be
occurred due to:
Due to the above fact I have tried to give the practical values and graphs for the emissivity at appropriate places for
AFBC, Dumping grate and fired boilers with working of example.
The heat transfer by radiation is given as Q = A εw εg σ [ TM4 – TS4]. But mostly the heat transfer will be of both
convection and radiation occuring simultaneously and so to put both process on a common basis, we may define a
radiation heat transfer coefficient by symbol Hr.
Hr = σ εwεg[TM4-TS4]/(TM-TS)
Q = (Hc + Hr) A (TM –TS) for fired furnace where gas throughout furnace is same.
By this equations we can get theoretical Hr value but in practice these values are corrected by effectiveness factor.
This depends on various manufacturers experience on their steam generator.(Normally for oil fired boilers the value
will be of 0.79 and gas fired boiler 0.67).
FURNACE CHAMBER
REFRACTORY
The drawing shown gives complete idea of the above construction. Refractory lined wall construction is out dated
design since it calls for a lot of refractory work and flue gas leaks are heavy and it can not with stand positive
furnace pressure.
FURNACE CHAMBER
REFRACTORY
Tangent tube is a improvement of refractory lined. Here requirement of boiler tubes is comparatively more and also
refractory structure is not eliminated.
Membrane wall construction
In industries widely used boiler furnace construction is of membrane wall construction type. In this design the tubes
are joined by welding a continuous longitudinal strip forming a solid panel, which can be as large as transportable.
Panels can be welded together on site to form the furnace. The gap between the tubes(pitch) are maintained in a
such a way that the fin can be cooled by either of the two side tubes and prevent warping of the panel. Water cooled
furnaces not only eliminated problem of rapid deterioration of refractory walls due to slag, but also reduced fouling
of convection heating surfaces to manageable extent, by lowering the temperatures leaving the furnace. In addition
to reducing furnace maintenance and fouling of convection heating surfaces, water cooling also helped to generate
more steam. Consequently the boiler surface was reduced since additional steam generating surface was available in
water cooled furnace.
Ex.1.0 . Find the furnace outlet temperature for a fluidized bed boiler operating at 15 kg/cm^2(g) having furnace
EPRS of 28.43 sq.m and having the following gas parameters.
Flue gas produced 11016 kg/hr at a temperature of 900°C and partial water vapour pressure 0.15 ata , partial carbon
di oxide pressure 0.14 ata .
= 1.1269 meter/sec.
(As steam side heat transfer coefficient is very high, in over all heat transfer coefficient its effect will be negligible)
Nu = 0.037 Re 0.8 Pr n where n= 0.3 for cooling fluid
0.8
3.7392 x 10-5
L = 1.2709 m
_________________
√ (0.14 +0.15)1.2709
= 0.2904
= 0.2778
[820 –200]
= 537419 kcal/hr.
Heat lost by gas QL = Wg ( Hi – Ho)
= 549147 kcal/hr
Ex 02. Evaluate the size of bed for a 10 tph boiler, operating at 14.5 ksc, satuated steam from and at 100°C. Coal as
a fuel. The efficiency of boiler is 80% and GCV of coal as 3800 kcal/kg , Flue gas produced per kg of fuel is 6.802
kg/kg at 20% excess air operation.
= 3.977 m^2.
Bed size arrived = 3200 x1250 mm x mm a refractory wall thickness of 370 mm can be considered and above
which water wall is located. Hence a water wall of size 3584 x 1680( 35 @ 112 pitch and 15 @ 112 pitch ) can be
obtained.
The sizing of bed area and water wall size is an art rather than a scientific approach a better configuration has to be
arrived on the basis of experience.
Note: From and at 100°C is the term used in boiler industry to specify the heat capacity of boiler. This is value is
assumed that water at 1kg/cm^2 100°C is given as input and steam drawn at 1kg.cm^2 .(i.e. latent heat at 1kg/cm^2
pressure only absorbed )
EX 03. Find the furnace outlet temperature of a 55Tph dumping grate bagasse fired boiler operating at 42 kg/cm^2
and 420°C super heater outlet at furnace exit plane. The effective projected area of furnace and superheater plane
works out to be 212m^2 and 13.6m^2 respectively. Consider convection heat transfer coefficient negligible and
lower heating value of bagasse 1828 kcal/kg, 85% of air required flows through air heater at a temperature of 170°C
and 15% air for fuel distributor and OFA at 40°C into the furnace. Fuel consumption 24209 kg/hr. 2% of gross heat
input goes as carbon loss and 1% goes as radiation loss.
where,3.909 is air required for burning one kg of bagasse at 35% excess air.
3.0 Un burnt carbon loss = 0.02 x 24209 x2272 = 1.1 x 10^6 kcal/hr
Q = A εw εg σ [ TM4 – TS4]
As it is a bagasse fired boiler volatile combustion is more TM will be equal to temperature exit and εw εg is equal to
0.72.
(it is assumed that 70% of heat absorbed will go to steam temperature raise)
Ex.04. Estimate FOT for the furnace operating at 20.66 bara, having EPRS area 112m² and size 5.74 x 3 x 6 m.
firing LDO as fuel having LCV of 41867 kj/kg and fuel consumption 1.16 kg/sec and flue gas generated 19.03
kg/sec at 10% excess air. Air required 17.87 kg/sec at 27°C. Consider a radiation loss 0.33% and wall emissivity
0.85, heat transfer effectiveness 0.79. adjacent radiation chamber extends by 1.01 m length wise.
K =(1.6x1558/100)-0.5 = 1.9928
= 187.768 W/mK4
Velocity = 19.03 /(0.345 x 3x6) = 3.064 m/s where 0.345 is density kg/m^3
0.8
4.13276x10^-5 5.74
= 5.769 W/mK
Heat absorbed by Furnace
= 18.34MW
= 1.0316MW
Enthalphy of leaving gas = 1.526 Mj/kg For this gas temperature is 1255°C.
4.0 SUPER HEATER
4.1 INTRODUCTION:
The steam temperature above its saturation temperature corresponding to the pressure is achieved by introducing
super heater coils. In the modern industrial world, it is expected to get the maximum attainable temperature for a
pressure, since the cycle efficiency depends on pressure and temperature. But nature restricts the maximum
temperature with material availability and metallurgical limitations.
Super heater is a critical section, where high metal working temperature involves, since working fluid in super
heater is hot steam when compared saturated water in other regions. The super heater will work out approximately
5% of the cost of the boiler and the material must be selected carefully. If improper selection of material leads
losses due to oxidation and improper sizing or thickness selection leads larger reserve in thickness which is
uneconomical and lesser thickness cause tube failure.
The mechanical arrangement of super heaters is governed by factors like furnace design i.e. furnace outlet
temperature which is explained in furnace chapter, fuel characteristics, degree of super heat and manufacturer
practice. The fuel characteristics such as ash content, ash particle size, salts of alkali metals like sodium and
potassium which volatilize in the process of combustion and condenses as a sticky substance at a temperature
corresponding to super heater tubes. These decide transverse pitching of super heater. Some light density fuels like
husk burns at the top resulting high heat flux input to super heater reducing heat transfer area requirement itself.
4.3 POINTS TO BE NOTED WHILE DESIGNING SUPER HEATER
1.0 The super heater surface required to give the desired steam temperature.
A change in any of the first six items will call for counter balancing change in all other items.
Super heaters are normally classified as Radiant and Convection super heaters. Radiant super heaters are located in
the radiant zone receiving energy directly from the flame in the furnace. Convective super heaters do not receive
furnace radiation. A few super heaters receive energy partly from the flame are called semi radiant.
The other classification of super heaters depends on location arrangement and flow pattern.
1 Radiant super heater located at radiant zone of boiler
2 Convection super heater located at the convection zone of boiler
3 In modern fluidized bed boilers, to achieve higher steam temperature a portion of super heater located in the
fluidized bed called bed super heaters.
Depends on arrangement
Horizontal arrangement of super heaters have a advantage of easy drainage, which is quite important in boilers
where shut down will be for longer periods. Drainability helps in non-accumulation of salts in water or steam inside
the tubes.
In vertical arrangement the problem of expansion can be tackled easily than horizontal arrangement.
Staggered bundles are difficult to clean but they offer a marginal improvement in heat transfer coefficient. Inline
arrangement provides lower gas side pressure drop.
Counter flow arrangement offers a slight improvement in log mean temperature difference and there by decreasing
surface area compared to parallel flow. The parallel flow arrangement leads to cooler tubes. Metal temperature can
be higher with counter flow arrangement since both gas and steam temperature are higher at steam exit portion.
4.5 DESIGNING A SUPER HEATER
Designing a super heater or any other heat transfer involves three steps one is the thermal design, second is the
mechanical design and other is the performance calculation.
In a thermal design we have to perform the heat duty, heat transfer and surface area required for the known thermal
input and output parameters
In a mechanical design thickness and material with standing capacity are to be checked.
Performance calculation involves confirmation of the designed equipment for various loads.
4.6 OVERALL HEAT TRANSFER ACROSS BANK OF TUBES
According to the gentleman Mr. Colburn the following equation can be applied for gas/air flowing normal to the
bank of tubes
While calculating Reynolds number external tube diameter has to be used. This expression can also expressed after
introducing geometry factor. Geometry factor F has to be taken from graph depends on transverse pitch to diameter
ratio and longitudinal pitch to diameter ratio
According to another gentleman Mr. Grimson the outside heat transfer coefficient was explained by the following
equation
Arrangement Factor F
ST/d SL/D 1.25 1.50 2.00 3.00 1.25 1.50 2.00 3.00
1.25 Re
1.5 2000 0.95 0.95 1.03 1.03 1.17 1.15 1.08 1.02
2.00 2000 0.73 0.73 0.98 1.08 1.22 1.18 1.12 1.08
3.00 2000 0.66 0.66 0.95 1.00 1.26 1.26 1.16 1.13
B and N are factors governed by the geometry, the values of B and N is given in the table.
