Quantum Physics Berkeley Physics Course Volume 4 PDF

The constants In this table might well be memorized so that
they are always available for simple estimates. See Table A

in Appendix for precise values.
! Avogadro’s number; Nn ^6x IQ2B (mol)-1
Velocity of light; 6 ^ 3 x IQ10 cm/sec
Electronic charge; e;1.6x IQ-10 coulomb
Fine-structure constant: a cr 1/137
Rest energy of electron; me2 ^ 0.5 MeV
Rest energy of proton: Mpc2 ~ 940 MeV
Ratio of proton to electron mass: Mp/m zz 1800
Ionization energy of hydrogen: = fa£mc2 ~ 13,6 eV
Bohr radius in hydrogen: ao = %/a ^ 0.5 A - 0.5 x 10^s cm
Bohr magneton: (eH)/(2mc) ^ 5,8 x TO-9 eV/gauss
Nuclear radius (mass number A): r ^ A1/3 x (1.2 x 10 13 cm)
Nuclear binding energy/nucleon; ~ 8 MeV
11 Room temperature”: k x (293*K) sr (1/40) eV
"Optical region”: 4000 A-70G0 A

3.0 eV-1.8 eV
ONE ELECTRON VOLT corresponds to:
r Temperature: zz 12,000ffK
Frequency: ~ 2.4 x 1014 cycles/sec
-< Bulk energy; ^ 23,000 cal/mol
Wave number: ^ 8000 cm-*
L Wavelength: :zr. 12,000 A
Front cover: Term scheme of neutral thallium atom .

Back cover: Baryon decuplet
quantum
physics
berkeley physics course—volume
The preparation of this course was supported by a grant

from the National Science Foundation to Education
Development Center, Incorporated,
Eyvind H. Wichmann
Professor of Physics
,
University of California Berkeley
quantum physics
Copyright © 1967, 1971 by Education Develop¬
ment Center, Inc. (successor by merger to
Educational Services Incorporated). All rights
reserved. Printed in the United States of
America. This book, or parts thereof, may not
be reproduced in any form without the written
permission of Education Development Center,
tnc.r Newton> Massachusetts.
Library of Congress Catalog Card Number

64-66016
04861
1234567890 MWMW 79876543210
Preface to the Berkeley Physics Course
This is a two-year introductory college physics course for students

majoring in science and engineering. The intention of the writers
has been to present physics in so far as possible as it appears to
physicists working on the forefront of their field. We have sought
to make a course which would vigorously emphasize the foundations
of physics. Our specific objectives were to introduce students early
to the ideas of special relativity, of quantum physics, and of statis¬
tical physics. At the same time we wanted our presentation to be
of an elementary character* and it was never our intention to de-
velop a course limited to honors students or to students in advanced
standing. This course is intended for any student who has had
physics in high school. A mathematics course including calculus
should be taken concurrently.
The five volumes of the course include: *
I. Mechanics (Kittel, Knight, Ruderman)
IL Electricity and Magnetism (Purcell)
III. Waves (Crawford)
IV. Quantum Physics (Wichmann)
V. Statistical Physics (Reif)
The initial work on this course led Alan M. Fortis to devise a new
elementary physics laboratory, now known as the Berkeley Physics
Laboratory. Because the course emphasizes the principles of
physics, some teachers may feel that it does not deal sufficiently
with experimental physics. The laboratory is rich in important ex¬
periments, and is designed to balance the whole course.
In recent years several new college physics courses have been
planned and developed in the United States. The idea of making a
new course has come to many physicists, aware of developments in
science and engineering, and of the increasing emphasis on science
in elementary schools and in high schools. Our own course was
conceived in a conversation between Philip Morrison, now of the
* Of these Volumes I, II, III, and V have appeared previously. The changes in our
common preface for the present volume reflect some organizational changes under
which this volume was prepared
V
f?i Preface to the Berkeley Physics Course
Massachusetts Institute of Technology, and C. Kittel late in 1961,

We were encouraged by John Mays and his colleagues of the Na¬
tional Science Foundation and by Walter C. Michels, then the
Chairman of the Commission on College Physics. An informal
committee was formed under the Chairmanship of C. Kittel to
guide the course through the initial stages. The committee met first
in May 1962, in Berkeley, and at that time drew up a tentative out*
line, incorporating topics and attitudes which we believed should
and could be taught to beginning college students of science and
engineering. The membership of the committee has since under¬
gone some changes, and it now consists of the undersigned. In the
development of the course each author has been free to choose that
style and method of presentation which seemed to him appropriate
to his subject.
The financial support of the course development was provided by
the National Science Foundation, with considerable indirect sup¬
port by the University of California. The funds were administered
by Education Development Center, Incorporated0 (EDC), a non¬
profit organization established to administer curriculum improve¬
ment programs. We are particularly indebted to Gilbert Oakley,
James Aldrich, and William Jones, all of EDC, for their sympathetic
and vigorous support. EDC established an office in Berkeley, most
recently under the very competent direction of Mrs, Lila Lowell, to
assist the development of the course and the laboratory.
The University of California has had no official connection with
our program, but it has aided us in important ways. For this help
we thank Professor Burton J. Moyer, Chairman of the Department
of Physics, and the faculty and nonacademic staff of the Depart¬
ment. We are particularly grateful to those of our colleagues who
have tried this course in the classroom and who, on the basis of their
experience, have offered criticism and suggestions for improve*
ments.
Your corrections and suggestions will always be welcome.
Frank S. Crawford, Jr,

Charles Kittel
Walter D. Knight
Alan M. Portis
Frederick Reif
Malvin A. Ruderman
Eyvind H. Wichmann
A. Carl Helmholz \ ^ ,
Edward M. PurceD / Cha,mm
* Formerly Educational Services Incorporated.

Preface to Volume IV
This volume of the Berkeley Physics Course is devoted to Quantum

Physics, It is an introductory book, intended for the student whose
background in physics corresponds to a fair fraction of the material
in the preceding volumes of the series, My ideal reader-learner is
thus a student of science or engineering in his sophomore year. To
postpone the study of all aspects of quantum phenomena beyond
the sophomore level does not seem reasonable and fair today in
view of the developments in physics during the last fifty years. A
well-balanced introductory course should certainly reflect some of
these developments,
I do not believe that the study of quantum physics is intrinsically
more difficult than the study of any other branch of physics. In
every domain of physics we encounter phenomena which we feel
are simple and transparent, as well as phenomena which are very
difficult to account for in a quantitative fashion. It is true, of
course, that all quantum phenomena were at one time regarded as
highly mysterious and perplexing. In the period during which the
field was first explored, physicists experienced very real psycholog¬
ical difficulties which derived partly from understandable prejudices
in favor of the classical view of the world, and partly from the frag¬
mentary nature of the experimental picture. There is, however, no
reason why these same difficulties have to be re-created for the
beginning student of today, It is now known with certainty that
the classical description is only approximately correct, and there is
now available an enormous body of experimental results which sup¬
port and illuminate various aspects of present theoretical ideas. I
firmly believe that among the known facts one can find topics for
discussion which are clear-cut and simple enough to be dealt with
in an elementary manner, but which at the same time illuminate
important ideas and principles, I doubt very much that the student
who is guided to think about a well-chosen sequence of simple but
significant physical facts will feel that quantum phenomena are
more mysterious than, say, the phenomenon of universal gravitation.
My purpose in this book is to present characteristic examples of
quantum phenomena, to acquaint the reader with typical orders of
viii Preface to Volume IV
magnitude of physical parameters in microphysics, and to introduce

him to quantum-mechanical thinking. 1 have tried to include
among my topics for discussion, phenomena and issues which are of
particular importance for the understanding of physics. At the
same time I have tried to keep the discussion as elementary as pos¬
sible. I have selected my topics from the various domains of micro-
physics, but I have made no attempt to present a detailed systematic
account of any of these domains. Such accounts should, in my
opinion, be left for courses at the junior-senior level.
The requirements with respect to mathematical preparation are
modest. I assume that the reader has had a course in calculus, in¬
cluding a first introduction to ordinary differential equations and
some vector analysis. In order to prevent a shift of attention from
the physical issues to technical mathematical questions, 1 have tried
to avoid topics which at this stage might appear mathematically
difficult. Topics which call for some knowledge of the properties
of special functions, or of the method of separation of variables in
the theory of partial differential equations, are not discussed at all.
With regard to algebra I have concluded, with some regrets, that I
should not assume familiarity with matrix theory, and I have there¬
fore avoided topics for which matrix theory is the natural mathe¬
matical tool.
I do not by any means believe that the fulfillment of the general
aims of this part of the course demands that all the material in this
book be taught in class. On the contrary I wanted to leave the in¬
structor considerable latitude in the selection of topics for discus¬
sion. To aid the instructor in the planning of his course I discuss the
specific aims of the various chapters in the teaching notes following
this preface, and 1 try to outline what might be regarded as a min¬
imum program. I feel there is no harm in having more material
available for reading than is actually taught in class, as there will
always be some students who will want to read beyond the lectures.
Eyvind H. Wichmann
October, 1967
Berkeley, California
Acknowledgments
I am greatly indebted to the other members of the Berkeley Physics

Course Committee for their continual help and encouragement
during the past few years* I wish to thank in particular Professors
C. Kittel, A. M, Portis and A* C* Helmholz for their many sugges¬
tions for improvements and for their constructive criticism*
Very many of my colleagues in the Department of Physics at
Berkeley have helped me at one time or another, and I here want to
express my gratitude to all of them* I am particularly grateful to
Professors S* P* Davis, W* B* Fretter, W. D* Knight, L. B. Loeb,
J. H. Reynolds, A. H, Rosenfeld, E* G. Segr&, and C* H* Townes,
and to Dr. W, Hines for providing me with photographs, and for
their comments on my manuscript
This book has been developed from earlier drafts used in teaching
this part of the course in Berkeley and elsewhere* The earliest ver¬
sion was used by myself when I taught a small group of students in
Berkeley during the spring term of 1964. I wish to thank these
students for their interest and for the very many helpful comments
and suggestions which they made* Later drafts have been subse¬
quently used as texts in the same course by Professors K* Dransfeld,
F. S* Crawford, L* T* Kerth, and A. C* Helmholz* I thank these
colleagues of mine for sharing with me their experiences in teaching
this course*
My manuscripts have been typed by Mrs. Lila Lowell, and I wish
to thank her for her infinite patience and her careful work. The
manuscript has been critically read and checked for errors by Dr*
J* D* Finley and Dr. L. J. Landau, and I am greatly indebted to
them for their many useful comments* I also wish to thank Dr.
J* Crichton, who similarly read the manuscript for the preliminary
edition.
I am indebted to my wife, Marianne Wichmann, for illuminating
my serious discussion of some topics with a few drawings of a not
entirely serious character. All the other drawings were prepared
in their final form by Mr* Felix Cooper, and it is a pleasure to thank
him for his careful work*
IX
Notes for Teaching and Study
The material is presented in nine chapters. Each chapter is divided
into many short, consecutively numbered sections, each corre¬
sponding roughly to one idea or one step in the train of thought
Equations, figures, and tables within the text are numbered by the
numbers of the sections within which they occur or to which they
refer. Specific references to particular topics in the text are given
in footnotes. General references are given at the end of the chap¬
ters. Tables of physical data are given in the Appendix, as well as
on the insides of the covers of the book.’ Problems for individual
study are given at the end of the chapters. The serious student
should do a very substantial fraction of these problems.
My references are to original papers, other textbooks, and ele¬
mentary review articles of the kind which can be found in Scientific
American, To my student-reader I want to say the following. You
will get a distorted picture of physics if you confine your reading to
textbooks alone, A textbook provides a framework for orderly and
systematic studies, but it cannot possibly mirror the richness and
variety of the intellectual effort in physics. This book, for instance,
is very deficient in its description of experimental procedures. To
encourage you to begin to become acquainted with the literature,
I have included references to papers which report on original re¬
search. I certainly do not expect you to read more than a small
fraction of these papers, but when you encounter a subject which
you find particularly interesting I urge you to go to the library to
look up the original sources. You will probably find other papers
which also interest you, and soon you will become a habitual reader.
Do not try to read papers for which you clearly do not possess the
necessary background. There are many papers, especially on ex¬
periments, which you can read with your present preparation, and
you should select among these. Your instructor can give you
further advice on where to look. The elementary review articles
0 (Note added in proof.) The completed manuscript was submitted to the publisher
at the end of 1967, and the book accordingly does not contain references to more recent
work. It may be stated, however, that nothing has happened in the meantime which
would significantly affect the contents of this book.
xi
xii Notes for Teaching and Study
in the Scientific American, which require very little preparation for

reading, also can be very useful at this stage. There you can learn
about current experiments and current topics of interest*
The question of units is not an issue in this book. The instructor
can use the cgp system or the MKS system according to his pref¬
erence. (The only place where it makes any difference is in the ex¬
pression for the fine-structure constant*) Constants are presented
in both systems of units. Experimental results are presented in the
practical system. In the theoretical discussion I frequently write
the equations in a dimensionless form in which the macroscopic
units do not appear at all.
I wish to comment next on the contents of each chapter, to ex¬
plain my intentions, and to indicate how cuts can be made. Some
of the material is specifically identified in the text as “Advanced
Topics*” These topics are not necessarily more advanced than the
other topics discussed, nor are they necessarily more difficult. They
represent, however, a digression from the main line of presentation,
and they can therefore safely be omitted without making the rest
of the book incomprehensible.
Chapter I is a general introduction. The scope of quantum
physics is discussed, and some aspects of the history of quantum
physics are commented upon. The most important message is,
perhaps, that quantum physics is relevant for all of physics, and not
merely concerned with “microscopic” phenomena. In a minimum
program most of Chapter 1 might well be left as a reading assign¬
ment, and the instructor might restrict his lecture discussion to the
material contained in Sections 27-52, which are concerned with the
entry of Planck's constant into the world of physics. The problems
at the end of the chapter require no particular preparation and all
can be assigned within the minimum program*
Chapter 2 is concerned with magnitudes of physical quantities in
microphysics. The aim is to familiarize the student with these mag¬
nitudes, to discover “natural" combinations of physical constants,
and to show the student how one makes simple estimates based on
simple models. I regard these aims as very important, and the
chapter, with the exercises at the end, is worth careful attention*
In a minimum program Sections 47-57 can be omitted.
Chapter 3 is concerned with energy levels, but not with the theo¬
retical explanation of the occurrence of levels. This explanation
comes later, in Chapter 8. The reason for this somewhat peculiar
order of presentation is that I wanted to place all topics requiring
some knowledge of differential equations as late as possible in the
book. Depending on the students' preparation this order might be
changed. In Chapter 3 I wanted to give realistic examples of level
Notes for Teaching and Study xiii
systems and term schemes, and to show how simple conclusions

can be drawn, based on the empirical fact that level systems occur
in nature. Part of the chapter can well be left as a reading assign¬
ment. An important point which should be fully discussed is the
connection between lifetime and level width (Sections 14-26).
Chapter 4 is concerned with the wave and particle properties of
photons. Important experimental facts are presented, and the
reader is guided to thuik quantum-mechanically about these facts.
I feel that this chapter should not be cut
Chapter 5 discusses the wave nature of all material particles.
The student who has read Chapters 4 and 5 will thus have learned
that all real particles found in nature have wave properties, and he
will have some ideas about the immediate implications of this
simple experimental fact. He will also have learned that the wave
nature of particles does not directly contradict our experience with
macroscopic physics, and why. Chapter 5 is thus to a large extent
concerned with very fundamental issues. The derivation of the
Klein-Gordon equation (Sections 36-46) should not be omitted.
The discussion of the interpretation of the solutions of a wave equa¬
tion as corresponding to vectors in a vector space (Sections 47-54)
might be left as a reading assignment, or perhaps omitted entirely.
The discussion of diffraction of waves by a periodic structure (Sec¬
tions 16-22) might also be omitted in a minimum program, although
it is a shame to omit a theory which has so many beautiful and clear-
cut experimental applications.
In the first part of Chapter 6 the uncertainty relations are dis¬
cussed (Sections 1-19). This material is of crucial importance and
should not be cut. In the remainder of Chapter 6 an attempt is
made to formulate and discuss some general rules of quantum-
mechanical thinking. A theory of measurements is presented, and
the notion of a statistical ensemble and of coherent and incoherent
superpositions are discussed I have tried to keep this discussion as
physical and concrete as possible. It cannot be denied, however,
that the discussion in this chapter goes much further than has been
customary in introductory books, and many readers might feel that
this material could wait until later. On the other hand I feel that
some of the main ideas of this chapter are not particularly difficult
if presented in an orderly fashion, and that it is worthwhile to try to
present these ideas early.
An introduction to the Schrodinger theory is presented in Chap¬
ters 7 and 8. My purpose was to show in some detail how a wave-
mechanical theory works out in practice. Sections 49-51 of
Chapter 7 and Sections 49-58 of Chapter 8 can be omitted in a
minimum program. The discussion of barrier penetration in alpha*
xiv Notes for Teaching and Study
decay (Sections 37-48, Chapter 7) should probably not. be omitted,

as the comparison between theory and experiment is bound to have
a strong impact. *.
Chapter 9 is concerned with the problem of how fo describe
interactions between elementary particles. Sections 1-18 contain
an elementary discussion of collision processes. Some known facts
and some theoretical ideas about particles are discussed in Sections
19-31. This discussion is followed by a qualitative discussion of
some basic ideas of quantum field theory. The tangible result of
this discussion is the simplified derivation of the Yukawa potential
in Sections 47-55. In a minimum program Chapter 9 might be
omitted as a whole, but I do feel that some remarks about the inter¬
action problem ought to be made somewhere in the course. Irre¬
spective of whether the material in Chapter 9 is taught or not, I felt
that it should be readily available to the interested student. The
issues are, after all, at the center of attention in present-day physics.
The problems at the end of each chapter are intended to further
illustrate the topics under discussion. They vary considerably in
degree of difficulty. There are comparatively few problems of the
land which merely involve the substitution of numerical values into
a formula which occurs somewhere in the book. A certain number
of such problems do serve a useful purpose in giving the reader a
feeling for relevant orders of magnitude. In my selection I wanted,
however, to emphasize problems which really test the reader’s
understanding of the text, and I did not want to submerge these
in a mass of very trivial problems. I have furthermore assumed that
every instructor will want to make up a certain number of his own
problems, appropriate for his particular course, and if the need
arises some of these can well be of the simple substitution variety.
If an instructor omits certain portions of the text, he will naturally
omit the corresponding problems and perhaps replace these by
others.
Besides these definite suggestions about what might be omitted,
an instructor has the option of further omitting an occasional section
here and there, and of shortening and simplifying the discussion,
without thereby upsetting the aims of this book. In a minimum
program the lectures might thus cover as little as from one-half to
two-thirds of the material in the book. I estimate that this might
correspond to about twenty hours of lectures, and this is thus the
minimum amount of time which should be devoted to the Quantum
Physics part of the course.
Contents Preface to the Berkeley Physics Course v
Preface to Volume IV vii
Acknowledgments ix
Notes for Teaching and Study xi
Chapter 1 Introduction 1
1-7 The Scope of Quantum Physics 2

8-19 Atoms and Elementary Particles 5
20-20 The Limits of Applicability of Classical Theory 14
27-40 The Discovery of Planck's Constant 18
41-46 The Photoelectric Effect 28
47-55 The Problem of the Stability and Size of Atoms 32
References for Further Study 38
Problems 39
Chap ter 2 Magnitudes ofPhysical Quantities in Quantum Physics 43
1-10 Units and Physical Constants 44

11-18 Energy 49
19-32 Magnitudes Characteristic of Atomic and Molecular Physics 56
33-39 The Most Basic Facts of Nuclear Physics 66
40-43 Gravitational and Electromagnetic Forces 73
44-46 Concerning Numerical Work 75
47-57 Advanced Topic: The Fundamental Constants of Nature 78
Problems 85
Chapter 3 Energy Levels 93
1-13 Term Schemes 94

14-26 The Finite Widths of Energy Levels 104
27-42 Further Discussion of Levels and Term Schemes 111
43-46 Doppler Broadening and Collision Broadening of Spectral Lines 127
47-56 Advanced Topic: On the Theory of Electromagnetic Transitions 130
Problems 137
XV
xvi Contents
Chapter 4 Photons 141

1-17 The Photon as a Particle 142
18-30 The Compton Effect: Bremsstrahlung; Pair Creation and Annihilation 152
31-50 Can Photons Be “Split”? 162
Problems 175
Chapter 5 Material Particles 179
1-15 The de Broglie Waves 180

16-22 Theory of Diffraction in a Periodic Structure 191
23-27 There Is But One Planck’s Constant 196
28-35 Can Matter Waves Be Split? 200
36-46 The Wave Equation and the Superposition Principle 205
47_54 Advanced Topic: The Vector Space of Physical States 211
Problems 217
Chapter 6 The Uncertainty Principle and the Theory of Measurements 221
1-19 Heisenberg's Uncertainty Relations 222

20-40 Measurements and Statistical Ensembles 234
41-49 Amplitudes and Intensities 249
50-56 Can the Outcome of Every Measurement Be Predictable in Principle? 2
57-61 Polarized and Unpolarized Light 259
Problems 262
Chapter 7 The Wave Mechanics of Schrodinger 267

1-18 Schrodinger’s Non-Relativistic Wave Equation 268
19-36 Some Simple “Barrier Problems” 279
37-48 Theory of Alpha-Radioactivity 292
49-51 Advanced Topic: Normalization of the Wave Function 304
Problems 307
Chapter 8 Theory of Stationary States 311

1-26 Quantization as an Eigenvalue Problem 312
27-41 The Harmonic Oscillator. Vibrational and
Rotational Excitations of Molecules 328
Contents xvit
42-48 Hydrogen-like Systems 339

49-58 Advanced Topic: The Position and
Momentum Variables in the Schrtidinger Theory 344
Problems 350
Chapter 9 The Elementary Particles and their Interactions 357
1-18 Collision Processes and the Wave Picture 358

19-31 What Is Meant by a Particle? 372
32-46 Basic Ideas of Quantum Field Theory 382
47-55 Pions and Nuclear Forces 393
56 Concluding Remarks 400
Problems 401
Appendix 405
A General Physical Constants 406
B The Most Stable Elementary Particles 408
C The Chemical Elements 410
Index 413
Chapter 1
Introduction
Sections I to 7 The Scope of Quantum Physics 2
s to 19 Atoms and Elementary Particles 5
20 to 26 The Limits of Applicability of Classical Theory 14
27 to 40 The Discovery of Planck's Constant 18
41 to 46 The Photoelectric Effect 28
47 to 55 The Problem of the Stability and Size of Atoms 32
Problems 39
Chapter 1 Introduction
The Scope of Quantum Physics
1 In this part of our course we shall study physics in the realm

of atoms, nuclei and elementary particles. In so doing we will
encounter new aspects of nature: new in the sense that we have not
discussed them systematically in the preceding volumes. These
aspects of nature are commonly referred to as quantum phenomena,
and we therefore call the subject matter of this volume quantum
physics. The currently accepted basic mathematical theory of
quantum physics is known as quantum mechanics.
Now it should not be thought that "quantum physics” is some¬
thing which does not concern the macroscopic world. Actually all
of physics is quantum physics; the laws of quantum physics as we
know them today are our most general laws of nature.
2 In the preceding volumes of the Berkeley Physics Course we

have studied physical phenomena in the macroscopic world. The
laws of nature which we have discovered are the laws of classical
physics. Generally we can say that classical physics is concerned
with those aspects of nature for which the question of the ultimate
constitution of matter is not of immediate concern. In this volume,
on the other hand, we will specifically study the elementary par¬
ticles, and we must now try to discover the laws which govern the
behavior of these particles. We will naturally focus our atten¬
tion on physical situations in which these !awrs stand out as clearly
as possible, and this means that we study situations involving the
interactions of only a few particles at a time. Most of the physics
studied in this volume could, therefore, be called microphysics: we
study "small” systems consisting of a small number of elementary
particles.
An example of a quantum-mechanical system. The
However, if we know' the basic laws governing the elementary
behavior of this electric motor (and the flashlight bat¬ particles wê can also, in principle, predict the behavior of macro¬
tery used as a power supply) is governed by the laws of scopic physical systems, consisting of a very large number of ele¬
quantum mechanics, although the author never sus¬ mentary particles. This means that the laws of classical physics
pected this when the motor was given to him about
follow' from the law's of microphysics, and in this sense quantum
thirty years ago.
The design of an electric motor can, and should, be mechanics is just as relevant in the macroscopic world as in the
based on classical electromagnetic theory and classi¬ microscopic world.
cal mechanics, which are limiting forms of quantum
mechanics. No engineer in his right mind would at¬
3 When wfe apply the laws of classical physics to macroscopic
tempt to describe a macroscopic system such as this
one in terms of the interactions between all the ele¬ systems we try to describe only certain gross features of the behavior
mentary particles which make up the system. of the system. We consider, for instance, the motion of a "rigid
Sec. 1A Introduction 3
body” as a whole, but we do not try to discuss the motions of all the
elementary constituents of the body. This is a characteristic
feature of classical theories of physics as applied to macroscopic
systems; the finer details of the behavior of the system are ignored
and no attempt is made to consider all aspects of the situation.
In this sense the laws of classical physics are approximate laws of
nature. We should regard them as limiting forms of the more basic
and comprehensive laws of quantum physics.
The classical theories are, in other words, phenomenological
theories. A phenomenological theory attempts to describe and
summarize experimental facts within some limited domain of
physics. It is not intended to describe everything in physics, but
if it is a good phenomenological theory it does describe everything
within the limited domain very accurately. The philosophically
minded reader may want to remark that ultimately every physical
theory is “phenomenological,” and that the difference between a
basic theory and a phenomenological theory is only a question of
degree. As physicists we recognize, however, a clear difference
between the two kinds of theories. Our basic laws of nature are
distinguished by their great generality; we are not aware of any
exceptions to what they state. We regard them as true and exact
and universally valid until there is clear experimental evidence to
the contrary. In contrast to this, the laws contained in a phenom¬
enological theory are recognized not to be of universal validity;
we know that they are valid (i.e., sufficiently accurate) only in some
Albert Einstein. Born 1879 in Ulm, Germany; died
limited domain of physics, and that outside this domain the 1955. Studied at the Institute of Technology (ETH)
phenomenological theory may be completely meaningless. in Zurich. Switzerland. After receiving his diploma in
1900 he held a position as a patent examiner in the
Swiss Patent Office in Bern. During this time he wrote
4 We should, of course, not be contemptuous of phenomeno¬
three famous papers, all of which appeared in the
logical theories. They serve the very useful purpose of summa¬ 1905 issue of Annaien der Physik, dealing with the
rizing our practical knowledge of the various domains of physics. photo electric effect. Brownian motion, and special
There are many instances in physics in which we do believe that relativity. Subsequently he held positions in Bern,
Zurich, and Prague, and as director of the Kaiser Wil¬
we have available a basic theory, but where the complexity of the
helm Institute in Berlin. In 1933 he became a mem¬
phenomena prevents us from making accurate predictions based ber of the Institute for Advanced Study in Princeton,
on “first principles.” In such a case wre try a simplified phenomeno¬ INIJ., settling permanently in the United States. He
logical theory which is partly based directly on the experimental received the Nobel prize in 1921.
Einstein is generally regarded as the most outstand¬
facts, and partly based on some general features of the basic theory.
ing physicist of this century, and as among the greatest
We let, in other words, “the physical systems do some of our theo¬ scientists of all time. He possessed to an extraordi¬
retical work.” There are, furthermore, many instances in physics nary degree the ability to grasp the essence of physical
where the basic theory is missing. Any phenomenological theory phenomena, and no short summary could do jus¬
tice to his numerous, always profound contribu¬
which we can construct (based on some simple model) is then useful
tions on the fundamental problems of physics. His
as a steppingstone in the search for a more comprehensive theory. theory of General Relativity stands out as one of the
When we try to understand an unfamiliar physical phenomenon most remarkable intellectual creations of all time.
it is clearly rational to try the simplest thing first, i,e., to try a theory, (Photograph by courtesy of Physics Today.)
4 Introduction Sec. 1.5
or model, which has worked successfully in a seemingly analogous

situation. If our model turns out to be successful we have learned
something, but if it turns out to be unsuccessful we have also
learned something.
The important thing to keep in mind is that models are only
models and that all of physics need not be described in terms of
a single model.
5 People often talk about the “revolution” in physics brought

about through the discovery of quantum mechanics. “Revolution”
is a dramatic word (with a strange appeal, it seems) which sug¬
gests that something has been completely overturned, It should
be noted, however, that the laws of classical physics, as applied to
those situations which the classical theory was designed to describe,
have not been overturned. The motion of a pendulum, for exam¬
ple, is described today in the same way as it was described in the
nineteenth century.
It is furthermore the case that classical concepts often can be
successfully employed to gain some understanding of phenomena
in microphysics: they are of approximate validity. It is important
that we understand the limits of applicability of classical ideas, and
in this chapter we will try to give the reader a rough idea of these
limits. As we learn more about quantum phenomena in later
chapters, the reader will reach a more precise understanding of this
important question.
That the classical theories of physics are not of universal validity
has been convincingly established through many experiments per¬
formed during this century. In this volume we shall present some
of the relevant experimental evidence to convince the reader of
this fact of life.
6 When we think about the changes that have taken place in

physics during this century we should keep in mind that no com¬
prehensive classical theory of matter ever existed. The laws of
classical physics are good phenomenological laws, but they do not
tell us everything about macroscropic bodies. In terms of these
laws we can describe the behavior (motion) of a mechanism con¬
sisting of springs, levers, flywheels, etc., if we are given some “ma¬
terial constants,” such as the density, modulus of elasticity, etc., of
the materials of which the mechanism is built. However, if we
ask why the densities are what they are, why the elastic constants
have the values they have, why a rod will break if the tension in
the rod exceeds a certain limit, and so on, then classical physics
Sec* 1.7 Introduction 5
is silent* Classical physics does not tell us why copper melts at

1083PC, why sodium vapor emits yellow light* why hydrogen has
the chemical properties it has* why the sun shines, why the uranium
nucleus disintegrates spontaneously, why silver conducts electricity,
why sulfur is an insulator, nor why permanent magnets can be
made of steel- We could go on and on listing everyday observa¬
tional facts about which classical physics has very little or nothing
to tell us.
7 The reader wants to know, do we now have a comprehensive

theory of matter? The answer is no; we do not have a detailed
theory for everything taking place in our world. However, our
knowledge about nature has expanded enormously during the last
sixty years. We have discovered aspects of nature never before
dreamed of, and we have succeeded in solving many old problems*
It is, for instance, fair to say that we now understand the facts of
chemistry and the properties of matter in bulk quite well: in these
domains of physics we can answer the questions that could not be
discussed within classical theory*
Atoms and Elementary Particles
8 Let us talk about the idea of elementary particles* Some ancient

Greek philosophers are credited with being the first to introduce
the concept of atoms into the theory of matter. (This does not
exclude the possibility that other people might have speculated
along similar lines long before*) It should be stated immediately
that the "atoms" of the ancients are most certainly not the same
things as the atoms of today* It is in fact not an easy matter to
understand precisely what the Greek philosophers really meant by It might well have occurred to some early natural phi¬
the term, but the central problem with which they were concerned losopher that the strikingly regular and beautiful
shapes of crystals reflect the way in which they are
was the question of whether matter is, or is not, infinitely divisible* built from small particles, or atoms. Today this seems
If matter is not infinitely divisible, then we must discover, on a a very natural idea. It would appearr however, that this
sufficiently small scale, elementary constituents of matter, or idea did not occur early. So far as the author knows
“atoms.” We take a chunk of matter, and we divide it again and there is no indication in the historical record that the
Greek atomists speculated about crystals in this
again into smaller and smaller pieces. Eventually this splitting manner.
comes to an end; we find something which cannot be split further, Crystallography as a science began to develop at the
and that is the “atom” (the word actually means “indivisible”). end of the eighteenth century. Among early workers
The Greek atomists believed that all matter is indeed built of we can mention Rome de Lisle and Haiiy, who made
precise measurements of the angles between cleavage
“atoms,” and presumably they felt that all the extremely varied planes. Before them both Robert Hooke and Christian
aspects of matter are somehow explainable in terms of different Huygens had speculated about how crystals might be
configurations (and motions?) of “atoms,” We believe something built of small {invisible) parts.
vaguely similar today, but there is certainly an enormous difference

between our quantitative theories and the nebulous speculations
of the ancients,
9 We are not going to discuss the early history of the atomic

theory of matter in this book, but the reader is urged to ponder
the remarkable understanding of natural phenomena which was
achieved during the nineteenth century on the hypothesis that
matter is made of atoms. On this assumption we can understand
the basic fact of chemistry, namely that a given chemical com¬
pound always consists of certain basic chemical elements in fixed,
definite proportions, characteristic of the compound. Consider, in
particular, the striking fact that we can represent chemical com¬
pounds by such simple formulas as H2O, H2SO4, Na2SC>4, and
NaOH. What is striking about these formulas is the occurrence
of small integers which tell us that two units of hydrogen combine
Hydrogen chloride
molecule with one unit of oxygen to form one unit of water, and so on. If
we assume that matter is made of atoms we can immediately under¬
stand these empirical facts: Chemical compounds consist of mole¬
Hydrogen cules, which in turn are composite systems of a small number of
molecule atoms. Two hydrogen atoms combine with one oxygen atom to
form one water molecule. Clear and simple.
As further evidence in favor of the atomic hypothesis we point
to the successes of the kinetic theory of gases, developed in par¬
Chlorine
molecule ticular by J. C Maxwell and L, Boltzmann, This theory could
explain many properties of gases on the hypothesis that a gas in a
container is a swarm of molecules moving randomly inside the
container, incessantly colliding with each other and with the walls
Hydrogen chloride
of the container. The kinetic theory could furthermore be used
molecule
to estimate Avogadro s number, A7o = 6,02 X 1023, which is the
Fig, 9A A very schematic representation of the number of molecules in a mole of any gas. (By a mole of any chem¬
chemical reaction H2 + Cl2 -* 2HCI, in which a hydro^ ical compound is understood a quantity of the substance which has
gen molecule reacts with a chlorine molecule to form
a mass in grams equal to the molecular weight of the compound.)
two molecules of hydrogen chloride. The figure sym¬
bolizes the idea that a chemical reaction consists in The first crude estimate of No was given by Loschmidt in 1865,
the redistribution of the 'elementary" constituents. In view of such evidence for the existence of atoms it is hard
The details of the processes which actually take to understand a certain school of thought* which persisted until
place when hydrogen gas burns in an atmosphere of the turn of the century, and which rejected the atomic hypothesis
chlorine are very complex. Energy, in the form of light
and of kinetic energy of the reaction products, is liber¬ on the grounds there was no direct (I) evidence that matter is made
ated in the process. The resulting heating of the gases of atoms.
leads to a partial dissociation of the hydrogen and
chlorine molecules into atoms, which can then coni'
10 The * "atoms” of the Greek philosophers do not correspond to
bine into hydrogen chloride molecules. Other proo
essesr in which the atoms and molecules are excited our atoms of today, because our atoms are not indivisible: they are
internally through collisions or by light, also play an made of protons, neutrons and electrons. It is rather the protons,
important role. neutrons* electrons* and a host of other elementary particles which
Sec. 1.11 Introduction 7
play the role of the Greek “atoms.” What do we mean by an

“elementary particle”? The precise definition of this term is some¬
what controversial today, but for our purposes we can give a simple
and practical answer to the question: A particle is to be regarded
as elementary if it cannot be described as a composite system of
other more elementary entities. An elementary particle has no
“parts,” it is not “built” of anything simpler. Our mental splitting
attempts have come to an end. With this definition, the proton,
the neutron and the electron are all elementary, but the hydrogen
atom or the uranium nucleus is not.
We can say that the essence of the idea that matter is not in¬
finitely divisible is this: We cannot go on forever analyzing
things in terms of the parts of which the things are built. Finally
this process loses its meaning- we encounter irreducible entities,
and these are our elementary particles.
11 How can we assert that the electron is really elementary?

Might not what is regarded as elementary today be found to be
composite tomorrow? After alt, the atoms of today were the ele¬ 8 protons
mentary particles of the nineteenth century: could not history 9 neutrons
repeat itself?
There are many experimental facts which strongly suggest that
history will not repeat itself, and that particles such as the electron,
the proton or the neutron will never be found to be composite in
the same sense as the hydrogen atom was found to be composite. CL particle
Let us try to describe the nature of this evidence. 2 protons 7 protons
If two marbles collide with a sufficiently high relative velocity 2 neutrons 7 neutrons
they will break into smaller fragments. In the same way two hydro¬
gen molecules colliding with a high relative velocity will break into
Proton
fragments. Unless the velocity is very high we will find among the
fragments such things as hydrogen atoms, or protons, or electrons; Fig. UA Schematic representation of a nuclear re¬
in other words, the components of which hydrogen molecules are action. in which an alpha particle (helium nucleus)
collides with a nitrogen nucleus to produce an oxygen
built. In both these cases it is fair to describe what has happened
nucleus and a proton. This particular reaction, dis¬
as follows: the violence of the collision overcame the cohesive forces covered by Rutherford in 1919, was the first observa-
which keep the parts together in a marble, or in a hydrogen mole¬ tion of the transmutation of stable nuclei. [E, Ruther¬
cule, and the objects therefore broke apart. A similar interpreta¬ ford, Ph/Josopbjcaf Magazine 37, 581 (1919).] In
tion can be given to many nuclear reactions. Nuclei are made of Rutherford's experiment nitrogen was bombarded by
alpha-particles from a radioactive source, and the
protons and neutrons, and if an energetic proton collides with a
occurrence of the reaction was established through
nucleus it may happen that a few protons and neutrons are knocked observation of the emitted protons.
out of the nucleus, The figure, quite analogous to Fig, 9A, symbolizes
the ideas that nuclei are made of protons and neu»
trons, and that (low-energy) nuclear reactions consist
12 However, if we study a violent collision of two elementary
in the rearrangement of these particles among nuclei.
particles, such as two protons, we discover phenomena which are It should, of course, not be taken literally: in no sense
qualitatively different from the phenomena considered above. For of the word do nuclei "lock” like this.
8 Introduction Sec* L13
IT O instance, if a proton of very high energy collides with another pro¬

Pions
ton it may happen that the two protons remain after the collision
1T+o \ and that we find in addition one, or several, new elementary par¬
ticles such as pi mesons, among the reaction products. We say
Proton that the pi mesons, also called pions, are created in the reaction*
Proton
- •
Proton
This is not the only thing which can happen in a proton-proton
collision: the protons may disappear and a number of entirely new
particles, known as K-mesons and hyperons, may appear instead*
Similarly it can happen, in a violent collision of two electrons,
1 that the final reaction products consist of three electrons and one
positron* (The positron is an elementary particle similar to the
electron, except that it carries the opposite charge*) On the other
Proton hand, if an electron and a positron collide with each other it can
happen that these two particles disappear (we say that they are
Fig, 12A Schematic representation of the creation
annihilated) and we are left with only electromagnetic radiation
of two pi mesons in a high-energy collision of two
protons. One pion carries the charge +e, and the in the form of gamma rays.
other the charge — e, where e is the magnitude of the
electronic charge. The total charge is thus conserved 13 An interesting example of a creation process is the creation
in this event.
of an electron-positron pair when a gamma ray passes through the
Since the two protons remain after the collision and
two new particles appear it is strikingly obvious that electric field in an atom* Material particles can thus be created
naive models of the kind shown in Figs. 9A and UA from electromagnetic radiation* Figure 13A, which is a doud-
cannot apply here: the event cannot be thought of as chamber photograph of so-called cascade showers, “shows” many
a “rearrangement of the elementary constituents (?)
instances of this phenomenon. The explanation (see also Figs*
of the two protons."
13B and C) for what is seen is as follows. If an energetic charged
particle, say an electron or a positron, passes through one of the
horizontal lead plates seen in the photograph it may be very slightly
deflected in the field of one of the atoms in the plate* Such a de¬
flection constitutes accelerated motion, and consequently electro¬
magnetic radiation in the form of an energetic gamma ray is
emitted* (The particle may, of course, be deflected by several
atoms in a single plate, in which case several gamma quanta will
be emitted*) The gamma rays arising in this manner then create
electron-positron pairs in the fields of the atoms which they en¬
counter when they traverse the plates* These charged particles
in turn give rise to more gamma rays as they are deflected in the
plates, and the new gamma rays give rise to new pairs, and so on*
A single energetic charged particle, or a single gamma ray, can thus
give rise to a cascade of gamma rays, electrons and positrons* The
charged particles leave visible tracks in the cloud chamber; these
are the tracks we see in Fig, 13A* The gamma rays are not visible
in the figure*
The cascade shower in the right part of the photograph appears
to have been initiated by a gamma ray, incident from above. The
energy of this gamma ray was probably about 20 BeV* The shower
Fig. 13A Cloud chamber photograph showing cascade showers. Most of the visible tracks are due to electrons and positrons,
which generally move toward bottom of picture. The particle entering at the top right and penetrating three plates before
stopping in the fourth may be a pion. See text for further comments. (Courtesy of Professor W. B, Fretter, Berkeley.)
at the left appears to have been initiated by a charged particle, of

somewhat lower energy. Both showers probably originated from
some event which took place in the wall of the chamber, outside the
field of view. Most of the particles seen in the showers moved in
the downward direction. It is a characteristic feature of these
processes that the most energetic particles tend to be emitted in
the direction of the incident particle, whereas less energetic par¬
ticles can be emitted in other directions. If we look closely at the
photograph we notice that the secondary showers due to particles
emitted in directions other than those of the principal showers soon
“die out” A cascade shower naturally stops when the original
energy has been distributed among so many charged particles and
photons that none of them has enough energy for the creation of
additional pairs. The low-energy particles are then absorbed by
Fig, 13B An energetic charged particle (say a
the lead plates.
positron or an electron) is deflected by the electric
field within an atom, and as a result of this accelerated The energy of the particle initiating a shower can be estimated
motion a gamma ray (i,ean energetic photon) is from the number of charged secondary particles which are pro¬
emitted. This is the physical phenomenon of brams* duced
sfrah/ung. The shaded part of the figure represents
matter in bulk, say a portion of a lead plate in a cloud
chamber. (The size of the atom i s si ightly exaggerated 14 The creation and annihilation processes which we have men¬
for clarity.) tioned are important aspects of nature. It is obvious that these
phenomena are in no way analogous either to the shattering of
marbles or to chemical reactions. We can describe a chemical
reaction by saying that new molecules are formed from the ele¬
mentary constituents of other molecules, and for the purpose of
/
such a description the atoms are the elementary constituents of
/ molecules. Consider, in contrast to this, a collision event in which
/ Photon the two particles originally present remain after the collision, along
/ with a number of new particles created in the event. Clearly we
t
f cannot describe such an event in terms of a rearrangement of the
/
elementary constituents of the original particles into new composite
systems. Nor can this description be applied to events in which
some of the original particles disappear. A striking example of the
latter phenomenon is the annihilation of an electron-positron pair,
in which the material particles originally present disappear com¬
pletely and we are left with gamma rays,
15 To decide experimentally whether a particle is elementary or

composite we try to shatter it by letting it collide with another
Fig. I3C An energetic gamma ray colliding with the particle and observe the reaction products. In this way we can
electric field inside an atom gives rise to an electron* shatter molecules into atoms, and atoms into electrons and nuclei,
positron pair: this is the physical phenomenon of
and it is fair to say that molecules are built of atoms, which in turn
pair production. The two basic processes shown in
the above two figures are responsible for the develop* are built of electrons and nuclei. The nineteenth century physi¬
ment of the cascade shower shown in Fig, 13A. cists were really mistaken when they thought that atoms are inde-
structible and indivisible: atoms can in fact be shattered readily.

In the same way nuclei can be shattered, and it is fair to say that
nuclei are built of protons and neutrons. To shatter a nucleus,
however, requires much more energy than to shatter an atom, and
in this sense nuclei are much less "destructible” than atoms.
With modern particle accelerators we can produce beams of
very energetic particles, and we thus have the means for shattering
such particles as protons if they could indeed be shattered. But
protons do not shatter like atoms and nuclei: something quite dif¬
ferent happens. We must conclude that when we study electrons,
protons, neutrons, etc., we have reached a limit: it does not appear
to be sensible and useful to regard these particles as made up of
other more elementary particles.
16 Nobody would attempt today to create a comprehensive

theory of matter based on the proposition that matter is infinitely
divisible: such an undertaking would be futile. Let us, however,
speculate a bit on what features such a theory migftf have. If we
take a chunk of copper, and divide it into smaller and smaller pieces,
we never get anything but small chunks of copper. No matter how
small the pieces are, they are still recognizable as chunks of copper.
What does this mean? It means that the physical laws governing
the behavior of small chunks of copper are the same as the laws
governing the behavior of large chunks of copper; physical systems
can be “scaled down” indefinitely. Now it must be admitted that
our theory need not necessarily have this feature, but it would be
a very natural feature of a theory describing matter which is in¬
finitely divisible. We note that in many respects our classical
theories of physics do have this feature. The laws of physics which
we use to describe some machine weighing a ton are not qualita¬
tively different from the laws we use to describe a wrist watch.
Macroscopic physical systems can be scaled over a considerable
range.
This "preservation of the form of physical laws” which might
appear natural if matter were infinitely divisible is certainly totally
implausible if matter is made of elementary particles. An atom of
copper is in no way like a macroscopic chunk of copper; it is some¬
thing entirely different. We have absolutely no a priori reasons
to believe that the laws of physics which describe macroscopic sys¬
tems sufficiently accurately would also be adequate to describe the
structure of atoms and elementary particles.
17 To admit, as a matter of abstract principle, that classical ideas

might not be appropriate to atoms, and that the electron is really
12 Introduction Sea L18
an elementary particle is one thing, but to live up to such prin¬

ciples fully in one's thinking is quite a different thing. Experience
shows that our thinking tends to be prejudiced, and that we do not
easily give up ideas which we have once absorbed. Since our first
conscious observations of physical phenomena concern macro¬
scopic systems, we acquire a set of “classical prejudices” which have
to be overcome when we wish to study quantum physics,! Let us
try to illustrate the meaning of these remarks by considering two
closely related problems which have been the objects of much
speculation in this century.
18 Let us ask the following: What are the forces which keep an
electron together? What fraction of the mass of an electron is of
an infrirtsic nature and what fraction is due to the energy of the
electrostatic field of the electron? To try to deal with these ques¬
tions we assume a not unreasonable model according to which the
electron is a small uniformly charged sphere of radius r. The dif¬
ferent parts of this sphere repel each other electrostatically, and
there must therefore be some other kind of force which keeps the
sphere together. What is the nature of this force?
In Volume II of this series \ we have learned how to compute the
total energy “residing” in an electrostatic field: we integrate
(l/8w)E2 over all space, where E is the local electric field For our
model we obtain the expression W = %(e2/r) for the electrostatic
energy,§ where e is the electronic charge. (The coefficient in front
of the expression e2/r depends on the details of the model: for a
uniformly charged sphere it happens to have the value What is
important here is not the value of this coefficient but the propor¬
tionality of W to the expression e2/r* That W depends in this way
on e and r is immediately obvious on dimensional grounds.) We
can now write the mass of the electron in the form m = me + m*,
where mP = W/c2 is the electromagnetic contribution and m*
is the “intrinsic” part. The problem is: How large is m^? Could
it perhaps be that m = mP, in which case the entire mass would be
of electromagnetic origin? If we make this assumption we can
t It is not only the beginning physics student who has such prejudices, the senior
physicist has them too. Since rigidity of mind appears to increase with age it is
plausible that the senior physicist actually suffers more from his "classical prejudices”
than the beginning student does.
| Berkeley Physics Course, Vol. II, Electricity and Magnetism* Chap. 2, p. 51.
§ This holds for the egs-system of units. In the MKS system we have
Sec. 1J9 Introduction 13
compute the radius r and we find r = 1*7 X 10^13 cm. There are
many experimental facts which suggest that the electron must be
very “small/* and it is therefore comforting that we did obtain
something small. Note that we cannot make t much smaller, unless
we wish to contemplate the possibility that mi is negative.
Since the electron is supposed to be elementary it might appear
particularly tempting to try a model with r - 0, in which case the
electron would be a “point-particle** with no extent and no struc¬
ture. This, however, would lead to an infinite electromagnetic
self-energy W* and to a negative infinite intrinsic mass mi , which
hardly makes sense. (This circumstance, which raises an in¬
surmountable obstacle in the way of the mathematically simple
and attractive model of a point-electron, is referred to in the lit¬
erature as “the difficulty of the infinite self-energy of the elec¬
tron,”)
19 Let us now think critically about the above speculations; do

they really make any sense? In asking our questions we have clearly
made many assumptions which reflect our prejudices. We have
assumed that the electron is a small charged sphere, and we have
assumed that Coulomb’s law can be applied to the “parts” of this
sphere. How do we know that Coulomb’s law applies to this situa¬
tion? And what about the idea that a force has to hold together the
“parts” of the electron against the electrostatic forces of repulsion?
We have said earlier that the electron has no “parts”; it is an ele¬
mentary particle, To ask what holds the electron together means
we contemplate the possibility that it could break into parts,
but this is a very questionable idea. Note that the electrostatic
self-energy of the particle is the work which we could obtain by
letting the “parts” of the particle disperse completely; this is how
we originally derived the result that the electrostatic energy of any
system of charges equals the integral of the square of the electric
field strength over all space. If the particle cannot be dispersed,
then the electrostatic self-energy is a doubtful concept. This is
particularly true of the nonsensical infinite self-energy of the
“point-electron.”
Most physicists have realized by now that attempting to create
some kind of classical model for the electron is meaningless. The
electron does not behave like a charged sphere, and all discussions
about what would keep it together if it were like a charged sphere
or what its classical self-energy might be, are irrelevant in physics.
Our classical prejudices led us to ask questions to which no sensible
answers can be expected.
We should mention, however, the amusing circumstance that the
14 Introduction Sec. L20
ghost of the infinite self-energy has not yet been completely

exorcised from physics; remnants of this confusion still persist in
quantum mechanics.
The Limit* of Applicability of Classical Theory
20 In the theory of special relativity the velocity of light plays a

fundamental role. This velocity, c = 3x 1010 cm/sec, is the
upper limit on the velocity of any material particle and the upper
limit on the velocity by which energy or information can be trans¬
mitted in physical space. The existence of this velocity provides us
with a simple and natural criterion in terms of which we can decide
when a physical phenomenon may be discussed “non-relativistic-
ally” and when it must be discussed “relativistically.” Roughly
speaking a non-relativistic treatment is adequate, i.e., sufficiently
accurate, whenever all relevant velocities are small compared to the
velocity of light.
We may ask whether an analogous criterion exists which tells us
when we must apply quantum mechanics and when the theory of
classical physics is adequate. Is there a constant of nature, “anal¬
ogous" to the constant c, in terms of which the desired criterion
may be formulated?
Such a constant does exist, and it is known as Planck’s constant.
It is denoted by ft, and it has the value
ft “ 6.626 X 10-27 erg sec

“ 6.626 X 10'34 joule sec
The physical dimension of this constant is thus [time] X [energy]

= [length] x [momentum] = [angular momentum]. Such a
physical quantity is known as action, and accordingly Planck's con¬
stant is also called the (fundamental) quantum of action.
The criterion is roughly the following. If for a physical system
any “natural” dynamical variable t which has the dimension of
action assumes a numerical value comparable to Planck’s constant
ft, then the behavior of the system must be described within the
framework of quantum mechanics. If, on the other hand, every
variable having the dimension of action is very large when measured
against ft, then the laws of classical physics are valid to sufficient
accuracy.
t A dynamical variable is any variable which characterizes the state of the system;
for example, a position coordinate, a component of momentum, a component of
angular momentum, a component of velocity, the total energy, etc.
Sec, 1,21 Introduction 15
We emphasize that this is a rough criterion which merely tells us

when we have to be careful. The fact that an action variable is
small in any particular case does not necessarily mean that classical
theory is totally inapplicable. In many cases classical theory will
give us at least some insight into the behavior of the system, especial¬
ly if tempered by some quantum-mechanical notions.
21 We note immediately that Planck’s constant is “small,” which

means that h is numerically small when measured in units which
are appropriate for a description of macroscopic phenomena, i.e.,
MKS or cgs units. Differently stated, a quantity of action in the
macroscopic world is enormous when measured in units of ft.
We may, for instance, think about a pendulum in a pendulum
clock. To find a quantity which has the dimension of action we
form the product of the period of the pendulum with its total energy
when it is swinging. The period is of the order of a second, and
the energy is certainly much larger than an erg, which means that
the product of these two quantities is much larger than 1026 times h.
According to our criterion a classical description of the swinging
pendulum should be, and indeed is, completely adequate.
Consider similarly a rotating body. Let the moment of inertia
be 1 gm cm2, and let the angular velocity be 1 rad/sec. The
angular momentum is then 1 gm cm2/sec = 1 erg sec >1026ft,
and the angular momentum is thus enormous compared with ft, Max Karl Ernst Ludwig Planck. Born 1858 in Kiel,
Even if the body were just a small grain of sand with a rotational Germany; died 1947. After studies in Munich and
period of an hour, its angular momentum would still be extremely Berlin, Planck obtained his doctoral degree in 1879.
His thesis dealt with the second law of thermody¬
large when measured in units of ft. namics. After holding a position at the University of
Consider finally a small, but macroscopic, harmonic oscillator. Kiel, Planck was appointed professor of Theoretical
Let the mass be 1 gm, the maximum velocity be 1 cm/sec, and the Physics at the University of Berlin in 1899. He retired
maximum amplitude be x = 1 cm. The maximum momentum is at the age of seventy in 1928. He received the Nobel
prize in 1919.
then p = 1 gm cm sec^1. The quantity xp = 1 erg sec is an action
In the beginning of his career Planck devoted him¬
variable which is again > 1026 ft. self to the study of thermodynamics: a subject in
This discussion illustrates how our test, when applied to such which he remained interested throughout his life.
macroscopic systems, will always tell us what we already knew, In Berlin he became acquainted with the experimental
namely that the systems can be described classically. work on thermal radiation carried out by Lummer,
Pringsheim, Rubens and Kurlbaum, and he set him¬
self the task of deriving a theoretical black-body-
22 Let us now try to obtain a deeper understanding of what our radiation law. His successful effort marks the begin¬
criterion really means. ning of quantum physics, and what is now called
In classical physics we assume that every dynamical variable of Planck’s constant first appeared in his paper of 1900.
After this monumental discovery Planck continued to
a system can be specified and measured to arbitrary precision. This play an active role in the development of quantum
does not mean that we can do it in actual practice; it rather means physics. (Photograph by courtesy of Physics Today.)
that we do not admit that there is any limit to the precision in
principle* The set of dynamical variables in classical physics in¬
cludes such variables as position coordinates, components of
momenta, components of angular momenta, etc., for a system of

particles or a single particle, as well as such variables as the com¬
ponents of the electric and magnetic field vectors at a given point
in space at a given time.
A careful analysis of the actual behavior of microphysical systems
shows, however, that there is a fundamental limit to the accuracy
to which variables of this kind can be specified and measured. The
very penetrating and beautiful analysis by which this limit was
established was carried out by W. Heisenberg in 1927. We refer
to the existence of such limits as the uncertainty principle; a specific
quantitative expression of this principle in any particular case is
known as an uncertainty relation.
A particular uncertainty relation concerns the pair of variables
(q, p), where q is the position coordinate of a particle and p is the
momentum of the particle. This relation reads
i,APaA
Here Aq is the root-mean-square error in q and Ap is the root-
mean-square error in p, and the inequality thus asserts that the two
variables q and p cannot be known more accurately than that the
product of the “uncertainties” of the two variables is of the order
of Planck's constant.
We note immediately that because of the smallness of Planck’s
constant, ht the uncertainty relation is of no importance in macro-
physics; other sources of errors in q and p always mask the funda¬
mental uncertainty expressed in the inequality (22a). The relation
(22a) therefore does not in any sense contradict our empirical
knowledge of macrophysics even though it does contradict our
classical theories about macroscopic systems.
23 The uncertainty principle is often "explained*' as follows.

Dynamical variables such as position, momentum, angular momen¬
tum, etc., must be defined operationally, i.e., in terms of the experi¬
mental procedures through which they are measured. If we now
analyze realistic procedures of measurement in microphysics, it
turns out that a measurement will always perturb the system; there
is a characteristic unavoidable interaction between the system and
the measuring apparatus. If we try to measure the position of a
particle very accurately, we will perturb it in such a way that its
momentum after the measurement is very uncertain. If we try to
measure its momentum very accurately we perturb it in such a way
that its position will be very uncertain. If we try to measure both
the position and the momentum of the particle simultaneously.
Sec. L24 Introduction 17
then these two measurements will necessarily interfere with each

other in such a way that the accuracy of the final result will be sub¬
ject to the inequality (22a). The discussion then proceeds to show
how these perturbations arise in particular cases.
This kind of description of the meaning of the uncertainty prin¬
ciple is very common in texts on quantum mechanics. The author
does not want to maintain that it is completely wrong, but he does
feel that it is misleading and that it can give rise to grave mis¬
understanding. It misses the essential point, which is this: The
uncertainty relations state the limits beyond which the concepts of
classical physics cannot be employed. The 'classical physical
system,” described through classical dynamical variables which are
definite functions of the time, and which can be known in principle
to arbitrary precision, is a figment of imagination; it does not exist
in the real world. Experiments have been performed which tell us
that this is so. If we describe an actual system as a “classical sys¬
tem” then we make an approximation, and the uncertainty relations
tell us how far we can go.
24 To elucidate these ideas further, let us consider the one-

dimensional motion of a particle. According to classical dynamics
we describe the instantaneous position of the particle through the
position variable q = q(t). If the mass of the particle is m and if
it moves sufficiently slowly, then its momentum p is given by
p = p(t) — m dq (t) /dt. Now we might think that the uncertainty
relation merely expresses an unfortunate property of our measuring
instruments which prevents us from determining q(0) and p(0) to
arbitrary accuracy, although we can very well think about precise
values of these variables and about the precise subsequent motion
of the particle. We might, in other words, think that we can go on
using a classical description according to which every particle
follows a definite trajectory but with the refinement that we intro¬
duce an uncertainty about which one of the trajectories the particle
follows by imposing uncertainty relations on the initial conditions
which determine the trajectories.
This is not so. Experiments tell us that we have to modify our
ideas in a much more profound manner. The motion of a classical
trajectory must be rejected; to ask for, or think about, the simul¬
taneous values of q(t) and p(t) is as meaningless as to ask for the
hair color of the King of the United States,
25 Now it may seem that our discussion is logically contradictory.

First we state an uncertainty relation, and then we declare that the
variables q and p which occur in this relation make no sense. If
they make no sense, how then can the relation make any sense?
The answer is as follows. In the quantum-mechanical description
of the behavior of a particle we can introduce certain mathematical
objects q and p which in many respects correspond to the classical
position and momentum variables. These objects, however, are
not identical with the classical variables. The relation (22a) tells us
that if we try to interpret the quantum-mechanical objects q and p
as “position* and “momentum," and thus inteipret the motion in
classical terms, then there is a fundamental limitation on the ac¬
curacy with which “position” and "momentum” can be known.
In other words, the relation tells us that if we try to introduce
classical variables, and try to interpret the motion classically, then
the precision with which these variables can be specified is limited.
26 It should be clearly understood that no analysis of the measur¬

ing process in purely classical terms could ever lead to an uncertainty
relation. The uncertainty relations reflect experimentally dis¬
covered facts about nature. The particles occurring in nature do
not behave like classical point-particles, nor do they behave like
small billiard balls: fthey behave quite differently, and that is why
certain kinds of measurements cannot be made or even imagined.
In subsequent chapters we will learn about the properties of the
particles in the real world, and we will then see how naturally the
seemingly strange uncertainty relations fit into the scheme of things.
The Discovery of Planck's Constant
27 Let us now consider the early history of Planck’s constant, and

let us see how it was discovered, and how it made its way into
physics. We shall go back in time to the beginning of this century,
and consider some of the outstanding problems in physics of that
period, namely the following:
(i) The problem of the black-body radiation law
(ii) The problem of the photoelectric effect
(iii) The problem of the stability and size of atoms
These three problems were not, of course, the only ones which
tFor some reason the billiard ball has oome to play the role of the prototype of a
classical particle in textbooks on Quantum mechanics. The author, of course, conforms
to this tradition, It may amuse the reader to know that the author has never played
billiards and has never held a billiard ball in his hand His knowledge of the alleged
properties of billiard balls is, therefore, book knowledge, derived from texts on quantum
mechanics.
occupied the physicists of the time, but we single them out because
they illustrate the dilemma of classical physics in a particularly
clear-cut way.
The reader should realize that our discussion is extremely de¬
ficient as a historical account: we could not possibly hope to do
justice to the very interesting development of quantum physics in a
few pages. We are looking at the situation at the beginning of this
century in retrospect, and it is then easy to see that these three
problems were key problems. However, if we examine the publica¬
tions for the year 1900 in Annalen der Physik (which was one of
the leading journals in physics at the time) we find that the majority
of physicists were concerned with very different things. The ability
to distinguish the truly significant from the insignificant is a rare
ability indeed (at any time), and we have every reason to admire the
remarkable insight and imagination of the early pioneers of quantum
physics.
28 To dramatize the situation we shall regard these three problems

as three different aspects of the fundamental ‘‘Mystery of the Miss¬
ing Constant.” This is certainly not the way in which a physicist
in the year 1900 would have formulated the difficulties facing him,
but it is instructive to consider the matter in retrospect from this
point of view.
The missing constant is of course Planck’s constant h. In a purely
classical theory of matter this constant would not occur. Let us
therefore consider some of the other basic constants of physics
which would play a role in a classical description.
(i) The velocity of light, c = 3.00 X 1010 cm/sec. This constant
was known with fair accuracy in the year 1900.
(ii) Avogadro s number, No = 6.02 X 1023, which is the number
of molecules in a mole of any gas. A crude value of this constant,
based on the kinetic theory of gases, was available in 1900.
(iii) The mass of the hydrogen atom, MH = 1.67 x 10~24 gm.
To an accuracy of 1 part in 2000 this is also the mass of the proton, Joseph John Thomson. Bom 1856 near Manchester,
England; died 1940. For many years Thomson (af¬
Mp, Since a mole of hydrogen has a mass which is very close to fectionately nicknamed “JJ.rr) held the position of
2 gm, we have Cavendish Professor of Physics at Cambridge Uni*
versify, and also that of Professor of Physics at the
NqMh ~ NoMp = 1 gm (28a) Royal Institution, London. His many and varied
contributions to physics included researches on the
and if we know Avogadro’s number we can thus find Mr.
conduction of electricity through gases, the charge
(iv) The elementary charge, e = 1.6 x 10~19 coul = 4.8 x and mass of the electron, and the properties of positive
10“10 esu. The charge of the electron is — e, and the charge of the rays. Thomson discovered the electron in 1897. His
proton is -f- e. The charge carried by a mole of singly charged ions work on the positive rays led to his discovery of the
isotopes of neon. He received the Nobel prize in 1906.
(Le., each ion carries the charge e) is known as Faraday’s constant
(Photograph by courtesy of Professor L. B. Loeb,
F, We thus have Berkeley.)
20 Introduction Sea 1.29
F = N& = 96,500 coul (28b)
The Faraday constant F is readily measurable in an electrolysis

experiment* F is, for instance, the quantity of charge which has
to pass through an electrolysis cell in order to deposit one gram-
equivalent of silver (i,e-, 107*88 gm of silver since the atomic weight
of silver is 107.88).
(v) The ratio of charge to mass for the electron, e/m = L76 X 108
coul/gm, and the ratio of charge to mass for the proton, e/Mp
— 9.6 x 1CH coul/gm* These constants can be determined in
deflection experiments with beams of electrons or protons in electric
and magnetic fields. In this way e/m had been determined by
J. J* Thomson in 1897. t We should note that
e F
A#p NqMp
and this constant is therefore not independent of the constants
mentioned earlier*
We should also note that given precise values of e/m and e/Mp
we can find a precise value for
Afp _ e/m
(28d)
m e/Mp
even if the charge e is not known with corresponding precision.

This assumes, of course, that the charge of the proton is equal in
magnitude to the charge of the electron.
(vi) The mass of the electron, m = 9.11 X 10-28 gm* This con¬
stant can be inferred from e and e/m.
29 Avogadro s number JVq is the link which connects microphysics

with macrophysics* The enormous size of this number tells us
how small atoms and molecules really are, and why the granular
structure of matter is not more apparent in the world of macro¬
physics* As we have said jYq was not very well known at the end
of the last century. The constants F, e/m, m/Mp were, however,
much better known, and an independent good measurement of
either Nq or e would thus lead to a better knowledge of the basic
constants e, m, and Mp. One important aspect of Planck s theory
of black-body radiation was, as we shall see, that it permitted an
Fig* 30 A The crystal structure of sodium chloride.
independent, and better, evaluation of Yq*
The Eattice is cubical, with chlorine atoms and sodium
atoms alternating at the vertices. The centers of the About a decade later R* A. Millikan, in his famous oil-drop ex¬
small spheres in the figure indicate the mean positions periment, measured e directly by observing the motion of small
of the sodium and chlorine nuclei. The size of these
spheres is rot intended to convey any information
about the sizes of either the nuclei or the atoms. tj. J. Thomson* “Cathode Rays/" Philosophical Magazine 44, 293 (1897)*
charged drops of oil floating in air under the combined influence

of gravity and an electric field, f Although this land of experiment
can hardly be expected to yield a high-precision value of e, it was
of great importance as an independent, and conceptually simple,
measurement of this constant,
30 We want to go ahead of our story and mention that Avogadro’s

number No can also be measured very directly, by counting the
number of atoms in a crystal. The atoms in the crystal are arranged
in a regular lattice, say a cubical lattice, and if we Gan determine
the spacing between neighboring atoms in the crystal, the lattice
constantf we can clearly find No, This spacing can be determined
through X-ray diffraction experiments, provided we also determine
the wavelength of the X-rays used, for instance through measure¬
ments with a mechanically ruled “macroscopic” grating. No was
eventually determined in this manner.
The clever idea that Nature provides us with ready-made dif¬ fig♦ 3QB The crystal structure of diamond. Each
fraction gratings in the form of crystals first occurred to M, von carbon atom has four nearest neighbors located at
Laue, and on his suggestion diffraction experiments with X-rays in the vertices of a tetrahedron (nearest neighbors are
crystals were carried out in 1912 by W, Friedrich and P, Knipping | joined by solid lines).
This was in fact the first conclusive experimental proof that X-rays
are indeed waves of short wavelength.
31 In order to be able to understand the issues connected with

black-body radiation we have to digress to discuss heat and tem¬
perature* § These concepts are relevant to the description of the
behavior of matter in bulk under conditions of thermal equilibrium.
This topic has nothing to do with the structure, or behavior, of
isolated atoms, molecules, or nuclei, but it is of importance in many
manifestations of quantum phenomena. The reason for this is,
of course, that we do not, in general, carry out our measurements
on isolated atoms, molecules, or nuclei; we observe these particles
“embedded" in bulk matter.
Thermal energy is energy associated with the disorganized mo¬
tion of the constituents of a macroscopic body. Heat is thermal
energy in transfer (from one body to another). What is tem¬
perature?
Fig, 30C The crystal structure of graphite. Dia¬
f R. A, Millikan, "The Isolation of an Ion, a Precision Measurement of Its Charge, mond and graphite both consist only of carbon. The
and the Correction of Stokes's Law,” The Physical Review 32, 349 (1911). marked differences in the physical properties of these
t W. Friedrich, P, Knipping, and M. Laue, "Interferenzerscheinungen bei Rontgen- two materials derive from the different forms of their
strahlen," Annalen der Phy&ik 41, 971 (1913)* crystal lattices. The graphite lattice consists of equally
$ These topics are discussed more fully in Berkeley Physics Course, Vol. V, Statis¬ spaced parallel planes in which the carbon atoms are
tical Physics. See also Physical Science Study Committee, Physics, Chaps. 9 and 26, arranged in a hexagonal pattern. Compare the lattice
2nd ed. (D, C, Heath and Company, Boston, 1965), shown above with the diamond lattice in Fig. 30B.
22 Introduction Sec, 1,32
32 It is not quite so easy to give, in a single sentence* a precise

definition of the concept of temperature. In a sense we all “know,”
what temperature is, and we know how to measure temperature
with a thermometer. A thermometer is any body, or system, for
which a change in temperature produces a readily observable
change, such as a change in length; a change in volume; a change
in electrical resistance; etc. Let us consider, as an example, a
mercury thermometer. Temperature is read by observing the level
of a column of mercury in a capillary of uniform cross section. To
establish a temperature scale we might assign the temperature 0°
to the melting point of ice, and the temperature 100c to the boiling
point of water, and then define the intervening "degrees” by divid¬
ing the interval between the two reference points on the capillary
into a hundred equal parts. In this manner we can indeed define
a measure of temperature, but our procedure has the grave defect
(from the point of view of basic physical theory) that our temper¬
ature scale depends on the special properties of an arbitrarily
selected substance, in this case mercury. If we follow the same
procedure using another substance, say alcohol, we might find that
30c on the alcohol scale is not the same thing as 30° on the mercury
scale.
For scientific purposes it is clearly desirable to have a measure
of temperature which is independent of the special properties of any
particular substance, In the next volume of this series, which is
devoted to thermal physics, we shall discuss in detail how such a
measure can be defined. The resulting scale of temperature is the
absolute scale, on which temperature is measured in degrees Kelvin,
denoted °K. On the absolute scale 0*K is the lowest possible tem¬
perature: this temperature corresponds approximately to — 273°C*
For convenience the magnitude of the Kelvin degree is so chosen
that a temperature difference has the same numerical value on the
absolute scale as on the centigrade scale, and we thus have, by
definition,
(temperature in °K) = (temperature in eC) + 273.15
33 Let us try to obtain a qualitative idea of what temperature

"means” from the standpoint of microphysics. The basic idea is as
follows. As the temperature increases the average energy asso¬
ciated with the random motions of the elementary constituents of
a macroscopic body increases. At the temperature 0GK all random
motions cease, and this is the physical significance of the lowest
possible temperature. (The emphasis is on the word “random/’)
In statistical mechanics we often idealize the properties of a real

gas in terms of a model: we assume that the gas consists of a large
number of small identical particles (molecules), moving at random,
and with negligible mutual interactions. This model provides us
with a good description of a dilute real gas. If the particles in the
(model) gas are monatomic molecules, we speak of an ideal mon¬
atomic gas. It is possible to prove that for one mole of an idea! gas,
PV = iV0£kiQ (33a)
where P is the pressure, V the volume of the container, and £kin
Fig* 33A The relation PV = JAofiyn can be easily
the average kinetic energy per (monatomic) molecule. understood. Consider a container of volume V in
The absolute temperature is so defined that, within this model, which there are \:n molecules. Let us first assume
it simply expresses the average kinetic energy by £kin = where that all the molecules move to the right, with velocity r.
the constant of proportionality k is known as Boltzmann's constant. The number of molecules colliding with a unit area of
We can therefore write (33a) in the form the wall per unit time is Each molecule
transfers an amount of momentum 2mc to the wall.
FV=Sr0kT = RT (33b) The pressure J># is equal to the total momentum trans-
fer per unit area per unit time, and hence we have
where the constant fl = \rok is the universal gas constant. It is />' = 2muB(ArV'V) = 4 ftmOVo/V).
an experimental fact that this law holds accurately for all sufficiently in reality the direction of motion is random, and the
true pressure P is related to the pressure PT computed
rare gases: i.e., for any real gas the law holds better the less dense
above by P = which leads to Eq. (33a). (We can
the gas is. We can exploit this fact to construct a gas thermometer understand the factor £ if we imagine that the mole*
calibrated to show absolute temperature, cules move in six standard directions: in both direc¬
tions along three perpendicular axes. Only one-sixth
34 The universal gas constant has the value of the molecules will then contribute to the pressure
on the right wall.)
R = N0k =s 8.3 X 107 erg (QK)-i (mol)-i
= L99 cal (°K)~1 (mol)-1 (34®)
It is a macroscopic constant which can be readily measured on
the basis of the relation (33b),
Boltzmann's constant, k = fi/A'o, is the gas constant per mole¬
cule* It can be found provided No is known, and it has the value
k = 1,38 x 10-« erg (°K)-i (34b)

It is in effect a conversion factor from temperature to energy.
That temperature and energy are related in this way should not,
however, lead anybody to believe that energy and temperature are
“the same thing,”
35 After this survey of the basic constants of classical physics

we now consider the problem of the black-body radiation law. The
empirical facts are as follows. The surface of a material body held
at a high temperature emits light of all frequencies, or wavelengths.
If we plot the amount of radiant energy emitted per unit time per
unit area per unit wavelength interval versus wavelength we obtain
a curve which goes to zero for very long, and for very short wave¬
lengths; in general the curve will have a single maximum at some
wavelength \max> which depends on the temperature* The loca¬
tion of this maximum, and the total amount of radiation emitted,
is very roughly the same for all material surfaces. Instead of study¬
ing the radiation from a material surface one may observe the radia¬
tion emerging from a small hole in the wall of a dosed material
surface kept at a fixed temperature. In this kind of measurement
we thus have an enclosure, or "oven,” made of any suitable refrac¬
tory material, with a small hole in the side (i,e,, a hole small com¬
pared with the linear dimensions of the cavity). We direct our
instruments at the hole and thereby measure the radiant energy
emerging from the interior of the enclosure. It was found in such
measurements that
(i) A graph (see Fig* 35A), of the intensity of radiation from the
hole versus wavelength is a smooth curve falling to zero for long,
0 1 2 3 4 5 6 as well as for short wavelengths, and with a maximum at a wave¬
x 10 “4 cm length Amiut which depends on the temperature T of the walls in
Wavelength a very simple manner, namely
WT = C0 = 0.2898 cm *K (35a)
Fig. 3SA Graphs showing power emitted by a black-
body radiator per unit area per unit wavelength inter¬ (ii) The spectral distribution of the emitted radiation, i*e., the
val f tor four different temperatures. The total power
shape of the curve mentioned in (i), is independent of the shape
emitted is proportional to the areas under the curves;
it is proportional to the fourth power of the absolute of the cavity, and independent of the material of which the walls
temperature. Note how the location of the maximum are made. The constant Co in equation (35a) which expresses
depends on the temperature; the precise relationship Hfens displacement law, is thus a universal constant which de¬
is expressed by WienTs law. scribes a remarkable property of cavities in general
(iii) The intensity of the radiation emerging from the hole is
always larger, at every wavelength, than the corresponding intensity
of emission from a material surface kept at the same temperature
as the walls of the cavity; the order of magnitude of the intensity,
however, is the same.
36 A surface which absorbs all radiation incident upon it is called

a black-body surface. To an outside observer a small hole in the
wall of a cavity appears more or less like a black-body surface,
especially if the interior walls of the cavity are rough and blackened*
The reason is simply that any radiation (light) incident from the
outside upon the hole will be almost completely absorbed in mul¬
tiple reflections inside the cavity, even if the interior walls are not
perfectly absorbing*
Because of these circumstances we refer to the radiation emerg¬
ing from a hole in the wall of a cavity as black-body radiation* It
was shown by G* R* Kirchhoff, from very general thermodynamic
considerations, that, for any wavelength, the ratio of the rate of

emission from an arbitrary material surface to the rate of emission
from a black-body surface equals the absorption coefficient for the
material at the wavelength in question* The black-body surface
is, therefore, a suitable standard emitter, and we shall limit our
considerations to black-body radiation- i*e., radiation from a hole
in the wall of a cavity.
37 By the end of the nineteenth century careful measurements

had been carried out on the black-body-radiation law, and in par¬ Fig* 36A To an outside observer a small hole in
ticular the relation (35a) had been established The outstanding the wall of a cavity with a (partially) absorbing interior
surface is a black-body surface: it absorbs incident
theoretical problem was to derive the radiation law from first prin¬
radiation almost completely. A ray of light entering
ciples* That the hole should emit radiation is not in itself surprising; through the hole is partly absorbed and partly dif¬
we know that the constituents of matter are charged, and the fusely reflected when it hits the interior surface. The
thermal vibrations of the constituents in the walls naturally lead reflected rays are again partly absorbed, and partly
to the emission of radiant energy into the cavity. This radiation diffusely reflected, and only a very small fraction of
the incident light will find its way out again through
may also be absorbed by the walls, and if the walls are kept at a
the hole.
fixed temperature we will have some kind of equilibrium between Differently stated: a photon entering the cavity has
the radiant energy in the cavity and the walls, i.e., the emission a very small probability of escaping through the hole.
and absorption rates will be equal. The problem is thus to derive The reader can easily test for himself that a black'
an expression for the density of radiant energy in the cavity as a body surface can be realized in this manner. Paint
the interior of a small cardboard box black, and cut
function of wavelength and temperature*
a small hole in one side. Viewed from outside the hole
We here focus our attention on just one detail of this problem, appears considerably "blacker1' than any "black"
namely the relation (35a). To see what is involved we rewrite this material surface.
equation in the form
^ X kT = X, = (37a)
c c
where c is the velocity of light, k is Boltzmann's constant, and X%
is a new constant* Since the left-hand side of (37a) has the phys¬
ical dimension [time] X [energy] = [action] the constant Xi is a
quantity of action* How can we derive a theoretical expression for
Xj? How are we to produce a quantity having the physical dimen¬
sion of action from the constants of nature available? This is cer¬
tainly a dilemma because it is hard to see how the constants m,
Mr and e could possibly enter into the expression for Xi* The
physical situation seems very clear-cut; the radiant energy inside
the cavity is in thermal equilibrium with the walls* The radiation
emitted from the cavity is, however, independent of the size and
shape of the cavity and also independent of the material in the
walls; how then could constants like m and e, which refer to prop¬
erties of the walls, be relevant? Our suspicion that Xi cannot be
derived from the remaining constants seems quite justified and, as
a matter of fact, the relation (37a) cannot be understood on the
basis of classical physics. The situation was actually quite desperate

in the year 1900, before Planck’s discovery. The application of
classical statistical mechanics had led to the absurd black-body-
iadiation law stating that the intensity radiated increases mono-
tonically with the frequency in such a way that the total radiated
intensity is infinite, which means that radiation cannot be in thermal
equilibrium with matter at any temperaturel
38 On December 14, 1900 Max Planck presented a derivation of

the black-body-radiation law at a meeting of the German Physical
Society in Berlin, and this date can be regarded as the birthday of
the theory of quantum physics.t In his derivation of the theoretical
expression for the intensity of radiation as a function of the wave¬
length and the temperature, Planck departed from classical physics
by making a radical ad hoc assumption the essence of which can
be stated as follows. An oscillator of natural frequency v can take
up or give off energy only in parcels of magnitude E = hv> where h
is a new fundamental constant of nature. Planck was then able
to derive, among other things, an expression for our constant Xi,
namely
^2= X M* = — = Xi = 0.2014 X h (38a)

c c
This then is how Planck’s constant made its first appearance.
Planck himself was very reluctant to accept this departure from
classical physics, and after his great discovery he tried very hard
for many years to understand the phenomenon of black-body radia¬
tion on a purely classical basis. Of these fruitless efforts he later
said that he did not regard them as useless labor; only by his re¬
peated failures did he reach the final conviction that an explanation
could not be found within classical physics.
39 In its full glory Planck’s radiation law reads as follows:
W) = (^) X eip pjtfy rr '39s>
where E(\,T) is the density of radiant energy in the cavity per

unit wavelength interval, at the wavelength X, and at the temper¬
ature T. The constant k is Boltzmann’s constant, and c is the
velocity of light.
4M. Planck, "Uber das Gesetz der Energievorteilung in Normalspektrum/1 Annalen

der Physik 4,553 (1901).
The intensity of the radiation emitted from a small hole in the

wall of the cavity is proportional to the energy density inside the
cavity, and the expression (39a) is thus the mathematical expres¬
sion for the relationships illustrated in Fig. 35A.
To find the location of the maximum of as a function
of X, with T constant, we set the derivative of £(X,T) with respect
to X equal to zero, and solve for Xmax. This is how we obtain the
relation (38a), or the equivalent relation
Xraaj[T = Co = 0.2014 X y (39b)
Since Xmiuc and T can be readily measured, and since c is known,

we can thus determine h/k experimentally on the basis of the rela¬
tion (39b), Furthermore, by a detailed comparison of the experi¬
mentally measured EfX,?) with the theoretical expression (39a) we
can also determine the constant h. This permits a computation of
Boltzmann's constant k, and finally, by virtue of the relation
No = R/k, a computation of N$. The value for k which Planck
obtained in this way is about 2*5 per cent smaller than the best
modern value*
40 The detailed history of Planck's radiation law is fascinating*

Before Planck succeeded in deriving the expression (39a) from a
“microscopic” point of view he had actually guessed the correct
dependence of £(X,T) on X and T, This guess was partly based on
some careful measurements by H* Rubens and F* Kurlbaum, and
partly on some general theoretical considerations* [The relation-
ship expressed by (39a) is obviously too complicated to arrive at on
purely empirical grounds*] Planck presented his preliminary result
to the German Physical Society on October 19, 1900. In this
version the formula contained two constants without any physical
interpretation, say the constants which we would now write as
(Sirkc) and (hc/k). This formula was again checked against the
experimental results by Rubens, and by O. Lummer and E* Frings-
heim, and was found to agree with the facts with remarkable
precision* f Planck was thus faced with the problem of finding
some kind of basic theoretical justification for a formula which
appeared to be the correct one* This he succeeded in doing, after
about eight weeks of strenuous labor,
fFor latet tests of Planck's law* see H. Rubens and G, Michel, "Prufung der
Flanckschen Strahhmgsformel,” Physikalische 7>eitschTift 22,569 (1921),
The Photoelectric Effect

41 Around the turn of the century it was known experimentally
that when light (in the visible or ultraviolet region) is incident on a
metal surface, electrons will be ejected from the surface.! This
phenomenon is in itself not surprising since we know that light is
electromagnetic radiation, and we may thus expect that the electric
field of the light wave could exert a force on the electrons in the
metal surface and cause some of these to be ejected. What is
surprising, however, is to find that the kinetic energy of the ejected
electrons is independent of the intensity of the light, but does
depend on the frequency in a very simple way: it increases linearly
with the frequency. If we increase the intensity of the light
we merely increase the number of electrons emitted per unit time,
but not their energy. This is very hard to understand on a classical
basis as we would expect that when the intensity of the light wave,
and hence the amplitude of the electric field in the wave, increases,
then the. electrons would be accelerated to higher velocities.
These facts had been established before 1905 by P. Lenard and
others. Precise measurements of the relationship between the
frequency of the light and the energy of the ejected electrons were
not carried out until 1916, when the subject was studied very
carefully by R. A. Millikan.
42 In 1905 Albert Einstein suggested an explanation of these

phenomena. J According to this explanation the energy in a beam of
monochromatic light comes in parcels of magnitude hv, where v is
the frequency; this qtumtum of energy can be transferred com¬
pletely to an electron. The electron acquires, in other words, the
energy E = hv while it is still inside the metal. If we now assume
that a certain amount of work, W, has to be performed to remove
the electron from the metal, then the electron will emerge from the
metal with the kinetic energy Ekin = E- W, or
Ekin = hv - W (42a)
The quantity W, known as the work function of the material, is
assumed to be a constant characteristic of the metal, independent
of the frequency v.
The equation (42a) is Einstein’s celebrated photoelectric equa¬
tion. The energy of the emitted electrons increases linearly with
the frequency, but is independent of the intensity of the light.
t See P5SC, Physics, Chap. 33.

