Chemistry: Pearson Edexcel
Chemistry: Pearson Edexcel
International
Advanced Level
Chemistry
International Advanced Subsidiary/Advanced Level
Unit 3: Practical Skills in Chemistry I
Sample Assessment Materials for first teaching September 2018 Paper Reference
Instructions
• Use black ink or black ball-point pen.
• centre
Fill in the boxes at the top of this page with your name,
number and candidate number.
• Answer all questions.
• Answer the questions in the spaces provided
– there may be more space than you need.
• Show all your working in calculations and include units where
appropriate.
Information
• The total mark for this paper is 50.
• The marks for each question are shown in brackets
– use this as a guide as to how much time to spend on each question.
• There is a Periodic Table on the back page of this paper.
Advice
• Read each question carefully before you start to answer it.
• Checkanswer
Try to every question.
• your answers if you have time at the end.
Turn over
S58311A
©2018 Pearson Education Ltd.
1/1/1/
*S58311A0116*
Answer ALL questions.
(a) (i) Name the most suitable piece of apparatus for measuring 50 cm3 of
copper(II) sulfate solution.
(1)
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(ii) The diagram shows part of the thermometer at 4 minutes. Record the
temperature in the table of results and plot the point on the graph.
(1)
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60
50
40
Results
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Time / minutes 0 1 2 3 4 5 6 7 8 9 10
Temperature / C 19.0 20.5 20.0 20.0 62.5 58.5 55.0 52.0 48.5 45.0
80
70
60
50
Temperature 40
/ C
30
20
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10
0
0 1 2 3 4 5 6 7 8 9 10 11
Time / minutes
2
(b) The maximum temperature change for the reaction, T, is estimated by drawing
two lines of best fit on the graph and extrapolating them.
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T = ................................................. . . . . . . . . . . . . . C
(iii) Give a reason why the temperature of the solution is measured for 3 minutes
before adding the zinc.
(1)
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(iv) Give the main reason why the temperature of the solution is measured over a
period of time after adding the zinc.
(1)
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(c) (i) Use the value you have obtained for the temperature rise ( T ) in (b)(ii)
to calculate the heat energy produced in the reaction between zinc and
copper(II) sulfate solution. Include units with your answer.
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(Assume the specific heat capacity of the solution to be 4.2 J g–1 C–1 and the
density of the solution to be 1.0 g cm–3.)
(1)
(d) Suggest one improvement to the procedure, other than changing the measuring
equipment or repeating the experiment, which would give a more accurate result.
(1)
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2 A student was given five boiling tubes, each containing one aqueous solution:
dilute hydrochloric acid, HCl(aq)
Table 1
5
(a) (i) Identify each of the solutions from the observations recorded in Table 1.
Write the letter that corresponds to each solution in Table 2.
(3)
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Solution Letter
potassium carbonate, K2CO3(aq)
sodium iodide, NaI(aq)
sodium chloride, NaCl(aq)
Table 2
(ii) State how you use the observations to distinguish between potassium carbonate
and sodium chloride solutions.
(1)
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(b) The student suggested that a flame test could also be used to help to distinguish
between potassium carbonate solution and sodium chloride solution. State how
the flame colours would differ.
(1)
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(c) A further chemical test was carried out on the precipitates from Test 3 to confirm
the identity of the original solution.
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Give this test, and its result, which would distinguish between sodium iodide
solution and sodium chloride solution.
(2)
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3 This question is about the reaction sequence involving compound F, which has the
molecular formula C3H8O.
K2Cr2O7(aq) and
Reaction 3 Reaction 2
H2SO4(aq)
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(ii) State what can be deduced about compound F from this observation.
(1)
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(b) The infrared spectrum of liquid F is shown.
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Transmittance (%)
40
Give the wavenumber range of the absorption which confirms your deduction in (a)(ii).
(1)
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(c) Gas H, C3H6, was formed in Reaction 2. The functional group present in H was
identified by shaking a sample of H in a test tube with a few drops of bromine
dissolved in a non-polar organic solvent.
(i) Give the colour change observed for this reaction.
(1)
From ...................................................................................................... . . . . . . . . . . . . . . . . . . . . . .
To ...................................................................................................... . . . . . . . . . . . . . . . . . . . . . .
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(d) Reaction 3 was carried out by slowly adding a solution of acidified
potassium dichromate(VI) to liquid F in a cooled flask. The flask was set up for
distillation and gently heated. The product, J, was distilled directly out of the
(2)
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(e) The identity of J can be confirmed by spectroscopy and by chemical tests.
(i) The infrared spectrum of J has absorbances at 2716 and 2893 cm–1.
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Identify the bond responsible for these absorbances, and hence the
functional group in J.
(1)
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(ii) Give a chemical test and its expected result to confirm the identity of J.
(2)
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(f ) Name compound F.
(1)
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4 A class of students carried out experiments to determine the value of x in the formula
of hydrated sodium carbonate, Na2CO3.xH2O.
Measurement Value / g
Table 3
(b) (i) Calculate the number of moles of water removed on heating the hydrated
sodium carbonate.
(1)
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(iii) Use your answers from (b)(i) and (b)(ii) to calculate the value of x. Give your
answer to three significant figures.
(2)
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(c) Each use of the balance to find a mass reading in the table has a maximum
uncertainty of ±0.005 g.
Calculate the percentage error in the measurement of the mass of the crucible
and hydrated sodium carbonate (26.06 g) before heating.
(1)
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(d) The Data Book value for x is 10.
One student obtained a value for x of 8.63 and another student obtained a value
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(e) Devise an experiment involving a titration that could be used to determine the
value of x in Na2CO3.xH2O.
List the essential steps in the practical procedure.
You are not expected to explain how the data is used to calculate x.
(4)
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