Many such persons worked on the heat transfer and gave various correlation for certain pre defined condition and
hence for practical purposes certain factors to be considered for its accuracy. I have also tried to give those factors
in worked examples.
In the Colburn or Grimson equation correction factor for the heat transfer coefficient for gas angle of attack on the
tube has to be calculated into account.
Degree ° 90 80 70 60 50 40 30 20 10
Factor 1.0 1.0 0.98 0.94 0.88 0.78 0.67 0.52 0.42
ST/D 1.25 1.5 2.0 3.0
SL/D B N B N B N B N
STAGGE
1.25 0.518 0.556 0.505 0.544 0.519 0.556 0.522 0.562
1.5 0.451 0.568 0.46 0.562 0.452 0.568 0.488 0.568
2 0.404 0.572 0.416 0.568 0.482 0.556 0.449 0.57
3 0.31 0.592 0.356 0.58 0.44 0.562 0.421 0.574
INLINE
1.25 0.348 0.592 0.275 0.608 0.10 0.704 0.0633 0.752
1.5 0.367 0.586 0.25 0.62 0.101 0.702 0.0678 0.744
2 0.418 0.57 0.299 0.602 0.229 0.632 0.198 0.648
3 0.29 0.601 0.357 0.584 0.374 0.581 0.286 0.608
Number deep 1 2 3 4 5 6 7 8 9 10
Staggered 0.68 0.75 0.83 0.89 0.92 0.95 0.97 0.98 0.99 1.0
Inline 0.64 0.8 0.87 0.9 0.92 0.94 0.96 0.98 0.99 1.0
Simillarly Dittus & Boelter correlation gives heat transfer coefficient on inside tube.
Consider the super heater tubes of outer radius r1 & r2 respectively. Thermal conductivity of material k. Cold fluid
(steam) is flowing steadily inside the tube Tf1 and hot fluid Tf2 steadily outside the tube. Inner and outer wall
temperature tw1 & tw2. Heat transfer coefficient of steam and gas sides be h1 and h2. (h2 includes convection heat
transfer and non luminous heat transfer as explained in furnace chapter)
STEAM ho Tf2
= 2* π * k (tw2 – tw1)/ln(r2/r1)……………………………………..2
= ho * 2 * π * r2 [ tf2 – tw2]…………………………………………3
1=2=3
ql 1 ln(r2/r1) 1
tf2 – tf1 = + +
2*π hir1 k hor2
ql = 2* π *(tf2 – tf1)
1 + ln(r2/r1) + 1
hir1 k hor2
Q/l = U [tf2 – tf1]
Divide by πdo
U = 2* π
πdo
1 + ln(r2/r1) + 1
hir1 k hor2
U = 1
πdo
1 + ln(r2/r1) + 1
1 do + d0 ln(d0/di) + 1
=
U hidi 2k ho
Introducing fouling factors in steam side and gas side we can get,
1 do + d0 ln(d0/di) + 1
= +ffo +ffi
U hidi 2k ho
1/ho is gas side heat transfer resistance.(this gives temperature drop in the film)
doln(do/di)/2k is metal resistance(this gives temperature drop in metal side)
do/hidi is steam side heat transfer resistance.(this gives temperature drop in steam side film)
For extended surface following heat transfer coefficient equation can be applied.
1 At + At d0 ln(d0/di) + 1
= +ffo +ffi At/Ai
U hiAi Aw 2k η ho
Q = U * A * [tf2 –tf1] for specific tube, while considering bundle of tubes log mean temperature has to be used.
Q = U * A * lmtd.
Metal temperature of bare tube can be estimated easily by calculating various temperature drop across the resistance
given above. This simple equation is applicable for only bare tube surface. For extended surface fin temperature
calculation involves a detailed procedure which is discussed separately.
4.7 STEAM TEMPERATURE CONTROL
Super heater temperature depends on boiler working pressure. The degree of super heat varies directly with respect
to boiler working pressure. The various steam outlet temperature corresponding to a pressure is fixed up by cycle
efficiency and turbine manufactures practice. Operating variables like flue gas temperature inlet, load, excess air,
fuel creates fluctuation in steam temperature leaving the final super heater. If there is any fluctuation in steam
temperature, there is a change in volume of steam which will affect the turbine performance, since turbines are
designed for predetermined steam volume flow between stator and rotor and also the exhaust steam temperature
quality will varies with steam fluctuation which will affect condenser performance. Hence it is mandatory to have a
steam temperature control.
In practice two types of attemperators (de-super heater) is widely used in boiler industry, they are
1.0 Spray type
2.0 Surface type.
In the above two types, spray type attemperator gives a faster temperature control compared to surface type.
However quality water spraying into the super heater should be taken care for boiler and turbine life. Attempeator
temperature technique is nothing but a simple energy balance. It consists of spraying water in mist form in between
stages, depends on the final steam temperature and pick up by individual stages. The quantity of spray water varies
with respect to load and it is controlled by automatic control loops. Spray inside desuperheater accomplished by
means of nozzle arrangement.
Surface type attemperators are further divided into two types submerged type and Shell and tube type. In submerged
type the steam coils is submerged below the drum water level. Part of the steam flows through the submerged coils
and part of the steam by-pass the coil. The flow of steam through the submerged coil is regulated in such a way that
the outlet steam temperature is of desired level after mixing.
In shell and tube type attemperator super heater header itself modified into an exchanger. Steam from super heater
coils enter this intermediate header and leaves to the second stage. In the super heater header the cooling water coils
enter in both the sides and leaves. The steam gets cooled when it contact with low temperature cooling coils. In this
steam temperature is adjusted by regulating the flow of cooling water flow inside the coils. Higher the water flow
steam cooling will be more.
The water which absorb heat usually mixed with feed water to avoid the heat loss.
SPRAY TYPE ATTEMPERATOR Water qty (M KG/HR & enthalpy
Hfw kcal/kg)
Energy balance,
M1* H1 + M * Hfw = M2H2……………………………………………1
Mass balance,
M1 + M = M2……………………………………………….2
From 1 & 2,
M1*H1 + M*Hfw = (M + M1) *H2
M = M1 * { H1 –H2}/{H2 – Hfw}
Ex.01. Determine the spray quantity required for a 60TPH boiler having a primary super heater steam outlet temp of
332°C and secondary super heater inlet steam to be desuperheated to 316°c. The spray water temperature is 105°C.
The heat transfer coefficient outside the tube to water is natural convection heat transfer coefficient, governed by the
equation
‘hodo/k = 0.54 μ² k
0.25
0.03813 x 787.5² x 9.81x0.281x 5 x 0.83299 x 0.61184
ho = 0.54 0.000103067² 0.0381
= 19497 W/m²°K
Nu = 0.023 Re0.8Pr0.4
= 559812
= 476.6 w/m²K
= 7.1988 x 10-5
Overall heat transfer coefficient
= 8.12 m²
Ex.03. Calculate gas outlet temperature for a super heater intended to raise steam from 214°C to 258°C. steam flow
15.28 kg/sec, pressure 20 bar(a), tube size 38.1 x 3.25 mm thk and thermal conductivity 49.844 W/mK. The gas
flow 19.03 kg/sec, inlet temperature is 659°C and the pattern of flow is counter, furnace width is 3.06 meter and
length 2.7meters, tube pitching width side 80mm and depth side 78mm, inline arrangement, number of tubes in
steam side path is 74. Heat transfer area of super heater 88 sq.m. the super heater was enclosed in a water wall
having EPRS area of 21 sq.m and gas is flowing 90° to super hater tubes. Consider heat transfer effectiveness of
82% and 71% for enclosure. Partial pressure of water =0.1158 bar and carbon di oxide = 0.1249bar.
Properties of steam
Density kg/cu.m = 9.328189
Dynamic viscosity kg/ms = 1.72232 x 10-5
Prandtl number = 1.083
Thermal conductivity W/mK = 4.346819 x 10-2
Steam velocity = 15.28 x 4 /(9.3281 x74xπ x 0.0316²)
= 28.225m/s
Forced convection inside heat transfer coefficient is
= 1152 W/sq.mK
= 0.8439
= 0.10358
= 7.218 W/sqmK
total gas side heat transfer coefficient = hc + hr = 68.58 + 7.218 = 75.798 W/sqmK
1 do + d0 ln(d0/di) + 1
=
U hidi 2k ho
= 0.0381/(1152x0.0317) + 0.0381 ln(0.0381/0.0317) + 1/75.798
2 x 49.844
U = 69.898 W/sq.mK
Q = U x effectiveness x Ax lmtd
= 69.898 x 0.82 x 88 x 372 = 1.876 MW.
Neglecting metal resistance and internal conductance the convection heat transfer coefficient be 68.58 w/sq.mK and
non-luminous radiation heat transfer be
= 6.9538 w/sqmK
Total heat gained by super heater and encloser is = 1.8763 + 0.4426 = 2.319 MW.
= 0.209 kg/cm².