t A. Einstein, “Obereinen die Erzeugung und Verwandlung des Lichtes betreffenden
heuristisehen GesichtspunkC* Anndfen der Fhysik 17, 132 (1905),
Sec, 1.43 Introduction 29
The number of electrons emitted is naturally proportional to the

number of the incident quanta, and hence proportional to the
intensity of the incident light. In this manner Einstein was able to
account for the qualitative aspects of the photoelectric effect, such
as they were known to him at the time.
43 Einstein arrived at this idea by noticing that certain aspects

of Planck's strange black-body-radiation law could be understood
by assigning corpuscular properties to the electromagnetic radiation
in the cavity, Le*, by assuming that the radiant energy consists of
quanta of magnitude hv. We should note here that the real mean¬
ing of Planck's assumption was at that time shrouded in obscurity,
and Einstein's new way of looking at the phenomenon of black-body
radiation was therefore an important step forward. The most im¬
portant aspect of this matter was, however, that Einstein could
apply his insight into the phenomenon of black-body radiation to
a new physical situation, namely the photoelectric effect.
44 The equation (42a) was a precise theoretical prediction, and as

such susceptible to quantitative experimental tests, It furthermore
offered the opportunity for a new measurement of Planck's con¬
stant, assuming that Einstein's ideas were correct. As we have
mentioned before these extremely Important questions were studied
by R, A, Millikan in a series of very careful and beautiful measure¬
Incident light
ments, f in which he found complete agreement with Einstein's
equation (42a).
Millikans method is illustrated schematically in Fig, 44A,
Monochromatic light is incident on a metal surface, usually an alkali
metal, and causes the ejection of photoelectrons, A collecting elec¬
trode, which can be kept at an arbitrary potential — V with respect
to the photocathode, is placed near the photosensitive surface, and
the current of photo electrons is measured. If we now assume that
the electrons are all emitted with the same kinetic energy as
given by equation (42a), then it is clear that none of the electrons
can reach the collecting electrode if eV > EkLn, We can therefore
observe the current as a function of the retarding potential V, and
if Vo is the potential at which the current just becomes zero we have Fig, 44A Very schematic figure to illustrate the
principle of Millikan's experiment. Electrons are
ejected with an energy £^ = hv - W, where W is the
V° = (e) " ~ ? <■**>work function characteristic of the cathode material,
when light of frequency v is incident on the photo’
A plot of the cutoff retarding potential V0 versus the frequency cathode. The electron current to the collector will
cease when the retarding potential V > (hr - W)/e.
Observation of the critical retarding potential V0 =
t R, A. Millikan, "A Direct Photoelectric Determination of Planck’s h\" The {hv — W)/e versus v yields the constant h/e, (See
Physical Review 7, 355 (1916). Fig. 44B.)
30 Introduction Sec, IAS
Fig. 44B A graph taken from Millikan's paper [R. A. v will thus be a straight line, as shown in Fig. 44B taken from
Millikan, Physical Review 7, 355 (1916)] showing the Millikan's paper. From the slope of this line we can find the
linear relation between the critical retarding potential constant h/e> and from its intercept with the Vo-axis we can find
Vo and the frequency of the light, for a photosensitive
surface of sodium. As we see, Millikan presented his
the material constant W/e.
computation of Planck's constant on the basis of his This is a conceptually simple and clear-cut experiment, but to
curve on the graph. (Courtesy of The Physical Ra- obtain accurate and reproducible results considerable care is re¬
view.) quired.
45 Let us consider the relation (44a) numerically. With h = 6,63
X 10"27 erg sec = 6.63 X 10-34 joule sec, and e = 1.60 X 10_ie
coul, we obtain h/e = 4.14 x 10“15 volt sec. For visible light the
wavelength lies in the range 4000 A to 7000 A, where 1 A(ngstr6m)
= 10“s cm.t This corresponds to the frequency range (4.3 to 7.5)
X 1014 sec-1. Blue light corresponds to a frequency of about
7 x 1014 sec-1, and for this case we obtain {h/e)v ^ 2.8 volts. For
light in the visible or near-ultraviolet region the retarding potential
will thus be of the order of magnitude of one volt, It is an experi¬
mental fact that the material constant W/e is also typically of this
\ In honor of the memory of the Swedish physicist A. J. Angstrom, English-speaking

people might make an effort to pronounce his name correctly. The first vowel ‘‘A" is
pronounced like o in long, and the second vowel “ti" like the same letter in German or
like the vowel eu in the French word deux.
See* 1A6 Introduction 31
order. It is particularly small for alkali metals, which is why photo¬

cells intended for visible light have photocathodes made of these
materials. A photocell will obviously not respond to radiation for
which W > hv>
46 The qualitative features of photoemission which had been

discovered before 1905 were certainly remarkable, although it
required the insight of Einstein to fully appreciate the significance
of these phenomena. Had Millikans quantitative results been
available at that time they would certainly have been recognized
more generally as a major challenge to classical ideas.
The essence of the matter is clearly the strange relation
where E is the energy which can be transferred to an electron from

a beam of monochromatic light of frequency p and where X2 is a
constant independent of the intensity of the light, independent of
the frequency of the light, and independent of the material in which
the electrons are embedded. (That the electrons emerge with a
kinetic energy smaller than E would not have been regarded as a
mystery in 1905 any more than today: the work function W simply
represents the binding energy of the electrons in the material.) To
understand a relation such as (46a) on a classical basis, and to
express this understanding in a formula giving the mysterious
constant X2 in terms of the basic constants of classical physics,
appears to be a truly hopeless task. The constant X2 has the phys¬
ical dimension of action, and it is true that such a quantity can
indeed be formed from the basic constants, namely (e2/c) = (h/860).
We now know that X2 = K and the quantity (e2/c) is thus of the
wrong order of magnitude, about 1000 times too small, which is not
encouraging. Playing with dimensional arguments in this manner
does not, however, really lead us anywhere unless we can propose
a classical mechanism which leads to the equation (46a). Nobody
has been able to do that, and the facts concerning the photoelectric
effect very strongly support Einstein's idea that radiant energy is
quantized, f
As we will learn later the relation (46a) expresses a very basic
principle of quantum physics, namely that energy and frequency
are universally related by E = hv. Such a relationship is entirely
foreign to classical physics, and the mysterious constant X2 (= h) in
(46a) is a manifestation of secrets of nature unsuspected at the time.
f It may be mentioned here that Einstein did not use the term photon for the electro-
magnetic quanta In his paper; that term was introduced much later.
The Problem of the Stability and Size of Atoms
47 Let us now turn to the third of our problems, namely the

question of the stability and size of atoms, and let us in particular
consider the latter question. We can define the “size” of an atom
as the typical distance between neighboring atoms in a crystal or
liquid. Experimentally this size is known to be of the order of
1 A = 10-8 cm. The order of magnitude of this distance is related
to the order of magnitude of Avogadro’s number No as follows. One
cubic centimeter of any liquid or solid has a mass of, very roughly,
one gram. One gram of any substance contains, very roughly, No
atoms, and therefore the separation between neighboring atoms
in a solid or liquid must be of the order of (l/No)1/3 cm — 1 A.
A precise measurement of the interatomic spacing in a crystal leads,
as we have said before, to a value for Avogadro’s number.
The question is now whether we can find an explanation for the
size of an atom within the framework of classical physics; whether
we can compute the “radius” of an atom given the basic constants
of classical physics.
48 After Rutherford’s famous analysis! around 1910 of the alpha-

particle scattering experiments of H. Geiger and E. Marsden, a
certain picture of the atom had emerged, according to which the
atom consists of a very small central nucleus surrounded by one
or more electrons. There were good reasons to believe that both
the nucleus and the electrons are very small compared with the
size of the atom, smaller than, say, 10-11 cm at least. Furthermore,
most of the mass of the atom seemed to be concentrated in the
nucleus.
Under these circumstances it was very natural to try to create
some kind of solar-system model of the atom, with the nucleus
playing the role of the sun, and the electrons playing the role of
the planets. The particles would move under their mutual electro¬
Ernest Rutherford. Born 1871 near Nelson, New static interactions, and most of the atom would consist of “empty
Zealand; died 1937. After holding a professorship at space.” The size of an atom would be related to the radius of the
McGill University in Montreal, Canada, Rutherford orbit of the outermost electron.
accepted a position at Manchester University in 1907.
Let us accept this model temporarily for the sake of argument
In 1919 he succeeded J. J. Thomson in the Cavendish
chair at Cambridge University. He received the Nobel and let us also assume, at first, that the velocities of the particles will
prize in 1908 (in chemistry). be small enough to permit a discussion within nonrelativistic me¬
Rutherford did pioneering work of outstanding im¬ chanics. We must then answer the question: What determines the
portance in radioactivity and nuclear physics. His
experimental work is characterized by exceptional skill
and ingenuity, and his analysis of experimental facts IE. Rutherford. “The Scattering of a and ft Particles by Matter and the Structure
reveals a deep physical insight. (Photograph by cour¬ of the Atom,” Philosophical Magazine 21, 669 (1911). See also Berkeley Physics
tesy of Professor L B. Loeb, Berkeley.) Course, Vol. 1, Mechanics, Chap. 15, and PSSC, Physics, Chap. 32.
Sec. L49 Introduction 33
size of the orbit of the outermost electron? We note that in this

model there is no place for the velocity of light. But then we can¬
not form a quantity having the physical dimension length from our
remaining fundamental classical constants e, m} and Mh, and we
may suspect that our problem is insoluble within classical me¬
chanics. To see this very clearly we may argue as follows:
49 Consider an atom, consisting of Z electrons, each one of charge

- and a nucleus of charge + Ze, Without loss of generality we
can assume that these particles move in such a way that the center
of mass of the system remains at rest. Each particle then moves
along some orbit specified by the function rjt(f) which gives the
position vector of the fcth particle as a function of the time t (We
select the center of mass of the system as the origin.)
The functions r^(t), (k = 1, 2, . . . , Z + 1), taken together thus
constitute one solution of the equations of motion for the system.
From this one solution we can construct a whole family of new
solutions by a simple scaling as follows. If q is any non-zero con¬
stant, then the functions rk(t) defined by
r k(t) = q2rk(t/q*) (49a)
also satisfy the equations of motion. In other words: the function

rk'(t) describes the trajectoiy of the kth particle in the new state
of motion of the system. We can see this very easily as follows.
The force Fij which the jth particle exerts on the ith particle is
given by
where is the charge of the ith particle and Q, is the charge of

the jth particle. The new solution is obtained from the old solution
by multiplying all distances by the factor q2, which means that the
forces in the new state of motion are obtained from the forces in
the old state of motion by multiplication by the factor q~A. This
means that all accelerations must be scaled by the same factor q~4.
Since linear distances are scaled by the factor q2 we conclude that
all velocities must be scaled by the factor q-1, and that all times
must be scaled by the factor q3. This is just what the equation
(49a) expresses, and this equation thus defines a new solution, as
asserted.
Let us furthermore note that all angular momenta are scaled by
the factor q, and that all potential and kinetic energies, and hence
also the total energy, are scaled by the factor q~2.
The fact that we can obtain a new solution from a given solution
through a scaling of the kind described is really an extension of
Kepler's third law. Applied to the particular case of a single eleo-
tron moving around a fixed nucleus, our argument tells us that for
two elliptical orbits of the same eccentricity the ratio of the squares
of the periods is proportional to the ratio of the cubes of the semi¬
major axes.
Since we can give any value we please to q we actually have a
whole family of solutions, and there is no reason why we should
prefer any particular one of these; there is, in other words, no prin¬
ciple which tells us why a particular “size" for the atom should be
preferred. One might, of course, argue that the actual size of an
atom is determined by “accident" but such an argument would
hardly stand up. How is it possible that this “accident" always
leads to the same size of orbit for a given species of atoms? Why
don't we have a continuous distribution in size for, say, the hydro¬
gen atom?
50 In view of this dilemma we may wonder whether we were

justified in trying to discuss the problem non-relativistically. We
note that it is indeed possible to form an expression having the
dimension of length from the classical constants, if we include the
velocity of light, namely
— = 2.8 X 10-13 cm (50a)

me3
This is essentially the “classical radius of the electron,” which we
discussed in Sec. 18. We would thus expect that if relativity really
plays an essential role, i.e., if the electrons move with a velocity
comparable with the velocity of light* then the size of an atom
would be some multiple of the length e2/mc2. This length is, how¬
ever* more than 104 times too small* and it does not seem likely that
this line of approach will lead anywhere. It is true that our simple
scaling argument in the preceding section does not apply as such in
a relativistic model, but there is still no principle which would tell
us why only certain orbits can occur* corresponding to the observed
sizes of atoms.
51 We may regard our dilemma as a "mystery of the missing

constant.” Suppose now that we are bold and assume that the
present mystery is related to our earlier "missing-constant mys¬
teries,” and that Planck's constant should play a role in the descrip¬
tion of atomic structure. This constant has the dimension of angular
momentum* and we might try the ad hoc assumption that only
those solutions of the equations of motion for which the total angular
momentum of the atom is a definite multiple of h are realized in
nature. If we accept this principle we must give up our scaling
argument since under the transformations described by Eq. (49a)
the angular momentum will be scaled by the factor q, which now is
not allowed. This means that there will be preferred solutions, and
hence we now have a principle available for the determination of
the size of an atom.
In 1913 Niels Bohr presented a theory of the hydrogen atom along
these lines, f In the simplest version of this theory a single electron
moves in a circular orbit of radius do around a proton. The orbit is
determined by the equation of motion
m (51a)
together with the quantum conditions of Bohr;
J = mvao = — (51b)
27T
where v is the velocity of the electron and J is the angular momen¬

tum. The quantum condition thus states that the angular momen¬
tum equals h/2tt. If we eliminate v from the above equations we
obtain
00 = = 0-53 X 10- cm (51c)
which is of the desired order of magnitude. Furthermore, we

should note that the problem of atomic size is intimately related to
the problem of atomic binding energies; once we know the size of Niels Henrick David Bohr. Born 1885 in Copenhagen,
an atom we can also estimate the work required to break it up into Denmark; died 1962. After studies at the University
its elementary constituents. of Copenhagen Bohr went to Cambridge, and a few
months later to Manchester to work with Rutherford,
In 1913 he published his celebrated paper on atomic
52 As the reader undoubtedly knows, Bohr was able to go much structure. In 1916 Bohr became professor of theo¬
further; he was actually able to explain the spectrum of the hydro¬ retical physics at the University of Copenhagen, His
gen atom quantitatively, which was a spectacular success for the Institute for Theoretical Physics (established in 1921)
new ideas. His quantum condition was certainly foreign to classical became a world center at which most of the world's
physics, and in addition Bohr had to assume that the motion of the outstanding physicists spent some time as visitors.
Bohr was awarded the Nobel prize in 1922,
electron in the ground state of the hydrogen atom does not lead to After his pioneering work on the hydrogen atom
emission of electromagnetic radiation; otherwise, according to Bohr made many important and outstanding contri¬
classical electromagnetic theory, the electron would spiral in toward butions to the development of atomic physics, and
the nucleus in a very short time (of the order of 10-9 sec). later also to nuclear physics. Through his publica¬
tions, and through his personal contacts with other
physicists, his influence as a champion of new ideas
t N. Bohr, “On the Constitution of Atoms and Molecules,” Philosophical Magazine has been very considerable. (Photograph by courtesy
26,1 (1913).
of Professor L B. Loeb, Berkeley.)
36 Introduction Sec* 1,53
This planetary theory of atoms should not be taken seriously; it

is really quite wrong. That it works so well in the particular case
of the hydrogen atom is a fortunate (or unfortunate) accident.
Fortunate, because it encouraged Bohr and others to try to create
a quantum theory of atoms. Unfortunate, if it leads anybody to
believe that atoms in any way resemble planetary systems. Bohr
himself was not fooled: he regarded his own theory merely as an
intermediate step in the search for a more coherent theory, which
now exists.
Fig. 52A A symbol of the Atomic Age, which has
absolutely nothing whatever to do with the structure of 53 The three problems which we have considered may be re¬
atoms. Figures of this general appearance occur garded as three aspects of the discovery of Planck s constant, If we
widely as emblems of companies, government agen¬
think in particular about the last problem we see that the addition
cies and other organizations which have something
to do with "Atoms." Very fanciful versions can some¬
of this constant to our list of fundamental constants of nature will
times be seen in advertisements, in which the tremen¬ have far-reaching consequences. We can now hope to be able to
dous speed of the electrons is indicated by what took understand not only the sizes and binding energies of atoms, but
like vapor trails (presumably vapor trails in the ether?). also of molecules, and the road seems open to a quantitative atomic
No harm is done so long as it is understood that this
theory of matter in bulk.
is only a symbol, but there is always the danger that
some people might be misled into believing that atoms
It should be stressed that the essential aspect of the three prob-
really look this way. lems is, of course, that the resolution of the difficulties required a
departure from the classical macroscopic laws of physics. The
consideration of these problems therefore led to something much
more than the discovery of a new constant; namely, to the discovery
of new laws of physics.
The development of physics was very rapid after these initial
discoveries, and it became clear that the key had been found to the
explanation of many phenomena in microphysics. The theoretical
work culminated with the publication of two consistent mathemat¬
ical theories of quantum physics; namely the matrix mechanics
created by Werner Heisenberg in 1925 and the wave mechanics
created by Erwin Schrodinger in 1926. These two theories were
subsequently shown to be completely equivalent, and merely two
different forms of what we today call quantum mechanics, which is
the currently accepted fundamental theory on which the study of
microphysics is based
54 The reader may want to ask some questions. Are we sure

that quantum mechanics is the ultimate truth? What is there left
to discover in physics?
The author is happy to be able to reassure the reader with regard
to these questions. We can never know whether any theory is ‘"the
ultimate truth." Nor can we ever know “what there is left to dis¬
cover"; most likely very much, because, as we have said before, we
most certainly do not now have a comprehensive theory of all
Sec* L5S Introduction 37
phenomena occurring in nature* We have learned a lot, but there

is more to be learned. That is one of the reasons why physics is
interesting* The reader need have no fear that he was bom too late
to make discoveries in physics.
Let us try to answer these questions a bit more precisely* The
general principles of quantum mechanics are “true” in the sense
that there is no experimental evidence against them, but an enor¬
mous amount of evidence that they can be used for successful pre¬
dictions*
The favorable evidence is particularly convincing in the field of
quantum electrodynamics, which is the basic theory of atoms, mole¬
cules, electromagnetic radiation, and matter in bulk such as we
know it on our earth. As we have said before, there never was any
fundamental classical theory of physics in this realm; now we have
a theory, and a highly successful one* This means that we believe
that we now know the basic facts in terms of which we should be
able to explain, say, such phenomena as superconductivity and
superfluidity. To date, however, nolx>dy has really been able to
explain these two phenomena in a quantitative manner from first
principles. Knowing the basic principles is one thing, but explain¬
ing a complex phenomenon involving many particles is quite another
thing. Because we can explain the behavior of simple systems,
consisting of a comparatively small number of particles (such as
individual atoms and simple molecules), we l>elieve in our basic
principles. We are, however, quite unsophisticated mathemati¬
cally, and as the complexity of the situation increases we find it
harder and harder to make quantitative predictions, although we
may have a general qualitative understanding of the phenomena*
It is safe to predict that there will always be problems in physics
which are hard in this sense, and that there will always be a place
for clever ideas to overcome such difficulties* It is possible that
quantum electrodynamics is an almost “closed” subject from a
fundamental point of view, but it is certainly not closed in the sense
that all possible consequences have already been extracted from the
theory.
55 From the standpoint of physics around the turn of the century

the “stable and indivisible” atoms were the elementary particles of
the world. Today the atoms have lost this distinguished position;
they have been explained in terms of more elementary things
flirough the theory of quantum electrodynamics. The same is, in a
sense, the case with the nuclei as well* In this latter case we cannot
explain the properties of nuclei completely from first principles, but
we nevertheless firmly believe that it is proper to regard the nuclei
38 Chap. 1 References for Further Study
as composite systems essentially made of protons and neutrons.

After the composite nature of atoms and nuclei became clear the
number of recognized elementary particles took a sharp dip* This
number has subsequently steadily increased, and it is now about the
same as it was around the turn of the century* Electrons, muons,
neutrinos, protons, neutrons, hyperons, pions, kaons and many
other particles have taken the place of the atoms* We have already
explained in what sense these particles are elementary.
At present there does not exist a basic theory of the elementary
particles* What form the possible future theories may assume is
anybody’s guess, and the field is wide open for brilliant ideas.
References for Further Study
1) It will be assumed in this book that the reader has some familiarity with the most
basic facts of quantum physics, at the level at which these topics are discussed in a high
school physics text such as Pfiysfcs. by the Physical Science Study Committee (D. C.
Heath and Company* Boston, 1980). (Part IV* in particular.)
In the cases in which the above assumption does not correspond to the facts some
supplementary reading is called for. Any library will have a variety of semi-popular
accounts of "atomic physics," some of which are had and some of which are good.
Taken with a grain of salt such a book might serve the purpose. Articles in magazines
such as Scientific American can be very useful, and are jfrongty recommended. The
reading of such articles will probably whet the reader's appetite and lead to further
self-study and reading, Whenecer the reader & background permits it he should try to
reed original papers, but highly technical, or mathematically complicated accounts are
best avoided at this stage.
2) The reader may be interested in reading selected portions of some text on quantum
physics in which a more complete account of experiments is given than in this book.
Among the many such texts we mention the following:
a) E. Grimsehl and R> Tomaschek: A Textbook of Physics, vol V, Physics of the
Atom (Blackie and Son Limited* London, 1945).
b) G> P. Harnwett and J. J. Livingood: Experimental Atomic Physics (McGraw-Hill
Book Company* New York* 1933).
3) The following books are historical surveys of the development of modem physics:
a) M. Jammer: The Conceptual Development of Quantum Mechanics (McGraw-Hill
Book Company, New York* 1968). A magnificent piece of work, which, however,
requires a substantial knowledge of quantum mechanics for a full appreciation. The
beginning of the book* which deals with the early history, can be read with a modest
background. The many carefully compiled references to original papers is a valuable
feature.
b) E, Whittaker: A History of the Theories of Aether and Electricity, vols. I and II
(Harper Torchbooks* Harper and Brothers* New York 1960), The second volume dit-
cusses the development of quantum mechanics. These books (as well as Jammer's)
discuss the interesting false leads as well: the theories once taken seriously but now
forgotten.
Problems Introduction 39
4) a) An extremely interesting and penetrating analysis of the development of quan¬

tum mechanics as well as of relativity is given by Albert Einstein (in German with an
English translation) in the form of an autobiography published in: Albert Einstein,
Fhihsopher-Scientist, vol. I, edited by P. A. Schilpp (Harper Torchbooks, Harper and
Brothers, New York, 1959).
b) Planck's own account of the development of his ideas is presented in: M. Planck:
A Suruep of Physical Theory (Dover Publications, New York, 1960).
5) In the text of this chapter references to several of the important original papers
have been given. The reader is urged very strongly to at least look at these: several
of the papers can be read without undue difficulty. Collections of these, and other
papers, have been published subsequently. We mention two sources of this kind:
a) Great Experin\ent$ fn Physics, edited by M, H. Shamos (Holt, Rinehart and
Winston, New York, 1962). (Translated and abbreviated versions, with editorial
comments,)
b) The World of the Atom, edited by H. A. Boorse and L. Motz, vob. I and II (Basic
Books, Inc,, New York, 1966). This is a very complete collection, with editorial com¬
ments giving historical background and biographical information. Selective reading
of these books is strongly recommended.
6) Many of the experimental discoveries and theoretical ideas discussed in this volume
have in due time been rewarded by the Nobel Prize, Every recipient of this prize is
required to give a semipopular lecture in Stockholm about his work. Extracts from
these lectures, with short descriptions of the prize-winning work, can be found in
N, H. de V. Heathcote: ,Vohvt Prize \V7nnm in Physics 1901-1950 (Henry Sehuman,
New York, 1953).
Problems
1 (a) First consider, and then describe very briefly, the kind of reasoning
and the kinds of measurements that have led to definite assignments of atomie
and molecular weights.
(b) In 1815 William Frout suggested that all elements might be combina¬
tions of hydrogen, which would thus be the primordial material from which
everything else is made. What might have ted him to such a hypothesis,
and why was his suggestion rejected during the nineteenth century?
2 Many atoms (or rather nuclei) disintegrate spontaneously, usually

through the emission of either an electron or an alpha particle, which is
nothing else than a helium nucleus. This is the phenomenon of radioactivity,
first discovered by Henri Becquerel in 1896. [H. Becquerel, 4,Sur les radia¬
tions invisibles £mises par les corps phosphorescents,” Comptes Rendu# 122,
501 (1896),] The rate of disintegration is governed by a statistical law, which
predicts that out of Ni atoms originally present N(t) = \\ exp (- Af) will have
survived at the time t. The constant A* which describes the rate of disinte¬
gration, is characteristic of the atom (nucleus). The time T it takes for half
of the atoms originally present to decay is known as the half-life. We
obviously have T = (1/A) In 2,
40 Chap. 1 Problems
(a) Show that the above law of disintegration results if we assume that
each atom disintegrates independently of the other atoms, and also assume
that the probability that an atom* which has survived until the time tt will
disintegrate dining the time interval (f, t + Af) is independent of
(b) In the decay of radium atoms an alpha particle is emitted. If this
alpha particle strikes a zinc sulfide screen, a flash of light (called a scintil¬
lation) will mark the point of impact. It is thus possible to count directly
the number of alpha particles emitted per second from I gram of radium,
and this number was determined by Hess and Lawson as 3.72 X 1010* The
atomic weight of radium is 226. Use these data to find the half-life of
radium. (Measurements with radioactive substances have been used to give
independent estimates of Avogadro’s number. In the above problem the
procedure is reversed, and we instead determine the half-life of radium.)
3 The moving parts of a wrist watch are pretty “small.” Making reason¬
able estimates of the magnitudes of the physical parameters which charac¬
terize a ‘"typical" wrist watch, show, however, on the basis of the general
criterion given in Sec, 20, that quantum mechanics is totally irrelevant to
the art of watchmaking.
4 In the spirit of the preceding problem, consider a simple electrical

lumped-constant circuit, consisting of a capacitor of capacity 100 pF
(100 nfiF) and an inductance of 0,1 mH. Suppose that the circuit oscillates
so that the maximum voltage across the capacitor is 1 mV. Try to find a
""natural” physical quantity with the physical dimension action, and compute
this quantity in units of Planck’s constant h.
5 A broadcasting antenna emits radiation (radio waves) at the frequency

1 Mc/sec at the rate of 1 kW. What is the corresponding number of photons
emitted per second? The size of this number explains why the quantum
nature of electromagnetic radiation is not immediately apparent when we
study radiation from antennas.
This example, and those in Probs. 3 and 4, are ridiculous in the sense that
the relevant numbers are ridiculous. We shall not try to apply quantum
mechanics to obviously macroscopic problems in the rest of this book. It
may, however, be edifying to have done problems of this nature once—if only
to learn the lesson that they are ridiculous.
6 To see that the statement that electromagnetic radiation comes in

packets of energy E — hvt where v is the frequency, does not violate common
sense (that is, does not violate your experience with macroscopic phenomena),
compute the number of photons emitted per second by a light source of
strength I candela. We assume for simplicity that the light emitted is of
yellow color, the wavelength being 5600 A (Angstrom units). A source of
strength 1 candela emits light energy at the rate 0.01 watt.
Problems Introduction 41
Suppose that an observer looks at an isotropic light source of strength I

candela at a distance of 100 meters. Compute the number of photons enter¬
ing one of his eyes per second; assume that the entrance pupil of the eye
has the diameter 4 nun. Because the number of photons is as large as it is,
we do not observe any “flickering” even though the luminous flux received
by the eye is small by macroscopic standards.
7 We all know that stars “twinkle.” To see whether this may be a

manifestation of the quantum nature of light, estimate the number of photons
entering the eye of an observer when he looks at a star of first apparent visual
magnitude. Such a star produces a flux at the surface of the earth of about
10“6 lumen/meter2. One lumen at the wavelength of maximum visibility,
which is about 5560 A, corresponds to 0.0018 watt. A star of the first ap¬
parent visual magnitude is a fairly bright star, easily visible to the naked eye,
although not among the very brightest stars. The star Aldebaran is an
example.
Suppose that N photons per second enter the eye o f the observer. How
large is the mean fluctuation in this number? After you have determined Nt
decide what is the likely explanation of the twinkling. Why do planets
appear to twinkle much less, or not at all?
8 (a) Consider Wien’s displacement law, and suppose that we have a

black-body radiator kept at a temperature of 2500 °K, Compute the wave¬
length in Angstrhm units, as given by Wien’s law, for which the emission is
a maximum. Does this wavelength lie in the visible region?
[b) Derive Wien’s displacement law from Planck’s formula (39a).
(c) On the basis of Planck’s radiation law (39a), show that the total rate
at which radiation is emitted by a black-body radiator (i.e., all frequencies
included) is proportional to the fourth power of the temperature T,
9 In our historical discussion of the black-body-radiation law we men¬

tioned that Planck, in his derivation, made the assumption that a harmonic
oscillator, of frequency v, can take up energy only in packets of magnitude
hv. (The reader should note that we did not attempt explanations in our
historical survey, and at this time the reader is therefore under no obligation
to understand how Planck arrived at his final result.) It is of interest to see
what connection there may be between Planck’s assumption, and the assump¬
tion which Bohr made in his derivation of the characteristics of the hydrogen
atom. Let us therefore consider the following: A harmonic oscillator, of mass
m and spring constant K, behaves in accordance with Planck's assumption.
This means that the energy of the oscillator can change only by integral
multiples of hv, where v is the frequency of the oscillator. Let us introduce
the action variable / = at qoPoi where q$ is the maximum displacement of
the oscillating mass point, and where po is the maximum momentum.
Chapter 2
Magnitudes of Physical Quantities

in Quantum Physics
Sections l to to Units and Physical Constants 44
II to IS Energy 49
19 to 32 Magnitudes Characteristic of Atomic and
Molecular Physics gg
33 to 39 The Most Basic Facts of Nuclear Physics 66
40 to 43 Gravitational and Electromagnetic Forces 73
44 to 46 Concerning Numerical Work 75
47 to 57 Advanced Topic: The Fundamental Constants
of Nature 78
Problems 85
Chapter 2 Magnitudes of Physical Quantities
in Quantum Physics
Units and Physical Constants
1 One of the aims of this chapter is to give the reader a feeling for
the orders of magnitude of various physical quantities in the realm
of quantum physics* Many of the important physical quantities,
such as the electronic charge, the electronic mass, Planck’s constant,
etc., have numerical magnitudes when expressed in our familiar
macroscopic units which are inconvenient and untransparent be¬
cause they are so very small. It is difficult to grasp directly what it
means that Planck’s constant has the value h = 6*6 x 10*"27 erg
sec. It is therefore important that we study in detail how these
various constants occur in physics, and what their numerical values
actually mean* t
Every domain of physics has what we may call natural units for
the physical quantities involved, which means that when we express
any physical quantity in terms of these natural units then the nu¬
merical values are reasonable in the sense that their significance can
be readily grasped* The numerical values may vary over the range
10-6 to 106, but we will not encounter numbers such as 10~27.
Our familiar macroscopic units (in the MKS system) are particularly
suited for our everyday experiences with physical phenomena, and
they are based on readily available macroscopic standards. We
note that they are really “human units"'; units such as the meter and
the kilogram, and the second unmistakably refer to human char¬
acteristics. The so-called “scientific,” or cgs system of units is more
appropriate for small animals, such as cockroaches. We shall try to
free our discussion from the arbitrary standards of the human sys¬
tem, or the cockroach system, and try to identify the natural units
in the various domains of quantum physics.
2 We begin by listing some physical constants in a table. These

constants are commonly referred to as "the fundamental constants
of microphysics/ but there is really nothing fundamental at all
about the individual numbers in Table 2A because the macroscopic
j In so doing we will sometimes anticipate the later, more detailed, discussion. In

case the reader encounters some passages which now seem mystifying he need not be
overly concerned; he should return to the present chapter several times as we go along
in our course. HopefuBy most readers will already have some familiarity with the
topics of our discussion.
Sec. 2.3 Magnitudes of Physical Quantities 45
standards are arbitrary and “accidental.” This does not mean that TABLE 2A Some Physical Constants
the list is unimportant. Once we have selected our macroscopic
Planck*s constant:
standards we naturally want to relate the basic parameters of
h = = (6.62559 ± 0.00015)
quantum physics to these, and that is the purpose of the list.
X 10-27 erg sec
We have also quoted the estimated errors for the constants to # = h/2* - (1.05449 ± 0.00003)
give the reader a feeling for how accurately they are known at pres¬ X 10“27 erg sec
ent. At the level of this book the reader wiD almost never have Velocity of light:
c = (2.997925 ± 0.000001) x 10* u cm sec-1
occasion to carry out any computations to greater accuracy than
Electronic charge:
can be obtained with the slide rule, which accuracy is about 0.2 per
e = (4.80298 ± 0.00006) X 10-«> esu
cent per multiplication or division. The reader should also learn to
= (1.60210 ± 0.00002) X 10-lflcoid
make simple estimates which may vary in accuracy from 10 per cent E/ecfron mass:
to merely an estimate of an order of magnitude. On the inside of m - (9.10908 ± 0.00013) x 10“^ gm
the front cover of this book the reader will find a table of very rough
Proton mass:
values of the most important constants, and this table should prop¬ Mp = (1.67252 ± 0.00003) X I0~24gm
erly be committed to memory. Other, more detailed tables of
Avogadro's number:
physical data can be found in the Appendix. ATo = (6.02252 dr 0.00009) X 1023{moi)-i
Boltzmann's constant:
3 The definition of Avogadro's number requires discussion. k - (1.38054 ± 0.00006) x 10-™ erg (^K)-1
When chemists tabulated atomic weights in the past they employed
a scale in which naturally occurring oxygen was assigned by defini¬
tion the atomic weight 16 exactly. The atomic weight of hydrogen,
for instance, was thus defined as
(atomic weight of hydrogen)

(mass of hydrogen “atom”) TABLE 3A Atomic Weights (Atomic Masses)
= 16 x (3a)
(mass of oxygen “atom”) of the Lightest Elements f
The word “atom” is embellished with quotation marks because Element z Atomic weight
the weight of the “atom” always refers to the element as it occurs
H 1 1.00797
in nature. The atomic weights, as defined in Eq, (3a), are deter¬
He 2 4.0026
mined by the chemist through careful tveighing operations; he wilt Li 3 6.939
for instance, determine the amount, in grams, of naturally occurring Be 4 9.0122
hydrogen which will combine with 16 grams of naturally occurring B 5 10.811
oxygen to form water with nothing left over. The resulting number C 6 12.01115
N 7 14.0067
divided by two is the atomic weight of hydrogen.
0 3 15.9994
The atomic weights determined by the chemists in this manner F 9 18.9984
are called atomic weights on the chemical scale* Many of the ele¬ Ne 10 20.183
ments have atomic weights which are close to integers, but there are Na 11 22.9893
also notable exceptions; the atomic weight of chlorine, for instance, Mg 12 24.312
Al 13 26.9815
is 35.5.
Si 14 28.086
R 15 30.9738
4 As the reader knows, the mass of an atom is mainly concentrated S 16 32.064
in the nucleus. Nuclei are built of protons and neutrons. The Cl 17 35.453
A 18 39.948
number of protons plus the number of neutrons is known as the
mass number of the nucleus. This integer is commonly denoted t See Table C in Appendix for a complete listing.
46 Magnitudes of Physical Quantities Sec. 2.5
TABLE 4A Naturally Occurring Isotopes by A* The number of protons is called the atomic number of the
of Selected Light Elements nucleus. It is denoted by Z, and the nuclear charge is thus eZ,
where e is the elementary charge. The chemical properties of an
Iso¬ Natural
Ele¬ Atomic atom are determined almost exclusively by the nuclear charge, and
z tope
mass
abundance
Z is thus a characteristic of the chemical element. It is found that
ment
A percent
there are many instances of families of nuclei with the same charge,
H 1 1 1,007825 99,985 but with different mass numbers, and these different nuclei are
2 2.01410 0.015 referred to as different isotopes of the element. Isotopes differ in
He 2 3 3.01603 , 0.00013 the number of neutrons. The mass of the proton is almost equal
4 4.00260 100 to the mass of the neutron, and the masses of all nuclei are very
Li 3 6 6.01513 7.42 closely proportional to the integral mass number A. The explana¬
7 7.01601 92.58 tion for the occurrence of markedly non-integral atomic weights is
Be 4 9 i 9,01219 100 that many naturally occurring chemical elements are mixtures of
B 5 10 10.01294 19.6 two or more different isotopes, in which case the “atomic weight**
11 11.00931 80.4 of the element as measured by the chemists is an average of the
C 6 12 12.000000 98.89
more fundamental atomic weights of the different isotopes, t It is
13 13.00335 Ml an experimental fact that the relative abundances of the different
N 7 14 14.00307 99.63
isotopes occurring in an isotopic mixture of an element are very
15 15.00011 0.37 nearly the same all over the surface of the earth. Furthermore the
0 8 16 15.99491 99.759
different isotopes have, for all practical purposes, identical chemical
17 ! 16.99914 0.037 properties and are therefore almost impossible to separate from
13 17.99916 0.204 each other by “chemical * means. If this were not the case, the
F 9 19 18.99840 100 chemists* tables of atomic weights would be worthless.
■ p 4
5 When the chemist writes an equation for a chemical reaction

5 16 32 31.97207 95.0
33 32.97146 0,76 he employs symbols such as H (hydrogen), Li (lithium), Fe (iron),
34 33.96786 4.22 etc., to designate the naturally occurring chemical element which
36 35.96709 0.014 may or may not be a mixture of isotopes. From the standpoint of
Cl 17 35 34.96885 75.53 the nuclear physicist, however, the oxygen isotopes of mass num¬
37 36.96590 24.47 ber 16 and mass number 18 are entirely different objects, and he
. . . p H I i ► ■ ■ . . . . . .
has to distinguish between these objects when he writes his formula
for a nuclear reaction. This is done by subscripts and superscripts,
and an isotope is commonly denoted by
z (chemical symbol)^1 or (chemical symbol)^
Naturally, occurring oxygen is a mixture of three stable isotopes,

namely O16, O17, and O18, of which the isotope O16, which occurs
with relative abundance 99.759 per cent, is the dominant com¬
ponent.
t That a chemical element can consist of different isotopes was firmly established
by J. J. Thomson. [J. J. Thomson, “Rays of Positive Electricity," Proceedings of th&
Royal Society (London, Series A) SO, 1 (1913).]
Sec* 2.6 Magnitudes of Physical Quantities 47
6 Physicists and chemists have recently agreed upon a new

standard for atomic weights based on the mass of the carbon isotope
C12. The atom (not the nucleus) of this carbon isotope is thus
assigned a mass of precisely 12 atomic mass units, abbreviated
12 amu. This convention, to which we shall adhere, gives rise to
the new scale of atomic masses. Hence:
1 amu — ^ (mass of one C12 atom)

= (1.66043 ± 0.00002) X 10-** gm (6a)
Avogadro’s number Nq is defined as the number of atoms in 12

grams of isotopically pure C12, and this is the number quoted in
Table 2A.
On the new scale the atomic weight of naturally occurring oxygen
is 15.9994. This is very close to the number 16, which is the atomic
weight of oxygen on the old chemical scale. For most practical
purposes the difference between the new scale and the old chemical
scale can therefore be ignored,
7 Avogadro s number A'o is the link which connects microphysics

with maerophysics. Let us mention some important quantities
involving No which express this connection*
(i) The mass of the proton is L0073 amu, and the mass of the
neutral hydrogen atom (the isotope H1) is 1.0078 amu. The product
of Avogadros number No and the proton mass Mp is therefore
JVoMp = 1.0073 gm (7a)
which is quite close to 1 gm. In rough computations we thus

have
(mass of proton) ^ (mass of hydrogen atom) ^ gm (7b)

No
(ii) The product of Ao and Boltzmann’s constant k gives us the
universal gas constant R,
N0k = R = 8,314 x 107 erg (°K)-i (mol)-*

= 1.980 cal (°K)-i (mol)-1 (7c)
since Boltzmanns constant is the gas constant per molecule.

(iii) The product of No and the electronic charge e gives us the
Faraday constant F,
Noe — F = 96,487 coulomb (mol)-1 (7d)
This constant expresses the total charge carried by one mole of

singly charged ions.
8 Let us next discuss Planck's constant, which occurs in two

versions, denoted by h and ft, as shown in Table 2A. (The symbol
ft is read: “ft-bar/") Both constants are called “Planck's constant,”
and both are commonly employed, although one may loosely say
that ft is favored; it is a “better” constant. The reason why both
constants are employed is that it is easier to write an ft with a bar
than to write out factors 2m which would otherwise appear in many
of our formulas; i.e., the same reason why “frequencies” occur in
two versions.
In this book we denote a frequency, which is the number of
repetitions of a periodic phenomenon per unit time interval, or the
number of cycles/unit time, by the letter v. We denote angular
velocities by the letter c*>, and we measure angular velocities in
radians/unit time, or simply in 1/unit time. With every frequency v
we associate an angular velocity & according to
w = 2at (8a)
It follows that
and both expressions thus give the energy of a photon of frequency

v. It should be noted that the quantity w is also commonly called
“frequency," or angular frequency, the relation (8a) being under¬
stood*
A corresponding notation is also employed for wavelengths. The
true wavelength, which is the period of a periodic phenomenon in
a spatial dimension, is denoted by the letter ft, With every wave¬
length ft we associate a quantity ft by
X_
ft
2tt
For a monochromatic wave propagating with the phase velocity c

we have
ftp = ftto = c (8d)
The reader should carefully learn these generally accepted con¬

ventions.
9 The wavelength of a wave is often expressed in terms of its

inverse, P = 1/ft, called the wave number. This mode of expression
is employed extensively in optical spectroscopy, and the wave
number is expressed in units of cm-1. For a light wave in vacuum
we have
Sec, 2 JO Magnitudes of Physical Quantities 49
where v is the frequency* The wave number is proportional to the

frequency, but should not be confused with the frequency. It
should be mentioned that in the optical region the wavelengths
and wave numbers can be measured very accurately; much more
accurately than the velocity of light has been measured. Therefore*
in the optical region the wave numbers are better known than the
corresponding frequencies. On the other hand the frequency can
be measured very accurately in the microwave region, and in this
region the frequencies are much better known than the correspond¬
ing wave numbers or wavelengths.
10 In Chap. 1 we mentioned some methods whereby the funda¬

mental constants can be measured: historically these were the first
methods. The best numerical values for the basic constants are*
however, not obtained nowadays through such conceptually trans~
parent and simple measurements, and we mentioned the direct
methods only to make it immediately clear that these constants are
not beyond our reach. The best values come from a number of
measurements of derived quantities, i.e., expressions involving these
constants (and other constants) in various combinations which we
believe we understand well theoretically. From the derived quan¬
tities we can compute the basic constants. Since the number of all
fhe derived quantities measured is actually larger than the number
of basic constants, the equations are overdetermined, and this cir¬
cumstance provides us with valuable checks on the internal con¬
sistency of all the measured quantities which have been taken into
consideration in our determination of the constants.
Energy
11 Let us now consider the units which are used to describe

energy in microphysics. One of the most useful energy units is
die electron volt, abbreviated eV. It is defined as the energy ac¬
quired by an elementary charge of magnitude e when it passes
through a potential drop of one volt. Taking into account the
magnitude of e as given in Table 2A we can express the electron
volt in ergs:
I eV = (1.60210 ± 0.00002) x 10 12 erg (11a)

In addition to the electron volt we also employ die derived units
1 keV = 1000 eV> 1 MeV = 10* eV,

1 BeV = 103 MeV = 10* eV (lib)
where keV is an abbreviation for kilo-electron volt> MeV is an

abbreviation for million electron volts and BeV is an abbreviation
for billion electron volts A The unit electron volt is particularly
convenient in atomic physics since atomic binding energies are of
the order of an eV, whereas the unit MeV is useful in nuclear
physics since nuclear binding energies are of the order of an MeV.
The unit BeV is used in discussions of very-high-energy interactions
of the fundamental particles.
12 In Chap* 1 we discussed the fundamental role played by the

constants c and h> These constants are so fundamental in rela¬
tivistic quantum physics that one frequently employs a system of
units in this field in which $ = 1 and c “ 1; the constants ft and c
are dimensionless and equal to one* The reader may feel that such
a definition violates our notion of physical dimension. However,
it must be understood that our assignment of physical dimensions
to various physical quantities is arbitrary, and purely a matter of
convention. Strictly speaking only directly comparable physical
quantities have the same “physical dimension”; i.e,, quantities
which can l>e directly measured off against each other. All other
assignments of dimension are based on some relations between
physical quantities which we believe are particularly fundamental.
Because of the fundamental nature of the velocity of light we may
certainly relate distance, xr and time, f, through the relation x = ct
if we like, and hence measure distance and time in the same units.
This is in effect what the astronomers do when they measure dis¬
tances in light years*
To set 1i = c = 1 leads to clear and simple and esthetically ap¬
pealing formulas, and we will sometimes take advantage of this
possibility. The author was strongly tempted to set H — c = 1
consistently throughout the book; it would really be the right thing
to do* To take this step might, on the other hand, cause the reader
needless difficulties in reading other introductory books on quan¬
tum physics, since almost all such books are based on the conven¬
tional MKS or cgs systems. For this reason we will mostly adhere
to the conventions of the cgs system of units.
13 Let us now explore some relations between various physical
t Outside the United States this unit is also written GeV.

Sec. 2.14 Magnitude# of Physical Quantities SI
quantities which arise because of the existence of the distinguished

constants c and H. We consider a mass, my and associate with this
mass a number of other physical quantities constructed from mt
ft, and c, and we give the conventional physical dimensions of these
quantities.
m = [mass] = [time]-1
n
me = [momentum] (13a)
me2 = [energy] - — [length]

me
The reader should check that the physical dimensions (with the
conventions of the cgs system) are correctly stated* All these quan¬
tities “hang together1* through the constants h and c. Based on
the above relations an energy can be associated with a mass or a
frequency or an inverse length, and the magnitude of the energy
can be expressed in terms of the magnitudes of the associated
quantities*
14 With an energy E we thus associate the frequency E/h> the

wave number E/(hc), and the mass E/c2. We find the following
conversion factors:
(m2) = <a31478 ± 0.00005) X 10* (eV)/(anm) (14a)
= (2.41804 ± 0.00002)
(energy)
X 1014 (cycles/sec)/(eV) (14b)
(wave number)
= (8.06573 ± 0.00008) x 10^ (cm-1)/(eV) (14c)
(energy)
The table on the inside of the back cover of this book is partly
based on the above conversion factors. Each horizontal row shows
a set ,of corresponding quantities associated with the quantity in the
first column. The second and the third columns give the energy E
in eV and ergs. The seventh column gives the corresponding mass
E/c2, in atomic mass units, amu; the eighth column the correspond¬
ing frequency E/h, in cycles/sec; and the ninth column gives the
wave number E/(hc)} in cm^1. The tenth column gives the asso¬
ciated wavelength (hc)/E, in Angstrom-units, and this is the only
quantity in the table which is not directly proportional to E.
52 Magnitudes of Physical Quantities Sec* 2.15
15 In chemistry the units calorie, abbreviated cal, and kilocalorie,

abbreviated Col, or kcal, are commonly used to express an energy,
(The calorie is often called **small calorie*9 and the kilocalorie called
“large calorie,”) These units are defined by
I keal = 1000 cal, 1 cal - 4.186 joule = 4,186 X 107 erg (15a)
It is of interest to relate an energy E which refers to a single atom,

or molecule, to the corresponding bulk energy Ebuik* of No of these
particles: i.e„ the energy associated with one gram-atom* or one
mole. We then have
= Xo = 23,050 (cal)/(eV)
= 9.6487 X 10" (erg)/(eV) (15b)
In the table on the inside of the back cover the fourth and fifth
columns give bulk energies in erg/mol and cal/mol.
16 In Secs. 31-34, Chap. 1, we briefly discussed the concepts of

heat and temperature. We noted that Boltzmann s constant k is in
effect a conversion factor from temperature to energy. It is in fact
common practice to express a temperature in terms of the corres¬
ponding energy, and vice versa, where the correspondence is
defined, ariritrarily, by
(equivalent energy) = k X (temperature) (16a)
For the purpose of such a conversion it is convenient to express

Boltzmanns constant in the form
it = 8.617 x 10-5 (eV)/ 6K, ^ =Il,605°K/(eV) (16b)
In this correspondence “room temperature * (= 20flC = 293DK)

is equivalent to the energy
k X 2935 K (1/40) eV (16c)
The sixth column in the table on the inside of the back cover
gives the equivalent temperature, in Kelvin degrees.
17 That energy and temperature can be expressed in the same

units should not lead anybody to believe that energy and tempera*
ture are the "same thing." It is, for instance* not true that the
thermal energy of an arbitrary macroscopic body at a temperature
T equals the number of atoms in the body times kT. The internal
energy of a macroscopic body depends not only on the temperature*
Sec. 2.18 Magnitudes of Physical Quantities S3
but also on other (macroscopic) parameters, and furthermore the

precise relation between energy and temperature depends on the
nature of the system. This is an important point, and the formula
(16a) must not be misinterpreted.
However, we can make a highly useful statement. It is often the
case (but not always), that if a macroscopic body is kept at a tem¬
perature T> then the average "disorganized” energy per atom (or
molecule), of the body is of the order of kT,
This statement enables us to estimate the mean energy of an
atom, or molecule, in disorganized thermal motion once we know
the temperature. For many special systems we can make precise
statements. An important example concerns a gas of molecules at
the temperature T. The average kinetic energy Etr associated with
the translational motion of a molecule is given by
Etr = |*T (17a)
and this relation holds irrespective of whether the molecules are

monatomic or not. The derivation of this formula is a problem of
statistical mechanics, and we postpone it to the next volume* We
shall make occasional use of this result, even though we have not
derived it yet.
18 As we have said before, the concepts of heat and temperature

are not relevant when we consider isolated nuclei, atoms or mole¬
cules: these concepts apply to matter in bulk. However, we can in
general not carry out our measurements on isolated particles: we
have to observe these particles embedded in macroscopic quantities
of matter* The disorganized thermal motion is therefore often an
important factor to take into consideration when we wish to under¬
stand the behavior of quantum-mechanical systems, and in partic¬
ular when we study macroscopic manifestations of quantum phe¬
nomena.
The important feature of the thermal motion in a system is that
it is, from our standpoint, a random motion. It introduces an ap¬
parent element of chance in the behavior of the system, as observed
by us. We can say that the thermal random motion is "noise in the
symphony of pure quantum mechanics." And we can add that
often the noise is so loud that the music cannot be heard. In
principle the thermal motion could be suppressed by keeping the
system under study, and its surroundings, at a temperature in the
immediate neighborhood of 0°K, because the thermal motion
ceases at absolute zero. In practice this cannot be done; the
thermal motion is an essential feature of the world we live in.
The Energy Spectrum of Physical Phenomena
,V0E E/h Efk ch!E
joule cycles
eV erg cm
mol sec
E5 ftIO'11 —5 ; /
E7 E-1024 5 -3 Mass of a-particle
“3 z5 -3 E7 z5
-2 3 Mass of deuteron
-2 5
-3 2 F 7irt-13
=-1014 ■3 10 Mass of nucleon
—IQ9 13
E7 —7 h-2 1—10
-10" 3 7** 2
-5 Z5 3 Mass of X-meson
E7 a
-3 -5 -3 5
V 3 Energy released in fission
-2 -3 -2 o 7
2 Mass of pion
-2 13 tîo“13
—10B 10 Mass of muon
-7 H -101*
E7 -10“4 7 2
-5 -5 3
E7 tio“ 5
-3 =5 -3 5
Binding energy of a-particle
3
-2 -3 ~2 5 7
2
-2 h3 10
10 12
'
-107 1-1011 Approximate binding energy per nucleon in nuclei

E7
v* — 10_S E
“3
7V
7 2
Energy of a-particle from Ra22fl
s* =7 5 3
e -3 -5 -3 Binding energy of deuteron
tr
3 ■5
-2 -3 -2 5 Energy released in beta-decay of Brfl0
2
=-10*
-2 — 10U 10
Fur10. 1 MeV
E7 E7 Pi t-10
— 10“* t= t 2 Mass of electron (positron)
E7 klO 20 t 5 3
-3 -5 -3 **
-2 3 1 ;> Energy of gamma quantum emitted by In114 isomer
-2 ”3 2 E7 A
-2 — 1010 Ei ^10“9
n -103 =7 2 1-10*
E7 -10“' :7 2 Kor line (X-ray) from tungsten
% -5 -5
=7 -1019 5 3
-3 -5 -3 E7 3 5 Energy released in beta-decay of tritium
-2 -2 -5
1 -3 ■2 ^ 110
7
ft- s
B —104 -2 -3 I Angstrom unit
-109
'
tfl ”7 =7 2 1—108
■2
-
i-io-* :7 Ka line (X-ray) from copper

S' -5
-3 -3
-1018
“7
5 3
3 ■5
-2
o “2 -3 2 Approximate temperature at the center of the sun
-2 “3
-IQ'1 —108 2 I— 10T
“7
-5
kl0“9 -7
_
“a
v ;7 2
E7 -1017 ;5 ■3
-3 Z5 -3 E7 Ka line (X-ray) from carbon
-2 3
-2 -3 5
-2
-2 3 EL-V6
-10* -107 E2 b~10
6 Energy required for complete ionization of helium atom
=7 -10 E7 2
—5
-10 ’5 is 7
E7 -10 ;5 3
p*
-3 ^5 -3 — j
5 Ionization potential of helium
-2 3
-2 “3 =5
1 2 F-7 -5 (ionization potential of hydrogen)
£ -2 -3 ^10 5
D —101 —106 Ultraviolet line in mercury
= 7 -11 E7 -2 -10s
_ — 10 2
~ oV Z5 7 Fermi energy in silver
Visible -3
-7
-3
— 10 15 E5 3 Binding energy of Ha molecule
Z5 -7
light -2 -2 -5 3 11 y57 Blue line emitted by mercury
-3 2
^2 -3 —10“4 V^— (Yellow) sodium D line
“10° -105
Red line emitted by cadmium
Characteristic energies of physical phenomena. The
selected data on this page and the next are presented
to give the reader a general idea of typical energies for
various phenomena. The energies are expressed in
several commonly used units; see Secs. 14-16 for an
explanation.
E E N0E Elk Elk ch/E
DK cm
R-t (ionization potential of hydrogen)

Ultraviolet line in mercury
Fermi energy in silver
Binding energy of H5 molecule
Blue line emitted by mercury
(Yellow) sodium D line
Red line emitted by cadmium
Heat of vaporization for ethyl alcohol
Vibrational frequency of CO molecule
Debye temperature in diamond
Heat of melting for copper
Infrared
Curie temperature of iron
"‘Room temperature"’ (20ftC)

Vibrational frequency of Csl molecule
Far infrared
Debye temperature in lead
Boiling point of hydrogen

Heat of vaporization of helium
Temperature at which lead becomes superconducting
Boiling point of helium (He4)
Microwaves
Lambda point of helium

Interaction energy of two Bohr magnetons
separated by 1 A
Superconducting transition temperature for cadmium
Hyperfine transition in cesium
Rotational frequency observed in the IC1 molecule
21-cm hydrogen line (hyperfine transition)

Short radio waves
Bohr magneton in 100 gauss
Interaction energy of Bohr magneton and nuclear

Medium radio waves
magneton separated by 1 A
Precession frequency of proton in 1000 gauss
Nuclear magneton in 1000 gauss

Magnitudes Characteristic of
Atomic and Molecular Physics
19 Consider the atom as a dynamical system consisting of a nu¬

cleus, very small in size, surrounded by a cloud of electrons. The
electrons are attracted by the nucleus, and they interact mutually,
through electromagnetic forces. The belief that the electromag¬
netic forces are the only forces of importance in determining the
structure of atoms and molecules is based on the comparison
between theory and experiment which has been carried out to date.
The quantum theory of the interaction of charged particles with
the electromagnetic field is known as quantum electrodynamics.
This theory, which incorporates the Principle of Special Relativity,
is presently our most successful theory of fundamental processes
involving elementary particles. It is the theory within which we
are to describe the structure of atoms and molecules and the emis¬
sion and absorption of electromagnetic radiation by these objects.
20 Experimentally the order of magnitude of the size of a nucleus

is about 10-13 cm, whereas the size of an atom is about 10-8 cm.
The nucleus is thus very small compared to an atom.
The mass of a nucleus is large compared to the mass of an elec¬
tron, which is 0.0005486 amu, the ratio of the electron mass to the
proton mass being
m 1 (20a)
1836
It is therefore reasonable to expect that, at least in a first approx¬

imation, the motion of the nucleus does not play an essential role,
and in this approximation we may regard the nucleus as being
“infinitely” heavy, and hence fixed in space. Since the nucleus is
furthermore very small we make the further approximation that it
is a “point”: it plays no other role than to provide an electrostatic
field described by the potential
(20b)
r
where e is the elementary charge and Z is the atomic number.

The problem of atomic theory, in the first approximation, is thus
to study the motion of the electrons in this electrostatic field, taking
into account the mutual electrostatic repulsions between the elec¬
trons as well. The reader should be reminded that when, we speak
of “motion” we mean motion in the sense of quantum mechanics.
We will explain later precisely what that means.
21 Quantum electrodynamics in a restricted sense is concerned

with the interactions of electrons with the electromagnetic field.
Let us consider the relevant physical quantities in this theory,
namely the mass of the electron, m; the charge of the electron, — e;
the velocity of light c\ and Planck's constant H. From the constants
rra, cs and H we may form natural units of quantum electrodynamics,
as explained in Sec. 13: thus m is the unit of mass, me1 the unit of
energy, H/mc the unit of distance, and ftfmc2 the unit of time.
Furthermore H is the unit of angular momentum, and c the natural
unit of velocity*
So far we have not considered the elementary charge e. This
constant plays the role of a coupling constant; it tells us how
strongly the electrons are coupled to the electromagnetic field, t
We try to form a dimensionless quantity which measures the
strength of this coupling, and we consider the electrostatic energy
of repulsion, in the natural units introduced above, of ttoo electrons
separated by a distance of one natural unit This quantity is
denoted by ot and we obtain
_ e2f{Hfmc) _ e2
a (me'2} He
= (7.29720 ± 0.00003) X 10-3 ^ 1/137 (21a)(
This constant a plays a fundamental role in atomic physics and

it is known as the fine structure constant* It may be regarded as
the square of the elementary charge in natural units, and it describes
the magnitude of this charge in a manner independent of any arbi¬
trary macroscopic physical standards. That ot is numerically quite
small reflects a basic "weakness” of the electromagnetic inter¬
actions; the electrostatic eneqjy of two electrons placed at a unit
distance apart is small compared to the rest energy of an electron.
The fine structure constant is one of the truly fundamental con¬
stants of nature, and at present it is a purely empirical constant in
the sense that we have no theoretical understanding of its magni¬
tude. It might just as well have "turned out” to be large, in which
case the world would look very different indeed. In fact, unimag¬
inably different.
t This is a common mode of expression. It would, however, be more profound to say

that the coupling constant tells us how strongly elementary charges interact with each
other. The electromagnetic field is, after all, a mental construct introduced for the
purpose of discussing interactions between charges.
J This expression for a applies in the cgs system of units. In the MKS system we
have: ot = e2/{4ne^He).
58 Magnitudes of Physical Quantities Sec. 2*22
The reader should note, by inspection of Eq* (21a), that the mass
of the electron does not enter into the expression for a. Conse¬
quently a is the coupling constant which describes the coupling of
any elementary particle carrying the elementary charge e to the
electromagnetic field*
In Table 21A we list some important quantities which we can
form from m, f£, c, and et and we give the names under which these
quantities are known.
22 In Sec. 51, Chap. 1, we discussed one aspect of Bohr s semi-

classical theory of the hydrogen atom, namely the size of this atom,
and we stated that the constant o<>, defined in Eq. (51c) in that
chapter, is a typical atomic size. The reader will note that this
constant known as the first Bohr radius (in the hydrogen atom),
is the same as the one given in Table 21 A, In the discussion in
Chap, 1 oq stood for the radius of a circular orbit of the electron in
the planetary model of the atom, and hence the name. In the
quantum-mechanical discussion of the hydrogen atom this constant
has a different interpretation: 1/au is the average of 1/r in the
ground state of the atom, where r is the distance between the elec¬
tron and the proton. In either case aq can be regarded as the
“typical” distance between the electron and the proton.
TABLE 21A More Physical Constants

23 Let us continue with the seiniclassical discussion of Chap. 1
and try to estimate the binding energy of the electron in the hydro¬
Rest energy of the electron: gen atom. For an electron moving with velocity o (and hence
momentum p — int>) at a distance r from the proton, the total
me2 = (0.511006 ± 0.000002) MeV
energy E is given by
Compton wavelength of the electron:
(23a)
*, = — = (3.86144 ± 0.00003) X 10-11 cm
mr.
For a circular orbit, of radius r = n0, the condition for dynamical
First Bohr radius:
equilibrium reads
M'L
do = — = a-1
2
me* mo2 _ (23b)

= (5.29167 =t 0.00002) X 10-* cm
do «o2
Non relativistic ionization potential of hydrogen
with infinite proton mass: and combining this equation with equation (23a) we obtain
= icfcnr* - (13.6053 ± 0.0002) eV E = i(*L)-* = -f-= - ±a*nu* - -fi* (23c)

2 \flo / «o 2flo 2
Rydberg constant for infinite pro ton mass:
The energy of the electron in this orbit is thus “R®, or about
= R n/hc —13*6 eV. This energy should be compared with the total energy
4^t£Iq
when the electron is infinitely far away from the proton and at rest;
= (109737.31 i: 0.01) cm-1
by inspection of equation (23a) we see that this eneigy equals zero*
Therefore, to remove the electron completely from the circular

orbit considered we have to supply an energy Rx to the atom.
This energy is called the ionization energy. The ionization energy,
expressed as the equivalent wave number, is known as the Rydberg
constant, We denote it by Rx.f
It so happens, and in principle we should regard this as an
“accident/' that this simple estimate based on the otherwise not
very convincing planetary model gives precisely the same ionization
energy as the rigorous quantum-mechanical theory, and R& is
therefore the ionization energy of hydrogen, or, differently stated,
—Roo Is the ground state energy of the hydrogen atom.
It is furthermore the case that the ionization energies of all atoms
(i.e., the work required to remove one electron from the atom) is
roughly of the order of 10 eV; we will return to this question later.
24 Let us see how the weakness of the electromagnetic forces,

i.e., the smallness of the coupling constant a, manifests itself in the
structure of the hydrogen atom. If the coupling constant were of
order unity, then we would expect the size of the atom to be of the
order of the natural unit of length in quantum electrodynamics, i.e.,
the Compton wavelength — fi/mc. The coupling constant is,
however, “small" (a ^ 1/137), and the Coulomb field of the nucleus
is therefore unable to keep the electron confined within a Compton
wavelength. The orbit of the electron is large in the natural
quantum-electrodynamical unit, namely of radius a<> = Ae/a.
We find the velocity of the electron in the orbit by solving Eq.
(23b) for v:
The velocity is thus 137 times smaller than the natural unit,
which is the velocity of light c. This is the a posteriori justification
for our nonrelativistic discussion of this problem.
The kinetic energy, and the potential energy, Epot, are
given by
Arnold Sommerfeld. Born 1868, in Kbnigsberg, Ger¬
Ekin = imv2 = £m(ac)2 = R*> (24b) many (now Kaliningrad, USSR); died 1951. For many
years professor of physics at the University of Munich.
Epot =—— = £ — £jdn = —2R„ = -2Ekia (24c) Sommerfeld made important contributions in the
Qq development of quantum physics, and in particular in
early atomic theory. He refined Bohr’s theory in two
On the basis of these considerations we can say that the hydro- ways: to include elliptical orbits, and to take special
relativity into account. His relativistic theory of the
hydrogen atom introduced the fine structure constant
f The subscript oc in 7?* and refers to the model in which the proton is infinitely into physics. (Photograph by courtesy of Professor
heavy and stays fixed. The actual ionization energy is slightly smaller. L B. Loeb, Berkeley.)
60 Magnitudes of Physical Quantities Sea 2,25
gen atom is a loosely bound extended structure. The reader

should think very carefully about this and about the role which the
fine structure constant a plays in the theory of the atom.
25 Since the velocity of the electron turned out to be small in our

semiclassical description it is reasonable to expect that it is possible
to describe the atom within a nonrelativistic version of quantum
mechanics. In such a theory the velocity of light should play no
role if we regard the constants tn9 and e as the basic constants.
In particular it should be possible to express the Bohr radius a0 and
the ionization energy in terms of these constants only. This is
in fact the case, and we find
and
_ e2 _ e4m
■ia2ntc2 (25b)
2 " 2<io “ 2
The velocity of light does not appear in the extreme right-hand

side of these expressions. Furthermore the length flo is the only
length, and the energy R*> the only energy, which we can form
from the constants m, fi, and a We can therefore argue that since
these constants are the ingredients of the nonrelativistic quantum-
mechanical theory (which is so far unknown to the reader), every
length computed within the theory must be a numerical multiple
of do, and similarly every energy must be a numerical multiple of
Rx. (Numerical multiple here means a number independent of
the three constants. We expect that in a reasonable theory such
numbers will be “of the order of unity.")
26 The reader probably feels that these “derivations" are quite

outrageous. What value can there be in an argument based on the
Bohr model, which we have earlier declared to be quite wrong?
And how seriously are we to take the “dimensional argument in
the preceding section? Could it not happen that the constant of
order unity," which gives the correct energy in terms of Roo> in fact
turns out to be something like 4711, or maybe (2tt)-4? Such con¬
stants would obviously make quite a bit of difference in our
estimate.
The answer is that it could very well happen, but the experienced
author knows that it actually does not happen; the constant is
equal to unity. About “simple derivations” of this kind, which
occur frequently in physics texts, the cynic can always remark that
.
Sec 2.26 Magnitudes of Physical Quantities 61
the arguments seem to work out particularly well in all the cases in
which either the experimental results or the results of a more com¬
plete theory are known.
In defense of what has been done we say the following: (i) we
wish to form a picture of the orders of magnitude in atomic and
molecular physics. Instead of just telling the reader that the ioniza¬
tion energy of hydrogen is 13.6 eV we should try to relate this 13.6
eV to expressions formed from the basic constants. It is nice to
know that 13.6 eV equals a2 me2/2, and it is nice to know that
0.53 A equals (1/a) (ft/mc). Our discussion of quantum electro¬
Energy Wave number Wavelength
dynamics and its relevance to the hydrogen atom gives us at least eV cm'1 A
some understanding of how it all might hang together. The author
would certainly not have presented these ideas if they did not have
H 40000 2500
their counterparts in the precise theory. Our “derivations” are
therefore at least useful as mnemotechnic devices.
(ii) The Bohr theory is admittedly wrong. On the other hand the h- 35000
I— 3000
reader undoubtedly knows that it was successful in some instances, r 4-0
although it faded badly in other cases. In a vague sense the theory
\- 30000
therefore has some elements of truth in it. It introduces Planck’s f- 3300 Fraunhofer
Uqqi
constant into physics and thereby introduces a relation between >--* Ultraviolet
position and momentum which does not occur at all in a purely _/ * <Ga)
\- 23000 — 'if (Ca)
~h (h) Violet
classical theory: something like rp — #. We can take the point of
—-G (Ca}
view that our derivation based on the Bohr theory was really in Blue
- 4500
essence an experimentation with a relation of this kind: rp
Later we will play with this relation in a different way, and we will h 2.5 I— 20000
1' - y (H) j 1
— 5000
. Ch (Mg)
discuss a method of estimating the size and ionization energy of E‘ <Fe)
, Green
Maximum
the hydrogen atom on the basis of the uncertainty relation. At the — 5500
visibility
Yellow
same time we will gain a much better understanding of why the — 6000
-D <N»)
2.0 Orange
hydrogen atom does not collapse. -
— 10 6500 — t; <H)
(hi) The dimensional argument in Sec. 25 would be much more Bed
convincing in connection with a serious study of a definite equation

— 1.8 t 15000
=- 7000
■— B
a
(O)
(H,0) Infrared
— 1.7
for the quantum mechanical description of the hydrogen atom, such E- 7500 A CO)
— 1.0 K 13000
as the so-called Schrodinger equation. Without actually solving - z ■ 8000
- 1.5
this equation we could quite easily conclude that numbers such as I- 6500
4711 or (2t7)-4 will not occur. To draw a conclusion of this kind \— 11000
we must, of course, have some experience with the nature of solu¬
tions of differential equations. (The Schrodinger equation is a The spectral neighborhood of visible light. The Fraun¬
differential equation.) Dimensional arguments work best when hofer lines are prominent absorption lines (dark lines)
they are tempered by a good understanding of the general features in the solar spectrum. The left column gives the old
of a theory. letter designations of these lines, and the right column
Our simple dimensional argument is an introduction to argu¬ the chemical symbol identifying the atom or molecule
causing the absorption.
ments of this kind. The reader has been told that a “good” theory The assignment of colors to the various spectral
exists; what can this theory be expected to give us? That is the regions is, of course, only approximate. Mote the
question we have asked and answered. point of maximum visibility at about 5500 A.
27 Let us now continue with our discussion of atomic physics,

and let us try to obtain a rough understanding of the structure of
heavy atoms, i*e*, for the case when the atomic number Z is large.
The reader has undoubtedly heard that the electron cloud around
such a nucleus has a sheD structure in some sense, and we will try
to base our discussion on this idea. Let us imagine that we build
up the atom by starting from the bare nucleus and then adding one
electron at a time. How tightly will the first electron be bound?
The expression for the energy of the system now takes the form
(27a)
and a moment’s reflection shows us that the discussion for the case
of the hydrogen atom still applies, provided we replace the fine
structure constant or by aZ, In other words, the first electron will
he bound at an energy
e, = -Z*Rk = — Z2 (13.6 eV) (27b)
and at a 1‘distance” from the nucleus of
For large Z, this distance is small compared to the Bohr radius in

hydrogen, oq. The next electron added will also be bound at a
small distance, and the binding energy will be large compared to
the ionization energy of hydrogen; the electrostatic force of repul¬
sion between the two electrons is clearly Z times smaller than the
force of attraction to the nucleus* Let us consider the appearance
of the ion after we have added a few electrons. These electrons
will all be bound within a small distance of the nucleus, and if there
are n of these electrons the ion will present the appearance of a
“nucleus” of charge (Z — n)e beyond the distance at which the
electrons are bound* The next electron will therefore necessarily
also be tightly bound unless (Z — n) is small, but it will be less
Fig. 27A Graph showing ionization potentials of tightly bound than the first electron. We may thus imagine that
atoms versus atomic number. The ionization potem the successive electrons will be less and less tightly bound, and after
tial is the energy necessary to remove one electron
we have added (Z — 1) electrons the ion appears like a cloud of
from the neutral atom. We see that this energy is
roughly of the same order of magnitude for all atoms* charge of magnitude e, and of a size comparable to the Bohr radius
i.e. of the order of 10 eV, Oo* The binding energy of the last electron added will therefore be
The reader who has some familiarity with chemistry of the order of fl«, and thus of the order of ten electron volts. The
will at once notice that there is a marked correlation final size of the atom will be of the order of the Bohr radius a$.
between the magnitude of the ionization potential and
the chemical properties of the element. The ioniza¬
tion potential is particularly large for the noble gases, 28 This picture is certainly very rough. Note that we have
and particularly small for the alkali metals. neither proved, nor even made plausible, the idea that the electron
cloud has a *‘shell structure/’ Our discussion was, however, based

on that idea; we “built up” the atom in a particular way.
Now it is a fact that to really understand the structure of atoms
we must observe a fundamental principle of physics which we have
not mentioned so far and which is entirely foreign to classical
physics. This principle is known as the exclusion principle. It says
that no two electrons can ever be in the same state of motion in an
atom. The electrons “avoid” each other. (This “avoidance” is
something quite different from the Coulomb repulsion of two
similarly charged particles. To really understand the meaning of
the exclusion principle requires a knowledge of quantum me¬
chanics.) The exclusion principle is the key to the explanation of
atomic structure. It has profound consequences, and the world
would be unimaginably different if it were not observed by nature.
That this is so is most certainly not obvious at this stage.
The exclusion principle was discovered by Wolfgang Pauli in 1924
from a consideration of the empirical facts of atomic physics as
they were known at that time.!
29 Our discussion is therefore very defective, but it nevertheless

gives us some kind of picture of the nature of heavy atoms. It
follows from this picture that transitions in the state of motion of
the outermost or optical electrons will involve energies of the order
of an electron volt, which roughly corresponds to wavelengths of
the emitted photons in the optical region, i.e., in the energy range
1.8-3.0 eV, or the wavelength range 7000-4000 A. Transitions
involving the innermost electrons on the other hand correspond to
comparatively much larger energies, ranging up to 70 keV Wolfgang Pauli, Born 1900 in Vienna, Austria: died
1958. After finishing his PhD dissertation in 1921
(= 70,000 eV), which correspond to wavelengths down to 0.2 A.
Pauli spent some time at the University of Gottingen,
These photons lie in the far ultraviolet or X-ray region. The and at Bohr's Institute in Copenhagen. In 1928 he
dependence of these transition energies on the atomic number Z accepted the chair in theoretical physics at the Insti¬
is shown by formula (27b). tute of Technology (ETH) in Zurich, Switzerland. He
We note that the atom, which has a typical size of 1 A, is small received the Nobel prize in 1945,
Pauli was one of the most outstanding theoretical
compared to the wavelength of optical photons. This circumstance
physicists of this century. He made important contri
is a consequence of the smallness of the coupling constant a, and buttons in many areas, ranging from atomic structure
to see this we apply the following considerations: to the theory of quantum fields and elementary parti¬
The binding energy of an optical electron is of the order of cles. Pauli's work was characterized by a deep phys¬
ct2mc2. The transition energies characteristic of the optical elec¬ ical insight, as well as by great mathematical skill, and
he was known (and feared) as a stern critic of obscure
trons are of the same order of magnitude; they could certainly not
thinking. His discovery of the exclusion principle, and
be larger. The transition of one of the outermost electrons be¬ of the connection between spin and statistics, are
tween two quasi-stationary states is associated with the emission perhaps his most famous achievements, (Photo¬
graph by courtesy of Physics Today.)
f W, Pauli, “Ober den Zusammenhang des Abschlusses der Elektronengmppen im

Atom mit der Komplexstmktur der Spektren," Xeitschrift fur Physik 31, 765 (1925).
G4 Magnitudes of Physical Quantities Sec. 2.30
or absorption of a photon of an energy equal to the energy differ¬

ence between the two levels, and the corresponding wavelength
of this photon will therefore be of the order of
ZttHc
zz 1000 GO (29a)
a2mc2 a
which explains the order of magnitude of the ratio of wavelength

to size of the atom.
30 We have now gained a considerable understanding of the

relevant orders of magnitude in the realm of atomic physics. Let
us try to say something about molecules. The crucial problem here
is to understand the molecular binding; why do atoms sometimes
form stable molecules and other times do not? To really under¬
stand these questions requires much more sophisticated methods
than the ones we have used for atoms. Nevertheless we may try
to answer a small part of the general question, and we may ask;
Granted that atoms do form stable molecules in some cases, what
is the characteristic binding energy and what is the characteristic
separation of two atoms in a molecule?
Let us consider the simplest case, namely a hydrogen molecule,
which is a bound state of two protons and two electrons. We try
to estimate the binding energy and the intemudear distance
through a dimensional argument; our argument thus concerns those
favorable cases in which binding does occur, as in the hydrogen
molecule.
Since the proton is so much heavier than the electron, the motion
of the protons will again not play an essential role in the deter¬
mination of the ground state of the hydrogen molecule. In a first
approximation one may in fact regard the two protons as stationary,
at a fixed separation d, and these two protons are then surrounded
by the “cloud” of the two electrons. We imagine that we find
the ground state energy of the two electrons, as a function of the
inte [proton separation d. For a certain value of d this energy will
assume its smallest value, and at this energy we have a stable mole¬
cule. Our problem is nonrelativistic, and since the protons are
regarded as infinitely heavy we only have the constants m, and e
available. The only “natural” energy is then ft*, and the only
"natural” distance is the Bohr radius flo- These quantities should
thus be characteristic of the molecule. A more careful study con¬
firms this expectation, which is also in agreement with the experi¬
mental facts. The actual binding energy of the hydrogen molecule
is about 4.5 eV, and the average separation of the two protons is
about 0.75 A. These values are quite typical for molecules in TABLE 3€A Characteristics of Somewhat
general; molecular binding energies are of the order of 1-10 eV, Randomly Selected Diatomic Molecules
and the intemuclear separations are of the order of one Angstrom
Distance
unit, i.e., of the order of 10-8 cm. Dissociation
between
The same “mechanism” which holds a molecule together also Molecule Energy
holds solids together, and the typical separation between two Nuclei
eV
neighboring atoms in a solid is also of the order of 1 A. A
AgH 1.62 2.5

31 These estimates now provide us with an understanding of the BaO 1.94 4.7
magnitude of the energy released or absorbed in a chemical reac¬ B r2 2.28 1,97
CaO ; 1.82 5.9
tion. The elementary process in a chemical reaction is that two
H2 1 0.75 4.5
or more different molecules collide and form one or more new HCI | 1.27 4.4
molecules. The energy associated with this rearrangement of the HF 0.92 6.4
atoms into new molecules must be of the order of typical molecular HgH 1.74 0.38
binding energies and hence of the order of 1-10 electron volts per KCI 2.79 4.42
elementary process. The bulk reaction energies are therefore of N, 1.09 9.76
0, 1.20 5.08
the order of (1-10) X A/b electron volts/mol, or roughly 20,000-
200,000 cal/mol. As an example we may consider the burning of
hydrogen gas in an atmosphere of chlorine, according to the
reaction
H2 + CI2 = 2HC1 + (44,000 calories) (31a)
The order of magnitude is in accordance with our estimate.
32 There is an amusing feature about our macroscopic units

which is worth a comment. We have said that the units cm, gm,
and sec refer to human characteristics, and we are therefore not
surprised that these units are not particularly suited to the discus¬
sion of atoms. One macroscopic unit seems, however, to be in a
special position: namely the volt as a unit of potential in that the
derived unit electron volt is “just right for atoms.” Is this an
accident?
The answer is no* Originally the unit volt was chosen such that
the EMF of voltaic cells would be of the order of a volt. In fact
the EMF of a certain cadmium-mercury standard cell is very dose
to one volt. We know that the operation of such a cell is based
on an electrochemical reaction taking place in the cell, and for
every electron leaving the terminal of the battery, one elementary
chemical process must have taken place. For every elementary
chemical process an energy of, say, X eV is released, and this
energy may be converted into mechanical or thermal energy out¬
side the battery. If the EMF of the battery is U we must have
Ue = JC, and, since by the choice of the unit volt, 17 is of the order
of a volt it follows that the typical electrochemical reaction energy

is of the order of one electron volt. This explains the mystery of
the suitability of the electron volt as a unit of energy in atomic
and molecular physics; the volt is in fact an “atomic unit”l
The Moat Baste Facts of Nuclear Physics
33 The building blocks of nuclei are protons and neutrons.

Protons and neutrons have many important physical properties in
common, and they are often regarded as two different charge states
of a “single” particle called the nucleon. The nucleon thus occurs
in two versions: the charged version, which is the proton and the
neutral version, which is the neutron.!
The number A of nucleons in a nucleus is the mass numlter or
nttcleon number. The number Z of protons is known as the charge
number, or, when we speak of the corresponding atom, as the
atomic number.
The masses of the proton and neutron are
.Yfp = (1.00727663 ± 0.00000008) amu

= (938.256 ± 0.005) MeV/c* (33a)
Mtt = (1.00866,54 ± 0.0000004) amu
= (939.550 ± 0.005) MeV/c* (33b)
Consider a nucleus of mass number A and charge number Z.

I jet its mass be .Yf(A,Z). The quantity
A(A,Z) = (ZM„ + (A - Z)Mn) - M(A,Z) (33c)
is called the mass defect of the nucleus. This quantity is positive,

which circumstance has a simple interpretation: the quantity
A(A,Z)r2 equals the binding energy of the nucleus, or the energy
which has to be supplied to break up the nucleus completely into
its elementary constituents, i.e., into protons and neutrons.
It is an empirical fact that the binding energy per nucleon is
roughly the same for all stable nuclei, i.e.,
Â’Z)c2 8 MeV (33d)

A
There are some marked exceptions among the very light nuclei,
and there is also a slight systematic decrease of the average binding
energy as the mass number A increases, as we see in Fig* 33a,
t The neutron was discovered by Chadwick in 1932, [J, Chadwick, The Existence
of a Neutron," Proceedings of the Royal Society (London), sex. A, 136, 692 (1932),]
Fig* 33A Graph showing the binding energy per

nucleon, &{A>Z)c2/A> versus the mass number A,
The dots refer to particular nuclei, some of which are
identified. The irregularities occurring for the very
lightest nuclei are not well represented by the smooth
graph, but for A > 25 the curve is an accurate repre
sentation of the facts.
The binding energy per nucleon is roughly 8 MeVk
As the mass number increases, the binding energy per
nucleon slowly decreases. This systematic trend is a
consequence of the electrostatic energy of repulsion
of the protons within the nucleus.
34 The reader should note that the mass values listed in most
tables of “nuclear” masses actually refer to the masses of the cor¬
responding neutral atoms* If Atf(A,Z) is the mass of a nucleus, and
M(A,Z) the mass of the corresponding atom, we have
fl(A,Z) = M(A,Z) + Zm - B(Z) (34a)
where m is the electronic mass, and where the positive quantity

B(Z) expresses the binding energy of all the electrons in the atom.
When we consider the energy balance in a nuclear reaction, it
will in most cases make no difference whether we use the true
nuclear masses, or the associated atomic masses, because the con¬
tributions from the electron masses cancel if we use the latter.
The binding energy B(Z) is very small compared with the nuclear
binding energy of 8 MeV per nucleon, and it can almost always
be neglected.
The reason why the atomic masses are listed instead of the
nuclear masses is that the atomic masses can be measured more
readily. Through deflection experiments in combined electric and
magnetic fields with an instrument developed specifically for this
purpose, called the mass spectrograph, we can determine the ratios
of charge to mass for ions. This work was initiated by J, J, Thomson
and F> Aston, and it has led to a precise knowledge of a large num¬
ber of atomic masses, f
fF< W, Aston, "Isotopes and Atomic Weights,7' Nature 105, 617 (1920). Also
F. W. Aston, Mass Spectra and Isotopes (Edward Arnold and Company, London. 1942).
Figs* 34A-B A mass spectrometer intended for the

analysis of small samples of noble gases from stony
meteorites. Here the purpose is not to measure ac¬
curate values of atomic masses, but to determine
relative abundances of the isotopes of the element
(xenon) as it occurs in the meteorite. The data ob¬
tained can be used to estimate the age of the mete¬
orite, which is of great interest in our attempts to
understand the origin and development of the solar
system. For a description of this work, see J. H.
Reynolds, “The age of the elements in the solar sys¬
tem," Scientific American 203, 171 (Nov. 1960).
A photograph of the instrument is shown above, and
the principle of operation can be understood with
reference to the drawing below. The noble gas sam¬
ple, which is admitted at left into the evacuated glass
envelope, is ionized by electron bombardment in the
ion source. The ions are accelerated, and deflected
by the magnet in the middle. (The pole pieces and
coils of the magnet can be seen in the middle of the
photograph.) Different isotopes are deflected by differ¬
ent amounts, and by varying the magnetic field
strength the current passing through the collector slit
at right can be measured for each isotope in turn.
The abundance of the isotope is, of course, propor¬
tional to the current. The magnetic field is wedge-
shaped in order to achieve partial focusing of the ion
beams, (/fiustrat/ons by courtesy of Prof. J. D.
Reynolds, Berkeley.)
The mass spectrograph can also be used to determine the abun¬

dances of the different isotopes in a naturally occurring chemical
element, and once these abundances are known we can obtain
information about “nuclear'* masses from the chemical atomic
weights.
Finally we obtain information about nuclear masses from a study
of the kinematics of nuclear reactions.
35 The ratio Z/A of charge number to mass number shows a

systematic trend as a function of the mass number A, For not too
heavy nuclei, say for A less than 50, this ratio is close to As A
grows larger the ratio decreases slowly; for the uranium isotope
92U238 it has the value Z/A = 0.39. For very small A we again
meet with irregularities; hydrogen, for instance, has three isotopes,
iH1, jH2 (deuterium), and iH3 (tritium).
Some nuclei are stable, whereas other nuclei are unstable and
decay through the emission of particles or gamma rays. The com¬
monly occurring nuclei are either absolutely stable or else have
very long lifetimes; if this were not so they would have decayed
at some early stage in the history of the earth and would no longer
be present. Nuclei formed in nuclear reactions may have very
short lifetimes, of the order of a small fraction of a second. When
the lifetime is very short we often speak of an excited state of a
nucleus, especially if the decay takes place through the emission
of a gamma ray, in which case A and Z remain unchanged.
At present about 900 nuclei are known, of which about 280 are
stable. If we plot these nuclei on a (ZA)-plane, then the points
representing the individual nuclei tend to cluster along a smooth
curve, in accordance with what was said before. (See Fig. 35a.)
The more removed a nucleus is from the "central curve" the more
unstable it tends to be.
36 It has been found experimentally that a nucleus has a quite

well-defined size and that it may be regarded as a sphere of nuclear
matter of radius
r = roA1/3 where ro = 1.2 X 10^13 cm = 1.2 fermi (36a)
(The unit fermi = 10~13 cm, named in honor of Enrico Fermi, is Fig. 34C Mass spectrum recorded with the appara¬
often employed as a unit of length in elementary particle physics.) tus shown in Figs. 34A-B, for xenon extracted from a
stony meteorite. Graph is taken from J. H. Reynolds,
Since the volume of the nucleus is proportional to r3, and hence,
"Determination of the age of the elements/' Physical
by formula (36a), to the nucleon number A, we conclude that the Review Letters 4,8 (I960). The short horizontal bars
density of nuclear matter in the different nuclei is approximately show the isotopic abundances for terrestial samples
constant. of xenon. As we can see, the meteorite sample is
The sizes of the nuclei, as summarized by the fonnula (36a), richer in the isotope Xelzs. Note that the graph is
drawn in two different vertical scales. (Courtesy of
have been determined from a variety of experiments.! The most Physical Review Letters,)
straightforward method consists in the measurement of the effec¬
tive cross-sectional area which a nucleus presents to a beam of
very-high-energy particles in a scattering experiment.
37 Let us now try to say something about the nature of the forces
which hold a nucleus together. All our experimental evidence
says that
(i) The nuclear force is not electromagnetic in nature; compared
with the electromagnetic forces the nuclear forces are much
stronger.
(ii) Hie nuclear force is of short range; when the separation
t R, Hofstadter, “Structure of Nuclei and Nucleons” (Nobel address). Science 136,

1013 (1962).
.
Fig 35A The stable and almost stable nudei. All
known nudei having half-fives greater than 5 x 10™
years are shown. This somewhat arbitrary lower
limit on half-life was chosen because it is about ten
times the estimated age of the solar system, and the
included nuclei are thus long-lived even on a geological
time scale. In this graph (consisting of two parts)
the ordinate is the neutron number (A — Z) and the
abscissa is the atomic number Z, It is at once appar¬
ent that the nuclei cluster about a smooth curve. For
the light nudei the number of protons is about equal
to the number of neutrons, but as the atomic number
increases the neutron number increases faster.
The steplike appearance of the pattern of nuclei
derives from the fact that the stability of a nucleus
depends on whether the number of protons and the
number of neutrons are even or odd, as follows: even-
even nudei are most stable, even-odd (and odd-even)
nudei are less stable, and odd-odd nuclei are most
unstable. The reader should study the graph care¬
fully to see how these rules manifest themselves.
There are very few odd-odd nudei on the graph. For
some neutron numbers, and some proton numbers
there are “gaps” corresponding to the absence of
stable nuclei. Note that these always occur when the
neutron or proton number is odd.
between two nucleons exceeds 10™12 cm the specific nuclear force

becomes insignificant,
(iii) The specific nuclear force between two protons is the same
as that between two neutrons. The nuclear force between two
protons is furthermore of the same nature as the nuclear
force between a proton and a neutron; we may say that they
are actually the same, although this statement does require some
qualification.
The evidence for these three statements comes from scattering
experiments as well as from the systematic study of stable or radio¬
active nuclei and their systems of energy levels. In particular the
statement about the short range of the nuclear force can be verified
as follows, We bombard a nucleus with protons accelerated to
high energy in an accelerator, and we study the scattering of the
protons from the nucleus. When the proton is far away from the
nucleus (i.e., beyond 10™11 — 10™12 cm), the only effective force
is the Coulomb repulsion. This repulsion prevents the proton
from approaching the nucleus closely enough for the nuclear force
to become effective unless the energy of the proton is very high.
If the statement about the short range holds we expect that protons
(or alpha-particles, as in Rutherford's experiment) of not too high
energy will scatter as though the Coulomb repulsion were the only
force present. We may thus test the statement (ii) through a
detailed analysis of scattering experiments, and the conclusion is
as stated.
Since the protons are charged they can also be acted upon by
electromagnetic forces, and two protons in a nucleus will certainly Enrico Fermi. Born 1901 in Rome; died 1954. He
exert a Coulomb repulsion on each other. At distances much received his doctorate in 1922 from the Scuola Nor-
male Superiore at Pisa, Italy. In 1926 he became pro¬
larger than 10™12 cm the electromagnetic forces are for all practical fessor of theoretical physics at the University of Rome.
purposes the only forces acting, but for smaller distances the nu¬ Fermi left Italy in 1938. and after holding a professor¬
clear force dominates. Electromagnetic forces do play a role for ship at Columbia University he went to the University
nuclear structure, but they do not play a dominant role. of Chicago in 1942, where he remained until his death.
He received the Nobel prize in 1938.
In this connection it should be stated very explicitly that elec¬
Fermi's contributions to physics cover an amazingly
trons seem to be completely unaffected by the specific nuclear wide range and no short summary can do justice to his
forces; the only significant forces acting on electrons are the work. From his early work we can mention his inven¬
electromagnetic forces. tion of the so-called Fermi-Dirac statistics of particles
(at the same time, and independently of Dirac who did
similar work), and his very successful quantitative
theory of beta-decay. His main work was in the fields
38 Let us elalxjrate a bit on the fact that the strong nuclear force of nuclear and elementary particle physics. Among
the many topics he studied we can mention artificial
is a short-range force. According to our present beliefs the general
radioactivity, slow neutrons, nuclear fission and chain
nature of this force, effective between two nucleons, is reasonably reactions, and the pion-nucleon interaction. Fermi
well represented by a potential function t/(r) of the form was one of the very few physicists who have done
outstanding work both in theory and in experiment.
U(r) zz C (£) exp (- j) (38a) (Photograph by courtesy of Professor E. Segre,
Berkeley.)
provided that the separation r is larger than 10“13 cm,t The con¬
stant b is a measure of the range of the force; it has the value
b = 1-4 X 10-13 cm. The constant C expresses the strength of
the force. The nature of the force at distances smaller than
10-13 cm is much more complicated and very poorly understood
at present.
We emphasize that the potential function l/(r) does not describe
the interaction between two nucleons precisely, but it does repre¬
sent the most important feature of this interaction which is that
the potential falls off exponentially with distance,
Let us see what this really means. At the distance r = b we have
U(b) = C/e. (This constant is roughly of the order of 10 MeV,)
At the distance r = 10b — 1,4 X 10~12 cm the potential equals
U(10b) = (0.1C) exp ( —10) 5 X 10_6C. At the distance
r — 100b = 1,4 X 10“11 cm the potential equals U(100b) —
(0*01C) X exp ( — 100) ^ 10*45C. We can oonclude from this
numerical exercise that when the separation between the two
nudeons exceeds 10~n cm, then the nuclear force is utterly negli¬
gible, For all practical purposes there is no nuclear force beyond
the distance quoted.
The reader should think carefully about this. At first sight the
expression (38a) might resemble the Coulomb potential. However,
the exponential factor makes all the difference in the world. Our
numerical exercise was intended to impress the reader with this
fact.
The specific nuclear force between nuclei in molecules and solids
is thus nonexistent for all practical purposes, and this is the kind
of situation in which the electromagnetic forces have a chance to
play a dominant role. At smaU distances, r — 10~13 cm, the specific
nuclear force is considerably stronger than the electromagnetic
forces, and the latter are relegated to play a secondary role. That
this is the case is immediately obvious from the fact that nuclei
exist. The electrostatic forces of repulsion try to disperse the
charged partides in a nucleus, but the nuclear forces try to keep
them together, and the nuclear forces win; they are stronger,
39 Since the typical binding energy of a nucleus is of the order

of 8 MeV per nucleon, we can expect that transmutations of nuclei
will involve eneigies roughly of the order of 1 MeV, The energies
with which material particles and photons (gamma rays) are emitted
from nuclei do in fact range typically from, say, 100 keV to 10 MeV.
t In Chap. 9 we shall present a theoretical explanation for this form of the potential
function.
Sec♦ 2,40 Magnitudes of Physical Quantities 73
The energies involved in nuclear reactions are therefore of an

entirely different order of magnitude than the energies involved
in chemical reactions, and we can readily understand why nuclei
are not affected by chemical processes. From the standpoint of
chemistry and atomic physics, nuclei are just small, hard, massive,
indivisible, charged spheres.
In our discussion of atoms we concluded that the wavelength
of an optical photon is large compared to the size of the atom.
It is worth noting that the situation is similar in nuclear physics.
Consider a gamma ray of energy 1 MeV, which is a typical nuclear
transition energy* The corresponding wavelength is 1.2 X 10-10
cm = 1200 fermi, and it is thus large compared with the typical
nuclear size*
Gravitational and Electromagnetic Forces
40 We should now explain why we neglect gravitational forces

in our discussion of atoms, molecules, and nuclei. For this purpose
we compute the ratio of the gravitational force to the electrostatic
force between two protons. This ratio is independent of the dis¬
tance between the two protons, and we find
M*Gfr* M 2G
= 8.1 X 10~37 (40a)
eVr2 e2
where we have inserted the value G = 6.67 x 10-8 dyne cm2

gm-2 for the constant of gravitation.
The ratio of the strengths of the two forces is thus very, very
small, and in the presence of electromagnetic interactions we ex*
pect the effects of gravitation to be completely negligible. Grav¬
itational forces can play a role only if all other known forces are
ineffective, hence only between (large) electrically neutral bodies
separated by distances large compared to the typical atomic
distances.
Einstein's Theory of General Relativity is a purely geometric
theory of gravitation. It is a theory of great beauty and internal
coherence* In spite of many attempts by Einstein and others it
has not been possible, to date, to incorporate the other forces of
nature in a natural way into this theory. The phenomenon of grav¬
itation therefore stands quite apart from the interactions which
govern the structure of matter on the microscopic scale; gravity
appears to be totally irrelevant to microphysics, which is the reason
why gravitation is neglected in this book. The reader should note
that the ratio given in equation (40a) is nothing but the ratio of the
74 Magnitudes of Physical Quantities Sec. 2A1
gravitational constant in natural microscopic units to the fine struc¬

ture constant. We have no place for a number of such small size in
our present theories of quantum physics. We can perhaps hope
that sometime in the future a connecting link may be found between
the apparently unconnected subjects of microphysics and gravita¬
tion, but at present we have no hints of how the gap might be
bridged.
41 Let us now consider the strength of the electrostatic field at a

distance of a Bohr radius aa from a proton. Since ao is of the order
of 10-s cm, and since the electrostatic potential energy of the
electron in the hydrogen atom is of the order of 10 eV, we see that
this field is of the order of 1011 volts/meter, or precisely
Emom = 5*14 X ion volts/meter (41a)
Compared with the strongest macroscopically realizable electro¬

static fields, which are of the order of magnitude of 107 volts/meter,
this is a very strong field. We conclude, first of all, that the effects
of external electric fields which we can produce in the laboratory
will be small on atoms and molecules and completely negligible on
nuclei. Nevertheless the effects are observable; an electric field
will split each of the spectral lines of an atom into several lines of
approximately the same frequency. This phenomenon is known as
the Stark effect
The circumstance that the electrostatic fields acting on the
electrons in an atom are large compared with the electrostatic
fields which can be realized macroscopically in the laboratory can
be readily understood as follows. It is an important feature of the
electrostatic field (as described by Maxwell's equations) that if such
a field is maintained in any empty region in space, then the field
strength must assume its largest value at some point on the con¬
ductors. The conductors are, however, built of atoms, and if the
field strength on the conductor should become comparable to the
field strength holding the atoms together then the conductor would
begin to disintegrate. The estimate (41a) is therefore an absolute
upper limit on realizable macroscopic electrostatic fields; in actual
practice electrical breakdown occurs long before this upper limit
is achieved.
42 Similar considerations apply to macroscopic magnetostatic

fields. The fields which we can realize in the laboratory must
necessarily be weak in the sense that their effect on the structure of
atoms cannot be very marked. A magnetic field also produces a
splitting of a spectral line into several components. This phenom¬
enon is known as the Zeeman effect
To set an upper limit on realizable magnetic fields we may deter¬

mine the magnetic field which produces the same energy density
as an electric field of the order of 1011 volts/meter; this magnetic
field is of the order of 107 gauss. Steady magnetic fields of strength
up to 50,000 gauss can be produced easily in the laboratory, and
fields in the neighborhood of 106 gauss can be produced for short
time intervals. Consideration of the stresses on the current-
carrying conductors which produce the fields, and which must not
exceed the limits set by the forces holding the atoms and solids
together, tells us that we cannot possibly produce static fields in
excess of 107 gauss,
43 If we look upon the strength of macroscopic fields from the

standpoint of natural field strengths in quantum electrodynamics,
we can conclude that even the electric fields in the atoms are very
weak. We might define the natural unit of field strength (electric
or magnetic) as the field which produces an energy density in space
of (one electron rest energy)/(Compton wavelength of the elec¬
tron)5. This unit of electric field strength is equal to 4.0 X 1017
volts/meter and the corresponding unit for the magnetic field is
equal to L3 X 1013 gauss. The theory of quantum electrodynamics
predicts marked deviations from Maxwell's equations in the vacuum
at these field strengths. In particular the principle of superposition
no longer holds, and the electromagnetic fields cannot be described
by linear equations* Actually quantum electrodynamics also
predicts very small deviations from linearity at the very weak
fields which can be realized in the laboratory. These deviations
are, however, so fantastically small that they are of no practical
importance macroscopically, and in fact they have not been de¬
tected in macroscopic experiments to date. The smallness of the
macroscopic fields when measured in natural units, which ulti¬
mately can be traced back to the smallness of the fine structure
constant a, provides us with a certain understanding of why the
linear Maxwell equations are so accurate in practice.
Concerning Numerical Work
44 Let us say something about the numerical evaluation of a

theoretical expression for some physical quantity. The reader may
feel that nothing need be said about this subject; numerical work is
a necessary evil (especially in homework problems), and we learn
no physics from such arithmetical exercises* This is not quite true.
There are ^bad” numerical evaluations and there are ‘‘good”
numerical evaluations. To carry out a good numerical evaluation
requires physical insight. Let us consider an example to show the

difference between "good” and "bad” work. In the study of the
finer details of the spectrum of the hydrogen atom it is found that
the spectral lines, which in a measurement of poor resolution appear
to be single, upon higher resolution actually consist of several very
closely spaced lines. We say that the spectrum has a fine structure.
In the theoretical study on fine structure we encounter an energy,
£/, which characterizes the typical separation between two of these
closely spaced lines, and this energy is given theoretically by the
expression
P _ e*m
1 ~ 32*V2
Now it would definitely be “bad” to evaluate Ef by inserting the

values of the constants occurring in the expression (44a) directly
from Table 2A. First of all it would be very tedious since we have
to compute ^ and tf4. Secondly, the formula (44a) is very untrans¬
parent; before we have carried out the computation we cannot
“see" what the magnitude of this energy is, and the expression as
it stands shows us nothing about the physical nature of the effect.
Suppose, however, that we first group the constants in Eq* (44a)
into factors which have a recognizable significance as follows:
e, = M£c ”*’) = Ti°2 (laW!) = f4*)

If we look at the expression to the extreme right we see that the
magnitude of the fine structure separation Ef is now quite trans¬
parent; it is a small correction to the gross structure of relative order
of about 10“5, If we wish to compute the energy Ef in electron
volts the computation is now simple; we have to multiply 13.6 eV
by the constant a2/16. It is, therefore, clear that the grouping of
the factors, as in Eq. (44b), leads to a simplification of the purely
numerical work. However, the expression (44b) also gives us some
insight into the nature of the effect. In a purely nonrelativistic
theoretical treatment of the hydrogen atom (in the approximation
of an infinite proton mass), and with the neglect of effects due to
the intrinsic magnetic moment of the electron, there would be no
fine structure. To see this we have to remember that in such a
theory only the constants e, m, and -fi, but not c, can appear. The
ionization energy is in fact independent of c. The fine structure
constant, which appears in the expression for Eft is, however, in¬
versely proportional to c, and in the nonrelativistic appproximation,
Sec. 2AS Magnitudes of Physical Quantities 77
In which c = oo, we obtain Ef = 0. We may, therefore, regard Ef

as a relativistic correction to the gross structure. We then expect
that the magnitude of this correction should be of the order of
(v/c)2Rw where v is the velocity of the electron* We have esti¬
mated the velocity v, and we have found that {vfc) — a and hence
we are led to an expression like the one in (44b), The fine structure
in hydrogen is therefore a relativistic effect*
45 The name "fine structure constant” for the constant a arose

historically in connection with SommerfekTs work on the fine
structure of hydrogen; the constant a was first recognized as an
important constant just in the expression (44b). At the time when
Bohr presented his theory of the hydrogen spectrum it did not
appear natural to write the hydrogen ionization energy fi* in the
form
R^ = ^ct2mc2 (45a)
as we have written it. It was rather written as
_ e*m
R TO (45b)
~ 2W
and for this reason a was not called the “gross structure constant,”
which would be more appropriate. The expression (45a) must be
regarded as a "better” expression for as it gives us a much better
insight into the nature of atoms. As we have explained, a is the
fundamental coupling constant between the electromagnetic field
and the elementary charge. Atoms are "loosely bound structures,”
with “slowly” moving electrons, because ot is small compared to
unity. For this reason a nonrelativistic theory leads to a good
approximation. The relativistic corrections are of the order of
(vfc)2t hence of order a2.
46 We hope that this example shows something of the spirit in

which numerical work should be approached. We always try to
recognize physically significant combinations of the constants in
our expressions, and we carry out a grouping of the factors, or
terms, before we evaluate anything numerically. This grouping
clearly requires insight; unless we understand the nature of the
phenomenon we cannot do it in a natural and meaningful way.
Our homework problems in this book are not intended to be
merely exercises in arithmetic. They are intended to familiarize
the reader with the orders of magnitude of quantum physics, and
they are intended to teach the reader how to apply the ideas dis¬
cussed in the text to concrete physical situations*
78 Magnitudes of Physical Quantities Sec. 2A7
Advanced Topic; The Fundamental Constants of Nature t
47 Let us speculate about the following interesting question: How

many independent fundamental constants of nature are there
really?
The idea behind this question is as follows. Our present physical
theories imply definite relationships between the parameters char¬
acterizing physical systems. The ionization energy of hydrogen,
for example, can be expressed theoretically in terms of the constants
m, e, and h, or, if we like, in terms of the constants m, c, and a.
If we already know the constants m, et and h, we can predict the
ionization potential, and then check our theory by comparing the
prediction with the experimental result. In the same sense a very
large number of other physical parameters are “understood theoret¬
ically": they can be expressed in terms of a few fundamental
constants.
The phrase “understood theoretically" should here be interpreted
in a very generous sense. We regard a constant as understood
theoretically whenever we can formulate a definite equation which
in principle determines the constant, irrespective of whether our
limited mathematical abilities actually suffice for the computation
of the numerical value of the constant.
Our classification of physical parameters into fundamental con¬
stants and derived constants is in principle quite arbitrary. In
practice we pick as our fundamental constants those parameters
which occur in a particularly “simple" way in our equations, and
which have a reasonably transparent physical interpretation. It is
clearly more reasonable to regard the fine structure constant as a
fundamental constant, and the ionization energy of hydrogen as a
derived constant, than to reverse the status of these two parameters.
A set of independent fundamental constants is thus a set of
suitably selected physical parameters which are not related to each
other theoretically. We have no understanding of their numerical
magnitudes: each one of these constants must be determined em¬
pirically. Our question is concerned with the maximum number
of independent constants, i.e», with the number of constants that
must be known before all other physical parameters can be com¬
puted (predicted).
It is clear that our question makes sense only with reference to
our present physical theories. A constant declared to be purely
empirical today might be "explained” tomorrow, within the frame¬
work of a new theory.
| Can be omitted in a first reading.

Sec- 2*45 Magnitudes of Physical Quantities 79
48 To explore the situation at present, let us try to list a number

of fundamental constants:
(i) The fine structure constant:
(ii) The ratio of the electron mass to the proton mass:
8 =
H Mp 1836
(iii) The constant of gravitation in natural atomic units:
= 5 902 xl0—3,
(MpC2)
(iv) A constant which characterizes the strength of the so-called

weak interactions, which are responsible for the beta-decay of
many nuclei. According to our present beliefs the weak inter¬
actions have nothing to do with the strong nuclear force, electro¬
magnetism, or gravity. All phenomena involving weak interactions
seem to be manifestations of a fundamental (universal) interaction
in nature, characterized by one single coupling constant- The
strength of this interaction is about 10”14 times smaller than the
strength of the nuclear force.
(v) The ratio m/m^ 1/200, of the electron mass to the muon
mass. The muon (or mu-meson), is an elementary particle which
does not seem to differ from an electron in any other way than in
its larger mass. The role of the muon in the scheme of things is
almost completely unknown*
(vi) Finally, we need some constants which describe the strong
interactions, which in particular include the strong nuclear forces.
The theoretical situation is very unclear, and we do not know how
many independent constants there are in this category. We may
consider the following two:
(mass of the pi-meson)
0.15
(mass of the proton)
= tFs
Mpc1
= 135 X 10-3
where B& = 2,23 MeV is the binding energy of the deuteron.

We have arbitrarily picked the constant $2* because of its imme¬
diate physical significance, as one possible constant to describe the
strength of the nuclear force. There is nothing very fundamental
about this number, but we can imagine that it does give us a
measure of the strength of the force. In other words, we believe

that all other nuclear binding energies can, in principle, be ex¬
pressed in terms of S2 and In this case we really have to take
an extremely generous view of what we mean by "understanding
things theoretically.” We do not know, in this case* what the
“correct equation” is* and our pious hope that such an equation,
involving only sq and s2, exists* may be totally unfounded
The truth is that at the time of this writing we cannot really
compute the ratios of the masses of such particles as the K-mesons,
the nucleons, the lambda-particle, etc. We do not have a funda¬
mental theory for doing this, and we should, perhaps, add all these
mass ratios to our list. On the other hand, it is possible that a
theory may one day emerge through which we can compute the
masses of some, or maybe all, of the strongly interacting particles.
According to the most extremely optimistic view the "correct”
theory will be such that strong interaction physics will contain no
empirical constant; everything will be computed, including the
numbers st and At this time, however, the question of the
number of constants characterizing the strong interactions must
be regarded as completely open,
49 We have not included in our list a very remarkable empirically

determined constant, namely the ratio of the charge of the electron
to the charge of the proton. According to an experiment per¬
formed by J. G. King in 1960, this ratio equals -1 to an accuracy
of one part in IO20, King similarly measured the ratio of the charge
of the helium nucleus to the charge of the proton and found that
this ratio equals 2, to a similar accuracy, t These results strongly
support the idea that the charge of any particle must be an integral
multiple of the electronic charge. There is much evidence in favor
of this idea, although this evidence is, in most cases, not as stringent
as in King's measurements. Physicists have, in fact* believed in
the "quantization of charge” for a long time. There is, however,
no theoretical understanding of why all charges should be integral
multiples of the electronic charge.
Why, then, did we not include the constant ( — 1 ± 10” z0) in
our list? Because our theories are such that we would find it very
upsetting if this constant is not actually equal to —1. We can
calmly contemplate the possibility that the constants actually in¬
cluded in the list would be slightly different; they are empirical
t We are here stating a reasonable inference. What King actually did was to estab¬
lish that the hydrogen molecule and the helium atom aTe neutral to the stated accuracy,
[J. G. King, “Search for a small charge carried hy molecules," Physteal Review Letters
5, 562 (1900)0
constants in just this sense. It would not upset quantum electro¬

dynamics if the fine structure constant were one per cent larger;
our laws of nature, as we know them, would not have to be changed
in any essential point. The situation is different with regard to the
quantization of charge; the structure of our theory depends on this
principle.
50 Quantum electrodynamics, as a theory of atoms, molecules,

and matter in bulk in essence contains only two fundamental em¬
pirical constants, namely a and 0 = m/Mp. What we mean by
this statement is that we believe that we know, in principle, the
dependence of all physical quantities in this realm of physics on
these two constants. Properties of the different atomic nuclei enter
only through the integers Z and A, and the other physical charac¬
teristics of nuclei have only a “small” effect on atoms, molecules,
and matter in bulk.
Our statement is, therefore, a simplification of the true situation,
but it is interesting to pursue this idea. At first sight it may appear
wrong, since the number of “fundamental constants” listed in
Table 2A is certainly larger than two. It should be noted, how¬
ever, that the constants listed are based on completely arbitrary
units {human units) and that their numerical values have no abso¬
lute significance at all.
In trying to understand the properties of matter in bulk it is
therefore essential that we distinguish between the fundamental
physical quantities and those that depend on our arbitrary units.
Consider for instance the velocity of sound in a crystal. To ask
for this velocity in cm/sec is not a “fundamental” question because
the answer depends on the arbitrary definition of cm and sec. Hie
most clear-cut theoretical question is to ask for the ratio of the
velocity of sound, cs, to the velocity of light; this quantity is clearly
independent of all macroscopic standards. We believe firmly that
this number is, in principle, computable within quantum electro¬
dynamics.
51 To understand the true meaning of the constants listed in

Table 2A let us consider the definitions of our macroscopic system
of units.
The kilogram has been defined, through international agreement,
as the mass of a certain chunk of metal kept in Paris. To indicate
that we mean just this chunk we shall denote the unit by (kg)p,
the “Paris kilogram.” The gram is defined as (gm)p = (kg)p/1000.
This chunk of metal contains a certain number of nucleons, say
ni nucleons. The precise value of ni is unknown, but we could
determine it in principle by counting. If we now assume that we
can compute, within nuclear physics, and within the theory of

strong interaction the ratio of every nuclear mass to the proton
mass, then we can write the mass of the chunk in Paris in the form
(kg)/> = niCiAfp = (51a)
where c\ is a constant, close to unity, which we determine through

our computation* Strictly speaking it does depend on a and fi,
but only weakly. The number «i, although not known precisely,
is a numerical constant selected through international agreement;
it is the number of nucleons in the chunk*
52 For the meter there exist, or rather have existed, two stand¬
ards. In the old standard the meter is the distance between two
notches on a certain metal rod kept in Paris; we shall denote this
meter by (m)P, the “Paris meter.” The new standard is “atomic”
in nature, and the corresponding meter, which we denote (m)fl,
the “atomic meter,” is defined as a certain multiple of the wave¬
length of a definite orange line in the spectrum of krypton, the
multiple being n2 = 1,650,763*73, by international agreement*
The wavelength of the orange krypton line is something which
we can compute in principle (but not in practice), and we can write
this wavelength in the form
\ = can-* ^ (52a)
w
where c2 is a constant which depends only very weakly on a and /?*
In a first approximation it is a purely numerical constant, and if
we should master the mathematics of atomic physics we could find
this number*
The atomic meter can thus be written
(m)* = n2c2a”2 f—) (52b)

\mef
53 The adoption of an “atomic standard” of time seems immi¬

nent, although the second is presently defined astronomically. Let
us, however, get ahead of history and assume that the atomic
standard has been adopted and thr.t the second has been defined
in terms of a certain transition frequency in the cesium atom which
lies in the radio-frequency region. This frequency, which can be
interpreted as the precession frequency of the spin of the cesium
nucleus in the field of the orbital electrons, has been measured very
accurately and found to have the value (in terms of the astronom¬
ical second)
— = vq = 9,192,631,770 zt 10 cycles/sec (53a)

!o
The precision of this number is characteristic of the precision

which can be achieved in radio-frequency measurements. The
theoretical expression for this frequency is of the form (according
to quantum electrodynamics)
*o = c3a (53b)
where c3 is a numerical constant almost independent of or and /?;

it can be evaluated in principle but not in practice, provided we
are given certain data concerning the cesium nucleus. Suppose,
therefore, that we define the second, denoted (sec)fl, or the “atomic
second,” as follows:
(sec)a = (9,192,631,770)7-0 = (53c)

\mcy
where Tq is the period of this atomic oscillation, and where the

number «3 = 9,192,631,770 is thus determined through inter*
national agreement,
54 Consider finally the old standard of length, the Paris meter

(m)p. It is defined as the distance between two notches on a metal
rod, and it is therefore equal to the length of a certain string of
atoms. The number, of atoms in this string is, in a sense, deter¬
mined by international agreement (although the number is not
accurately known), since is the number of atoms between the
two notches. The separation between two neighboring atoms in
the metal rod is something which we can compute in principle;
this separation is of the form £400, where oq is the Bohr radius, and
where C4 is a constant which depends only very weakly on a and /?,
To remind the reader that the spacing between atoms
We can therefore write the Paris meter in the form in any solid is of the order of the Bohr radius oo. The
above figure shows the crystal structure of cesium
(m)p — n^câ- chloride. This Kind of lattice is called a body-centered
cubic lattice. We can describe it by saying that the
chlorine atoms form a cubical lattice, with one cesium
This standard of length has been abandoned for obvious tech¬
atom at the center of each cube. Notice that this
nical reasons; the separation between the two notches is a poorly structure is different from the one of sodium chloride,
defined quantity* Two optical wavelengths can be compared with shown in Fig. 30A, Chap. 1.
greater accuracy, and there is then no reason why we should try The chemical formula for cesium chloride is CsCI,
to express these wavelengths in terms of the length of the metal rod. and the lattice contains an equal number of cesium
and chlorine atoms. The reader should convince him-
self that this is implied by the figure, although it
55 Our discussion shows the true nature of the macroscopic might at first sight seem as if there were more chlorine
standards. They are defined in terms of somewhat arbitrarily se- atoms than cesium atoms in the lattice.
84 Magnitudes of Physical Quantities Sec* 2*56
lected “atomic parameters,” and in terms of the numbers ni, *12,

and n3 which are selected through international agreement. (As
we said fit is actually not accurately known; it is defined implicitly,)
We note the following:
(i) To measure an optical wavelength amounts to comparing this
wavelength with the wavelength of the orange krypton line. This
can be done very accurately, and for this reason optical wave¬
lengths are accurately known quantities. The Rydberg constant
R, is in essence an optical wave number, and that is why this con¬
stant is known with such accuracy. Our most accurate length
measurements are nothing but measurements of ratios of optical
wavelengths. These data have potential theoretical significance;
if we could master the theory of atomic spectra sufficiently well
to enable us to predict these wavelength ratios to a comparable
accuracy, we could carry out meaningful comparisons between
theory and experiment. Our computational abilities are, however
very limited, and for this reason the actual theoretical significance
of the wavelength measurements is limited,
(ii) Two frequencies in the radio-frequency region can be com¬
pared very accurately. If we measure an atomic or molecular
frequency in this region we, in effect, compare it with the cesium
frequency.
(jil) To measure the velocity of light amounts to comparing the
frequency associated with the orange krypton line with the cesium
frequency, it is, therefore, not a measurement of a “fundamental
physical constant,” but rather an evaluation of our arbitrary stan¬
dard of length in terms of our arbitrary standard of time,
56 Consider the expressions (51a), (52b), (53c) and (54a). They

give us theoretical expressions for the macroscopic standards in
terms of (i) the numbers ni, n3, and n4, determined through
international agreement; (ii) the basic standards m, h/mc9 and
fi/mc2 of quantum electrodynamics; and (iii) the quantities Ci, c%,
03, and c4, which we believe we can compute in principle.
Even if we cannot compute the quantities ci, c2, 03, and c4 accu¬
rately in practice, we know that they are, to a first approximation,
just purely numerical parameters, independent of a and j8. If we
could really compute these numbers it would mean that we could
compute the value of the velocity of light, in units of (m)fl/(sec)a.
Our theoretical expressions for the macroscopic standards enable
us to deal with the following question: What would the world be
like if our constants of nature were slightly different? This means:
what would the world look like if the two empirical constants a
and were slightly different? This is an interesting question be-
Sec* 2*57 Magnitudes of Physical Quantities 85
cause it tests our understanding of the role of a and fi in the world*

We leave it to the reader to speculate about this question; he should
return to this problem after he has finished reading this book*
102H Woman
57 Suppose we ask the question, why is the size of an atom of
the order of 10-10 meters; why are atoms as small as they are?
This sounds like a metaphysical question, but it really is not* Sup¬
pose we reformulate the question as follows; why is the linear size io-l Cute animal
of a human about 1010 ao? That is what the question amounts to,
because the meter was so defined that the linear size of a human
is about a meter* We can answer this question roughly if we can
n Ladybug
explain the number of atoms in a human, and this problem is not
in principle beyond the reach of physics* It would be absurd to cm
try to compute this number precisely, but we ought to be able to
estimate it to within a factor of, say, 106. (If we knew more about 10_1 J Flea
biology and related subjects, that is.) We leave these frivolous
speculations to the reader. We mentioned this issue only to illus¬
trate how all the properties of the macroscopic world we live in
ultimately depend on the properties of the elementary particles w io"M Amoeba
and their interactions*
*
References for Further Study g 10-4 Red blood cell
CA
Among extensive tables of physical constants we mention the following;

a
1) Handbook of Chemistry and Physics (Chemical Rubber Publishing Co+, Cleveland,
2
Ohio). New editions have appeared yearly. The latest editions incorporate the 10“4- Cholera bacteria
changed scale of atomic masses resulting from the selection of C1? as the new standard.
2) American Institute of Physics Handbook (McGraw-Hill Book Company, New
York, 1957).
3) For a very interesting account of the struggles of mankind in the determination 10"SH Tobacco mosaic
of the constants of physics, we recommend Cohen, Crowe and DuMond: The Funda¬ $ virus
mental Constants of Physics (Interscience Publishers, Inc+, New York, 1957).
4) For a critical survey of the fundamental constants, see E. R. Cohen and J. W, M.
DuMond: "Our Knowledge of the Fundamental Constants of Physics and Chemistry 10"M Giant molecule
in 1905,” Reviews of Modem Physics 37, 537 (1965).
5) With reference to our discussion in Sec. 57 the reader may be interested in reading;
“Gulliver was a bad biologist," by Florence Moog, Scientific American, Nov. 1948,
p, 52. 10_7H Large molecule
Problems
Atom
1 In 1903, P. Curie and Laborde studied the heat emission of radium*
They found that 1 gram of pure radium (we now know that the isotope
86 Chap. 2 Problems
asRa226 is involved) emits about 100 cal/hr. From this and from the known
half-life compute the approximate energy in MeV with which the emitted
alpha-particles emerge. In the experiment of Curie and Laborde these par-
tides were captured within the source and the calorimeter, and their kinetic
energy therefore was converted to heat energy. (The half-life is 1622 years.)
2 (a) The radium nucleus has a posttfoe mass defect, but nevertheless
it is unstable and decays. How is this possible? Is not the necessary and
sufficient condition for stability that the mass defect be positive? Explain
in detail.
(fc) The radium isotope referred to above is asRa226; this is the isotope
discovered by P. and M. Curie. It decays through the emission of alpha-
particles, which are nothing but helium nuclei, 2He4.
We might be led to believe that only stable nuclei or long-lived isotopes
occur naturally since any short-lived isotopes would have decayed in geo¬
logical times. Now, measured against the age of the earth the half-life of
1622 years is not particularly large; it is, rather, quite small How do you
then explain the natural occurrence of radium?
3 In connection with the decay of a radioactive nucleus like Ra226 we

note a remarkable circumstance; the lifetime is “unreasonably long.” Try to
form, from the fundamental constants of nuclear physics and electrodynam¬
ics, a “natural time” and find this in seconds. No matter how you play with
your constants (nicely, that is), you must admit that RaZ2a lives much too
long. Clearly here we encounter a problem which we must try to solve
later; it is actually possible to account for the observed phenomena, and the
reason for the long lifetime (or if you like, the reason for the decay) is an
interesting quantum-mechanical effect, known as the tunneling effect.
4 The sun radiates energy from its surface at the rate of 3.86 X I02fl
watts. Before the development of nuclear physics it was something of a
problem to explain where this huge amount of energy comes from. Let us
try to make some simple estimates.
The sun is believed to be at least 4 billion years old. The mass of the sun
is 1.98 x lOô kg.
(a) What fraction of the sun's mass has to be converted into radiant energy
per year in order to account for the power radiated? You will find that this
number is quite consistent with the idea that the sun has not changed much
during its lifetime, i.e., during the last 4 billion years.
(b) Rule out chemical reactions as the source of energy.
(c) Do you know of any nuclear process which might take place in the
interior of the sun, and which might provide us with the explanation of
where the energy comes from? Consult some introductory astronomy book,
Problems Magnitudes of Physical Quantities 87
and convince yourself through some simple estimates that your explanation
is plausible, or at least not in violent contradiction with the facts.
5 We have said that the density of nuclear matter, i.e,, the density of the
“substance” inside a nucleus, is roughly the same for all nuclei* Give this
density in macroscopic units, i,e*, in gm/'crn3.
6 (a) With reference to the discussion in Sec. 17, estimate the mean
energy and the mean velocity of a nitrogen molecule in nitrogen gas held
at room temperature. The nitrogen molecule consists of two nitrogen atoms,
(Give energy in eV,)
(b) Under atmospheric pressure, and at room temperature, 1 mole of
nitrogen gas (or any gas) occupies a volume of 22.4 liters. Estimate the
number of collisions that a nitrogen molecule will undergo per second, assum¬
ing that a nitrogen molecule is of “typical molecular size." Compare this
collision frequency with a typical optical frequency.
7 One of the lines in the hydrogen spectrum has the wavelength

4861,320 A. It was discovered by H. Urey in 1932 that this line has a faint
companion located at 4859.975 A [See Phys, Rev, 39, 164 (1932); 40, 1
(1932),] The explanation is that ordinary hydrogen is not isotopically pure,
but a mixture of two isotopes, iHl and iH2 = D* The atom of the heavier
isotope, deuterium, occurs only to about 0.015 percent, and this isotope is
responsible for the faint line mentioned.
In the study of the hydrogen spectrum one may, to a first approximation,
neglect the motion of the nucleus. Suppose now that we try to take the
nuclear motion into account. It is then no longer the nucleus which stays
fixed but rather the center of mass of the nucleus and the electron, A theory
which takes the nuclear motion into account therefore predicts slightly
shifted locations of the spectral lines relative to the predictions in a theory in
which the nucleus is infinitely heavy, and the amount naturally depends on
the actual mass of the nuclei is (in our case the mass of the proton or
deuteron).
Try to formulate a simple theory which explains the ratio of the two
wavelengths given* Use the two wavelengths to compute the ratio of the
deuteron mass to the proton mass, and compare your result with the ratio
which can be obtained from a table of nuclear masses.
8 Singly ionized helium, i.e,, a helium atom with one electron removed
is, like the hydrogen atom, a system consisting of a single electron moving
around a nucleus. We may therefore expect that the spectral lines emitted
by singly ionized helium are entirely analogous to the spectral lines emitted
by the hydrogen atom* The two systems are, however, not identical; the
helium nucleus carries two elementary charges whereas the hydrogen nucleus
88 Chap 2♦
Froblems
(proton) carries only one. In view of what has been said in this chapter it
should be possible to find the consequences for the spectrum of the increased
central charge in singly ionized helium as compared to hydrogen, and it
should, therefore, also be possible to predict the wavelength of any line
emitted by singly ionized helium, given the wavelength of the corresponding
line in hydrogen. In other words, it is possible, without a detailed theory of
atomic structure, to find the ratios of the corresponding wavelengths.
One of the visible hydrogen lines has the wavelength 6562.99 A. What is
file wavelength of the corresponding line emitted by singly ionized helium?
Does ttus line fie in the visible region?
We may here assume that both nuclei are infinitely heavy. This example
teaches us that primitive dimensional arguments, like the one given in Sec. 27,
can sometimes be employed to make precise, quantitative predictions.
9 Suppose an alpha-particle collides head on with a nucleus of charge

number Z and mass number A. Derive an expression for the energy, in
MeV, which the alpha-particle must have in order to just reach the surface
of the nucleus, as & function of the mass number A. For simplicity we shall
assume that the nucleus remains stationary in the collision; that A = 2Z;
and that the alpha-particle is a point charge without any size. If the alpha-
particle does not reach the surface, the short-range nuclear forces cannot
oome into play, and the collision event proceeds as if only the electrostatic
forces were effective. The energy which you have computed is, therefore,
very roughly, a characteristic energy above which the outcome of the
scattering event will begin to differ significantly from the prediction in which
only the electrostatic forces are taken into account,
10 In this problem we shall consider the electrostatic energy of repulsion

in a nucleus. Since the density of nuclear matter is roughly a constant we
will assume that a nucleus is a uniformly charged sphere. This model is
reasonable for a not too fight nucleus.
(<j) Show that for a nucleus of mass number A, and charge number Z,
the electrostatic energy V€ is given by
Ue =2 A5'3 (fV X (0.7 MeV) (i)
Let us furthermore assume that the number of neutrons equals the number
of protons, i.e.( that A = 2Z. From (i) we then obtain an expression for the
electrostatic energy per nucleon, namely
y?~A2/3 X (0.17 MeV) (ii)
This energy should be compared with the average binding energy of a

nucleon which is about $ MeV. We thus see that for a not too large A the
electrostatic energy per nucleon is quite small- It grows, however, with A,

and this circumstance provides the explanation for the systematic trend
mentioned in Sec. 33. The nature of the specific nuclear force is such that
if it were to act alone, then the most stable nuclei would have roughly the
same number of neutrons and protons. Since, however, electromagnetic
forces are also effective, the net effect of the simultaneous presence of the
two kinds of force is that nuclei with an excess of neutrons are favored, and
this tendency for neutron excess increases with mass number A.
(.h) As a check on this picture of the nucleus we consider the following.
The (unstable) fluorine Isotope 9F17 and the oxygen isolope WQ17 differ in
mass by Af(17;9) — A/(17;8) = 3.0 x 10~3 amu* We note that the first
nucleus has 9 protons and 8 neutrons whereas the second has 8 protons and
9 neutrons* We may, in other words, obtain one from the other by inter¬
changing the neutrons and the protons. We say that we have a pair of
mirror nuclei.
We maintained in the text that neutrons and protons are quite similar
physically, and if this is true we would expect the mass defects for the two
nuclei mentioned to be equal. However, the proton and the neutron do
differ in their charge, and the same can be said alxmt the two mirror nuclei.
Assuming now that the two mirror nuclei are otherwise equal, except for the
charge, we rnay try to account for the difference in mass defect on the liasis
of the electrostatic energy of repulsion. Carry out a computation to see how
well these ideas check.
11 Some of the heaviest known nuclei can decay spontaneously by fis¬

sion. In this process the nucleus splits into two approximately equal parts,
with an energy release of about 200 MeV per fission. Fission can also l>e
induced by neutron bombardment. The nucleus absorbs the incident neu¬
tron, and is left in an excited state from which it subsequently decays by
fission. The uranium isotope U-:(S is an example of a nucleus which readily
undergoes fission after neutron ahsoqrtion. Since heavy elements have an
excess of neutrons over protons compared with elements in the middle of the
periodic table, the fission process will lead to the emission of a few neutrons.
These circumstances make a chain reaction possible: neutrons emitted in
fission induce more fissionable nuclei to undergo fission, which leads to the
emission of more neutrons, etc. Nuclear reactors and the (fission) atomic
bomb work on this principle.
(c) Estimate the energy which would he released (in calories, and kilowatt-
hours) if 1 gm of U233 underwent complete fission, and compare this energy
with the energy which is released in a typical chemical reaction involving
1 gm of matter*
(b) A small chunk of U233 metal will not explode spontaneously, whereas
a large chunk will. How do you explain this?
(c) To study the origin of the energy released in fission consider, on the
90 Chap. 2 Problems
basis of the relation (i) in Prob. 10, the electrostatic energy of the nudens
(say U235) before fission and the total electrostatic eneigy of the fragments.
Obviously some of the electrostatic energy will be released* Estimate this
energy and compare with the value 200 MeV per fission.
12 The mass of two deuterium nuclei is larger than the mass of the alpha-
particle (= the nucleus 2He4). (See Table 4A for atomic masses,)
(a) Compute the energy released if 1 gm of deuterium undergoes fusion to
form helium* and compare this with the energy released in fission,
(b) Why is it that a container filled with deuterium does not explode
spontaneously?
13 Let us assume that the electron is a classical point-particle, and let us

assume that an electron in an atom moves in an orbit in a plane perpendicular
to the z-axis, and in such a way that its angular momentum is constant and
equal to A*
(a) What is the effective magnetic moment of the electron? We shall
call tliis magnetic moment one Bohr magneton.
(b) What is the difference in energy (in eV) in the two situations when a
magnetic moment of 1 Bohr magneton points in the same, and in the oppo¬
site, directions of a magnetic field of 1000 gauss?
(c) Suppose that in an iron crystal there is a magnetic moment of 1 Bohr
magneton located at the position of every atom in the crystal, and suppose
furthermore that all the magnetic moments point in the same direction* Is
the resulting magnetization similar in magnitude to the magnetization en¬
countered in a saturated ferromagnet?
We are here interested in estimating the magnitude of the magnetic
moments which we can expect to find in atoms* Our naive classical model
of atomic magnetism should not be taken too seriously. It turns out, how¬
ever, that the Bohr magneton is indeed typical for atoms. In the complete
quant uin-mechani cal discussion of atomic magnetism one recognizes two
contributions to the magnetic moment. One is due to the "orbital motion”
of the electron, and it is analogous to our classical magnetic moment, The
other is due to the spin of the electron; an electron also possesses an intrinsic
angular momentum analogous to the angular momentum of a small billiard
ball spinning around an axis passing through its center. The magnitude of
this spin angular momentum is H/2, and the corresponding magnetic moment
is very closely one Bohr magneton*
The purpose of the estimate in part (c) of the problem is to find out whether
we can hope to explain ferromagnetism in terms of magnetic moments of
atoms* The result of this estimate is encouraging. It must be mentioned,
however, that ferromagnetism is a complicated phenomenon, and our simple
estimate does not tell the whole story.
14f In Secs. 51-56 we discussed the “atomic nature” of some of our

macroscopic standards of measurement*
Suppose, then, that at present our standards have been compared and
adjusted so that (m)j> = and so that the basic atomic constants e, m, Mpt
c and H have the values given in Table 2A in terms of these standards.
Suppose furthermore that at 1 a*m., on May 30, 1988, the constants a and ft
change suddenly to
a' = «{1 + u), ft' = 0(1 + w)
and then remain constant at their new numerical values. We shall assume
that the numbers u and w are small, say of the order of 1 percent; otherwise
the change in the world order may be too drastic. This natural catastrophe
will certainly be noticed, and for some time (after recovering from the initial
shock) physicists will be busy with the re measurement of their sacred con¬
stants. Let us denote quantities after the catastrophe by primes.
(a) Find (mW(m)i.
(b) What are the new values of the mass of the electron and the mass of
the proton? [In (gm)p.]
(c) What is the new value of the velocity of light, c\ in units of (m)o/(sec)^?
(d) What is the new value li' of Planck’s constant?
(e) What is the new value of the electronic charge in electrostatic units,
and what is the new value in coulombs?
(/) What will be the density of copper [in (gm)p/ (cm3 )o] after the
catastrophe?
1 This problem refers to an advanced topic*

Chapter 3
Energy Levels
Sections I to 13 Term Schemes 94
14 to 26 The Finite Widths of Energy Levels 104
27 to 42 Further Discussion of Levels and Term Schemes 111
431« 46 Doppler Broadening and Collision Broadening
of Spectral Lines 127
47 to 56 Advanced Topic; On the Theory of Electro¬
magnetic Transitions 130
Problems 137
Chapter 3 Energy Levels
Term Schemes
4742.5 —4728.6 A.
1 The fact that each chemical element is associated with a unique
Wave¬ Ele¬ Intensities Wave¬ Ele¬
length ment Arc R length ment optical spectrum is one of the striking aspects of nature. This
*742.589 Mo 10 4737.642 Sc I feature of nature is furthermore very general: not only do atoms
4742.549 Er 3w — — 4737.626 U
4742.5 bh 5c 5 —
Me 4737.561 Pt I have characteristic spectra, but so do molecules and nuclei as well.
4742.481 Sm 3 — *+ 4737.350 Cr
4742.392 Md 4 — - 4737.282 Ce These objects emit and absorb electromagnetic radiation at certain
4742.333 \J W 3 — 4737.1 bh C
4742.325 Pr 7 — — 4737.05 Tl U definite frequencies, which range from the radio frequency region
4742.266 Th 41 2 — 4736,965 Zr (for molecules) up to the region of very short wavelength X-rays,
4742.25 So I — [600] Rd 4736.958 Sm
4742+227 5m 2 — — 4736.945 Er or gamma rays (for nuclei). Historically the optical spectra of the
4742+110 Tf I 15 1 _ 4736+9 bh 2
4742.04 Ho 10 3 Ex 4736,79 Dy elements were discovered first, by G. R* Kirchhoff and R+ Bunsen
4741.997 Er 3w — — 4736.782 Ca
4741.937 Ge 11 - 50 - 4736.780 Fe in the middle of the nineteenth century, whereas the radio-fre¬
4741.922 Sr I 30 — JSn 4736.688 Pr
quency spectra of molecules, and the gamma ray spectra of nuclei,
4741.78 Cd n 3 Vs 4736637 Me
4741.775 Eu low — — 4736.608 Eu were discovered much later, during this century*
4741.726 Sm II 80 — — 4736.6 Rt
4741,71 o u — [20] FI 4736.491 Cl We interpret the spectra in terms of energy levels of atoms,
4741.539 Dy 3 2 — 4736.490 S'
4741.533 Fe 1 12 1 S 4736.30 T molecules and nuclei. Through our study of spectra we become
4741.620 W 12 2 - 4736,203 r
4741+503 Pr 30 — - 4736.151 i aware of an extremely important property of composite systems,
4741+404 Yt I 2 3 — 4736.116
4741.396 Er 20 — - 4736.069 which is this: with each such system there is associated a set of
4741.282 U 1 2 — 4736,062 energy levels, or stationary states, characteristic of the system.
4741+269 Ru 4 — — 4735+94
4741.10 Tm 3 - Me 4735.93 We find these levels in “small” systems, such as atoms, molecules
4741.018 Sc I 1W 60 h - 4735.848
4741.005 Pr 6 - — 4735.847 and nuclei, in which cases the levels manifest themselves very
4740.97 Sc u - [600] Bi 4735.77 directly in the spectra which we observe. We also find these levels
4740.928 Dy 3 2 — 4735,76
4740.68
4740,514
Cl I
ct>
—
3
[10]
3
Ks
-
4735.66
■ 4735,4?
in “large systems,” such as solids, liquids and gases. At first it might
4740.524 Eu 500 2 — 4735.4: not occur to us that there is a relationship between the emission
4740.517 Th 20 15 — 4735.3
4740.5 bh Zr 8 — L 4735.3 and absorption of gamma rays by a nucleus, and the vibrations of
4740+40 Cl H ,- [150] Ks 4735.1
4740.359 Me 5 5 — a quartz crystal in some electronic device, but there is*
4740.331 Ru 7 —
2 In this chapter we shall study energy levels in “small” systems.

Kg. JA A very small portion ol a table of wave-
lengths: Massachusetts Institute of Technology Wave¬
We shall discuss some of the relevant experimental facts, and we
length Tables, compiled under the direction of G. R. shall try to understand some aspects of what is observed on the
Harrison (MIT Press, Cambridge, Mass,, 1939). This basis of very simple theoretical ideas. In this chapter we shall not
table, which consists of 429 pages, lists more than attempt to explain why energy levels occur, but rather accept this
100,000 spectral lines between 10,000 A and 2,000 A. feature of nature as a basic empirical fact. In Chap. 8 we shall
Each page has three columns, and the lines are listed
face the challenge of explaining the levels, and we shall see how
in order of decreasing wavelength, The chemical
element corresponding to each line is identified, and they can be understood on the basis of quantum mechanics.
some data on method of excitation and on intensities Our order of presentation is actually somewhat analogous to the
are given. historical development of the subject, in the sense that many of
It is customary to list wavelengths in the visible the features of atomic spectra discussed in this chapter had been
region as measured in air, whereas wavelengths in the
ultraviolet region refer to vacuum. In the visible
discovered long before a satisfactory theory of atomic structure
region we have approximately: AVac ~ 1.0003 A**,.. (Le+, quantum mechanics) had been created. Our account is, how¬
(Courtesy of MIT Press.) ever, not really historical. We want to discuss the empirical facts
Sec. 3.3 Energy Leveb 95
concerning energy levels more generally, and therefore we shall '■ if-
:
also discuss nuclei, although the properties of nuclei became known
only much later.
- . f ^ ■. f ■ r . . . •
3 Some remarkable regularities in atomic spectra were noticed

early. As an example we mention the Ritz combination principle,
according to which the wave numbers of many spectral lines of
an element equal differences, or sums, of wave numbers of other
pairs of lines. For instance, in a certain element f the following
lines have been observed: iq = 82258.27 cm-1; = 97491.28
cm-1, and — 15232.97 cm-1. We have v2 — vi — 15233,01
cm-1, which is so close to that we would hardly be willing to
believe that this agreement is a mere “accident,” especially not
since the same feature occurs for other lines of the same element i
at
as well as for the lines of many other elements.
A more general principle was discovered later. The wave num¬
ber V of any line emitted by an atom can be expressed as a differ¬
ence v — Tf — T" of two spectral terms T' and Tf\ Each atom is
characterized by a set of such terms (expressed as wave numbers),
known as the term system of the atom.
This principle contains the Ritz combination principle. Suppose
that three spectral lines are associated with three terms} as follows:
v 12 — Ti — 7*2? ?13 = Ti — $23 = T2 — 1$
We then have
&23 = ( 7i — T3) — (Ti — Tv) — ^13 “ $12
which is an example of the combination principle.
4 Today we interpret a spectral term as corresponding to an

energy level of the atom, and the term system is therefore inter¬
preted as a manifestation of a set of energy levels characteristic of
Fig. JB The spectrum of hydrogen. (Wavelengths
the atom in question. This idea was first formulated by Niels Bohr
in Angstroms.) The appearance of this spectrum in
in his paper on the hydrogen atom. J the visible region is at first sight not particularly
Let us consider the matter in the light of what we already know dramatic. The wavelengths of hydrogen are, how¬
about the quantum nature of electromagnetic radiation. A light ever, of very great interest. Since the hydrogen atom
quantum, or photon, of frequency v, and hence wave number is the simplest possible atom it plays the role of a
probing stone for all theories of atoms: this spectrum
v — v/c, carries the energy E — hv = (he) v. This energy is the
most be explained. That Bohr could account for these
difference between the two energies Ef = (hc)Tf and Eff — (hc)T" lines was a spectacular advance in our understanding
if the wave number is the difference between the two terms Tf and of nature. Modern quantum mechanics can account
for everything visible on this plate, and much more,
and the history of the theory of the hydrogen atom is
t We shall not here reveal the identity of the atom, because that would take all the indeed a dramatic chapter in the annals of physics.
fun out of Prob. 1 at the end of this chapter, (Spectrum photographed by Dr. D. Goorvitch, Berke¬
\ N, Bohr, Fhibsophical Magazine 2ft, 1 (2913), ley, for th/s book,)
96 Energy Levek Sec. 3.5
T", The terms can therefore be alternatively expressed as energies,

wave numbers, or frequencies, since these quantities are always
related through the constants h and c. In view of this we can say
that a table of spectral terms is a table of “energy levels." As we
shall see this mode of expression has real physical significance: it is
more than a mere change in terminology.
5 In some elementary accounts of atomic spectra and atomic

structure the matter is stated somewhat as follows, in the form of
two theoretical postulates:
I. “An atom can exist only in certain definite stationary states
of internal motion. These states form a discrete set, and every
state is characterized by a definite value of the total energy.
II. “When an atom emits or absorbs electromagnetic radiation
it jumps from one stationary state to another. If the atom jumps
from an upper state of energy Eu to a lower state of energy Eu
(hence we have Eu > E*) a photon will be emitted, and the fre¬
quency co of the emitted photon is given byi
hv = fiio = Eu — Ei (5a)
The inverse of the emission process is the absorption of a photon

of frequency co3 in which case the atom jumps from the lower state
to the upper state.”
Now we should note immediately that if the above postulates are
interpreted literally, then the first postulate is manifestly false.
The “upper states” cannot be absolutely stationary or stable at all
since the atom indeed decays from these states spontaneously. On
a macroscopic time scale this decay is very rapid: we may quote a
time of 10-8 seconds as an order of magnitude estimate which
describes typical lifetimes of excited states of atoms. We should
note, however, that this lifetime is fairly long on an atomic time
scale. The frequency of an optical photon is of the order of 1014
sec~l, and the corresponding period is thus much shorter than the
typical lifetime of an excited state.
About the second postulate we may say that it is not very in¬
formative: we are left totally in the dark as to what it means that
the atom “jumps” from one state to another. Some writers would
actually not use the word “jump” at all, but would rather say that
“the atom makes a transition from one state to another.” This
mode of expression undoubtedly sounds more learned, but it is
t As we explained in See. 8, Chap. 2, both v and the associated quantity = 2nr are
called "frequency.” Similarly both h and ft = h/2m are called “Planck’s constant”
In the fallowing we will mostly use w and because the author likes them better than
v and h.
Several portions of the spectrum of iron photographed
on the same glass plate. Wavelengths written on the
plate are in Angstrdms. The purpose of this partic¬
ular photograph was not to measure the wavelengths
’■% of iron, but rather to use these well-known wave¬
lengths to calibrate the quartz prism spectrograph.
(Photograph by courtesy of Professor S. P. Davrs,
Berkeley.)
98 Energy Levels Sea 3.6
hardly more informative. What precisely takes place when the

e , atom makes the transition?
In spite of what we have just said the reader should not reject
our two postulates as meaningless statements: they should be looked
upon as a first approximation to the description of very complex
phenomena, and as such they serve a useful purpose.
6 To account for all the observed spectral lines in an atom (or

molecule or nucleus) we try to construct a term system, or energy
level system, for the atom, by which we understand a listing of a
number of energy levels E0, £i, £2, . . . , etc., such that every
observed spectral line corresponds to a transition between two
energy levels of the term system.
The level system so constructed is often represented graphically
t in the form of a term scheme, shown schematically in Fig, 6A,
The horizontal lines indicate four energy levels of the system. The
I vertical lines between the levels indicate possible transitions, and
* the arrow-heads indicate whether the transition is upward (absorp-
§ ^ tion), or downward (emission). The six possible transition fre-
f | quencies are tabulated below the figure. It is common practice to
draw the term scheme against a linear vertical energy scale, and
the transition frequencies are thus directly proportional to the
lengths of the arrows (or lines) between the levels.
As the figure suggests a comparatively small number of terms
describe a much larger number of lines: the number of pairs of
" _ levels which can be picked from n levels equals n(n — l)/2. It
t should be mentioned, however, that we do not in general observe
spectral lines corresponding to transitions between every possible
pair of levels, and in this respect Fig, 6A is a bit misleading. We
. i
-nlP sip-
shall discuss this important point later.
.S To fully appreciate the degree of order which this procedure
^ brings to the study of spectra we only need to look at some of the
more complicated atomic spectra, or better still at molecular band
spectra. (See Figs. 6B, and the other spectra in this chapter.) The
g latter kind of spectrum characteristically shows a number of bands,
H which when studied with very high resolution are found to consist
of an enormous number of closely spaced spectral lines. At first
sight a molecular band spectrum appears to be hopelessly complex.
Nevertheless it has been found possible to bring order into this
Spectrum of helium (long lines) superimposed on complexity: in many cases we can construct term schemes and
spectrum of iron (short lines). The numbers on the account for every single observed line,
plate give some of the helium wavelengths in Ang¬
stroms. The contrast between the complexity of the _ ^ „. ,. „ .
iron spectrum and the simplicity of the helium spec- 7 Consider again Fig. 6A and let us suppose that the Bgure shows
trum is striking. (Photograph by courtesy of Pro- the term scheme of an atom, in which case the level separations are
fessor S. P. Daw's, Berkeley.) typically of the order of an electron volt.
Energy Levels 99
Fig, 6A Term scheme showing four energy levels,

and transitions between them. The possible transi¬
tion frequencies are:
(E» - E0) (E, - EO

= —S— “31 = —n—
(Ei - Eo) (E* - Ex)
<020 = -*- «2X= j
(£3 - Eg)
“10 “32
n
Suppose we study the absorption spectrum of the atom. Using

light which originates in a source with a continuous spectral distri¬
bution, we observe the absorption lines in the light after it has
passed through a layer of a (monatomic) gas of the atoms in ques¬
tion. Suppose furthermore that the gas is reasonably cool, say at
room temperature. We will then observe absorption lines at the
frequencies (030, ^20 and coio, but not at the remaining three fre¬
quencies. The explanation for this is very simple: the overwhelm¬
ing majority of the atoms in the gas are in the ground state, and we
will, therefore, only observe transitions from the ground state to
one of the higher states.
As the temperature is raised the probability that an atom is
found in one of the excited states increases. In Volume V of this
series! we shall learn that in a gas held at temperature T the ratio
of the number of atoms in the n:th excited state to the number of
atoms in the ground state is given by
Fig. SB Parts of the spectrum of the molecule C2r
taken at two different dispersions. The spectrum at
left is taken at low dispersion, and shows the “bands'"
characteristic of molecular spectra. The spectrum
At “room temperature/’ for which kT zz (1/40) eV, this ratio is at right is taken with much higher dispersion (see the
wavelengths in Angstroms on the plate). The lines
a negligibly small number. It follows that a cool gas will not emit
which make up the bands are here seen very clearly.
(Photograph by courtesy of Professor S. P. Dav/s,
1 Berkeley Physics Course, Vol. V, Statistical Physics. Berkeley.)
100 Energy Levels Sec. 3.8
5790 (visible) light, unless the atoms are excited by some other (external)
6770
M61 (7,7) means.
4916 (9,2)
8 If we study the emission spectrum of a gas of the atoms, excited
for instance by an electrical discharge, we might observe all the
spectral lines indicated. If an atom, originally in its ground state,
4858 (7,1 4348 (2,5)
collides with an energetic electron the electron may transfer part
4109 (9,7)
of its energy to the atom. This causes the atom to jump to one of
4078 (7,5
4047 (7,7) the higher states from which it subsequently decays to a lower
8900 (9,8) level with the emission of light* It is self-evident that this process
cannot take place unless the electron has sufficient energy to raise
the atom to one of the excited states. If the energy of the electron
8663)
3665} (8,8) is less than (£h — Eo) then the electron can only undergo an elastic
86601
collision with the atom. If the energy is higher, inelastic collisions
no leading to light emission become possible.
<i 5
<
O
<1
o There is an obvious experimental test of this picture, and indeed
of the general ideas underlying our postulates of Sec* 5* We simply
Fig* 8A The spectrum of the mercury atom when vary the energy of the electrons used in exciting the atoms, and as
excited by electron collisions, for two different elec- the energy increases new emission lines ought to appear. Fig. 8A
tron energies. This photograph is taken from G. shows some results in such an experiment, for a gas of mercury
Hertz, N0ber die Anregung von Spektrallinien durch atoms* As we see the appearance of the emission spectrum changes
Elektronenstoss, I/1 Zeitschr/ft fur Pfiysik 22t 18
(1924).
When the electron energy is increased from 8,7 eV
(left spectrum) to 9.7 eV (right spectrum) a whole set
of new lines appears, of which there is no trace in the cm eV
left spectrum. The numbers within parentheses in
the figure show the electron energies at which the 79661
lines first appear, and the numbers without paren¬ 78404
77064
theses are the wavelengths in Angstroms. (Courtesy
74405
of Springer Vertag.)
71431
71396
71336
71333
flpooccxaD'Tj ©<
SO'fHdit'-L.
co^f'TtL0 to ic CO CO CO
Fig* 8B Greatly simplified term scheme of the neu¬

tral mercury atom, showing the levels involved in the
transitions seen in Fig. 8A, The numbers at left are
the energies of the levels expressed as wave numbers.
The corresponding energies in eV are shown at right.
Note that this term scheme is not drawn to scale.
Levels for which numerical data are omitted are indi¬
cated at right. The numbers on the transition lines
are wavelengths in Angstroms. All transitions to the
ground state are in the ultraviolet region. Two of
these transitions are shown in the diagram (with wave¬
lengths in parentheses). These lines are not visible 0-1-1-0
in the spectra in Fig. 8A. The ionization limit lies at
84184 cm-1 (corresponding to 10.4 eV),
Sec. 3.9 Energy Levels 101
in the expected manner, and the changes can be accounted for on

the basis of the term scheme shown in Fig, 8B.
9 The graph in Fig, 9A shows the results of a similar experiment

Mercury atoms, in the form of a gas at low pressure, are excited by
electron bombardment. The excited atoms decay back to the
ground state by emission of photons, and the presence of these
photons (in particular the ultraviolet photons) is observed through
the photo-electric current which they give rise to when they fall on
an iron electrode* As the energy of the bombarding electrons is
increased new levels can be excited, and as a consequence of this
new transitions become possible. At each new energy level of the
mercury atom the rate of increase of the number of photons emitted
with the electron energy increases abruptly, and the slope of the
graph will thus show discontinuities at these energies* The location
of these discontinuities in Fig. 9A should be compared with the
levels shown in the term scheme in Fig, 8B.
It is difficult to determine the energy of the bombarding electrons
precisely, but nevertheless measurements such as these can clearly
be very useful in the determination of the level system of an atom.
The curve in Fig. 9A establishes the approximate location of many
of the levels. These data are supplemented by accurate wave¬
length measurements of the emission lines, and since we can ob¬
serve at what electron energies a line first appears (if we employ
that method of excitation by electron bombardment), we get infor¬
mation about the levels involved in the transitions. Additional
information is obtained by study of the absorption spectrum.- in
this case we know that the ground state must be the lower level.
These and many other methods have been employed in the past,
and are still employed, in the collection of an enormous amount of
data on atomic spectra and atomic levels,
Fig. 9A The excitation of mercury atoms by elec¬

10 The phenomenon of fluorescence is easily understood on the tron collisions. Figure is taken from J. Franck and
basis of Fig. 6A, A photon of energy (E3 — £0) is absorbed by the E. Einsporn, “Ober die Anregungspotentiale des
atom in its ground state, and the atom accordingly makes a transi¬ Quecksiiberdampfes,” Zeitschrift fiir Physik 2, 18
tion to the level of energy E3, It may decay from this level via the (1920).
The abscissa shows the energy of the electrons (in
other levels, and we will then observe photons of all the frequencies
two different scales) and the ordinate is a measure of
listed in Fig. 6A,
the light emitted by the mercury atoms. (See expJa^
On the basis of this picture we can immediately understand nation in text.) As the electron energy increases new
Stokes' rule: the frequency of the light emitted in fluorescence levels will be excited, and for each new level the slope
cannot exceed the frequency of the exciting light. This rule holds of the curve changes abruptly because new transitions
involving additional photons become possible.
quite generally, although exceptions can occur if some of the atoms
The atoms are in the form of mercury gas, at a
which absorb the exciting light are not originally in the ground pressure of 0.014 mm Hg and a temperature of 50°C.
state. (Courtesy of Springer VerJag,)
102 Energy Levels Sec, 3.11
In the paper t in which Einstein discussed the photoelectric effect

he also discussed Stokes' rule, from the standpoint of the photon
picture. At that time the idea of energy levels had not yet been
bom, but the rule can also be understood if we assume that the
energy of the emitted quantum must derive from the energy of an
absorbed quantum.
11 At a certain energy above the energy of the ground state the

atom will become ionized. This energy is the smallest energy at
which an electron and the singly ionized atom can exist completely
separated from each other. At this energy, and above, the “atom”
no longer exists as an atom, but we may still consider the system
consisting of the singly ionized atom and the electron. This system
can clearly have any energy we like above the ionization energy.
The set of possible energies of the system therefore consists of a set
of discrete energy levels below the ionization energy, and of a con¬
tinuum above this energy. This situation is shown schematically
in Fig. 11A. The shaded area above the ionization level E% repre¬
sents the continuum.
The vertical line to the left represents the transition from the
Er ground state to the energy Ef in the continuum through the absorp¬
tion of a photon of energy (£' — £<>)■ This process is the photo¬
electric effect for a single atom. The ejected electron will appear
E" with the kinetic energy (Ef — E\).
The inverse of the photo-ionization process (photo-electric effect)
is the radiative recombination of the electron and the singly ionized
E1 atom. This process is shown by the vertical line to the right in
E3 Fig, 11A. An electron of kinetic energy (£" — £*) collides with the
E2 ion (at rest), and the system “jumps” down to the level of energy
E1 £2 with the emission of a photon of energy (£" — £2). From this
level the atom continues down to the ground state via the first
excited state, as indicated by the arrows. In each transition in this
cascade a photon of the appropriate frequency is emitted.
In atomic physics the ionization level is often assigned the energy
* Eo value zero, and the bound states thus ail have negative energies.
Ground .state
Other conventions are possible, and suitable, depending on the
circumstances. In nuclear physics we often assign the value zero
Fig, 11A Term scheme showing discrete energy
to the ground state of the nucleus. We should note that the choice
levels and the continuum (in gray) above the ioniza¬
tion level. Transitions between the discrete levels, of the zero-point is purely a matter of convention.
and to and from the continuum, are indicated by ver¬
tical arrows. The dotted horizontal lines embedded 12 We have so far considered only atoms in the light of our two
in the continuum do not symbolize energy levels of postulates. The notion of energy levels and transitions between
the atom, but rather two particular energies in a con¬
tinuous range of energies within which the system
consisting of an electron and an ion may be found. f A. Einstein, Annalen der Physik 17,132 (1905).
these levels is, however, of very general applicability, and we can

discuss molecules and nuclei in the same manner- Consider an
arbitrary system of particles, of any number and kind. The ioniza¬
tion level, or dissociation level, above which the possible energies
of the system form a continuum, is the lowest energy at which the
system can exist in two separate parts, at a large distance from each
other. Below this energy we may encounter a number of discrete
energy levels corresponding to bound states of the system- (This
characterization, which is in the spirit of our two postulates, must
be qualified if we wish to be very precise.)
As an example of a term scheme in nuclear physics we consider r~ 2
the term scheme of the deuteron, shown in Fig. 12A. The deuteion
has no discrete excited states. The binding energy, B, of the
r~ 1
deuteron is B — 2.23 MeV, which means that the continuum
begins at the energy B above the ground state. Above this energy
-1-
the deuteron” no longer is a deuteron, but is a system consisting
of a neutron and a proton separated from each other.
Fig, 12A Term scheme of the proton neutron sys¬
The vertical arrow in the figure represents the photo-disintegra¬
tem, showing the ground state of the deuteron, and
tion of the deuteron. A photon of energy Eph > B brings about the continuum which begins at the dissociation energy
the dissociation of the deuteron into a proton and a neutron of 2.23 MeV above the ground state. The arrow sym¬
combined kinetic energy (Eph - B). This process, which has been bolizes the photodisintegration of the deuteron.
studied experimentally in great detail, is clearly completely anal¬
ogous to the photo-ionization of an atom, which we discussed in
the preceding section. The inverse of this process is the radiative
capture of a neutron by a proton.
13 The author hopes that these introductory remarks on term

schemes have convinced the' reader that our two postulates are
indeed useful in our study of the structure of atoms, molecules and
nuclei. We are led to organize our observational material on
spectra with the help of term schemes. The important part of the
second postulate is clearly the relation (5a)* The statement about
the “jumping atom” is not intended to describe the details of the
emission or absorption processes: it is merely a picturesque way of
saying that something goes on.
Through custom the word “jump” has become well-established
as a colloquial term in quantum physics. Jn the opinion of the
author it has not been a happy choice of term, and one may surmise
that it has caused much needless suffering in the study of physics.
The word is dangerous because of its connotations: when we say
that a “system jumps from one state to another” it seems to imply
that the process has a certain abrupt and discontinuous character,
and the mental picture which we accordingly form may mislead
us seriously.
The Finite Widths of Energy Levels
14 In our discussion so far we have not run into any difficulties

with the “jump-picture/' and the reason for this is simply that we
have really not made any use of it: we have merely used equation
(5a)* Let us now consider a situation where we may get into
trouble if we take the "jump-picture” too literally*
A photon of frequency u)o is Incident on an atom originally in
its ground state* The frequency wq just happens to correspond to
the transition energy of the atom from the ground state to one of
the excited states, and the atom accordingly absorbs the photon
and makes the jump. Eventually it jumps down to the ground
state again, with the reêmission of a photon of frequency wo* This
photon may be emitted in any direction, and the atom will thus
scatter incident light of the right frequency uq. Suppose, however,
that the incident light is not of the right frequency w0, but is,
instead, of a frequency to very slightly different from Will the
atom then scatter light? The answer is yes. One finds, experi¬
mentally, that as we let the incident frequency to vary from a value
below goo the effectiveness of the atom as a scatterer changes: it
first increases to a sharp maximum at to — <o0 and then decreases
again* Somehow photons of the wrong frequency can also induce
the "jumps”: experiments tell us that this is so* We may further¬
more ask what the frequency of the scattered radiation will be if
the incident frequency is to wq* The “jump-picture” might sug¬
gest to us that this frequency should be the “correct” one, namely
too, which is not what is found experimentally: the re-emitted fre¬
quency is actually to, as we expect on the basis of energy conserva¬
tion (and the photon picture)*
In the discussion of this phenomenon, known as resonance
fluorescence, the term “jump” can hardly be regarded as appropri¬
ate: it could even lead us seriously astray.
Fig* ISA A mechanical model of an atom, which is 15 The observed facts can be understood very easily in terms of
helpful in understanding resonance fluorescence. another model* Let us regard the atom as a mechanical system in
If this contraption is excited by a kick (say in a colli¬ which the electrons are bound to the nucleus by springs. Such a
sion with an electron), it will oscillate, and since the
system will have a number of resonant frequencies, one of which is
electrons are charged, electromagnetic radiation wilt
be emitted at the resonant frequencies of the system* the frequency In the ground state of the atom this system is at
The motion is necessarily damped, because the sys¬ rest, but an incident electromagnetic wave will excite oscillations in
tem loses energy through radiation. the system* As a result the oscillating elections will radiate an
Under the influence of an incident electromagnetic electromagnetic wave of the same frequency as the incident wave.
wave, the atom will undergo forced oscillations at the
The amplitude of the oscillations will be larger the closer we are to
frequency of the incident wave, and hence will emit
radiation at the same frequency. This is the phe¬ the resonant frequency too and the effectiveness of the atom as a
nomenon of resonance fluorescence. scatterer will clearly be largest when the incident frequency is
equal to the frequency Furthermore, and this is most impor¬

tant the radiated wave will stand in a definite phase relationship
to the incident wave, and it will accordingly interfere with the
incident wave in a very definite way which the “jump-picture''
could not very well explain. The most serious defect of the “jump-
picture” in this case is that it dissects the scattering process in a
manner which in no way corresponds to reality: the scattering
process should be regarded as a single coherent process and not as
being made up of two jumps in which the photon emitted in the
second jump stands in no definite phase relationship to the photou
absorbed in the first jump.
Whether the re-radiated wave is coherent with the incident wave
or not is something which can be checked experimentally, and the
evidence is conclusively in favor of the oscillator model which
predicts coherence.
16 Our discussion of resonance fluorescence suggests to us a new

interpretation of the energy levels of atoms, nuclei and molecules:
the energy level differences correspond to frequencies at which the
system can resonate. The energy level differences are resonances.
Of course we should not take any mechanical model with springs
and levers seriously: that would be obvious nonsense. The reason
why such admittedly wrong models can nevertheless work so well
in describing such phenomena as resonance fluorescence is simply
that many aspects of a resonance phenomenon do not depend on
the details of the model: all that counts is the system of resonant
frequencies (with the associated damping constants) and the nature
of the couplings of the various resonant modes to the external source
of excitation.
17 Suppose, now, that we try to determine the energy of a level

above the ground state of an atom by determining the frequency of
photons which can cause transitions from the ground state to the
excited state. We try, in other words, to determine the frequency
at which the atom resonates. There is, however, no unique such
frequency: the atom responds throughout some small frequency
interval. We might, of course, say that the “correct” frequency,
which defines the energy of the level, is the frequency at which
the response is a maximum. The fact remains, however, that the
atom also responds in the immediate neighborhood of wo, and the
line in the absoiption spectrum of the atom cannot, therefore, be
absolutely sharp: it has a finite width. That this is so is an experi¬
mental fact: the lines in an absorption spectrum have finite widths.
We can then ask the question: how about the spectral lines
emitted by the atom? Do they also have finite widths? The an¬
swer is yes. The width of an emission line is the same as the width
of the corresponding absorption line. (We must mention here that
the lines of optical spectra, such as we observe them in practice,
are broadened because of several different effects. We are here
concerned with the width of a spectral line emitted, or absorbed,
by an isolated atom, originally at rest with respect to the observer.
This width is an intrinsic property of the atom. Let us forget
temporarily about all other causes of broadening: we will discuss
these causes later in this chapter.)
What does it mean that an emission line has a finite width? It
literally means what it says: if we photograph the line with a spec¬
trograph of extremely high resolution, we find that the line has a
finite width. The frequency of the emitted light is not precisely
too, but we also find frequencies in the immediate neighborhood
of ido-
lS Since the location of an energy level is determined through

observations on emission and absorption lines, and since these lines
always have a finite width, we must conclude that the energy of an
excited state cannot be a precisely defined quantity. If we believe
in the photon picture, and in the principle of conservation of
energy, we are forced to this conclusion. Our first postulate in
Sec. 5 is therefore not literally true. The energy levels above the
ground state have a finite width.
Suppose that we determine the energy of a particular excited
state in an atom (or molecule, or nucleus) by observing the absorp¬
tion line connecting the excited state with the ground state. If the
response of the atom is a maximum at the frequency too, we can
assign to the excited state die mean energy E = Eo + ^too, where
£o is the energy of the ground state. If the width of the spectral
line is ito, (defined in some suitable manner), we say that the
width of the excited level is AE = ffaW Once we recognize that
energy levels are of finite width there is not much point in using
the clumsy term “mean energy”: we simply talk about the“energy”
of the level with the understanding that this energy refers to a
suitably defined mean energy.
19 The nature of the simplifying assumption underlying our first

postulate can be very well illustrated by an example from classical
mechanics. Consider a pendulum set in motion, and then left to
swing by itself. We assume that the frictional forces (the most
important of which is air resistance) are small, but not zero, so that
the pendulum may execute several hundred oscillations before its
\
energy of oscillation has diminished to 1/e times its original value.
(The time required for this is the “mean-life of the oscillatory
state.”) Let the time interval between two successive outswings
to the right be one second.
Suppose now that someone asks us for the frequency of the
pendulum. Without much reflection we would answer that the
frequency is one per second. This is certainly a reasonable answer,
but strictly speaking it is wrong: by “frequency” we understand
the repetition rate of a periodic phenomenon. The motion of the
pendulum is, however, only approximately periodic since the
amplitude of oscillation does diminish as time goes on. The fre¬
quency of a damped harmonic motion is not precisely defined,
although it may, for all practical purposes, be very wefl defined
indeed. Fig* 19A An exponential damped oscillatory proo
An atom emitting radiation is in some respects analogous to a ess, showing the amplitude as a function of time.
Since the process is not strictly periodic in time it is
damped pendulum. The emission process does not go on forever,
wrong to say that the frequency of the oscillation is
and this must mean that the “oscillation inside the atom” is a coo, because the concept of frequency refers to a
damped oscillation. There is not, therefore, a precisely defined periodic phenomenon. If the damping is not too large
frequency, because the oscillatory phenomenon is not strictly it is fair to say that the frequency is approximate/y
periodic. The electromagnetic radiation emitted by that “some¬ It is intuitively clear that the smaller the damping,
Le., the smaller the decrease in amplitude for two
thing which is oscillating inside the atom” is thus not monochro¬
successive maxima, the better is the frequency de¬
matic. The emitted line has a finite width. fined.
20 If we think about Fig. 19A it might occur to us that the

smaller the damping, the better is the frequency defined, and we
might conjecture that perhaps the uncertainty A« in the frequency
is inversely proportional to the mean-life r.
To investigate this question we shall consider the emission and
scattering of light by an atom in the spirit of the “oscillator model”
of Sec. 15. We assume that only two states are involved: the
ground state and an excited state of energy A«0 above the ground
state.
We first consider the atom by itself, just after it has been excited.
We denote by A(t) the amplitude of whatever it is that oscillates
inside the atom, and we shall assume the time dependence
A(t) = A exp iwof — (20a)
where A is a constant. This is the time dependence of the ampli¬

tude of a damped harmonic oscillator of mean frequency «o, in the
complex representation.
Since the oscillation phenomenon involves charged particles we
expect that electromagnetic radiation (of mean frequency «<>) will
be emitted, and the time dependence of the amplitude of the
emitted wave must be of the same form (20a). The intensity l(t)
of the emitted radiation is proportional to the absolute square of
the amplitude:
l(t) = C|A(t) |2 = C\A |2 exp (20b)
where C is some constant We can therefore write
I(t) = /(()) exp | ^ (20c)