Pressure loss in Bends,
For 180° bend = 0.47v²/2g
For 45° bend = 0.12v²/2g
5.1 INTRODUCTION
The recent development in boiler field involves, critical pressure boilers or once through boilers in which drum is
not necessary. But other than critical pressure boilers, it involves two regimes of liquid and vapour phase where
separation of steam from liquid surface takes place in steam drum. The number of drums required for a boiler
depends on evaporator requirement, boiler pressure, stability, manufacture experience on the type of configuration.
Widely single drum boiler and bidrum boiler are in use and in certain cases three or four drum design also available
but they are outdated now. For higher capacity and high pressure(more than 70 kg/cm^2(g) pressure) boilers are
economical with single drum boilers and for industrial process steam application where bidrum boiler works out to
be economical. In practice it was found that drum cost around 10% of the boiler pressure part cost.
In world wide practice drums are designed in cylindrical shape with two dished end with or without man hole at its
end or cylindrical shell with tube sheet at its end or cylindrical shell with water box but the uniqueness of the drum
is cylindrical shape.
We consider the following three basic configuration for drum and let us analyze about drum geometry.
X X
Let the steam drum be a spherical shell of internal diameter ‘d’ and thickness ‘t’ and subject to an internal pressure
of intensity p
Resisting force = σ1 x π x d x t
σ1 = pd/4t
since any section taken in diagonal to a sphere is symmetrical, the stress at any point in the metal of sphere will be
equal and opposite and hence there will not be any shear stress. The strain at any direction is given by
Hence
If the shell has been riveted then factor e called efficiency factor to be introduced
i.e., ‘t ≥ pd/4σ1e
A square chamber has three planes of action and the stress and resisting force in all the three direction to be checked
for its stability
Let ‘d be the sides of the square section ,L be the length, t be the thickness and p be the intensity of pressure
= p x projected area
______
= p x √ d² + d² x L
_
Equating 1 and 2
σ1 = pd/√2 t or t = pd/√2σ1
Bursting force P = p x d x L
Resisting force = σ2 x 2 x L x t
σ2 = pd/2t or t = pd/2σ2
Bursting force P = p x d²
negligible)
σ3 = pd/4t or t = pd/4σ3
Z Y
X X p
Z Y
Let us consider the length and thickness of a cylinder be L and t whose mean diameter is d and the internal
pressure be p.
In this case section xx and zz experience same force and hence we have to calculate force in xx and yy section only
Resisting force = σ1 x 2 x t x L
= σ1 = pd/2t or t = pd/2σ1
This stress induced in circumferencial of the shell is called circumferencial stress of hoops stress.
‘σ2 be the tensile stress on the section yy, equating the resistance offered by the section yy to the total force on the
end of the shell
σ2 x π x d x t = p x π x d²/4
σ2 = pd/4t or t = pd/4σ2
This stress is longitudinal stress. Hence at any point in the metal of the shell there are two principal stress namely
hoop stress(pd/2t) and longitudinal stress(pd/4t) acting perpendicular and parallel to the axis of shell respectively.
From the above equation minimum thickness required for a cylindrical drum can be determined. Let σ be the
permissible tensile stress for the material than for shell to be safe major principal stress σ1 should not exceed σ
pitch
As per IBR regulation 270, introducing addition of corrosion allowance to the thickness the formula modified into,
As per ASME PG27.1 , introducing addition of corrosion allowance to the thickness the formula modified into,
DESCRIPTION XX YY ZZ
For a same pressure, material, dimension the minimum thickness required for sphere, cylinder and square is in the
ratio of 1: 2 : 2.83 (thickness governing formula shown in bold letters in the tabular column )
Sphere as a drum, there will be problem of having holding capacities and then fabrication difficulties. Hence sphere
can not be used in place of drum due to the smaller volume.
For square when compared to circular drums it calls for 1.414 times greater thickness in turn weight of the drum.
Number of welds for making a square is more where as a single fusion weld will do for circular drums. Square
chamber has to be placed in diagonal position for the lift of steam and therefore opening has to made in the bends,
which is very stress prone area. Practically speaking square sections are inferior in strength compare to circular
section. According to IBR regulation square sections can be used as header and circular sections can be used for
both drums and header. The main advantage of square header is at one side openings for tubes can be made and
other opposite side openings for mechanical cleaning can be made for straight inclined tubes. For this purpose some
manufacturer prefer square header, where inclined tubes are used.
According to the IBR regulation 281, there are certain minimum requisite of mountings, fittings and auxiliaries to be
provided in pressure vessels for the safety of the system. IBR regulation says that every boiler to be provided at
least with following
1.0 Two safety valves (minimum diameter 0.75 inches)
6.0 One feed apparatus(pump) when the heating surface exceeds 200 sq.ft and two
independent feed apparatus each such apparatus shall have a capacity of not
In case of boilers fitted with integral super heaters an additional safety valve shall be fitted at the end of the super
heater outlet header.
There are also other attachments not in the IBR regulation such as steam separator, air vent and pressure gauge stub
more than one as desired by the manufacture or user.
The opening in drum made for stubs, manhole, mud hole will weaken the plate which calls for strengthening the
plate by compensating plates. According to IBR the maximum diameter for uncompensated opening is given by the
following formula
_________
2Fe -P
If the diameter of opening is less than the calculated value then it is not necessary to give compensation for the
drum. If it exceeds the limit compensation have to be provided.
The steam drum must be large enough to accommodate drum internals, the necessary steam surface for steam
separation and water holding capacity. The drum also provide sufficient space for change in water level that occur
with change in load. A sudden increase in steam demand cause a temporary pressure surge, until firing rate is
increased sufficiently for more steam generation. During this interval due to lower pressure, steam volume
throughout the boiler is increased (pressure α 1/volume). This results in SWELL raise in water level in the drum.
The raise in water level depends on the rate at which heat and feed inputs can be changed to meet the load demand.
The higher the drum diameter better the control of raise in water level
In GT HRSG during starting the steam generation cause sudden increase in drum level and it is estimated that 70%
of the evaporator water gets raised into the drum. Hence the during start up the HRSGs are started with low water
level and at once the increased water level goes to high-high level blow down valve will be opened to control the
increase in water level. Normally blow down valve for HRSGs are sized based on the same, by finding the 70%
evaporator volume less the drum volume between low to high-high. This difference in water has to be discharged
with in 2 to 3 minutes.
STEAM SPACE
In the steam drum water and steam regions are clearly separated, the space above the normal water level is called
steam space. Steam space governs the steam loading of the drum. Steam loading is the ratio between steam space
and the specific volume of the steam for pressure it is operating(M^3/m^3hr). Steam loading for different pressures
is fixed by the manufactures according to their practice or experience. Steam loading is one of the important
decision factor in deciding the size of the drum. Steam loading ensures the velocity of separation in the inter phase
and steam carry over.
Let L be the length of steam drum and D be the internal diameter, r be the radius and x be the distance from center
line to normal water level.
o D
k α
a b x nwl
‘h
Sin α = ak/oa
‘α = Sin-(x/r)
Θ = (180 – 2α)
‘ab = 2 ac
= 2.r. Sin(Θ/2)
4x 360
Steam space volume = ( πD² /4 - area acba) (L +2l) + 2 volume of dished head
M^3 M^3
SEMI ELLIPSOIDAL π. D3/24 π.h².(1.5D –h)/12
TORIS SPHERICAL
Ex 01 Estimate the shell thickness required for a single drum boiler, whose design pressure is 73 kg/cm² and the
internal diameter is 1300mm. The drum is located outside the gas path.
Single drum the ligament efficiency is 1. However for practical estimation 0.95 is considered.
2fE –P
= 73 x 1300__________ + 0.762
Note. Stress value 1230.4 kg/cm² is calculated for the saturated temperature of boiler design pressure. If the drum is
exposed in gas path additional temperature allowance of 28°C has to be added to saturated temperature and for this
stress value has to be considered.
Ex.02 Estimate the thickness required for the 2:1 semi ellipsoidal head as per IBR, whose design pressure is 73
kg/cm² and the inside diameter is 1300mm. A opening in the dished end of size 545 x 500 mm is made for man hole
opening. The material of construction is SA 516 Gr.70.
I 150
60
II 150
W.P = 2f(T-C)/(DK)
Where,
T = Minimum thickness
‘f = Allowable Stress = 1230.4 kg/cm² (As per ASME section II part D 1995)
K= Shape factor
Limit of Reinforcement
L2 =√d.Tt
_______
Since the lenth of the nozzle projection inside the dished end is 150< 180.83, the whole length is considered for
compensation.
Area of reinforcement
= -ve
T/D = 49/1398
=0.035<0.1
H/D = 374/1398 = 0.267 (H is height of dished head for semi ellipsoidal ( (ID/4)+ T)
2f
2 x 1230.4
= 49 mm selected is sufficient. (Over the selected thickness dishing thinning allowance has to be considered)
Thickness = P.D____ +C
2f + P
= 73 x 545_____ + 0 = 15.702
( 2x 1230.4 +73)
The nozzle thickness provided 60mm(Which is used in reinforcement calculation of the above problem)
= Pdn/(2f-P) + C
= 47.08 mm
= 26574.25mm²
Compensation shall be considered adequate when the sectional area X to be compensated measured through the axis
of the shell is less than the compensating are Y. In other words area X should be less than Area Y for the design to
be satisfied, if X area is greater than area Y additional compensation pad to be provided or thickness of nozzle to be
increased.
In our case condition is satisfied and hence there is no need foe external compensation pad.
Ex 04 Estimate the thickness required for end plate of thickness or closing the man hole nozzle.