(
We have chosen to write the exponential decay factor in (20a)
in the form exp ( —£/2t) because we wanted to have the factor
exp (— £/t) in the expression for the intensity* It is clearly a matter
of convention how we write this factor, i.e,, how we define t. With
our definition t is the time it takes for the intensity of the radiation
to decrease by the factor 1/e* Since r is a measure of the duration
of the process, we can interpret t as the mean-life of the excited
state. “Most of the decay takes place within a time of the order t”
21 The oscillator-amplitude A(#) given by (20a) satisfies the first-

order differential equation:
^ + (i«o + ^)a(*) = 0 (21a)
This homogeneous differential equation describes the oscillator

in the absence of any external influences* Suppose now that mono¬
chromatic light, of frequency cot is incident on the oscillator* The
equation (21a) must then be modified by the addition of a term
describing the harmonically varying applied driving force. The
resulting inhomogeneous differential equation for the oscillator is
then of the form
+ (ico0 + ^) A(f) = Fexp (-iut) (21b)
where F is a constant which describes the magnitude of the driving

force.
The differential equation (21b) lias the steady-state solution
(ignoring transients)
A(f) - iFexP(~i<of? (21c)

W («-«„) + i/2t
which corresponds to an oscillation with constant amplitude at the

applied frequency w*
The intensity of the radiation emitted by the oscillator is pro¬

portional to the absolute square of A(t). The emission from the
driven oscillator is observed as scattered radiation, and the amount
of scattering is proportional to the intensity. Let us denote the
total amount of radiation scattered per unit time, for unit ampli¬
tude of the incident radiation, by S(w), where to is the incident
frequency. In view of (21c) we may then write
1 2
S(«) proportional to
(w — wo) + i/2t
or
Fig. 21A The Universal Resonance Curve. It de¬
scribes the response of any linear (or approximately
(1/2t)2
S(w) = S(<d0) (2 Id) linear) system to a sinusoidally varying external force
(d0)2 + (1/2t)2 in the neighborhood of a resonant frequency provided
no other resonant frequency is close by.
where S(«o) is the amount of scattering “at resonance,” i.e., when (Two bell shaped curves play a particularly impor¬
CO — LO0h
tant role in physics: the resonance curve and the
A schematic plot of S(co) versus co is shown in Fig, 21A. gaussian curve. As usually drawn they may look very
similar, It must be remembered, however, that the
gaussian falls off very rapidly outside the central
22 The function S(tj) expresses “the intensity of response" of the
region, whereas the resonance curve has a long
system under an external perturbation at the frequency co* This "tail.")
kind of resonant response is a very general phenomenon in quan¬
tum physics, and it is by no means restricted to the interaction of
l&ght with atoms* We find the same resonant response when we
study the scattering of material particles, such as protons, of a
well-defined energy, from a nucleus, or the scattering of pions from
a proton. One might well say that a quasi-stable energy level of
a quantum-mechanical system “exists” in precisely the sense that
the system exhibits a resonant response, as given by equation (2Id),
at the appropriate frequency*
In nuclear physics the resonance formula (2 Id) is known as the
Breit-Wigner one-level resonance formula, after G* Breit and
E. P. Wigner*
23 Let us now note an important feature of the resonance formula

(21 d). We consider the frequency at which the response is one-
half of the response at maximum and we find
“ = “° ± ~kr (23a)
The width of the resonance curve (see Fig. 21 A) at half-maximum

is accordingly given by
(23b)
T
110 Energy Levels Sec* 3.24
This agrees with our conjecture, in Sec. 20, about the relation¬
ship between the uncertainty in the frequency and the mean-life
of the excited state,
Since we can define the width of the (excited) energy level by
AE = fi Aw, we immediately derive from (23b) the very important
relation
AE = - (23c)
T
which gives the uncertainty AE of the energy of a level in terms

of the mean-life r of the state* The longer the state lives, the better
is the energy defined,
24 The reader may have strong doubts that a simple differential

equation such as (21b) can really describe such a complicated phe¬
nomenon as the interaction between light and an atom. Actually
it does not, but the point is that we do not try to describe every
aspect of the interaction, but merely the response of the atom to
(almost) monochromatic light of a frequency in the immediate
neighborhood of the resonant frequency coo, corresponding to a
transition from the ground state to an excited state. The formula
(2 Id) describes only a single resonance, and if there are several,
as is always the case with atoms, molecules and nuclei, then the
theory must be modified* The formula (21d) can be expected to
hold with good accuracy in a neighborhood of the resonance line,
far away from all other resonances*
To present the complete story of radiative transitions would take
us too far, and we must be satisfied by our somewhat vague theory,
The essence of the matter is clearly that something oscillates, and
Eg AE2 that this something is charged, and that the response (in amplitude)
to an external perturbation is linear*
CO 21
25 Let us next consider the width of a line emitted in a transition
between two excited states. This situation is shown schematically
in Fig* 25A. The widths of the energy levels are represented (in a
greatly exaggerated fashion) by the thickness of the horizontal
lines* We consider a cascade of two transitions: from the second
^-AEo = 0 excited state to the first excited state followed by a transition from
the first excited state to the ground state* The width of the line
Ftg. 25A Schematic term scheme to illustrate dis* (of frequency «io) emitted in the second transition is A«io =
cussion in Sec. 25. The width ol the line (of mean AEt/fl.
frequency toai) emitted in the transition from the
We may also ask for the uncertainty in the sum of the two fre¬
upper excited state to the lower excited state depends
on the widths of both levels, and we have: Awai = quencies emitted in the cascade from a single atom* If we denote
(AE* + AEO/fl. the sum of the two frequencies by w20 = W21 + W10 we will have
A to 20 = AE2/#, This result follows from the principle of energy

conservation: the uncertainty in the total available energy is clearly
the same as the uncertainty in the energy of the second excited
level.
From this we can surmise that the width of the line (of frequency
W21) emitted in the first transition is given by AW21 = (AE2 +
AEij/H, and if the first exdted state is broad the emitted line will
be broad even if the width of the second excited state is very narrow
(corresponding to a long lifetime)* The width of the first excited
level introduces an uncertainty in the way in which the total avail¬
able energy is partitioned between the two emitted photons.
The results which we have just presented, and which are based
on energy conservation and on the idea of a finite width of the
energy levels, are certainly extremely plausible. Our discussion is,
however, not rigorous, but it suffices for us to understand the quali¬
44 J A C K SIC A L;
tative features of the problem, and the important point is that the
TA8L.E V.-Obitr nrtJ d^cirjl line* «f G*
width of an emitted line must depend on the widths of both levels
A air 1 Pit easily £T Cla«ifieiiiun □ -c X air
involved, A (cm-1) A
4623.197 20 21624.00 101354,-122978', -0.03 4356.035
4616.233 60 21656.62 103612 ^125269% + 0.01 4346.333
26 Consider again the relation Aw = 1/t, Since the frequency 4613.803 60 2166B,02 21*49*3 - 43517 ( + 0.03 4344 025
4612,328 2 21674,01 101354 a-123023% -0.05 4539.205
is inversely proportional to the wavelength A, the fractional un¬ 4612.3*4 4 21674.69 101354 a -123029DL + 0.03 4536.143
certainty in the wavelength equals the fractional uncertainty in the 4610.723

4599.003
30
1
21682,50
21733,97
103612 , -125295% -0.03 4335.515
4331.168
43*2,264 200 21*17.16 103351 * -125163*a
frequency, and we have 4576.904 300 21342.71 103331 *-125193*!
0.00'
+ 0.01
4327.503
4321.304
4575.494 3 21849.44 0 * - 21849*1 -0.03 4314.767
AA _ Aw _ 1 4570.430 2 21*73.65 4309.634
(26a) 4568,802 20 21001.44 103351 4-125232*i -Q.OZ 4304.710
A w WT 4551.460
4544.250
60
100
21964.81
21909.66
103231
10323 L
,-125196%
,-125230%
+ 0.01
-0.01
4300 97C
4296,17*
4536,526 1 22037.12 103231 1“ 125268% -0.05 4289.791
For optical transitions in atoms the quantity wr is always very 4536.330 10 22038.07 103231 , -125269% + 0,01 4207.78
4535.726 1000 22041.01 21476% - 43517 * + 0.01 4285.50
large. The frequency v = w/2tt is of the order of 5 X 1014/sec, 4527.061 6 22079.29 103079 4 -125150°, -0,01 : 4284.77
45266S5 4 22085.17 103079 4 -125164% -0.02 4282.30
whereas the mean-life is of the order of r — 10”7 — 10~8 sec, and 4525.931 2 22083.71 103079 < -125168% + 0.01 4280.4?
4325.330 loo
the fractional uncertainty in the wavelength (or frequency) is thus 4324.6Q9 10
22091.64
22094,77
100814
100814
4
*
-122905%
-122908%
+ 0,03
-0,04
4271.2i
4264.6
4321.924 1000 22 EOS.23 100&U 4 -122922*, -0.01 4247. f
of the order of AA/A — 10^7, which is a very small quantity. The 4320.709 3 22114.22 103079 4 -125193% — 0.02 4239
4319.913 10 22118:09 1 DOS 14 * -122932*i — 0.04 42,’
resulting width of the spectral line is known as the natural line-
4503.372 10 22199.36 100734 ,-122933% + 0.02
width: it is an intrinsic property of the atom (Le*, of the levels 4502*25 100 22202. OS 70433 , - 92635',
4494.6*9 2 22242.24 100734 , - J 22976'-
involved in the transition.) 4491.454
4490.855
100
4
22258.26
22261.23
102*97
11**'
4-'"'
Further Discussion of Levets and Term Schemes Fig. 27A Portion of a tabfe in a paper by J, Sugar,
MDescription and Analysis of the Third Spectrum of
Cerium (Ce III)/1 Journal of The Optical Society of
27 Let us now look at a number of typical term schemes. They America 55, 33 (1965); exhibit taken from page 44.
have been constructed on the basis of actual measurements, inter¬ First column shows wavelength in air of observed lines
preted within the framework of quantum mechanics. We should of the doubly ionized cerium atom. Second shows
relative intensity of line. Third shows energy of pho¬
look at them with proper respect: each diagram, or rather the asso¬
ton, expressed as a wave number. The fourth column
ciated table of wavelengths, is the fruit of a considerable amount shows spectral terms involved, with energies ex¬
of human labor. pressed as wave numbers,
Fig. 28A Term scheme for the neutral lithium atom, We have drawn our term schemes in the form in which the
The slanted lines represent observed electric dipole reader will find them in the literature. The drawing of such
transitions. The numbers on these lines are the scheme^ and the labeling of the different energy levels, is governed
wavelengths in Angstrdms. For other details, see the
by a number of conventions of long standing. For greater realism
explanation in the text. Based on a figure in W.
Grotrian, Graphische Darsfef/ung der Spektren von we wanted to adhere to these conventions, even if we cannot here
Atomen. , , r vol. M, p. 15 (Verlag von Julius Springer, explain every detail of the drawings. The reader may want to
Berlin, 1928). object that we should not show anything in the diagrams that we
are not now prepared to explain theoretically. Such an attitude,

carried to its logical conclusion, would forbid us to consider term
schemes at all, before we have shown theoretically that energy
levels do occur. Our purpose in this chapter is, however, to discuss
some aspects of physical systems, given the empirical fact that
energy levels do occur. It is also an historical fact that term
schemes for atoms, of which the one shown in Fig. 28A is a typical
example, were constructed on the basis of spectroscopic measure¬
ments before the full significance of the details of the schemes was
understood: i.e., before the discovery of quantum mechanics.
28 The energy levels of a quantum-mechanical system are labeled

by a number of quantum numbers. These numbers are the numer¬
ical values of important physical parameters which occur in the
quantum-mechanical description of the system. We shall discuss
the physical interpretation of some of these quantum numbers in
connection with the term schemes. The reader is, however, under
no obligation to understand and remember in detail all the labels
on the levels shown.
Figure 28A shows the term scheme of the neutral lithium atom.
The energy scale at the left expresses the energy both in electron
volts and in equivalent wave numbers. The horizontal bars repre¬
sent the energy levels. The lines connecting the levels represent
observed electromagnetic transitions between the levels, and the
numbers attached to these lines give the wavelengths, in Angstrom
units, of the spectral lines, Particularly prominent lines in the
spectrum are indicated by thick lines between the levels.
The energy levels in the term scheme in Fig. 28A have been
arranged into columns. Four of these are shown, labeled by the
letters s, p, d and /. Actually the lithium atom has more levels,
which we would arrange into columns to the right of the ones
shown, but these levels lie dose to the ionization level, and they
do not contribute to the visible spectrum of lithium.
We notice that the spectral lines indicated in Fig. 28A obey an
interesting rule: the transitions are between two levels in neiglv-
boring columns. Actually the transitions shown in Fig. 28A do not
include all possible transitions. Quantum mechanics predicts that
there will also be transitions from the s-column, or the d-column,
to the 3p-level; from the p-column to the 3s-level; from the p-col-
umn, or the /'-column, to the 3d-level, and so on. Many of these
transitions have actually been observed but we have not shown
them in the diagram in order not to overload the figure. These
additional transitions, which lie in the infrared region, also obey
the rule mentioned, namely that the transitions are between levels
62 in neighboring columns, This rule is an interesting example of a

Fe m—Contlnned selection rule, which tells us that only certain pairs of levels can
be involved in a transition. The empirical support for this rule is
AlltlMU OORflff* Deelg. J Level Interval
strikingly apparent when we look at the observed lines shown in
* 'Pi 3lP)4p f'P* 2 119697. 64 —284. AS
Fig. 28A. We note in particular the absence of transitions between
■Pi 1 119982. 2(f — 197, 69
0 1E0179. 95 the 3s- and 2s-levels; between the 3p- and 2p-levels, and so on.
v *Fi JW*{a *D>4p y *F* 1 I £0697. 10 129 07 Because this selection rule governs the spectrum of the lithium
■F* 3 mats, 17 132. 61
3 moos. 7S 232. $9 atom, it appears natural to arrange the levels into columns as we
■F* 4 12124U 67 227. IS
•F. 6 121468. 82
have done.
f 1G* 8* (a <G)4p e »G* 3 121819. 74 21 55
'Gi 4 121941. 29 8,33
•o* 6 121949 62
r *D, E *D“ 3 122346. 61
29 The selection rule mentioned is a striking feature of the spec¬
— SKI 73
»Dt 2 122628. 34 -214. 69 trum of the lithium atom. Can we explain it theoretically? The
■D. 1 122249 OS
V *D)4p V *Dfl 4 122941 114 60

answer is yes: we can understand this phenomenon completely.
3 122829. 55 _ fifl £9
2 122893. 84 -22. S3
The explanation is based on two things: the isotropy of physical
l 122321.37 ’—534. 55
*Da 0 123465.92 space, and the smallness of the fine structure constant a = e2/-Hc
If'Pi Btffa <D)4p 1 123562. 96 144. 23 ~~ 1/137. We shall not attempt to present the complete explana¬
'Pi 3 123697, 18 53. 21
'P. 3 123750. S3 tion in this book, because we cannot assume knowledge of the
3ri»(fl *D)4p 3 124854* 04 — 49 SS appropriate mathematical tools, but we shall try to give the reader
3 124903. $2 -SO, 96
iD, 1 124954 88
at least a rough idea of what is involved.
If *F, *D)4p *FB 4 126448. 68 —194 40
*F* 3 1258S7. 98 —34, 35
Because of the smallness of the fine-structure constant a certain
*Fj 2 126672. 83
type of electromagnetic transition plays a dominant role in atomic
I »Sx *P)4p *>se 1 126390. 57
physics, namely transitions in which the emitted electromagnetic
wave has the same symmetry properties as a wave emitted by a
Fig* 28B Term schemes (diagrams) are useful for
an overall view, but extensive sets of accurate data small electric dipole oscillator. This we shall actually show later.
are best presented in tables. Above is shown a por¬ We call such a wave (or photon) an electric dipole wave (or electric
tion of a table of energy levels in doubly ionized iron. dipole photon). It can be shown, within the framework of quan¬
The energies, measured from the ground state, are
tum mechanics, that it carries off an amount of angular momen¬
expressed in wave numbers, cm-1 (fifth column).
The column labeled / gives the angular momentum tum K.
of the state. The first three columns show various The isotropy of physical space means that there is no distin¬
designations of the levels, which need not be ex¬ guished direction in the world: the behavior of an isolated system
plained here. does not depend on how it is oriented in space. Under very general
Exhibit taken from C. E, Mooref Atomic Energy
conditions this implies (within quantum mechanics, as well as clas¬
Levelst vol. II, p. 62. (Circular of the National Bureau
of Standards 467, U.S, Government Printing Office, sical mechanics) that the angular momentum vector of an isolated
Washington, 1952). system is conserved: it does not change with time. This means
that if an atom emits an electric dipole photon the angular momen¬
tum of the atom before the emission must equal the angular mo¬
mentum of the atom after the emission plus the angular momentum
carried away by the dipole photon. This conservation principle
implies selection rules because each stationary state of an atom is
characterized by a definite value of angular momentum.
30 According to quantum mechanics the square of the angular

momentum of an atom (neglecting any angular momentum which
might possibly be carried by the nucleus) is of the form
Sec, 3.31 Energy Levels 115
J2 = /(/ + 1)«2 (30a)

where / is the angular momentum quantum number. The possible
values of; are restricted by the rule that 2/ can be any non-negative
integer, 2/ = 0, 1, 2, * . . , such that 2/ is even if the atom has an
even number of electrons, and odd if the number of electrons is
odd. It is common practice to say that a state characterized by
the angular momentum quantum number / ‘‘has angular momen¬
tum j.3>
Within quantum mechanics it can then be proved that in an
electric dipole transition from an initial state of angular momen¬
tum ji to a final state of angular momentum jf the allowed changes
in the angular momentum are governed by the rule:
Aj = jf-U=-h 0, or+1 (30b)
This is a rigorous rule which holds for all isolated quantum-

mechanical systems, be they atoms, molecules or nuclei, and it
follows from the conservation principle discussed in the preceding
section. In this book we shall not discuss the theory of angular
momentum, and we shall therefore leave the reader's curiosity
about the derivation of the relations (30a) and (30b) unsatisfied,
31 The theorem which we have stated is, however, not the whole
story of the selection rules which operate for the lithium atom. In
atomic physics there is an additional, approximate, selection rule
governing electric dipole transitions, and it can be stated as follows;
in an electric dipole transition the orbital angular momentum of the
electrons must change by precisely one unit, or
Al = If — k — — 1 or +1 (31a)
where the letter /, suitably indexed, denotes the orbital angular

momentum quantum number of the electrons in the atom. What
is the significance of Z ? This quantum number also has a “classical5*
interpretation: if we think about the atom in classical terms, then l
expresses the magnitude of the angular momentum associated with
the orbital motion of the electrons* It is a fact that every electron
also has an intrinsic angular momentum, or spin, For an electron
the spin angular momentum quantum number has the value
/spin = h and we say that "the electron has spin The total
angular momentum of an electron in an atom is made up of two
parts: it is the vector sum of the orbital angular momentum and
the spin.
The theoretically possible values of l are all the non-negative
integers: l = 0, 1, 2, 3, 4. The letters s, p, d, /, by which the
5+14
5.0
Fig. 32A Term scheme for t

atom. The numbers on the si an
lengths in Angstroms of observed
Grot ri an.)
Sec* 3.32 Energy Levels 117
columns in Fig. 28A are labeled, are in fact code letters for the
orbital angular momentum, as follows: 'V' means 1 = 0; <fp*’ means
1=1; means 1 = 2 and “f* means 1 = 3* The selection rule
which we mentioned in Sec. 28 is equivalent to the selection rule
(31a).
It is not always possible to make a definite assignment of orbital
angular momentum quantum number to an energy level in an atom,
although it so happens that it can be done without ambiguity for
an alkali atom, such as lithium. The reason for this is that whereas
the total angular momentum is a constant of motion, neither the
orbital angular momentum, nor the spin angular momentum is.
The levels, in other words, do not, in general, have a definite value 90
of L This is the sense in which the rule (31a) is only approximately Na I—Continued
|
valid. As we have said, it is a good rule for alkali atoms (and for Config. De&ig. J j Level Inters'*] i1
hydrogen).
V »F°
{ %X } ssjm i
32 Consider again Fig. 28A* What about /, and the selection eft 4U 33403. i
{ }
rule (30b)? This rule does not quite show up in Fig. 28A because rp 7p »P* 33540. 4Q
X a 74
we have exhibited a simplified form of the term scheme* We should W 33541.14
actually have drawn the p-, d-f and /-columns double* The sub¬ a# 8s *S x 3S9G& 35
7d 3920a 962
scripts f and £ on the column-labels s, p, d and / indicate the IX 39200. 963 -OL001
total angular momentum For alkali atoms (and hydrogen) the V 2H
following rules hold: if l = 0, then / = \ (the entire angular mo¬

7/
{ &X } 89SQ9, $
Sjj X 39338. 54
a 47
mentum is due to the electron spin)* For all other values of l, IX 39899. 01
j can have the values / = l + £ and / = £ — ■£■* (For other atoms 0s *S X 39574. 51
2X
the rules are different)* The level 2p is thus actually double, but the ed 8cf *D
{ } 39729. 00
separation in energy between the two levels of the doublet is quite TF* [S9734. O]
{ }
small, and within the accuracy of the figure, the levels coincide.
Op *PD X 39794. S3 a 47
Fig. 32A shows the term scheme of the sodium atom. Sodium is 39795.00
also an alkali atom, and it is quite obvious that its term scheme is, 10s 10s *8 X 39983. 0
in many respects, similar to the term scheme of lithium* In this Gd iD

{ IX } 4009a 37
case we have drawn the p-column double, but left the d- and /- 2H
V 6/ tp* 40093. t
columns single to save space (and labor). All the transitions shown { 9X }
X
in Fig. 32A are electric dipole transitions* The transitions respon¬ lDp lOp
{ IX } 40137. 33
sible for the characteristic yellow light of a sodium lamp are the
transitions from the 3pi/2- and 3p3/2-levels to the ground state
Fig. 32B A portion of a ta ble of energy levels in the
3$i/2- “The yellow sodium line” is in fact a doublet* neutral sodium atom. The energies (fourth column)
The reader should ponder the term scheme in Fig* 32A and are expressed in wave numbers, cm-1, measured
convince himself that the transitions shown obey the selection rules from the ground state. The column labeled / gives
(30b) and (31a) for ; and respectively. the angular momentum of the state.
Exhibit taken from C. E. Moore, Atomic Energy
Levefs, vol, lF p. 90 (Circular of the National Bureau
33 The energy levels of the helium atom, shown in Fig* 33A form, of Standards 467, U.S. Government Printing Office,
as it were, two almost completely independent systems: the singlet Washington, 1949).
Fig. 33A Term scheme for the neutral helium atom. system and the triplet system. The observed spectral lines arise
Note the remarkable separation between the singlet from transitions within these systems: from singlet levels to singlet
and the triplet systems ol levels. In the triplet states
the electron spins are parallel, and in the singlet states
levels, and from triplet levels to triplet levels.
anti-parallel. There is an obvious correspondence The helium atom is a two-electron atom. In the singlet levels
between the triplet and singlet Jevels, except that the the two electron spins are oppositely directed, whereas in the
singlet ground state has no analog among the triplet triplet levels the two electron spins are parallel,
states. This circumstance is a consequence of the
The letters S, P, D, F, . . , , designate the total orbital angular
Pauli exclusion principle: two electrons whose spins
point in the same direction cannot both occupy the momentum of the electrons. The left superscript I or 3 designate
lowest level. There is no such restriction if the spins the multiplicity (singlet or triplet). For the singlet levels the total
are oppositely directed. angular momentum equals the orbital angular momentum. For the
triplet levels the total angular momentum / can assume the values
/ = f — 1, Z, Z -|- I, with the provision that we always have ; ^ 0.
In the triplet system the S-levels are single, and the remaining levels
triple. The singlet levels are, of course, single.
34 We note an interesting detail in the term scheme for the

S 1/2
^5/2 ^S/2,7/2
0
8F 5000
- 1
10,000 H
eV
15,000
- 2
20,000 H
- 3
25,000 —
30,000
-4-
35,000—
cm'1
-5 40,000 H
6^3/2
45,000—
- 6h
1/2 50,000 J
Fig* 34A Term scheme for the neutral thallium
atom. The numbers on the slanted lines give the
wavelengths in Angstroms of observed transitions.
(“After Grotrian.)
120 Energy Levels Sec, 3.35
Fig*35A Term schemes of zinct cadmium and mer¬ thallium atom, Fig, 34A, An atom in the state 72S±/2 can decay
cury, shown together to illustrate the fact that chemi¬ either to the state 62IV2? or to the ground state 62Pi/2. The atom
cally similar elements have similar term schemes.
has a choice which way to make the “jump,” There are other
This figure is taken from W. Grotrlan, Graphiscfte
DarsteMung cfer Speitfren von Afomen und Jonen . , . , examples of this feature in the thaDium term scheme, as well as in
voL II, Sfrukfur der Materie, Band VIII, p. 131 (Verlag some of the other term schemes shown in this chapter* (The reader
von Julius Springer, Berlin, 1928). (Courtesy of should hunt for these examples,) If an excited state can decay in
Spr/nger Vertag>) several different ways, each mode of decay occurs with a definite
probability. This probability is known as the branching ratio for
the decay mode in question. That the branching ratios are intrinsic
properties of the excited state, i.e., insensitive to how the excited
state was reached, is an experimental fact.
35 The quite similar term schemes of sodium and lithium, which

are both alkali metals, are strikingly different from the term schemes
of helium and thallium. An examination of a large number of term
schemes would reveal the remarkable fact that chemically similar
1 2
H He
1,0080 4.008
3 4 5 6 7 8 9 10
Li Be B c N 0 F Ne
6.940 9.013 10.82 12,011 14.008 16.000 19,00 20.183
11 12 13 14 15 18 17 18
Na Mg Al Si P s Cl At
22.991 24,32 26.98 28,09 30,975 32,000 35,457 39.944
19 20 21 22 23 24 25 26 27 23 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
39,100 40.08 44.96 47.90 50.95 52.01 54,94 55.85 58.94 58.71 63.54 65.38 69,72 72.60 74.91 78,96 79.916 83,80
38 39 40 41 42 43 44 45 46 47 48 49 50 mm 52 53 54
Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Te I Xe
37.63 38.92 91,22 92.91 95.95 101,1 102.91 106.4 107.880 112.41 114.82 118.70 1S1.70 127.61 126,91 131.30
55 56 57-71 72 73 75 76 77 78 79 80 81 82 83 84 85 86
Cs Ba La Hf Ta Be Os Pt Au Hg Tl Pb Ri Po At Bn
Ir
132,91 Series 178.50
137,36 180.95 186.22 190,2 192.2 195.09 197.0 200.61 204.39 207.21 208.99
87 KW 89-103 <104) (105) (106) (107) BRgn
Fr Ac ■1
Series
Lanthanide
57 58 59 80 ei 62 63 64 65 66 67 68 69 70 71
series La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
138.92 140.13 140.92 144.27 150.35 152,0 157,20 156,93 162.51 164.94 107.27 103.94 173,04 174.99
Actinide
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
series Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lw
227,04 232.05 231.05 238.04
elements have similar term schemes* Figure 35A shows an example Fig* 35B The periodic chart of the elements. The
of this* The reason for this is that the optical spectrum and the atomic number Z is given above the chemical symbol,
chemical properties of an element are both determined by the and the atomic weight (for reasonably stable elements)
below.
electronic configuration in the atom, and in particular by the con¬
Note the lanthanide series (rare earth series) con¬
figuration of the outermost electrons. sisting of 15 chemically very similar elements. All
The remarkable periodic table of the chemical elements, shown these atoms have the same configuration of electrons
in Fig, 3SB, can be understood in terms of the shell structure of in the outermost shell. The series arises because
atoms* In this rectangular table the elements are arranged in a Inner shells which were "bypassed" are being filled
as we progress in the series. On the basis of this
certain way, in order of increasing atomic number Z, and with
picture Bohr predicted that the element of atomic
elements of similar chemical properties standing in the same col¬ number 72, hafnium, at that time undiscovered, would
umn, The number of electrons in an atom equals Z, and as we be chemically similar to zirconium rather than to the
progress in the table, in the direction of increasing Z, the “shells” rare earths. Hafnium was indeed later found in a
zirconium mineral, which was a striking triumph for
are filled with electrons in a regular manner. The chemical prop¬
the theory.
erties depend on how the shells are filled. For instance, noble gases The so-called actinide elements form an analogous
will occur in the table when certain shells are completely filled series.
122 Energy Levels Sea 3.36
The number of electrons which can be accommodated in a shell is

determined by the Pauli Exclusion Principle, and this principle is
therefore of decisive importance for chemistry. These circum¬
stances were, of course, quite unsuspected before Pauli's great
discovery.
fe Shells To explain the details of the periodic table along the lines out¬
lined is a fascinating task which we shall not undertake in this book.
This study is best done in connection with a systematic study of
1 a
*pH
atomic spectra and energy levels, and this would be a bit too much
I < in an introductory course. To whet the reader’s appetite we show,
in Fig* 35C, a portion of a table of electronic configurations of
1
atoms*
He 2
Li 3
Be 4 36 When the periodic table was first proposed by D* I. Mendele-
B 5 jeff in 1869 neither electrons nor nuclei were known* Mendelejeff
c 6 therefore did not arrange the elements according to the charge Z,
N 7 but rather in order of increasing atomic weight. Fortunately this
0 8 gives the right order, with very few exceptions* The sequence
f; 9
argon-potassium is such an exception: argon has a larger atomic
Ne! 10
weight than potassium although the chemical properties of these
Na 11
elements (argon is a noble gas and potassium an alkali metal) estab¬
Mg 12
lish without a trace of doubt that argon must come first. From
A1 13
Si 14 the standpoint of chemistry the order of the elements in the table
P 15 is quite clear, and on this basis it is thus possible to assign an atomic
S 16 number Z to each element.
Cl 17 We should mention here that Mendelejeff had the foresight to
A 13 leave some empty spaces in his table, to accommodate elements not
K 19 yet discovered.!
Ca 20
Sc 21 37 The realization that the atomic number actually measures the
Ti 22 nuclear charge, and hence equals the number of electrons, was an
important step forward in atomic theory* The work of H, G* J.
Kg, 35C The shell structure of light atoms. The Moseley around 1913 was particularly important in settling this
main shells, designated by the letters Kf L, M, Nt,. , , question, He systematically measured the wavelengths of X-rays
are divided into subshells as shown. The different from a large number of elements and was able to show that the
periods are indicated by the thin horizontal lines.
wavelengths of analogous lines (in different elements) depend on
Completed noble gas configurations are shown in
gray. For the first three periods the shells are sue- the atomic number in a very simple way.f Let us discuss this
cessively filled in a pleasingly regular manner, but question briefly*
beginning with potassium an outer shell is being filled
before an inner shell has been completed. This phe¬ f For an account of Mendelejeff $ work, and the history of the periodic table, see
nomenon also occurs later in the periodic table. It is The World of the Atom, Vol. 1, edited by H. A. Boorse and L. Motz (Basic Books, Inc.,
well understood theoretically. New York, 1966).
An $'$ubshell can accommodate 2 electrons, a p- J H. G. J, Moseley, "The High-Frequency Spectra of the Elements,” Philosophical
shell 6P and a d'Shell 10 electrons, Magazine 26> 1024 (1913), and 27, 703 (1914),
Sea 3.38 Energy Levels 123
When an atomic species is bombarded with energetic electrons

(whose energy may range up to 100 keV) it is found that short
wavelength electromagnetic radiation is emitted in the form of
X-rays, It is furthermore found that the spectrum of this radiation
consists of a number of sharp lines, which are characteristic of the
element in question, superimposed on a continuous background,
(See Fig, 23A, Chapter 4, for an experimental curve,) In the
spirit of our discussion in Sec, 27, Chapter 2, we assume that the
innermost electrons must be involved in the emission of the char¬
acteristic lines* The incident electron can knock out an electron
from the innermost shell (known as the K-shell), and one of the
electrons in an outer shell will subsequently ^fall” into the empty
“hole/* The difference in binding energy will appear in the form
of an X-ray photon.
In Sec, 27, Chapter 2, we argued that the binding energy of the
innermost electron should be approximately of the form
Bk = (37a)
where ôt2mc2 is the Rydberg constant. We have not pre¬

sented a theory for what the binding energy in the next shell should
be, but let us assume that it is proportional to B*, but smaller*
Therefore, if an electron falls into the innermost shell from the next
outer shell we expect that the wavelength A of the emitted photon
should be of the form
where C is a constant which depends but weakly on Z, A plot of

In (A) versus In (Z) should therefore be a straight line if these ideas
are correct* Such a plot is shown in Fig, 37A, and as we see the
experimentally determined wavelengths do fall on a straight line to
good accuracy. The constant C is approximately equal to fp which
is what Bohr’s theory predicts.
Since the electron which fills the hole can come from a number
of different shells, and since the hole might have been created in
one of several sheUs, we expect several characteristic lines. This is
in fact what is found. In Fig. 37A we have plotted only one of these
lines, involving the same shells in all the atoms. Fig. 37A Plot of ln(A) versus ln(Z). Here X is the
As we see, the nuclear charge can be determined through such wavelength of the so-called Ka2-line in the X-ray spec¬
X-ray measurements, and Moseley’s work thus led to a new under¬ trum of an element of atomic number Z. To the accu<
racy of the drawing the experimental points all fall on
standing of the meaning of the periodic table*
a straight line. Data are available for almost all the
elements, although only selected atoms appear on
38 Let us next discuss some aspects of nuclei* The term scheme this graph. For a simple theory of the graph, see text,
in Fig, 38A shows the nuclear energy levels of the boron isotope
gB11, as they have been determined experimentally.
In this figure we have assigned the energy zero to the ground
state. The total angular momentum of the ground state is j = f.
Levels which are particularly broad have been drawn hatched,
and the hatching is an approximate measure of the widths.
The dissociation limit of this nucleus is at 8.667 MeV: above
this energy the nucleus can dissociate into an alpha-particle and
the lithium isotope 3L17. This mode of dissociation is indicated at
the right of the main term scheme. Above an energy of about 11
MeV the boron nucleus can dissociate in two different ways: either
into a neutron and the boron isotope gB10, or else into a proton
V
and the beryllium isotope 4Be10. These modes of dissociation
n are likewise indicated at the right of the level scheme for the
isotope 5B11.
Note, however, that the isotope gB11 has a system of energy
levels above the dissociation energy 8.667 MeVt Below this energy
the nucleus can only emit gamma rays, but above it the nucleus
can also emit material particles. (The observed gamma ray tran¬
sitions in 5B11 are indicated by vertical lines.)
10.61
10.32 As this example shows, we have to be a bit careful about inter¬
IIHMHlDHt
tni)iitnm»tiinwi preting the “continuum.” Levels can very well exist above the
□ 19 9.28t3/a+)
—8,92= dissociation limit. The dissociation energy is merely an energy at
8.57- which the system can dissociate into two material particles. Below
7,99 3Li7 + a 8.607
this limit the system can still "dissociate/7 but only into a photon
7.30
IIII If] I (3/JD and one material particle. If we wish to treat photons on the same
ML
6.76 footing as material particles we can conclude that the levels above
the dissociation limit (which are often called “virtual levels”) are
5,03 not different in principle from the levels below the dissociation
4.46 (5/2-)
limit: all levels above the ground state are unstable. Actually even
the ground state may be unstable: consider the ground state of a
radioactive nucleus. In our example in Fig. 38A the ground state
2.14 is stable: the isotope gB11 occurs in the boron found in nature.
39 Two nuclei are said to form a pair of mirror nuclei if one can
be obtained from the other by changing all protons into neutrons,
B 11 J = 3'a~
and vice versa.
As we said in Sec. 37, Chapter 2, the sfrong interactions, which
Fig, 38A Term scheme showing energy levels of the are the dominant interactions in nuclear physics, are believed to be
boron nucleus 5B11. This figure is a simplified version invariant under this change. The proton-proton force is the same
of a graph which appeared in F. Ajzenberg and T.
as the neutron-neutron force. If this belief is correct* and if there
,
Lauritsen, IJEnergy levels of light nuclei," Reviews of
Modern Physics 27 77 (1955). It is recommended
that the reader look at the original.
were no other interactions but the strong interactions, then the
level systems in two mirror nuclei must be identical.
Sec. 3AQ Energy Levels 125
In Fig. 39A and Fig. 39B we show the experimentally found 7.47“ — 7.10
energy levels of two pairs of mirror nuclei. As we see, it is possible 6.50- 0.35
to establish a correspondence between the levels of the pairs.
The energies of the corresponding levels are not* however, identi¬
--4.«5
cal, as the figures show. The reason for this is that electromagnetic
forces are also present, and the electromagnetic forces are not MeV MeV
invariant under neutron-proton interchange.
40 The term scheme in Fig. 40A explains why the alpha particles
emitted by a radioactive nucleus do not always emerge with a single ,477-.430
0-;-=-0
well-defined energy. The figure shows the alpha decay of the 3 Li7 4 Be'
bismuth isotope gaBi212 to the isotope siTl208 of thallium. The
decay takes place from the ground state of the parent nucleus to Fig. 39A The lithium and beryllium isotopes of
one of several excited states, or to the ground state, of the daughter mass number 7 form a pair of mirror nuclei: if the
neutrons in the lithium nucleus are changed into pro¬
nucleus. The term scheme is drawn so that the ground state of
tons, and vice versa, we obtain the beryllium nucleus.
the parent nucleus lies 6.2 MeV above the ground state of the Mirror nuclei have similar but not identical, level sys¬
daughter: this energy is the maximum kinetic energy with which tems. The difference is an effect of electromagnetism.
the alpha particle can be emitted. It is clear that if the decay takes
place to an excited state of the daughter, then the alpha particle
will emerge with a smaller energy. For the level system shown in
the figure, the alpha particle may be emitted with one of five well-
defined different energies* The tilted lines show these decays.
The numbers within parentheses are the branching ratios for the
different decay modes.
If the daughter nucleus is left in one of the excited states it
will emit gamma rays, indicated by the vertical lines, and eventually
reach the ground state.
8,93 ^ /8M
For many other alpha-active nuclei the decay always takes place 8.57- -8,44
to the ground state of the daughter, because no suitable excited 7,99 — ^8.12
states are available. The alpha particles will then emerge with a 7.30 — - 7.33
6,81--; - 6,77
single well-defined energy, and there will be no gamma-rays asso¬
6.78 / ^ 0.40
ciated with the alpha-decay.
5,03
4.77
4.48
41 By beta-disintegration we understand a process in which a 4.23
nucleus emits an electron or a positron. The simplest process of MeV MeV
this kind is the beta-decay of a neutron, which is a phenomenon
well established experimentally. The mean-life of the free neutron 2.14-
1,85
is 16 minutes. Since the neutron-proton mass difference is
— mp) = 1.3 MeV, we might draw a term scheme like the one
shown in Fig. 41A. The oblique line indicates the transition. If
only an electron were emitted, it would always be emitted with the
same energy (about 1.3 MeV), just as is the case in alpha-decay. Fig* 39B The boron and carbon isotopes of mass
Experimentally it is found that the electron, in fact, can be emitted number 11 form another pair of mirror nuclei,
126 Energy Levels Sec* 3.42
with any energy between the rest energy 0*5 MeV and the available
energy L3 MeV,
The explanation for this is that another particle, in this case the
massless anti-neutrino, is also emitted, and the available energy is
shared between the electron and the anti-neutrino. The reaction
formulas for beta-decay thus read
Electron emission: ZXA —* z+iXA + e + p
Positron emission: zXA —> z-iXA + e+ + v
where X stands for the chemical symbol of the radio-isotope; e—

for the positron or electron; v for the neutrino and v for the anti-
neutrino.
42 The term scheme in Fig, 42A shows the origin of a beta-

gamma-cascade emitted by the cobalt isotope 27C060. This isotope
first beta-decays to an excited state of the nickel isotope 2sNi603
which lies 2.4 MeV above the ground state, The maximum kinetic
energy of the emitted electron is 0.3 MeV* The electron may
emerge with any energy between zero and this maximum energy*
The reaction formula for this part of the process may be written
2TCo60 _► MNi“* + e- + v
where the asterisk indicates that the nickel isotope is left in an

excited state. It subsequently decays (for all practical purposes
immediately) from this state, via another excited state 1.3 MeV
above the ground state, to the ground state by emission of gamma
rays. The beta-decay is therefore always accompanied by two
gamma rays, of energies 1.1 MeV and 1.3 MeV.
The half-life of the cobalt nucleus is 5,3 years, and this cascade
process thus provides us with a fairly long-lived source of gamma
rays*
Beta-active nuclei frequently have very long half-lives, just like
tire alpha-emitters* In the case of beta-emitters the reason for this
is the intrinsic weakness of the interaction responsible for the beta-
decay* This interaction, known as the weak interaction, is, roughly
estimated, about 1014 times weaker than the strong interactions,
and hence also considerably weaker than the electromagnetic inter¬
Fig, 40A In the alpha decay of the bismuth isotope action, The weak interaction is responsible for the (comparatively
asBi212 the daughter nucleus may be left in the ground
slow) decay of many fundamental particles, which might be stable
state, or in any one of four excited states. The alpha
particles can accordingly emerge with five different but for the weak interaction. Examples of this are the charged
energies. The daughter nucleus decays from the pions, the neutron, the muon, the K-mesons and the lambda-
excited states through gamma emission. hyperon.
Doppler Broadening and Collision Broadening Neutron
of Spectral Lines
43 Earlier in this chapter we discussed the relationship between

the natural linewidth Ato of a spectral line emitted by an atom, and
the mean-lives of the states involved in the transition. In the
particular case that the lower state is the ground state we found
that
Fig. 41A Term scheme showing the beta-decay of
A<o = - (43a) the neutron. The mass of the neutron is 939,55 MeV,
T
and the mass of the proton is 938,25 MeV. Part of
where r is the mean-life of the upper state. the difference of 1.30 MeV, namely 0.50 MeV, appears
In Sec, 26 we quoted typical values of t for atoms, and we esti¬ as the rest mass of the electron, and the remainder
mated the fractional linewidth to be Aw/w ~ 10"7, This is, of appears as kinetic energy of the electron! antineutrino
and proton, which result from the decay. The kinetic
course, only a very rough order of magnitude estimate.
energy carried by the proton is very small, and most
Spectral lines of atoms, as observed in nature, are in general much of the available energy is therefore shared between
broader than the above estimate. Our theory in Secs. 14-26 applies the electron and the antineutrino.
to an isolated atom, originally at rest, but in practice the atoms
under study are neither isolated, nor at rest. To study the causes
of the additional broadening, let us suppose that we study the MeV
emission of light from a gas of atoms, at a temperature T and pre&-
sure P. Let the atomic weight be A. The atoms in the gas will
move around in a random fashion, and they will incessantly collide
with each other,
44 Because of the random thermal motion some of the atoms will

move toward the observer, and some of the atoms will move away
from the observer. As a result, the spectral line, which is a super¬
position of the lines emitted by many atoms, will be broadened
because of the Doppler effect For an atom moving toward the
observer with velocity v the Doppler shift is given by &o/w = v/c.
To estimate the amount of the Doppler broadening, (Acd/w)^ we
insert the mean velocity Vo of the atoms in the gas into the formula
for the Doppler shift. Actually Do is the mean velocity in the
direction of observation, which we may take to the 3-axis. In
Sec, 17, Chapter 2, we stated that the mean kinetic energy of the
atoms and the temperature T are related by
-Ekin = £M(u0l2 + Dq22 + Uq32) = ffeT (44a) ftg*42A Term scheme showing beta-gamma cas¬
cade emitted by the cobalt isotope btCo00. This Iso¬
where M ^ AMP is the mass of the atom, (Mp is the mass oi a tope first beta-decays to an excited state of the nickel
proton.) The mean velocities in the three different coordinate isotope seNi™ which lies 2.4 MeV above the ground
directions are clearly equal, and we obtain state, The maximum k/net/c energy of the electron
is 0,3 MeV. The excited state of the nickel isotope
subsequently decays through the emission of two
t)0 — Dos (44b)
gamma rays in rapid succession.
The Doppler broadening is thus given by
= (0,52 X 10-5) (44c)
45 The collisions between the atoms also lead to a broadening of

the spectral lines. To estimate this effect we shall assume that,
for any single atom, there is a time interval tc between two suc¬
cessive collisions. The inverse of this time, 1/r^ is the collision
rate of the gas. We shall furthermore assume that each collision
completely interrupts the emission process. The time tc is then
the effective mean-life of the atoms, and in analogy with the rela¬
tion (43a) we can assume that the corresponding broadening of
the spectral line is given by
(Au)c — — (45a)
Tc
We must now estimate the collision frequency l/rc. We regard

the atoms as spheres of radius r. Let us focus our attention on
one particular atom, immediately after it has undergone a collision.
Let its velocity be u. We wish to find the average time it takes
before this atom undergoes its next collision. For an order of
magnitude estimate of this time it is permissible to assume that
all the other atoms are at rest: for a precise value of rc we would,
of course, have to consider the motion of the other atoms as well.
In a small time interval dt our atom travels a distance v dt Con¬
sider a cylinder, of radius 2r, with the trajectory of the particle as
axis, and centered about this trajectory. The height of this cylinder
is then v dt If no other atom is found inside the cylinder there
will be no collision in the time interval dt The probability that a
collision takes place during the interval equals the probability of
finding another atom inside the cylinder. The volume of the
cylinder is 4jrr2 v dt and if u is the average number of atoms per
unit volume in the gas, the average number of atoms inside the
cylinder will be 4<nr2 nv dt. If this number is small compared with
unity it will also give the probability of finding an atom inside the
cylinder, and thereby the probability that a collision takes place
in the time dt. To estimate rc we impose the condition
4rrr2nvrc — 1 or — — iwftnv (45b)

Tr
which says that the mean number of atoms found inside a cylinder
of radius 2r swept out by an atom in the time rc shall be of order
unity.
Sec. 3A6 Energy Levels 129
One mole of any gas contains ATo = 6 X 1023 molecules (in our
case the molecules are atoms). At a temperature of 273° K, and
at a pressure of 1 atm* 1 mole occupies a volume of 22.4 liters. In
other words, at this temperature and pressure the number of atoms
per unit volume is given by
Np
no = = 2.7 X 101& atoms/cm3 (45c)
(22.4 liters)
The number of atoms per unit volume at any other pressure F,
and temperature T, is then given by
n — no (45d)
(This result follows from the equation of state for a gas.)

As a reasonable estimate of the radius r we may take the Bohr
radius, r = 0.5 X 10-8 cm. We obtain the characteristic velocity v
from
^- = $kT (45e)
2 2
where M = AMP is the mass of the atom. Combining all the above
equations (45) we finally obtain
(Au)« ~ j- ~
(2 X 10- sec-) X (j^) X y^(^F) <«>
46 If we now compare the collision broadening, as given by (45f),

and the Doppler broadening, as given by (44c), with the broadening
due to the finite lifetime of the excited state of an isolated atom,
we notice that the broadening due to the last mentioned cause
will in general be very small compared to the broadening due to
the first two causes. The magnitude of the collision broadening
diminishes as the pressure is reduced, and at low pressure the
Doppler broadening dominates* and is the principal cause of the
finite width of the spectral lines. The natural linewidth can only
be seen under very special conditions.
We shall not discuss collision broadening and Doppler broaden¬
ing further. These phenomena, although extremely important in
practice, are extraneous to the basic problem of emission and ab¬
sorption of light by an atom. The author felt it was necessary to
discuss them anyway in this context, as the reader may otherwise
be left with the impression that the width of the observed spectral
line is always the natural linewidth.
130 Energy Levek Sec. 3.47
Advanced Topic: On the Theory

of Electromagnetic Transitionsf
47 We consider two important questions* Why is it that the

mean life of an excited state (in an atom, or nucleus) which is stable
against particle emission, but unstable against photon emission, is
long compared with the inverse of the frequency of the photon
emitted? Why is it that electric dipole radiation is the most promi¬
nent mode of radiation in atomic physics?
Let us try to discuss these questions on the basis of a "semi-
classical” electromagnetic theory. This means that our arguments
are partly classical and partly quantum mechanical in spirit. The
justification of such a simple-minded approach as the one in this
chapter lies in its success: we cart answer the above two questions
in a reasonable way.
48 The answer to the first question is: "Because the fine structure
constant a is so small.” Let us try to see what this means*
First of all, we recall the conclusion which we reached in Secs*
29 and 39 in Chapter 2 that the wavelength of the emitted electro¬
magnetic radiation is in general large compared with the size of
the atom or nucleus which emits the radiation. This circumstance
has important physical consequences, and it also simplifies the
mathematical discussion of radiation phenomena* Let us first sup¬
pose that an atom, or nucleus, in an excited state acts like an oscil¬
lating electric dipole* Let o> be the frequency of oscillation; this
is also the frequency of the emitted light. Let a denote the size
of the object* Since the thing that oscillates is one or more ele¬
mentary charges, we can assume that the electric dipole moment
is of the order of magnitude ea. That the object is small compared
with the wavelength is expressed by the condition
a<d
< 1 (48a)
In Volume III of this series J we learned that such an electric

dipole emits radiative energy at the rate
W = (48b)
3?"* W
This formula gives the power emitted. Since we know that our
t Can be omitted in a first reading,

t Berkeley Physics Course, Vol. Ill, Waves, Chap. 7.
atom (or nucleus) will only emit a single photon, we are interested
in the time r it takes for the object to emit an amount of energy Tico.
This time is given by
A = W. = « (^\ (aoA2 (48c)

r Tkd 3 \Hc) \ c J
or, as an order of magnitude estimate,
1 con (48d)
r cf
We interpret t as the mean-life of the excited state: this is the
time it takes for the? excited state to decay through the emission
of a photon. Let- us consider the dimensionless quantity
a\cj
This quantity is proportional to the number of oscillations which
the system has time to perform during the time t, before it decays.
Clearly the excited state is the more stable the larger is the quantity
cdT. As we see <or is large for two reasons: it is proportional to the
‘Targe” quantity 1/a = 137, and it is proportional to the inverse
of the square of the quantity (cmo/c), and as we have said (ato/c) is
in general small.
49 For the case of an atom we can take a to be the Bohr radius,

oo = (1 /a)(#/mc). For an optical transition the frequency is of
the order of magnitude to — a2mc2/fi, and we thus obtain
which shows the dependence of t and cjt on the fine-structure

constant. In the optical region the formula predicts mean lives
ranging from 10”7 to 10-9 sec, which is in accordance with the
observed values.
To obtain a crude estimate of the lifetime of an excited state
of a nucleus, which can decay through an electric dipole transition,
we may take a = 10-13 cm. A gamma ray of energy 200 keV has
a wavelength of about 6 X 10-10 cm, and we obtain t — 10”12 sec.
This estimate, we emphasize, is very crude, but as a rough order
of magnitude estimate it agrees with what is observed experi¬
mentally. Note that according to (48e) the lifetime is inversely
proportional to the cube of the emitted frequency.
We have answered the first of the two questions raised in Sec. 47,
132 Energy Leveb Sec* 3.50
and we now understand why excited states which can only decay
electromagnetically live long compared with the inverse of the
frequency of the light emitted.
50 Let u$ now turn to the second question, concerning the domi¬

nant role of the electric dipole transitions in atoms* To study this
issue we must consider the emission rate from a configuration of
moving charges which is such that the electric dipole moment
vanishes at all times.
Fig* 50A shows a source which emits electric quadrupole radia¬
tion. The two arrows represent two electric dipoles oscillating at
the frequency to. These dipoles are of the same magnitude, but
they are oppositely directed. The distance between the dipoles
is and they are placed symmetrically with respect to the origin
O, which is the center of the “atom.” We observe the radiation
at the point P, at a large distance r from the atom.
The electric dipole moment of this source is clearly zero. The
same is true for the magnetic dipole moment, because we have no
circulating currents in the source.
Let us now consider the electric field in a fixed direction, at a
very large distance r from the source- This field lies in the plane
of the figure, and is perpendicular to the radius vector OP, Let Ei
be the electric field which we would find at P if only dipole 1 were
present, located at the origin O. This field is of the form
* (c ~ f) w (50a)
where C(0) is a function of 9 which is proportional to the electric
dipole moment. Its precise form need not concern us here*
If both dipoles are now present, as in the figure, then the elec¬
tric fields due to the two dipoles almost cancel, but not quite,
because the distance from P to dipole 1 is ^ (r + § cos 9% whereas
the distance from P to dipole 2 is ^ (r — f cos 9): consequently
the field due to dipole 1 differs in phase from the field due to
dipole 2. The electric field, E2> is therefore given by
Fig* 50A Schematic picture of electric quadrupole
source. The arrows represent two electric dipoles,
Eo =
m exp X
oscillating with the same frequency w. They are of
equal magnitude, but oppositely directed. The elec¬
tric, as well as the magnetic, dipole moment of this
configuration vanishes, but the electric quadrupole
moment does not. if a is small compared with the
X
(iao> cos 9 — iaos cos ff'
j - exp (—-
2c
(50b)
wavelength X the rate at which energy is radiated from
the system is smaller by a factor (a/X)2 than the rate 51 We shall now make use of our assumption (48a) that (aw/c) is
from a single dipole. very small compared to unity: this assumption is clearly valid for
optical transitions in atoms since a could not very well be larger

than the typical atomic size. We can, therefore* expand the two
exponential functions within the bracket in the right side of (50b),
and neglecting all terms of higher order than the first in a we obtain
£&d\
(cos 6) E1 (51a)
c /
where Ei is given by (50a). The electric field £2 produced by the
electric quadrupole shown in Fig. 50A is therefore everywhere
smaller by at least a factor (au/c) than the electric field E\ pro¬
duced by a single one of the dipoles "making up the quadrupole.”
Since the radiation rate is proportional to the square of the electric
field we can conclude that the typical rate of electric quadrupole
radiation is smaller than the typical rate of electric dipole radiation
by a factor (ao>/c)2, The corresponding lifetimes are then related by
?E2 (51b)
where stands for the mean-life in electric dipole transitions,

and r#2 stands for the mean-life in electric quadrupole transitions*
We have estimated that (aufc) is of the order of oc in an atom,
and the ratio of the lifetimes thus ranges from 10-4 — 10-6.
Similar considerations apply to nuclei* in which case a is a length
characteristic of nuclei, and « is the emitted frequency. In this
case too {aw/c) is small* say of the order of 10-3 or less.
52 Fig. 52A shows an example of a source with a vanishing

electric dipole moment, but with a non-vanishing magnetic dipole
moment. The small arrows again represent (oscillating) electric
dipoles* and we can imagine that such a dipole consists of a charge
oscillating back and forth along the direction of the arrow. This
corresponds to an alternating current along the edges of a square,
and the magnetic dipole moment of the system is proportional to
the product of the strength of the current and the area of the
square*
It is obvious that arguments very similar to those presented in
Secs. 50 and 51 apply here too, and we can conclude that
Fig* 52A A configuration of oscillating electric di'

where tî stands for the mean-life in magnetic dipole transitions. poles with a vanishing electric dipoie moment, and a
vanishing electric quadrupole moment, but a non¬
vanishing magnetic dipole moment. The four arrows
53 The classification of the emitted radiation into categories such represent four electric dipoles of equal magnitude
as electric dipole, magnetic dipole, electric quadrupole, magnetic oscillating at the same frequency.
quadrupole, electric octupole, etc., is a classification according to

the symmetry properties of the emitted radiation. Each type of
radiation is characterized by a distinctive kind of intensity distri¬
bution as a function of direction, and by a distinctive polarization
pattern* The symmetry pattern of the emitted radiation is, of
course, uniquely defined by the symmetry properties of the source,
and we may just as well classify the types of radiation in accordance
with the properties of the source. An electric dipole emits electric
dipole radiation, (abbreviated El), a magnetic dipole emits magnetic
dipole radiation, (abbreviated Ml), an electric quadrupole emits
electric quadrupole radiation, (abbreviated E2), etc. In term
schemes showing electromagnetic transitions in nuclei we often
find symbols such as El, M3, £4, etc,, which indicate the nattire of
the radiation emitted.
Our discussion of electric quadrupole and magnetic dipole radia¬
tion can be readily generalized to the study of higher multipoles,
To produce an electric octupole we place two electric quadrupoles
dose to each other, but oppositely oriented, so that the resulting
quadrupole moment vanishes. It is easy to understand that the
rate of radiation from such a system is smaller than the rate of
radiation from a single quadrupole by the factor (aco/c)2. Every
time we go one step higher in the hierarchy of electric multipoles
the characteristic rate drops by a factor of order (aw/cf, where a is
a typical linear dimension of the system. Similarly for the magnetic
multipoles.
We can thus understand the prominence of electric dipole transi¬
tions in atoms. If an excited state can decay in several different
ways, one of which is by El-radiation, then it will decay through
El-radiation with a very high probability* The other types of
radiation may also be present, but the intensities of the spectral
lines which do not correspond to El-radiation are much smaller
than those of the £l-lines.
54 When we discussed the selection rules for electric dipole

transitions in Secs. 29^31 we said that these rules derive from the
principle of conservation of angular momentum. We also men¬
tioned that the origin of the latter principle is the isotropy of
physical space. We can therefore describe the selection rules in a
seemingly different manner: the selection rules derive from the
isotropy of physical space* Let us explore this idea a bit.
We have said that the angular momentum quantum number /
measures the angular momentum of the state of a system, say an
atom. Within the framework of quantum mechanics / has an
alternate interpretation: j describes the rotational symmetry type
Sea 3,55 Energy Levels 135
of the state. We can say that / describes the appearance of the

atom when looked at from all possible directions. For instance, if
the atom is in a state such that / = 0, then the atom has the same
appearance from all directions: / — 0 means that the state is
spherically symmetric. If j — 1, then the state has the same sym¬
metry properties as a vector. The radiation field emitted in an
electric dipole transition is an example of such a state of the photon:
the entire field pattern in space must have the same symmetry
properties under rotations as the source, and the source is an elec¬
tric dipole vector. We have said that an electric dipole photon
carries one unit of angular momentum, and this is an example of
the general connection between symmetry types and angular
momentum. The radiation pattern from an electric quadrupole is
characterized by the rotational symmetry quantum number j — 2,
and correspondingly an electric quadrupole photon carries two
units of angular momentum. The selection rules for electric quad¬
rupole transitions are therefore different from the selection rules for
electric dipole transitions: in a quadrupole transition the angular
momentum of the atom can change by as much as two units.
55 In view of the above, all the selection rules governing electro¬

magnetic transitions can be derived from the principle that the
rotational symmetry properties of a system are conserved. To
illustrate this profound idea we shall prove one particular selection
rule, namely that the transition (/* = 0) to (jf = 0) is forbidden for
all (one-photon) electromagnetic transitions. Differently stated Eugene Paul Wigner. Born 1902 in Budapest, Hun¬
this says that an atom in an excited state which is spherically sym¬ gary. Studied in Berlin, and received a doctorate in
metric, (i.e., ji — 0), cannot decay through the emission of a photon chemical engineering from the Technische Hochschule
in 1925. After spending some time in Berlin and at
to another state which is also spherically symmetric, (i.e., jf = 0).
Gottingen, Wigner came to the United States in 1930.
We argue as follows: before the emission the atom is in a spher¬ He is now professor of Physics at Princeton University.
ically symmetric state. It has the same appearance from all direc¬ Wigner was awarded the Nobel prize in 1963.
tions. After the emission the system, which now consists of the Wigner's work in theoretical physics covers a re¬
atom in the final state plus the emitted electromagnetic wave, must markably wide range. He has made many important
contributions in such diverse fields as atomic physics,
also be in a spherically symmetric state. Originally there was no theoretical chemistry, solid state physics, nuclear
preferred direction in space, and if physical space is isotropic there physics, the theory of nuciear reactors, relativity and
cannot be any preferred direction after the emission either. This is elementary particle theory. In the author’s opinion
what we mean by the preservation of the rotational symmetry his most outstanding contribution is his amazingly
properties. Consider now the situation after the emission. If the deep and penetrating analysis of the role of symmetry
principles in quantum mechanics. His ideas on this
final state of the atom is spherically symmetric, corresponding to topic are presented in a series of papers (and one
jf = 0, we conclude that the emitted electromagnetic wave must book) spanning the time from 1931 to the present.
also be spherically symmetric: it can have no angular dependence. (Photograph by courtesy of Reviews of Modern
Such an electromagnetic wave does not exist, and it follows that Physics.)
the transition cannot take place at all It is clear that there cannot
be any electric (or magnetic) dipole wave which is spherically
136 Energy Levels Sec, 3,56
symmetric, because an electric dipole (or magnetic dipole) defines

a direction. There cannot be any other spherically symmetric
multipole wave either, because at a given instant of time, and at a
given position in space, the electric field defines a direction per¬
pendicular to the radius vector. The electric vector at that point
and at that instant of time cannot, therefore, remain unchanged
under a rotation of the field configuration about the radius vector,
and hence the field pattern cannot be spherically symmetric,
56 A transition forbidden by the dipole selection rule can be

allowed for quadrupole, or higher multipole transitions. If we
examine the term schemes for atoms, shown in this chapter, we see
that almost all the excited states can decay to some lower state by
electric dipole transitions. The level structure of nuclei is often
quite different, and we may find a state just above the ground state
which differs in /-value by several units from the ground state.
Such an excited state cannot decay by dipole emission, and con¬
sequently lives longer. If the difference in /-values is very large,
and the energy difference small, the lifetime may be of the order of
minutes since the photon emitted is of high multipole order. Such
states are called isomeric states.
1) Energy levels of atoms* molecules and nuclei are, of course, discussed in very many
tests on these subjects. Among these we mention the following fairly elementary ones:
a) G, Herzberg: Atomic Spefrtrti and Atomic Structure (Dover Publications, New
York, 1944).
b) H, White: Introduction to Atomic Spectra (McGraw-Hill Book Co,, New York,
1934).
c) G. Hersberg: Molecular Spectra and Molecular Structure: I, Spectra of Diatomic
Molecules (D. van Nostrand Co., New York, 1953).
d) D. Holliday: Introductory Nuclear Physics (John Wiley and Sons, Inc., New York,
1950),
e) E. Segr&: Nuclei and Particles (W. A, Benjamin, New York, 1964),
2) a) Term schemes of many atoms can be found in the book: W, Grotrian; Graph-
ische DarsteUung der Spektren von Atomen und lonen mit Eiro, Ztvei und Drei
Valenzelektronent vol II (Verlag von Julius Springer, Berlin, 1928),
b) For energy level diagrams of selected nuclei see: F. Ajzenberg and T, Lauritsen:
“Energy levels of light nuclei,” Ren. Mod, Phys, 27, 77 (1955)>
3) For shorter tables relating to spectra and energy levels we refer to:
a) Handbook of Chemistry and Physics (Chemical Rubber Publishing Co>).
b) American Institute of Physics Handbook (McGraw-Hill Book Co>, New York,
1957).
Froblems Energy Levels 137
4) There are several articles in the Scientific American which the reader can read
with profit at this point:
a) A- Bloom: ‘Optical Pumping," October I960, p, 72.
b) Hr Lyons: “Atomic Clocks," February 1957, p. 71.
c) G. E. Pake: “Magnetic Resonance,” August 1958, p. 58.
d) J, Pr Gordon: “The Maser," December 1958, p. 42.
e) A, L, Schawlow: “Advances in Optical Masers,” July 1963, p. 34.
f) Sr de Benedetti: “The MossbaueT Effect/' April I960, p. 72.
Problems
1 The following spectral lines were observed (early in this century) for
a certain atom:
Pi = 82258.27 ?5 = 15232.97 vE = 5331.52

Ps = 97491.28 Pq = 20564.57 P9 = 7799.30
?3 = 102822.84 P7 = 23032.31 Fi0 = 2469.
Pa = 105290.58
where the numbers listed are wave numbers, in units of cm-1.

(a) Find as many instances as you can which illustrate the Ritz combina¬
tion principle* i.e,, cases in which a wave number can be expressed as a
difference of two other wave numbers r
(fr) Show that all the lines can be regarded as combinations of five terms.
Find these (up to a common arbitrary additive constant) and draw a term
scheme showing the terms and the transitions which correspond to the above
lines,
(c) Gan you find a simple formula for the terms? Does this term scheme
occur anywhere in this book?
(After you are through with your analysis you may want to peek in a table
of wavelengths to identify the atom.)
2 In a study of resonance fluorescence the contents of a quartz vessel C
is illuminated by ultraviolet light of wavelength 2537 A emitted by a mercury
lamp (in the lamp an electrical discharge is run through mercury vapor
contained in a quartz vessel).
The following facts can be observed:
(a) If the vessel C contains mercury vapor* and nothing else, then the gas
in C will scatter the incident light very strongly: the atoms in the gas will
resonate. The scattered radiation is also of wavelength 2537 k
If the vessel C contains thallium vapor, and nothing else, then C will be
(b}
transparent to the incident radiation and there will be very little scattering
of the incident light.
(c) If the vessel C contains both thallium and mercury vapor, then C will
emit the mercury line 2537 A* and it will also emit a number of lines charae-
138 Chap. 3 Problems
teristic of thallium at the wavelengths 2768 A, 3230 A, 3529A, 3776 A and

5350 A, If a glass plate is placed between C and the lamp, none of the above
lines will be emitted.
(d) Under the conditions described in (c) it is found that the thallium line
3776 A is much broader than the thallium line 2768 A, and the first mentioned
line is* in fact, much broader than could be explained on the basis of the
Doppler broadening corresponding to the temperature in the vessel C, and it
is also much broader than the same line would be if it were emitted from a
discharge tube Med with thallium vapor.
Try to explain all these phenomena. As a hint we refer to the term scheme
of thallium, Fig. 34A of this chapter. It is interesting to note that only a few
of the lines of thallium are observed in the experiment* The lines 2826 A and
5584 A, for example, are notably absent*
3 The lifetime of the 3pi/2-state in sodium (see Fig. 32A of this chapter)
is about 10-a sec* Consider a vessel filled with argon gas at a pressure of
10 mm Hg, and at a temperature of about 200°C. Inside the vessel we have
a small speck of sodium, which is heated so that the vessel will contain a
small amount of sodium vapor* We observe the absorption line 5896 A in
light from a tungsten filament passing through the vessel. (The heated
tungsten filament emits radiation with a continuous spectral distribution.)
Estimate:
(а) the natural width of the line;
(б) the magnitude of the Doppler broadening of the line;
(c) the magnitude of the collision broadening of the line.
Express your results in wave numbers {also express the frequency of the line
in question in wave numbers, cm-1)* Compare these widths with the fine-
structure separation of the (yellow) sodium lines Di and D2.
(d) In the term scheme in Fig. 32A we note a line of wavelength 5688.22 A.
Will we see this line in the absorption experiment described above?
The argon gas in the vessel has no other effect on the process than to
establish a pressure and a mean temperature in the vessel. Its presence must
These two figures refer to Prob. 4. The upper figure be taken into account when we wish to consider the effect of collisions on the
shows a common appearance of a spectral line (under absorption line: since the number of sodium atoms in the vessel is extremely
extremely high resolution) from a gas discharge tube.
small compared to the number of argon atoms the sodium atoms primarily
Under certain conditions the same spectral line,
from a similar gas discharge tube, may instead have collide with the argon atoms.
the appearance shown below.
4 Let us consider the shape of the spectral lines emitted by an atom.
We assume that the atoms are present in the light source in the form of a gas.
We measure intensity versus frequency with a spectrograph of very high
resolution. For some light sources the line may have the appearance shown
in the upper figure in the margin, whereas for other constructions of the light
source the same spectral line may have the appearance shown in the lower
figure in the margin. Furthermore we may note that as a rule only the lines
arising in a transition to the ground state show the appearance in the lower
Problems Energy Levels 139
figure- Can you explain these phenomena, and can you explain the physical
characteristic of the light sources in which the line can be expected to be of
the kind shown in the upper figure?
5 Under the experimental conditions described in Frob, 3, estimate, on

the basis of formula (7a) in this chapter, the fraction of sodium atoms which
at any given time are in the first excited state. (Assume 7" = 200 °C.)
6 (a) From the experimental data presented in Fig. 37A, compute the
constant C in Eq, (37b).
(b) In the study of X-ray emission it is found that in order to make one of
the characteristic lines (of frequency u) appear, the energy E of the bombard¬
ing electrons must be quite a bit higher than tfw. For the Ka-lines, to which
Fig. 37A refers, the condition for the appearance of the lines is roughly
E > Why does not the line appear as soon as E >
7 Although the author cannot assume any responsibility for the harmful
mental images which might be formed if the reader studies Bohr*s planetary
model of the atom, he does not want to go as far as to outright forbid the
reader to consider this model, Bohr assumed that the electron moves in a
circular orbit in the hydrogen atom, and in such a way that the angular
momentum of the electron is a positive integral multiple of ft. It is a remark¬
able accident that this model gives the correct location of all the energy
levels to a very high accuracy. Since this model is of considerable historical
interest the reader may wish to follow in Bohr's footsteps, and construct the
term scheme, and identify the lines shown in Fig. IB. (The wavelengths
noted on the photographic plate are: 4861.3 A, 4340,5 A, 4101.7 A, 3970,1 A*
3889.1 A, and 3835.4 A.)
8 The radioactive nucleus S4P0212 (formerly called ThC) emits alpha-

particles of several different energies. In this case the explanation is not as
given in Fig. 40A of this chapter. Find out what the explanation might be.
Draw a term scheme to illustrate your ideas and your acquired knowledge.
Label correctly the states corresponding to the different nuclei involved.
9 Fig. 38A is a simplified version of a diagram appearing in an article by

F. Ajzenberg and T. Lauritsen, Reviews of Modem Physics 27 (1955), p. 107,
Fig, 15. Study the original figure. Note that above the line labeled Ld7 + a,
there is shown a curve with a number of maxima. These coincide with some
of the levels of the nucleus B11. This curve shows the results of some actual
measurements. Explain in detail the significance of this curve, and discuss
the measurements on which it is based.
To the right in the original figure, we furthermore note a horizontal bar
labeled B11 + p — p\ and above this a short horizontal bar labeled 15.8.
140 Chap, 3 Problems
This latter bar is joined to some of the levels of B11 by lines with arrowheads.
This feature of the diagram also refers to some measurements. Discuss these
measurements, and explain what the arrows represent.
10 Consider an experiment in which a beam of atoms moves parallel to

a screen with a narrow slit in it. The slit is perpendicular to the direction of
the beam. For simplicity we assume that all the atoms in the beam have the
same velocity v. Some of the atoms are brought to an excited state at some
point before they fly past the slit. Let x be the distance between the slit and
the point at which the atoms are excited. The atoms can decay from the
excited state to the ground state through the emission of a photon, of fre¬
quency gj. Let r he the mean life of the excited state. We study the light
emerging through the slit,
(a) How does the intensity of the light emerging through the slit depend
on the distance x? Motivate your answer.
(h) Suppose that we let the light emerging through the slit fall upon a
photocell, and suppose that we determine the retarding potential at which
the photocell ceases to register. State, and motivate, your expectations as
to how this retarding potential wall depend on the distance x. It does not
matter whether you come up with the right answer or not: the important
thing is that you think about the problem and formulate a definite prediction
based on your present knowledge.
Ilf It is interesting to study the angular distribution (in intensity) of the

electric quadrupole radiation emitted by the source shown in Fig. 50A and
to compare this angular distribution with the one we would observe for a
single electric dipole. The intensity is proportional to the square of the
electric field. Show that the emitted intensity as a function of the direction
of observation is given by
hi (8) = A sin2 (0)
for the case of an electric dipole, and by
1e2 (8) = B sin2 (28)
for the ease of the electric quadrupole shown in Fig. 50A, Here A and B are
constants. The intensity is independent of the azimuthal angle. This ex¬
ample indicates how the different kinds of multipole radiation can be distin¬
guished from each other by their characteristic intensity patterns.
f This problem refers to an advanced topic: Sec. 50,

Chapter 4
Photons
Sections 1 to 17 The Photon as a Particle 142
1$ to 3D The Compton Effect; Bremsstrahlung; Pair
Creation and Annihilation 152
31 to 50 Can Photons Be “Split?” 162
Problems 175
Chapter 4 Photons
The Photon as a Particle
1 In this chapter and the next we shall explore both the particle
and wave aspects of such fundamental entities as the photon, the
electron, the proton, the neutron, and the other elementary particles
found in nature. We shall look at some basic experimental facts
and try to obtain a preliminary consistent picture of what is ob¬
served. In many instances, the outcome of a particular experiment
may suggest a new experiment: when this is the case, we shall try
to make a prediction and then study what has actually been ob¬
served. Our approach is one of experimentation with ideas, and we
should be careful not to commit ourselves too firmly to any specific
model yet: let us see how things work out.
2 We may properly begin with the study of photons. The

photons are the “quanta** of the electromagnetic field: we know
that almost monochromatic radiation of frequency oi comes in
packets carrying an energy E = 'Ho). The most immediate evi¬
dence for this comes from the study of the photoelectric effect,
but there are, as we shall see, other observations which lead to the
same conclusion. Considered all together, these observations imply
that the relation E = Ho) must hold over a very wide range of
frequencies. We shall now make the (daring) extrapolation that
this relation between the energy of the packet and the frequency is
completely general, and holds for all photons.
3 We ask the following question; suppose that we have a packet

of electromagnetic radiation of frequency traveling in some direo-
tion, with the velocity of light c. Will this packet also cany mo¬
mentum, and, if so, what is the magnitude of the momentum? If
the packet, which we call the photon, has some particle properties,
we would expect that it does carry momentum, and we may think
about experiments in which we can directly measure the momen¬
tum.
In Vol. Illf of this series we learned that for a monochromatic
electromagnetic wave traveling in a well-defined direction the
energy E and the momentum p are related by p = E/c, where the
momentum is in the direction of propagation. This is what clas-
t Berkeley Physics Course, Vol. Ill, Waves, Chapn 7,

Sec. 4A Photons 143
sical electromagnetic theory predicts, and it is reasonable to expect

that the same relation holds for the electromagnetic quanta.
4 It is instructive to derive the relation between energy and mo¬

mentum from a different point of view. Let us therefore pretend
that we do not yet know that p = E/c, but that we do believe that
the relation E = -fiw is universally valid. This means, in particular,
that this relation holds in every inertial frame. The principle of
special relativity implies that if we can find general relations be¬
tween energy, momentum, frequency and direction of propagation,
which hold for all photons in one inertial frame, then these same
relations must hold in every inertial frame. The requirement of
relativistic invariance therefore introduces a constraint of the pos¬
sible relations between the physical quantities mentioned, and the
idea of our argument is to make use of this constraint to find an
expression for the momentum p of a photon.
Let the photon travel, in one inertial frame, in the direction of
the positive x-axis. We shall regard the photon as a particle of en¬
ergy E — -Kos, and of an unknown momentum p. For reasons of
symmetry p must be in the direction of the x-axis. Consider now
the same situation as observed in another inertial frame, the “primed
frame, moving with a uniform velocity t' along the positive x-axis
with respect to the “unprimed frame.” An observer in the primed
frame sees a photon of frequency <*/, carrying an energy E’ — ffw',
and a momentum p'. Since c > v the photon in the primed frame
will travel in the direction of the positive x'-axis. Furthermore we
conclude (on the basis of symmetry) that in both frames the mo¬
menta must be directed along the direction of motion of the photon.
We can therefore omit the vector notation for the momenta, and
simply write p and p' for the x- and x'-components, the other com¬
ponents being zero.
5 Let us recall two results on Lorentz transformations from Vol. I

of this series.f The first of these is the formula for the longitudinal
Doppler shift, which relates the frequencies cc and «' according to
w' = " {5a)
The second is the relativistic transformation law for the energy
f Berkeley Physics Course, Vol. I, Mechanics. The formula for the longitudinal
Doppler shift was derived in Chap, II, and the transformation law for energy and
momentum was derived in Chap. 12.
144 Photons Sec♦ 4.6
and the momentum of a particle, Acording to this law the energy

E' is given by
E — vp
VI - (v/c)2
If we now make use of our assumption
E = 4toP E* = (5c)
to eliminate E and Ef from (5b), and then eliminate w' from the
resulting equation by using (5a), we obtain
fibs — vp
VI - (v/W
This equation can immediately be solved for p, and we obtain
or
p = ± (5e)
c
These relations of course hold in all inertial frames, because

there was nothing special about our “unprimed frame/* In partic¬
ular they hold in our “primed frame.” As we said, the relation (5e)
can be derived within classical electromagnetic theory. The rela¬
tion (5d) is definitely quantum mechanical: it says that a light
quantum of frequency always carries the momentum ■ftto/c. This
relation, of course, follows immediately from (5e) and (5c), and
conversely (5c) follows from (5d) and (5e).
6 The rest mass, mPh, of the photon is zero. In VoL I we derived

a general relation between rest mass, energy and momentum,
which when applied to this particular case reads
(tn&c* )* = E* - (cp)3 (6a)
In view of (5e) the right side of this equation vanishes, and we

accordingly have fnpj! = 0.
At first sight this result might appear slightly peculiar: since the
photon has some particle properties it ought to have a mass when
observed in its rest frame. However, there is no inertial frame in
which the photon is at rest: electromagnetic radiation propagates
Sec. 4.7 Photons 145
with the velocity c in every inertial frame. A photon at rest is

therefore a meaningless concept.
One might well argue that an object which can never be at rest
should not be called a "particle/’ It has, however, become estab¬
lished custom to talk about "mass-less particles,” of which the
photon and the neutrino are examples, and we should conform to
this practice. Ultimately it is purely a matter of taste how we
define the word "particle/’ It is clearly convenient to treat photons
and neutrinos on the same footing as the massive particles. On the
other hand it should be very strongly emphasized that a photon is
no billiard ball: it merely has some properties in common with
billiard balls.
7 Let us next consider some thought experiments in which we

try to see whether the particle picture of the photon is consistent
with some results obtainable from classical electromagnetic
theory. In this manner we can further familiarize ourselves with
the idea that packets of electromagnetic radiation have particle
properties.
A word of explanation is in order* When we talk about "particle
properties” here, we mean the properties which particles are sup¬
posed to possess within classical physics. Actually the word
“particle” is of course nowadays used as a common name for such
objects as photons, electrons, protons, neutrons, etc. Strictly
speaking, "particle properties” are therefore all those character¬
istics which are shared by these objects. In particular, it is a prop¬
erty of a real physical particle that it can behave like a wave. At
this point of our discussion, we are, however, trying to find out
what the properties of the real particles are, and one aspect of this
study is to try to see to what extent the real particles behave like
the imaginary "classical particles.”
8 Consider a stationary source of light, emitting photons of fre¬

quency We let this light be incident perpendicularly on a per¬ Standing wave
fect mirror, at rest in the rest frame of the light source.
Classical electromagnetic theory predicts that the reflected
light will also be of frequency u, and that the flux of energy against Fig. SA Reflection of light from a mirror (with a per
the mirror is the same as the flux of energy away from the mirror. fectly conducting surface) according to the wave pic¬
ture. A standing wave builds up in front of the mirror,
Furthermore, classical electromagnetic theory predicts that the
and currents are induced in the surface. The wave
incident radiation will exert a pressure on the mirror, namely the exerts a force on the mirror through the interaction
radiation pressure. If we assume that the intensity of the radiation of the magnetic field in the wave with the induced cur¬
is uniform over the mirror, this pressure P is given by rents. For normal incidence the radiation pressure
P is given by P = Wt where W is the energy density
P=W in front of the mirror.
146 Photons Sec. 4.9
where W is the energy density of the radiation field in the imme¬

diate neighborhood of the reflecting surface.
Suppose now that is the flux of incident radiation: i.e.s is
the amount of energy flowing against the mirror per unit time
through a unit area perpendicular to the direction of incidence.
If we similarly let denote the flux of the reflected radiation we
must have In unit time the radiation travels a distance c,
and the density of energy W must then be given by
where the first term gives the energy density due to the incident
radiation, and the second term gives the energy density due to the
outflowing radiation. The flux and the radiation pressure are thus
related by
which we obtain by combining (8a) and (8b).
9 Let us now look upon this situation from the standpoint of the
photon picture. In this picture there is a flux of, say, N photons
per unit time through a unit area against the mirror. Each photon
carries an energy E = -fiw and a momentum p = ftw/c* After
colliding with the mirror each photon has its momentum reversed
(regard the mirror as being infinitely heavy since it remains at rest),
and each photon therefore transfers an amount of momentum 2p
to the mirror: in this picture the radiation pressure arises from the
bombardment of the mirror by the photons.
The radiation pressure P is equal to the amount of momentum
Mirror transferred per unit time to a unit area of the mirror, and we thus
have
Incident photons
P = 2Np = ^ (9a)
c
Reflected photons On the other hand the energy flux $ is simply given by
0 — Af-Hu (9b)
Fig. 9A Reflection of light from a mirror according and the energy density (since each photon travels with the velocity
to the particle picture. The radiation pressure arises of light) is given by
when the photons collide with the mirror, and have
their momenta reversed (for the case of normal inci- ^ = f jyrito (Qc)
dence). The relation between radiation pressure and c
energy density is the same as in the wave theory, (See . p
Pig gA,) If we combine the formulas (9a)-(9c) we recover the relations
(8a)-(8c), which means that for the case considered the photon
picture is consistent with the wave picture*
10 Let us next consider the following situation: a source of light

is stationary in the laboratory. It emits photons of frequency w,
and these photons are incident perpendicularly on a perfect mirror
moving away from the source with the small velocity v, We shall
assume that the mass M of the mirror is very large. (We let v be
small and M large so as to be able to discuss the problem non-
relativistically*)
From the standpoint of the photon picture, let us consider what
happens when a single photon collides with the mirror. Before the
collision the photon has an energy E and a momentum p = E/c,
and after the collision the photon has the energy E' and the momen¬ Fig* 10A The laws governing elastic collisions pre¬
dict that the energy E' of the reflected photon will be
tum pf = Ef/c. The conditions for conservation of energy and
smaller than the energy £ of the incident photon, if
momentum read:
the mirror moves away from the source. From the
relations E = hw and Er = ku' we can find the shift
p + Mv = —pf + Mb' (momentum) (10a)
in frequency. Assuming that the mirror is infinitely
heavy we obtain the same result as from the wave
E + ^Mv2 = E* + ^Mv*2 (energy) (10b) picture, (See Fig. 12A.)
Here we have taken into account the fact that the mirror may
have a (slightly) different velocity v' after the collision: the direction
of velocity will, however, remain unchanged* The reflected photon
will travel in the opposite direction, and hence the term — pf in
(10a)*
Let the frequency of the reflected photon be to' = E'/fi. We
may rewrite equations (10a) and (10b) in the form
+ Mv — — 4- Mvf (momentlun) (10c)
+ %Mv2 = fho' + ^Mv*2 (energy) (lOd)
Eliminating vr from these two equations we obtain
—j^t(io -f- c*/) (u + «')2 (lOe)
We consider the limiting case of an infinitely heavy mirror, in

which case the second term in the right-hand side of (lOe) drops
out, and we obtain
=" i1 - fK1+1) <iof>

Since we assumed that v/c is small we may expand (lOf) in
powers of v/ct and, retaining only the linear terms, we obtain for
the reflected frequency the approximate expression
148 Photons Sec. 4,11
1 - (10g)
11 Let us also consider the intensity of the reflected radiation.

For this puipose we imagine that the observer is located at a plane
fixed in the laboratory, and parallel to the mirror. Let there be a
flux of N photons per unit time through a unit area of this plane
towards the mirror, and let the returning flux be N* photons per
unit time through a unit area. We shall assume that the light
source is of large lateral extent, and that all the photons travel
strictly perpendicularly to this plane* We claim that
1 - (lla)
To see this we argue as follows: let the incident photons passing

through a unit area of the plane of observation be equally spaced
in time. The interval between the passage of two successive pho¬
tons is thus 1/M Let a given photon return at a time t: the next
photon must, however, travel a larger distance since the mirror
has meanwhile moved by the amount v/N, and it will return at
the time t 4- 1/M + 2(u/c)/M The spacing in time between the
returning photons is thus 1/JV' = (1/M) (1 + 2v/c) which, for a
small v/c leads to the approximate expression (lla)*
Now the intensity of the beams of photons, i.e., the flux of energy
per unit area per unit time, is given by O — ■ftwM for the incident
beam, and = fiu'N' for the reflected beam, and we thus con¬
clude that the intensities are related by the (approximate) formula
1 - (lib)
We have been led to two interesting results: the frequency of

the reflected photon is changed in accordance with (10g) and the
intensity of the reflected beam is related to the intensity of
the incident beam by (lib). Can we obtain the same results
through classical electromagnetic theory?f
12 On the basis of the wave theory we argue as follows: to an

observer stationary in the laboratory the reflected light appears to
come from a “source behind the mirror/' Le., from the mirror image
of the light source. This mirror image moves with a velocity v
f Of course we can. This game is not really necessary, but it is instructive. An

alternative way of discussing problems of this kind is to make a transformation to the
rest frame of the mirror, and back again.
Sec. 4,13 Photons 149
with respect to the mirror, and the mirror itself moves with a veloo
ity v with respect to the stationary observer* Since o is small we Moving
Stationary image
can employ the non-relativistic law for addition of velocities, and
source
we conclude that the image of the light source appears to move L—f-r'
away from the observer with the velocity 2v. The frequency must
therefore be Doppler shifted, and the reflected frequency os' will To stationary 2v
be given (in the non-relativistic approximation) by os' = w(l — 2u/c), observer
which is in accordance with (10g),
Moving mirror
13 Let us next consider the intensity* In Vol. II of this seriesf
we have discussed the transformation laws for the electromagnetic Fig. 12A Light from a stationary source reflected
fields under Lorentz transformations* Let E and B be the ampli¬ from a moving mirror appears to come from a moving
tudes of the electric and magnetic fields of the wave in the rest source: the image moves with twice the velocity of the
frame of the source. The fields E and B are perpendicular to the mirror* The wave theory accord ingfy predicts that
the frequency of the reflected Fight will be Doppler
direction of propagation. We denote the corresponding amplitudes
shifted. (Imagine, for simplicity, that the figure shows
in the frame in which the source moves away from the observer a monochromatic candle.)
with the velocity vf by E' and Bf, For a plane linearly polarized
wave we in fact have E = B and Ef = B\ The transformation
laws then say that the primed and unprimed amplitudes are
related by
E = <13*>
The intensity (Le,, the flux of energy) is in this case proportional

to the square of the amplitude, and we accordingly have
c — vf
(13b)
c + vf
where <6 is the intensity in the rest frame of the source, and where
is the intensity in the frame in which the source moves away
from the observer with velocity v\ If we now write v' = 2vy and
expand the right side of (13b) in powers of u/c, assuming that this
quantity is small, we recover the expression (lib) in the linear
approximation.
We see that the particle picture leads to conclusions identical
with those which can be drawn from the wave picture, i.e.5 from
classical electromagnetic theory*
14 Finally we remark that we can account for the net flow of

energy through the “plane of observation” towards the mirror:
since the reflected radiation is of lower intensity than the incident
radiation there will be a non-zero net flow. Where does the energy
t Berkeley Physics Course, Vol. H, Electricity and Magnetism, Chap* 6, Sec* 7.

go? Since the mirror is moving, the radiation pressure will perform
work on the mirror: this work accounts for half the net flux* The
other half goes toward building up the electromagnetic field in the
space between the mirror and the plane of observation: since the
volume of this space increases steadily but the energy density re¬
mains constant, energy has to be supplied at a steady rate. In the
photon picture we would rather say that the number of photons in
transit between the mirror and the plane of observation increases
uniformly because the distance increases. The reader should carry
out the indicated very simple computations in detail to convince
Fig. 14A The intensity, i.e., the flux of energy per
himself that the energy flow is balanced.
unit area per unit time, of light reflected from a mirror
moving away from the source and observer is smaller
than the incident intensity. The radiation pressure 15 Let us next consider an example which teaches us the need
does work on the mirror, and the volume filled with for caution* An extremely monochromatic beam of light of fre¬
radiative energy increases. quency Wo (as may be obtained using a laser as a light source) is
Both the particle picture and the wave picture cor¬
rectly account for the energy balance.
incident perpendicularly on a mirror which vibrates with the fre¬
quency in the direction of the beam* We wish to find the
frequency of the reflected light.
On the basis of a naive particle picture, one might argue as fol¬
lows: if the photon happens to hit the mirror at an instant when
the velocity of the mirror is v, away from the source, then the
reflected photon will be of frequency w = Wo(l — 2u/c), in accord¬
ance with our earlier discussion* The photons arrive randomly at
the mirror, and therefore we will encounter a continuum of fre¬
quencies ranging from w<)(l — 2vo/c) to wq(1 -f 2vq/c) in the re¬
flected light: the spectral distribution of the initially almost
monochromatic light will be broadened. In the above formula t?o
is the maximum velocity of the mirror.
16 On the basis of the classical wave picture, we arrive at a dif¬

ferent conclusion* The reflected light is the product of two periodic
processes, and we therefore expect that the frequencies observed
in the reflected beam will be combination frequencies formed from
the two frequencies wq and A careful study of this problem,
on the basis of classical electromagnetic theory, shows that the
frequencies expected in the reflected light will form a discrete set
of the form w = wo + ro«m, where n is any integer (positive, nega¬
tive, or zero). The intensities associated with these different fre¬
quencies will, for a physically realistic case in which the velocity
of the mirror is small compared with c, be largest for small values
of n,
The author hopes that the above result appears plausible to the
reader* We shall not study the general case here, but we can in¬
crease the credibility of our statement by considering a special
case. Suppose that coo is, hi fact an integral multiple of tow. In

this case, the entire process giving rise to the reflected beam is
strictly periodic, with period 2After the time 2w/cjto every¬
thing repeats itself. This clearly implies that the electric field
observed in the reflected beam must also be a periodic function
of the time, with period 2fl,/com, The frequencies observed in the
reflected beam must therefore be integral multiples of the fre¬
quency tom, which is consistent with the statement that the frequen¬
cies are of the form « = wo + It is certainly plausible that
the intensities associated with the various frequencies are largest for
frequencies in the neighborhood of the frequency (To see this,
consider what must happen in the limit when the amplitude tends to
zero.) In any case, it is clear that we cannot expect to observe a cor\r
tinuum of frequencies, as predicted by the naive particle picture.
The frequencies predicted by the classical wave theory corre¬
spond to what is actually observed. Experiments of this kind have
been performed with the light source itself vibrating. In one such
experiment, performed by Ruby and Bolef, the "light source” con¬
sisted of gamma-emitting Fe57 nuclei located on the surface of an
oscillating quartz crystal. Several of the predicted frequencies
were observed in this experiment, as shown in Fig, 16A.
17 The apparent sharp contradiction between the predictions of

the wave theory and the particle theory can be blunted if we note
that our particle theory was in this case outrageously naive. We FREQUENCY, MC/SEC
assumed that the reflection takes place suddenly, as if the photon
were a point particle, without any spatial extent. This assumption Fig, 16A Graphs showing frequency spectrum of
is not justified: the wave train has a finite length which is inversely gamma-rays emitted from a vibrating source of ex¬
proportional to the precision with which the frequency is defined. cited Fe57 nuclei. The different curves correspond
We can easily estimate the length of the wave train, on the basis to different amplitudes of oscillation, at the same
vibrational frequency of 20 Mc/sec. The dips in the
of our discussion in Sec. 23, Chap, 3, of the relation between the
curves show the emitted spectral lines. As we see,
uncertainty Awq of the frequency and the duration t of the emission we have lines at the central frequency, and at ±20
process. We concluded that Mc/sec and ±40 Mc/sec away from the central
frequency.
The curves actually show the transmission rate of
gamma rays through a uniformly moving absorber
containing Fe57 nuclei in the ground state, versus the
The length L of the wave train (in space) is then velocity of the absorber. With the source at rest we
have strong absorption at zero velocity. With the
source oscillating we have strong absorption at those
velocities at which the Doppler shifted emitted lines
coincide with the resonance line in Fe57,
and we see that if the frequency is very well defined then it is cer¬
Figure taken from S. L. Ruby and D. I. Bolef,
tainly not correct to regard the photon as a point particle. "'Acoustically modulated y rays from Fe57,” Physi'caf
We can also state the matter as follows: suppose that ^ Awo. Review Letters 5, 5 (I960) (Courtesy Physical Review
The time which the photon “spends” at the vibrating mirror is Letters,)
then larger than the period of oscillation of the mirror, and it is

dear that we cannot imagine that the photon is reflected from the
Incident
mirror at an instant when the mirror has a definite velocity v. The
wave train
reflection takes place over a time interval during which the mirror
aa/vvwvH; has time to perform several complete oscillations.
The Compton Effect, Brermstrahlung;

Pair Creation and Annihilation
Fig. 17A It is wrong to describe the interaction of
a photon with a vibrating mirror as if the photon would 18 Let us now turn to an experiment in which the energy and
collide with the mirror at one definite instant of time: momentum of a photon can be studied, namely A. HL Compton s
the photon is not a point particle. The wave picture
experiment in which the collision of a photon with an electron is
is more appropriate in this case. The length of the
wave train, and hence the duration of the collision observed. Figure 18A shows this collision schematically.
process, is inversely proportional to the precision with A photon of frequency collides with an electron, of mass m,
which the frequency of the photon is defined, A originally at rest. After the collision there emerges a photon of
strictly monochromatic photon is infinitely long. If frequency w' at an angle 8 relative to the incident direction. The
the frequency of vibration of the mirror is ow and the
frequency of the incident light is o>0, then the frequen¬
electron recoils in the collision, and it emerges with an energy Ee
cies found in the reflected light are of the form at an angle qp with respect to the incident direction.
(tfo + nojm)T where n is any integer. Energy and momentum can be conserved only if the whole
process takes place in a plane, and in this plane (say the plane of
the figure) the conservation laws read:
Hu + me2 — -fiw' = Ee (energy) (18a)

p — p' = (momentum) (18b)
If we now subtract the square of the second equation from the

square of the first divided by c we obtain
-^(^to + me2 — Kw')2 — (p — p')2 — — pe2 = m2c2 (18c)

c1 c
Since
Two
P = -; p' — p • p' = pp' cos 9 (18d)
c
we can solve (18c) for and we obtain
(18e)
W — 1 + (fco/mc2) (1 — cos 8)
Fig. 18A To illustrate the kinematics of Compton 19 If we introduce the wavelengths X = 27tc/w, Xf — 2mcf(d\ we
scatter!ngt in which a photon collides with an electron may write (18e) in the alternative form
originally at rest. The conservation laws of energy
and momentum imply a unique frequency aA and Xf = X + 27r{K/mc) (1 — cos 8} (19a)
momentum p\ of the scattered photon as a function
of the scattering angle 0. The quantity 2tt(iifnw) = h/mc is known as the Compton wave-
length of the particle, in this case the Compton wavelength of the

electron: h/mc = 2.43 X 10“10 cm = 2.43 X 10-2 A.
The wavelength of the scattered radiation is longer than the
wavelength of the incident radiation, or, what amounts to the same,
the frequency of the scattered radiation is smaller than the incident
frequency: this has to be so since some energy is transferred to the
electron. By inspection of (18e) we see that the fractional change
in frequency is very small if the quantity (/ftto/mc2) ^ (ffw)/(0J5
MeV) is small: we must therefore go to hard X-ray energies before
we can see an appreciable effect. We might have concluded the
same thing by inspection of (19a): the fractional change in wave^
length is small as long as the Compton wavelength is small com¬
pared to the incident wavelength.
20 The scattering phenomenon which we have just discussed was

observed experimentally by A. H. Compton in 1922. f It seems
that he was led to his experiment by a previous observation by
Barkla that when hard X-rays are scattered at large angles by a
solid material, the scattered rays seemed to consist of two com¬
ponents: one component having properties identical with the inci¬
dent radiation but the other component being different, which
difference manifested itself through a difference in the rate at which
this radiation was absorbed by intervening media. On the basis of
the wave picture we can readily understand the occurrence of the
first component. The incident electromagnetic waves, i.e., the
incident X-rays, set the electrons bound in the atoms in oscillation
at the same frequency to as the frequency of the wave, and these
oscillating electrons will then emit electromagnetic radiation in all
directions at the frequency to. In this process, the state of the
atom is only temporarily disturbed, and the electrons are not
ejected. We may expect that it is mostly the tightly bound elec¬
trons which will give rise to this kind of scattering.
Some electrons in an atom are, however, very loosely bound, with
binding energies of the order of 10-100 eV, and such electrons
could conceivably be ejected in the scattering process. In Comp-
tons experiment X-rays from an X-ray tube with a molybdenum
target, operated at a voltage of about 50,000 volts, were scattered
at various angles from graphite. The wavelength of the incident
radiation was the so-called Mo K-radiation of wavelength 0.7 A,
corresponding to an energy of about 20,000 eV, This energy is
f A, H, Compton, “The Spectrum of Scattered X-rays,*' Physical Review 22, 409

(1923). For Compton s theoretical analysis, see “A Quantum Theory of the Scattering
of X-rays by Light Elements,” The Physical Review 21, 483 (1923).
154 Photons Sec* 4.21
very large compared to the binding energy of the outermost elec¬

trons in the carbon atom: actually it is large compared to the bind¬
ing energies of all the electrons. Under these circumstances we
can expect that the scattering process will proceed in a manner
very similar to the situation when the electrons are not bound at
all, and the analysis of Sec* 18 then applies. Compton, in fact,
found that the wavelength of the scattered radiation contained a
second component with a wavelength /V which depend on the
angle of scattering in accordance with the formula (19a)* (See Fig.
20A)*
In later experiments by Compton and others, the recoiling elec¬
tron was also detected, and it was possible to show that the recoiling
electron and the scattered photon are associated with each other,
and that momentum and energy are conserved in the process.!
21 Let us now assess the significance of the observations with

regard to the Compton effect* First of all, we may note that a
classical packet of electromagnetic radiation would also be expected
to scatter from an electron, and the phenomenon of scattering as
such therefore does not require quantum mechanics for its explana¬
tion* However, the specific relation (18e) between the frequency
of the scattered radiation and the angle of scattering does depend
on Planck's constant, and in a way that lends strong support to the
photon picture* We should note that we derived the formula (18e)
under the assumption that a whole photon is scattered, and not a
third, or a fifth, of a photon: if only a fifth of a photon were scattered
the conservation laws would give a quite different result. The
importance of the Compton effect is therefore that the observa¬
tional results give further support for the universality of the relation
E = fico. The photons cannot be “split” in Compton’s experiment:
a photon of frequency cc always carries the energy fiw and the
momentum fico/c.
In optical experiments with the photo-cell (in the visible, or
Fig, 20A Graph taken from Comptonfs paper [Phys. ultraviolet region) we can check the relation E = ■fiw only over a
Rev. 22, 409 (1923)], showing spectrum of scattered
very limited frequency range. The study of the Compton effect
radiation at three different scattering angles. The
uppermost graph shows the line of the incident radia¬ extends this range to the hard X-ray region* Of course, if we
tion, of wavelength 071 A, The abscissa is propor¬ believe firmly in special relativity, which we do, we conclude that
tional to the wavelength and the ordinate is a measure the relation is completely general as we argued in the beginning of
of intensity. The peaks at left in the lower three this chapter. Nevertheless any experiment which directly tests
graphs show that part of the scattered radiation is of
this relation in a new frequency region is worthwhile: we test the
the same wavelength as the Incident radiation. The
peaks at right show the Compton-scattered radiation,
at a shifted frequency. The shift in the frequency
increases with the angle of scattering in accordance t A, H, Compton and A. W. Simon, "Directed quanta of scattered X-rays," Physical
with Compton's formula. (Courtesy of The Physical Review 26, 289 (1925). See also C, T. R. Wilson, "Investigations on X-Rays and /?-rays
Review.) by the Cloud Method," Proceedings of the Royal Society (London) 104,1 (1923).
Sea 4.22 Photons 155
consistency of our ideas, and among other things, we test special

relativity.
There exists today overwhelming support for the generality of
the relation E = It forms, we may say, an integral part of
present-day physics. To study further the implications of this rela¬
tion, let us consider two other phenomena; the emission of X-rays
in an X-ray tube, and the annihilation of an electron-positron pair.
22 In an X*ray tube, shown schematically in Fig. 22A, electrons

emitted from an incandescent cathode (heated by a filament) are
accelerated in a potential drop, Vo, between the filament and the
anode. As the electrons hit the anode, or target, they are stopped,
and on the basis of classical electromagnetic theory we expect that
this deceleration will be accompanied by the emission of electro¬
magnetic radiation. The presence of this radiation was first de¬
tected by W. C. Rontgen, in 1895. t The emitted rays are known as
X-rays, or Rontgen rays*
The true nature of the rays was at first a matter of some contro¬
versy, but in the beginning of this century it became increasingly
clear that X-rays are in fact electromagnetic radiation, Through an
Fig. 22A Very schematic figure showing operation
ingenious double-scattering experiment in 1904 C. G. Barkla was of an X-ray tube. Electrons emitted from a cathode
able to show that the rays are transversely polarized. The most heated by a filament are accelerated towards the
conclusive evidence came in 1912 when W. Friedrich and F. anode. X-rays are emitted when the electrons hit the
Knipping could show, following the suggestion by M. von Laue, anode. Part of the radiation is characteristic radia¬
that X-rays are diffracted in crystals, as already mentioned in tion for the material in the anode, and part is brems-
strahlung.
Chap* 14
23 After techniques had been developed making possible the

spectroscopic study of X-rays, the intensity of the emitted rays as
a function of the wavelength could be measured for a wide variety
of experimental conditions. A typical plot of intensity versus wave¬
length for three different substances but the same voltage Vo, is
shown in Fig* 23A* We see that superimposed on a continuous
background there are several sharp “spikes/' or intensity maxima.
It has been found that the locations of these spikes is a property of
f W, C. Rontgen, “Ober eine neue Art von Strahlen/’ Sitzungsberlchte Med. Phys.
Ges. Wurzburg, 1895, p. 137; 1896, p. 11. These papers have been translated; W, C.
Rontgen, "On a New Kind of Rays,” Science 3, 227 (1896); "A New Form of Radia¬
tion," Science 3, 726 (1896),
| C* G. Bar Ida, “Polarized Rontgen Radiation/7 Phil. Trans. Rot/ Sac. 204, 467
(1905). C. G. Barkla, “Polarisation in Secondary Rontgen Radiation/' Proc. Roy. Soc>
(London) 77, 247 (1906). (The latter paper reports on the double-scattering experi¬
ments.)
W. Friedrich, P. Knipping and M, von Laue, Annalen der Physik 41, 971 (1913).
the material in the target. The continuous background, on the

other hand, is, for the same accelerating potential Vo, of the same
shape for all materials. Examination of all the experimental mate¬
rial has led to the conclusion that there are two different mechan¬
isms responsible for X-ray emission. The sharp spikes are analogous
to the light emitted by atoms undergoing collisions: this radiation
is known as the characteristic radiation of the substance, and it is
an emission by an atom which has been excited in the collision with
one of the energetic incident electrons. The continuous back¬
ground, on the other hand, is an emission by the electron which is
being decelerated in the target. It is known under the German
name bremsstrahlung. This word has become incorporated in the
English language by now: literally translated it means “braking
radiation/*
It has furthermore been found experimentally that for a given
accelerating potential Vo there is no radiation of shorter wavelength
than a certain minimum wavelength, \m\n, which depends on the
potential Vo, but not on the substance in the target: this we can
see illustrated in Fig, 23A.
24 Let us see how we can understand the last mentioned circum¬

stance theoretically.
First of all, we note that according to classical electromagnetic
Fig* 23A Graph showing intensity of emitted X-rays theory a uniformly moving electron cannot emit radiation. We can
versus wavelength, for three different substances, but draw the same conclusion on the basis of the photon theory as
the same accelerating potential V0 = 35,000 volts. follows. Consider the rest-frame of the electron before any possible
The sharp spikes correspond to the characteristic emission: in this frame the total energy is me2. If an emission of
radiation of the substance. The continuous back-
one or more photons could take place these photons would carry
ground is due to bremsstrahlung.
The figure is taken from 0. Tr Ulrey, uAn Experi¬ away energy, and the total final energy after the emission would be
mental Investigation of the Energy in the Continuous larger than me2, which violates energy conservation. The emission
should therefore not take place.
,
X-Ray Spectra of Certain Elements,'1 Physical Review
11 401 (1918). (Courtesy of The Physical Review.) The situation is different, however, when the electron passes
through the strong electric field of a nucleus in the target. It is
then possible for the electron to transfer some energy and momen-
turn to the nucleus, and the conservation equations for energy and
momentum can be balanced. Let us see how this works out. The
nucleus, of mass M, is originally at rest (in the laboratory frame),
and the electron, of mass m and initial momentum pi, impinges
upon it. After the collision the electron has momentum p/, and
the nucleus has momentum pn. In addition, there emerges a
photon of momentum p and frequency co = pc/H. The conserva¬
tion equations read
Pi — Pf + Pn + P (momentum) (24a)
&i + Me2 — Ef + En + 'foo (energy) (24b)
Sea 4.25 Photons 157
where E* and E/ are the initial and final energies respectively of the
electron, and where En is the final energy of the nucleus.
These equations taken together give us four conservation equa¬
tions. There are, however, nine variables which characterize the
final situation, namely the nine components of the three vectors
pn and p. The detailed investigation of the permissible range of
these vectors is somewhat involved and we shall not attempt it.
One can show, that for any given direction, the photon can emerge
with an energy ranging from zero to some maximum* This maxi¬
mum actually occurs when both the electron and the nucleus
have the same velocity, say v, after the collision: that this must
be so is immediately obvious if we consider the problem in the
center of mass system. Let us rewrite the conservation equations
for the case when the final electron and nuclear velocities are
indeed equal:
(M + m)y
Pi “ P = y , ,' (24c)
V1 - (v/c)2
(M + m)c2
Ei + Me2 — cp ~ (24d)
VI - (t?/c)z
Multiplying the first equation by c, and subtracting the square of
the result from the square of the second equation gives us
_Ej — me2_
(24e)
1 + (Ei — piC cos 8 )/(Mc2)
where 8 is the angle between the emerging photon and the incident
electron. The above formula thus gives the maximum photon
energy at the angle 8, We note that is is approximately equal to
{Ei— me2), the kinetic energy of the incident electron, which in
turn is equal to eVo. The second term in the denominator in the
right side of (24e) is very small for X-ray tubes since the constant
Me2 ~~ 940 A MeV, for a nucleus of mass number A, is large com¬
pared with Ej, which may range from 1 keV to 100 keV.
25 In the limit when the nucleus is assumed to be infinitely heavy,

we thus obtain for the minimum wavelength \min the expression
^ 2*ne ch /at£ ^
Amin —-= —rr (25a)
o) eVo
This we could, of course, have concluded directly: the energy

of the emitted photon cannot exceed the kinetic energy of the inci¬
dent electron, and for an infinitely heavy nucleus the maximum
energy must occur when the electron is brought to complete rest
in the collision.
The minimum wavelength is known as the quantum limit.

Its existence is a manifestation of quantum phenomena: classical
theory predicts that arbitrarily short wavelengths will be emitted.
Very precise measurements of the quantum limit as a function of
Vo have been carried outf and such measurements lead to precise
values of the constant e/ch (and e/h).
26 Let us finally consider the annihilation of an electron-positron

pair. Positrons were first observed by C. D. Anderson in 1932, in
the cosmic radiation (see Fig. 26A). Positrons are known today to
arise in the decays of many unstable particles, as for instance in the
decay of the radioactive phosphorus isotope P30. Positrons are
also observed when very energetic gamma rays pass through matter,
and as we mentioned in Chap. 1, our picture of this phenomenon
is that in the electric field of a nucleus a gamma ray is able to create
an electron-positron pair. This process is known as electromagnetic
pair production.
When a positron collides, or interacts, with an electron, this pair
Fig. 26A The cloud chamber picture in which An¬ of particles may annihilate, which means that the particles dis¬
derson's discovery of the positron was presented to
the world. [From C. D. Anderson, “The Positive Elec¬
appear and their energy is completely converted into electromag¬
tron,’ ’ Physical Review 43, 491 (1933).] A positron netic radiation. This annihilation phenomenon is observed when
of an energy of 63 MeV passes through the horizontal positrons impinge upon matter in bulk. According to our present
lead plate (of 6 mm thickness,) and emerges with an picture, the positron entering the material first loses most of its
energy of 23 MeV. The tracks are curved because the kinetic energy in collisions with the atoms of the material, although
chamber was placed in a magnetic field perpendicular
some of the positrons may annihilate in a direct collision with an
to the plane of the picture. The quality of the picture
is poor near the edge of the chamber, and the very electron before slowing down. The positrons which have slowed
faint portions of the tracks near the edge, which show down diffuse around in the material, and eventually are captured
that the positron did pass through the chamber, are by the electrons in the atoms. Under favorable circumstances a
therefore somewhat hard to see. positron may actually form a hydrogen-like "atom” with a single
For some interesting questions concerning this pic¬
electron, known as positronium. The slowed-down positrons inter¬
ture, see Prob. 11 at the end of this chapter. (Cour¬
tesy of The Physical Review,} act with the electrons, and eventually the annihilation takes place.
To the best of our knowledge the mass of the positron is equal to
the mass of the electron.
27 Let us now consider the annihilation process, which we repre¬

sent by the reaction formula
e+ + e~ = ny
where the symbol y stands for a photon (a gamma quantum). Sup¬
pose that the electron and the positron are practically at rest when
the reaction takes place (in the laboratory frame), and suppose
t J. A. Bearden, F, T. Johnson and H. M. Watts, "A New Evaluation of h/e by

X-rays,” The Physical Review 81, 70 (1951).
furthermore that the reaction takes place iiji free space, far away
from all other particles.
First of all we note that there must be at least two gamma rays:
n ^ 2, since we cannot otherwise conserve energy and momentum.
(If the electron and positron are initially at rest the initial momen¬
tum is zero: if only one photon is emitted, the final momentum
would not be zero.) Let us therefore assume that two photons are
emitted. Since the initial momentum is zero it follows that the
final (total) momentum must also be zero, and the momenta of the
two photons are thus equal and opposite, which means that their
energies, and hence their frequencies are also equal. Let us denote
the frequency by u: the conservation of energy then implies that
= 2me2 or X = = — (27a)
to me
The wavelength of the emitted photons therefore equals the
Compton wavelength of the electron, h/mc — 0.0243 A: to this
wavelength corresponds the rest energy of the electron* me2 =
0.511 MeV.f
For the positrons which have been slowed down and captured
in the material we can assume that the above prediction is valid: the
presence of the other particles in the material may have an effect
but this effect should be small since the atomic binding energies are
very small compared to the rest energy of the electron.
We may therefore look for the two gamma rays formed in the
annihilation. They should emerge in opposite directions, and their
wavelengths should be the Compton wavelength of the electron.
It has been found experimentally that these predictions are cor¬
rect in every detail: annihilation into two gamma rays indeed takes
place-! In addition it has been found that annihilation into three
gamma rays also takes place.
28 There is one point which we should clarify. We argued that

an electron-positron pair cannot annihilate into a single photon in
empty space since energy and momentum cannot then be con¬
served. It follows that the inverse process, in which a single photon
suddenly changes into an electron-positron pair must also be impos¬
sible* On the other hand we said that electron-positron pairs are
created when very energetic photons traverse matter in bulk. The
f Note that the quantity h/mc = 0.00386 A is also often called the Compton wave¬
length.
\ See, for instance, O, Klemperer, "On the Annihilation Radiation of the Positron/'
Proceedings of the Cambridge Philosophical Society 30, 347 (1934).
160 Photons Sec♦ 4,29
resolution of this apparent contradiction is that this process can

and does take place in the field of a nucleus. A certain amount of
energy and momentum is transferred to the nucleus, and it is then
possible to balance the conservation equations.
The inverse of the annihilation process which we have discussed
is the process in which two colliding photons would produce a pair.
This process has never actually been observed, and the reason for
this is that we cannot produce sufficiently intense photon beams at
high energy for the process to take place at an observable rate: we
believe firmly that we would see this phenomenon if we could
produce such photon beams. The inverse of the pair-production
process in the field of the nucleus is the process in which an elec¬
tron-positron pair annihilates in the field of the nucleus into one
photon, with the nucleus taking up the energy and momentum
necessary to balance the conservation equations. This process does
take place, but it turns out that in general the twophoton annihila¬
tion process is more probable, and therefore dominates.
29 Since we are on the subject of positrons, we may speculate a

bit about particles and anti-particles. Our present-day formula¬
tion of quantum electrodynamics is a theory in which the electron
and the positron play a completely symmetric role. This is a
general feature of our theories of the fundamental particles: for
every particle we believe there also exists an anti-particle (some
particles, such as the neutral pion, may be their own anti-particles),
and the world is believed to be symmetric (in a sense) under the
exchange of particles for anti-particles, f An anti-particle has the
same mass, but the opposite charge as the particle. It has thus been
found experimentally that both antiprotons and antineutrons exist
which we find pleasing from the theoretical standpoint: it enables
us to persist with our symmetric theories of nature.
It is a fundamental property of particles and their anti-particles
that they can annihilate each other, say, into photons. However,
it is often the case that the annihilation Is into other particles. For
instance, the proton-antiproton system tends to annihilate into
f Very recently some experiments have been performed which seem to indicate that
the weak interactions axe not invariant under the exchange of particles for anti-particles.
This implies that whereas the strong and electromagnetic interactions might obey the
symmetry principle mentioned, the weak interactions do not. Since the strong and
electromagnetic interactions are the dominant interactions in the world, it is perhaps
fair to say that the symmetry principle is almost (but not quite) true.
J For the discovery of the antiproton* see O. Chamberlain, E. Segre, C. Wiegand and
T. Ypsilantis* “Observation of Antiprotons,” The Physical Review 100, 947 (1955).
An annihilation star in a photographic emulsion. Note

that this is a composite picture in which different
sections of emulsion have been pieced together so
that the tracks of the various particles can be followed.
The scale is shown at bottom left, where 1 jut =
mm. Note that portions of four of the tracks have
been omitted in order to keep the picture within a
reasonable size.
The horizontal track at left shows the incident anti-
proton. As it traverses the emulsion it loses energy
(and consequently slows down). It is finally captured
by a nucleus in the emulsion (perhaps a carbon nu¬
cleus) and is annihilated together with one of the nu¬
cleons in the nucleus. A few pions are created in the
process (tracks 2, 3, 5t 7 and 8) and the nucleus
breaks up into fragments. Tracks 1 and 3 are prob¬
ably protons, and track 6 is caused by a heavier
fragment, possibly a H* nucleus. The total kinetic
energy of the visible (charged) particles plus the total
rest energy of the pions is estimated as about 1.3 BeV.
Note track 5 which shows a positive pion decaying into
mesons, that process being more probable than annihilation into a neutrino (invisible) and a positive muon which sub¬
photons. sequently decays into a positron and two neutrinos.
30 The reader may wonder why, if the particles and anti-particles

This photograph appeared in an article by E. Segr6,
“Antinucleons,” Annual Review of Nuclear Science 8
127 (1958), which reviews the early work on anti¬
,
really play an almost completely symmetric role in the world, antinucleons. (Photograph by courtesy of Professor E,
particles are not more evident. Why are positrons not “more G. Segrfe, Berkeley.)
commonly encountered/* and why were they not discovered
earlier? Our world as we know it does not seem to be in a sym¬
metric state at all: our world consists of protons, neutrons, electrons
and hydrogen atoms, etc., but not of antiprotons, antineutrons,
positrons or anti-hydrogen atoms. The reason for this lack of
symmetry is that the symmetric state would not be stable against
annihilation: matter and antimatter cannot peacefully coexist in an
intimate mixture. Granted that the earth exists, it must consist
either of matter or else of antimatter. It could not possibly exist
as a mixture.
It is an interesting question whether this lack of symmetry of
the state of the world extends to the entire universe. It could pos¬
sibly happen that there are galaxies consisting of antimatter: since
the average separation between the galaxies is of the order of three
million light years, the annihilation cannot take place readily. This
question cannot be answered at present, although one might be
inclined to believe that anti-galaxies do not exist. How the galaxies
were formed is not known, but if we assume that they were formed
through some kind of condensation process from “dust** it becomes
hard to understand how a segregation of matter and antimatter
Bubble chamber photograph showing a charge-ex¬

change scattering of an anti proton by a proton, fol¬
lowed by an annihilation reaction of a proton and the
antineutron produced in the first event. See the
schematic figures on the next page for identification
of the tracks* The events take place in a liquid hydro¬
gen bubble chamber, placed in a magnetic field per¬
pendicular to the plane of the figure* (The reader
should try to determine which way the magnetic field
vector points.) Neutral particles do not leave visible
tracks, but charged particles leave tracks which are
curved because of the magnetic field. In the above
situation positive particles turn in the clockwise direc¬
tion, whereas negative particles turn in the opposite
direction.
It so happens that this photograph shows another
interesting event, namely the decay of a positive pion
into a positive muon and a neutrino, followed by the
decay of the muon into a positron, a neutrino and an
antineutrino. The neutrinos (and the antineutrino)
are neutral and leave no visible tracks. (Photograph
by courtesy of Dr. P. Schmidt, Berkeley.)
could have taken place so that some galaxies consist of matter

whereas others consist of antimatter. If we reject the idea of anti¬
galaxies there then remains the mystery of why the state of the
world is so unsymmetric in that one kind of matter dominates, in
spite of the fact that the basic laws of physics seem to be almost
completely symmetric.
Can Photons Be “Split?”
31 Our discussion so far suggests an interesting and very funda¬

mental question: is it possible to split a photon of frequency w into
two parts, such that each part carries some fraction of the energy
fiw, but such that each part is still of frequency w?
We know that classical electromagnetic theory describes a wide
variety of experiments with light very accurately. We have also
said that the relation between energy and momentum of a “photon”
is something which can be derived within classical electromagnetic

theory. Is it not then permissible to say that a photon is simply a
wave packet, or a wave train, of radiation which is governed by the
laws of classical electromagnetic theory? We have clearly now
asked a question of fundamental importance. If photons can be
split in the above sense then the whole structure of ideas which we
have tried to build in this chapter would totter.
To answer our question, we must turn to experiments. In order
to see what kind of experiments we should perform, we will now
adopt a completely classical point of view and then make some pre¬
dictions which we can test in actual experiments to decide whether
the classical picture is correct.
32 A classical wave train of electromagnetic radiation may arise

as follows. As the source of radiation, we have an antenna and a
transmitter which we can switch on and off at will We let the
transmitter, which operates at a frequency w, be on for a certain
length of time, and the antenna then emits a wave train of finite
duration: this wave train is the classical almost monochromatic
“photon.” We may imagine that an excited atom acts like an
antenna of this kind.
Let us again emphasize that we are trying to compare the be- These two figures identify the tracks seen in the
havior of a physical photon, such as it manifests itself in actual bubble chamber photograph on the preceding page.
experiments, with the behavior of the classical wave train* This In the upper figure an incident anti proton collides with
discussion involves the comparison of an object actually occurring a proton at the point C. A neutron and an anti neutron
result from this reaction. The invisible track of the
in nature, namely the photon, with something which, as we shall anti neutron is shown dotted above. At the point A
see, does not occur in nature at all, namely an electromagnetic the anti neutron undergoes an annihilation reaction
wave train which follows the laws of classical electrodynamics with a proton. Five charged pions are produced in
exactly. We are therefore comparing fact and fantasy: to avoid this reaction. The incident anti proton is one among
mixing fact and fantasy, we shall call the real thing the photon and a number of negative particles in a beam of particles
traversing the chamber from right to left. These par-
the imaginary thing the wave train, To convince ourselves that tides are probably all anti protons,
the wave train is not the real thing, we must make some definite The lower figure shows the tracks of the charged
predictions based on the wave train picture which we can then particles involved in the sequential decays of a positive
test through experiments. pion. The spiral track is due to the positron. As it
moves through the liquid hydrogen it looses energy,
and the radius of curvature of the track accordingly
33 We consider the emission of light from a mercury atom which decreases. Its ultimate fate is to disappear in an
has been excited in a collision* The emitted light is blue, of fre¬ annihilation reaction with an electron in the liquid.
quency o). That the emitted wave train should always be of the
same frequency w is not hard to understand: this frequency must
correspond to some natural frequency of oscillation of the atom.
It is hard, however, to understand, on the basis of classical theory,
why the energy carried by the wave train should always be ftw.
We would expect the collisions to differ in violence: sometimes
164 Photons Sea 4.34
more, and sometimes less energy becomes available for light emis¬
sion. What is even harder to understand is why two totally dif¬
ferent atoms, say a sodium atom and a mercury atom, which emit
light of different frequencies, wna and <OHg> should emit wave trains
of total energy and Hg> respectively. From a classical
standpoint the appearance of the universal constant of propor¬
tionality ii is very mysterious.
If we think about the totality of all the many experimental facts
which we discussed in Chapter 3 it is very clear that the phenomena
cannot be understood on a classical basis. Let us, however, try to
forget temporarily what we already know about the emission and
absorption processes, and instead concentrate on the study of
“isolated” photons. We consider wave trains which have been
emitted from some source, and we study these wave trains with
a photocell in the experimental region.
34 We study, in other words, the photoelectric effect. We set

the retarding potential in the cell at a value Vo. If W is the work
function of the photosensitive surface we will thus detect a wave
train (the register attached to the photocell will “click”) provided
the energy carried by the wave train exceeds the value
£mm = *V0 + w (34a)

We set Vo such that
Ho) > Emin > ffico (34b)
Robert Andrews Millikan. Born 1868 in Morrison,
Illinois. Died in 1953. After studies in the United where w is the frequency of the light. (We arbitrarily pick $ as a
States and Germany, Millikan held a professorship at number larger than \ but smaller than one.) Therefore, if we
the University of Chicago, and later at California Insti¬ concentrate the entire energy of the emitted wave train into the
tute of Technology, Pasadena, Millikan is known in
photocell, then the register will click. However, if only half of
particular for his determination of the charge of the
electron, and for his work on the photoelectric effect. this energy reaches the cell, the register will not click, because then
He received the Nobel prize in 1923. (Photograph by the energy imparted to the electron could not possibly overcome
courtesy of Professor L B. Loeb, Berkeley.) the retarding potential.
35 The classical picture suggests an obvious experiment in which

we split a wave train, for instance with the arrangement shown in
Fig. 35A. Light from a source of very low intensity falls on a beam
splitter, say a half-silvered mirror, or a suitable beam-splitting
prism. We can arrange it so that the intensity of the transmitted
beam equals the intensity of the reflected beam, and so that the
intensity of each one of these beams is half the intensity of the
beam emerging from the source through the slit. This is, in other
words, a possible realistic experiment, and we do find that the
intensities of the transmitted and reflected beams are as stated.
Sec. 4,36 Photons 165
QassicaDy, we can understand these facts easily: each wave train Screen
arriving at the mirror is split into two parts, with
Consider now what happens when a single wave train arrives at slit Beam
the mirror* On the classical model, we expect it to be split into I splitter
two parts, and in such a way that the energy carried by the trans¬
mitted part of the wave train is one-half the energy of the incident Light -~a
Photocell 2
wave train. Therefore, the photocell 2 should never click! source
This prediction* based on classical theory, is in flat contradiction
p
with experience. The light which goes through is still blue, of
i
frequency cj, and the register of cell 2 does click as long as
Hw > Emin, which shows that the energy of the transmitted light Photocell 1
comes in packets of Huy. What does happen when the mirror is
inserted is that the counting rate is only half its value in the absence Fig. 35A Schematic figure to Illustrate the discus¬
of the mirror. sion in Sec. 35. The light beam from the source is
divided into two parts by the beam splitter, which may
be a hall-silvered mirror. Are the individual photons
36 How convincing is the evidence that photons cannot be split split?
with the experimental arrangement shown in Fig. 35A, or with any
other arrangement of a similar kind? The evidence is exceedingly
good* and, in fact, photon-splitting experiments go on all the time.
Every optical device in which we have a photoceD, or a photo¬
graphic plate, can be regarded as an instrument in which we try
to split photons, but fail* The simplest observation of this kind is
the observation of the photoelectric effect at different distances r
from the light source. If an atom is like an antenna, then it should
emit light in the form of a spherical wave train. The intensity of
the emitted light is proportional to 1/r2, and on the classical pic¬
ture, the amount of energy carried by a single wave train through
a unit area at a distance r is proportional to 1/r2. Therefore, since
the photocell has some definite cross section, it would seem that
by merely placing the photocell at a sufficiently large distance, the
fraction of the energy in a wave train which can possibly be active
in the photocell can be made as small as we please, and for a fixed
retarding potential, the photoceD should cease entirely to register
as soon as the distance exceeds a certain limit. This is most cer¬
tainly not what we observe: all that happens is that the counting
rate of the photoceD diminishes as 1/r2. Perhaps the most striking
example is the observation of the photoelectric effect for light from
a very distant star. The wave train was emitted thousands of years
ago, and should have spread out over a large portion of space.
Only a minute fraction of the energy carried in the wave train
should be able to reach the photoceD through the telescope. Never¬
theless, the amount of energy given to the electron in the photoceD
is found to be just as if the source were a lamp close to the
photoceD.
166 Photons Sec, 4.37
37 Any attempted explanation of these facts along the lines that

we might be seeing a cumulative effect in which very many “frao-
tional photons” transfer a small amount of energy to the electron
in the photosensitive surface and in such a way that the electron
is finally ejected, when the accumulated energy is large enough,
is wholly untenable* If this were the explanation, then this cumu¬
lative effect should also work when the retarding potential is set
such that Emin > 100 $co, which is certainly not what we
observe: if the retarding potential is too large, the photocell never
registers*
38 The experimental facts connected with the photoelectric effect

therefore lead to the inescapable conclusion that almost mono¬
chromatic photons cannot be split into two photons of the same
frequency which carry only a fraction of the energy of the original
photon: photons do not behave like classical wave trains in this
respect. This conclusion is further supported by the experimental
results concerning the Compton effect, X-ray emission, pair pro¬
duction and pair annihilation which we have discussed earlier in
this chapter. In our theoretical analysis of these phenomena we
made the definite assumption that the relation £ = always
holds, i*e*, that “fractional photons” do not exist, and on this basis
we could indeed understand many of the experimental facts*
Something must therefore be wrong with the classical ideas, and
we want to find out just what it is that has to be changed* We
should be careful not to draw any hasty conclusions at this point*
Let us instead consider some other experimental facts which also
have a bearing on the question of whether photons can be “split.”
Our discussion so far has shown us that in one definite sense of
the word, photons cannot be split. This does not exclude the pos¬
sibility that photons can be “split” in some other sense*
39 Consider a two-slit diffraction experiment, as shovvn schemat¬

ically in Fig. 39A* The opaque screen has two slits, U and L,
perpendicular to the plane of the paper. The light source S illumi¬
nates the two slits with light (photons) of a well-defined frequency
co. For simplicity, we assume that the slits are identical in size,
and with a width small compared to the wavelength* We further¬
more assume that the separation, 2a, between the slits is compa¬
Fig. 39A Very schematic figure to illustrate our dis¬ rable to the wavelength A = 2i7c/£d.
cussion of two-slit diffraction, Does an individual We carry out measurements of the intensity of the diffracted
photon go through only one of the slits, or can it go
light as a function of the angle of observation 8, and at a distance r
through both as the classical wave train picture sug¬
gests? Does the two-slit interference pattern change from the screen which is large compared with the slit separation 2a*
as the intensity of the incident light is diminished? To measure this intensity, we can imagine that we employ a photo-
cell: the intensity is then proportional to the counting rate observed

with the cell.
40 Let us now see what classical electromagnetic theory says

about the intensity distribution to the right of the screen. Our
assumption that the width of the slits is small compared to the wave¬
length means that if either slit is covered, then the angular distribu¬
tion of the diffracted radiation is a smooth function of the angle 6.
Let Aq denote the amplitude of the diffracted wave for the case
when there is only one slit, either the upper or the lower slit shown
in Fig. 39A. Ao — Ag(r,0) is, of course, a function of r and 0, and
using the complex representation, we can write
A0 = e-*»* (40a)
where /(r,0) describes the spatial dependence of the amplitude.

With the experimental arrangement shown in Fig. 39A the dif¬
fracted wave observed at a large distance from the screen is the
sum of the two waves from the two slits. They are of equal ampli¬
tude, but the wave from the lower slit is retarded in phase by the
amount (4tto/A) sin 8 relative to the wave from the upper slit. The
amplitude of the combined wave is thus
iwa
A = /(r,0)e_w exp sin +
= 2Ao cos sin (40b)
The intensity of the diffracted radiation is proportional to the

absolute square of the amplitude, and we accordingly have
2 == 4Io(rt8) cos2 (40c)
where
Io(r,8) = | A012 (40d)
is the intensity observed with only a single slit. The intensity

I(r,8) in the two-slit experiment is thus equal to the product of the
intensity in the single-slit experiment and the factor 4 cos2 [(2ma/X)
sin 0], which describes the effect of interference of the waves
emerging from the two slits. We note that because of this inter¬
ference we will observe zero intensity in certain directions, pro¬
vided 4a/A >1. In certain other directions the intensity will be
four times as large as in the single-slit experiment. We are here
specifically interested in these interference effects, as described by
168 Photons Sec. 4A1
our relation (40c)* That the intensities I and Jq should be related

in this manner is the essence of our classical prediction,
41 In view of what we have learned about the impossibility of

“splitting” photons we might be tempted to conclude that the clas¬
sical prediction contained in Eq* (40c) must be wrong* We could
argue as follows* Each photon must go through one of the slits
since photons cannot be split* Suppose a particular photon goes
through the upper slit. In that case the presence of the lower slit
cannot affect the diffraction of this photon, and the intensity pat¬
tern of all the photons going through the upper slit must be given
by Iq(*\0)* Similarly for the photons which go through the lower
slit, and we might conclude that the intensity J* with both slits
open is given by
/*M) = 2/oM) (41a)
We have denoted the predicted intensity by I * to indicate that

we arrived at this prediction by rejecting the classical ideas leading
to the prediction of Eq* (40c), Now the reader should note that
we have not said that we are forced to the conclusion (41a) by our
earlier discussion of photon splitting: we merely wanted to explore
this possibility*
42 The experimental evidence is conclusively in favor of the

wave-theory prediction (40c), We can regard our simple two-slit
diffraction experiment as the prototype of a large class of inter¬
ference experiments among which we note measurements with
diffraction gratings, and X-ray diffraction experiments with crystals*
The equation (41a) states that the waves diffracted by the two slits
do not interfere with each other, and if this prediction were correct
for the two-slit experiment it would clearly follow that we could
not see any interference effects with diffraction gratings or crystals
either*
Before we reject the prediction (41a) as absolutely wrong we
should worry about the following: could it perhaps be the case that
the interference phenomenon described by Eq. (40c) arises because
of some kind of “interaction” between several photons? With a
sufficiently intense light source we will have several photons in
transit at the same time, i*e*, several photons passing through the
slits simultaneously, and we might wonder whether the interference
effects are possibly “many-photon phenomena*” This line of think¬
ing leads us to inquire whether the prediction (41a) is correct for
extremely feeble sources, such that only one photon is effectively
in transit at a time, whereas the prediction (40c) is correct for
Sec. 4A3 Photons 169
sufficiently intense sources. In other words: Is it so that the nature

of the diffraction pattern changes from that described by Eq. (40c)
to that described by Eq. (41a) as the intensity of the source is
decreased?
The answer to this question is no: there is not the slightest evi¬
dence that diffraction patterns would change their nature as the
intensity of the radiation tends to zero. Our accumulated results
of experiments on diffraction and interference support, beyond
reasonable doubt* the ideas on which the prediction (40c) is based.
43 An experiment directly bearing on this question was carried

out in 1909 by G. I. Taylor, f Taylor photographed the diffraction
pattern in the shadow of a needle illuminated by an extremely
feeble light source. In one of these experiments the exposure time
was 2000 hours, or about 3 months. In this case the intensity is so
low that only a very small number of photons could have been
effectively present within the apparatus at any one instant. The
diffraction pattern produced was, however, just as dear and sharp
as the pattern produced with a strong light source. The precise
theoretical analysis of Taylors experiment is a bit tricky (among
other things because his description of what he actually did is not
sufficiently detailed) and we shall not attempt it here. We can,
however, assert with confidence that the intensity of the light was
indeed so low that if the nature of the diffraction pattern really
changes as the number of photons in transit is reduced, then this
effect should have shown up in the experiment. As we have said,
there was not the slightest hint of any such effect.
We want to emphasize that our belief that diffraction patterns
do not arise as the result of some kind of “interaction” between
a large number of photons does not rest only on Taylors somewhat
barren experiment. It rests on a very large number of other inter¬
ference experiments which we have found that we can describe
correctly on the basis of the wave picture, irrespective of the inten¬
sity of the radiation present.
44 Let us now try to formulate a simple theory in terms of which

we can account for the experimental results which we have dis¬
cussed so far. Our theory goes as follows:
L Almost monochromatic radiation, of the approximate fre¬
quency w, emitted by a light source can be thought of as consisting
of discrete “packets of radiation,” which we call photons.
t G. I. Taylor, “Interference Fringes with Feeble Light,1' Proc. C ambridge Phil, See
15, 114 (1909).
IL The propagation of each photon in space is correctly de¬

scribed by Maxwell's equations of classical electromagnetic theory*
Each photon can, for the purposes of this description, be regarded
as a classical wave train defined by the two vector fields E(r,f) and
B(r,f) which satisfy Maxwell's equations with the appropriate
boundary conditions determined by the physical situation at hand.
In particular, photons will be diffracted by obstacles, and the dif¬
fracted waves can be described within classical theory* A wave
incident on a half-silvered mirror, or on a screen with two slits, will
indeed be “split” into two waves, and these two waves can interfere
with each other as predicted by classical theory*
III. It is not correct to interpret the sum of the squares of the
amplitudes E and B as representing the energy density in space
associated with the photon. This classical idea is wrong. Instead,
every quantity depending quadratically on the wave amplitude is
to be interpreted as being proportional to a probability for some¬
thing to happen* For instance, the integral over the sum of the
squares of the amplitudes E and B over some finite region in space
does not equal the energy carried by the photon in this region, but
is instead proportional to the probability that the photon will be
observed in this region if we try to “catch” it with a photocell.
Similarly the classically computed flux of radiation passing through
a hole in a screen is to be reinterpreted as being proportional to
the probability that the photon will be detected if we place a photo¬
cell immediately behind the hole*
IV* If a photon is detected (with a photocell) anywhere in space
the energy delivered to the detector is always equal to #<0. Since
the probability of detecting the photon i$ proportional to the sum
of the squares of the amplitudes E and B we can conclude that the
classical energy density integrated over a region equals the product
of the energy carried by a photon with the probability of finding
the photon in the region. Therefore, if the source of light is kept
steady for a long time, such that a large number of photons are
emitted, then the average energy which can be observed in a region
is indeed equal to the classically computed energy in the region*
*
45 We have now departed from the ideas of classical electro¬

magnetic theory. The new idea which we have introduced is the
probability interpretation of all quantities which depend quad¬
ratically on the electromagnetic field amplitudes. We can continue
to study the propagation of photons in space in terms of Maxwells
equations, but we have a new interpretation for the classically com¬
puted energy density and the classically computed flux of radiant
energy. These quantities are to be interpreted as average quan¬
tities which we will observe with a very large number of photons.
It follows that in an experiment in which we only measure these

averages but do not attempt to observe individual photons, the
classical theory will appear to be correct* On the other hand, if
we do observe individual photons, with a photocell, then the limita¬
tions of the classical theory immediately become apparent
46 Let us now see how we can describe the observational facts

in some concrete cases in terms of our new ideas. We consider
the situation discussed in Sec, 36 in which we observe the photo¬
electric effect at various distances from a steady light source located
at the origin. Suppose the source is approximately monochromatic,
and suppose that it emits, on the average, N photons per second of
frequency w. The photocell is placed at some fixed distance from
the source. It is coupled to a register so that we can count the
number of photons detected by the cell.
Consider now a typical photon emitted by the source. It can be
regarded as a wave train of finite duration, spreading out in all
directions in space, and carrying a total energy flw. We compute,
classically, the total flux of energy Ec which this wave carries into
the photocell. This energy is a certain fraction q = Ec/1i<a of the
total energy emitted. However, according to our new interpreta¬
tion of quantities which depend quadratically on the wave ampli¬
tude, q is in fact equal to the probability that the photon enters
the photocell. (For simplicity we can assume that our photocell
has 100 per cent counting efficiency, in which case q is equal to
the probability that the counter will click when a photon is emitted
by the source.)
For each photon emitted by the source we cannot predict
whether the counter will actually click or not, but we can say that
the probability for this to happen is q. If the counter clicks, then
the amount of energy transmitted from the source to the photocell
equals It follows that the average power transmitted from the
source to the photocell, when the source is kept steady, equals
Wav = Qi\%o = NEe. This average power is in accordance with
the classical prediction.
The classically computed quantity Ec is naturally proportional
to 1/r2 where r is the distance of die photocell from the source.
It follows that q — Ec/H<o is also proportional to 1/r2, and since
the counting rate of the photocell equals qN we see that the count¬
ing rate is inversely proportional to the square of the distance, in
accordance with what is actually observed,
47 Many people have felt that there is something paradoxical

about the circumstances described above. They have argued as
follows. Suppose the distance r is very large, say one light year,
172 Photons Sec* 4A8
After the photon has been emitted it spreads out like a spherical
shell. By the time the wave arrives at the detector the energy
carried by the wave has spread out over a very large region in spaee3
say within some spherical shell of radius one light year. How is it
then possible that the entire amount of this energy can suddenly
become concentrated within the photocell in case the cell does
register? It should take more than a year for the energy within the
“far side" of the shell to reach the cell, otherwise we violate the
principle that no signal can propagate faster than the velocity of
light.
The fallacy in this line of reasoning is to believe in the classical
of radiation expression for the energy density in terms of the electric and mag¬
netic fields. We must remember that the whole purpose of intro¬
Pig. 47A The atom, shown in the center, emitted ducing the concept of the electromagnetic field in physics is to
fight one year ago. The spherical shell of radiation
accordingly has a radius of one light year. It is about describe the interactions between charges* In Vol. II of this series
to reach the photocell at right. If the ceil registers, we learned that it is a convenient concept, and we also learned
the entire energy of the wave is suddenly concentrated that it is sometimes convenient to imagine (in typical macroscopic
in the cell. How is this possible? How can the energy situations) that energy is distributed in space with a density propor¬
from the far side of the shell reach the photocell in
tional to the square of the field amplitude. There was, however,
less time than two years?
The J<paradox’1 evaporates if we give up the das- no physical fact discussed in Vol, II which says that we must take
sical idea that the energy density is proportional to the this idea literally, and we now know that the classical expression
square of the field amplitude. According to quantum for energy density refers to the average energy density which we
mechanics the transfer of energy from the atom to the will observe for a very large number of photons, but it does not
cell is governed by a probabilistic law, and the square
describe the energy density associated with a single photon.
of the field amplitude must be interpreted as a prob¬
ability density. The real question is this: what laws govern the transfer of energy
from an atom in the source to an electron in the detector? This is
what we are studying, and we have now discovered some features
of these laws.
48 Let us return to the diffraction experiment discussed in Secs.

39-42. Suppose that we observe the photons in some direction 8
with a photocell. By observing the counting rate as a function of
8 (while holding the source steady) we can observe the diffraction
pattern* Suppose now that the counter has just clicked. Question:
Through which slit did this photon come? Answer: It came through
both slits: partly through slit U and partly through slit L.
This answer is in the spirit of our simple theory of Sec* 44* If
the object under study were a billiard ball obeying the laws of
classical mechanics then the answer would be shocking* Since,
however, we deal with photons there is nothing surprising about
this answer: it simply corresponds to what actually takes place*
Question: Can we arrange it so that we know through which slit
the photon comes? Answer: Yes, very easily. We simply cover slit
[7, and then we know that all the photons detected must have come
Sec, 4A9 Photons 173
through slit L* If we do that we will, of course, not see the two-

slit diffraction pattern, but only the one-slit pattern. That does
not answer the real question, says the reader. We want to do this
experiment with the help of some ingenious device without cover¬
ing either slit* In other words: we want to preserve the two-slit
diffraction pattern in exactly the form it has without the ingenious
device, but nevertheless be able to tell through which slit each
particular counted photon came. Can we do this?
Suppose it were possible* In that case we would simply first
discard all the counts for which the photons came through slit [/,
and then plot a diffraction pattern on the basis of the remaining
counts, for which the photons came through slit L, What would
this pattern look like? It would have to look like the single-slit
pattern, because we are assured that “nothing came through slit t7,”
and in that case slit U might as well have been closed. Similarly
the pattern obtained on the basis of all the counts associated with
photons which came through slit 17 must be the single-slit pattern*
All counts taken together would then lead to a pattern as predicted
in Sec. 41, i*e*, the pattern would not be the actually observed
two-slit pattern* In an experiment in which we observe the two-
slit pattern we cannot tell through which slit any particular photon
came. The pattern can arise only if the photons go partly through
both slits, and it is then meaningless to ask which one of the slits
the photon came through.
49 We have now learned many interesting things about the

behavior of photons* The simple theory which we formulated in
Sec* 44 is the first step toward the formulation of a quantum-mechan¬
ical theory of electromagnetic radiation. Naturally our discussion
in this section is not the whole story of quantum electrodynamics:
there is much more to be learned. In particular there is much
more to be said about processes involving many photons. Our aim
in this chapter was, however, to arrive at a simple preliminary
quantum-mechanical formulation in terms of which we can describe
the most basic facts having to do with photons, and this we have
done. The essence of our theory is that whereas the wave ampli¬
tude associated with a photon can be discussed as in classical
electromagnetic theory, all quantities which depend quadratically
on the amplitude must be interpreted in terms of probabilities, A
photon can be “split” in the sense that the wave can be divided into
two, or several, parts by half-silvered mirrors or other devices, just
as in classical electromagnetic theory* However, an almost mono¬
chromatic photon cannot be “split” in the sense that we can detect,
with a photocell, a “fractional photon” which carries only some
174 Photons Sec, 4,50
fraction of the energy #<0, where to is the frequency of the photon*

These ideas constitute a dear departure from the ideas of classical
electromagnetic theory. It would, however, be an exaggeration to
say that the classical theory has been completely overturned: we
have merely discovered limitations of the classical theory.
We want to emphasize that there is nothing paradoxical or mys¬
terious at all about the experimental facts which we have discussed.
Naturally we may occasionally feel perplexed about what we find
in nature, and the reason for this is that we look at the facts with
prejudiced minds* We have opinions about how things ought to
be, and then we feel unhappy when our expectations are netful-
filled. We must learn, however, to accept things as they are, and
try to find simple and consistent descriptions of the observed phe¬
nomena*
The reader should understand clearly that our theoretical ideas
in this chapter derive from experimental facts. The results of one
set of experiments never enable us to derive, by pure logic, what
must happen in some different set of experiments* We might be
led to guesses, but that is another thing* There is no reason in the
world why things have to be the way we have described them in
this chapter. It could just as well have been the case that “frac¬
tional photons” occur, or that a diffraction pattern does change its
character as the light intensity is reduced.
50 We conclude this chapter by urging the reader to think about

the remarkable theoretical value of an “Optics Kit” containing a
few photocells, with associated electronic counting circuits, diffrac¬
tion gratings, some monochromatic light sources, and a few other
standard optical devices. With such a kit we can learn a lot about
fundamental physics* In its high ratio of educational to monetary
value the Optics Kit is quite unique among the apparatus of experi¬
mental physics*
1) A set of reprints has been published by the American Institute of Physics, 335 East
45th Street, New York, N.Y., under the title: Quantum and Statistical Aspects of Light
As the title indicates, these papers deal with various properties of photons* and the
reader may find some of them interesting. A short survey of the literature is included.
2) We refer again to the books The World of the Atom, edited by H. A. Boorse and
L. Motz, Vols. I and II, (Basic Books, Inc., New York 1966), for translations and reprints
(with editorial comments) of many early papers relevant to the subject matter of this
chapter.
Problems Photons 175
3) The following articles in the Scientific American can properly be read at this stage
of our discussion;
a) G, E, Henry: "Radiation Pressure/' June 1957, p. 96.
b) W. H, Jordan: "Radiation From a Reactor/' Oct. 1951, p. 54 (discusses the
Cerenkov radiation).
c) G, Burbidge and F. Hoyle: "Anti-Matter/' April 1958, p. 34,
d) G. B, Collins: "Scintillation Counters/' Nov., 1953, p, 36.
Problems
1 An atom, or nucleus, of mass Mu decays by the emission of a photon.

The final mass of the particle is Mf (after the emission of the photon). The
emitted photon is observed in the inertial frame in which the atom was
originally at rest; let the frequency of the photon be w. Let us define wq by
wo “ (Mi — Mf)c2/H,
(a) Show that
(Mi + Mf) Wo#

W — ---=
W0 = Wo
2Mi 2 MiC2
(b) Compute — to)/w for the yellow line emitted by sodium. Similarly
(wq
compute (wo — w)/w for the 113 keV gamma ray emitted by the hafnium
isotope 72Hf177.
The formula above describes the recoil-effect In photon emission. As we
see, the emitted photon is always of smaller frequency (in the rest frame of
the emitter) than the frequency w0 which it would have for an infinite Mf,
For optical photons emitted by atoms the effect is extremely small,
2 Consider the inverse of the process discussed in Frob. 1. An atom, or

nucleus, of mass Mf, originally at rest in the laboratory, absorbs a photon of
frequency w* The final mass of the atom (or nucleus) is Mu Let again wo =
(Mi — M/)c2/#. Derive a relation between w, w0, Mt and M{♦ Note that for
small relative changes in mass the frequency eo is very close to wo.
3 On the basis of the data given in the graph in Fig. 23A, determine h/e
to the accuracy permitted by the accuracy of the graph. (The velocity of
light is regarded as known.)
4 Examine Compton's curves in Fig, 20 A* The abscissa is roughly pro¬

portional to the wavelength. Using the data in the third graph, try to predict
the displaced maxima in the second and fourth graphs, and compare with the
actual curves.
5 Examine the graphs in Fig. 16A, We notice that the abscissa is

expressed in two different ways: as a velocity and as a frequency. The energy
of the gamma ray emitted from the excited Fe57 nucleus is 14,4 keV,
Knowing this, can you relate the velocity to the frequency in the two scales
shown on the graph?
6 If we think about the graphs in Fig. 16A we notice a remarkable

feature: the recoil effect discussed in Frob. 2 is absent. This phenomenon is
known as the Mossbauer effect after its discoverer, f Can you think of any
explanation of this effect? After you have thought about it you can peek in
the literature: it is an interesting phenomenon,
7 Gamma rays of wavelength 0.710 A are scattered in a thin foil of

aluminum. The scattered radiation is observed at an angle of 00a from the
incident direction. What wavelengths would you expect to see?
8 Suppose an electron-positron pair annihilates into three gamma rays.

If we observe one of the gamma rays in the rest frame of the electron-positron
pair (we assume that the annihilation takes place when the electron
and the positron are almost at rest), what are the possible energies of the
photon?
9 Photons are incident normally On the plane boundary which separates

a uniform dielectric, of refractive index n, from the vacuum. We assume
that the photons, of frequency w, enter from the vacuum.
(a) What is the frequency, and energy, of a photon inside the dielectric?
(b) Can one assign a momentum to the photon inside the dielectric? If so,
give an expression for the momentum. How is the momentum related to
the wavelength, and what is the wavelength inside the dielectric?
10 A charged particle traveling in empty space at a uniform velocity

cannot radiate electromagnetic radiation (photons): conservation of energy
and momentum forbids it. Investigate whether a charged particle traveling
inside a dielectric at a uniform speed greater than the velocity of light in the
medium can emit photons. It turns out that this is possible, and the radiation
is known as Cerenkov radiation. (We are here only concerned with balancing
energy and momentum, and not with the detailed 'mechanism” responsible
for the emission,) The emitted photons emerge at a certain angle with
respect to the direction of the charged particle, Find this angle under the
assumptions that the refractive index is 1.5, the particle is a pion of energy
5 BeV, and the photon is in the optical range. Detectors for charged particles
f R. L. MQssbauer, "Kernresonanzfluoreszenz von Gammastrahlung in Ir191,”

Zeitschrift fur Physik 151, 124 (195S). A translation of this article, and reprints of
other articles on the same subject can be found in The Mimhauer Effect, edited by H.
Frauenfelder (W, A. Benjamin, Inc,, New York, 1962).
Problems Photons 177
in which the phenomenon of Cerenkov radiation is exploited are commonly

employed in high-energy physics. The mass of a pion is 140 MeV.
11 (a) When a charged particle moves in a plane perpendicular to a

uniform magnetic field its trajectory will be a circular arc. Assuming that
the particle carries one elementary charge, show that the momentum of the
particle is proportional to the quantity Br, where B is the magnitude of the
field, and r is the radius of the trajectory. Find the conversion factor which
gives the momentum in units of MeV/c if the quantity Br is given in gauss-cm,
(c is here the velocity of light.)
(b) In analyzing his cloud chamber picture (see Fig. 26A) Anderson
determined the energy of the positron from the known magnetic field and
the observed curvature of the tracks. He expresses the momenta in the two A faked cloud chamber picture, showing the track of
a charged particle in a magnetic field which points out
portions of the trajectory as Br = £.1 x 105 gauss-cm, and Bt = 7.5 X 104
of the plane of the figure. (This figure refers to Prob.
gauss-cm. Show that this corresponds to the energies 63 MeV and 23 MeV. 11 on this page.)
(c) Can the sign of the charge, and the direction of motion of the particle, Is this the track of a positron, and if so, in what
be determined from a picture such as the faked cloud chamber photograph direction is it going? Or is this the track of an electron
going in the opposite direction?
on this page? How did Anderson know (see Fig. 26A) that the particle was
How did Anderson know that his picture (see Fig.
a positron rather than an electron going in the opposite direction?
26A) shows the track of a positron, rather than an
(d) In Fig, 26A the magnetic field is perpendicular to the plane of the electron?
figure. Does it point into the paper, or out of the paper?
See Anderson's paper [Phys. Rev. 43, 491 (1933)] for his arguments ruling
out the possibility that his photograph shows the track of a proton.
12 We consider a refinement of the two-slit diffraction experiment dis¬

cussed in Secs. 39-42. (See figure on this page.) We place polarization
filters in front of the slits, in front of the light source, and in front of the ob¬
server, The problem is to find expressions for the intensity, analogous to
Eq. (40c), for various combinations of filters, We assume that the light source
itself emits unpolarized light, and that the slits are not sensitive to the state of
polarization. Consider the following cases:
ft Pu ft Po
absent absent horizontal absent
absent horizontal vertical absent
circular horizontal vertical circular
circular horizontal horizontal circular
circular horizontal vertical absent
A refinement of Fig. 39A. Polarization filters have
been placed as follows: in front of the source, Pv
In the table above “horizontal” refers to a filter which lets through only and in front of the upper and lower slits, and Po in
front of the observer.
light polarized in the horizontal direction, “vertical” refers to a filter which
This figure refers to Prob. 12 on this page. What
lets through only light polarized vertically, and “circular” refers to a filter kind of fringes will we see, for various choices of
which lets through only left-circularly polarized light. filters?
Chapter 5
Material Particles
Sections 1 to 15 The de Broglie Waves 180
16 to 22 Theory of Diffraction in a Periodic Structure 191
23 to 27 There Is But One Planck’s Constant 196
28 to 35 Can Matter Waves Be Split? 200
36 to 46 The Wave Equation and the
Superposition Principle 205
47 to 54 Advanced Topic: The Vector Space of
Physical States 211
Problems 217
Chapter 5 Material Particles
The de Broglie Waves
1 In this chapter we shall study the properties of material par¬

ticles, by which we mean particles of non-zero rest mass, such as
electrons, protons, neutrons, mesons, molecules, etc.
It is a simple experimental fact that material particles have wave
properties. This fact is known today not only by people educated
primarily in the physical sciences, but also by many others. We
must remember, however, that the wave nature of an object such
as the electron was once regarded as quite surprising. The reason
for this surprise was simply that physicists had become accustomed
to thinking about the electron as if it were a classical corpuscle.
The early experiments concerning electrons seemed to imply such
a model, and before 1927 nobody had performed any clear-cut
experiments in which the wave nature manifested itself. In his
high school physics coursef the reader has very likely already
learned about some of the experiments through which the wave
nature of the electron was established, and we shall discuss these
experiments further in this chapter*
For photons the wave properties were discovered first and the
corpuscular properties later. For electrons the order was reversed.
Because of this historical sequence of events | the general public
tends to believe that light consists of waves, and that electrons are
corpuscles. This is an incomplete picture* In the future it will
undoubtedly become much more generally known that photons
and electrons, and indeed all particles, are very similar in the sense
that they all have some corpuscular properties and some wave
properties.
2 It is of interest to retrace the prediction and discovery of matter

waves because this was an important advance in our knowledge
of physics. We shall follow a quasi-historical approach in the first
part of this chapter, and the reader is asked to forget, temporarily,
what he learned in high school about matter waves. We will imag¬
ine that we have gone back in time to the period around 1923*
At that time quite a bit was known about the electron as a classical
tSee, for instance, PSSC, “Physics" (D. C. Heath and Company Boston, 1965),
Part IV,
f The author believes that the historical order of discovery can be understood
theoretically, on the basis of the smallness of the fine structure constant a.
Sec* 5.3 Material Particles 181
particle, but nothing was known about its wave properties, That
the photon has some corpuscular properties was, however, known.
Let us play a make-believe game in which we ask whether a
material particle, say an electron, might possibly have some prop¬
erties of a wave. To find out we must turn to experiments, but
before we do that we should try some theoretical ideas first to see
what we might expect.
3 To associate a wave with a particle may seem like a highly un¬

motivated act, and we certainly do not claim that we can prove
logically that such a wave must exist. There are, however, analogies
with optics to which we can point. Consider an optical instru¬
ment, and the passage of light through this instrument* We know Fig* 3A The refraction of a plane wave at the plane
that we could in principle describe the instrument by solving Max¬ interface of two homogeneous media of different
refractive indices. The wave fronts, i.e., surfaces of
well's equations with the appropriate boundary conditions, and if constant phase, are here planes. They are repre¬
we do this we can describe the propagation of the waves from the sented by the thin whole lines in the figure. The rays,
light source to the image of the source. There is, however, a sim¬ which are‘perpendicular to the wave fronts, are drawn
pler way of discussing optical instruments, namely by the method dotted. We can think about them as representing
of ray optics. We can show, basing our discussion on the rigorous trajectories of photons. To a given family of wave
fronts corresponds a set of trajectories, of which the
wave equations, that this method must yield an approximate solu¬
two trajectories shown are particular members.
tion. We trace the passage of a Eight ray through the instrument, Actually the wave is aiso partially reflected, although
and this ray can be regarded as the trajectory of a photon. How this is not shown in the figure for aesthetic reasons.
is the ray related to the waves? The ray is at each point perpen¬
dicular to the wave front: in each small region in space the wave
appears approximately like a plane wave, and a light ray passing
through this region is perpendicular to the planes of constant phase*
We have here an association between a "particle” and a wave, and
it is this optical analogy which we try to exploit to formulate a wave
theory of material particles*
Ideas along these lines were first put forward by L. V, de Broglie
around 1923. t We can well admire him for the intellectual courage
he showed in presenting a new idea of this kind.
Fig* 3B This figure is analogous to Fig. 3Ar and is
intended as an illustration of the discussion in Sec. 3.
4 Let us now follow in de Broglie's footsteps and suppose, for the Wave fronts are shown for the case of a plane wave
purpose of theoretical experimentation, that there is a wave asso¬ incident on a lens from left Two rays, or trajectories
ciated with every moving particle. Let the particle be moving in of photons are also drawn. Note that they intersect
the absence of any external forces, in which case the motion is at the local point. To the system of wave fronts cor¬
responds again a set of trajectories.
uniform. Let the energy be E and the momentum be p, and let Close inspection reveals some imperfections in this
the mass of the particle be m, figure. These are not merely due to defective drafts¬
// there is a wave associated with a particle moving in this man- manship, but reflect the fact that a perfect lens does
not exist. The figure is strictly correct only in the
paraxial region, i.e., in the immediate neighborhood
f L, V. de Broglie, “Ondes et quanta/' Comptes Rettdus 177, 507 (1923); "A tenta¬ of the axis.
tive theory of light quanta/' Philosophical Magazine 47, 446 (1924); " Recherches snr Reflections will, of course, take place at the various
la throne des quanta," de Physique 3, 22 (1925). interfaces. This is not shown in the figure.
182 Material Particles Sec* 5.5
ner we would expect that this wave must be moving in the same
direction as the particle* We represent the wave by the complex
wave function
^(x,t) = A exp (ix - k — icof) (4a)
where A is the constant amplitude of the wave, k is the wave vector

and co is the frequency. Our problem is to try to guess the rela¬
tionship between k and w which characterize the wave, and the
variables p, E and m which characterize the particle.
The wave described by the wave function is a plane wave:
the planes of constant phase being given by (x - k — cot) = const.
These planes, and thereby the wave, propagate with the phase
vebcity
We might at first be tempted to equate the phase velocity Vf

with the velocity of the particle, v = pc2/E, but on second thought
it is the group velocity which we expect to be equal to the velocity
of the particle. The group velocity is the velocity by which a signal,
or an amount of energy, can be transmitted in space, and we may
properly think about the particle as a "packet*' of energy.
5 In Vol. III of this series t we derived an expression for the group

velocity v of a wave packet, namely
1 _ dk^ _ dto dv
v do) 1 dv dk
We argued that the group velocity v must be the velocity of

the particle* To go further we must make a guess on how the
frequency to depends on p and E. Let us guess that the relation
E — which holds for photons, also holds for material particles.
We then have
me2
■fito
VI - (u/c)3
Inserting this into the second equation (5a) and rearranging,
we obtain
dk _ 1 dw
dv v dv
t Berkeley Physics Course, Vol, III, Wavest Chap. 6,

Sec. 5.6 Material Particles 183
Integrating this equation, assuming that k = 0 if v = 0, we

obtain
mv
yl “ (v/c)2
or, in vector form,
ftk = p
This was the relation proposed by de Broglie,
6 In arriving at the relation rftk = p we made the somewhat

dubious assumption expressed by the left side of equation (5b),
We may ask whether we might not obtain the same result from a
less drastic assumption supplemented by the requirement of rela¬
tivistic invariance. Let us explore this possibility and at the same
time convince ourselves that our equations (5b) and (5d) are con¬
sistent with the theory of special relativity.
First of all we must find out how k and w transform under Lorentz
transformations. Suppose that the wave is described by the wave
function as given by Eq. (4a) in the unprimed frame. The
same wave is described in the primed frame, which moves with
the velocity v with respect to the unprimed frame, by the wave
function
^(x',0 = A' exp (?xy * k' — i<oY) (6a) Louis Victor de Broglie. Born 1892 in Dieppe, France.
De Broglie first studied history, but later changed over
where A' is a constant amplitude which may or may not be equal to physics. He obtained his doctoral degree from the
to A, University of Paris in 1924. Since then he has held
Let us suppose that the primed frame is the rest frame of the positions at the Sorbonne, at the Henri Poincar£ Insti¬
tute, and at the University of Paris. He received the
particle. In this frame we thus have k' = 0, p' = 0, and Ef = me2,
Nobel prize in 1929.
Let us furthermore suppose that the relation (5b) holds in the rest The title of de Broglie's doctoral thesis was iJRe-
frame (but perhaps not in any other frame): under this assumption cherches sur la Th4orie des Quanta,’' and it contained
we have to' = me2/ft. the essence of his ideas about matter waves. (Photo¬
graph by courtesy of Physics Today.)
7 The phase of the wave is given in any one frame by the expres¬
sion (x • k — <of), and this quantity we assume to be an invariant:
if the phase has a certain value at the point x', at the time f, in the
primed frame, then the phase should have the same value at the
corresponding point x, at the corresponding time t, in the unprimed
frame, We defend this assumption by pointing to the periodic
nature of the wave. If the phases for two events in space-time
differ by an integral multiple of 2*it in one frame of reference, then
the phases of the same wave must differ by the same integral mul¬
tiple in every frame of reference. From this it follows that the
184 Material Particles Sec* 5.7
phases in the primed and unprimed frames can differ by at most a

constant, and this constant can be absorbed in the ratio AfA\ in
which case the phase is an invariant as we have assumed* With
this assumption, and with our choice of the primed frame as the
rest frame of the particle, we have
x * k — uf = — H — — f (7a)
The quantity if may be expressed in terms of x and t, and the

velocity — v by which the unprimed frame moves with respect to
the primed frame, and the relation between these quantities is
given by the Lorentz transformation discussed in Vol* I of this
series, f namely
f - (x • v)/c2
(7b)
Vi - (u/c)2
and if we insert this expression into (7a) we obtain
. V (mc2/^) f(x ■ v)/c2 —

-
(7c)
Since this relation must hold for every x and every t it follows that
w = (7d)
VI - («/c)2
k _ (7nv/K)
(7e)
>
C*
rH
V
1
On the other hand the velocity of the particle in the unprimed

frame is just v, since the particle was assumed to be at rest in the
primed frame* The energy E and momentum p of the particle in
the unprimed frame are therefore given by
me2 mv
(7f)
vT VI - Wcf
Taken together the equations (7d) to (7f) lead to
E (7g)
We accordingly recover the result (5e) and furthermore we see
that the equation (5b) which was introduced ad hoc in Sec* 5 indeed
must be generally true if it holds in the rest frame. This line of
reasoning thus shows us that the relations (7g) are consistent with
f Berkeley Physics Course, Vol. I, Mechanics, Chap. 11.