____
C= 1mm
K= 0.19 for ends integral with or flanged and butt welded to the header.
K= 0.32 for ends integral with or flanged and butt welded to the header.
In our case Ellipsoidal header is assumed as if circular header/nozzle and checked for both major and minor axis.
_____________
Ex 05 Find maximum allowable uncompensated opening can be made in the above drum.
_________
T = Thickness of shell
0.5
E= 40.505/42.66 =0.949
_______
N = 6x(√(1-0.949) = 1.35
_____________________
=119.66mm
6.0 EVAPORATOR AND ECONOMISER
6.1 INTRODUCTION
In steam generator boiling phenomenon takes place in furnace and evaporator section only. Even though the
terminology boiler is commonly used for whole steam generator, boiler is applicable to the furnace and evaporator
only. The other units such as super heater, economiser, air heater etc., are only the heat exchanger used to improve
the cycle efficiency.
EVAPORATOR ECONOMISER
unit.
boiler water and the temperature of the medium economiser is feed water.
cool the flue gas beyond its working temperature. Well below its saturation temp.
pressure.
Temperature gradient.
Evaporator gets its working fluid (boiler water) Economiser gets its working
steam drum.
There are several types of fin types such as helical solid fins, serrated helical fins, circular fins, rectangular (H type )
fins, peg pins, longitudinal fins are available due to development in heat transfer study. Out of the various fin
configuration longitudinal fin configuration is the simplest fin configuration for estimating the fin efficiency, from
which correlation can be made to get other fin type fin efficiency.
hf
hb
hi l=b l l=0
hfo
At any cross section as in figure let Tc be the constant temperature of the hot fluid everywhere surrounding the fin
and let t be the temperature at any point in the fin and variable. Let Θ be the temperature difference driving heat
from the fluid to the fin at any point in its cross section. Then
Θ = Tc – t
‘dΘ/dl = -dt/dl
The heat within the fin which process through its cross section is
Q = ka dΘ/dl…………………………………………….A
‘dQ/dl = ka d²Θ/dl²……………………………..1
Where a is the cross sectional area of the fin. This is equal to the heat which passed into the fin through its sides
from l=0 down to the darkened cross section.
If P is the perimeter of the fin, the area of the sides is Pdl and the film coefficient from liquid to fin side, whether on
fin surface or tube surface, is hf.
kad²Θ/dl² -- hfPΘ = 0
Rearranging,
d²Θ/dl² - hfPΘ/ka =0
0.5 0.5
_____
‘m = √(hfP/ka)
Θe = c1 + c2
C1 = C2 = Θe/2
Equation 3 becomes,
Θ = Θe cosh(ml)
Thus an expression has been obtained for the temperature difference between constant fluid temperature and
variable fin temperature in terms of the length of the fin.
d²Q/dl² = hfPdΘ/dl………………………………….4
Substituting in equation A
Q = kad²Q/hfPdl²
d²Q/dl² = hfPQ/ka………………………………..5
d²Q/dl² - hfPQ/ka = 0
0.5 0.5
Q = C3eml + C4e-ml
At I =0,
Q = hfPΘe /m sinh(ml)
The ratio of heat load Q to the temperature difference Θ at the fin base is
Q/Θ = hfPΘe sinh(ml)
m Θe cosh(ml)
‘m
hf = Qm/Θptanh(ml)
Let hf is the heat transfer coefficient of fin and the bare tube and the heat absorbed by fin through the heat transfer
coefficient hf is getting transmitted into the tube by means of base heat transfer coefficient hb. The ratio of heat
transfer coefficient hb to the heat transfer coefficient hf is termed as fin efficiency.
hb = Q/ΘlP
η’ = hb/hf = Q Θ P tanh(ml)
Qm ΘlP
= tanh(ml)
ml
This equation applies only to the fin and not to the bare portion of the tube between fins. The total heat removed
from the annulus liquid and arriving at the tube inside diameter is a composite of the heat transferred by the fins to
the tube outside diameter and that transferred directly to the bare tube surface. These may be combined by means of
the weighted efficiency.
If the heat tranferred through the bare tube surface at the tube outside diameter is designated by Q0, then
Qo = hf AoΘ where A0 is the bare tube surface at the outside diameter exclusive of the area beneath the bases of the
fins. If there are N number of fins on the tube l.P.Nis all of the fins surface. The total heat transfer at the outside
diameter is given by
Q = Qb + Qo = hb.l.P.N.Θ + hf.Ao.Θ
=(hb.l.P.N.Ao/Ao + hf.l.P.N.Ao/P.l.N)Θ
=(hb/Ao + hf /P.l.N)l.P.N.Ao.Θ
=(l.P.N.tanh(ml) + Ao ) hfΘ………………………………………………..8
ml
Calling hfo the composite value of hf to both the fin and bare tube surfaces when referred to the outside diameter of
the tube, the fin effectiveness or weighted fin efficiency is by definition η =hfo/hf. Combining equation 7 and 8
η =hfo/hf = l.P.N η’ + Ao
l.P.N +Ao
inserting At –At,
= (At+Ao -(1-η’)At)/(At+Ao)
Ex.01. Design a feed water heater for a 10 tph boiler whose exhaust gas flow is 21355 kg/hr at an outlet
temperature is 185°C and the desirable outlet temperature is 140°C. The feed water is available at 60°C.
=259890 kcal/hr
Where 48.26 kcal/kg enthalpy of gas at 185°C and 36.09 kcal/kg enthalpy of gas at 140°C.
=85.98°C.
III. For the heat exchanger, gas is flowing inside the tube internal heat transfer coefficient governs the overall heat
transfer coefficient. The overall heat transfer coefficient is around 85% of inside heat transfer coefficient.
= 23252.559
= 39.2 kcal/m²hr°C
= 259890/(33.32 x89.15)
= 87.49m²
Considering tube length for welding to the tube sheet clearance 10 mm on both sides
Ex.02. Calculate gas outlet temperature for a evaporator intended to generate steam flow 15.28 kg/sec, pressure 20
bar(a), tube size 38.1 x 3.25 mm thk and thermal conductivity 49.844 W/mK. The gas flow 19.03 kg/sec, inlet
temperature is 1180°C and the pattern of tube arrangement furnace width is 3.06 meter and length 2.7meters, tube
pitching width side 80mm and depth side 78mm, inline arrangement, number of tubes in width side 36 and depth
side 20. Heat transfer area of evaporator 246 sq.m. the evaportor was enclosed in a water wall having EPRS area of
26 sq.m and gas is flowing 90° to evaporator tubes. Consider heat transfer effectiveness of 82% and 71% for
enclosure. Partial pressure of water =0.1158 bar and carbon di oxide = 0.1249bar.
1 do + d0 ln(d0/di) + 1
=
U hidi 2k ho
= 0.0381/(14000x0.0317) + 0.0381 ln(0.0381/0.0317) + 1/83.63
2 x 49.844
U = 82.55 W/sq.mK
Heat transferred to evaporator tubes,
Q = U x effectiveness x Ax lmtd
= 82.55 x 0.82 x 246 x 673 = 11206 KW.
Heat transferred to water wall encloser,
Neglecting metal resistance and internal conductance the convection heat transfer
coefficient be 82.55 w/sq.mK
Q = 82.55 x 0.71 x 26 x 673 = 1025 KW.
Total heat gained by evaporator and encloser is = 11206 + 1025 = 12231 KW.
7.0 AIRHEATER
7.1 INTRODUCTION
Air heater is a heat recovery unit, which is employed to recover heat from lower temperature levels usually 240°C
and below. Air heater is used in most of the industrial and utility boilers. The construction of this equipment being
a simple and also a non pressure part. Gas temperature drop 240°c to 170°C can be effectively achieved by means
of air heater there by 4% boiler efficiency can be improved. In cases of low capacity , low pressure boilers
manufactures prefers to have an air heater instead of economiser. This is to avoid problems arised due to
economiser like oxygen pitting, corrosion higher feed water temperature, necessity of having deaerator more over
economiser is a pressure part. These are avoided by means of air pre heater
1.0 Recuperative
2.0 Regenerative
In recuperative heat exchanger heating and cooling medium are separated by partition and the heat is transferred
from one fluid to other by means of conduction and convection and there is no moving part employed in
recuperative heat exchangers. According to the construction it is again sub divided into tubular or plate type air
heater.
This usually consists of large number of steel tubes of either welded or expanded into the tube plate at the ends.
Either gas or air may be designed to flow through the tube. Gas through the tube normally requires higher size tube
and vertical flow to reduce fouling. Single or more passes on the gas side and multi pass to and fro on the air side
usually fits in with shorter tube length so as to facilitate maintenance o surfaces due to corrosion and fouling. In
some cases instead of using of boiler flue gases separated external firing is used particularly during starting
This comprise of parallel plates which provide alternate passage for gas and air. This type is simple and compact to
that of tubular type. The narrow passes between plates make cleaning tedious but with shot cleaning method it is
improved. But replacement is a major task and nowadays it is not used in industry or utility boilers.