Sec, 5,8 Material Particles 185
special relativity: we have now in fact derived these relations on

the basis of relativistic invariance.
8 Following in de Broglie's footsteps we have thus been led to

the hypothesis that there may be a wave associated with a moving
particle, and that this wave is characterized by the wave vector k
related to the momentum p of the particle by p = fikr Differently
stated the wavelength X of the matter wave will be given by
h __ 2?r
X
p k
which is known as the de Broglie equation} the wavelength X being

known as the de Broglie wavelength of the particle. Notice that
these relations also hold for photons.
In order to see how the de Broglie wavelength depends on the
parameters of a moving particle, let us write the relation (8a) in
several alternative forms. The form
X= (MV1-fr/c)2
\mc / (u/c)
shows us that X decreases as the velocity v increases* For a fixed
velocity v the wavelength X is inversely proportional to the mass m.
9 If £ denotes the total energy of the particle, as before, we can

write
he (hc/E)
VE2 “ m2c4 Vi - K /£)2
which shows us that for m fixed the wavelength X decreases when E

increases* For a fixed total energy E the wavelength X increases
with the mass m, A massless particle has the smallest de Broglie
wavelength (for a given energy), and it is given by
X = £ (9b)
Since this expression is obtained from (9a) by setting (me2)/

E = 0, we see that it also holds approximately in the extreme rela¬
tivistic limit when the velocity v is very close to c, or, differently
stated, when the total energy is very large compared with the rest
energy.
Let T denote the kinetic energy of the particle, in which case
E = T + me2 (9c)
186 Material Particles Sec* 5.i0
We substitute this expression for E into (9a) and we obtain
X = = k - 1 - (9d)
\/T(T + 2me2) V§mT VI + T/(2mc2)
For a fixed rest mass m the wavelength A decreases when the
kinetic energy T is increased. For a fixed kinetic energy T the
wavelength A likewise decreases as m is increased.
In the limiting case when the velocity of the particle is very small
compared to c, the ratio T/mc2 becomes very small. Setting this
ratio equal to zero in Eq* (9d) we thus obtain an expression for the
wavelength A in the non-relativistic approximation
X gs h - - eg A (9e)
y2mT mV
which we could, of course, also have obtained directly from (8a).
10 We now wish to see whether de Broglie's hypothesis about

the matter waves is confirmed by experiments. First of all we
should convince ourselves that the idea of the matter waves does
not contradict our common-sense knowledge of macroscopic
physics.
Consider a particle which is small for the macroscopic standpoint
Suppose, for instance, that the mass m of the particle is 10"5 gm5
or 10 micrograms, and suppose that this particle moves with the
velocity v = 1 cm/sec. Using the nonrelativistic expression (9e)
for the de Broglie wavelength we obtain, for our case, A ^ 6.6 X
10~22 cm, which is a ridiculously small wavelength. The smallness
of this wavelength explains why the matter waves, if they exist, are
not more apparent in macroscopic physics: the wave lengths are
simply too small to be observed. We may refer to the optical
analogy to understand this point clearly* The method of ray-optics
is more accurate the smaller the wavelength is compared to all rele¬
vant dimensions of the optical instruments. To see the wave
properties of light in an optical experiment we have to arrange it
so that some geometric parameters of the instrument are compar¬
able to the wavelength of the light: only then will we observe
deviations from ray-optics in the form of interference and diffrac¬
tion effects* To detect the presence of the matter waves, we must
likewise arrange it so that the wavelength is comparable with some
geometric parameter of the instrument* Specifically we should try
to find a grating by which we can observe diffraction effects,
11 Inspection of the formula (8b) shows that if we wish to have a

large wavelength we should try to perform the experiment with a
particle with the smallest possible mass, namely the electron, and
furthermore we should try to keep the velocity as small as is feasible.
Since we want to consider the case when the velocity is very small
we can employ the nonrelativistie approximate expression (9e) for
the de Broglie wavelength. If we rewrite this expression specifically
for electrons, of mass m, and kinetic energy T, we obtain
x = = A“gs“,m (lla)
The wavelength will thus be one Angstrom unit = 10_s cm if

the kinetic energy of the electron is 150.4 eV. This wavelength is
of the same order of magnitude as the lattice constant of crystals,
and, just as in the case of X-rays, we could try to employ a crystal
lattice as a grating.
Experiments along these lines were first performed by C. J.
Davisson in collaboration with L. H. Germer, and independently
by G. P. Thomson, in 1927. t In the experiment by Davisson and
Germer the reflection of electrons from the face of a crystal was
studied, whereas in Thomson's experiment the transmission of elec¬
trons through a thin crystalline film was studied.
12 Let us consider the Davisson-Germer experiment in some

detail: the experimental arrangement is shown schematically in
Pig. 12A.
We shall let Davisson describe the history of his own experiment:
the quotation is taken from his Nobel lecture, given in Stockholm
in 1937. (Davisson and Thomson shared the 1937 Nobel prize for
their discoveries.) This quotation is interesting because it reveals
that the experimental issue was not as clear-cut in 1927 as it seems
in retrospect. After a preliminary discussion of de Broglie's hypo¬
thesis Davisson continues:
It was implicit in the theory that beams of electrons like beams of light
would exhibit the properties of waves, that scattered by an appropriate
grating they would exhibit diffraction, yet none of the chief theorists
mentioned this interesting corollary, The first to draw attention to it
was Elsasser, who pointed out in 1925 that a demonstration of diffraction
would establish the physical existence of electron waves. The setting of
the stage for the discovery of electron diffraction was now complete.
f C. J. Davisson and L, H. Germer, "Diffraction of electrons by a crystal of nickel,"

Physical Review 30, 705 (1927).
G. F. Thomson, “Experiments on the diffraction of cathode rays,” Proceedings of the
Royal Society (London) 117A, 600 (1928), and “The diffraction of cathode rays by thin
films of platinum,1* Nature 120, 80S (1927).
155 Material Particles Sec. 5*13
It would be pleasant to tell you that no sooner had Elsasser’s sugges¬

tion appeared than the experiments were begun in New York which
resulted in a demonstration of electron diffraction—pleasanter still to say
that the work was begun the day after copies of de Broglie’s thesis
reached America* The true story contains less of perspicacity and more
of chance. The work actually began in 1919 with the accidental dis¬
covery that the energy spectrum of secondary electron emission has, as
its upper limit, the energy of the primary electrons, even for primaries
accelerated through hundreds of volts; that there is, in fact, an elastic
scattering of electrons by metals.
Out of this grew an investigation of the distribution-in-angle of these
elastically scattered electrons. And then chance again intervened; it
was discovered, purely by accident, that the intensity of elastic scatter¬
ing varies with the orientations of the scattering crystals* Out of this
grew, quite naturally, an investigation of elastic scattering by a single
crystal of predetermined orientation. The initiation of this phase of the
work occurred in 1925, the year following the publication of de Broglie's
thesis, the year preceding the first great developments in the wave mech¬
anics. Thus the New York experiment was not, at its inception, a test of
the wave theory. Only in the summer of 1920, after I had discussed the
investigation in England with Richardson, Bom* Franck and others, did
it take on this character.
The search for diffraction beams was begun in the autumn of 1926, but
not until early in the following year were any found—first one and then
twenty others in rapid succession. Nineteen of these could be used to
check the relationship between wavelength and momentum and in every
From case the correctness of the de Broglie formula, A = h/p was verified to
electron gun within the limit of accuracy of the measurements.
I will recall briefly the scheme of the experiment. A beam of elec*
trons of predetermined speed was directed against a (111) face of a crys¬
tal of nickel as indicated schematically in [Fig* 12A], A collector
Collector designed to accept only elastically scattered electrons and their near
/\ neighbors, could be moved on an arc about the crystal. The crystal

itself could be revolved about the axis of the incident beam. It was
possible thus to measure the intensity of elastic scattering in any direo-
tion in front of the crystal face with the exception of those directions
lying within 10 to 15 degrees of the primary beam.
13 In the experiment the beam of electrons was produced in an

electron gun, in which the electrons were accelerated to the desired
energy., of the order of 50 eV* The crystal was, of course, placed
in a vacuum* The electrons were incident perpendicularly on a
particular crystal plane, technically known as the (111) plane. In
Fig* 12A Schematic figure showing the diffraction this plane we can imagine a lattice of regularly spaced atoms on the
of electrons from the surface of a single crystal. For
surface of the crystal* To understand the principle involved we
a fixed energy of the incident electrons the intensity
of the e/asfrcafiy scattered beam is observed as a first consider a simple one-dimensional model, shown schematically
function of the angle 0, in Fig* 13A* (We shall consider the general theory a bit later*)
Sec. 5.14 Material Particles 18Q
The incident wave is diffracted by each atom in the row* In certain j

directions (in the plane of the figure) the diffracted waves from all Incident :
beam | Reflected
the atoms will reinforce each other, whereas in other directions i beam
they will tend to cancel* The condition for constructive inter¬
ference (i.e.? mutual reinforcement of the diffracted waves) is that
the differences in the distances from different atoms to the point Crystal
of observation shall be integral multiples of the wavelength* If we surface
imagine that the point of observation is very far away we easily
see, by inspection of Fig* 13A, that the condition for constructive
interference is
Fig. 13A To illustrate discussion in Sec. 13. Figure
d sin 6 = nk (13a) shows linear array of equally spaced atoms. We car
also interpret a dot as a line of atoms perpendicular
where n is an integer. This relation simply says that the difference to the plane of the figure. Diffraction maxima occur
in directions such that d sin 0 is an integral multiple
in path from two neighboring atoms to the point of observation is
of the wavelength.
an integral multiple of the wavelength* We thus expect diffraction
maxima in the directions for which the angle 9 satisfies the condi¬
tion (13a). We regard the lattice spacing d as known: it can be
determined by other means, for instance through X-ray diffraction
measurements.
Our simple theory obviously also applies to the case of a two-
dimensional lattice if we imagine that each dot in Fig. 13A actually
represents a row of atoms, in a direction perpendicular to the plane
of the figure* Photographic plate
In a typical experiment the data were as follows: d = 2*15 x Cones of
10^8 cm, E — 54 eV, and a maximum was observed at 9 — 50°, diffracted rays
For n = 1 the experimentally observed 6 gives a wavelength of
1.65 A, whereas the wavelength computed from Eq. (11a) is L67 A, Incident
which is a satisfactory agreement. Davisson also observed higher direction
order maxima, corresponding to n > 1, all in accordance with the
theoretical predictions* Sample
14 Thomson^ method is analogous to the so-called Debye- Diffraction rings

i
Scherrer method in X-ray diffraction work* A unidirectional mono¬
chromatic incident beam of X-rays or electrons is scattered by a Fig* 14A Diffraction of X-rays or electrons from a
sample consisting of a very large number of small randomly oriented sample which is an aggregate of small randomly ori-
microcrystals* The theory predicts that the diffracted waves will ented crystals. The diffracted rays lie along a set of
circular cones, the pattern of which depends or the
emerge along the surfaces of circular cones, centered about the
crystal structure and on the incident wavelengths.
incident direction* (See Fig. 14A*) If the scattered radiation is The photographs 14B^C, 22 A and 22C were ob
recorded photographically on a plate perpendicular to the incident tained by this method. In electron diffraction work
direction we thus obtain a set of concentric circles* The pattern the sample must be inside the vacuum of the diffrac-
of circles depends on the crystal structure in a characteristic way, tion apparatus, because the electrons would be
strongly scattered by air and by any intervening J'win¬
and if the wavelength is known it is possible to determine com¬
dow’' in the tube. X-rays are scattered much less,
pletely the geometry of the crystal lattice. and the sample can be kept in air, outside the X-ray
Figs. I4B and 14C are two photographs obtained by this method, tube,
190 Material Particles Sec. 5.15
Fig. 14B Photograph showing electron diffraction

by white tin, by the method shown in Fig, 14A. Very
small tin crystals (size about 300 A) were deposited
on a thin film of silicon monoxide. The film was
placed as the sample in an electron microscope which
was here used as an electron diffraction apparatus.
The sample was illuminated by electrons of an energy
of 100 keV, (This corresponds to a wavelength of
about 0,04 A,) The diffraction rings which can be
seen correspond to the intersections of the cones in
Fig, 14A with the photographic plate.
The purpose of this particular diffraction experi¬
ment was to check the crystal structure of the very
small tin crystals formed by an evaporation process.
(Photograph by courtesy of Dr. W. Hines and Profes¬
sor W. Knight, Berkeley.)
the first with electrons and the second with X-rays. The samples
were in both cases aggregates of small crystals of white tin. The
similarity in the pattern of circles is very striking. Even if we know
nothing about the detailed theory of diffraction of waves in lattices,
a glance at these two photographs will at once convince us that
X-rays and electrons are diffracted in the same way.
15 The experiments of Davisson and Germer and the related

experiments of Thomson thus show beyond any reasonable doubt
that matter waves do exist, and that their wavelength (at least for
electrons) is given by the de Broglie relation. In 1929 Estermann
and Stemt showed that helium atoms and hydrogen molecules are
also diffracted in accordance with the de Broglie theory. Their
experiments greatly strengthen our belief in the universality of the
matter waves since they involve two new particles very different
from the electron. Apart from the difference in mass the helium
Fig. 14C Photograph showing X-ray diffraction by atoms and hydrogen molecules differ from the electron in that they
white tin, by the method shown in Fig. 14A. (This are clearly composite systems whereas the electron is (perhaps) an
is actually not a flat photographic plate, but a strip elementary particle. The experiments thus show that the atom
of film which was curved as a circular arc during the
exposure. This does not change the essence of the
as a whole and the molecule as a whole are waves, and we are per¬
experiment.) The sample was in the form of a small haps now willing to believe that under suitable experimental con¬
amount of finely powdered tin, with an average crystal ditions a grand piano will also behave like a wave.
size of about one micron. The wavelength used was Later the diffraction of very slow neutrons in crystal lattices was
about 1.5 A, shown to take place, and out of these observations there have devel¬
This picture should be carefully compared with Fig.
oped techniques which are used today in a routine manner to
14B. The similarity is striking, and there can be no
doubt that electrons and X-rays are diffracted by tin
crystals in the same way, (Photograph by courtesy t1. Estermann and O. Stern, “Beugung von Molekularstrahlen,” Zeitschrlft fur
of Mr, George Gordon, Berkeley.) Physik 61, 95 (1930).
investigate the structure of crystals and molecules as a complement

ei
to X-ray and electron diffraction methods, t
Fig, ISA Linear array of equally spaced atoms.

Theory of Diffraction in a Periodic Structure$
16 Let us consider the diffraction by a one-, two-* or three-dimen¬

sional lattice in some detail, A lattice is a periodic structure which
we can imagine built up of replicas of a unit cell Pigs. 16A-C
illustrate this idea. For a one-dimensional lattice the unit cell is
simply a line segment \ for a two-dimensional lattice a parallelogram,
and for a three-dimensional lattice a parallelepiped, Let us imag¬
ine, for simplicity, that an atom (of a given kind) is located at each
comer of the unit cell. The positions of all the atoms in the lattice
are then given by
x = niei (16a)
for the linear lattice and by

x = mei 4- n2e 2 (16b)
for the plane lattice and by
Fig, 16B Two-dimensional lattice. The unit cell is
x = rciei + ra2e2 + n3e3 (16c) delined by the two vectors ©i and ©2. Its edges are
drawn heavier in the figure, The entire lattice is built
for the three-dimensional lattice. The numbers ni, n2, and n3 are up of replicas of the unit cell.
here integers, and the vectors ei, e2, and e3 define the unit cells,
as shown in Figs. 16A-C,
In the following we shall imagine that the lattice contains a finite
but very large number of atoms. To prevent misunderstandings,
let us also state explicitly that we are considering one-, two-, and
three-dimensional arrays embedded in three-dimensional space,
and not, say, a two-dimensional lattice in a two-dimensional world.
17 We consider the situation illustrated schematically in Fig. 17A.

A wave is emitted by a source located at the point x*. It is dif¬
fracted by an array of identical atoms, and the diffracted, or
scattered, wave is observed at the point xo. We shall assume that
the center of the array (occupied by one of the atoms) is at the
origin, and that the distances %{ = | x* | and Xo — | xo | are very large
compared to the linear dimensions of the array. We first consider
the case of a one-dimensional array. Very similar considerations
t D, P. Mitchell and P, N, Powers, "Bragg reflection of slow neutrons,” The Physical Fig. 16C Three-dimensional lattice. The edges of
Review 50, 486 (1936), See also E. O. Wollan and C. G. Shull, “Neutron diffraction the unit cell are again drawn heavier, The position
and associated studies," Nucleonics 3, 8 (1948), vector of any lattice point is some linear combination
| Sections 16-22 can be omitted in a first reading, but do not fail to look at the photo¬ with integral coefficients of the vectors ©i, ©2, and ©3.
graphs in Sec, 22, (These vectors are not necessarily perpendicular,)
192 Material Particles Sec. 5,18
Source apply to a two-dimensional or to a three-dimensional scattering

array.
The length of path from the source to the observer via the origin
is so = Xi ± xo* Let s(ni) be the length of path from the source
to the observer via the atom whose position is descrilied by the
integer n\y according to the formula (16a). We then have
Xi — -n-iei + xo — ritei (17a)

The waves arriving at the observer from the different atoms
interfere with each other, and the resultant wave amplitude is the
sum of the amplitudes from each atom. For a diffraction maximum
all the waves must arrive in phase with each other, otherwise the
waves from the different atoms will cancel* The condition for this
is that for each atom, i.e., for each integer ni3 the path difference
Fig* 17A Diffraction by a linear array. (To illustrate s(ni) — so must be an integral multiple of the wavelength X.
discussion in Sec. 17.) In the text it is assumed that Since we assumed that the size of the array is very small com¬
the distances from the array to the source and to the pared to the distances to the source and to the observer, the vector
observer are large compared with the size of the array.
ttiei will be very small compared to the vectors x^ and xo- We can
The array itself consists of a finite but very large num¬
ber of atoms. then write an approximate expression for the two distances in the
The unit vector u* points in the incident direction, right side of Eq* (17a), namely
and the unit vector in the direction of the scattered
beam. (*i * ei)
Xf — rciei \ = %i — Ui (17b)
Xi
x0 — niei (17c)
The geometric significance of this approximation is at once ap¬

parent from Fig. 17B*
We then have for the difference in path
s(na) - s0 s -the!1 (17d)

\ Xi Xo/
18 Let Mi be the unit vector in the direction of the incident beam,

and let u<> be the unit vector pointing in the direction of the dif¬
fracted beam. We then have
Xi x0
Ui —-> u0 = — (18a)
Xi Xo
If we now let x% and xq in (17d) tend to infinity we obtain

Fig. 17B To illustrate an important approximation
which is frequently made in discussions of physics. s(n-i) — so — mei • (u* — u0) (18b)
If the length of the vector e is very small compared
with the vector x, this vector is almost parallel with and the condition for a diffraction maximum reads
the vector x + f, The length of the latter vector is
approximately equal to the length of x plus the projec¬ that ’ (Ui - uo)
(18c)
tion of e on the direction of X
where nT must be an integer for every choice of the integer

This will obviously be the case if and only if
ei * (uj — up)
= mi (18d)
X
where mi is an integer. This we might have concluded imme¬
diately* The waves from any pair of atoms arrive in phase with
each other if and only if the waves from two neighboring atoms
arrive in phase with each other* and this is just what the condition
(18d) says.
Making use of the de Broglie relation we can rewrite (18d) in a
physically interesting form, as follows. Let p* be the incident
momentum, and let po be the momentum in the scattered beam*
We then have
_ Pi u0 _ po
X “ h * X ~ h
and the condition (18d) can be written
ei - (pi - po) = ei • q = mxh (18f)

where q = pi — po is the momentum transfer to the array* For a
one-dimensional array the condition for a diffraction maximum is
thus that the scalar product of the momentum transfer q with the
vector ei must be an integral multiple of h: the momentum transfer
in the direction of the array is “quantized,”
19 It has been tacitly assumed in our discussion that the scattering

process is elastic, which means that the energy (or frequency) of
the scattered particle is the same as the incident energy (or fre¬
quency), This implies another condition: the magnitude of the
incident momentum is the same as the magnitude of the scattered
momentum, The locations of the diffraction maxima are thus deter¬
mined by the two conditions
ei * (pi - po) = ei * q = mih (19a)
and
|Pi| = |po (19b)
where mi is any integer.

For an infinite array the scattered momentum must satisfy the
conditions (19a) and (19b) exactly* For a finite array we also ol>
serve some scattering outside the directions defined by the above
conditions. The sharpness of the diffraction maxima (as functions
of the angle) depends on the number of atoms in the array- We
194 Material Particles .
Sec 5.20
assume that the number is large and the scattered particles there¬
fore emerge in very well-defined directions, as given by (19a) and
(19b). These equations define a set of cones, one for each integer
mi. These integers are, of course, subject to the constraint
W*i| =i2|ei| |pi|/fe (19c)

since the momentum transfer cannot exceed twice the incident
momentum*
20 We can easily find the corresponding conditions for diffraction

maxima for a two-dimensional array. The condition (19a) must
hold in each lattice direction, i*e*, for each fine containing more
than one atom* In particular it must hold for the edges of the unit
cell, and we thus have the conditions
ei ‘ (Pi - Po) = mih, e2 • (p* - po) = m2h (20a)

Fig* 20A Above is shown the diffraction pattern of
electrons scattered backward from the face of a nickel
| pi | = | Po| (20b)
crystal. The electrons were incident perpendicularly
where mi and m2 are any integers. We can again say that the
on the crystal surface, and their energy was 76 eV.
momentum transfer in the plane of the lattice is “quantized.” To
This is a typical case for which our theory of diffrac¬
tion by a two-dimensional lattice applies. show this more clearly, let us define two vectors qi and q2 in the
(ei,e2)-plane by the conditions
Fig* 20B Below is shown the planar symmetry of
this particular face of the crystal. We can imagine = ft, <*•<], =0
that the small circles represent the nickel atoms in
the surface layer. The diffraction pattern exhibits a
ei ■ q2 = 0, e2 • q2 = h v
similar rectangular symmetry. Question for the
reader: are the two figures correctly oriented with These equations always have a unique solution* Notice that the
respect to each other, or should the lower figure have vectors qi and q2 will in general not have the same directions as
been turned 90°? the vectors ei and e2, unless the lattice is rectangular.
(Electron diffraction photograph by courtesy of Dr. The conditions (20a) then read
A. U. MacRae, Bell Telephone Laboratories, New
Jersey.) q = Pi - po = raiqi + ^2q2 + q* (20d)
where mi and m2 are any integers, and where the vector q* is an

arbitrary vector perpendicular to the lattice plane* The momen¬
tum transfer in the lattice plane is quantized, but the orthogonal
component is not. Its magnitude is determined by the condition
(20b) which says that the scattering is elastic. We can therefore
find several solutions to the equations (20a) and (20b) provided the
incident momentum is not too small (i.e*, provided the wavelength
is not too large). The diffracted rays in this case emerge in a num¬
ber of sharply defined discrete directions, and not along cones, as
was the case for the one-dimensional array*
In the experiment of Davisson and Germer the low-energy elec¬
trons do not significantly penetrate the crystal. The diffraction is
by the atoms in the surface layer, and the theory for the two-dimen¬
sional lattice therefore applies.
21 For the three-dimensional array we have
ei' (pi - Po) = miK

*2 * (p* - Po) = mh, (21a)
e3 • (pi - po) = m3h
IPil = po| (21b)
where mi, m2, and m3 are any integers. In analogy with what we
did in the preceding section, let us define three vectors qi, q2, and
q3 by the conditions
ei - qi = ht ©2 ’ qi = 0, e3 * qi = 0
ei - q2 = 0, e2 ■ q2 = h, e3 ■ q2 = 0 (21c)
ei * q3 = 0, e2 ■ q3 = 0, e3 * q3 = h
These equations always have a unique solution. We can then

write the conditions (21a) in the form
q = Pi — Po - wiqi + m2q2 + m3q3 (2 Id)

The momentum transfer q is “quantized” in such a way that it
must be a linear combination, with integral coefficients, of three
vectors qi, q2, and q3 determinedly the geometric structure of the
lattice. If we think about Eq. (21d) we notice that the possible
values of the momentum transfer form a lattice, in momentum
space. This lattice is known as the reciprocal lattice of the crystal.
For an arbitrary incident momentum it is in general not possible
to satisfy both the equations (21d) and (21b). The equations (21a)
and (21b) taken together constitute four equations to determine
the three components of the final momentum po. A solution will
exist only if the crystal happens to be oriented in the right way.
22 Suppose now that we do a diffraction experiment with a

sample which consists of a very large number of randomly oriented
microcrystals. There will then always be some microcrystals so
oriented in the sample that the conditions (21a) and (21b) can be
satisfied (at least approximately). For such a sample we thus have
two conditions for diffraction maxima, namely
miqi + m2q2 + m3q3 (22a)
(22b)
where mu m2, and m3 are any integers, and where qi, q2l and q3
are the vectors discussed in the preceding section, for some par¬
ticular orientation of the crystal lattice* The above equations do
have solutions, and we see that the diffracted rays emerge along
a set of cones centered about the incident direction,
Fig, 14A shows schematically how a diffraction experiment based
on the above theory is performed. In X-ray work the sample is
often a small amount of a fine powder consisting of many small
microcrystals. This is the way the photograph 14C was obtained.
The lines on the film strip are the intersections of the cones [defined
by the conditions (22a) and (22b)] with the film strip.
We can easily understand that if the sample is too small, in the
sense that it does not contain sufficiently many crystals, then the
distribution of the diffracted rays along the cones will be very non-
uniform, We will not see continuous circles on the photographic
Figs, 22A-B The upper photograph shows electron plate, but rather individual dots. This effect is shown very beauti¬
diffraction rings obtained with the method illustrated
fully in the photographs 22A and 22C, These photographs, which
schematically in Fig. 14A. The sample consisted, as
for the photograph 14B, of small white tin crystals should be compared with the photograph I4B, show the diffraction
deposited on a thin film of silicon monoxide. The of 100 keV electrons by tin crystals. In this case the electron waves
lower photograph shows the appearance of the sample completely penetrate the small crystals. An electron microscope
in the electron microscope (8 mm corresponds to was used as a diffraction apparatus. Photographs 22B and 22D,
1000 A). The dark spots are the images of the crys¬ taken with the same electron microscope, show the appearance of
tals (their darkness depends on their orientation).
The lightest spots are pits in the SiO once occupied the sample.
by crystals which have disappeared in the preparation
of the sample. The average size of the crystals is
about 600 A.
In obtaining the diffraction photograph the electron There Is But One Planck's Constant
beam was limited to a comparatively small area of the
sample. In view of the theory in Sec, 22 we expect 23 The subheading above perhaps surprises the reader. Of
to see individual dots, as the photograph indeed course there is only one Planck's constant, by definition. What
shows, rather than well-developed rings,
deep conclusion does the author intend to draw from this trivial
(Photographs by courtesy of Dr. W. Hines and Pro¬
fessor W. Knight, Berkeley.) fact?
The entirely nontrivial point is that we do not need more than
one “Planck-type constant” in physics. Consider the de Broglie
relation written in the form
h = Ap (23a)
where p is the momentum of the particle, and A its de Broglie wave
length. Both p and A are independently measurable quantities,
and by measuring a pair of corresponding variables (p,A) we can
determine Planck's constant ft. It is a remarkable empirical fact
that we always get the same value for ft, irrespective of which kind
of particle we are observing, and that this is so is not a triviality.
The reader is perhaps not impressed by this. We could, after all,
derive this relation on the basis of some very simple ideas. Let us,
however, examine the premises of our derivation.
24 In our discussion in Secs. 3-5 we assumed that there is a

wave associated with every material particle, and in such a way
that the group velocity of the wave equals the velocity of the par¬
ticle. Furthermore we assumed that the particle-wave description
satisfies the principle of special relativity, which means that the
relationship between the wave vector and frequency of the wave,
and the momentum and energy of the particle, must be the
same in every inertial frame. On this basis we drew the conclusion
that
E = p = #k (24a)
where E is the energy, p the momentum, to the frequency and k the
wave vector, and where # is a constant defined by
£0 = me2 = #w o (24b)
Figs. 22C-D These two photographs were obtained
in terms of the rest energy Eq and the “rest frequency” coq. in the same way as the photographs 22A-B. The
How did we conclude that the constant # is actually Plancks sample here consists of smaller crystals (average size
constant? By guessing. The relation E = holds for photons, about 200 A), and the diffraction pattern arises from
and it is tempting to guess that it will also hold for material particles. a much larger number of crystals. The rings are
better developed, although individual dots can be
But that is just the crucial point: Does the first relation (24a) really
seen. The photographs 22A and 22C should be com-
hold for all material particles? pared with the photograph 14B, in which individual
Therefore, what we really derived in Secs. 3-5 was that the con¬ dots can no longer be seen. The latter photograph
nection between energy, momentum, frequency and wave vector is was taken with an electron beam traversing a much
larger portion of the film. We accordingly expect a
E = Cto, p = Ck (24c) well-developed ring pattern since all orientations of
the crystals are well represented in the sample.
where C is a constant characteristic of the particle, and this constant The electron energy was 100 keV for the pictures
is defined, for instance, by 14B, 22A and 22C. This corresponds to a wavelength
of about 0.04 A.
(Photographs by courtesy of Dr. W. Hmes and Pro¬
(24d)
fessor W. Knight, Berkeley.)
There is, however, no reason why C has to be the same constant

for all particles. Our world might have been different, and we
might have found, experimentally, that C = # for photons, C = 7#
for electrons, C = 17# for protons, and, to top it all, we might have
found that whereas electrons and protons are associated with
de Broglie waves, there are no matter waves associated with neu¬
trons!
25 Fortunately the available experimental material seems to rule

out the horrible possibility that the “Planck-type constants” C are
different for different kinds of particles. We say “fortunately”
because our aesthetically pleasing present-day formulation of quan¬
tum mechanics depends in an essential way on the assumption that
C = # is a universal constant, independent of the kind of particle.
198 Material Particles Sec 5,26
*
If this were not the case the theory of the'elementary particles and
their interactions would have to be very different indeed.
How well is the hypothesis that C = H for every kind of particle
verified experimentally? Direct experiments, analogous to the
experiments of Davisson and Germer, or Thomson, have been
performed only for a few kinds of particles. Such experiments are
very readily interpreted as tests of the relation h = but they
are naturally of limited precision* They support our belief in the
universality of the relations (24a), but the real basis of our faith in
these relations is the general success of quantum mechanics. There
exists an enormous amount of experimental evidence which sup¬
ports the relations (24a) indirectly. The interpretation of this
evidence is not always as clear-cut and simple as in the case of elec¬
tron diffraction in crystals, but in its totality it is very convincing.
Our belief that the relations (24a) are exactly true is somewhat
analogous to our belief that the relation Eq = me2 is also exactly
true* The direct evidence for this latter relation is quite strong,
but the totality of the indirect evidence, concerning the general
validity of the ideas of special relativity, is what really convinces us*
There is not the slightest hint in our experimental material that the
relations (24a) or the relation Eq = me2, might be only approx¬
imately true* We assume that they are true exactly, and we regard
them as cornerstones of physical theory.
Let us recall our discussion in Sec* 12, Chap. 2* We argued that
because of the fundamental role played by the constants c and #
in relativistic quantum physics one might well select a system of
units in which ft = c — 1. Such a system of units would clearly
not make much sense if there were a different Planck-type con¬
stant C for every particle* Since we believe that there is only one
such constant it means that, for instance, mass, energy and fre¬
quency are always related in the same way, and we can regard
the words “mass," “energy," and “frequency” as different names
for the same thing*!
The reader may wonder whether sound waves also

obey the relations (24a). Indeed they do, and we call
26 In view of the relations (24a) we can restate the conservation
the "particles" of sound waves phonons. The energy laws for energy and momentum which hold for collision processes*
of a sound wave, say in a solid, comes in packets of Understood in a general sense a collision event can be described
magnitude ffo. where w is the frequency, as follows* There is present, at some early time, a number of par¬
We do not regard phonons as elementary particles, ticles moving in such a way that they are well separated from each
because they can be completely explained in terms
of the E1realM particles in the solid. Elastic waves are
collective motions of electrons and nuclei. It isp how¬ t The author would prefer to use the term “mass” only to denote the “rest-mass”
ever. often useful to think about phonons in the same of an isolated system (i.e,, the rest energy divided by c2). With this usage "the mass
way as we think about other particles, and conversely of a particle," whether moving or not, means the rest-mass of the particle. Other
it is sometimes useful to think about the "real" par¬ writers often talk about the “mass" of a particle when they mean the total energy
ticles as if they were "sound waves in the ether." divided by c2.
Sec. S.26 Material Particles 199
other. Let their momenta be pi, p£, ■ * ■ , pi, and let their energies
be Ei, , EJi When we say that the particles are initially
“well separated” from each other we mean that the particles initially
move in such a way that all interactions between the particles are
effectively absent at the early time. This idea makes sense if we
assume that the inter-particle forces tend rapidly to zero as the
distance between the particles increases. At first each particle
therefore moves as if the other particles were absent. As time
goes on the particles may converge in a “collision region,” and
the inter-particle forces come into play. An interaction takes place,
and in this process the particles are deflected Furthermore some
of the particles may be destroyed, and new particles may be
created.
If we wait for a sufficiently long time the particles involved in the
collision event will again be dispersed, and the interactions between
the particles will effectively cease for the simple reason that they
are no longer close together. At some late time each particle will
move as if the other particles were absent. Let the momenta of
the particles after the collision event be pL . .., pj', and let their
energies be E", £2 * * ■ « ? £"■
The conservation laws then read
if if
z*
T—l s—1 r=l 5=1
The total initial energy equals the total final energy, and the total
initial momentum equals the total final momentum. The condition
that the particles effectively do not interact with each other at the
“early time” or at the 'late time” is essential; because otherwise the
total energy would not be equal to the sum of the energies of the
individual particles. If the particles do interact with each other we
have to include an “interaction energy” in the expression for the
total energy.
The reader should note that the particles need not be elementary
particles; they can just as well be composite particles, like atoms or
nuclei. When we discuss collision events we mean by “particle”
any object which is reasonably stable so that it can be assigned a
momentum, an energy and a (rest) mass as soon as it is well sepa¬
rated from other similar objects. As an example we can consider
the collision between a neutral helium atom and an electron. Sup¬
pose that the helium atom is ionized in the collision. There are
then two initial particles, namely the electron and the neutral helium
atom. There are three final particles, namely two electrons and
one singly-charged helium ion, (This is* of course, not the only
possible outcome of the collision event. The helium atom might
lose both its electrons in the event* or it might lose none. Further¬
more the event can lead to the emission of one* or several, photons,)
27 If we now recognize that because of the relations (24a) there

is associated a frequency and a wave vector with each one of the
initial and final particles, we can rewrite the conservation laws
(26a) in the form
i 7 i j
K = V K'
/ j
(27a)
T—l 8=1 r—1 8=1
The sum of the initial frequencies equals the sum of the final
frequencies, and the sum of the initial wave vectors equals the sum
of the final wave vectors. These conservation laws are com¬
pletely equivalent to the conservation laws (26a), Each set of laws
implies the other. This is so because there is only one Planck's
constant.!
Can Matter Waves Be Split?

4
28 In the preceding chapter we discussed the sense in which

photons can, and cannot, be “split” We should now undertake a
similar discussion for matter waves. We can be quite brief, because
the behavior of matter waves is quite analogous to the behavior of
photons. In this respect nature is simple.
To be specific we will now discuss electrons, but our results are
completely general and apply equally well to any other particle.
In the preceding chapter we concluded that a monochromatic
photon* of frequency w, cannot be split in the sense that we could
detect, with a photocell, a “fractional photon,” which carries only
some fraction of the energy In an analogous sense an electron
cannot be split either, because nobody has ever detected a “frac¬
tional electron.”
t To the leader with an advanced knowledge of quantum mechanics: it may seem

as if the relations (27a) could be derived independently, on the basis of the homo¬
geneity of physical space. Such a derivation can indeed be given, provided we accept
certain ideas characteristic of quantum mechanics. On the other hand it is clear that
no purely logical argument could tell us that there is a de Broglie wave associated with
protons, given that electrons have wave properties. Similarly pure logic cannot tell us
that the constant C must be the same for all particles. Momentum and wave vector
have independent operational definitions, and they need not necessarily be connected
by the de Broglie relation.
29 Let us consider an electron-diffraction experiment, shown Incident beam

schematically in Fig. 29A. The beam of electrons incident on the
crystal surface has a well-defined momentum. The reflected elec-
trons are detected by four counters, Ci to C4, and we imagine that
counters Ci and C4 are located at different diffraction maxima,
whereas C2 and C3 are located at diffraction minima.
The first thing to note is that, experimentally, the counting rate
of each counter remains proportional to the incident flux of eleo
trons as this flux tends to zero. This circumstance rules out any
explanation of the observed diffraction phenomena as collective
effects involving a large number of electrons: it is really each
individual electron which shows the wave behavior. To mate the
issues clear we may assume that the counting rates in counters Ci
and C4 are equal, and that the counting rates in counters C2 and
C3 are zero.
Fig. 29 A Schematic figure (to illustrate discussion
Suppose now that we regard an electron as a classical wave in Sec. 29} showing setup to observe electron diffrac¬
packet. We then expect that this wave is “split” in the reflection tion in various directions from the surface of a crystal.
at the crystal: part of the wave is reflected in the direction of Since the incident wave is i£splitls by the crystal, wifi
counter Ci, and part in the direction of counter C4, but nothing in we find only half an electron with counter Ct?
the direction of counters C% and C3. Since the original incident
packet is “split” in this manner we would expect that this “splitting”
manifests itself in some way. For instance: that the energy carried
by the “part” reflected toward counter Ci is some fraction of the
energy of the incident electron. This is, however, not what is
found experimentally, as we may recall from Davisson’s own ac¬
count: the reflected electrons carry the fuU energy of the incident
electrons. If an electron is detected by a counter at all, it is the
whole electron which is detected, with the full electronic charge
and electronic mass. As we have said nobody has ever seen a third
of an electron. Electrons have wave properties but they are most
certainly not classical waves: the electron-wave packet cannot be
split like a classical wave packet.
30 Now it may happen that the reader does not have any firm
opinions about the properties of a “classical wave,” and therefore
the statement that an electron is not a classical wave might appear
a bit colorless. What we have in mind here is that for a classical
wave the absolute square of the wave amplitude at a given instant
of time, and at a given point in space, represents a physical quantity
such as a charge density, or an energy density. This idea is analo¬
gous to the idea in classical electromagnetic theory that the squares
of the electric and magnetic fields represent energy densities.
Suppose, for instance, that the square of the wave amplitude is
proportional to the charge density. We could then compute the
flux of charge into one of the counters, and since the wave is
“divided” between the oounters Ci and C4 we would expect to find

only half the electronic charge in counter Ci* This might be true
on the average; if we perform the diffraction experiment with a
very large number of electrons the flow of charge into counter Ci
may indeed be one-half of the total incident flow of charged
However, each individual electron is either detected by counter Ci
or by counter C4: the charge of an individual electron is not split.
In the spirit of quantum mechanics we describe what happens as
follows. The incident electron wave is divided into two parts by
the crystal. One part of the wave propagates in the direction of
counter Ci, and the other part in the direction of counter C4, The
intensity of the wave in a given direction is proportional to the
absolute square of the wave amplitude. In quantum mechanics the
intensity has a probabilistic interpretation: a quantity which de¬
pends quadratically on the amplitude always represents the prob¬
ability for something to happen. The classically computed flux
into one of the counters is proportional to the probability that the
counter will dick.
This probability interpretation of intensities is a distinguishing
feature of quantum mechanics, and it is clearly contrary to the
spirit of a classical wave theory.
31 In analogy with our discussion in Sec. 47, Chap. 4, the reader

should consider an imaginary experiment in which the arrange¬
ments are as in Fig. 29A, but with the counters at a very large
distance, say one light year, from the crystal. Suppose that an
electron is detected by counter Ci. On the basis of the classical
wave theory it would again be hard to understand how the physical
quantities, such as charge, energy and mass, carried by the wave
could suddenly be concentrated in the counter Ci after having
first been spread out over a large region in space. With the quan¬
tum-mechanical probability interpretation this difficulty evaporates:
we can describe what happens in a consistent way.
32 We have said that the wave is divided into two (or several)
“parts” in the diffraction experiment shown in Fig. 29A. The
reader may then ask: Can the wave traveling in the direction of
counter Cj be made to interfere with the wave traveling in the
direction of counter C4P If an electromagnetic wave is divided by
a half-silvered mirror, then the two “parts” can oertainly interfere
with each other, and we expect the same behavior from the de
Broglie waves. In other words, if we somehow deflect the wave
f This may not be true in practice, but, for the sake of argument, we can assume that
every incident electron goes into either counter Ci or counter C4.
Sec. 5*33 Material Particles 203
traveling in the direction of counter C4, and “mix” it with the wave
traveling in the direction of counter Ci, will we then see interfer¬
ence effects?
The answer is that we certainly expect to see interference effects*
On the other hand it must be admitted that it would be very diffi¬
cult in practice to perform this experiment exactly as described,
with electrons* Fortunately we do not have to do this experiment,
because the very fact that we can observe electron diffraction at all
with the crystal is conclusive proof of the reality of the interference
effects* Each atom in the crystal surface gives rise to a diffracted
wave when “illuminated” by the incident wave, and all these
diffracted waves combine to produce the overall interference
pattern which we observe with the crystal* What does it mean
that the waves diffracted by the individual atoms “combine?”
How do we describe the “combination?” We describe it by adding
the amplitudes of all the separate waves to obtain the total ampli¬
tude of the wave emerging from the crystal* The square of this
resultant amplitude is an intensity variable, to be understood
quantum mechanically, which describes the response of a detector*
33 In Secs, 39-42, Chap. 4, we discussed a two-slit diffraction

experiment with photons. Suppose we perform the same experi¬
ment with electrons* The arrangement is shown schematically in
Fig. 33A. This figure is identical, except for the text, with Fig* 39A,
of Chap. 4. The analysis is also the same, and the intensity I(r,8)>
observed at a distance large compared with the separation between
the slits, is given by
l(r,0) = 4Zo(r,0) cos2 ft- sin 6

s
where is the intensity which we would observe with only one

slit open*
The dependence of the intensity on the angle 0 can be deter¬
mined by counters, and the intensity is then simply proportional to
the counting rate when the experiment is performed with a beam of
electrons*
Experiments entirely analogous to this oversimplified imaginary
experiment have been performed, and we can conclude from the
results that the prediction of Eq* (33a) is correct*!
t G, Mollenstedt and H, Duker, “Beobachtungen und Messungen an Biprisma-

Interferenzen mit Mektronenwellen," Zeitschrift fur Physik 145, 377 (1966)* See also Fig* 33A An imaginary experiment on two slit dif-
R. G* Chambers, “Shift of an electron interference pattern by enclosed magnetic flux,” traction of electrons. This figure is the same as Fig*
Physical Review Letters 5? 3 (I960). This latter paper reports on a very interesting 39A in Chapter 4, except that the light source S is
effect, which we shall not discuss in this book, but which the reader may want to study replaced by a source of electrons,
on his own*
34 If we are to see the interference effect both slits must be open

and each electron must thus pass through both slits. If we want
to make sure that the electron passes through only one of the slits
we must close the other slit, but then we will naturally not see the
two-slit diffraction pattern. If we try to find out through which
slit the electron went by placing counters immediately behind the
slits we will also destroy the interference pattern. The counting
rates observed in the two counters will be the same. For each
electron incident on the screen one, but only one of the counters
may click, and the electron so detected will carry the full charge
and the full energy of the incident electron. We cannot say before¬
hand which one of the counters will click, but we can compute and
predict the probability for registration by finding the intensity of
the wave penetrating the slit.
The reader should return to our discussion, in Sec. 48, Chap. 4,
in which we prove that the two-slit pattern is incompatible with a
knowledge of which slit the photon went through. The same argu¬
ment applies to electrons. There is no clever arrangement whereby
we can determine through which slit the electron went without
disturbing the two-slit pattern.
35 Let us tighten up our language a bit. When we discussed the

discovery of the de Broglie waves we talked about “waves asso¬
ciated with a particle/" This is bad language because it sounds
as if we would have a classical corpuscle traveling together with
a wave in some fashion. Some people like to call the de Broglie
waves “guide waves/' or ‘pilot waves,” but this terminology is also
bad. The de Broglie waves are not waves traveling together with,
and “guiding,” a classical corpuscle. The de Broglie wave and the
particle are the same thing; there is nothing else. The real particle,
found in nature, has wave properties and that is a fact. If we want
to emphasize this fact we might talk about the de Broglie wave of
an electron, but this term is really a synonym for “electron.” Our
excuse for our previous bad language is that our discussion was at
first tentative, as well as historical, and the cautious term “wave
associated with a particle” was therefore defensible. The time has
now come for us to be more precise and definite, and we should
reject a terminology which might lead our thinking astray.
Consider again the two-slit experiment. There is nothing in this
experiment which suggests to us that there might be a classical
corpuscle passing through one of the slits, “guided” by a wave
which passes through both slits. Better stated: Our description
of what takes place in no way improves if we try to introduce this
idea. It is quite enough to discuss the wave only, with the quantum-
Sec♦ 5.36 Material Particles 205
mechanical interpretation of intensities as probabilities. Any talk

about the "hidden" corpuscle is metaphysics unless the assumption
that the corpuscle exists has some definite experimental conse¬
quences which cannot be predicted on the basis of the quantum-
mechanical wave theory alone. No such experimental circumstances
are known, and in view of this we must firmly reject all mental
images of classical corpuscles guided by waves.
The Wave Equation and the Superposition Principle
36 We now want to present arguments in favor of a differential

equation, known as the Klein-Gordon equation, in terms of which
we can describe the propagation of matter waves in empty space.
Our most important assumption is that the wave equation which
describes a single particle, of mass m, shall be a linear differential
equation. This means that the solutions of the equation satisfy a
principle of superposition: Any linear combination of two solutions
of the equation is again a solution of the equation. Furthermore
we assume that every solution of the equation which satisfies cer¬
tain mild conditions represents a possible physical situation, at least
in principle. The physical implications of these assumptions are
far reaching. Amplitudes of matter waves can be added just like
amplitudes of electromagnetic waves. (Maxwell's equations are
also linear differential equations.)
The reader should note that in our discussion of diffraction of
matter waves by atoms on a crystal surface, or by a double slit, we
have tacitly assumed linearity. We thus have added, for instance,
the amplitudes of the waves emerging from the two slits to obtain
a resultant amplitude. We here elevate this procedure to a general
principle of physics.
37 Let us now find a differential equation satisfied by all matter

waves describing a particle of mass m. The procedure is as follows.
We first find a differential equation satisfied by all plane waves, of
the form
i£(x,f;p) = exp (ix * p — io)t) (37a)
We employ units such that ft — c — 1, and we denote the mo¬

mentum (= wave vector) by p, and the energy (= frequency) by to.
Each such plane wave is determined (except for a constant factor
which fixes the amplitude of the wave) by the momentum p. We
try to write a linear differential equation in which p does not occur
explicitly, and which is satisfied by every plane wave. Since it is
linear this differential equation will then be satisfied by every linear

combination of plane waves, and therefore, we shall argue, by every
de Broglie wave describing the particle of mass m.
The energy to and the momentum p are related by
to2 — p2 = m2 (37b)
since the mass of the particle is m,

If we differentiate the wave function ^ twice with respect to
the time t we obtain
= -w2^(x,t;p) (37c)
If we differentiate the wave function twice with respect to the

coordinate xi we obtain
g^2 p) = -Pityfcftp) (37d)
and similarly for the second derivatives with respect to the other
two space coordinates %2 and £3.
We thus obtain, taking into account the relation (37b),
>Kx,t;p) - V2^(x,t;p) = - m2^(x,t;p) (37e)
where V2 stands for the Laplackin operator, defined by
r* = JL + _?L + _?!_
03Ci2 GX22 dXs2
The equation (37e) is the desired wave equation. As we see, this

equation is satisfied by all plane waves of the form (37a) he., for all
momenta p, and hence is also satisfied by any de Broglie wave
which is a superposition of plane waves.
38 The wave equation (37e) is known as the Klein-Gordon equa¬

tion. It is, in a sense, the simplest differential equation satisfied by
the de Broglie waves. Note that this equation is also satisfied by
electromagnetic waves in empty space, with the photon mass
m = 0. The reader can easily convince himself that there cannot
be any differential equation of first order, i.e., involving only first
derivatives with respect to the independent variables, satisfied by
all de Broglie waves. The equation must be at least of second
order, and the reason is that the relation (37b) between energy and
momentum is a quadratic algebraic relation.
We must repeat again, because this is an important point, that
the equation (37e) can describe the propagation of a particle only
in empty regions in space-time, Le*, far away from all other par¬
ticles* Similarly the homogeneous Maxwell's equations, i.e., with
the current density and charge density both equal to zero* describe
the propagation of electromagnetic waves only in regions free of
charges and currents, Le,? in regions free of other particles,
39 A superposition of two plane waves, i.e*, a wave of the form
i£(x,t) = A' exp (ix ■ p' - ito'*) + A” exp (ix * p" - to"f) (39a)
where A' and A" are two arbitrary complex constants, also satisfies
the differential equation (37e). In other words,
= -to2^(x,*) (39b)
Let us consider a more general (continuous) superposition of

plane waves, of the form
I <P(p) A(p) exp (ix * p — ko*)

Jbc) (39c)
Here A(p) is a complex-valued function of the vector p, The

integral is over the entire three-dimensional p-space. The quantity
to is a function of p such that > 0, and such that the equation
(37b) is satisfied. In other words,
w = w(p) = \/p2 + m2 (39d)
The wave function ^(x7t) defined by the integral in Eq. (39c)

also satisfies the differential equation (39b). This is a very general
de Broglie wave, in fact the most general such wave. We assume,
of course, that the function A(p) is a reasonably well-behaved func¬
tion of p so that the integral in Eq. (39c) makes good sense.
40 In the theory of the Fourier integral the following theorem

can be proved: If i^(x,0) is any reasonably well-behaved function of
x, and if we define a function A(p) by the integral
A(p) = (2?r)“3 f d3(x) V'&O) exp ( — ix ■ p) (40a)

*/(*)
then it follows that
^(x,0) = f d3(p) A(p) exp (ix • p) (40b)
This is a theorem. Its precise statement, and its proof, hinges on

an appropriate definition of “a reasonably well-behaved function.”
We shall not prove this theorem here, and we shall not really
depend on the theory of the Fourier integral in our discussion in
this book* In due time the reader will learn how to state this
theorem precisely, and how to prove it, in her calculus course* Our
aim here is to discuss the physical implications of the theorem, and
thereby provide the reader with a strong “physical” motivation for
learning about the Fourier integral* It is of central importance in
physics,
41 Let us now see what the theorem implies. Suppose that

i£(x,0) is a de Broglie wave function at the time t — 0. We can
then associate with this wave function an amplitude A(p) in mo¬
mentum space, through the integral in Eq. (40a), In terms of the
momentum space amplitude A(p) we can then define a new wave
function by
= j d3(p) A(p) exp (ix * p — ioit) (41a)
If we set t = 0 in the above expression and compare with the

formula (40b) we see that î(x,0) = i//(x,0)* The new wave func¬
tion iî(x,£), which satisfies the Klein-Gordon equation (39b), is thus
identical with the wave function i^(x,0) at the “initial time” t = 0.
This means that we have a procedure for solving the Klein-Gordon
equation subject to the initial condition that the solution shall
agree with a given function (of x) at time t = 0.
42 Let us consider the question of the uniqueness of the solution

of the Klein-Gordon equation which we find in this manner* What
is true is that our procedure, according to which we construct the
functions A(p) and iî(x,f) from a given function ^(x,0), is a definite
procedure which leads to a unique function 1//1 (x,t) satisfying the
equation (39b). The question arises whether there might not be
other solutions of the differential equation (39b) which also agree
with ip(x,0) at time t = 0* The answer is yes. The differential
equation (39b) is also satisfied by wave functions of the form
i//(x,£) = exp (ix - p -f u> = ^/p2 + m2
We call these solutions “negative frequency solutions,” in con¬

trast to the “positive frequency solutions” of the form (37a).
We exclude the negative frequency solutions on physical grounds*
They do not represent particles of positive energy (= positive
frequency). Now it is clear that for every positive frequency solu¬
tion of the equation (39b) there also exists a negative frequency
solution of the same momentum p, and the Klein-Gordon equation
Sec* 5.43 Material Particles 209
therefore has twice as many solutions as we want* The reason for

this is that the equation (37b) has two solutions w for every p; one
positive and one negative* Only the positive solution has physical
meaning; the energy of a particle is a positive quantity*
The Klein-Gordon equation (39b) is therefore not the whole
story of the de Broglie waves* We have to add the condition that
all negative frequency (= negative energy) solutions are to be
excluded. With this provision it can be proved that every permis¬
sible solution of the equation (39b) is uniquely determined by its
values at t — 0, and that answers the question which we asked. We
shall not prove this theorem here*
43 The important idea which emerges from our discussion is that

every physically acceptable de Broglie wave function ^(x,tf) can be
represented in the form (41a) where A(p) is uniquely determined,
through Eq* (40a), by the wave function at some specific time, say
time t — 0* Every matter wave can thus be regarded as a super¬
position of plane matter waves* If we like we can regard this as
our basic assumption, and thus down-grade the importance of the
Klein-Gordon equation. It is merely a nice differential equation
satisfied by the physicaDy acceptable wave functions*
44 By a suitable choice of the momentum space amplitude A(p)

in the Fourier integral (39c) [or (41a)] we can construct wave
packets which are approximately localized in some region in space
at a given time. Such a wave has the property that it is appreciable
only in some Limited region in space, but decreases rapidly to zero
as | x tends to infinity. A wave packet of this kind represents a
particle which is approximately confined to a finite region in space*
It is clear that all particles studied experimentally must be described
by such wave functions* We assume, of course, that the particle
is most likely to be found (when we look for it with a counter) in
those regions in space where the wave function is large. This is in
accordance with our quantum-mechanical inteipretation of the
absolute square of the amplitude: it has something to do with the
probability for something to happen* For the time being it suffices
for us to assume that "the particle is most likely to be found where
the wave function is large*” Later we will discuss a particular kind
of wave function, for which we will state a precise prescription for
how to compute the probability of finding the particle in a region*
We can conclude that a single plane wave cannot represent a
particle in an actual experiment. For such a wave the absolute
square of the amplitude is a constant, independent of x (and t),
and the probability of finding the particle in any region of unit
volume is independent of the location of the region. Since space

can be built up of an infinite number of such regions it follows that
the probability of finding the particle in any specific one of these
must be zero. The probability of finding the particle within any
finite region is also zero, which does not make physical sense.
Strictly monochromatic plane waves therefore do not exist. It is
possible, however, for a wave to look like a plane wave of constant
amplitude over an arbitrarily large region of space, although the
amplitude does tend to zero outside this region, If this region
includes the region in which the physical phenomena under study
take place, we can think about the wave as an idealized plane wave.
It is common practice in physics to talk about plane waves, and it
is then understood that such a wave is approximately plane; it looks
like a plane wave over a very large region in space.
45 The Klein-Gordon equation (39b) is satisfied by every wave

function describing the state (of motion) of a particle of mass m. If
we set m = 0 we obtain an equation satisfied by both the electric
and magnetic vector fields of electromagnetic theory. The Klein-
Gordon equation is, however, not identical with Maxwell’s equa¬
tions, and the reader may be bothered by this fact. Is it possible
that Maxwells equations say more than the Klein-Gordon equation?
The answer is yes. Maxwells equations also describe the polariza¬
tion of the photon. The state of motion of a photon is not fully
specified by giving its momentum and energy; we also have to give
its polarization. For every momentum there are two linearly inde-
pendent states of polarization, say the state of left-circular polariza¬
tion and the state of right-circular polarization.
The question arises: can material particles also exhibit different
states of polarization? The answer is that some particles do and
some do not* The pion and the alpha-particle are examples of
particles which cannot be polarized. The electron, the proton and
the neutron are examples of particles which can be polarized. These
latter particles all have an intrinsic angular momentum, or spin, and
to the different orientations of the spin correspond different states
of polarization. The pion and the alpha-particle, on the other hand,
have no spin: there is nothing that defines a direction in the rest
frame of these particles. They are spherically symmetric.
To describe the state of polarization of the particles which have a
non-zero spin we must introduce, besides the variables x and t, a
variable which describes the spin* The wave equation which de¬
scribes the full story of electrons, protons and neutrons, is therefore
more complicated than the Klein-Gordon equation (39b) but the
wave function nevertheless also satisfies the Klein-Gordon equa-
tion, This equation describes, so to speak, the behavior of the

particle in space-time without regard to the spin. We shall not
discuss the quantum-mechanical description of polarization here.
It is somewhat analogous to the description of the polarization of
an electromagnetic wave,
46 In concluding this part of the chapter, let us restate the wave

equation (39b) for the case that we employ the cgs- (or MKS-)
system of units. The constants ft and c are easily restored, and we
have
~2 - V2 ^(x,f) = - (~J 1p(x,t) (46a)
The reader should convince himself, through a dimensional argu¬

ment, that this equation is correct* Note that each term has the
dimension (wave function)/(length)2. The restoration of the con¬
stants ft and c is unique.
Advanced Topic: The Vector Space

of Physical States t
47 Let us state concisely the Principle of Superposition which we

assume holds for the matter waves.
Let 3C' be the set of all wave functions yp which do not vanish
identically, and which represent possible physical states of a par¬
ticle of mass to, To this set of wave functions we add the wave
function which is identically zero everywhere in space, at all times*
The resulting set is denoted 3C. This set has the following prop¬
erties:
(a) If i/q and yp2 are two wave functions in the set 5C, then the
sum (î + ^2) is also in 3C,
(b) If yp is in 3C, and if c is any complex number, then the funo
tion cyp is also in 3C.
The principle of superposition of wave functions specifically says
that if ypi and \p2 are two physically meaningful wave functions,
and if c\ and c2 are any two complex numbers, then the function
yp = + c2yp2 (47a)
is also a physically meaningful wave function provided that it does

not vanish identically.
f Can be omitted in a first reading.

48 The properties of the set X are characteristic properties of

an abstract mathematical object, namely an abstract complex vector
space. Let ns state the postulates in terms of which this object is
defined,
A linear complex vector space X is a set of elements, called
vectors, such that;
I. For any two vectors and in £fC there exists a unique
vector ^ in X, called the sum of i/q and ^2* and denoted ^ +
$2* The operation of forming the sum of two vectors satisfies the
conditions
(a) + ^2 = ^2 + f°r any two $2 in X.
(b) + (fa + 1^3) = (^1 + ^2) + ^3, for any three ^1, ^2, ^3
in X.
(c) There exists a unique vector 0 in X, called the null vector,
such that $ + 0 = for every $ in X*
II. Given any vector |inK, and any complex number cs there
exists a unique vector in X* denoted op, called the product of the
vector ^ by the scalar c. The operation of multiplying a vector by a
scalar (= a complex number) satisfies the conditions
(a) (ciC2)^ = Ci(c2^p) for any vector ip, and any two scalars c±
and c2.
(b) (ci + C2$ — cup + c24> for any vector ip, and any two scalars
ci and C2*
(c) c(ipi + 1P2) — cip 1 + op2 for any two vectors ipi and ip2, and
any scalar c*
(d) For the particular scalar 1 we have 1 ip = ip.
These are the postulates which define an abstract linear vector
space over the field of complex numbers* The latter phrase means
that the scalars by which the vectors may be multiplied are the
complex numbers. If the scalars are restricted to be real numbers
we speak of a linear vector space over the field of real numbers.
For brevity we simply say "complex vector space/1 respectively
“real vector space.” The reader has already encountered an ex¬
ample of a real vector space, namely the three-dimensional Euclid¬
ean "‘physical space.”
49 The postulate la is the commutative law for addition; the

postulate lb is the associative law for addition; postulate Ic con¬
cerns the existence and uniqueness of the null vector* The postu¬
late Ila is the associative law for scalar multiplication, and the
postulates life and lie are distributive laws for scalar multiplication.
Postulate lid says that the identity times a vector equals the vector.
From these postulates we may prove many almost self-evident
facts, such as
0^ = 0, (— l)i// + $ — 0, ( — c)\p = — (op\ etc.
We shall not list all the trivial theorems here, as the author is
confident that the reader's intuition will not lead him astray.
What is the virtue of introducing the concept of an abstract
complex vector space? The answer is that in our study of mathe¬
matical theories we encounter over and over again sets of elements
which, among any other properties which these sets may have,
have the particular property of satisfying all the axioms of an ab¬
stract complex vector space. When we encounter such a set we
need not list the properties of an abstract vector space anew but
we can simply say that the set is a complex vector space, and then
everyone who knows the axioms for a vector space immediately
knows quite a bit about the set.
50 We can now state that the set 3C of all physically acceptable

wave functions, with the identically vanishing wave function ad¬
joined, is a complex vector space. It is a concrete complex vector
space because the vectors are actually “tangible” complex func¬
tions of space and time. If we compare the postulates given in
Sec. 48 with the properties of the set of all wave functions which
we mentioned explicitly in Sec. 47 we notice that the list in Sec. 48
is longer. However, many of the postulates for an abstract vector
space are trivially satisfied by the set of concrete wave functions,
and there was no need to state these trivialities explicitly.
51 Let us note that in the definition of the abstract complex

vector space there is no mention of the dimensionality of the vector
space: it may be finite-dimensional or infinite-dimensional. Let us Paul Adrien Maurice Dirac. Born 1902 in Bristol,
elaborate on this question a bit. England, Dirac first studied electrical engineering,
A set of N vectors $2, . * . , in a complex vector space 3C but later switched to theoretical physics. In 1932 he
are said to be linearly independent if the equation was appointed Lucasian Professor of Mathematics at
Cambridge. He received the Nobel prize in 1933.
Dirac has made many important contributions to
the development of quantum mechanics and quantum
electrodynamics. His celebrated relativistic theory of
the hydrogen atom led him to a theory of anti-particles
which received its spectacular confirmation with
implies that ci = c% = ... = = 0: otherwise they are said to be Anderson's discovery of the positron.
linearly dependent In the early days of quantum mechanics Dirac did
A complex vector space is of dimensionality AT if it is possible much to develop the algebraic approach to the theory.
His ideas are presented in his book The Princip/es of
to find a set of N linearly independent vectors in the space, but
Quantum Mechanics, 4th ed. (Oxford University
impossible to find a set of more than N linearly independent vectors. Press, 1958). (Photograph by courtesy of Physics
The vector space is infinite-dimensional if it is possible to find a Today.)
214 Material Particles Sec♦ 5.52
set of N linearly independent vectors in the vector space for every

integer N.
The vector space 3C of all physically meaningful de Broglie wave
functions is clearly in/irate-dimensional; there is an infinite number
of linearly independent wave functions.
52 We have been concerned with the solutions of the Klein-

Gordon equation, but we can now conclude that if we consider
the totality of the solutions of any linear differential equation, then
this set is always a (complex) vector space. Many different kinds
of linear differential equations have been proposed to describe,
within quantum mechanics, the particles occurring in nature. The
sets of all physically acceptable solutions of these equations always
form vector spaces.
We can state this as follows: To describe a given kind of particle
one may introduce a complex vector space, and associate a vector
in this vector space with every possible state (of motion) of the
particle.
This idea, which is the essence of the mathematical theory of
quantum physics, is a great idea. At first it might not seem so;
to say that a state (of motion) of a particle is described by a vector
in a complex vector space might seem to be nothing more than a
restatement of the principle of superposition satisfied by the solu¬
tions of the wave equation, and perhaps a restatement of question¬
able value* As we penetrate further into quantum physics we
discover, however, the great merits of this idea. For instance: By
noticing that the wave functions form a vector space we can actu¬
ally achieve a considerable simplification in many practical com¬
putational problems. The computational techniques appropriate
to vector spaces are in a sense algebraic in character, and we are
accordingly led to consider the algebraic aspects of the solutions
of differential equations. It turns out that in many problems the
algebraic methods are vastly superior (in computational economy
from the human standpoint) to the direct solution of the differential
equations, especially in problems characterized by special sym¬
metries. In this book we will not be able to demonstrate that this
simplification takes place* The author felt that it was nevertheless
worthwhile to state this fact: the seemingly abstract theory of
vector spaces leads to great simplifications in the solution of prac¬
tical problems. One minor aspect of this simplification is a certain
simplification in notation. (Questions of notation are, by the way,
not always so minor. A bad notation retards progress, whereas a
good notation advances it.)
53 Heisenberg's Matrix Mechanics is a particular formulation of

quantum mechanics in which the vector space aspect of the theory
is emphasized, whereas the wave equations play a secondary role*
At first Heisenberg's theory appears to be very different from the
wave theories, such as Schrodinger s wave mechanics, but the dif¬
ferent kinds of theories are in fact completely equivalent, and lead
to the same physical predictions. They have a common abstract
skeleton, and this skeleton is the abstract vector space theory. Since
we cannot assume that the reader has already learned about ma¬
trices in his mathematics courses we will have to omit the discussion
of Heisenberg’s theory in this book. The theory is not particularly
difficult, but since there are so many other things for the reader
to learn we do not want to load the discussion with a presentation
of matrix theory.
Werner Heisenberg’s first paper on the subject appeared in
1925. t In this paper matrix theory is not mentioned explicitly
because Heisenberg had not realized that his mathematical opera¬
tions had a matrix theory interpretation. The connection with
matrix theory was soon thereafter clarified in an important paper
by Max Bom and Pascual Jordan. \
54 The reader should note that historically matrix mechanics was

invented and developed before Schrodinger had invented his wave
mechanics. We have said that it is a natural idea to regard the set
of all solutions of a linear differential equation as a vector space,
and thereby be led to consider algebraic aspects of the equation.
There is no doubt that had Schrodinger's wave mechanics been
invented first, matrix mechanics would soon have been discovered
as a reformulation of the wave theory. This was, however, not the
way things actually happened. The historical sequence of events
is almost incredible to this author, and he regards the invention Werner Karl Heisenberg. Born 1901, in Wtirzburg,
Germany. Heisenberg studied under Sommerfeld at
of matrix mechanics as one of the most astounding accomplish¬ the University of Munich, and received his PhD degree
ments in physical theory. in 1923. After a fruitful period as Born's assistant
That matrix mechanics and wave mechanics are physically equiv¬ at the University of Gdttingen, Heisenberg spent three
alent was proved by Schrodinger in 1926. § years at Bohr's institute at Copenhagen. He later
held positions at the University of Leipzig, and at the
Max Planck Institute for Physics in Berlin. Since
f W, Heisenberg, “Ober quantentheoretische Umdeutung Idnematischer und mecha- 1946 he has been director of the Max Planck Institute
nischer Beziehungen,” Zeitschrift fur Physik 33, 879 (1925). for Physics in Gottingen. He was awarded the Nobel
{M. Bom and P, Jordan, "Zur Qimntenmechanilt,” Zeitschrift fur Physik 34, 858 prize in 1932,
(1925). The principles of quantum mechanics were further developed by these authors Among Heisenberg's many important contributions
and by Heisenberg in M. Born, W. Heisenberg, and P. Jordan, “Zur Quanten- to theoretical physics his discovery of matrix me¬
mechanik II,” Zeitschrift far Physik 35, 557 (1926). chanics stands out as a most remarkable intellectual
§ E, Schrodinger, “Ober das Verhaltnis der Heisenberg-Bom-Jordanschen Quanten- achievement. (Photograph by courtesy of Physics
mechanik zu der meinen,” Annalen der Physik 79, 734 (1926). Today.)
1) For the history of the topics discussed in this chapter we again refer the reader
to the books mentioned at the end of Chap. 1. (Items 3 and 5.)
2) There exists a vast literature on the mathematical theory of linear partial differen¬
tial equations. The author does not expect the reader to go deeply into this theory
at this time, but he wants to mention one treatise which has played an important role
in physics, namely R* Courant and D* Hilbert; Methoden der mathematischen Physik,
vols. I and II (Verlag von Julius Springer, Berlin, 1931 and 1937.) This work has been
translated under the title; Methods of Mathematical Physics, vols. I and II (Interscience
Publishers, Inc*, New York, 1953 and 1962)*
The second volume discusses partial differential equations* Hie first discusses a
variety of subjects of interest in physics, Such as Fourier analysis, the theory of matrices
and vector spaces, the calculus of variations, and the theory of certain ordinary linear
differential equations which appear in many physical problems.
It so happened that important developments in mathematics, which Later were found
to be '‘made to order*' for quantum mechanics, took place about the time quantum
mechanics was discovered. David Hilbert at the University of Gottingen played a
central role in these developments, and the infinite-dimensional vector space in terms
of which quantum mechanics is formulated today is called Hilbert space, after him.
Hilbert did not originally develop his theory of linear spaces for physical applications,
but the discovery of quantum mechanics naturally stimulated mathematical inves¬
tigations of the questions raised by the physical applications. The period was one of
considerable interaction between mathematicians and physicists.
The theory of quantum mechanics from a mathematician's standpoint is presented
in J* von Neumann: Mathematische Grundlagen der Quantenmechanik. (Verlag von
Julius Springer, Berlin, 1932* Reprinted by Dover Publications, New York, 1943.)
An English translation has appeared under the tide: Mathematical Foundations of
Quantum Mechanics (Princeton University Press, 1955)*
3) Matrix mechanics is discussed in most advanced textbooks on quantum mechanics.
For an introductory account of quantum physics in which the algebraic approach is
discussed and used we refer to R* P* Feynman, R. B* Leighton, and M* Sands: The
Feynman Lectures on Physics, vol* III (Addison-Wesley Publishing Co*, Inc*, 1965)*
This is the final volume in a series of three books on basic physics. The presentation
in these books is magnificent, and the reader is strongly advised to become acquainted
with them,
4) We say very little about solid state physics in this volume. Among introductory
books on this subject we mention C. Kit tel: Introduction to Solid State Physics 3rd ed.
(John Wiley and Sons, Inc., New York, 1966)* Among many other topics the reader
will find discussions of crystal structure, diffraction theory, and the theory of phonons.
Concerning crystals the reader should note the long article on the subject in the
Encyclopaedia Britannica under the heading "crystallography.”
5) The reader may find the following articles in the Scientific American interesting:
a) K* K. Darrow: "The quantum theory,” March 1952, p, 47
b) K* K. Darrow; "Davisson and Germer,” May 1948, p. 50
c) E. Schrodinger: "What is matter?” Sept. 1953, p* 52
Problems Material Particles 217
d) P. and E, Morrison: “The neutron,” Oct. 1951, p. 44

e) G, Gamow: “The principle of uncertainty,'' Jan, 1958, p, 51
Problems
1 The resolving power of a microscope expresses the limit of our ability

to see, with the microscope, fine details in the object under study. We can
express the resolving power by the smallest distance between two points in
the object such that the two points are clearly seen as two separate points.
In an optical microscope the maximum possible resolution is clearly limited
by the finite wavelength of the light used for illumination: we cannot expect
to see features of the object which are much smaller than this wavelength.
To overcome this limitation of the optical microscope, electron microscopes
have been constructed. Instead of lenses made of glass an electron micro¬
scope employs suitably shaped electric and magnetic fields. Let us consider
a typical electron microscope, in which the illumination is provided by a
source of electrons of an energy of 50 keV. Compare the maximum possible
resolving power of such an electron microscope with that of an optical
microscope.
We must state that the actual resolving power achieved in a microscope
(whether optical, or electron) is also dependent on certain design character¬
istics of the device, and these have to do with the magnitude of the angle
within which “light” from the object is accepted by the microscope. For
technical reasons this angle is much smaller in an electron microscope than
in an optical microscope, and therefore the actual practical resolving power
of the electron microscope is considerably smaller than the maximum theo¬
retical resolving power. In spite of this the resolving power of an electron
microscope is vastly superior to the resolving power of an optical microscope,
2 Consider helium gas at room temperature. This gas is monatomic.

The average energy of a helium atom in a gas of temperature T is given by
Fkin = 3kT/2> and from this expression we may find the average velocity
(and momentum) of the helium atoms.
(a) Compute the average velocity (in cm/sec) of the helium atoms,
(b) Compute the de Broglie wavelength corresponding to this average
velocity, in cm. Compare this wavelength with the mean spacing between
the atoms in the gas. We assume that the pressure is one atmosphere, and
the mean spacing may then be found from the known density.
One may suspect that quantum effects could play a role if the de Broglie
wavelength is larger than the mean spacing, whereas a classical description
should be adequate when the de Broglie wavelength is much smaller than
the mean spacing. In the classical picture the gas is a collection of billiard
balls, incessantly colliding with each other, whereas in the quantum-mechan¬

ical description the gas is a collection of interacting waves* It is therefore
of great interest to carry out the above comparison for an actual gas*
(c) The density of liquid helium is about 0.15 gm cm-3. Under atmos¬
pheric pressure this substance stays liquid at the lowest attainable temper¬
atures* In analogy with the study in (fo) compare the de Broglie wavelength
with the mean separation at the very low temperature of 0,01 °K.
3 Carry out the same comparison between the de Broglie wavelength

and the mean spacing for a “gas” of electrons in a chunk of copper. There
are models of a metal in which the electrons are regarded as forming a “gas/1
just like helium atoms in a container* Assume that there is one electron
which can move freely in the lattice per copper atom. The spacing between
the atoms is then the mean spacing between the electrons*
4 Consider a three-dimensional problem in which a particle is incident

obliquely on the plane interface between two regions, Hi and #2- We as¬
sume that the potential energy of the particle has the constant value V1 in
most of Hi, and the constant value V% in most of H2, except for the imme¬
diate vicinity of the interface in which the potential changes rapidly from
Vi to V2. Inside the regions Hi and H2 the particle will therefore experience
no forces, but it will experience a strong force in the neighborhood of the
interface in the direction of the normal of the plane* Let us assume that the
total energy of the particle is £, and that E > Vi and E > V2* The particle
will then be refracted in the interface, and we wish to study the refraction
both classically and quantum mechanically,
(a) Derive the law of refraction on the basis of classical mechanics. In
this case there will be a change in the normal component of the momentum
of the particle as it passes the interface, but no change in the lateral compo¬
nent, The energy principle gives the momentum in region H2 if we know
the momentum in region Hi, and we may thus derive the law of refraction*
(b) Derive the law of refraction on the basis of wave mechanics^ and show
that you can obtain the same result as in the classical case- In considering
this problem within quantum mechanics you will again have to study the
connection between the energy £, the momentum p, the frequency u, and
the wave vector k of the particle. Our earlier discussion applied to the case
of a region in which the potential is zero, and it might therefore not be valid
in the present case* You are invited to present your ideas about how the
theory is to be created. Questions to worry about include the following:
Is the frequency the same on both sides of the interface? Must the tangential
component of the wave vector be continuous at the interface? Is the rela¬
tion p = k always true? How about E — Ha?
In this particular problem you really know the answer: The law of refract
bon must be correctly given by the classical discussion in part (0), This
Problems Material Particles 219
helps in your search for good ideas; You know that your quantum mechanical Grating
theory must in this case yield a known result*
(c) According to classical dynamics the particle will not be reflected at
the interface, but only refracted. Light incident on the interface between
two different dielectrics is both reflected and refracted Express your opin¬
ions about what the situation ought to be in the case of a quantum mechan¬
ical particle, he., a real particle.
5 We consider diffraction with a ruled grating, shown schematically in

the adjoining figure. Such a grating consists of a large number of very fine
parallel scratches of equal separation on a plane surface (made of glass, metal
or plastic). For simplicity we shall regard this as a two-dimensional problem, The figure above, which refers to Prob, 5, shows a
which is permissible if we assume that the incident wave propagates in a diffraction grating schematically. The incident mo¬
direction contained in a plane perpendicular to the lines* The incident mentum p* is represented by the vector. The spacing
between adjacent lines of the grating is the grating
direction thus lies in the plane of the figure, constant a.
L«t the incident wave be a plane wave of frequency ( = energy) to and The figure below shows how the directions of the
wave vector (= momentum) p^. Find the possible directions of the diffracted diffracted rays can be found by a simple geometric
waves, and show that they can be described as follows, A particle of mo¬ construction. The final momenta are determined by
the intersections of a circle, corresponding to an un¬
mentum p* collides with the grating. It emerges after the collision with
changed magnitude of momentum, and a set of paral¬
momentum pQ, The energy of the particle does not change in the collision, lel lines corresponding to the allowed values of the
but an amount of momentum q = p* — p*> is transferred to the grating. vertical component of the momentum transfer to the
Show that the possible directions of the diffracted waves are determined by grating. Ten possible final momenta, including the
the simple rule that the component of the momentum transfer q along the incident momentum, are shown by the vectors in the
figure.
grating, i.e,, the vertical component in the figure, must be an integral mul¬
tiple of 27r/a, where a is the distance between the lines, The vertical com¬
ponent of the momentum transfer is *'‘quantized,”
6 (a) We consider the diffraction of visible light in a grating such as the

one discussed in the preceding problem. Let the grating constant a be equal
to twice the wavelength of the light, and let the angle of incidence be 45a.
Find all the angles at which the diffracted rays can emerge. Draw a figure.
(b) Let us modify the arrangement such that the grating is sandwiched
between a plate of crown glass (refractive index 1.51) and a plate of Hint
glass (refractive index 1.74). Both plates are of a uniform thickness of 5 mm,
and the crown glass plate is toward the side from which the light is incident.
The wavelength, the grating constant and the angle of incidence are as in
the first part of the problem* Find the directions at which the diffracted
rays can emerge from the double-slab, and compare with the first part of
the problem.
7 In a Davisson-Germer type experiment electrons of the energy 88 eV

are incident normally on the surface of a metal crystal in which the atoms
are arranged in a quadratic lattice of side length a = 2.9 A. Draw a figure
showing the points of intersection of the diffracted rays with a plane parallel
220 Chop, 5 Problems
to tlie crystal surface, at a distance of 5 cm from the surface. This figure must
be drawn in the correct scale, and all diffracted rays must be shown.
8 Once upon a time there was a physicist who performed experiments,

such as described above, with a number of different metals. In his report
of his results he said: “With metal A I observed a diffraction pattern of three¬
fold symmetry; with metal B a four-fold symmetry; with metal C a five-fold
symmetry; and with metal D a six-fold symmetry,” (The pattern is said to be
of n-fold symmetry if it remains invariant under a rotation by a angle 2«r/n.)
Evaluate this report in detail.
9 Neutrons from a reactor are made to pass through a column of (poly¬

crystalline) beryllium. This material is chosen because it does not absorb
neutrons appreciably. It is found that the neutrons which emerge at the
other end are “cold,” they have kinetic energies corresponding to tempera¬
tures below 50The “wanner” peutrons, with kinetic energies corre¬
sponding to room temperature, are found to be strongly scattered out of the
beam by the beryllium. Can you give an explanation of these phenomena?
10 Suppose that the wave function i£(x,t) is a positive-frequency solu¬

tion of the Klein-Gordon equation (with mass m). We assume that this wave
function represents a particle (wave packet) reasonably well concentrated in
space, and moving in some more or less well-defined direction. Consider
the function i£fi(x,f), defined by
{a) Show that is also a positive-frequency solution of the Klein-

Gordon equation,
(h) The wave function ^jz(x,t) accordingly represents another state of
motion of the particle. Describe physically how the state of motion de¬
scribed by is related to the state of motion described by ^(x,£), (A
nice and simple statement can be made. To guide yourself you can first
think about the “average” trajectories in the two cases.)
11 The following problem is analogous to the Problem 10, but it is

probably more difficult. Consider the function ^r(x,f)» defined by
^r(x,f) = ^(x, -t)
where the star indicates the complex conjugate,

(a) Show that is also a positive-frequency solution of the Klein-
Gordon equation.
(b) Describe physically how the state of motion described by i£r(M) is
related to the state of motion described by ^(x,f).
Chapter 6
The Uncertainty Principle and the
Theory of Measurements
Sections 1 to 19 Heisenberg’s Uncertainty Relations 222
20 to 40 Measurements and Statistical Ensembles 234
41 to 49 Amplitudes and Intensities 249
50 to 56 Can the Outcome of Every Measurement Be
Predictable in Principle? 254
57 to 61 Polarized and Unpolarized Light 259
Problems 262
Chapter 6 The Uncertainty Principle and
the Theory of Measurements
Heisenbergs Uncertainty Relations
1 In the preceding two chapters we have learned that the par¬

ticles which occur in nature have wave properties. A moving
particle with a well-defined momentum p can behave like a wave
of wavelength \ ~ h/p, and this relation between wavelength and
momentum is universal, i.e., valid for all real particles. We em¬
phasized that one should not think about the wave properties in
terms of a “guiding wave” associated in some manner with a clas¬
sical corpuscle, A real physical particle is a single irreducible
entity, and its wave properties and its corpuscular properties are
manifestations of different aspects of its intrinsic nature*
2 We have learned that the state of motion of a particle can be

described by a complex wave function i£(xtf), For an isolated
particle this wave function satisfies the Klein-Gordon equation,
subject to the additional condition that only positive frequencies
will occur in the Fourier resolution of the wave function. As we
have explained, it is possible to solve the Klein-Gordon equation
subject to this condition, given an initial wave function ^(x,0) at
time f = 0 (or at any other fixed time). The initial wave function
is quite arbitrary, and we can therefore have a very wide variety
of different waves corresponding to different states of motion of
the particle. It is important to understand that a wave in quantum
mechanics need not look like a sine wave: that is a very special
case* The Klein-Gordon equation determines the time dependence
of the wave function, but it imposes no restriction on the “appear¬
ance” of the wave at some single instant of time. It will, however,
restrict the appearances of the wave at two different times. The
wave function at time t = h uniquely determines the wave
function at all other times, and thereby uniquely determines the
state of motion of the particle. In this sense quantum mechanics
is a deterministic theory.
Figt2A An assortment of waves, shown to remind
the reader that a wave in quantum mechanics need 3 Consider now a state of motion of a particle described by the
not took like a sine wave (at a given instant of time). initial wave function i//(x,0)* What can we say about the position
An arbitrary wave can be an almost arbitrary function and momentum of the particle at time t = 0?
of position, and in its appearance it need not be as
We have said that the wave amplitude must be given a probabil¬
harmonious as the above waves. We have here
plotted the real part of the (in general) complex wave istic interpretation. The particle is most likely to be found in those
function. regions in space in which the amplitude is large. More precisely
Sec, 6A Uncertainty Principle and Theory of Measurements 223
the absolute square of the wave amplitude at a point is a measure

of the probability that the particle will be detected if we look for it
with a (small) detector in a neighborhood of the point. If the initial
wave function is such that the amplitude is zero except in a very
small region, then we can say that the particle is in the region (at
time t = 0): its position is accurately known. On the other hand,
if the initial wave function is very much spread out such that its
amplitude is approximately constant over a very large region we
cannot assign a precise position to the particle: the position at time
t = 0 is subject to a large uncertainty*
The idea that a precise position cannot in general be assigned
to a particle (at a given time) follows naturally, as we have seen,
from the wave picture* The precision with which the position is
known depends on the state of motion of the particle* There is
nothing that forbids a wave function (a state of motion) for which
the position is known with extreme accuracy, and there is nothing
that forbids another kind of wave function for which the position
is not better known than to within a light year.
4 Analogous considerations apply to the momentum variable.