In regenerative heat exchangers the heating fluid heat the closely packed matrix to raise its temperature which is
again placed in cooling medium to transfer the heat to cooling fluid. In regenerative exchangers either matrix or the
hoods are rotated to achieve this. This is sub divided by the names of inventors into
i) Ljungstrom type
A heat pipe is a device with a high thermal conductance. It is based on the large latent heat of
vapourisation/condensation of working fluid inside the heat pipe. Hence all heat pipes are completely sealed one
and the working fluid is the heat transfer element between the hot and cold fluid passing through its ends separated
by a partition plate. In heat pipe heat is absorbed in the evaporator portion of the heat pipe, and of vapourises the
internal working fluid. The vapour is transferred to the condenser portion on the other end where the fluid
surrenders the heat to the cold surrounding and condenses. This fluid is then returned to the evaporator and the
cycle is repeated. Heat pipe contains a working fluid specifically selected for operating temperature range and
hence heat pipes are arranged in modules containing different working fluid for the range of temperature.
Types of heat pipes differ according to the method used to transport the working fluid.
The name itself indicates heat pipes uses gravity, buoyancy and vapour pressure forces to transport the phase of the
working fluid. It requires the heat source to be below the heat sink that is evaporator must be below the condenser.
The vapour generated in the evaporator travels upward because of the buoyancy and expansion forces. In the
condenser the vapour is condensed to a liquid and turns to the evaporator by gravity. The thermo syphon heat pipe
can be made to function efficiently with an orientation of approximately 10 to 90 degree from horizontal.
The working fluid is transferred through capillary action and it does not require gravity to return the condensate to
the evaporator section. This type of heat pipes contain an internal element known as wick, which spans the length of
the pipe. The wick may be made of gauze wire mesh or other materials that provide closely spaced longitudinal
paths for returning condensate. The path spacing is chosen based on the working fluid to obtain high capillary
forces and there are no orientation restriction for this type of heat pipe.
There should not be gap between heat source and sink in the heat pipe. If a gap exists then it can be spanned by an
adiabatic(non heat transfer) section of heat pipe. This adiabatic region is created by externally insulating the
appropriate section of heat pipe.
Toluene and naphthalene are commonly used heat transfer fluids in air heaters. The major advantage of heat pipe
design compared to conventional tubular heat exchanger commonly used are that it is isothermal and can be built
with better seals to reduce leakage. Each pipe is fixed only at the center support plate separating the hot flue gas and
cold air. The ends of each pipe are free to expand and contract independently. Since heat pipe has no hot and cold
spot the possibility of cold end corrosion is reduced.
A COMPARISON OF VARIOUS AIR HEATER TYPES
(TUBULAR) (ROTARY)
Will be there
boilers
Air heater are in low temperature operating region, it is subject to metal temperature below dew point, which is
primary cause of condensation of acid or moisture from flue gas. Minimum metal temperature occurs at cold end
where most fouling and corrosion occurs. If the air heater is not cleaned at frequent intervals the fouling increases
and velocity increases in other tubes which cause severe erosion of high velocity tubes and corrosion of fouled
tubes. These problems can be eliminated by frequent cleaning of air heater.
On load cleaning
Recuperative type proven practical method is by shot rain and regenerative type can be cleaned by fixed or moving
soot blowers. Heat pipe which uses finned tubes can be cleaned by soot blowers.
If not provided with on load cleaning, air heater has to be cleaned at intervals during shut down manually or
mechanical methods. Large quantity of cold or warm water has to be used for flushing the air heater since small
quantity of water will actually do harm by making deposits compact and hard. If deposit is severe soda ash solution
will assist in dissolving it.
Leakage
Leakage in air heater can be checked during operation by analyzing the flue gas for carbon di oxide drop across the
air heater. This leakage is through the tube leak joint corrosion, erosion holes etc., in case of tubular air heater.
While through seals in case of regenerative air heater.
In addition to increase in boiler efficiency the other advantages that may result are
2.0 Intensified and improved combustion which result in faster load variation and fluctuation.
4.0 High heat input to the furnace and hence high heat flux and high heat transfer rate.
5.0 Less unburnt fuel particle in flue gas, thus combustion and boiler efficiency further improved.
6.0 In case of FBC and pulverized coal combustion hot air can be used for drying the coal as well as for
transporting the coal into furnace.
7.0 This being a non pressure part shut downing of unit is not required due to corrosion of heat transfer surface or
failure.
The operation region involves low temperatures, where heat transfer takes place predominantly through convection
and little conduction. Since the thickness of tube is very less conduction heat transfer can be neglected.
As the air heater is located in cold end of heat transfer side, non-luminous radiation will be very negligible and
hence the same can be eliminated. (Above 400°C non luminous radiation heat transfer will be negligible).
The over all heat transfer coefficient can be estimated as per the derivation given in the super heater chapter. In that
equation neglecting fouling resistance and metal resistance we will get
U = ho x hidi/do
(ho + hidi/do )
1.0 Gas or air velocity inside tube has to be limited to maximum of 15 to 18 meters/sec and out side tube has to be
limited to 6 to 7 meters/sec beyond which hysterisis will occur.
2.0 The air or gas passes over the tubes, where the lesser number of tubes deep arranged this is to avoid higher
pressure drop.
3.0 The unit height of tube should not exceed 3.5 meters to avoid vibration problem and preferable height be 2 to
3m between tube sheets.
4.0 In FBC and conventional boilers it is desirable to heat the air not more than 180°c, in order to have a better
cooling for grate or Distributed plate.
Ex 01 Design tubular air heater for 200 TPH steam generator having following parameter,
Let the air heater be cross type and staggered arrangement and the boundary condition of air heater be
0.242x213156
Air flow area = h(num. of tubes in air path * pitch – num. of tubes in air path * od)
= 8.051 m/s
=25711
= 39.36 kcal/hrm²°C
Nu = 0.3 Re0.6
= 21097
2Km
U = 21.46 kcal/hrm²°C
Ln[(160.-26.67)/(271.3 –194.47)]
= 102.49°
As the flow is not perfectly counter flow, correction factor in lmtd of 0.95 has to be made.
‘f = 0.184/Re0.2
f = 0.184/ 257110.2
= 0.02414
=17.89 mmWc
‘f = 1.632/Re0.15
f = 1.632/ 210970.15
= 0.3665
8.1 INTRODUCTION
The advent of scientific and technological revolution has brought tremendous benefits to mankind and also given
rise to many problems related to our environment. Rapid industrialization as associated with scientific exploitation
of natural resources and this has resulted in contamination of three major constituents of our environment – air,
water and soil.
Combustion process is the main source of elements that pollute the atmosphere. A 500MW thermal power plant
produces 2000 tones of ash every day, it also produces about 50 MT of sulphur di oxide (considering sulphur
content in coal as 0.5%).
The consequences of air pollution have to be gauged from the factors like
1.0 First the amount of substances polluting the atmosphere are eventually accumulating
2.0 The distribution of pollutants is not uniform and in certain places, their concentration is in-admissibly high
4.0 The damages caused by air pollution is enormous. It involves losses in all the spheres of the national economy.
PARTICULATE EMISSION
Smog is closely linked to air pollution. Many cities in the world, particularly in London catastrophe of 1952,
roughly 4000 people are known to have lost their life due to smog. The phenomenon of smog is a mixture of smoke
and fog, has been related to temperature inversion, the heavier cold air saturated with industrial and transport
emissions remains near the grounds compressed under a dome off light warm air. Hence it is necessary for industry
to let the particulate emission to a maximum height possible. Pollution control board framed minimum height
required for letting out the smoke in atmosphere.
The unburnt carbon mono oxide in the presence of oxygen react and form carbon di oxide. This carbon mono oxide
loss reduce efficiency of power cycle and also it affects human population causing branchits problem.
CARBON DI OXIDE
The effects of air pollution cannot be completed without a reference to the green house effect. The dramatic
increase in the carbon di oxide level in today’s atmosphere is 27% higher than the year 1850. Scientists believe that
the growing burden of carbon di oxide and other gases are the causes for change in earth’s climate. ( Recent ELINO
effect increase in pacific temperature cause shift in monsoons) Carbon di oxide allows most of the solar radiation to
penetrate the atmosphere but prevents part of the heat re-radiated by land and water bodies from escaping into
space. It is estimated that the earth’s mean temperature could rise 1.5 to 4.5°C by the middle of next century if
green house gases continue to increase at current rate. This impact could be even greater at the poles. The rise in
global temperature could result in shift in rain fall patterns, melting of the polar ice caps and raising of ocean levels.
The wide ranging effects of atmospheric pollution under lines the need for controlling the industrial and other
emissions and heaving clean air in our atmosphere. The cost of providing clean air may be more, but the cost of
polluted air is much more.
Apart from particulate matter the other major air pollutants are gaseous pollutants. In general, gaseous pollution is
classified into two categories, namely inorganic and organic vapours. In the former class there are sulphur di oxide,
nitrogen oxides, hydrogen sulphite, hydrogen chloride, hydrogen fluride, carbon mono oxide and ammonia. In the
latter are the hydrocarbons, mercaptans, keytones and esters.
As per recent BIS standard the following limits have been recommended. The ambient air standards as propounded
by EPA(Environmental protection agency) of USA and adopted by BIS are shown in the following table.
SULPHUR DI
OXIDE
120 80 30
CARBON MONO
OXIDE
5000 2000 1000
NITROGEN
OXIDE
80 30 12
Air pollution control equipment is broadly classified into two categories- one controls particulate matter and the
other controls gaseous emissions. Various consideration are required to be made while selecting a control device for
an industry. Mostly industries face problem with particulate matter collection and gaseous emission has to be
controlled by proper pre treatment and maintaining certain design parameters such as dew point. For particulate
matters, some of the major factors are collection efficiency of the device, initial cost operating and maintenance
cost, space required arrangement, material of construction. Important factors considered in this connection are as
follows.
1.0 Particulate characteristics such as particle size range, shape, density and physical, chemical properties such as
agglomeration tendencies, corrosiveness, hydroscopic tendencies, stickiness, inflammability, toxicity, electrical
conductivity and others.
2.0 Gas characteristics such as temperature, pressure, humidity density, dew points of condensable components
viscosity, electrical conductivity etc.,
3.0 Process factors such as volumetric gas emission rate, particulate concentration, variability of material flow rates,
collection efficiency allowable pressure drop, product quality requirement etc.
4.0 Operational factors such as floor space, pressure, temperature, corrosion etc.
In boiler applications bag filter, ESP, Wet scrubber and centrifugal mechanical dust collector are quite widely used
for fly ash removal. So let us try to understand how these systems are operating and the merits and demerits of these
systems.
PRECIPITATOR
It is the cheapest and most effective dust collector. In the multi cyclone device there is a nest of cyclones in parallel
having one header and dust hopper. Here the centrifugal action removes the particulate from the gas stream. The
larger the particles, the more easily or they likely to be collected due to their proportionate higher ratio of centrifugal
force imparted to the particle of given mass. Dust collection depends on the radius through which the gas is turned,
the smaller the radius the higher the centrifugal force. Centrifugal action throw the heavy particles to the side of the
cyclone, where the dust can slide down to a hopper at the bottom. The cyclone works with two vortex. The cyclone
possesses a high separation factor given as the ratio of the radial velocity in the cyclones to the stokes velocity in
the setting chamber.
Large separation factor requires high tangetical velocities and small diameters, both of which result in a large
pressure drop. In India the industrial application of both large and small diameter cyclones are very common. The
multi cyclone dust collector can effectively remove dust particle of diameter above 50 microns and having a particle
density of 600 kg/m^3. So it is not always possible to meet the stringent emission levels to PCB norms, it becomes
essential to provide either a bag house or ESP.
BAG HOUSE
Basically, bag house is a large metal box divided into two chambers of plenums, one for dirty air and one for clean
air. Rows of cloth bags form a partion or interface between the plenums. A polluted gas stream is ducted into the
dirty air plenum, and is exhausted into the atmosphere through a stack. Almost 100% of the particulate matter in the
process effluent can be filtered out by bags if the system is designed, operated and maintained properly but bag
house will not be suitable for fuels like bagasse where burning particles may enter into bag house causing burning of
bags.
When a new bag house is first started up with factory fresh bags, some stack emissions are usually visible. This is
because the filtering medium (which is the bags made of fabric called Ryton and bag size is of 5m length and 0.3m
diameter) is porous and allows a certain amount of very fine particulate matter to pass through the interstices
between the fibers. After a short period of operation, a dust cake builds upon the surface of the bags and become
actual filtering medium. The bags, in effect act primarily as a matrix to support the dust cake.
The dust cake is desirable only upto a point, when that point is reached the bag must be cleaned properly other wise
the pressure drop through the filter system will continue to increase. At high pressure drops, particles of dirt can be
forced into the bag filters causing bags to become blinded. When this happens, air flow is restricted and the bags
may have to be replaced or removed and cleaned.
Maintenance personnel must learn to recognize the cause of the difficulty, and to mend it either by in planed action
or by contact with the manufacture. High pressure drop across the system is a symptom for which there are many
possible causes, example, 1. Difficulties with the bag cleaning mechanism 2. Low compressed air
3. Loose bag tension are usually available the reasons for high pressure drop and corrective action to be taken
appropriately. I have furnished below some of the check points to be taken care while doing routine bag house
inspection.
----------------------------------------------------------------------------------------------------------------
COMPONENTS CHECKLIST
----------------------------------------------------------------------------------------------------------------
daily)
Dust removal system Worn bearings, loose mountings, deformed
lubrication.
(housing, hopper)
Pulse system)
lubrication, damaged.
tight closing.
----------------------------------------------------------------------------------------------------------------
ELECTROSTATIC PRECIPITATOR
An electrostatic precipitator (ESP) consists very basically of a precipitator chamber and an electrical unit. The
precipitator chamber includes discharge and collection electrodes, an electronic cleaning system, gas distribution
devices, and a precipitator shell and hopper. The electrical unit is made up of a power supply, high voltage
transformers, rectifiers and precipitator bus sections.
ESP is physical process by which a particulate suspended in a gas stream is charged electrically and then, in the
influence of an electrical field, is separated and removed from gas stream. The system that does this consists of
positively charged collecting plate in close proximity to a negative charged emitting electrode. A high voltage
charge is imposed on the electrode and the grounded collection surface. The dust particles pass between the
electrode and grounded collection surface. The dust particles pass between the electrodes, where negatively charged
and diverted to the positively charged collecting plates.
Periodically, the collected particles must be removed from the collecting surface. This is done by vibrating (usually
by rapping) and or water washing the surface of the collection plates to dislodge the dust. This dislodged dust drops
into a dust removal system and is collected for disposal.
Discharge electrode failure is the primary cause of operational breakdown. After this are rapper malfunctions,
insulator failure, shorts caused by dust build up, hopper plugging and transformer- rectifier failures. Most of these
problems occur when preventive measures are not used. For example discharge electrode failures can be reduced if
the hoppers are properly discharged and cleaned to prevent grounding out and burning off the discharge electrodes.
Fly ash build up on the collecting plates should normally be about 1/8 to ¼ inch thick. If the build up exceeds this
thickness, the intensity of the plate rappers should be increased. If the collecting plates are clean, this may be an
indication of high gas velocity or low operating voltage.
Collecting plates should be checked for proper alignment and spacing. Hangers and spacers at the top and bottom
should be adjusted so that they do not bind the plates or prevent proper rapping. It is necessary to check for
corrosion.
Hoppers should be checked periodically to be sure they empty properly and to inspect for corrosion, which is likely
to be most severe at points where at points where dust builds up. The heating system and insulation on the hoppers
are checked to prevent condensation.
Insulator compartments and housings must be checked frequently, leakage of corrosive gases from the precipitators
into this area can cause dirt deposit that result in breakdown of electrical insulators.
9.0 WATER CHEMISTRY
9.1 INTRODUCTION
All system obeys law of conservation, energy can be neither created nor destroyed but energy can be converted from
one form to another. In the system of power cycle, water is basically most important raw material which acts as
energy transferring element.
As the raw water contains dissolved solids, suspended matters like mud, clay, calcium and magnesium salts free
minerals and dissolved gases like oxygen and carbon di oxide, hydrogen sulphite etc., it is required to be treated
before it is fed into the boiler to prevent boiler damages and to get required steam purity.
Most of the boiler shut downs are arise due to uncontrolled water treatment, an unnoticed boiler shut down runs in
loss of money to company. Therefore it is necessary to have a controlled water quality for the boiler.
Although the manufacturers supplies and recommends water quality, it is upto the plant personnel to meet the
required water quality. It is not possible to suggest one type of water treatment for all the industry as composition of
different water supply vary greatly from place to place and from time to time. Therefore selecting water treatment
plant starts with analyzing the raw water. The water should be analyzed periodically, if the supply or availability is
seasonal, the treatment plant selected is based on the worst analysis made by the study conducted in series for
minimum of one year. In high pressure boiler plant, engineer should not hesitate to stop the boiler if water treatment
plant fails or water quality is poor.
e) Demineralised
water or
f) Deaerated
g) Feed water - Any mixture of the above to pass through feed pump.
Surface water: Ponds, Lakes, Reservoirs, Streams and rivers are the sources of surface water.
Ground water: Wells, Mines and Springs are sources of ground water.
In water the major dissolved impurities are bi-carbonate, sulphates, chlorides, nitrates of calcium and magnesium.
Minerals have two components Radial or acidic component and metallic component. In the water analysis as there
are various solids dissolved in various percentage, the concentration of dissolved salts impurities are reported in
CaCo3 terms only.
Temporary hardness are due to calcium, magnesium bi carbonate salts. These does not cause hard scales and these
can be removed by boiling the water. Calcium and magnesium bi carbonates are broken down by moderate
heating(100°C) into relatively insoluble mono carbonate and carbon di oxide as given in the reaction.
The less soluble salt like calcium carbonate precipitate and settle in the boiler water which can be removed by blow
down.
Permanent hardness are due to sulphates, phosphates of calcium and magnesium salts. These form sticky hard
scales and the amount of dissolved salts in water is the measure of hardness. Among all, calcium is the principal
scale forming agent and particularly calcium sulphate. Solubility of Ca SO4 decreases with increase in water
temperature.
a) Acidity
Boiler water should be always alkaline in nature. The alkalinity is to be maintained for the following reasons.
1.0 To keep magnetite layer (Iron oxide) uniform, which protects the metal and minimize corrosion and to promote
formation of magnetite layer as and when impaired.
3.0 To keep silica in soluble condition preventing precipitation and carry over.
Highly acidic water dissolves metal and mild acidic water hastens pitting and oxygen corrosion.
b) Alkalinity
Alkalinity should also be maintained as per recommended value based on drum pressure ratings. Higher values
result in foaming leading to carry over and also caustic embrittlement. In highly concentrated alkali the protective
film of magnetic is dissolved forming a mixture of ferrite and hypo ferrite irons. But at low concentration the layer
of magnetite is porous. In the presence of pororus deposit hydroxyl ions tend to concentrate between metal and
deposit leading to a typical corrosion pattern called caustic gauging.
c) Hardness
Most of the calcium and magnesium salts present in the water contribute hardness. Ex: calcium carbonate,
magnesium silicate etc., there salts form sludge and calcium sulphate, calcium silicate etc., form scales on the
evaporating surface. Hardness is measured in terms of mg/lit or ppm as CaCo3.