Since momentum and wavelength are related by the de Broglie
equation it is intuitively clear that the momentum cannot be well
defined unless the wavelength is well defined For the wavelength
to be well defined it is necessary that the wave function exhibit
some pattern of periodicity. A long sine wave has a well-defined
wavelength, but for an arbitrary irregular curve the whole concept
Fig. 4 A An example of a wave train for which the
of wavelength has no precise meaning. We can therefore under¬ concept of wavelength has very little meaning. For
stand that the precision to which momentum is defined depends such a wave the momentum is very poorly defined.
on the state of motion of the particle: it can be very well defined, See also Fig. 2A; the momentum is poorly defined for
or it can be very poorly defined. alf the waves shown except for the one in the middle.
It was realized by Heisenberg that whereas there are no limits
to the accuracy to which either the momentum or the position can
be defined, there is a fundamental limit to the accuracy to which
position and momentum can be defined at the same time (i*e*, for
the same wave function). This insight finds its expression in the
celebrated uncertainty relations, formulated by Heisenberg in
1927. f We shall now derive these relations through simple intuitive
arguments*
5 Let us first consider de Broglie waves in a one-dimensional

world. For simplicity we employ units such that ft = 1 Wave- *
t W. Heisenberg, “t)ber den anschaulichen Inhalt der quant entheoretischen Kine-

matik und Mechanik/* Zeitschrift fur Physik 43, 172 (1927).
224 Uncertainty Principle and Theory of Measurements Sec. 6.5
Position poorly defined length and momentum are then related by A = 2 m/p, and we do
Momentum well defined not have to distinguish between wave vector and momentum.
We shall argue in terms of pictorial representations of waves,
(A)
and for this purpose we have plotted four particular wave trains of
finite length in Figs. 5ABCD. (The ^-coordinate is the abscissa in
these figures.) Now the reader should note that the wave function
$(x,0) is in general a complex-valued function, which fact creates
Position better defined problems when we want to represent it graphically. We can, how¬
Momentum less well defined
ever, plot the real part and the imaginary part of the function sepa¬
(B) rately, and the reader can interpret the Figs. 5ABCD as showing
either the real or imaginary parts of r//(x,0) ■
The graphs show "interrupted sine waves,” described by the
function sin (px) in the region in which the wave function does not
Position well defined
Momentum very poorly defined
vanish. The wave is, however, not really a pure sine wave, because
it is “cut off” at both ends. For this reason the wavelength (and
the momentum) are not precisely defined: these quantities can be
(C)
precisely defined only if the wave is a pure sine wave.
Looking at the figures 5ABCD we can see very clearly that the
better the position is defined, the more poorly is the momentum
Position very well defined defined. Let us denote the uncertainty in the position x by Ax.
Momentum very poorly defined As a rough measure of the uncertainty in position we may take the
length of the wave train: if the wave train consists of n full waves
(D) we have
Ax ~ nA = (5a)
Figs. SABCD To illustrate our discussion of the P
position momentum uncertainty relation. A well-de¬
fined position requires a short wave train. A well- where A is the wavelength. Now it is dear that the wavelength
defined momentum requires many well-developed must be better defined the larger the number of full oscillations in
sinusoidal cycles. The two requirements are in con¬ the wave train. As a rough measure of the fractional uncertainty
flict with each other. in the wave length we may take the quantity
1 AA _ Ap
n X ~~ p
where Ap is the uncertainty in the momentum. (Since X = 2mfp

it follows that AA/A = Ap/p.)
Combining (5a) with (5b) we obtain the order of magnitude
relation
Ax Ap 1 (5c)
We have here dropped the factor 2m because we are only inter¬

ested in an order of magnitude estimate. Our definitions of Ax
and Ap are not precise, but only qualitative, and because of this
our result is also just a qualitative result.
Sec. 6.6 Uncertainty Principle and Theory of Measurements 225
6 The relation (5c) is the form the uncertainty relation takes for
the particular kinds of waves shown in Figs, 5ABCD. The general
uncertainty relation, which holds for all waves, is in the form of an
inequality* To convince the reader of this fact we show another
Fig. 6A For the above wave train the position is as
kind of wave in Fig. 6A* It is clear that for this wave the uncer¬ poorly defined as in Fig. 5A, The momentum is, how¬
tainty in the position is about the same as in Fig, 5A. The un¬ ever, a/so very poorly defined, and certainly much
certainty in the momentum (or wavelength) must, however, be more poorly defined than in Fig. 5A. The correct
much larger for the wave in Fig. 6A than for the wave in Fig, 5A* uncertainty relation must be an inequality: it is pos¬
sible to imagine wave trains for which the uncertain¬
The correct position-momentum uncertainty relation must there¬
ties in both momentum and position are arbitrarily
fore be of the form large.
Ax Ap > 1 (6a)
The reader will recognize that this is the uncertainty relation
which we discussed very briefly in Chap* 1.
7 Let us next consider a wave in three-dimensional space. First

of all we note that our discussion of the one-dimensional wave
applies to each coordinate direction separately* Therefore, if xa
and pA (a = 1, % 3) are the Cartesian position and momentum
coordinates of the particle, we have
Ax* Ap* >1, a = I, 2, 3 (7a)

On the other hand it is perfectly possible for the wave to be very
well localized in space in, say, the xi-direction, whereas the mo-
mentum of the wave is very well defined in the 2-direction. To see
this the reader should think about a wave packet which is confined
to a very small region around the 2-axis, but which has a large extent
in the direction of this axis* The xi-coordinate of the particle
(= wave packet) is then very well known* In the direction of the
^-axis we can, on the other hand, have a strictly periodic wave
over a large distance along this axis, which means that the momen¬
tum p2 can be very well defined* The precision with which the
xi-coordinate of the particle is known therefore places no limitation
on the precision with which the momentum component P2 can be
known, and we have the general relations
Ax* App 5; 0, for a 7^ fi (7b)
The inequalities (7a) and (7b) are the uncertainty relations for
waves (= particles) in three-dimensional space*
8 To gain further insight, let us again consider the representation

of an arbitrary wave as a superposition of plane waves:
i£(x,0) = / #(p)A(p) exp (ix • p) (8a)

JU)
where
A(p) — (2flr)-~3 f d3(\) ^(x,0) exp ( — ix • p) (8b)
We discussed this representation in Secs. 39-44, Chapter 5, and

as we said there, it is a fact that either one of these equations im¬
plies the other.
Suppose now that the function A(p) is very well localized in
momentum space. This means that A(p) is large only in the imme¬
diate neighborhood of some point p = po, but small elsewhere.
For simplicity we can assume that A(p) vanishes outside some very
small neighborhood of po- If we look at the integral defining
^(x,0) we expect, intuitively, that the wave function i/y(x,0) will
then not be well localized. The wave function i£(x,0) will look
approximately like a plane wave, of momentum po- To see this the
reader should think about the extreme case when the region in
which A(p) is different from zero shrinks to a point. (In going to
this limit we must, of course, increase the amplitude A(p) at the
same time, otherwise the integral giving i/'fcjO) will tend to zero.)
The author hopes that the reader can "see** that the more con¬
centrated the function A(p) is, the more spread out is the wave
function ^(x,0). There is, however, a remarkable symmetry be¬
tween the equations (8a) and (8b), and we can also conclude that
the more concentrated the function ^(x,0) is, the more spread out
is the function A(p). If the function ^(x,0) is very concentrated,
i.e., large only in some small region around a point xo, it means that
the position of the particle is well defined. The momentum is,
however, then poorly defined because a large range of momenta
will contribute in the expansion (8a).
9 These ideas can be given a precise form, and we can relate the
concentration of the function A(p) to the concentration of the func¬
tion ^(x,0). The result is an uncertainty relation; the precision
with which the position is defined is inversely related to the preci¬
sion with which the momentum is defined. Since we have pro¬
mised the reader not to depend on the theory of the Fourier integral
in this book we shall not present a rigorous derivation of the un¬
certainty relations.! The important thing for us is to understand
f For a standard derivation of these relations we refer the reader to L. I. Schiff,

Quantum Mechanics (McGraw-Hill Book Company, New York, 1966), 3rd edition,
p. 60.
qualitatively how the uncertainty relations arise. As we have seen,

the idea is extremely simple. If the position of the particle is to be
very well defined, the wave train must be very short. But this
condition is incompatible with the condition for a well-defined
momentum, namely that the wave train must resemble a sine wave
over a range which includes a large number of complete periods.
If we accept the wave description of particles we must therefore
conclude that the position and the momentum of the particle can¬
not be known simultaneously to unlimited precision.
We remind the reader of our brief discussion in Secs, 20-26,
Chap. 1, of the physical significance of the uncertainty relations.
It should now be perfectly clear that these relations do not merely
describe some unfortunate and unavoidable “perturbations*7 of our
measuring instruments on the orderly classical motion of a classical
corpuscle. They state instead the limit beyond which classical
ideas cannot be pushed. It simply does not make any sense to talk
about the simultaneous precise position and precise momentum of
the quantum-mechanical particle (= wave packet).
10 What are the conditions which have to be satisfied so that

we may think about an electron as a classical corpuscle; as a
"charged billiard ball*? These conditions are analogous to the
conditions for the validity of ray-optics. The linear dimensions of
the apparatus through which the particle passes must be large com¬
pared to the wavelength, otherwise we will see the diffraction
effects characteristic of waves. Let d signify some linear dimen¬
sion of the instrument; d may be the diameter of a lens, or the width
of a slit. Let X be the de Broglie wavelength of the particle, For
the classical corpuscle description to be sufficiently accurate we
must have d ^ X, Since X = 2 nfp we can write our criterion in
the form
dp > 1 (10a)
With the cgs-system of units this criterion reads dp ^ and
this is the same criterion which we discussed in Secs. 20-26 of
Chap. 1.
11 To iffustrate the implications of the uncertainty relations, let

ns study to what precision a classical trajectory can be assigned to
an electron in a particular case. The situation is illustrated in Figs.
11ABCD, A beam of electrons, each one described by a plane
wave, is incident from the left on the screen at left. The screen
has a slit of width d. We wish to select d in such a way that the
spot produced on the screen at right by the beam passing through
the slit is as narrow as possible. The distance between the two

screens is L.
We assume that the electrons all have the same incident momen¬
tum p, If an electron passes through the screen at left the uncer¬
tainty in its lateral position will be d, The uncertainty Ap in its
lateral momentum is then given by
Ap — ™ (11a)
Fig* 11A We attempt to produce a narrow beam of
electrons by limiting a broad beam incident from the If we assume that Ap is small compared to p we can restate (Ha)
left by the slit in the screen at left. The beam is in terms of the uncertainty A6 in the angle 9 (with respect to the
diffracted at the slit, and the uncertainty M in the incident direction) with which the electrons emerge* and we have
angle at which the electrons leave the slit is inversely
proportional to the width d of the slit. The size of the
spot on the screen at right is given by A* — d + L M.
P
Let Ax measure the size of the spot produced on the screen at
right. The magnitude of Ax is determined by two things: the size
of the opening in the screen at left, and the spreading of the wave
by diffraction at the slit. (See Fig. 11A.) We can therefore write
Ax~d + LA0~d + Lr (He)

pa
Since the wavelength X is given by X = 2^/p, we can rewrite
(11c) in the form
Ax~d + ^f- (lid)
where we have dropped a factor 2m in the last term. We are here

only concerned with an order of magnitude estimate, and since our
final result will be neater without the factor 2m we leave it out.
We see that if we make d too small the second term in (lid) will
become large because of the diffraction effects, whereas the first
term is large if the width d of the slit is large. It is a simple problem
in calculus to determine the optimum value do of d for which the
estimate (lid) for Ax assumes its minimum value Arming and we find
do = \AET Axmir, = 2do = 2\/XL (lie)

In the optimum case the spot on the right screen is twice as large
as the slit in the left screen* (The factor 2 should not be taken too
literally: remember that we are making only an order of magnitude
estimate* and that we have set 2?r — 1*) Suppose L = 1 meter,
and suppose that the energy of the electrons is 150 eV, Their
wavelength is then 1 A* and the estimate (lie) tells us that the spot
on the screen at right can in principle be as small as 0.02 mm. The
“tracks” of the electrons between the two screens are thus narrow
and well defined from a macroscopic point of view.
12 The detailed investigation of the conditions under which a

physical system appears to obey the laws of classical physics is an
interesting, but non-trivial problem. Some people describe what
has to be done as follows. First solve the problem quantum me¬
chanically, and then set ft = 0 to obtain the classical limit. This
idea is not correct We cannot set fi = 0 because we know that ft
is really (with the right choice of units) equal to one. The real
problem is to show how it comes about that a system which obeys
the laws of quantum mechanics, as all physical systems do, appears
to obey the laws of classical physics, i.e,, obeys these laws to a
considerable accuracy. In the study of this problem it is a good
idea to employ units such that ft = 1, as we did in our example,
because then one is forced to face the real issue.
The problem of how the classical limit is attained has many
aspects, and it is quite impossible to give an exhaustive explanation
in a single statement. One condition, if we understand by the
“classical limit” the classical theory of particle dynamics, is that the
arrangement must be such that diffraction effects are not readily
observable. We have discussed this point in the preceding section.
If a wave packet is to stay well localized, and is to have a well-
defined trajectory which can be interpreted as the trajectory of a
corpuscle, then the linear dimensions of the slits which define the
0)
trajectory must be large compared to the de Broglie wavelength.
Classical dynamics is, however, not the only “classical limit.” It is
Figs. 11BCD These three very schematic figures
also interesting to find out under what conditions classical electro¬
illustrate how the width of the beam depends on the
magnetic theory appears to be valid. In this case the condition is width d of the entrance slit. (Note that the wave¬
not that diffraction effects must be unobservable, but rather that length of the electrons is shorter in the above figures
the individual photons must not manifest themselves as particles. than in Fig. 11A.) In B the size of the spot on the
We shall not pursue the question of the classical limit further. screen at right is large because the entrance slit is
large. If we make the width of the slit very small, as
For the time being our rough qualitative understanding of this limit
in Dh the spot on the screen at right will be large
is sufficient. The reader should think about these problems on his because of diffraction effects. We obtain the smallest
own. As our discussion shows, what we mean by the ^classical spot by selecting d — y£L7 in which case the size of
limit” depends on the system under consideration, and this is an the spot is of the same order of magnitude. Fig. C is
important point to realize. intended to symbolize this optimum choice.
13 As a further example of arguments involving the uncertainty

relation, let us try to estimate the binding energy of the hydrogen
atom on the basis of this relation, as we promised to do in Sec. 26,
Chap. 2. In this discussion we want to employ the cgs-system of
units, in which the uncertainty relation (6a) takes the form
A*: Ap > a (13a)

23© Uncertainty Principle and Theory of Measurements Sec* 6,14
To make the estimate we assume that the classical expression
2m r
for the total energy of an electron in the electrostatic field of the

proton continues to have a meaning in quantum mechanics* The
variable p then refers to the momentum of the electron wave, and
the variable r is some kind of “position coordinate" for the wave*
The first term in the expression for E is manifestly positive,
whereas the second term is negative. The ground state energy is
the lowest possible energy of the system* and we know that it must
be negative, otherwise there is no binding* Classically we can
make the binding energy as large as we please simply by selecting
an orbit for the electron which has a very small radius. For such a
state of motion the uncertainty in position would be small, and if
we now try to work in the spirit of quantum mechanics as well, we
conclude from the uncertainty relation that the uncertainty in the
momentum must be large* which means that the quantity p2/2m
must be large. In other words, if we try to make the potential
energy large (and negative) by making r small, then the kinetic
energy will be large, which may lead to a large total energy if the
kinetic energy term “wins*" On the other hand, if we try to make
the kinetic energy small by making p small, then r will have to be
large, in which case the negative potential energy is small. We can
well imagine that there will be some optimal radius for which the
total energy assumes its smallest value.
14 To see how this “balance” between the kinetic and potential

energies leads to binding we shall make a rough approximation as
follows* Let us replace the uncertainty in position by r, and let us
replace the uncertainty in momentum by p, and let us rewrite the
uncertainty relation in the form
rp H (14a)
or, for definiteness, let us assume that
rp — (14b)
Let us now employ the relation (14b) to eliminate r from the

expression (13b) for the total energy £, We obtain
p2 _ _£p
2m ft
As a function of p the energy E will have a minimum at a point
p ~ Po> which we determine by setting the derivative of E with
respect to p equal to zero, i,e.t
'3£\ _ Po _ _ o
(14d)
dp jp~Po m *
Solving for p0, and defining r0 = fi/po, we thus obtain
e2m *2
Po = ro = (14e)
IT’ e2m
and
Po2 e2Po e*m

E = = —R (14f)
2m -H 2*2
Comparing these results with the results obtained in Sec, 23,

Chap, 2, we find that the energy E given in Eq* (14f) is exactly right
The “radius” r0, given by Eq* (14e) is also "right,” it is the Bohr
radius, r0 = Oq — 0.53 X I0_s cm.
Fig. 15A If the electron is confined to a very small

15 It is certainly an “accident” that our crude argument should
region around the nucleus the uncertainty in its posi-
give the correct binding energy, Whether we obtain the precise tion will be smaH, The uncertainty in its momentum
energy or not is, however, not the important point. The important must then be large, and this means that its kinetic
thing is that we obtain the correct order of magnitude, both for the energy must also be large. Its potential energy is, of
binding energy and size of the atom, and that we can understand, course, negative, and large in magnitude.
on the basis of the wave theory, why atoms do not collapse, The
structure of an atom results from a compromise* The ground state
energy is the lowest possible energy with which the atom can exist,
and this energy is the sum of two terms of opposite sign. If we try
to make the negative term, i,e*, the potential energy, large by con¬
fining the electron waves to a very small region around the nucleus,
then the kinetic energy term becomes large because the waves will
carry a large momentum. On the other hand we must not spread
out the waves too much, because then the potential energy term
becomes insignificant. The ground state corresponds to the
“best” possible compromise* These considerations are illustrated
schematically in Figs* 15AB.
Our discussion also shows us that the idea of classical orbits in an
atom is utterly incompatible with the wave picture. In the preced¬
ing section we found that the uncertainty in the position of the
electron in the hydrogen atom must be of the order of the Bohr Ftg* 15B If we want the kinetic energy to be very
radius qq> This estimate clearly applies to the position coordinate small we must allow enough space for the electron:
in each direction, and under these circumstances it makes no sense the uncertainty in its position must be large. Its mean
to talk about a circular orbit of radius uq. distance from the nucleus is then large, and the mag¬
nitude of its potential energy is small.
The ground state results from a compromise in
16 Let us next employ the uncertainty relation to obtain a crude which the total energy has the smallest possible
estimate of the strength of the nuclear force* We consider a value consistent with the uncertainty principle.
Time poorly defined nucleon, confined in a nucleus within a sphere of roughly the radius
Frequency very well defined fo = 1.2 X 10^13 cm, The uncertainty relation then tells us that
the momentum must be at least of order p ~~ ftfro9 and hence the
(A)
kinetic energy of the nucleon must be of order
e^~M^ ~10Mev m
Time better defined Since the nucleon is bound in the nucleus the average of the
Frequency less well defined
potential energy, denoted (17), must be negative and larger in
(B) magnitude than the kinetic energy, and we may conclude that
- (U) > 10 MeV (16b)
Time well defined This estimate is very rough, but it does give an idea of the order
Frequency very poorly defined of magnitude involved.
\ 17 We note that the same kind of argument can be employed to

refute the idea that nuclei consist of protons and electrons* If we
look at Eq. (16a) we note that the kinetic energy is inversely pro¬
portional to the mass of the particle, and we would thus be led to
Time very well defined
the conclusion that the average potential energy of an electron
Frequency very poorly defined
would be about 2000 times larger than the estimate in Eq. (16b),
which is totally incompatible with our experimental evidence that
the dominant interactions of electrons are electromagnetic in na¬
ture,
Figs. 18ABCD To illustrate the time-frequency
uncertainty relation. These figures are identical with 18 We can state a time-frequency uncertainty relation which is
Figs, 5ABCD, except for the legends.
completely analogous to the position-momentum uncertainty rela¬
tion. Let/(t) be the (complex) amplitude for some physical process.
For instance, f[t) may be the amplitude as a function of the time t
of an electromagnetic wave at some fixed position in space. If the
wave was emitted by an atom it will be a wave train of finite length,
and the amplitude will tend to zero as t tends to + oo or — oo+
Such a wave can be regarded as a superposition of monochromatic
waves, and the resolution of the wave into its monochromatic com¬
ponents is expressed by the Fourier integral
f(t) = f g(co) (18a)
where the function g(to) is given by
g(w) = (ftr)-i j dtf(t) (18b)

J—«
As we stated in Chap. 5 it is a theorem that either one of these
integrals implies the other, for a large class of “well-behaved” fiinc-
tions f(t) or g(w)* This theorem thus permits us to analyze an

arbitrary time-dependent process in terms of its harmonic com¬
ponents*
If the function g(w) in (18a) is large only in the immediate
neighborhood of the point w = w0 we can say that the frequency is
very well defined: the amplitude /(f) represents an almost mono¬
chromatic process* For a long time interval the amplitude /(#) will
be approximately of the form f(t) = A e-W. If, 0n the other
hand, the amplitude /(#) is large only in some small time interval
about the time t = to, corresponding to the case when /(f) repre¬
sents a sharp pulse, then the frequency will be very poorly defined.
The function g(w), given by (18b), will be appreciable over a large
interval of frequency- The frequency associated with the process,
and the time at which the process takes place, cannot both be
defined to arbitrary precision. The uncertainty Aw in the fre¬
quency, and the uncertainty At in the time at which the process
takes place, are subject to the uncertainty relation
Aw At > 1 (18c)
The reasoning which leads to this uncertainty relation is obviously

entirely analogous to the reasoning leading to the position-momen¬
tum uncertainty relation* We have illustrated our ideas in Figs* (A)
18ABCD.
19 The reader will recall that we discussed, in Secs. 20-23, Chap*

3, the relationship between the mean-life r of an excited state, and
the finite width A£ of the corresponding energy level. We con¬
cluded that the width is inversely proportional to the mean-life.
Let us now consider this relationship in the light of the time-fre¬
quency uncertainty relation*
Suppose that the system decays from the excited state to the Figs. 19AB Above is shown an exponentially damped
ground state by the emission of a photon. The uncertainty in the harmonic oscillation. It is intuitively clear that the
frequency of the photon will then be Aw = AE/-K, if A£ is the frequency is much better defined for such a process
width of the excited level* The duration of the emission process is than for the “irregular” process Illustrated by the
curve in Fig. 19B beiow. For the upper curve it is
of the order of the mean-life t, and the uncertainty in the time at
reasonable to guess that the inequality in the general
which the emission takes place is therefore of order t* In view of uncertainty relation is an approximate equaf/ty.
(18c) we can then write
r Aw — 1 or r AE ~ ji (19a)
We have written an approximate equality rather than an inequal¬

ity* We here deal with an exponentially damped harmonic oscilla¬
tion, as shown schematically in Fig. 19A. The amplitude for this
process is clearly more akin to the amplitude shown in Fig. 18A,
for which the uncertainty product assumes its lower limit, than to
234 Uncertainly Principle and Theory of Measurements Sec. 6.20
an amplitude such as the one shown in Fig, 18B} for which both the
time and the frequency are very poorly defined.
The relations (19a) are just the relations we derived in Secs, 20-
23, Chap. 3, by a seemingly different line of reasoning. If the
reader thinks more about this matter he will notice that the basic
ideas of our two derivations are not really so different. Our dis¬
cussion in Chap. 3 could be characterized as “Fourier analysis in
disguise.”
Measurements and Statistical Ensembles
20 In the remainder of this chapter we shall discuss the process

of measurement in physics. We shall do this by analyzing some
simple physical situations in terms of what we now know. Our
aim here is to find patterns of quantum-mechanical thinking, rather
than to try to formulate some kind of complete theory of measure¬
ments, Physical measurements are of a most varied nature, and no
short discussion could possibly reflect this variety. When we want
to understand the implications of a theory it is natural that we
consider highly idealized experimental situations in which the parti¬
cular feature in which we are interested stands out as clearly as
possible. We temporarily disregard all the technical experimental
difficulties with which we are faced in the real world. Our theo¬
retical discussion of measurements is therefore far from being a
faithful account of what actually transpires in the laboratory*
Very schematic picture of a Geiger-Mfiller counter.
The device consists of two electrodes inside an enve-
lope containing a suitable gas. In the figure the posi¬ 21 It is often convenient to think about the process of measure¬
tive electrode is a thin wiref and the negative electrode ment as if two stages were involved: the preparation of the system
is a cylinder centered about the wire. The electrodes under study, followed by the actual measurement, This is cer¬
are kept at a potential difference of about 1000 volts,
tainly a schematic description because there is often no sharp
A fast charged particle traversing the space between
the electrodes will ionize the gas molecules along its distinction between the preparation and the measurement: some of
path. The ions and electrons so produced will be the measuring process can just as well be regarded as being part
accelerated toward the electrodes, and if the potential of the preparation, and vice versa.
difference is sufficiently high, secondary ionization The analysis in terms of two stages is particularly appropriate
will occur to the extent that an avalanche of electrons
when we consider scattering experiments. We study the inter¬
is produced. The resulting current pulse can be
amplified and registered, and the device can thus action of a particle in a beam with a particle in a target. The pre¬
count individual charged particles. It is, of course, paration stage involves the setting up of the target and the produc¬
necessary to arrange it so that the discharge is “extin¬ tion of the beam in an accelerator. The measurement stage in¬
guished" after each pulse. This can be achieved volves the observation of the particles which emerge from the
either electronically through an auxiliary circuit which
region in which the interaction takes place. Experiments with a
momentarily lowers the potential difference after each
pulse, or else by using a filling gas such that the dis¬ beam of light belong to this class. The preparation of the photons
charge will extinguish itself. Tubes of the latter kind takes place in the source, which might be some kind of “lamp” in
are said to be self-quenching. conjunction with a system of lenses, polarizers, prisms, slits, etc.
The measurements are carried out in some region of observation

which is physically separated from the source; the measuring instru¬
ment might be a photomultiplier tube in association with other
optical devices.
22 It is a characteristic feature of measurements in microphysics

that we repeat the measurement a large number of times, always
preparing the system in the same way* The statements of the
results are typically statistical in character: we say that of N incident
photons an average of N' photons were registered by a particular
photomultiplier* The single experiment, or single measurement,
involves only one photon, but our final report involves statistical
averages of a large number of identical single experiments.
Now it is clear that two single experiments are not in principle Two examples of commercially available Geiger
identical since they are performed at two different times* We Muller counters. An important design consideration
believe however, that the Laws of Nature are invariant under dis¬ is to provide for the entry of the particles to be counted
into the active space of the counter The counters
placements in time, and the time at which the experiment was
shown are provided with very thin mica windows for
performed is therefore immaterial. For this reason a sequence of this purpose. The upper counter is a self-quenching
repeated single experiments can be regarded as a set of identical counter suitable for Counting alpha-particles, beta-
experiments in the sense that the preparation of the system was particles and gamma quanta. The length of the
the same in each elementary experiment. counter is about 5 in.r and the diameter about 3/4 in.
The mica window can be seen at the lower end. The
detection efficiency for very fast beta-particles is about
23 A beam consists of very many particles, but if the intensity of 85 per cent. The lower counter is designed to have as
the beam is sufficiently low each individual scattering event will large an entrance window as possible. (The diameter
involve only one particle from the beam. This situation always is about 1 3/4 in.) The metal envelope is one elec¬
prevails in scattering experiments with material particles, as well trode, and the other electrode can be seen through
as in most experiments with photon beams* We can say that the the mica window. (Photographs by courtesy of EON
Corporationt Brooklyn, N.Y.)
beam is a one-particle beam. Doing experiments with a beam is
the practical way of repeating the single elementary experiment
(which involves only one particle at a time) a large number of times*
The target in a scattering experiment might be a thin slab or a
thin foil of solid material, or it might be a container filled with a gas
or a liquid* If the intensity in the beam is reasonably high it can
well happen that two or more interactions take place at the same
time in the target. This does not invalidate our description of the
beam as a one-particle beam, because the two (or several) simultan¬
eous events in the target are completely independent of each other*
They correspond to two independent elementary experiments
which just happened to take place at the same time.
In principle we can carry out our measurements with a beam of
very low intensity, say one particle per minute, and we can then be
sure that only one particle interacts with the entire target at a time*
Since it is conceptually simple to think about beam experiments in
terms of a succession of one-particle experiments, we shall assume
in the following that our beams are of such a low intensity that only
one particle is in transit at a time. In actual practice we would
not deliberately limit the intensity of the beam, but, on the con¬
trary, we would try in general to work with the highest intensity we
could achieve.
24 To illustrate our ideas, let us consider an experiment with a

beam of light. We shall analyze the sfngte experiment, i.e., the
sequence of events which takes place when a photon from the
source arrives. Suppose that the detection system is some optical
device fitted with photon counters (say photomultipliers). After
the photon has arrived we find that some of the counters have
“clicked” whereas some have not: we list in our record of the ex¬
periment the counters which have clicked. We imagine that all
the detectors are restored to their original condition before the
next photon arrives. When it does arrive some other counters may
dick, and these are not necessarily the same ones which clicked
1—10: Dynodes
11: Anode in the preceding measurement. We again record the facts, reset
the detectors and wait for the next photon. We continue in this
Fig. 24A The photomultiplier tube is extensively manner until we have repeated the elementary measurement a
used as a photon detector. The figure shows such a very large number of times, say after Ar photons have arrived from
tube schematically. Photons enter through the glass the source.
faceplate of the tube! and release photoelectrons
A single measurement on the system thus involves the observa¬
from a very thin alkali-metal film on the inside of the
faceplate, The electrons are accelerated and focused
tion of all the counters, and the basic data recorded are whether
on the first dynode (denoted by the number 1 in the a particular counter clicked or not. After a sequence of N single
figure). Each electron which hits the first dynode measurements we might say:
gives rise to several secondary electrons, which are (a) The counter 1 clicked an average number of pi times per
accelerated and focused on the second dynode where incident photon. This average is defined experimentally by
they give rise to more secondary electrons. These are
accelerated and focused on the next dynodef and so Ni
on. For each detected photon an avalanche of elec- Pi (24a)
N
trons reaches the anode which is coupled to an ex¬
ternal amplifier. The device is thus In effect a photo¬ where Ni is the number of times counter 1 clicked in the sequence
electric cell with an amplifier in the same glass
envelope. A current amplification of the order of 10s
of N single experiments.
can readily be achieved. (fc) The event that the counters 1 and 2 both clicked in a single
experiment occurred an average number of P12 times per incident
photon. This average is defined experimentally by
Nu (24b)
P12
N
where is the number of elementary experiments in the sequence
in which both counters 1 and 2 clicked.
(c) The counter 1 clicked an average number of p(l;2) times per
click of counter 2. This number is defined by
N12
P(l;2) (24c)
n2
where N2 is the number of times counter 2 clicked, and N12 the
number of times both counters 1 and 2 clicked.
25 If we state our results in the above form we merely state what

we have directly observed: the above numbers are our primary
data. We may, however, perform an abstraction and report the
results of the measurements as follows:
(a) The probability that counter 1 clicks under our experimental
arrangements is pi.
(b) The probability that both counters 1 and 2 click (in a singlA
experiment) is pi2.
(c) The probability that counter 1 clicks given that counter 2
clicked is p(l;2).
If we state our results in this manner we clearly make an assump¬
tion, and this assumption is that if we would continue the run of
the experiment indefinitely then the numbers Ni/N, N12/N and
N12/A/2 would tend to definite limits. These hypothetical limit-c
are what we try to determine: we designate the limits as the prob¬
abilities pi, P12 and p(l;2). Since N is necessarily finite in any Fig*24B An example of a commercially available
actual sequence of experiments the assumption that the limits exist photomultiplier tube. The arrangement of the dy-
and can be determined to any desired accuracy and with any de¬ nodesf which can be seen in the middle of the tube, is
roughly as in the schematic figure 24A. The light-
sired degree of confidence provided we choose N to be sufficiently sensitive cathode is inside the front end of the tube.
large is thus a pious expectation. The nature of this expectation This particular kind of tube is intended for use with
has given rise to much philosophical speculation. We should scintillation counters. It is characterized by a very
regard it as an empirical fact that Nature possesses this kind of high quantum efficiency (see Fig. 24C). (Photograph
orderliness. by courtesy of Radio Corporation of America, Har¬
rison, NJ.)
The results of a sequence of N single experiments may thus be
stated in terms of probabilities, of which the numbers pi, p\2 and
p(l;2) are particular examples. The number pi is a simple prob¬
ability for the event that counter 1 clicks, pi2 is a probability for
the simultaneous occurrence of two events, and p(l;2) is a condi¬
tional probability for the occurrence of an event given that another
event occurred. We may consider many other probabilities of a
similar nature, say the probability that counter 1 clicked, given t-liat
counters 2 and 3 but no other counter clicked, etc.
26 We might describe our measurements as a sequence of ex¬

periments performed on a large number of photons, all prepared
in the same way in the source. Let us, however, think a bit about
what it means to prepare a set of photons “in the same way.” Sup-
235 Uncertainty Principle and Theory of Measurements Sec. 6*27
pose that there are two independent lamps in the source, say a
sodium lamp which emits yellow photons and a mercury lamp
which emits blue photons. A photon in a particular single experi¬
ment can thus be either yellow or blue, and the color is one of the
variables characterizing the photon which we might determine in
the experiment. Suppose that we do this for a long sequence of
photons. We can then report that the probability is pi that the
photon in any particular experiment is blue, and that the prob¬
ability is P2 that the photon is yellow. We assume that the inten¬
sities of the two lamps are kept steady so that these probabilities
are reproducible: if we perform several runs of large numbers of
repeated experiments we always find the same probabilities pi and
P2 in each run.
Are we willing to say, under these circumstances, that the pho¬
tons are all prepared “in the same way” in the source? Whether
this is an appropriate mode of expression or not is not immediately
obvious. One might argue that our arrangement with the two
lamps introduces an element of chance into the preparation process
which could easily be avoided if we would carry out our observa¬
tions with only one lamp operating at a time. Perhaps we should
not say that the photons have all been prepared in the same way
unless we are assured that the photons are in some sense identical
to the highest possible degree?
The difficulty with such a position is that we would then have
to decide, for each kind of experiment, whether the particles are
“identically prepared to the highest possible degree” or not. This
2000 3000 4000 9000 6000 7000
is obviously not a trivial problem. Furthermore, the two-lamp
WAVELENGTH-ANGSTROMS
experiment is really just as respectable as the one-lamp experiment
Fig. 24C Graphs showing detection efficiency of the in the sense that the probabilities pi and P2, as well as any other
photomultiplier tube in Fig. 24B. Note the curve probabilities describing the responses of detectors, are stable and
labeled "quantum efficiency." It represents the reproducible* This, of course, is the essential thing for any experi¬
probability for the detection of a photon, as a function ment in which we determine counting rates and probabilities, and
of the wavelength. The maximum probability is about
unless the source is stable in just this sense the discussion in Sec. 25
25 percent, which is a very high efficiency for a photo*
tube. The graph is taken from the manufacturer's would be irrelevant and meaningless.
booklet describing the tube, (ti/ustrat/on by courtesy It is therefore more practical to regard the photons as being all
of Radio Corporation of America, Harrison, NJ.) prepared in the same way whenever the source can be kept steady
in such a manner that all the relevant probabilities are stable and
reproducible. This is the position which we shall adopt in the
following.
27 In a certain sense the two-lamp experiment is more realistic

than the one-lamp experiment. Ideally we might prefer to do the
experiment with only the yellow lamp on, but in the laboratory
Nature will see to it that the blue lamp is also on (although its inten-
Sec, 6.28 Uncertainty Principle and Theory of Measurements 239
sity may be very weak). Let us consider two examples to illustrate Counter D
what we have in mind here.
Fig, 27A shows a semi-realistic electron diffraction experiment
in which the objective is to observe the diffraction pattern due to
the two slits in the screen S2. The electrons are emitted by the
filament F, and accelerated toward the screen Si, which is provided
with a slit* Let the electrons emerge through this slit with a mo¬
mentum p. We observe the two-slit diffraction pattern with the
help of the counter Dt placed at a very large distance from the
center of the second screen This counter can be moved along
the circular arc shown in the figure. We assume, for simplicity,
Fig. 27A To illustrate our discussion in Secs. 27-
that the distance from the counter to the slits is so large that we
30, of a two-slit electron-diffraction experiment, The
can regard the rays connecting the entrance slit of the counter with counting rate is observed as a function of the angle B
the two slits in S2 as parallel (This is not what the figure shows, when the counter and the entrance slit Sa are moved
because if we drew the figure correctly it would be hard to see the along the circular arc. If the separation between the
two slits in the screen S2. The essence of our discussion is, how¬ slits in S2 is large compared to the wavelength t and
if the source produces monoenergetic electrons, the
ever, not affected by whether the rays are parallel or not.)
counting rate will be an extremely rapidly varying
Let the separation between the two slits in S2 be 2a. The angular function of B. The diffraction pattern wifi not be
distribution 7(0,p) of the radiation detected by D can then be observable unless the angular resolution defined by
written, as we found in Sec. 40, Chap* 4 the counter slit arrangement is very good. If the elec¬
trons are not monoenergetic, as would be the case if
l(9yp) = 47O(0) cos2 (ap sin ff) (27a) the source is a simple filament the patterns for the
different energies overlap and the diffraction maxima
where 7o(0) is the angular distribution which we would observe might be smeared out to such an extent that they can
with a single slit.f no longer be seen*
28 We have written the intensity as l(0,p) to emphasize that the

angular distribution is a function of p. We shall assume that the
widths of the two slits in Sg are equal, and very small compared to
the wavelength of the incident electrons. Within the range of
momenta p which come into consideration the intensity Io(0) is
therefore independent of p, On the other hand, we shall assume
that the slit separation 2a is very large compared to the wavelength.
To be specific, let us assume that for the mean momentum po of
the beam, we have ap0 = rr X 105. For this mean momentum
we then have the angular distribution
7(0,Pq) 4Jq(0) cos2 [(at X 105) sin 0]

= 2JO(0) {1 + cos [(2ff X 105) sin 0]} (28a)
If we now examine the expression for the intensity we notice
that it is a very rapidly varying function of the angle 0. The sepa¬
ration S between two successive maxima is given approximately
by 8 ^ 10^5/cos 0.
f We use units such that A = c = 1 in this discussion.

Therefore, if we want to see the diffraction pattern clearly it is

essential that the angular resolution of our detection equipment
be very good. The angle which the entrance slit of the detector D
subtends when observed from the center of Sg must be much less
than 6, i.e., much smaller than 10^5. Let us assume that this is
the case. If it is not the case, i.e., if the angular resolution is much
poorer than 10-5, then the second term in the extreme right-hand
expression in (28a) will effectively average to zero and we will
observe an intensity which is twice the intensity with a single
slit.
29 Suppose now that the angular resolution of the detector is

very good, so that we can see clearly the two-slit pattern for a beam
of electrons all having the momentum po* Such a beam is, how¬
ever, not realistic. The electrons are not all emitted with the same
energy by the filament F, and they will therefore not emerge with
the same momentum from the slit in Si. The reason for this is the
thermal motion of the electrons in the filament. We have said
earlier that the random thermal motion is “noise in the symphony
of pure quantum mechanics,” and we will now see how the noise
can prevent us from hearing the music.
In a realistic experiment the momentum p of the emerging elec¬
trons will exhibit a finite spread. For simplicity, let us assume that
every momentum in the range (po — Q, Po + q) is equally likely.
The quantity q describes the spread in the momentum* and to be
specific we shall assume that q = 10-3 po: the momentum is defined
to within one per cent.
If we now observe the diffraction pattern with such a beam
we will clearly not observe the distribution I(8tpo), but rather an
average of I(8,p) over the range of momenta in the beam. Let us
denote this average intensity by 1(8). It is given by
m=ik)lZ’ *im=
cos (2opo sin 9) sin (2aq sin 9)
(29a)
2aq sin 9
Note that if we let q tend to zero in the expression (29a) we re¬

cover the expression (28a).
In accordance with our specific assumptions that apo = w x 105,
and that q = 10-2 po, we can conclude, from (29a), that
sin {(2*7! x 103) sin 9\

1(9) - 2I0(9) ^ 2IO(0) (29b)
(2ir X 103) sin 9
In the strictly forward direction, i.e., for 8 = 0, we see from (29a)

that 1(8) — 4Iq(8). In this particular direction we always have
constructive interference, irrespective of the momentum p. Sup¬
pose, however, that we carry out the observations outside the
strictly forward direction, say for angles 8 which satisfy the condi¬
tion J sin 8\ (2tt)“1 x 10-1 = 0.016* The inequality (29b) then
tells us that
\I(8) - 2IO(0)| < 10-2 X 2TO(0) (29c)

For these angles the two-slit pattern is therefore hard to see,
because the intensity distribution agrees, within one per cent, with
the pattern for a single slit*
30 For a classical billiard ball theory, which we discussed for

photons in Sec. 41, Chap. 4, we would predict an intensity
for the two-slit experiment, given by
1 *(8) = ZI0(S) (30a)

In this model there is no interference, and as we have said this
Mirror 2
is the wrong prediction; it does not agree with experiments. How¬ i
ever, if we compare this prediction with the prediction contained ii
i
in the inequality (29c) we notice that the prediction (30a) can some¬
i
times appear to be right. If the quantum-mechanical interference !L2
effects “wash out” for some reason, we end up with the classically I
predicted observational result.
Our discussion is a very interesting illustration of one aspect of I
l
the “passage to the classical limit.” Suppose that the energy of I
the electrons in the experiment considered is 10 eV. The slit sepa¬

ration 2a is then about 0.04 mm, which we can regard as a macro¬
scopic quantity. In spite of this the quantum-mechanical inter¬
ference effects are certainly there, but in order to see them we must
carry out our experiment with an extremely good control over the
source of the electrons so that the spread q in the momentum is
kept very small. Unless this is the case, the music of quantum
mechanics disappears in the noise.
31 As another example of the disappearance of interference

effects, consider the observation of interference fringes with a
Michelson interferometer, shown schematically in Fig. 31 A. Light Fig* 31A Schematic picture of a Michelson inter*
from a sodium lamp is “split” by a half-silvered mirror, and the ferometer with arms of unequal lengths. (The
essence of the experiment is the observation of interference be¬ lengths, i.e,, the distances from the mirrors to the
tween the two beams returning from mirrors 1 and 2. We have beam splitter, are I* and L2f as shown above,) The
maximum path difference 2- I*) for which Inter¬
drawn the two “arms” of the interferometer to be of unequal
ference can be observed depends on the width of the
lengths, and L3* The difference in path for the two beams is spectral fine of the almost monochromatic light source.
242 Uncertainty Principle and Theory of Measurements Sec* 6,32
thus d = 2{L,2 — Li)* The question arises: can interference fringes

be observed for arbitrarily large d?
The ahswer is: in principle yes> but in practice no, The precision
with which the wavelength of the light is defined sets a limit to the
path difference d for which fringes can be seen, and in practice the
wavelength is never defined with perfect precision.
Consider a photon of frequency w emerging from the source.
The part of the photon returning from mirror 2 will be retarded in
phase relative to the part returning from mirror 1 by an amount
S(w) given by
§(w) = a>d — 2?7 (31a)
where \ is the wavelength. Consider next two different frequen¬

cies, w' and w". The difference between the retardations in phase
for these frequencies is then given by
fi(w') - S(w") = (of - w") d (31b)
If this difference is numerically very small, Le*, |S(w') — 5(w")|

7T, then the interference fringes will look the same, to a good
accuracy, for the two frequencies. On the other hand, if this dif¬
ference is <n, i.e. 15(cor) — 5(w") | = then constructive inter¬
ference for the frequency of corresponds to destructive interference
for the frequency w", and vice versa. The system of fringes for
the two frequencies are complementary, and if they are super¬
imposed on each other with equal intensities no fringes will be
observed. This leads to a simple criterion for the visibility of the
fringes: the frequency spread Aw in the source must be such that
d Aw < rr (31c)
if the fringes are to be easily observable. For a given source, i,e,

for a given Aw, the criterion (31c) gives us the desired upper bound
on d.
32 For an approximately monochromatic light source (frequency

w), the quantity Aw is the linewidth of the emitted light. As we
have explained in Chap, 3 several physical effects contribute to
the linewidth. One of these is the Doppler effect due to the motion
of the atoms in the source. The source is a collection of identical
‘Tamps/’ but the frequencies emitted by these lamps will not all
be the same in the laboratory frame, because the lamps move in
a random fashion in the source.
Let us consider the limitation on d arising from the Doppler
broadening. The condition for clearly visible fringes is
d<jt=fe)(t) <32a>
In Sec. 44, Chap* 3, we derived an expression for the fractional
Doppler broadening, namely
{¥). ~(om x “Vi (si) «*x

where T is the effective temperature in the source, and where A is
the molecular weight of the emitting atoms, which we assume are
present in the form of a gas. Combining (32a) and (32b) we obtain
(is''vW^sjxl°5 (32c)
For T — 293°K (room temperature), and for X = 5000 A (visible
light), and for A — 100, we thus obtain d < 50 cm* This estimate
is in accordance with observations. The maximum path difference
for which interference fringes are seen is of the order of 1 meter
for "ordinary7’ light sources, such as gas discharge tubes (lasers
excepted).
33 The two examples which we have considered illustrate how

Nature conspires to “keep two lamps on.” The background of
thermal noise in our surroundings introduces a certain randomness
in the preparation of the system before the measurement*
Technical imperfections in our equipment also contribute to the
randomness in the preparation process* Suppose, for instance, that
we wish to produce a beam of high-energy electrons with a very
precisely defined momentum* In order to do this we must be able
to control all accelerating potentials very precisely, and the arrange¬
ments for the focusing of the beam must be nearly perfect* Fur¬
thermore we must be able to maintain a very high vacuum, because
the electrons in the beam can lose energy and have their direction
of motion changed in collisions with residual gas molecules in the
vacuum system. Nothing in the world is perfect, and it is clear
that we can never achieve complete control over the preparation
stage in practice* It is therefore of interest to see how an "imper¬
fect” preparation process might be described theoretically.
34 Suppose that we have an arrangement for the preparation of

a system in a sequence of repeated measurements such that the
"system is always prepared in the same manner.” As we have
agreed before, this means that the probabilities and averages which
we measure in long runs are stable and reproducible. We imagine
244 Uncertainty Principle and Theory of Measurements Sec. 6*35
that we have measured the averages of all possible physical vari¬

ables. We say that the totality of these averages defines a statis-
Heal ensemble of the system, and we say that any particular example
of the prepared system, as encountered in a single measurement,
is an element of the ensemble.
A particular method of preparation, whether “perfect” or “im¬
perfect,” gives rise to a particular statistical ensemble. From a
mathematical point of view an abstract statistical ensemble is equiv¬
alent to a set of probabilities and averages of physical variables.
When we want to consider the concrete physical realization of this
abstract concept we can regard the ensemble as a collection of a
very large number of prepared systems (elements). We thus de¬
scribe a beam of light as a statistical ensemble of photons, where
the elements of the ensemble are the individual photons.
Another important application of the concept of a statistical
ensemble is the description of a quantity of gas in a container as
a statistical ensemble of molecules. This description is appropriate
if we are studying the average behavior of individual molecules in
the gas. Each time we measure, say, the velocity of a molecule
we are doing an experiment on an element of the ensemble. The
results of a large number of velocity measurements give us the
average velocity, which is one of the averages which characterize
the ensemble. The conditions under which the gas is kept in the
container define, in this case, the preparation procedure. If the
temperature and pressure are kept constant the average velocity
will also be constant. We can say that the molecules are all pre¬
pared in the same way, because they are all subject to macro-
scopically identical external conditions. This does not, of course,
mean that we will find the same velocities in two particular meas¬
urements on two individual molecules. The velocity of a molecule
(at an infant of time) is a random variable from our standpoint:
the values which we encounter exhibit a statistical spread.
35 Consider a statistical ensemble. To have a concrete example

at hand we can think of a beam of electrons emerging from a accel¬
erator operating under conditions which are stable and stationary
to the best of our technical abilities. We repeatedly measure a
particular physical variable, say the momentum p in the direction of
A pair of scintillation counters. When charged parti¬
the beam. We denote the average of the values of momentum in
cles strike the vertical white panels at left scintillations
are produced in the material. The light of these a long sequence of measurements by
scintillations is “piped" through the lucite guides to
Av(p;p)
the photomultiplier tubes at right When in use the
counter and light pipe are wrapped in aluminum foil where the letter p symbolizes the particular statistical ensemble, i.e.,
and tightly sealed from stray light. (Courtesy Lawrence
the particular beam. We call the quantity Av(p;p) the ensemble
Radiation Laboratory, Berke/ey.)
Sea 6,36 Uncertainty Principle and Theory of Measurements 245
average of p. The average of the squares of the values of momen¬

tum is denoted Av(p2;p): this is the ensemble average of the square
of momentum* In general Av(p2;p) will be different from
[Av(p;p)]2* Let us study this point* We denote the values of mo¬
mentum found in the individual measurements by pi, p2, * * * , p$.
The two averages are defined by
Av(p;p) = Av(p2;p) = Vp k2 (35a)

k k
We can then write the identity
Av(p2;p) - [Av(p;p)]2 = i V [pA - Av(p;p)]2 (35b)

k
as the reader should immediately convince himself* The right side

of (35b) is a sum of non-negative terms, and we can conclude that
Av(p2;p) - [Av(p;p)]2 ^ 0 (35c)
where the equality sign applies if and only if all the numbers pft,
k = 1> 2, . . * , 2V, are equal, in which case their common value
equals Av(p;p)* In this particular case the particles in the beam all
have precisely the same momentum,
The quantity in the left side of (35c) measures the statistical
spread in the variable p* In general it will be greater than zero,
which we can express by saying that there is an uncertainty in the
momentum for the particular ensemble*
36 We can discuss all other physical variables in the same way as

we have discussed momentum* For a particular ensemble (beam)
we determine their averages, and their dispersions, by which we
mean their statistical spreads defined in analogy with the expression
at left in (35c)* The simplest kind of variable is a variable which
describes the response of a counter. Let us denote it by jD, and There is a striking contrast between the small and
let us adopt the convention that D has the value +1 in a particular neat “theoretician's counters" which appear in the
experiment if the counter clicked, and the value 0 if it did not click. schematic figures in this chapter, and some of the
counters actually used in the laboratory. This photo¬
Av(D;p) is then simply the probability that the counter will click
graph shows a stack of 24 scintillation counters,
when we do an experiment with a single element of the statistical assembled for an experiment in elementary particle
ensemble p. physics. The side length of the assembly is about I
At first it might seem that a counter variable D is not of the meter. The plastic scintillators are In the middle of
same kind as a momentum variable p. We might feel that p refers the figure, and the photomultiplier tubes are sym¬
metrically placed on the periphery. The direction of
to the system, i.e*, the particle, whereas D refers to a measuring
the particle beam is normal to the plane of the figure.
instrument. We must realize, however, that all our information (Photograph by courtesy of Lawrence Radiation Lab¬
about the properties of the system is derived by observing the oratory, Berketey.)
246 Uncertainty Principle and Theory of Measurements Sec, 6,37
responses of measuring instruments: the intrinsic variables of the

system are abstractions. If we know the probability that a certain
counter placed in a certain way, will click we do know something
about the nature of the statistical ensemble, i.e., something about
the particles in the beam. The momentum of particles in a beam
Source Counter is in fact often measured by counters, as illustrated in Fig. 36A.
Fig. 36A To illustrate the principle of a so-called
semi-circular beta-spectrograph. The device is used 37 Let us discuss further the situation considered in Sec. 26, in
to measure the distribution in momentum (or energy) which there are two lamps in a source of light: a sodium lamp and
of the electrons emitted in the decay of beta-active
a mercury lamp. Let us first consider an experiment in which only
nuclei. The electrons are emitted from the radio¬
active source at left, and are constrained to move in the sodium lamp operates, and the beam thus consists of “yellow
or close to the plane of the figure. The device is photons.” The source gives rise to a statistical ensemble p% of
placed in a uniform magnetic field perpendicular to photons, and for this ensemble we find the average value di of a
the plane of the figure, and the trajectories are thus certain counter-variable D:
circular arcs, the radii of which depend on the mo¬
menta of the electrons. The apparatus contains a Av(D;Pl) = d1 (37a)
number of slits so placed that an electron cannot
reach the counter at right unless the radius of its Next we consider an experiment in which only the mercury lamp
trajectory lies within a narrow range. By counting the operates. This arrangement defines a statistical ensemble p2, and
number of electrons reaching the detector per unit the ensemble average of the same counter variable D is found to be
time for different values of the magnetic field we can
determine the momentum distribution of the emitted Av(D;p2) = &2 (37b)
electrons, i.e., the relative number of electrons
emitted within different intervals of momentum. We finally consider the case when both lamps operate simultane¬
ously. The two lamps together give rise to the statistical ensemble
p, and the average of D in this case is
Av(D;p) = d (37c)
Suppose now that lamp 1 gives rise to a flux of fti photons per
unit time in the beam, and that lamp 2 gives rise to a flux of ri2
photons per unit time in the beam. The total flux in the beam is
thus (ni + n2) photons per unit time. In any single experiment
the photon is either “yellow” or “blue,” depending on whether it
came from lamp 1 or lamp 2, and we conclude that the probability
that we find a “yellow” photon in any single experiment is
ni
Fig.36B The beta spectrum of P3S. The graph
shows the relative number of emitted electrons as a
(»i + ns)
function of momentum. The momentum is expressed whereas the probability that we find a “blue” photon is
in terms of the quantity Bp (in units of gauss centi¬
meters), where p is the radius of curvature in the field n2
B. The maximum momentum at 7200 gauss cm (37e)
(n± + n2)
corresponds to the maximum kinetic energy 1.7 MeV.
The electrons can emerge with an energy ranging The numbers 0i and 02 satisfy the conditions
from zero to the upper limit because the total (kinetic)
energy released in the decay is shared (in a random 1 g 02 ^ 0, 01 + 02-1 (37f)
fashion) between the electron, the daughter nucleus,
and an anti-neutrino. as a consequence of the definitions (37d) and (37e). The conditions
Sec, 6,38 Uncertainty Principle and Theory of Measurements 247
(37f) are characteristic for the probabilities of two mutually ex¬

clusive events, one of which must take place.
38 Consider now a single experiment: i.e., an event involving a

single photon. What can we say about the probability d = Av(23;p)
that the counter described by the variable D clicks? The photon in
question is either yellow or blue. The probability that it is yellow
is 0i; if it is yellow then the probability that the counter D clicks
is d±. The probability that the photon is blue is 03, and if it is blue,
then the probability that the counter D clicks is d3* Since the two
cases yellow-blue are mutually exclusive we conclude that the
probability d that the counter D clicks must be
d = + 02d2 (38a)
or
Av(D'p) = 0i Av(D;pi) + 02 Av(D;p2) (38b)
The average of D in the ensemble p is thus given in terms of the

averages of D in the ensembles pi and p2 and in terms of the prob¬
abilities 0i and 02. These latter probabilities describe how the
“combined” ensemble p is formed from the ensembles pi and p2,
and they are therefore quantities which characterize the “com¬
bined” source; the are independent of the variable D which de¬
scribes a particular counter in the region of observation. The
formula (38b) therefore holds for every counter variable D,
More generally the formula (38b) applies to the averages of an
arbitrary physical variable. If Q denotes such a variable we must
have
Av(Q'fp) = 0! Av(£;pi) + 02 Av(£>;p2) (38c)
We say that the statistical ensemble p is an incoherent super-

position of the two ensembles pi and p2 with probabilities 0i and
02. We express this statement symbolically in the form
P = 0ipi + ®2P2 (38d)

The reason for the qualifying attribute “incoherent” is that we
must carefully distinguish between this kind of superposition, and
the superposition of wooes, which we discussed in Secs. 36^46,
Chap. 5. We shall have more to say about this distinction later.
39 We can clearly generalize the idea of the superposition of two

ensembles to include the incoherent superposition of any finite
number of ensembles, Let us thus consider the statistical ensembles
Pfo fc = 1» 3» . . , , n. We associate with each one of these en-
248 Uncertainty Principle and Theory of Measurements Sec. 6AO
sembles a probability 0*, such that the numbers 0* satisfy

n
1 s 0* a 0, V ek = 1 (39a)
k-1
Let p be the incoherent superposition of these ensembles, with

probabilities we express this symbolically by
n
P = ^ &kPk (39b)
h=l
This means that the average of any physical variable Q for the
ensemble p is given by
n
Av(Qip) = y 0fc Av(Q;pk) (39c)

k-1
We shall make the assumption that if pi, pa, P3, * * *, Pn is any set
of possible statistical ensembles, then every incoherent super¬
position of these ensembles is also a possible ensemble, This as¬
sumption is mathematical rather than physical, and we make it
because we want the set of aU statistical ensembles to have the
property that it is closed under incoherent superposition This
means that if the set contains any finite number of ensembles it also
contains all possible incoherent superpositions of these ensembles.
40 Note that we have already considered, in our discussion in

Secs. 27-29, an incoherent superposition of an infinite number of
distinct statistical ensembles. Let D(8) be the variable describing
the counter D in Fig. 27A for a given angle 0. Let p denote the
statistical ensemble which a given source, to the left of the screen
Si, gives rise to. We assume that the intensity of the sources which
we shall consider is always such that one electron per second enters
through the slit in Si. If the intensity 1(0), observed with the
Counter D counter D, is expressed in number of electrons per second, we have
Av[D(0);p] = 1(0) (40a)
In our discussion in Sec. 27 we first considered the intensity

J(0,p) for a hypothetical source which produces electrons of an
extremely well-defined momentum p, Let us denote the statistical
ensemble defined by such a source by p(p). We then have
Av[D(0);p(p)] = 1(8,p) (40b)
We pointed out that if the source is a hot filament with a single

accelerating electrode, then the electrons will not emerge through

the slit in Si with a well-defined momentum. [There is, however,
nothing to prevent us from designing a very elaborate source, with
"momentum filters/' such that the momentum of the emerging
electrons is extremely well defined: such a source is described by
p(p).] Let us denote the statistical ensemble which the simple
filament source gives rise to by p. In accordance with our discus¬
sion in Sec* 29 we then have
/ 1 \ fPo+g
Av[D(0);p] = 1(8) — jj dp Av[D(8);p(p)] (40c)
This is to be compared with Eq, (39c)* Our reasoning in Sec* 29

clearly amounts to regarding the statistical ensemble p, correspond*
ing to the “realistic” hot filament source, as an incoherent super¬
position of the ideal sources corresponding to the statistical en¬
sembles p(p). In other words, in analogy with Eq* (39b), we have
/ 1 \ /"po+?
f=y jL * ^ <4od)
Amplitudes and Intensities
41 We can state the difference between coherent and incoherent

superposition as follows: in a coherent superposition we add ampli¬
S' S
it
tudes, but in an incoherent superposition we add intensities.

Let us exercise ourselves in the handling of amplitudes and in¬ _ll
tensities in quantum mechanics* Figure 41A illustrates a semi-
realistic double double-slit experiment* Particles with a very wefl- ^1a ®2i
defined momentum enter through the slit in the screen S, at a rate / \
V
of, say, one particle per second* We observe the flux of these
particles through the other five slits by placing a counter im¬
mediately behind the slits, one slit at a time. If the observed
counting rate is P particles per second for a particular slit we can
say that P is the probability that a particle entering through the Fig.41A To illustrate our discussion in Secs. 41-
slit in S will pass through the slit in question* 43 of a somewhat idealized double double-slit experi¬
ment The particles (photons) enter through the slit
We assume that the wavelength of the particle is large compared in S. We are interested in the probabilities that the
to the widths of the slits, and we furthermore assume that all the particles pass through the other slits, and in particular
slits are of the same width* We can then talk about the (complex) through the slit in D. At each slit we must, ot course,
amplitude of the wave at a slit* add the amplitudes rather than the intensities ol the
waves which arrive from the preceding slits. The
complex numbers Am, B^, and C*, are the transfer
42 Let Ai be the amplitude of the wave at the slit V when the amplitudes between the slits. All the probabilities
amplitude at the slit in S is equal to unity* Similarly, let A2 be the can be expressed in terms of the transfer amplitudes.
amplitude of the wave at the slit 2* when the amplitude at the slit
in S is unity. Let flu be the amplitude of the wave at the slit 1"
when the amplitude at the slit V is unity, but the amplitude at the
slit 2' is zero. Similarly, let B$i be the amplitude of the wave at
the slit l" when the amplitude at the slit V is zero, but the ampli¬
tude at the slit 2' is unity. Ci stands for the amplitude at the slit in
the screen D when the amplitude at the slit 1" is unity, but the
amplitude at the slit 2" is zero. The remaining amplitudes are
defined in an analogous manner. We can call these amplitudes
transfer amplitudes, because they describe the propagation of the
wave between the slits, from left to right. The dotted lines in Fig.
41A represent this propagation symbolically. A transfer amplitude
is associated with each dotted line, as we have explained.
The transfer amplitudes are complex numbers. Their absolute
squares define transfer probabilities as follows. Pi = | Ai 2 equals
the probability that a particle which has passed through the slit in
S is detected immediately behind the slit V. P& = A212 equals
the probability that a particle which has passed through the slit in
S also passes through the slit 2'. P12 = | Si2 [2 equals the prob¬
ability that a particle which has passed through the slit lr also passes
through the slit 2". In this case the slit 2' must be closed, to make
sure that the particle really passed through the slit V. The absolute
squares of the other transfer amplitudes have analogous interpreta¬
tions. Let us list all the transfer probabilities corresponding to the
eight amplitudes:
The reader should think carefully about how these transfer prob¬
abilities can be measured with counters, closing some of the slits
when required.
43 Suppose we now ask the question: with all the slits open, what
is the probability P that a particle which enters through the slit in S
will emerge through the slit in D?
Let us first give a thoughtless answer: since we know all the
transfer probabilities between the slits we can find P by compound¬
ing these probabilities according to the rules of probability theory.
The probability that the particle passes through the slit 1" should
thus be equal to the sum of the probability that it passes through
i" via the slit V and the probability that it passes through 1" via
the slit 2\ or, in other words equal to (FiPn + P2P21). This kind
of reasoning leads to the final wrong result
tJPpg§; (43a)
What is the correct answer? It is given by
F = |(AiUii + + (A1B12 + A 2^622)^2 f ^ (43b)

and this is not equal to the wrong expression in Eq* (43a). At each
slit we must add the amplitudes of the waves arriving at the slit,
because the waves can interfere. Equation (43b) gives the correct
answer according to quantum mechanics, whereas we might regard
the expression in Eq* (43a) as the prediction according to a classical
billiard-ball theory,
44 How do we find P if we are given only the transfer probabil¬

ities, but not the transfer amplitudes? Answer: We cannot find F
at all. To find P we must know both the phases and the absolute
values of the complex transfer amplitudes, but the transfer prob¬
abilities only teD us about their absolute values.
Let us discuss further the fallacy in the “compounding-of-
probabilities” argument which led us to the wrong prediction (43a)*
Consider the quantity FjFn* What does it represent? It repre¬
sents the probability that a particle entering through the slit in S
passes through the slit 1" when the slit 2/ is closed, Similarly F£F2i
represents the probability that a particle entering through the slit
in S passes through the slit 1" when the slit I" is closed. If both
slits V and 2' are open the probability that a particle entering
through the slit in S passes through the slit lff is not given by the
sum (F1P11 + P2F21). The waves arriving at the slit V* from the
slits lf and 2' are coherent with each other, and we must add their
amplitudes and not their intensities*
45 Consider the slightly modified arrangement shown in Fig, 45A*

We insert a phase-retarder If in the path of the wave which passes
from the slit in S to the slit l\ otherwise the arrangement is exactly
as in Fig. 41A. The only effect of the phase-retarder is that the
amplitude Ai becomes replaced by the amplitude A\ei9\ the phase- Fig. 45A This figure shows a modification of the
retarder retards the phase by an amount 6, but does not affect the double doube-sfit experiment illustrated in Fig, 41A.
amplitude of the wave* If the experiment is done with light we can A phase retarder R has been inserted in front of the
use glass plates as retarders. slit 1It changes the complex amplitude of the wave
passing through it by the factor eif, The theory of the
Let P(6) be the probability that a particle entering through the experiment shown in Fig. 41A applies, provided we
slit in S emerges through the slit in D (with all the other slits open). replace the transfer amplitude Ai by the quantity
According to Eq* (43b) we have A1ei9.
252 Uncertainty Principle and Theory of Measurements Sec, 6.46
P(ff) = |Aieitf(BnCi + B12Q2) + A2(B21Ci + -622^-2)1 2

= | Ai(BnCi + B12C2) |2 -h | A3(B3iCi + B22C2) \2
+ 17 cos 8 + V sin 8 (45a)
where
U = A^BnCi + B12C2)Ai(B%lC*1 + EhC*2)

+ At(fl!iC! + B?2C^)A2(B21Ci + B22C2) (45b)
and
V= + BiaGiJARBSiCi + BM)
- AUBhCl + B?2C ?)A2{B21Ci + B33C2) ] (45c)
as the reader should convince himself.
If we like we can rewrite the expression for P(8) in the form
P(8) = £[P(0) + P(i?)] + |[F(0) - F(w)] cos 8

+ ^ [2P(tt/2) - P(0) - F(ff)] sin 8 (45d)
which means that F(0), as a function of 8> is uniquely determined

by its values for the three angles 0 = 0, tt/2 and ir.
46 Next consider the arrangement shown in Fig. 46A, We now

have two separate sources, 1 and 2, "illuminating” the slits V and 2',
In all other respects the situation is as in Fig. 41A. Let the two
sources be of equal intensity.
What is the probability P\ that a particle which has passed
through the screen S passes through the slit in D? It is clearly
given by
Pi = ^|Ai(BuCj + B12C2} |2 + ^-|A2(B2iQi + B22C2) |2 (46a)
In this case we have to* add the intensifies produced by each

Fig.46A In this modification of the double double¬
slit experiment illustrated in Fig. 41A the slits 1' and source separately at the slit in D to find the intensity with both
2f are illuminated by two motepencfent sources of sources operating together. The expression | Ai(BnCi + Bi2C3) |3
equal intensities. The waves from the two sources is the probability that a particle from source 1 passes through the
are incoherent, and the intensity at any particular slit slit in D, and the expresssion |A3(B3iCi + B22C2)j2 is the prob¬
with both sources operating is the sum of the inten¬
ability that a particle from source 2 passes through the slit in D.
sities we would observe with only one source operating
at a time. Every particle passing through the slit in D either comes from
There is an interesting relationship between the source I, or else from source 2, with equal probabilities: hence the
experiment illustrated above and the experiment illus¬ factors ^ in the expression (46a),
trated in Fig, 45A, Any intensity measured in the
present experiment is the average over the phase
angle 6 of the corresponding intensity measured with
47 Let us ask some further questions, concerning Figs. 45A and
the arrangement in Fig. 45A. This fact is often ex¬ 46A. Let us regard the screen S', and everything to the left of this
pressed by saying that two incoherent sources emit screen, as the source. Figures 45A and 46A then show the same
waves of random relative phase. experiment performed with two different sources. We can ask:
for the situation shown in Fig. 45A, what is the probability F(8)
Sec, 6.48 Uncertainty Principle and Theory of Measurements 253
that a particle coming through the screen S' will also pass through
die slit in the screen D? Since every particle coming through the
slit in D must have passed through the screen S' it follows that F(0)
must be equal to the ratio of the probability P(0), given by Eq. (45a),
and the probability that a particle coming through the slit in S
passes through S'. This latter probability is clearly equal to
[|Ai|2 + | As | s]3 and we thus obtain
F(0) = [ | AifBxiCj. + B12C2) |2 + | A2(B21C1 + B22C2) 12

+ 17 cos 0 + Vsinfl] [|Ai|* + |A2|2]-i (47a)
which can also be written
F(9) = * [F(0) + F(*)] + * [F(0) - F(ir)] cos 6

+ ±[2F(ir/2) “ F(°) “ nn 0 (47b)
Similarly we can ask: for the situation shown in Fig, 46A, what is
the probability PI that a particle coming through the screen Sy will
also pass through the slit in DP We easily see that
P'i = [IA^BuCi + Bi2C2)j2 + |A2{£21Ci + B22C3)|2]

[IAx]2 + |A2|»]-i (47c)
Comparing the expression (47c) with the expression (47a) we
notice an interesting fact: if we average F(8) over all angles 6 be¬
tween 0 and 2tt we obtain Pi, i.e.,
(47d)
Actually it is not necessary to average over aU angles, We also

have
PI = * [F(0) + F(tt)] (47e)
We can therefore regard the statistical ensemble defined by the

source shown in Fig, 46A (the screen S', and everything to the left
of S', is the source) as an incoherent superposition of two, or an
infinite number of statistical ensembles defined by the sources
shown in Fig. 45A, with 6 regarded as a variable parameter. (Dif¬
ferent values of 8 correspond to different sources.)
48 The result (47d) illustrates a general principle concerning an

incoherent superposition. If we have two sources which are in¬
coherent we first regard them as coherent and add the amplitudes
of the waves from the two sources, but with a variable relative
phase factor We compute any interesting “intensity” 1(8), as
a function of 0, and we finally average 1(8) over all angles 9 between
0 and 2The resulting average, I, is the appropriate average when
254 Uncertainty Principle and Theory of Measurements Sec. 6,49
the two sources are incoherent Two sources of random relative

phase are incoherent*
49 After these exercises on amplitudes, intensities and probabil¬

ities, let us continue with our systematic discussion of statistical
ensembles.
The set of all statistical ensembles clearly consists of two
subsets: those ensembles which can be regarded as incoherent
superpositions of two or several other distinct statistical ensembles,
and those which cannot be regarded as such superpositions* The
stastistical ensembles which cannot be regarded as incoherent
superpositions of other ensembles are called pure ensembles, or
pure states: the other kind of ensembles are called mixed ensembles,
or statistical mixtures.
Consider now a mixed ensemble. We know that such an en¬
semble must be an incoherent superposition of other ensembles*
Is it also true that the mixed ensemble can be thought of as an
incoherent superposition of pure ensembles? This question is really
a question about the nature of the set of all physically realizable sta¬
tistical ensembles. It might certainly be the case that the set of
all physically realizable ensembles does not contain any pure states,
in which case our question would have to be answered in the nega¬
tive* On the other hand, we could regard the pure ensembles as
limiting cases of mixed ensembles, and we might therefore enlarge
our set of statistical ensembles to include not only all physically
realizable ensembles but also all limiting cases of these ensembles.
If we perform this purely mathematical abstraction, as we shall do,
we might expect intuitively that our enlarged set of ensembles will
have the property that every statistical ensemble is either a pure
ensemble or else an incoherent superposition of pure ensembles*
We shall make this reasonable assumption in the following. As
a physical assumption it is an idealization: we imagine that it is
actually possible to realize all the pure ensembles, and to regard
all other ensembles as statistical mixtures of these. In practice
we may not be able to realize the ideal of a pure ensemble, but
there is no reason why we could not approach this ideal arbitrarily
dosely.
Can the Outcome of Every Measurement

Be Predictable in Principle?
50 It is intuitively clear that we know more about the elements

of a pure ensemble than about the elements of a mixed ensemble.
Consider, for instance, our example of the light source with two
Sec. 6,51 Uncertainty Principle and Theory of Measurements 255
lamps. We obviously know less about the properties of the indi¬

vidual photons emerging from the source when both lamps operate
than when only one lamp operates: in particular we know less about
the color of the photons.
In order to prepare a pure ensemble we must have perfect con¬
trol over the preparation stage: we must be able to suppress all
sources of statistical fluctuations which can in principle be sup¬
pressed.
Now it should be clear that when we perform measurements
it is desirable to try to arrange the preparation stage in such a way
that the ensemble is as pure as is technically feasible. By so doing
we minimize the statistical spread in our data* which means that
we increase the accuracy of the results. We can furthermore say
that the theoretical interpretation of the experimental results is
simpler and more clear-cut for a pure ensemble than for a mixed
ensemble. For a pure ensemble we can study the behavior of a
system under the best possible conditions, undisturbed by avoidable
a , »
noise.
51 There now arises a fundamental question. Are the pure states

characterized by a complete absence of statistical spread in all
physical variables? Differently stated: are the pure states such that
the outcome of every measurement can be exactly predicted?
We should understand clearly that this question is a question
about the nature of our world which can only be answered on the
basis of experimental studies. Pure logic tells us nothing about
what the answer should be.
The theories of Classical Physics are based on the proposition
that the answer to the question is yes. Quantum Mechanics is a
theory based on the proposition that the answer is no, (To prevent
misunderstandings we must state here that quantum mechanics is
merely a particular one among conceivable theories which answer
the question by no.) When we accept quantum mechanics as our
theory we thus introduce an indeterminacy in our description of
nature in the precise sense that no matter how we prepare a pure
ensemble there will always be a measurement the outcome of which
is not predictable in any particular case. (The measurement which
is not predictable depends on the ensemble,) This does not mean
that quantum mechanics is “chaotic and vague,” The theory is
a very definite theory in which we can make precise quantitative
statements about probabilities, or about average values of physical
variables,
52 It is in the nature of the question which we have asked that

no single set of experiments could possibly decide with finality what
the answer should be. Whenever we encounter a phenomenon

where we would be tempted to say that the answer is noy we might
always try to save the situation by the argument that if the meas¬
urements are done in a “better way,” then the conclusions would
be different. In other words: it could always be argued that the
indeterminacy arises only from the fact that the experimental ar¬
rangements are not the best possible. This kind of argument is
hard to refute in an absolute sense. On the other hand, it is fair
to ask the person who argues in favor of a deterministic theory of
nature, in the classical sense, to show explicitly how the measure¬
ments are to be performed such that the indeterminacy character¬
istic of quantum mechanics disappears.
The evidence in favor of the answer no is two-fold. First of all,
the detailed analysis of a large variety of experiments, in which
we take into account observed properties of particles, always seems
to lead to the conclusion that the answer should be no. Secondly,
there is the fact that all the predictions of the theory of quantum
mechanics, in which theory the answer no is a cornerstone, seem
to be in very excellent agreement with all the observed facts: as¬
suming no as the answer never seems to lead us to any contradiction
with experience.
53 In Chaps. 4 and 5 we have already presented very convincing

evidence that the answer must be no. The real particles found in
nature spread out like waves in space. The waves are divided by
half-silvered mirrors and by double slits, and in general diffracted
by any obstacle. On the other hand, if we look for the particle
with a photo-cell, or some other particle detector, we never find
“fractional photons,” or “fractional electrons.” To describe con¬
sistently all of these phenomena we are forced to a probability
interpretation of the intensity of a wave: quantities which are pro¬
portional to the absolute square of the wave function must repre¬
sent probabilities. We can only state the probability for a counter
to click, but we can never arrange it so that we are certain about
the response of every counter in every single experiment.
Consider, for instance, the double-slit experiment. If we want
to be certain about the momentum of the incident beam we must
arrange it so that the momentum of the particles is extremely well
defined. When such a beam is incident on a screen with two slits
we will observe the characteristic two-slit diffraction pattern. This
pattern can arise only if both slits are open, i.e,, only if the particle
passes through both slits. However, if we try to catch the particle
with a counter placed behind one of the slits we do not detect half
of the particle, but the entire particle. In any single experiment
the counter may, or may not, click, and we do not know beforehand
what will happen with certainty: we can only state the probability
that the counter will click The reader may say: Well, that is only
because the ensemble is not pure, But what does the reader sug¬
gest that we should do in order to make it purer?
54 The crux is clearly whether it is possible to describe a particle

in some other way in more detail than it can be described in terms
of the wave theory. If the wave description is correct, and if in
addition the particles have the property of indivisibility so that we
can never detect "fractional particles,” then there seems to be no
escape from the probability interpretation of intensities* Let us
recall our discussion of the uncertainty relations in the beginning of
this chapter. If the momentum of the particle is to be accurately
known it must be described by a wave which is spread out in space,
but then the position of the particle cannot be accurately known.
A small statistical spread in momentum measurements implies a
large statistical spread in position measurements, and as long as we
accept the wave description with the probability interpretation of
intensities there is just no way of beating the uncertainty relation.
On the other hand, there is no experimental material which would
suggest that a particle can be described in more detail than the
wave description permits: there is absolutely no evidence for any
'^hidden variables.”
These considerations have led to the following basic assumption
of Quantum Mechanics: the pure states of a particle are described
by waves. An ensemble of one-particle states is pure if and only if
every element of the ensemble is described by the same wave func¬
tion* When we can state a wave function which describes all the
particles of an ensemble it means that we have maximum possible
control over the source. Nothing can be purer than a definite wave,
55 It is interesting to compare some aspects of the classical world

of fantasy with the real world. The concepts of statistical en¬
sembles, statistical mixtures and pure states are not at all foreign to
classical physics. The idea of a statistical ensemble was in fact
introduced in classical statistical mechanics long before the dis¬
covery of quantum mechanics. A good portion of our discussion
of the measurement process remains applicable within the frame¬
work of a classical description. A pure state thus arises when we
have perfect control over the preparation stage, whereas a statistical
mixture arises when our control is less than perfect. The crucial
difference between the classical and quantum-mechanical descrip¬
tion lies in the nature of the pure state. According to classical ideas
a pure state has the property that the outcome of every single
measurement is exactly predictable. If a given counter clicks in
one single experiment, it clicks in every subsequent experiment as
well. Each time an experiment is repeated the same things happen
which have happened before. For a pure state there is no statistical
spread in any physical variable.
Physicists have recognized for a long time, and long before the
development of quantum mechanics, that happenings in the macro¬
scopic world cannot in practice be predicted with unlimited pre¬
cision. Thermal noise and many other kinds of “disturbances”
over which we have no control are always present, and in macro¬
scopic situations these causes of uncertainty in the value of a phys¬
ical variable completely mask the characteristic quantum-mechan¬
ical uncertainty. The classical physicist's belief that pure states
are characterized by a complete absence of statistical spread in the
variables was never really critically tested in macroscopic situations,
and this explains why the belief could persist for so long.
56 The recognition of the probabilistic nature of all predictions,

even in the case of a pure ensemble, was an important step in the
development of physical theory. When we consider in retrospect
the early history of quantum physics we can appreciate the con¬
ceptual difficulties which physicists faced before the emergence of
the probabilistic description. That light could exhibit both wave
properties and corpuscular properties was a liewildering discovery.
This “duality/' as it was then called, can now be easily understood
along the lines discussed in Chap. 4, but in the early days of quan¬
tum physics the situation was different. It had not occurred to
anybody to interpret the square of a wave amplitude in terms of
probabilities, and without this idea, which is a radical departure
from classical ideas, the “duality5* of light cannot be understood.
That there is a limit in principle to our ability to predict future
events has been regarded by many, and in particular by philosoph¬
ically minded non-physicists, as a most profound and revolutionary
idea. Inevitably an enormous amount of nonsense has been
written about this issue (and about the uncertainty relation) and
the authors have drawn all kinds of far-fetched conclusions about
the implications of quantum mechanics for human affairs in general.
The author does not deny that the question of predictability
versus non-predictability is an interesting question of principle, and
that it is a legitimate subject of philosophical speculation. He
wants to mention, however, that professional physicists today
appear to pay very little attention to this issue. The author cannot
recall a single lunch-table discussion in which this issue has been
Sec* 6*57 Uncertainty Principle and Theory of Measurements 2S9
mentioned, (Lunch-table discussions otherwise range over all

questions which occupy the thoughts of physicists*) It is, in fact,
fair to say that physicists think very little about the theory of
measurements in quantum mechanics, except when they teach an
introductory course on the subject.
Polarized and Unpolarized Light
57 A study of the polarization of light can give us a nice illustra¬

tion of the distinction between a pure state and a statistical mixture
within quantum mechanics. Consider the experimental arrange¬
ment shown in Fig. 57A* Almost monochromatic photons of fre¬
quency w pass through a polarization filter F*, and emerge from the
source through the slit in the screen S. The preparation of the
statistical ensemble thus takes place to the left of S, The emerging
photons are studied by a photo-cell P, fitted with a polarization
filter Fjy, and the filter together with the photo-cell is to be regarded
as a single instrument described by the counter variable D.
It is possible to construct polarization filters which perform to a
very high degree of perfection, and which thus have the property
that they let through unhindered waves of a definite state of polariz¬
ation, but completely absorb waves in the opposite state of polariza¬
tion. We shall assume that the filters Fs and Fp are perfect polariza¬
tion filters> the properties of which we can select at will,
58 Suppose now that we let the filter F* be a filter which lets

S
through only left-circularly polarized waves: the emerging photons Photocell F
Lamp
are elements of a statistical ensemble pWe first determine the
counting rate with the filter Fp removed: this will tell us the number
®—
-B
of photons emerging per unit time, and serves to normalize our Filter Filter Fp
data. We assume that the counter P has 100 percent efficiency so
that it counts every photon which reaches it. Let the counting Preparation of Measurement of
rate be n photons per unit time* the ensemble p the variable D
We consider several different filters Fp, and to every filter-counter
combination corresponds a counter variable D. The average of D
Fig. 57A Schematic figure showing an experiment
is defined as the ratio n'fn, where nf is the counting rate in the with polarized light. The filters Fs and Fp are assumed
presence of the filter. If Fp is a filter letting through only left-cir- to be ideal polarization filters. (Light passing through
cularly polarized light, the corresponding counter variable is an ideal polarization filter emerges in a definite pure
denoted by Dif it lets through only righLcircularly polarized state of polarization, and the filter is completely trans¬
light we denote the counter variable by D& if it lets through light parent for such light.)
The response of the counter F for an individual
polarized linearly in the x-direction we denote the variable by
photon is not precisely predictable unless the filters
if it lets through light polarized linearly in the (/-direction we denote F3 and Fp correspond to the same (pure) state of polar¬
the variable by Dy> Finally, we consider filters which let through ization.
light linearly polarized along the line which bisects the quadrant
bounded by the positive x- and y-axis (counter variable 045°) and
filters which let through light polarized perpendicular to this bi¬
sector (counter variable D1350).
For the ensemble p£, we find the following averages:
Av(Z>L;pL) = 1, Av(DapL) = 0 (58a)
Av(Dx;pL) = Av(Dp;pL) = Av(D45°;Pl) =

Av(D1350;Pl) - i (58b)
For this ensemble the two variables Dl and Du are precisely

known, whereas we are in a state of maximum ignorance about the
remaining four variables. Is the ensemble pz, pure? What this
question redly means is: can we make it purer? The answer is no.
If we require that the variables and Dr be precisely known and
have the values given in Eq. (58a) we know that the photons emerg¬
ing from the source must be strictly left-circularly polarized. But
every left-circularly polarized wave can be resolved into two
linearly polarized waves, of equal amplitude, and polarized per¬
pendicular to each other. If we insert a filter which removes one
of the linearly polarized conponents the intensity of the transmitted
wave will be ^ the intensity of the incident light. The averages of
the variables D$, Dv,, and Di3s° must therefore necessarily be
as stated in Eq. (58b). If we now combine this experimental result
about the averages with the experimental result that photons cannot
be split (“in energy”) by a polarization filter, we draw the inevitable
conclusion that none of the four variables DVt D45° and D135°
is precisely predictable in any single experiment. In fact, the
uncertainty about these variables is as large as it can be, and this is
despite the fact that the ensemble must be regarded as the purest
possible ensemble of circularly polarized photons.
59 The reader should note carefully that the conclusion would

be entirely different if photons behaved in every respect like classi¬
cal wave trains. Then the average of the variable Dx would depend
on the sensitivity of the detector. If the sensitivity is such that the
energy carried by half a wave train is registered, then the counting
rate of Dx would be the same as the counting rate of D^ i.e.
Av(Af;pl) =1, whereas the average would be zero if the sensitivity
is such that the energy carried by half the wave train is not suffi¬
cient to trigger the counter. Actual photons do not behave like
classical wave trains: irrespective of what filter we place in front of
the counter we will always find that each photon registered by the
counter carries the energy foo.
The response of the counters D^ Dy> D^ and 1)135° is therefore
not predictable in any single experiment on the pure ensemble pL,

and we here have strong evidence in support of the general con¬
clusions stated in Secs* 51-54*
60 What happens if we remove the filter Fs? If we assume that

the “lamp" is a spherically symmetric object there will be no pre¬
ferred directions, and every state of polarization is just as likely as
any other state of polarization* We say that the light is unpolarized.
The corresponding ensemble, po, is the most chaotic ensemble with
respect to the polarization-degree-of-freedom, and irrespective of
the nature of the ideal polarization filter Fp the counting rate with
the filter will be ■£■ times the counting rate without the filter* We
thus observe the averages
Av(P^;p0) = Av(Ds;po) = i (60a)
Av(Da;po) = Av(Dy;po) = Av(D45*;Po) =

Av(E>i35*;po) = £ (60b)
We note that the averages in (60b) agree with the averages in