Alkaline hardness
Hardness caused by the presence of bicarbonate, carbonate, hydroxide of calcium and magnesium (temporary
hardness). Alkalinity is the concentration of alkaline salts. Bicarbonate alkalinity due to bicarbonate salts, caustic
alkalinity due to hydroxide salts (P or phenophthaline alkalinity).
M- alkalinity is the total alkalinity which is a combined hardness of bicarbonate and hydroxide salts. Hence in an
analysis P never exceeds M alkalinity.(if P= M then alkalinity is due to hydroxide, if P=0 then alkalinity is due to
bicarbonate and carbonate)
Total hardness(H)
Total hardness is the concentration of calcium and magnesium salts. If total alkalinity (M) exceeds total
hardness(H) then the hardness due to bicarbonate, carbonate and hydroxide only the value(M-H gives sodium
bicarbonate present in water)
Total alkalinity (M) less than total hardness (H) then the value (H – M then gives carbonate hardness) ie. Remaining
is non alkaline hardness.(chlorides, nitrates, sulphate)
If total hardness is equal to total alkalinity the only carbonate hardness is present.
d) Oxygen
Water at room temperature always contain oxygen in dissolved form of air. Oxygen promotes corrosion. The rate
of wastage and thinning of tubes in highly acidic water is enhanced heavily by the presence of oxygen. Oxygen is
released from water on heating.
All the salts dissolved in the water (sodium, calcium, magnesium ) are together accounted against total dissolved
solids. The effects of the total dissolved solids in feed water depends on the type of salt and the type of boiler. The
effect are also complex due to mutual action between the various salts. Generally, presence of chlorides, iron salts
accelerate corrosion. Presence of other salts increase scale formation, priming (sweeping action of suspended solids
towards steam outlet) and foaming ( Persistent bubble formation). Priming and foaming cause carryover of solids
and heavy fluctuation in water level. A high TDS in the boiler water will also increase steam contamination. 0.1
mg/lit is the limit to TDS in steam used for TG sets. Approximately value of TDS in mg/lit can be obtained by
measuring the electrical conductivity in micro siemens/cm. It is found that TDS will be approximately half that of
conductivity.
Conductivity
Pure water is a poor conductor of electricity, but water contain ionized impurities such as salts, acids, alkali is
conductive and it can be used to define purity of water. The conductivity produced by the presence of given
concentration of impurity depends upon nature of impurity and temperature of water. It is measured in terms of
micro siemens per cm because the numerical value of the same is found proportional to the concentration of
dissolved solids in mg/lit or ppm.
f) Turbidity (NTU)
Turbidity is an indicator of undissolved solids. Turbid water may induce erosion. The undissolved solids also
impair circulation of water on the heating surface which in turn can reduce the cooling action of the water. The
undissolved solids cause consequent over heating of the surface. In practice suspended undissolved solids are
expressed in ppm and micro organic undissolved solids are expressed in NTU.
Dissolved carbon di oxide appears in the water in the form of carbonic acid. The bicarbonate salts present in the
water are often considered as bound carbon di oxide in the water. Carbon di oxide being a gas separated out of
water on heating. The carbon di oxide released from water gets carried away along with steam and when steam
condenses the carbon di oxide redissolves in the condensate forming carbonic acid. This acid corrodes pipe lines
and other user equipment.
h) PH value.
It is not a constituent or impurity. The concentration of hydrogen ions produced by various chemicals dissolved in
water.
+ _
H2O Æ H + OH
In pure water hydrogen ion concentration will be 0.0000001 gm/lit. of water or 10-7 of hydrogen ions per liter. This
is balanced by hydroxyl ions(same amount). If HCl or any acids dissolved in water it gives additional hydrogen ions
causing increase in hydrogen ions 10-7 Æ 10-6 Æ 10-5 ie water becomes acidic. Hence for PH value of 7 water is
neutral and PH less than 7 is acidic greater than 7 in alkaline. The corrosion rate is foud to be very slow when PH
range is 9.5 to 10.5 in boiler water. The protective magnetite (a corrosion product) is not distubed under the above
regimes.
Tube failure.
Hydrogen damage is mainly due to low PH environment. Presence of carbonic acid, improper deaeration, condenser
leakage. Hydrogen produced in the boiler water diffuses through underlying metal producing decarburisation and
inter granular micro fissuring of the structure. Brittle fracture occurs in the tubes, the failure will be of thick edged
fracture.
Ductile corrosion is more probable when boiler water contains highly soluble alkaline treatment chemicals such as
sodium hydroxide. PH VS PHOSPHATE curve has to be followed to limit free hydroxide. In this the metal is
gradually eaten away and when tube is insufficient to with stand the pressure, tube fails by pinhole or burst. It is
predominantly seen in low sloped tubes such as roof tube, bed coils, idle compartment with zero flow are attacked
by this.
j) Iron
Iron will form sludge like layer and prevent heat transfer. Iron content in water will be removed by oxidizing
ferrous iron to ferric iron by air and catalyst, then filtered and in some cases special iron removing technique/
equipment will be employed.
k) Organic matter
The soluble organic matter present in natural water are either fulvic or humic acid material ( Fulvic fairly recent
organic decay, Humic – old organic decay). Main source of organic matter in the boiler water is oil, grease with in
the boiler, pipeline, pumps etc. It is difficult to predict the effects of organic matter in the water as it depends on
their nature. Oil and grease induce priming and foaming consequently water level fluctuations and carry over.
Methods to get rid of the offending impurities in the water and to ensure the quality requirement is given
below.
Hydrazine chemical
Deaeration doser
Demineralize
Sand filter
High pressure boilers are normally designed close to the limiting conditions of heat transfer, tube metal temperature,
circulation etc., to make the units compact and economical. Modern steam turbine rated for high capacities call for
stringent steam quality to avoid damages. Without strict control over the impurities in steam cause, deposits over
turbine blades and nozzles reducing the output. Thus successful operation of high pressure boiler and turbine unit
requires a through understanding of all aspects of water treatment. In short the following are the reasons for need of
treatment.
1.0 In an effort to optimize capacity and efficiency, deposit of any sort on tubes are virtually intolerable.
2.0 Optimization of tubes thickness can not even a moderate level of corrosion tgo take place.
3.0 Blow down requirements are being cut to have energy conservation.
4.0 High steam purity requirement calls stringent quality. Foreign particles like oil, organic matter, iron and copper
ions contaminate the purity.
TDS in steam = ( TDS in boiler water/ sodium in boiler water) x sodium in steam
Removal of suspended solids or flocullants can be achieved by sedimentation coagulants or salts of aluminium or
iron added. Salts react with alkalinity to produce precipitate that attract and absorb fine suspended solid and
organic matter to form large floc particle which settle easily. This process is clarification and done in clarifier.
Filter alum
Coagulation is the process by which the positively charged co-agulants attract the negatively charged fine
suspended matter and repulsive force is reduced. For effective coagulation temperature and PH conditions to be
maintained properly. Floculation is the aggregation of particles under the influence of agitation. Chlorine addition
to destroy organic matter because organic matter tends to keep some iron and manganese in solution and aeration is
preceded in the case of iron and manganese presence. Aeration leads to oxidation of iron and manganese and
removal of carbon di oxide.
FILTERATION
Filter bed are of stone gravel or coarse anthracite. Anthracite is non silcieous and does not add silica to water.
Gravity filter are open type RCC tank and treatment is carried 5 to 6 meter per hour and used for treatment of high
amount of water.
ION EXCHANGE
Demineralization use of both cation and anion exchange for removal of dissolved solids. Ion exchange resins are
hard spherical beads of 0.3 mm to 1.2mm diameter. It swells when it condact with water. Resin is to be kept moist
and supplied in wet form. When resin gets dried the resin will be cracked and lose its ion exchange properties.
Hence storing for long period is not advisable. In ion exchange SAC,WAC,SBA, WBA,MB and degasser are
arrangement in different combination to get the desired water quality based on the raw water analysis.
Ca HCO3 HCO3 Ca Ca
Na SO4 H2SO4 Na Na
REVERSE OSMOSIS
Recent times due to the fast industrialization all natural resources are more polluted which results in water level
TDS increase to 1000 and above ppm of CaCO3. To use thes high TDS water for boiler, TDS level has to be
brought down and more over chemically treating this high TDS water will be highly uneconomical. Osmosis is the
technique where in two solutions of low and high TDS water are separated by semi permiable membrane results
movement of ions from high concentration to low concentration zone. Reverse osmosis is the reversal of osmosis
process by applying external force where in movement of ions will be from low concentration to high concentration
zone.
After deaeration, deaerated water gets collected in deaerated storage tank. This deaerated water contains traces of
oxygen due to the in complete mechanical/ thermal deaeration. These traces of oxygen is scavenged by chemical
deaeration. Chemicals like sodium sulphite or hydrazine is dosed to the suction header offered pump by LP dosing
pump. Residual hydrazine of 0.02 ppm has to be maintained in feed water.
Hydrazine reaction
N2H4 + O2 Æ N2 ↑ + H2O
2Na2SO3 + O2 Æ 2Na2SO4
Na2SO3 + H2O + HEAT Æ 2NaOH + SO2 at 900 to 1000 psi
Hence it is not recommended in high pressure boilers. It also can not be used with co-ordinated phosphate treatment
since it affects balance of sodium and phosphate.
Ex.02. Calculate the quantity of hydrazine required for the steam generator of capacity 65000 kg/hr. after deaerator.
The oxygen percentage after deaerator is 0.02 ppm and the desired level of oxygen in feed water is 0.007 ppm.
Hydrazine for 55.6 kg/sec of water = 0.046 x 65000 = 2990 mg/hr at 100% conc.
Hydrazine available is at 60% conc. Therefore the required hydrazine of commercial grade = 4983 mg/hr.
Scale formation is limited by converting hardness salts to a free flowing sludge. Hp dosing is done by carbonate
control or phosphate control by addition of sodium carbonate or tri sodium phosphate respectively. Other chemicals
such as sodium hydroxide or calcium oxy phosphate can also be added. Best result of calcium carbonate ,
magnesium hydroxide, calcium silicate, magnesium silicate will be available as free flowing sludge where caustic
alkalinity is 10 to 15% of the dissolved solids. OH alkalinity leads to prevention of magnesium phosphate as bad
scale by converting magnesium to magnesium hydroxide. If there is no effective means of blow down is available it
is better not to concentrate on internal treatment. Tri sodium phosphate is done in such a way that boiler blow down
contain residual phosphate(PO4) of 7 ppm.( I.e., 4 ppm of Na3PO4.12H2O contain 1PPM PO4, hence 28PPM tri
sodium phosphate required, 0.028 kg tri sodium phosphate per 1000 kg of water blow down.)
Ex.03. Calculate the tri sodium phosphate quantity required for the above specified boiler in example 01. Consider
blow down of 1%.
BLOWDOWN
In spite of all treatment, boiler water will contain dissolved solids. In order to keep the level of total dissolved solids
in boiler within the limits and to remove any sludge, loose scales and corrosion products, a certain quantity of boiler
water should be regularly drained. This process is known as blow down. The blow down can be intermittent say
once a shift or continuous. The quantity of the water to be blow down will depend on the dissolved solids entering
the boiler through the feed water and the maximum tolerable levels of these salts in the boiler water. While
determining the dissolved solids content in the feed water it is necessary to takes into account not only the original
dissolved solids but also the dissolved solids added in the form of dosing.
Continuous blow down
Continuous blow down is a continuous removal of boiler water controlled by a specially designed adjustable valve
or by an orifice plate. The installation of heat recovery equipment in continuous system may be economically
justified. Suspended solids may block or erode the adjustable valve or orifice plate and continuous blow down is
there fore limited to the control of dissolved solids. Additional manual blow down is necessary to control suspended
solids and prevent the build up of sludge.
When boiler water from high pressure is suddenly reduced to low pressure blow down water, water enthalpy will
drop and steaming will occur. In utility boilers recovering this blow down flash steam proves economical. The
quantity of flash steam generated is the product of ratio between difference in boiler water enthalpy and blow down
water enthalpy to latent heat of blow down water and blow down quantity.
Intermittent blow down may be effected by specially designed values either operated manually or automatically
controlled by timers, feed water flow and conductivity. It should be noted that the most effective intermittent blow
down is achieved by frequent full open operation for short intervals rather than small extended infrequent operation.
It is not practicable to recover waste heat from infrequent intermittent blow down.
Ex.04 Find the blow down quantity and flash steam produced for a 160tph boiler operating at a pressure of 120
bar(a) and the permissible silica content in feed water and boiler water be 0.01ppm and 0.8ppm respectively. The
flash steam blow down vessel is maintained at 4.5 bar(a).
( C –S)
At 120 bar(a)
4.5 bar(a)
In modern industries automation is carried by means of micro processor chips (µp) made of silicon, the semi
conductor which controls all the functions. The basic building blocks of integrated chips are of diodes, gate circuit.
Today’s boiler are designed with high heat flux and very high capacity, safety and automation is becoming prime
important. Automation of boiler is done primarily by relay system and microprocessor system. Relay technology is
the oldest one, even now adapted for small industrial boilers for the basic boiler inter locks like trips and alarms.
Most of the automation is carried by microprocessor based control.
1.0 Boiler water level has to be maintained always in the system in order to prevent starvation boiler and tube
failure due to over heating.
2.0 The steam temperature at the outlet of superheater has to be controlled within the limits other wise higher
metal temperature leads metallurgical problem and also it affects turbine and condenser performance due to
volumetric change and dryness fraction shift.
3.0 The draft system has to be controlled according to the design of the boiler, i.e. if the boiler furnace designed
for negative pressure and if subjected to positive pressure due failure of draft equipment back firing will take place,
Which is hazardous to boiler and the people.
4.0 In the view of boiler performance, the combustion of fuel takes place completely with minimum excess air.
Hence air flow control with respect to fuel has to be done and fuel flow with respect to steam demand has to be
achieved.
5.0 Considering acid dew point corrosion to metals, the metal temperature at the back end of economiser tubes or
air heater tubes has to be achieved. For this cooling medium temperature inlet temperature at exhaust gas exit
temperature above the dew point has to be maintained.
6.0 If there is any tripping of rotating equipment like fans, pumps due failure of the equipment or power the boiler
has to be tripped automatically. For this interlock arrangement has to be made. Further to this, if equipment trips
due to its own defect the stand by equipment has to be started automatically.
In the above point numbers one to five involves variables with complex non linear and linear relation ship this is
grouped as PID controls and point number six is interlocks with change of two states (on or off) is called on/off
control.
Instrumentation
In boiler controls, as explained earlier the instrument can be broadly classified into field instruments and panel
instruments. The field instrument comprises mainly of Sensors, Transmitters, Actuators etc.,
10.7 FIELD INSTRUMENTS
Sensors
Sensors which has to sense the mechanical process parameters like pressure, temperature, flow etc., In boiler
application the following are the major process parameters to be converted into electrical signal for measuring and
controlling purposes.
1.0 Flow
2.0 Pressure
3.0 Temperature
4.0 Level
5.0 Flame
Transmitters
The sensed or measured process parameter variable has to be transmitted from the field to control panel. For this
transmitters converts the process parameter into electrical current of 4 to 20 mA which will be transmitted through 2
core, copper cables.,
1.0 FLOW
The flow measurement is made based on several principle, some of the commonly used instruments are, differential
pressure flowmeter, area flowmeter, positive displacement flowmeter, eletro magnetic flowmeter, ultrasonic
flowmeter. The type of flow meter selection is based on accuracy, magnitude of flow, type of fluid being used like
liquid or gas, properties of fluid like temperature, pressure, viscosity etc.,
This is also called constriction flowmeter. The flow sensors either orifice or nozzle or venturi etc., this type of
flowmeters are widely used in industries for various application.
2.0 PRESSURE
Pressure is applied to the two sides of the twin diaphragm capsule. The pressure is transmitted from the twin
diaphragm to the sensing diaphragm through the sealing liquid. Two fixed electrodes are placed symetrically on the
left and right side of the insulator and electrical capacitance is formed between these electrodes and sensing
diaphragm.
3.0 TEMPERATURE
a) Sebeck's effect
When junctions formed between two dissimilar metals kept in two different temperature, an electromotive force is
induced in the system. It is called Sebeck's effect.
.
4.0 LEVEL
In boiler drum level maintenance is one of the critical parameter for safe boiler operation.
5.0 FLAME
Flame or light is detected by photo electric cells. Presense of UV or IR rays is detected by the Photo cells and
produce an emf. This signal is used in burner scanner and fire alarm application.
The position of an actuator has to be constantly feed backed to the remote center. In order to have a control over the
process parameters. The actuator movement can be either of linear or circular.
b) Inductive Sensors
The actuator movement is transmitted to the rotating shaft of the positioner. The cam is attached to the shaft is
scanned by an inductive non contact sensors. The angle of rotation is then converted to an electrical signal, as
shown in the diagram. The main advantage of this type of sensors is there is no frictional contact between rotating
part and sensor. The sensor senses the varying gap due to the cam movement and produces varying current level by
induction. Sensors are supplied with 24 V DC for generation of 4 to 20 mA.
(e.g.) The control valve actuators used in flow control and pressure control uses this type of inductive principle.
The signal given from field instrument is processed in panel and necessary control signal will be generated in the
panel and the same is send to field for control action. Due to the industrial development various control techniques
and automation has been adapted in industry. The following Instrumentation system hierarchy gives the basic
concept behind the same.
Management
Distribution Concentration
F Steam
L Drum LT PT FT TT
4 to 20 mA signal
A Σ √
E PV
L SP internal Σ
LIC
I CV Σ
N SV
T FIC
M PV
E I/P √
F FCV
I
E Air supply FT
Three element drum level control loop have one or more drum level, feed water flow and steam flow transmitters
for achieving level control. The controller receives input from the above three main transmitters and depends on the
level set point the processed output of the controller will actuate the control valve in feed line either to close or open
as desired by the controller.
E TE thermocouple
L 4 to 20 ‘mV
D signal
A Controller mA signal
N TIC
I/P
Air supply
F SCV
L Air supply
D
I Furnace pressure
E PT
L 4 to 20 ‘mA
D signal
A Controller mA signal
N PIC
I/P
Air supply
F Power cylider
L Air supply
D ID fan damper
In super heater steam temperature control the measured variable steam temperature is compared with set point or
desired temperature in the controller and accordingly the spray control valve is regulated. Similar to the temperature
control, in draft control furnace pressure is measured by means of pressure transmitter and controlled by regulating
the ID fan damper.