58b), and the amount of ignorance about the four variables Dy,
1)45° and Di35* is therefore the same for the ensembles pl and po.
The ensembles differ in the amount of information which we have

about the two variables Dl and Dr; for pL we have perfect knowl¬
edge about these variables whereas we know as little as is possible
about them for the ensemble po.
We thus expect that the ensemble po must be a statistical mixture*
To see this explicitly we first consider an experiment when the filter
F3 lets through only right-circularly polarized waves* Call the
corresponding ensemble pr. The ensemble averages are then given
by
Av(Dl;pr) = 0 A\(Dr;pr) = 1 (60c)
Av(D*;ps) = Av(Dv;pR) = Av(D45sPjs)-

Av(Di3s°;pjg) = \ (60d)
As the reader should check in detail, the ensemble averages for

po, Pr and pl are such that we can write
Po = iPi + \pr (60e)

in accordance with our discussion in Sec* 38, We can therefore
regard the chaotic ensemble po as an incoherent superposition of the
two pure esembles pr and p£.
61 The author wants to mention that he was bothered in his

childhood by the difference between unpolarized light and dr-
cularly polarized light. The books said that unpolarized light is a

mixture of light polarized in two perpendicular directionSj and the
books also said that circularly polarized light is a superposition of
light polarized in two perpendicular directions* The author finally
realized that for circularly polarized light one adds the amplitudes
of the two linearly polarized components, but for unpolarized light
one adds the intensities* Circularly polarized light is a coherent
mixture of light polarized in two perpendicular directions, whereas
unpolarized light is an incoherent mixture.
1) It is proper that the reader supplement the theoretical studies ii> this chapter with
some reading on actual counters and related equipment.
a) Chapter 5, of D, Halliday; Introductory Nuclear Physics, (John Wiley and Sons,
Inc., .1950), is devoted to a discussion of the detection of charged particles and photons.
Various types of counters, and associated electronic equipment, are discussed,
b) The statistical analysis of counter data is discussed in the above reference. See
also, L. J. Rainwater and C, S. Wu: "Applications of Probability Theory to Nuclear
Particle Detection,” Nucfeomcff vol. 1, no. 2, p, 60, (1947) for a simple and clear dis¬
cussion,
c) G, D, Rochester and J. C. Wilson: Cloud Chamber Photographs of the Cosmic
Radiation (Academic Press, Inc.t New York, 1952), It is eminently worthwhile to look
at this book and its many interesting pictures,
d) An elementary discussion of the detection of particles is given in Chap. 3, in
D, H, Frisch and A, M. Thorndike: Elementary Particles (D, van Nostrand Company,
Inc., 1964),
e) For a collection of stereoscopic bubble chamber pictures, sec Intnxlurtion to the
De tertian of Nuclear Particles in a Bubble Chamber (Prepared at the Lawrence
Radiation Laboratory, The University of California, Berkeley.) (The Ealing Press, 1964,)
2) Note the following articles in the Scientific American magazine:
a) O. M. Bilaniuk, "Semiconductor Particle-Detectors,” Oct. 1962, p. 76.
b) G. B. Collins, "Scintillation Counters,” Nov. 1953, p. 36.
c) G. K. O’Neill, "The Spark Chamber,” Aug. 1962, p. 36.
d) H, Yagoda, "The Tracks of Nuclear Particles,” May 1956, p. 40.
e) D, A. Glaser, "The Bubble Chamber,” Feb, 1955, p. 46.
f) D, E. Yount, "The Streamer Chamber,” Oct. 1967, p. 38.
Problems
1 One of the favorite arguments of those who want to refute the un¬
certainty relation goes as follows. (See adjoining figure.) A monoenergetic
beam of electrons, of momentum p, is incident normally on the screen Si
from the left. This screen has a circular hole, of diameter a♦ At a distance d
Problems Theory of Measurements 263
from the screen Si we have another screen 82, which likewise has a circular
hole of diameter a. We assume that the two holes are lined up in the direc¬
tion of the incident beam. Some of the electrons which pass through the first Incident
hole might be deflected, but some of them will go on to pass through the beam r*-d-J
Si S2
second hole. Consider an electron which has passed through the second hole.
The uncertainty in its lateral position is of order Ax ^ a, The magnitude of
This figure refers to Prob, lf in which the author fal¬
its momentum is p, the same as in the incident beam, because the electrons laciously argues that the uncertainty relation can be
do not lose or gain energy in this experiment. Since we know that the elec¬ violated if we make the slits narrow and the separation
tron has passed through both holes the uncertainty in the direction of the d large. It then seems that the product of the un¬
momentum must be less than, or equal to, A6 — a/d, It follows that the certainty in lateral momentum with the uncertainty in
lateral position at the moment the particle passes
uncertainty in the lateral component of the momentum of the electron is of
through the second slit can be made as small as we
order Ap = (a/d )p. We thus have
like. What is wrong with this idea?
ap
fur the product of the uncertainties in lateral position and lateral momentum.
By making a small and d large we can make this product as small as we please,
and hence violate the uncertainty relation, which is one of the cornerstones
of quantum mechanics.
Can you demolish this argument? Make sure that you meet all counter¬
arguments to your arguments.
The above argument is one among many that have been advanced against
quauturn mechanics via the uncertainty relation. Now it should be clear
that there is never any danger that the uncertainty relation will be refuted by
this or any similar arguments, as long as the premises of toave mechanics are
acceptedJ because with these premises the uncertainty relation can be proved.
One might group the “refutations” of wave mechanics into two classes:
(a) Arguments in which the ideas of wave mechanics are really denied,
although this is not always stated explicitly,
(b) Arguments which are "muddled” but which are based on some of the
ideas of wave mechanics.
A careful conceptual analysis will clarify the nature of the “refutation.” An
outright denial of the principles of wave mechanics cannot, of course, be
contradicted on logical grounds, but one can always appeal to experimental
facts: the “refutation” carried to its logical conclusion might contradict one
of these facts. The arguments in the category (b) are simply faulty.
2 (a) We consider an idealized experiment in which almost perfectly

monochromatic light of wavelength 6000 A passes through an extremely fast
shutter. Suppose that the shutter opens and closes periodically in such a
way that the shutter is open for a time of 10-10 sec, and then closed for 0.01
sec during a period. The light passing through the shutter would then no
longer be monochromatic, but would show a certain spread in wavelength.
Estimate the magnitude of the uncertainty in the wavelength in Angstrom

units.
(h) We let the light emerging from the shutter pass through a long tube
filled with carbon disulfide. This medium is dispersive, and for the wave¬
length considered the variation of the refractive index n with wavelength Ls
given by
A dn
0.075
n dX
The velocity of the pulse of light let through the shutter could be measured
by another shutter placed at a certain distance from the first, and opened at
a slightly later time. What is the velocity by which the pulse propagates in
the carbon disulfide?
3 The author has a new idea for violating the uncertainty principle: this
time the time-frequency uncertainty relation. The arrangement is shown
very schematically in the adjoining figure. Almost monochromatic light is
incident through the slit at left which is fitted with an extremely fast shutter.
We shall not be concerned here with purely technical difficulties, and we
thus assume that the shutter can be opened for an arbitrarily short interval of
time, to admit a sharply defined pulse into the spectrograph indicated sym¬
bolically by the prism in the figure* The entering fight will, of course, no
longer be monochromatic, but will exhibit a spread in frequency as discussed
in Prob. 2. We can, however, fit the spectrograph with a suitable narrow exit
slit, shown at right in the figure, and thereby select a portion of the incident
light whose wavelength falls within an extremely narrow range. The fight
emerging through the exit slit can therefore be made monochromatic to an
arbitrarily high degree: the uncertainty in the frequency can be made as
Fast shutter
small as we like. On the other hand the duration of the pulse can be made
as short as we like with the help of the shutter The pulse emerging through
the exit slit can therefore be of arbitrarily short duration, and be of an arbi¬
trarily precise frequency, contrary to what the uncertainty relation says* Can
you find the fallacy in this argument?
4 With reference to our discussion in Sec, 29, suppose that the tempera¬
This figure refers to Prob, 3. The author again tries
ture of the filament is 1000° C, and suppose that the accelerating potential is
to violate the uncertainty relation. The prism sym¬
bolizes a spectrograph of very high resolution which 10 volts* Estimate the fractional precision in the momentum of the emerging
is used to select an extremely narrow frequency electrons, i,e*, estimate the quantity q/po- A crude estimate is enough.
range of the transmitted light* The incident light is Explain your ideas*
controlled by a fast shutter. The author erroneously
maintains that the light pulse emerging from the exit
slit can be arbitrarily well defined both in frequency 5 If we could produce electron beams of very low energy it would be
and time. What is wrong? possible to do macroscopic” electron-diffraction experiments. Suppose
that we try to produce a beam of well-defined momentum, with a mean
Problems Theory of Measurements 265
energy of 0.01 eV* Discuss the practical difficulties which we might en¬
counter in this attempt. It is clear that a hot filament with a single accelerat¬
ing electrode would not do, but there are perhaps other methods which you
might think of* If so, state your ideas, and discuss their technical feasibility*
6 Consider the grating shown in the figure illustrating Prob. 5 in Chap. 5*

Suppose that the grating is not infinitely long, but contains only N openings.
In this case the grating is not strictly periodic* and it follows that the diffracted
beams exhibit an angular spread. We can express the matter as follows:
the characteristic minimum momentum transfer to the grating is no longer
precisely 2vr/a* but is only defined within an uncertainty of Aq. Try to find
a relation between N and Aq* Turn the figure 90% and compare with Figjs,
5ABCD in the present chapter: this comparison might give you some ideas.
Use your result to derive an expression for the uncertainty in the angles at
which the various diffracted rays emerge*
7 Consider an almost monochromatic beam of light emerging from a

steady source* The problem is to determine the unknown state of polarization
of this beam through measurements carried out in the “experimental region.”
(a) You have available ideal polarization filters and a photomultiplier.
What is the smallest number of intensity measurements which you have to
carry out in order to determine the polarization state of the beam completely?
Explain the basis for your stated conclusion.
(b) Suppose you are given a photo-multiplierf two identical sheets of
Polaroid and a quarter-wave plate. How would you determine the state of
polarization of the beam, using only the equipment mentioned? lu this case
you must not assume that the polaroid is an ideal polarization filter.
& The adjoining figure shows a refinement of the double double-slit ex¬
s ^ a 9X
periment discussed in Secs* 41-43. Ideal polarization filters are placed (or not
^M
\
placed) in front of the slits and in front of the source %nd the detector. We
0
\ / P21
X
assume that the transfer amplitudes discussed in Secs* 41-43 are independent /\
B
of the state of polarization, and we assmne that the light source emits un¬
polarized light. Derive expressions, analogous to (43b), for the probability
Nil/ B\lk'
F'|—%—fF''
that a photon entering through the slit in S will pass through the slit in D, for
the various combinations of polarization filters listed below*
This figure refers to Prob, S. It illustrates a refine¬
F
L X Fi F'a F£' F? Frf ment of the double double-slit experiment shown in
Fig. 41 A. Ideal polarization filters can cover the
abs H V abs abs abs various slits. The problem is to determine the prob¬
LC H V abs abs abs ability that a photon entering through the slit in S
LC H V abs abs RC emerges through the slit in D for various combinations
LC H V RC LC H of filters. The numbers AWl and Cm are the
abs II abs abs H abs transfer amplitudes in the absence of the filters. We
assume that the transfer amplitudes do not depend on
In this table “abs” means that the filter is not there, H means a horizontal the state of polarization.
polarizer, V a vertical polarizer, LC a left-circular polarizer and RC a right-

circular polarizer.
9 Let us consider the difference between an ideal counter and a practical

counter. The practical counter will unfortunately click even if the event
under study does not take place, and it will also sometimes fail to register
when it ought to. The rate of clicking with the source shut off is known as
the background rate, One source of background counts is the cosmic radia¬
tion which is always present. Furthermore, if two events are separated by
too small a time interval the practical counter responds with only a single
click. We call the smallest time to for which two events are registered as
separate events the resolving time of the counter* We can determine the
resolving time of a counter as follows* We have two radioactive sources,
1 and % which can be placed at certain definite positions near the counter,
such that they produce roughly the same counting rate in the counter* Let
Ao be the counting rate with both sources removed. Let Ni be the counting
rate with source 1 present, and let A7g be the counting rate with source 2
present. Let be the counting rate with both sources present* We ar¬
range it so that N12 is considerably smaller than I/to» although not completely
negligible compared with l/to. We furthermore assume that ATo is smaller
than A'i, or Ar2 or Ari2, Show that it is possible to determine to from these
four rate measurements, and derive an expression for fo in terms of A7o, iVi,
AT2 and Nw-
Note that for an ideal counter, and for the case of no background, we
would have Ati2 = Nx + N2.
Chapter 7
The Wave Mechanics
of Schrodinger
Sections 1 to IS Schrodinger’s Non-Relativistic Wave Equation 268
19 to 36 Some Simple “Barrier Problems’* 279
37 to 48 Theory of Alpha-Radioactivity 292
49 to 51 Advanced Topic: Normalization of
the Wave Function 304
Problems 307
Chapter 7 The Wave Mechanics
of Schrddinger
Schrodinger’s Non-Relativistic Wave Equation
1 We shall now turn our attention to a phenomenological theory

which has played an extremely important role in the development
of quantum physics. This is the theory of the Schrodinger equa¬
tion, first formulated by Erwin Schrodinger in 1926f shortly after
Heisenberg’s invention of matrix mechanics. These two theories
were the first quantitative formulation of some of the principles of
quantum mechanics.
We discuss the Schrodinger theory in this book because we want
to see how a wave theory works out in practice, and see how one
can actually compute things within such a theory. We have
selected the non-relativistic Schrodinger theory as our example of
a wave theory because it is, in many respects, a particularly simple
theory.
2 The theory of the Schrodinger equation (in the most restrictive

sense) is based on several drastic approximations, among which we
note the following two:
L Creation and destruction phenomena of particles are ignored,
and in any given physical situation it is thus assumed that the
number of each kind of particle remains constant as the process
evolves in time.
II, It is assumed that all relevant velocities are sufficiently small
so that a non-relativistic approximation is valid: the discussion is
non-relativistic throughout.
Erwin Schrodinger, Born 1887 in Vienna; died 1961.
We recognize these two assumptions as drastic approximations
Schrodinger studied physics at the University of
Vienna, and obtained his degree in 1910. After short
because we know, empirically, that creation and destruction phe¬
stays in Stuttgart and Breslau he became professor nomena do occur in nature, and because we also know that any
of physics at Zurich. In 1927 he was invited to Berlin fundamental theory must take the facts of special relativity into
as Planck's successor. Schrodinger left Germany in account.
1933, and eventually accepted a position at the Insti¬
The two assumptions which we have made are not unrelated to
tute for Advanced Studies in Dublin, as director of its
School for Theoretical Physics. He received the
each other. Consider, for instance, a collision process in which
Nobel prize in 1933. two particles of equal mass collide with each other in such a way
The four papers of Schrodinger mentioned in the that the velocity of each particle in the center of mass system is
beginning of this chapter constitute a monumental close to the velocity of light. Under these circumstances there may
contribution to physical theory. Within a very short
be available sufficient kinetic energy for the creation of additional
time of his discovery of wave mechanics great ad¬
vances were made in atomic physics, Schrddinger
himself played a very active role in this development. f E. Schrodinger, “QuanHsierung ds Eigenwertproblem,” Annalen der Physik 79,
(Photograph by courtesy of Physics Today.) 361 (1926); 79, 489 (1926); 80, 437 (1926); 81, 109 (1926).
Sec, 7.3 The Wave Mechanics of Schrodinger 269
particles of the same mass, or perhaps of different masses. If, on

the other hand, the velocities are small, and the available kinetic
energy thus likewise small, then creation phenomena cannot take
place: they are forbidden by the law of conservation of energy.
There is one notable exception to this statement. Since the rest
mass of the photon is zero, photons can always be created or
destroyed (i.e,, light can be emitted or absorbed) even if all the
other particles of non-zero rest masses move at non-relativistic
velocities. If we understand the Schrodinger theory in a wider
sense, we incorporate the description of light absorption and
emission into the theory. We must then amend our assumptions as
follows:
L* Creation and destruction of material particles are assumed
not to take place, whereas photons may be emitted and absorbed.
II** All material particles are assumed to move with small velo¬
cities and they can thus be described non-relativistically. The
photon, which can never be described non-relativistically, is ac¬
corded a special treatment.
We should mention that there are theories of “relativistic” wave
equations in which our second assumption is relaxed. The famous
Dirac equation is an example of such an equation. There is also a
“relativistic” version of the Schrodinger equation. We shall not
discuss these theories here: when we speak of the Schrodinger equa¬
tion we mean the non-relativistic version, based on our stated
assumptions*
3 In the first paragraph of this chapter we referred to the

Schrodinger theory as a phenomenological theory. It should be so
described because it is clearly recognized that the Schrodinger
theory cannot claim to be a fundamental theory. We have men¬
tioned some reasons why this is so, and we want the reader to
understand this point clearly. The theory of the Schrodinger
equation is not the same thing as the theory of quantum mechanics
in general.
However, we also want to state explicitly that the Schrodinger
theory has proved to be extremely successful when applied to atoms
and molecules, and nothing that has been said should be construed
as a down-grading of the Schrodinger theory as a useful approxima¬
tion.
4 Before we discuss the Schrodinger equation itself, let us try to

understand why the Schrodinger theory, which is based on the two
assumptions stated in Sec. 2, should be so successful when applied
to atoms and molecules. The basic reason for this is the “small”
2 70 The Wave Mechanics of Schrodinger Sec. 7,5
value of the flue structure constant a ~ 1/137* We concluded in

Chap, 2 that because a is much smaller than unity, atoms and
molecules are loosely bound structures of slowly moving particles.
We found, among other things, that to the extent that it makes
sense to talk about the velocity of an electron in the hydrogen
atom, its velocity will be of the order of ac ~ c/137, This velocity
is also characteristic of the outermost electrons in other atoms.
The nuclei in a molecule will move with a still smaller velocity,
and the second assumption on which the Schrodinger theory is
based is therefore reasonably well satisfied in the realm of atoms
and molecules,
5 Concerning the first assumption we refer to our qualitative

discussion in Chap, 2 of the characteristic transition energies in the
physics of atoms and molecules. The energies characteristic of
molecular binding and of optical transitions are typically of the
order of 1-10 eV. The highest energies relevant for atomic struc¬
ture are the energies of X-rays emitted by the heavy elements, and
these energies do not extend beyond 100 keV,
These energies may be contrasted with the rest energy of an
electron which is 0,5 MeV, There are no lighter particles than the
electron (except the photon, which we agreed should be treated
differently), and an electron cannot be created alone in an electro¬
magnetic process but only together with a positron. The creation
of a pair requires, however, an energy of 1 MeV, which is much
larger than the typical atomic and molecular energies. (The reader
All attempts at a realistic pictorial representation of
may object that neutrinos> which have zero rest mass, are indeed
an atom are doomed to failure. Such a picture sug¬
gests to us something which we could actually see lighter than electrons. The neutrinos interact however, only very
with our eyes. The behavior of an atom is so differ¬ weakly with other particles, and in comparison with the electro¬
ent, however, from the behavior of any familiar macro¬ magnetic interactions the neutrino interactions are completely
scopic object that a direct visualization is out of the negligible. In atomic and molecular physics we can forget about
question. This does not prevent us from representing
the existence of neutrinos,)
some aspects of an atom by a picture. A schematic
picture of this kind is somewhat analogous to a car¬
toonist's representation of complex human activities. 6 Quantum electrodynamics, which is a particular example of a
If the conventions upon which the picture is based so-called quantum field theory, has a good claim to being the
are generally understood, the picture does convey a “correct” theory of atoms and molecules. The Schrodinger theory,
message.
The above representation of the helium atom is not
applied in this realm, can be regarded as the first approximation to
intended to be frivolous. The reader is here reminded the “correct” theory. If we compare the predictions of quantum
that the electrons move slowly in (light) atoms, which electrodynamics with the predictions of the Schrodinger theory
is why the non-relativistic Schrodinger theory is ap¬ we can explicitly study the accuracy of the latter theory. The
plicable. There is another purpose behind the figure.
general result is that the main features of atomic and molecular
Whenever the reader sees a picture which is supposed
to represent an atom, nucleus or molecule, he should
structure are accounted for correctly by the Schrodinger theory.
remember the Wichmann model and the above re¬ We can express this mathematically as follows. Many theoretical
marks about pictorial representations. expressions for atomic and molecular quantities, such as energies of
Sec. 7J The Wave Mechanics of Schrodinger 271
stationary states, wavelengths of emitted lines, lifetimes of excited

states, geometric parameters of molecules, etc*, can be expanded
in powers of the fine structure constant a. In such expansions the
Schrodinger theory gives the leading term correctly* The terms of
higher order can be thought of as “relativistic corrections/1 These
corrections are generally small because of the smallness of a*
7 Let us now try to formulate the Schrodinger theory for a very

simple physical situation, namely the motion of a particle, say an
electron, in an external field of force* The Schrodinger theory is
to be sure much more general than that, and it may be employed
to describe the motion of any number of particles interacting
mutually with each other* To understand the general features of
this theory we should, however, begin with the simplest physical
situation*
Let us first consider an even simpler case, namely the case of a
single particle moving in the absence of any external forces: in this
case we speak of a free particle. The Schrodinger theory is con¬
cerned with a wave equation, known as the Schrodinger equation,
which describes the de Broglie waves associated with the particle*
In Sec. 37, Chapter 5, we have already derived such a wave equa¬
tion, namely the Klein-Gordon equation. This equation is rela-
tivistically invariant: it holds irrespective of whether the particle
moves slowly or rapidly, and it has the same form in every inertial
frame of reference. We now wish to modify this wave equation in
accordance with the principles on which the Schrodinger theory is
built, which means that we wish to carry out a non-relativistic
approximation. Furthermore we will give a definite physical inter¬
pretation to the wave function i//(x,£) which describes the de Broglie
wave.
8 In Chap. 5 we have already given a rough interpretation of the

wave function: the “particle is most likely to be found in those
regions of space in which the amplitude ^(xj) is large*" We shall
now make a specific assumption through which this idea becomes
precise.
The Schrodinger wave function ip(x,t), i*e., the amplitude of the
de Broglie wave in the Schrodinger theory, describes the probability
distribution of the particle in space and time, as follows. If we
attempt to locate the particle through a measurement of its position
at a given instant of time t the probability that we find the particle
in a small region of volume d3(x) containing the point x is propor¬
tional to | l/'fx,#) f 2d3(x). The probability density is thus proportional
to the absolute square of the wave function*
272 The Wave Mechanics of Schrodinger Sec. 7,9
This assumption is characteristic of, and fundamental to, the

Schrodinger theory. If we wish to be able to make precise com¬
putations we naturally have to give some interpretation to the wave
function, and the probability interpretation which we have formu¬
lated above is both convenient and physically transparent. This
profound and important idea was first stated by Max Bomf
9 The Schrodinger wave function is a complex-valued function

of position and time which satisfies the (linear) Schrodinger equa¬
tion which we shall presently write down. Every definite wave
function corresponds to a definite state of motion of the particle.
Now we should note that if is a possible wave function, so is
the function ei<?^(x,£) = î(x,£) where 0 is any real constant.
Furthermore, and what is most important, the probability distribu¬
tions defined by ^ and by are identical. This means that the
two wave functions ^(x,f) and î(x,f) describe the same state of
motion of the particle. We may express this as follows: to every
wave function corresponds a unique state of motion of the particle.
The converse is not true: a given state of motion of the particle
defines a Schrodinger wave function only up to a constant complex
factor of modulus unity, i,e., up to a complex factor of absolute
value 1, Two wave functions which differ only in such a factor
correspond to the same physical state.
10 Let the mass of the particle be m. We consider a plane wave

of momentum p. The energy of the particle is then given by\
E = -yjm2c4 + c2p2 (10a)
Let us now go to the non-relativistic approximation in which we

Max Born. Born 1882 in Breslau, Germany (now in assume that the velocity of the particle is much smaller than the
Poland). Born first studied mathematics at Breslau,
velocity of light. This means that in Eq, (10a) the term (cp)2 is
Heidelberg, Zurich and Gottingen, but later changed
to physics. In 1921 he was appointed professor of
much smaller than the term (me2)2, and we shall therefore expand
theoretical physics at the University of Gdttingen. the square root in (10a) keeping only the first two terms:
Born left Germany in 1933, and after three years at
Cambridge he was appointed professor of natural E ^ me2 + (10b)
philosophy at the University of Edinburg. After his
retirement in 1953 he returned to Germany. He was
awarded the Nobel prize in 1954. The first term in (10b) is the rest energy of the particle, and the
Born made many significant contributions to the second term is the non-relativistic expression for the kinetic energy
development of both matrix mechanics and wave me¬ of the particle.
chanics, as well as in other domains of physics. His
The corresponding de Broglie wave function, which we denote
statistical interpretation of quantum mechanics is
particularly noteworthy. It was an essential step that
had to be taken before the theory could realty be phys¬ f M. Bom, ‘ ‘ Quant enmechanik der Stossvorgange/’ Zeitsckrift fiir Physik 38, 803
ically interpreted in a consistent manner. (Photo¬ (1926).
graph by courtesy of Physics Today.) J We use MKS or cgs units in this chapter.
Sec. 7A1 The Wave Mechanics of Schrodinger 273
by is then given approximately by
Wx,() = exp(H^-^)«p(-^) (10=)
We have written the wave function as a product of two factors.

The first of these we shall denote by ^jg(x,f):
(V'- S) <1M>
and we then have
= ^s(x,0 exp (- ^j^-j (10e)
and hence
\M^)\*= |* (lot)
As we see from equation (lOf) the two wave functions and
\pB differ only in a complex factor of modulus unity and this factor
is independent of the state of motion of the particle, i.e*, it is in¬
dependent of p* The absolute squares of the two wave functions
are identical everywhere and at all times* To describe the prob¬
ability distribution of the particle we can employ the wave function
t/'s just as well as the “correct” de Broglie wave function ^ This
Ls precisely what is done in the Schrodinger theory, and as
given by (lOd), is thus taken to be the Schrodinger wave function
describing a free particle moving with the small momentum p. This
convention is purely a matter of convenience; why should we carry
along the factor exp (—itmc2/1i) in our calculations when it ulti¬
mately has “no physical effect?”
II An arbitrary Schrodinger wave can be obtained as a super¬

position of plane Schrodinger waves of the form (I0d)* To find the
wave equation satisfied by every Schrodinger wave we proceed as
in Sec* 37, Chap. 5* We find, in other words, the simplest linear
wave equation satisfied by every pZane-wave function. The deriva¬
tion is entirely analogous to our discussion in Chap. 5 and we obtain
72 >Kx’f) (lla)
where we have dropped the subscript S from the wave function:

henceforth we will only deal with the Schrodinger wave function
= i^(x,t) and the subscript is therefore superfluous.
The equation (lla) is the Schrodinger wave equation for a free
274 The Wave Mechanics of Schrodinger Sec. 7.12
particle. It describes the motion of such a particle in the nonr

relativistic approximation. Comparing (11a) with the relativistic
equation (37e) in Chap. 5 we note that (Ila) involves only the^trof
derivative with respect to time. Also* the velocity of light does not
appear in Eq. (11a) which is in accordance with the non-relativistic
nature of the Schrodinger theory.
12 Consider the plane wave solution (lOd) of the Schrodinger

equation (11a). The phase velocity v/ of this wave is
<o p p2 P
where « — k (12a)
k ~ 2m 2mH *
The phase velocity Vf of the de Broglie wave given (in the non-
relativistie approximation) in (10c) is, on the other hand,
me2 P (12b)
V 2m
The reader may be bothered by the fact that the two phase
velocities v/ and v-f are not equal, although the two kinds of waves
^ and are supposed to describe exactly the same physical situ¬
ation. However, there is no cause for alarm: the phase velocity is
not the same thing as the velocity of the particle, and it does not
correspond to anything directly observable. The group velocity o,
on the other hand, is given by
1 _ dk __ m
(12c)
v do* p
for the Schrodinger wave, and this velocity Ls indeed equal to the
velocity of the particle as it should be. We have already shown,
in Chap. 5, that the group velocity of a de Broglie wave is also
equal to the velocity of the particle, and the two kinds of waves
therefore do propagate with the same group velocities.
13 Let us now try to go one step further and consider the motion
of the particle in an external field of force derivable from a poten¬
tial. We shall denote the potential energy of the particle by V(x):
the potential is a function of position but not of time.
The reader may have some doubts about the idea of introducing
a potential in quantum mechanics to describe the forces acting on
a particle. The forces on a particle are, of course, due to the pres¬
ence of other particles, and consistency requires that these other
particles should also be described quantum mechanically. AH the
particles in a given physical situation should be described as waves,
and a fundamental theory of particle interactions must therefore
Sec. 7.14 The Wave Mechanics of Schrodinger 275
be a theory describing the interactions between the de Broglie

waves of the particles. Quantum field theory is a theory in which
such a fundamental description is attempted. According to this
theory the de Broglie wave describing an electron interacts with
the quantized electromagnetic field, and this field may in turn inter¬
act with the de Broglie wave describing a proton. The electro¬
magnetic interaction between an electron and a proton thus arises
indirectly; it is mediated by the quantized electromagnetic field
We express this by saying that the interaction arises through an
exchange of phoUms. (This is a nice figure of speech.)
In this chapter we are, however, working within the framework
of the approximations characteristic of the Schrodinger theory: we
are not working with a fundamental but with a phenomenological
theory. We are only interested in the motion of a single particle,
and it is then reasonable to try to represent the effect of all the
other particles by an effective potential V(x), and it is furthermore
reasonable to be guided by the classical analog in the selection of
this potential.
The justification for the introduction of a potential function is
particularly transparent if we consider the motion of a charged
particle in a macroscopic electric field, defined by a number of con¬
ductors connected to batteries. In this case we know that we can
describe the motion of an electron to a high accuracy within clas¬
sical theory, and the nature of the trajectories is determined by the
electrostatic potential defined by the system of conductors. In the
language of quantum field theoiy tire electron exchanges photons
with all the charged particles in the conductors. It should be in-
tuitively obvious, however, that the net effect of all these “photon
exchanges” can he described in terms of an electrostatic potential
which the electron “sees” in space.
14 The idea of introducing an effective potential function in the

Schrodinger theory is in many respects quite analogous to the
introduction of a refractive index in classical optics. We know
very well that on the microscopic scale glass is not a homogeneous
substance, but is made up of atoms. If we wish to describe the
propagation of a light wave (a photon) through the glass in & funda¬
mental way we would have to consider the interaction of the light
wave with all the individual atoms in the chunk of glass. If, on
the other hand, we are contented with a phenomenological de¬
scription of how the light propagates through the chunk of glass
(which may be a component of an optical system) then we may
describe the effect of all the elementary interactions by an effective
refractive index. As we have said there is a certain analogy be¬
tween this refractive index and the potential in the Schrodinger
276 The Wave Mechanics of Schrodinger Sec. 7J5
Fig., ISA We "derive" the Schrddinger equation by E

first finding the equations which a wave might reason
ably obey in the regions I, U and III within which the
potential is constant. We easily see that the equa¬
tions (16c), (16e) and (16f) must hold, and then,
hocus-pocus, we combine these into the single equa¬
tion (17a) which is the Schrodinger equation.
In the figure the potential is represented by the solid
line. The energy E is assumed larger than the poten¬
tial in the three regions. The magnitude of the energy
is represented by the heavy dashed line, which thus
lies above the potential energy curve. theory, and it wiB aid our understanding of the Schrodinger theory
if we keep this analogy in mind. We should also remember that
the description of the electromagnetic properties of a solid through
a refractive index has its limitations. Similarly there are physical
situations in which the interactions between elementary particles
cannot be described at all by a potential function: the potential
function makes sense only in those physical situations in which the
two basic premises of the Schrodinger theory hold true.
15 Consider now a situation in which there is a bounded region

in space* region I, in which the potential energy of the particle
is Vi. Let there be another bounded region, region II* in which
the potential energy is Vn. Let us furthermore assume that at the
boundaries of these regions the potential falls rapidly to zero* We
designate the outside as the region III, and we thus assume that
Vm — 0. The situation is shown schematically in Fig. 15A, where
the heavy solid line represents the potential as a function of posi¬
tion.
Suppose now that a particle of total non^relativistic energy E
moves around in this potential field of force. Since our discussion
is non-rektivistie E stands for the sum of the kinetic and potential
energies of the particle; the rest energy me2 is not now included.
According to classical mechanics the kinetic energy of the particle
is then E in region III, (£ — Vi) in region I and (£ — Vn) in
region II, The kinetic energy, is related to the momentum p
of the particle through
=£ (13a)
The total energy is indicated by the dashed line in Fig* 15A* We

assume for the moment that the total energy is everywhere larger
than the potential energy.
16 Let us now consider the behavior of a Schrddinger wave asso¬

ciated with the particle. The frequency w of the wave is related
to the energy E through E = fito, and the wave function therefore
depends on the time t through the factor exp ( — itE/fi) only* It

follows that a Schrodinger wave associated with a particle moving
with a definite energy E satisfies the equation
« ^f) = E$(x>t) (16a)

or
The spatial dependence of the wave is determined by the mo¬

mentum of the particle: the momentum p and the wavelength X
being related through the de Broglie equation X — h/p, Consider
a wave of energy E in the region IIL We imagine that we resolve
this wave into a superposition of plane waves. The spatial de¬
pendence of these plane waves will be given by the exponential
factor exp (ix * p/-K) where the magnitude of p is given by
p*
E = (16b)
2m
It follows that each one of these plane waves satisfies the dif¬
ferential equation
V2 x[s(x,t) = (16c)
2m
Therefore, the Schrodinger wave corresponding to a particle of
energy E must satisfy the differential equation (16c) throughout
the region IIL
Consider now the wave in the region I. If we resolve the wave
in this region into plane waves of the form exp (ix * p/K) the mag¬
nitude of the momentum p will now be determined, in accordance
with (15a), by
Pi = Eton = E — VI
2m
(16d)
and we conclude that the Schrodinger wave in the region I must

satisfy the equation
- = (E- Vi) t(x,t) (16e)
Similarly we conclude that the Schrodinger wave function in the

region II must satisfy the differential equation
-~v
Zm
2 = {E~ Vn) #£,#) (iff)
17 Our reasoning, leading to the three equations (16c), (16e) and

(16f), satisfied by the wave function in the regions I, II and III, is
certainly plausible, and it is very tempting to summarize these
278 The Wave Mechanics of Schrodinger Sec, 7.17
three equations into the single equation
_ J!. = [E - V(x)l *(x,t) (17a)

2m
where V(x) is the potential function which assumes the values V/,
V// and Vr/i — 0 in the three regions. It should l>c noted, however,
that we presented no arguments for what the “correct” differential
equation should be in the boundary-regions in which the potential
changes rapidly, and it is therefore not self-evident that the equation
(17a) must hold everywhere. In fact the author now wants to eon-
fess that he arranged the arguments leading to our equations, and
drew the picture in Fig* 15A in a manner deliberately designed to
lead the reader to believe that die equation (16e), for instance*
must be true* There is actually a flaw in our argument* As long
as the region II is very large compared to the wavelength of die
de Broglie wave in this region we can safely accept our conclusion
(I6e) as extremely plausible. The heal behavior of the wave in the
region should not depend on the potential elsewhere, and the rela¬
tion between wavelength and kinetic energy must then be in ac¬
cordance with our assumption. The situation is different, however,
if the region II is small compared to the wavelength, i,e., if the
potential V(x) varies considerably over a wavelength* In this case
it is not so clear what the spatial dependence of the wave function
should be, because the “wavelength” at the point x, as defined
through the de Broglie relation in terms of the kinetic energy
[E — V(ac)]s is a function of position.
It is therefore not self-evident that the equation (17a) is the
correct equation everywhere in space, and for every potential
function V(x)* Nevertheless we shall assume, following Schrti-
dinger, that the equation (17a) is correct* As an equation describ¬
ing the behavior of the Schrodinger waves it is at least a reasonable
equation, and we should give it a fair trial* We wanted to make it
clear, however, that our discussion is not a proof of the correctness
of equation (I7a) but rather a plausibility argument in its favor.
Actually one can do a bit better. One possible approach is to start
from quantum electrodynamics, in which case one can show that
the equation (17a), as applied to non-relativistic problems involving
atoms and molecules, arises as an approximation to the field theoiy
formulation. Another approach is to study systematically what the
possible wave equations are which allow a sensible physical inter¬
pretation, including the probability interpretation discussed in Sec.
8* We wish to preserve this interpretation of the wave function in
the case when the particle is subject to forces. One may then show
that the equation (17a) is, in a certain sense, the simplest wave
equation for the quantum-mechanical problem which "corres-

ponds” to the classical problem of a particle moving in the potential
field of force V(x), It would take us too far to examine these
arguments in detail, and we must therefore accept the equation
(17a) as a working hypothesis on the basis of the arguments which
we have presented.
18 The equation (17a) refers to a wave of definite energy E. For

such a wave the relation (16a) holds, and we may therefore rewrite
(17a) in the form
~ 2^ + ^ ^ ^ (18a)
In this equation E no longer occurs, and (18a) therefore holds for

every E, and hence for every Schrodinger wave.
The equations (17a) and (18a) are the celebrated Schrodinger
equations. The equation (18a) is known as the time-dependent
Schrodinger equation> whereas (17a) is known as the time4ndepen-
dent Schrodinger equation. We should keep in mind that (18a) is
the equation holding for all Schrodinger waves, whereas (17a) (for
a given value of E) holds only for Schrodinger waves describing a
particle of total energy E.
The l>e$t possible justification for the equations (17a) and (18a)
comes, of course, from a comparison of predictions based on these
equations with experimental facts. Within a short time after
Schrodinger7 s great discovery the equation was applied to many
problems within atomic and molecular physics with spectacular
success, and these branches of physics took a great leap forward.
In this development Schrodinger himself played an active role, and
in the next chapter we shall see how he was able to account for
the quasi-stable states of atoms* We have every reason to admire
Schrodinger's insight in writing down just the equation (18a) which
has turned out to be the correct one for the situations for which it
was intended.
It is not our intention to discuss the general theory of the solution
of Eq. (18a) in this course: that must be reserved for more advanced
courses. We merely wish to consider a few very simple applica¬
tions of the Schrodinger theory to see how it works out.
Some Simple “Barrier Problems ”
19 We have assumed that the Schrodinger equations (17a) and

(18a) are valid for an arbitrary potential function V(x). In our
“derivation” of Eq, (17a) we considered* however, only the case

when the potential V(x) is everywhere smaller than the total energy
E. Let us now see what happens in the case when there are regions
in space in which the potential is larger than E. According to
classical mechanics these regions are not accessible to the particle,
but we will see that the situation is different in quantum mechanics.
For simplicity we shall restrict our discussion to a one-dimen¬
sional world: the particle can move along a line, and its position is
given by the coordinate x. The one-dimensional model has the
great advantage that the time-independent Schrodinger equation
is an ordinary differential equation instead of a partial differential
equation, and the mathematical discussion is therefore an order of
magnitude simpler. The essential features are* however, already
present in this simple model.
20 We consider the Schrodinger equation for the case when the

energy of the particle is E > 0, and the one-dimensional analog of
Eq. (17a) then reads
~ Mx,t) = [E~ V{x}] ^ (20a)
The time-dependence of the wave function is given by the

factor exp (— itE/fi)y and if we like we may write
= <*>(*) exp (- (20b)
in which case the time-independent factor <p(x) satisfies the same

equation (20a)* namely
Total energy V(x) - = [E- V(x)J ?(x) (20c)

E
which is an ordinary differential equation. If we can solve this

Classically I Classically
equation for tp(jc) we obtain the Schr&dinger wave function
allowed ] forbidden from (20b),
region ■ region
Turning
21 Consider now the situation shown in Fig, 21 A, The dashed
point line indicates the total energy E, whereas the solid line represents
the potential function V(a;). We assume that as we go to the left in
Fig, 21A To illustrate discussion in Sec. 2L The the figure the potential tends to the constant value zero, whereas as
solid line represents the potential, and the heavy we go to the right it tends to the constant value Vq ]> Er The point
dashed line indicates the magnitude of the total erv r0, where the kinetic energy has the value zero, is known as the
ergy E. The point x0 at which the potential equals E
turning point According to classical mechanics a particle incident
is the classical turning point. According to quantum
mechanics there is a finite probability that the particle from the left would stop and turn around at this point. The region
will be found in the classically forbidden region. to the right of #q is inaccessible to the classical particle.
Sec, 7,22 The Wave Mechanics of Schrodinger 281
We should now solve the equation (20c) for the potential shown
in Fig* 21A* The solution <p(x) is some function of x which is con¬
tinuous and has a continuous first derivative* Without really solving
the equation explicitly we may guess that the wave function <p(x)
will not vanish to the right of x&, which, according to our probability
interpretation of the wave function, means that there is a certain
non-vanishing probability that we will find the particle to the right
of xq. Quantum mechanics therefore predicts that a particle can
penetrate into a region forbidden to it according to classical
mechanics*
22 Let us try to study this phenomenon more explicitly. For this

purpose we simplify our problem further and replace the smoothly
rising potential in Fig* 21A by the step potential in Fig* 22A* For
convenience we also select the turning point xq as the origin, *o = 0,
on the x-axis* We thus have
V{x) = 0 for x < 0 V(x) = V0>E for x > 0 (22a) V,o

Total energy V(z)
The potential shown in Fig* 22A can be regarded as a limiting
■E
case of potentials of the kind shown in Fig. 21A* The potential
rises more and more steeply until we reach the idealized situation
shown in Fig* 22A. As long as the potential is a continuous func¬ Classically Classically
tion the wave function will be continuous and have a continuous allowed forbidden
first derivative, and this property is also preserved in the limiting region x0 - 0 re®on
case of a step potential* In this latter case, however, the second Turning
derivative of the wave function will, in general, exhibit a “jump*” point
These statements, it should be noted, are mathematical statements
about the differential equations which arise in the Schrodinger Fig* 22A To simplify the mathematical discussion
theory* As physicists we should always regard the step potential as the continuously varying potential in Fig. 21A is re¬
placed by a step-potential, as shown above.
an idealization of the actual potential, and then there will never be
any doubt that the physical wave function must satisfy the contin¬
uity properties mentioned.
23 Let us consider the wave equation in the region x > 0* In

this region it assumes the form
- ££?« = <E - V»M*) W

and we can immediately find two linearly independent solutions,
namely
exp ( — xq), exp (-\-xq}7 where q = (23b)

The solution exp (+xt/) increases exponentially as x increases,

and so does its absolute square. According to our probability inter¬
pretation of the wave function this means that the probability den¬
sity for finding the particle increases without limit as x increases.
A solution of this nature is not physically acceptable. We here
encounter another example of the boundary conditions which
physically meaningful solutions of a wave equation must satisfy:
a solution which increases indefinitely as we go to infinity must be
ruled out on physical grounds. This leaves us with the solution
exp (—£<?) as the only possibility, and if we denote the wave func¬
tion in the region x > 0 by <Pr{x) we have
<Pr(x) = exp (-xq) (23c)
24 We next consider the region x < 0. In this region the Schro-

dinger equation assumes the form
(24a)
and two linearly independent solutions of this equation are

1mE
exp (kfc), exp (—ixk}, where k = (24b)
These solutions are oscillatory solutions: they do not increase

indefinitely as x tends to — oo. Both solutions are physically ac¬
ceptable,! and if we denote the wave function in the region x < 0
by we conclude that this wave function must be of the foim
= A exp (ixk) -f B exp (—ixk) (24c)
where A and B are constants.

How do we determine the constants A and B? We have said that
the wave function must be continuous and have a continuous
first derivative. This means that the functions and <piix)
must match at the origin in such a way that
VirfO) = 9l(0), <,4(0) = <pL(0) (24d)

since they both represent the same wave function but in two differ¬
ent regions which meet at the turning point xq = 0. The two con¬
ditions (24d) give us two equations, namely
A + B = 1, ik(A — B) = -q (24e)
f If the reader is bothered by this statement, see Sec. 51 of this chapter.

Sec. 7,25 The Wave Mechanics of Schrodinger 283
and these two equations determine the constants A and B. The

solution is simply
A _ (1 + *?A) B _ (1 - *Q/k)
25 To interpret our solution it is convenient to multiply our wave

function (everywhere) by the constant 1/A: this we can do since
the Schrodinger equation is a linear equation. We may then write
our solution explicitly in the form:
1 -iyWo/E - 1
for x < 0 (25a)
1 +iy/%f&= T_
and
2e~w
for x > 0 (25b)
l + WVo/E-T
where
2mE _ /2m(Vo - E)
& ’ q ~y W (25c)
Consider now the wave function in the region x < 0, as given by

(25a), It is a superposition of two waves. The first term, exp (ixfc),
represents a wave traveling to the right. The second term, pro¬
portional to exp( — irfc), represents a wave traveling to the left.
Hie coefficient standing in front of exp (— ixk) in the second term
is of modulus unity:
1-WVo/E-l
l + WVo/E - 1
and the two waves therefore have amplitudes of the same magni¬
tude, The absolute square of the amplitude of a wave must some¬
how be proportional to the “flux” of the particle, and we can con¬
clude that the wave function in (25a) describes the situation in
which a particle incident from the left is reflected back to the left
by the potential “hill,” This interpretation is in accordance with
our classical picture of what goes on.
The wave function in the region x > 0, as given by (25b), de¬
scribes the penetration of the Schrodinger wave into the region
forbidden to the classical particle. The amplitude of the penetrat¬
ing wave decreases exponentially as we go further into the forbidden
region, and at large distances from the barrier the amplitude is for
Fig, 25A The upper part of the figure shows the

potential V{x). The total energy E is indicated by the
heavy dashed line. The lower part of the figure shows
the absolute square of the wave function <p00> As we
see the wave penetrates into the classically forbidden
region. To the left of the barrier we have a standing
wave pattern, which arises because the reflected wave
interferes with the incident wave. Note that the wave
function and its derivative are continuous at the turn¬
ing point.
all practical purposes zero, in accordance with the classical picture.

These features are illustrated in Fig, 25A,
26 It is interesting to consider the limiting case when the height

of the potential barrier tends to infinity, i.e., when Vo —> +00.
(The energy E is kept constant) By inspection of (25c) we see that
as Vo tends to infinity, q will also tend to infinity, which means that
the rate of decrease of the wave function with the distance (from
ihe classical turning point) tends to infinity. The wave function
penetrates less and less into the forbidden region. By inspection
of (25b) we see that the amplitude of the penetrating wave tends
to zero as Vq tends to infinity. In the limiting case of an infinitely
high potential “hill” we thus obtain:
<p(:c) = eixk — e~ixk for x < 0 (28a)
<p(x) — 0 for x > 0 (26b)
Our conclusion is that if the potential barrier is infinitely high,

then the wave function must vanish at the barrier, i.e,, for x = 0,
and to the right of the barrier, i.e., for x > 0.
Fig, 26A shows the behavior of the absolute square of the wave
function, i,e,, the probability density for the particle. Note that
the probability density shows an oscillatory behavior to the left of
the barrier. This is a quantum-mechanical interference effect
which has no counterpart in classical mechanics. The same feature
can, of course, also be seen in Fig. 25A.
27 We have considered the case of the step potential in such

detail in order to give the reader confidence that the Schrodinger
equation can be solved, and that the solutions can be interpreted
physically. Given any reasonably continuous, or stepwise con¬
tinuous, potential, we can be confident that the solution exists. To
+ Fig. 26A This figure illustrates the limiting case of

an infinitely high potential step. (Compare with Fig.
25A.) The upper part of the figure shows the poten¬
tial, The heavy dashed line indicates the total energy
E. The lower part shows the absolute square of the
wave function <p(x). The wave function, but not its
derivative, vanishes at the turning point. The deriva¬
tive of the square of the wave function will, of course,
vanish at this point.
find it explicitly is, however, often not an easy matter, but the
complications are only of a technicahmathematical nature. Even
without knowing the precise explicit solution we can often say
quite a lot about the nature of the solution, and hence make general
statements about the behavior of the physical system. On the basis
of our studies so far we can conclude that it is a general feature of
quantum mechanics that the Schrodinger wave can penetrate into
regions forbidden to the particle within classical mechanics,
28 To increase the reader’s understanding of the Schrodinger

equation, let us consider the following. Figure 28A shows a “poten¬
tial step.” We want to study the motion of a particle of energy
E > Vo in this potential, (The detailed study is left to the reader
as an exercise: Frob, 1 at the end of this chapter.)
The reader will note that we can find two physically acceptable
solutions of the wave equation (20c) in the region to the left of the
step, and we can also find two physically acceptable solutions in
the region to the right of the step. How do we know which ones
to pick? That depends on the physical situation which we wish
to study. Suppose that we want to consider the case when a par¬ E
ticle is incident on the step from the left. The wave will perhaps
be partially reflected at the step, but part of the wave will continue -yo
to travel to the right past the step. This means that the correct
-- 0
wave function for this problem must be such that it represents a
particle traveling to the right in the region to the right of the step:
it must be of the form exp (ixk') for x > 0, In the region to the Fig, 28A To illustrate discussion in Sec. 28. The
left of the step the wave function can be of the form [A exp (ixk) energy E of the particle is here larger than the height
of the potential barrier. According to classical theory
+ B exp (— ixfe)], where the first term describes a wave traveling
a particle would not be reflected by this barrier, but
to the right, and the second term describes a wave traveling to the according to quantum mechanics the incident wave
left. This second term describes the reflected wave, whereas the will be partly transmitted and partly reflected.
286 The Wave Mechanics of Schrodinger Sec 7,29
*
first term describes the incident wave* How do we find A and B?

A and B are determined by the two conditions that the wave func¬
tion and its first derivative must be continuous everywhere and
in particular at the step. This gives us two equations for the two
unknowns A and B, and after we have found these amplitudes we
can also find the intensities of the incident, reflected, and trans¬
mitted waves, and hence the reflection coefficient of this kind of
'‘barrier.”
Suppose that we want to consider instead what happens when
the particle is incident from the right. In this case we know that
the wave function to the left of the barrier must be of the form
exp (— ixk), because to the left of the barrier we only have a wave
traveling to the left. To the right of the barrier the wave function
is of the form [A' exp {•ixkf) +- Bf exp ( — tofc')]. We again find A*
and R' by imposing the conditions that the wave function and its
first derivative must be continuous at the step. The choice of wave
function thus depends on the particular physical problem which
we want to consider,
The lesson to be learned from a consideration of the behavior
of a particle moving in a potential of the kind shown in Fig, 28A
is that in general the particle will be partly reflected by any dis¬
continuity in the potential, and it will be partly able to penetrate
past the region of the discontinuity*
29 Let us next consider the situation shown in Fig. 29A in which

the potential is discontinuous at the two points x = 0, and x = a*
In view of what we learned in the preceding section, a wave will
be partly reflected and partly transmitted at both discontinuities.
Suppose we want to consider the case when the particle is inci¬
dent on this barrier from the left. The reader might feel that this
is a difficult problem which should be solved as follows. We con¬
sider a wave incident from the left, and we find the part of this
E wave which is reflected, and the part of this wave which is trans¬
mitted, at the first discontinuity at x = 0. The transmitted wave
-V0
hits the second discontinuity, at x = a, and is partly reflected and
partly transmitted. The reflected part returns to the discontinuity
at x = 0, and is again partly reflected and partly transmitted To
find the wave which is emerging toward the right from the barrier
Fig, 29A To illustrate discussion in Sec. 29. This we thus have to consider an infinite number of reflections back and
problem could be solved by taking into account all the forth between the two discontinuities, and then add the amplitudes
repeated partial reflections and transmissions at the of all the partial waves which are transmitted to the right of the
discontinuities at x = 0 and x = a. It is, however,
point x = a. Can we really solve this problem? The answer is that
much easier to find the globa/ solution of the Schro-
dinger equation directly: all the multiple reflections
the problem can indeed be solved in this manner, but there is a
are then taken into account in one sweep. much easier way of finding the answer* All we have to do is to
fmd that solution of the Schrodinger equation (20c) which is con*

tinuous everywhere, and has a continuous derivative everywhere,
and which is of the form exp (ixfc) for x > a. The last condition
means that the part of the incident wave which is able to pene¬
trate the barrier must travel to the right in the region x > a:
this corresponds to the physical situation which we wanted to
consider.
For x > a the wave function is thus of the form exp (tefc). For
a > x > 0 the wave function is of the form [A exp (irifc') + B exp
(— txfc')], and to find A and B we impose the conditions that the wave
function and its first derivative must be continuous at x = a. In
the region 0 > x the wave function is of the form [A' exp (ixfr)
-(- Bf exp (— ixfc)], and we can then determine A' and Bf by im¬
posing the conditions that the wave function and its first derivatives
must be continuous at x = 0* In this manner we find the global
solution of the Schrodinger equation (20c) which corresponds to V(x)
the physical problem which we wish to study, and this solution is
unique (except for an overall constant factor). With a finite effort
we can clearly solve this problem*
30 The important thing to understand is that to solve a barrier

problem of this kind all we have to do is to find the solution of the
Schrodinger equation (20c) which is valid everywhere, and which
is subject to boundary conditions determined by the physical prob¬
Fig. 30A The particle (wave) is reflected by this
lem under study, i.e,, conditions such as the condition that the barrier because the energy £ is less than the limiting
wave must be of the form exp (ixfc) to the right of the barrier. This value of the potential at right. (The total energy is
procedure automatically takes into account all the "multiple re¬ indicated by the dashed line, and the potential by the
flections” which we are led to think about on the basis of our phys¬ solid line.) Where does the reflection take place?
The answer is that it takes place throughout the region
ical intuition. It is not wrong to try to solve the problem by
in which the potential is changing.
considering the multiple reflections, but it is much easier to find
the global solution of the Schrodinger equation directly.
Consider the potential barrier shown in Fig. 30A. Where does
the reflection of the particle take place? The answer is that it
“takes place” throughout the entire region in which the potential £
is changing. If we like we can approximate the continuously vary-
ing potential function V(x) by a function which increases by a large
number of very small steps, as shown in Fig. 30B. At each step
a wave is partly transmitted and partly reflected, and we can again
regard our problem as a "multiple reflection problem.” The
Schrodinger equation (20c) describes concisely all these multiple
reflections, and if we like we can interpret the equation in this Fig. 30B The potential shown in Fig. 30A is approxi¬
mated by a potential which changes stepwise. At
manner. If we find the global solution of Eq, (20c) we have in
each discontinuity a wave is partly reflected and partly
effect taken into account all these infinite local reflections and transmitted. The solution of the Schrodinger equa¬
transmissions in one sweep. tion takes into account all the "multiple reflections."
Potential 31 Let us now consider another problem which readily suggests

harrier itself. What happens if the potential is of the form shown in Fig.
---
31 A, when the height Vo of the barrier is greater than E?
Total energy It is easy to guess the answer: a wave incident from the left will
be partially reflected by the barrier, and will be partially able to
penetrate the barrier into the region IIL Classically a particle
Region I III I III originally in region I would be reflected at the point x — 0, and it
x —0 x — a could not penetrate into the regions II and IIL That a particle
can “leak through"’ a potential barrier which is absolutely opaque
Fig. 31A The solid line represents the potential, classically is one of the striking features of quantum mechanics.
and the heavy dashed line indicates the total energy. The phenomenon is known as the tunnel effect
According to classical theory a particle incident from
To solve the Schrodinger equation for the situation shown in
the left cannot pass through this barrier. According
to quantum mechanics there is a finite probability that Fig, 31A we could proceed just as we explained in Secs, 28-30,
the particle "leaks through." This phenomenon is We find the general solution in each one of the three regions I, II
known as the tonne/ effect. and III, and we then impose the condition that the wave function,
as well as its first derivative, shall be continuous everywhere, and
in particular at the two turning points x = 0 and x = a* The bar¬
rier problem of Fig, 31A is therefore not difficult in principle, but
to find the detailed solution is somewhat laborious. Fortunately
we can understand the essential features of this problem without
actually solving the Schrodinger equation completely, and we can
therefore leave the detailed solution for a later course, (Or as a
homework problem: See Frob. 2.)
32 Let us consider the solution in the following particular case:

a particle is incident from the left. It is partially reflected by the
barrier, and it is partially able to penetrate. This means that we
are interested in a solution of the Schrodinger equation for which
the wave function is of the form exp (ixk) in the region III, which
represents a particle propagating to the right in this region. In the
region I we will necessarily have two waves: one propagating to
the left and one to the right. The first of these represents the re¬
flected wave and the second the incident wave. In the region I
the wave function is therefore of the form
<p(x) = eixh + Ae-*»*, (32a)

where h=
and where A is a constant which describes the amplitude of the

reflected wave. Its absolute value will be less than 1 since part
of the incident wave penetrates the barrier.
Inside the barrier the wave function will be essentially an ex¬
ponential function of the form
2m(V0 - E)
<p(x) = B exp (-xq), q =
V- (32b)
Set?. 7.33 The Wave Mechanics of Schrodinger 289
where B is a constant. The above wave function is only approxi¬

mate, but the approximation is good if the potential barrier is not
too low.
Let us suppose that aq is large compared to unity. In that case
the ratio <p(a)/<p(0) = exp (— aq) for the wave function given by
(32b) is a small number. If we recall how we matched the two
solutions at the turning point in the discussion in Sec. 24, we may
conclude that the absolute value of the ratio of the amplitude of
the wave in the region III to the amplitude of the wave traveling
to the right in region 1 must be roughly given by the ratio
<p(a)/<p(0) ^ exp ( —aq). It is certainly true that the ratio in ques¬
tion is not simply the exponential factor, but, what is most impor¬
tant, this factor completely dominates the situation when aq is
large compared to unity, i,e„ when the barrier is high and thick.
33 We have assumed that the incident wave is of unit amplitude.

The amplitude of the wave penetrating into region III is smaller.
Its magnitude, or more correctly its order of magnitude, is approxi¬
mately equal to exp (—aq), The (absolute) square T of this ampli¬
tude has a simple physical interpretation. It is equal to the
probability that a particle hitting the barrier passes through the
barrier. This probability is thus given by
T = | tp(a) |2 — exp (—2aq) (33a)

or, in view of the second expression (32b),
2m(V0 - E)
2a
exp
Y &
(33b)
The quantity T is known as the transmission coefficient of the

barrier. Our approximate derivation of the expression (33b) for
this quantity is, as we see, based on the very simple fact that the
amplitude of the wave decreases roughly exponentially as we go
to the right inside the barrier. We are primarily interested in the
case when aq is large, which means that T is very small. We could
of course, derive an exact expression for T, in which case an addi¬
tional factor would appear in the expression (33b). The exponen¬
tial factor given above is, however, the crucial factor, and the
approximate expression (33b) is completely adequate for our
purposes.
Figure 33A shows the barrier effect schematically. The upper
portion of the figure represents the potential, whereas the lower
portion shows the absolute square of the wave function. The trans¬
mitted wave is a single complex wave traveling to the right. It is
therefore of constant modulus as shown in the figure.
Fig. 33A Schematic illustration of the tunnel effect.

The upper portion of the figure shows the potential
(with the total energy indicated by the dashed line).
The lower portion shows the absolute square of the
wave function. Note the transmitted wave and note
the exponential decrease of the wave function inside
the barrier. To the left of the barrier we have an im¬
perfect standing wave pattern. The amplitude of the
reflected wave is smaller than the amplitude of the
incident wave, and the combined amplitude is there¬
fore nowhere zero.
34 Before we consider a physical application of our theory of the

quantum-mechanical tunnel effect we wish to point out an analogy
to this effect in classical electromagnetic theory. This has to do
Optically with the reflection of a plane electromagnetic wave at the plane
rare ipedium interface of two regions of different refractive indices.
Suppose a plane wave traveling in some medium (represented by
the shaded regions in Fig. 34A) is incident on a plane boundary
between an optically rare medium and an optically dense medium.
(The refractive index is larger in the dense medium than in the
rare medium.) Suppose further that the angle of incidence is larger
Fig. 34A Total reflection of a plane electromagnetic than the angle of total reflection, and that the rare medium extends
wave at the plane interface of two media of different
to infinity to the left of the boundary. The wave will then be
refractive indices. The dashed line shows the reflec¬
tion of a ray. totally reflected. This is indicated schematically in Fig. 34A, in
which the dotted line represents a “ray,” i.e., a normal to the local
Optically wave front, Whereas it is true that the wave cannot propagate
in the rare medium, the electric field in the neighborhood of the
interface is not zero: the field penetrates into the rare medium.
As we go further to the left from the interface the electric field
amplitude decreases exponentially* This situation is entirely anal¬
ogous to the quantum-mechanical problem considered in Sees*
22-25*
Consider now the situation shown in Fig* 34B, in which the rare
medium is merely a thin slab- In this case the wave incident on
the boundary from the right is partially reflected Part of the wave
will however be able to penetrate through the “forbidden region”
and this part will then propagate in the dense medium to the left.
Fig. 34B Frustrated transmission. Classical elec¬ This situation is analogous to the quantum-mechanical barrier
tromagnetic theory predicts that a wave incident on penetration. Note that we have not drawn the “ray” in the for¬
a thin slab at an angle larger than the critical angle bidden region, and the reason for this is that “ray-optics” is not
of total reflection will be partly transmitted and partly
applicable in this region: the wave vector is a complex vector.
reflected. This phenomenon is analogous to the
quantum-mechanical tunnel effect, A transmitted The phenomena just described can be completely accounted for
and a reflected ray are indicated by the dashed lines. by classical electromagnetic theory. The transmission coefficient
Sec * 7.35 The Wave Mechanics of Schrodinger 291
for the situation shown in Fig. 34B is very small whenever the
thickness of the slab of the optically rare material is large compared
to the wavelength of the incident radiation. As the thickness de¬
creases the transmission coefficient increases, and it reaches the
value one when the thickness is zero.
35 Let us now generalize our discussion of the quantum-mechan¬

ical tunnel effect. Instead of the rectangular potential barrier
shown in Fig. 31A we consider a barrier of arbitrary shape, as shown
in Fig. 35A. Suppose a wave of energy E is incident from the left.
This wave will be partially reflected and partially transmitted. We
are primarily interested in the overall transmission coefficient T for
the barrier, and to find this coefficient precisely we must solve the
Schrodinger equation for the potential V(x). We can, however,
obtain an approximate expression for Tby a different method, based
on our discussion in Secs. 32-33. This approximation is better the
smaller the wavelength is compared to the width of the barrier.
To derive an approximate expression for the transmission co¬
efficient T we imagine the region of the potential barrier divided
into several subregions, as indicated in Fig, 35B. In each one of
the subregions we replace the actual potential by a constant poten¬ E
tial, as shown in the figure. We have already found the transmis¬
sion coefficient for a rectangular barrier. Let the transmission 0
coefficients for the 5 rectangular barriers shown in Fig. 35B be
Ti, . . . , Tf>. The overall transmission coefficient T must then be Fig. 35A The solid line represents the potential
approximately equal to the product of the transmission coefficients and the heavy dashed line indicates the total energy E.
How can we derive an expression for the transmission
of the subregions, and we have
coefficient of this barrier?
Tss T&TzTtTs (35a)
or
in T == /n 1 + in Tg -h in H- in -f- in T5 (35b)
36 Consider now Eq. (33b), If dxn denotes the thickness of one

of the rectangular barriers, and if V(^) is the height of the barrier,
then the transmission coefficient Tn of this barrier is given by
Fig. 35B To illustrate our derivation of an approxi¬

2 m[V(xn)
\A (36a) mate expression for the transmission coefficient for
the barrier shown in Fig. 35A. We imagine the con¬
tinuously varying potential approximated by a set of
The logarithm of the overall transmission coefficient is obtained, rectangular barriers. The overall transmission co¬
efficient is the product of the transmission coefficients
according to (35b), by summing over all the subregions, and if we
for all the rectangular barriers. Note that this method
now go to the limit of an infinitely fine subdivision wc can replace is only approximately correct: multiple reflections have
the sum by an integral, and we finally obtain not been taken into account.
292 The Wave Mechanics of Schrddinger Sec. 7.37
hrs.2j[^v@MEI (36b)
We remind the reader that this formula is an approximate ex¬

pression for the transmission coefficient* It is, however, a highly
useful formula as it gives us a good qualitative picture of the barrier
penetration phenomenon* Note that the integral is evaluated be-
tween the two classical turning points x! and xff<
The dependence of the transmission coefficient on the parameters
occurring in the expression (36b) should be carefully noted* Other
parameters remaining fixed, the transmission coefficient decreases
as the mass of the particle increases. Similarly the transmission
coefficient increases as the total energy E increases, and for two
reasons* The integrand, which is always positive, becomes smaller,
and furthermore the range of integration becomes smaller as the
turning points move toward each other. The transmission co¬
efficient naturally increases as the width of the barrier decreases*
Theory of Alpha-Radioactivity
37 Let us now try to apply our theory of barrier penetration to

an actual physical situation.
In Frob. 3 at the end of Chap* 2 we noted that the half-life of
the alpha-particle-emitting radium nucleus 88Ra226 must be re¬
garded as being “unnaturally long/* The half-life is 1622 years,
and this seems very long indeed on any sensible nuclear time scale.
As a characteristic time for nuclear processes we might select the
time it takes for light to pass through a nucleus, and this time is
of the order of XO’-23 seconds* The half-life of radium, is, however,
5 X 1010 seconds, or something like 1033 “natural nuclear time
units,” We are thus faced with the problem of explaining the
enormous number 1033* Admittedly the “natural nuclear time
unit” is a somewhat loose concept, but our problem would not be
any simpler even if we made the nuclear time unit 1000 times
larger*
There is a further experimental fact which we must note: some
alpha-radioactive nuclei have very much shorter lifetimes. For
instance the alpha-active polonium isotope &4P0212 has a half-life
of only 3 X 10-7 sec. At the other extreme we note the uranium
isotope 92U238 which is also an alpha-emitter: its half-life is
4.5 X 109 years* The real problem is therefore the enormous range
encountered in the lifetimes of alpha-emitters.
The energies of the emitted alpha-particles typically lie in the
range 4-10 MeV. Each alpha-active isotope is in general char¬

acterized by a definite energy of the emitted alpha-particle, although
there are cases in which a nucleus can emit alpha-particles of several
different discrete energies* Let us forget about the latter com¬
plication, which we discussed briefly in Sec. 40, Chap. 3. Empir¬
ically it has been found that there is a strong correlation between
the lifetime of the nucleus and the energy of the emitted alpha-
particle: the larger the energy the shorter the lifetime.
38 Let us now see whether we can explain the observed facts, f

As long as the alpha-particle is inside the nucleus it is acted upon
by the strong nuclear forces. These forces, as we have explained,
have a short range, and we may imagine that they are inoperative
outside the nuclear surface, of radius R. Outside the nuclear sur¬
face the dominant force is the electrostatic repulsion between the Fig* 37A Early cloud chamber photograph showing
alpha-particle, which carries the charge +2ey and the daughter tracks of alpha-particles emitted by a radioactive sub¬
nucleus remaining after the decay. It carries the charge +Z'e stance. The photograph is taken from L. Meitner:
“Ober den Aufbau des Atominnern/' Die Naturwissen-
if Z' is the atomic number of the daughter. The original nucleus, schaften 15:1, 369 (1927).
the parent, carries the charge +Ze, where Z = (Z' + 2) is its An alpha-particle of a given energy has a quite well-
atomic number. We have shown the situation schematically in defined range in matter in bulk. The particle loses
Fig. 38A. The distance from the center of the nucleus increases energy by ionizing the atoms in the material. The
toward the right. The solid curve represents the potential energy track ends when it has lost all of the initial kinetic
energy. The range R in cm in air at standard pres¬
of the alpha-particle in the presence of the daughter nucleus. Out¬
sure and temperature is very roughly given by
side the nuclear surface, i.e., for r > B, this potential is simply the R = 0.32 x R3/2, where E is the energy in MeV.
Coulomb potential The radioactive source, located at the bottom of
the picture, emitted alpha-particles of two different
V(r) = , for r > R (38a) energies. We can clearly see the well-defined range
of the more energetic group. The slower particles
reach only about half the distance of the faster par¬
As we reach the nuclear surface the strongly attractive nuclear ticles. (Courtesy of Springer Verlag.)
force becomes operative, which means that the potential must dip
sharply. In Fig. 38A we have idealized the situation by assuming
that we actually have a step potential. We have not drawn the
potential curve inside the nucleus because it is not well known:
it is in fact not well defined since the alpha-particle may lose its
individuality as a particle in the strong nuclear force field.
The dashed line represents the total energy of the alpha-particle.
This energy, E, is also the energy with which the alpha-particle
finally emerges at large distances from the nucleus, where the
electrostatic potential energy is effectively zero.
f The justification for trying to find the explanation on the basis of the Schrodinger
theory is that the velocity of the alpha-particle outside the nuclear surface is "noil-
relativistic,” as the reader can estimate for himself. Remember that the energy of the
alpha-particle does not exceed 10 MeV,
Fig. 38A Schematic representation (by the solid

line) of the potential which an alpha-particle sees in
the vicinity of a nucleus. Outside the nucleus, i.e.,
beyond the distance it, the potential is the Coulomb
potential. Inside the nucleus the forces are strongly
attractive. The precise form of the potential is not
known, but the attractive force is represented by the
sudden drop in the potential at it. The dashed line
represents the total energy of the alpha-particle. Ac¬
cording to quantum mechanics the alpha particle can
penetrate the potential barrier. This takes place in
the alpha-decay of heavy nuclei.
39 We have drawn Fig. 38A in a manner which suggests that the

alpha-particle has to penetrate a potential barrier, in the region
from H to RCf before it can be emitted, Let us check immediately
whether this is the correct picture* If the picture is correct, then
tiie classical turning point Rc given by
2e2Z'
Rc (39a)
E
must satisfy the condition > Ji-

Inserting numerical values relevant for ggRa2^, for which Z =
88, 71 — 86 (the atomic number for the noble gas radon), E =
4.78 MeV, we obtain Rf. ^ 50 X 10-13 cm = 50 feririi. (To sim¬
plify the numerical work we may write ZL = (e2fmec2) x (2Z') X
(mec2/E) ^ (2*8 X 10-13 cm) X (172) X (0.5 MeV/4.78 MeV)
= 50 fermi, where m? is the electron maSsS.)
In Sec. 36, Chap. 2, we stated that the radius R of a nucleus of
mass number A is given by
R ^ roA1/3 - L2 X cm (39b)
and for ggRa226, for which A = 226, we thus obtain R = 7.3 fermi.
The picture is therefore qualitatively correct; the alpha-particle
indeed has to penetrate a potential barrier. Quantitatively the
picture is wrong: the barrier should have been drawn much thicker.
Our execution of the figure has been motivated by aesthetic con¬
siderations: the important features of the situation are nevertheless
reproduced qualitatively.
The inequality Rc R is true generally for the alpha-active
nuclei. These radioactive elements are all heavy elements with a

large atomic number Z. The isotope ggRa226 can be regarded as a
typical alpha-emitter. The potential barrier which the alpha-
particle has to penetrate is therefore an essential feature of the
alpha-decay process, and we may hope to understand the extra¬
ordinary variation of the lifetime as a function of the energy E in
terms of our simple theory of the tunnel effect.
40 Let us therefore compute the transmission coefficient T for the

potential barrier shown in Fig. 38A. According to our results (36b)
T is given by
lnTs* —2 J‘ie dr y/2w42c2Z7r - E) (40a)
where we note that in view of (39a) the integrand vanishes at the

upper limit Rc* To discuss this integral we introduce a new vari¬
able of integration defined by x ~ r/Rc. As r varies from R to Rc
the new variable x varies from xc = R/R f. to +1. Taking the rela¬
tion (39a) into account we may then write the integral (40a) in the
form
“ T“ - jC * Vi-* (40b)
The integral occurring in (40b) can be evaluated in closed form
easily enough. Since, however, the quantity xc = R/Rc is in
general a fairly “small” quantity, it will suffice for our purposes to
carry out an approximate evaluation in which we retain only the
first two terms in an expansion in We proceed as follows:
(40c)
The first term in the extreme right-hand side of (40c) can be
evaluated trivially if we make the substitution x = sin2 8, and we
get
(Ux\/~ -1 = 2 d$ cos2 0 = | (40d)

o y * Jo 2
The integral in (40b) is therefore given approximately by

f-2w (4fle)
and if we substitute this expression into (40b) taking into account
(39a) we obtain
<«*>
41 To obtain a useful and transparent formula we shall make

some further approximations. We shall set 71 = 86, and R = 7,3
fermi, which are the values of these parameters for the case when
the radium isotope ^Ra226 is the parent. We thus regard these
values of 7* and R as "typical” for all alpha-active nuclei. The
alpha-emitters are all heavy nuclei, and the variation in 7* actually
found for this class of nuclei is not very large. The important
parameter in (40f) is the energy E, which, as we said varies from
4-10 MeV. Our approximation is therefore reasonably justified,
especially in view of the other approximations which we have
made.
Inserting now the appropriate numerical values for the physical
constants in (40f) and setting Zf = 86, R = 7,3 fermi, we finally
obtain
Log T =-+ 32,5

y/E/MeV
Notice that (41a) gives the common logarithm (for which 10 is
the base) of T. To go from natural logarithms to common loga¬
rithms we make use of the relation Log x — (Log e) (In x) m 0,434 In x.
We have now derived the general expression (41a) for the trans¬
mission coefficient T, as a function of the energy E, for the potential
barrier which the alpha-particle has to penetrate in alpha-emission.
Let us see how we can use this result to find the lifetime of the
alpha-emitter*
42 For this purpose we consider a very naive model of the process.

We assume that before the emission the alpha-particle bounces
back and forth inside the nucleus along a diameter. Let the time
between two successive coflisions with the "walls” be tq. In each
collision there is a certain chance that the particle will leak through
the potential barrier, and in fact the probability for emission in any
single collision is just equal to the transmission coefficient T, It
follows that the alpha-particle has to make of the order of 1/T
collisions before it gets out, and we may therefore write the life¬
time r as
Sec* 7.42 The Wave Mechanics of Schrodinger 297
To
r (42a)
or
148
Log r = Log r0 + 32*5 (42b)
\/Ef MeV
To estimate tq we may assume, on the basis of our native model,
that the alpha-particle inside the nucleus moves with the same
velocity v as it will have after emission* We then have
2R
to v (42c)
v
If we apply this to the case of the radium isotope S8Ita220, which

we have used as a “standard” alpha-emitter, we obtain r<> ^ 10~31
sec.
As we see from (42c) the time to does depend on the energy E
as well as on the nuclear radius R. The quantity tq occurs, how¬
ever, as the argument of a logarithm in (42b) and the variation of
the first term with E is completely insignificant compared with the
variation of the second term with E, To see this explicitly we con¬
sider what happens when E changes from 9 to 4 MeV. The incre¬
ment of the first term in (42b) is then equal to Log ($) “ 0*18.
The increment of the second term in (42b) is much larger, namely
148 X (i — J) ^ 25* We may therefore well assume that the
value to = 10“21 sec is approximately valid for all alpha-emitters,
and we shall do so* We may state the matter as follows: The domi¬
nant factor in alpha-emission is the barrier penetration phenom¬
enon. What goes on inside the nucleus before the emission we do
not know too well, but we may say that the inside process defines
a time which can be interpreted as the time between successive
attempts by the particle to penetrate the barrier. This time cer¬
tainly depends on the parent nucleus in question, but it can reason¬
ably be assumed to be of roughly the same order of magnitude for
all alpha-emitters* Anyway the variation in the first term in (42b)
can for any reasonable model be expected to be small compared
to the variation in the second term, and for this reason our naive
model, which should at least give the right order of magnitude for
To, is not as bad as it may seem at first, or, more correctly stated:
it may be bad but it does not matter very much if it is bad*
We have thus reached our final goal, which is a general relation
between the lifetime r and the energy E of an alpha-emitter:
148
Log (r/sec) ^ 53*5 (42d)
\jEfMeV
Fig. 43A Half-life of alpha-emitters versus energy.

The small circles in this graph show a selection of
a Ip ha-radioactive nuclei. The ordinate is the loga¬
rithm of the half-life, and the abscissa is the quantity
— l/^/ITwhere E is the kinetic energy of the emitted
alpha-particle. Our simple theory predicts that the
points should lie on a straight line, shown dashed in
the graph. As we can see, the agreement is far from
perfect in the details, but the general trend in the
dependence of half-life on energy is correctly repro¬
duced. Considered as a whole this graph is a most
impressive confirmation of the ideas of quantum
mechanics.
Energy E in MeV
43 In Fig. 43A we have plotted the half-life of an alpha-emitter

versus the energy E: the dashed line represents Eq* (42d). In this
graph the ordinate is Log (t/scc) and the abscissa is — 1/ vÊ/MeV,
and the relation (42d) is thus represented by a straight line. In the
same graph we have plotted a large number of known alpha-emitters
in order to compare our theory with the observed facts. We note
that the experimental points by no means all fall on the theoretical
curve* but it is also clear that the general trend of the observational
data is correctly reproduced by our curve* We can regard it as
a spectacular triumph of quantum mechanics that our simple and
Sec* 7.44 The Wave Mechanics of Schf&dinger 299
naive theory should take us to this level of understanding of alpha-

radioactivity, which at first sight seems to be such a hopelessly
complicated phenomenon.
The theory of quantum-mechanical barrier penetration was first
given by Gamow, and independently by Condon and Gurney, in
1928* f Since then many refinements have naturally been added
to the theory of alpha-disintegration, and with these it is possible
to account for the observational results in much more detail.
44 The “lifetime” given in Fig* 43A is the half-life of the radio¬

active nucleus* As the reader undoubtedly knows, radioactive
decay is governed by an exponential law such that if there are
initially present, at time t — 0, No nuclei of the species in question,
then the average number of nuclei present at a later time t is
given by
N(t) = No exp (— \t) (44a)
The constant X is known as the decay constant or decay rate*

Its inverse, l/\, is known as the mean life of the nucleus* The
half-life is defined as the time at which N(t) = No/'2\ at this time
half the nuclei originally present have decayed, on the average*
Denoting the mean life by and the half-life by ti/2, we have
ti/2 = -1 In 2 = rm In 2
We may wonder whether our formula (42d) gives us the mean

life, half-life, or maybe some other “lifetime*” Our reasoning
actually gives us the mean life, but within the accuracy of our dis¬
cussion it makes absolutely no difference whether we speak of the
mean life or the half-life* As we can see in Fig* 43A our result is
correct only within a factor of 100 or 1000.
45 Consider again Fig. 38A. This figure is also relevant to the

“inverse” process in which a charged particle of energy E, less than
the height of the barrier, collides witli a nucleus* The particle in
question may be an alpha-particle or a proton, or maybe a deuteron.
If the particle can get inside the barrier, i*e*, into the region in
which the strong nuclear forces are active, a nuclear reaction will
{ G. Gamow, “Zur Quantentheorie des Atoinkernes/’ Xeitschrift fur Physik 51, 204
{1928). See also G. Gamow, “Quantum theory of nuclear disintegration/' Nature 122,
805 (1928); R. W, Gurney and E, U, Condon, “Wave mechanics and radioactive
disintegration/' Nature 122, 439 (1928).
300 The Wave Mechanics of Sckrodinger Sec* 7A6
in general take place. According to classical mechanics the particle

cannot penetrate the barrier, but we now know that the situation
is different in quantum mechanics. If the energy E is very small
the transmission coefficient T is also small, and it is unlikely that
a nuclear reaction will take place in any particular collision* As
the particle energy is increased the transparency of the barrier in¬
creases, and the chance for a nuclear reaction likewise increases.
This increase is furthermore roughly represented by an exponential
function of the energy. The phenomenon of barrier penetration
is thus an important feature of many nuclear reactions involving
charged incident particles of not too high energy. The situation is
T1 Bi At Fr Ac Pa Np Am Bk Es
entirely different when the incident particle is a neutron. The
Coulomb barrier is then absent, and the neutron may freely enter
the nucleus no matter how small its energy is. In fact many nuclear
reactions take place with a large yield for thermal neutrons, by
which we understand neutrons of an energy corresponding to room
temperature, i.e,, about 1/40 eV.
46 The heavy radioactive nuclei can be arranged into four groups

corresponding to four different radioactive series, or decay-chains.
In alpha-emission the mass number A of the nucleus changes by
— 4 units, and the charge number Z by — 2 units. In beta-decay,
in which an electron (positron) and an anti-neutrino (neutrino) are
emitted, the mass number does not change, but the charge number
changes by +1 ( — 1). Some heavy nuclei decay through alpha-
emission, and some decay through beta-emission. There is a further
possibility: a nucleus can capture one electron from the cloud of
electrons surrounding it, and at the same time emit a neutrino.
This process is known as K-capture. It is closely related to beta-
decay, The basic interaction responsible for K-capture and beta-
decay is the universal weak interaction, which we have mentioned
before. The electron, positron, and neutrino do not participate in
the strong interactions of which the “nuclear force” is an example,
whereas the alpha-particle does. The reason for the long lifetimes
Atomic number Z
encountered in beta-decay or K-capture is not a barrier penetra¬
Fig, 46A Heavy radioactive nuclei, whose mass tion effect, but simply the intrinsic weakness of the weak inter¬
numbers are of the form A = (4n + 2). The arrows actions.
indicate radioactive decays, the type of decay being In alpha-decay, beta-decay or ^-capture, the mass number A
shown by the directions of the arrows as in the small either changes by four units, or not at all. The radioactive nuclei
insert in the lower right of the figure. The symbol a
indicates a-decay, the symbol indicates beta-decay
can thus be grouped into four sets, and the mass number within a
(through the emission of an electron and an anti’ set is of the form A = (4n + r), where n is variable, but r is fixed.
neutrino), and the symbol K indicates K-capture. The four sets correspond to the four different values r = 0, 1,2 or 3.
Note that some nuclei decay in two different ways. One such radioactive decay series, for r — 2, is shown in Figs.
Note also that the end product of all the above decay
46A-B.
chains Is the stable lead isotope Pbaw}.
A naturally occurring radioactive element either has a very long
.5 X 10° Vr
Sec. 7A7 The Wave Mechanics of Schrodinger 301
Tir1 2
' \. i 'lavs
lifetime, or else it is a member of a decay chain originating from
a long-lived element. Among heavy nuclei with long lifetimes we
note U238 with half-life 4.5 X 109 years; Th232 with half-life Ik fi.7 hr
1.4 X 1010 years, and U235 with half-life 7,13 X 108 years. The
most long-lived member of the (4n + l)-family is a neptunium ,.|C
isotope, Np237 with half-life 2.2 X 106 years. This is a short time X id' vr
measured on a geological time scale, and tfye (4n + 1)-family there¬
fore does not occur naturally.
A few of the naturally occurring light nuclei are also radioactive. 8.3 X to4 vr
Examples are the beta-active nuclei K40 with half-life 1,3 X 109
years and Rb87 with half-life 4,7 X 1010 years.
yr
47 The phenomenon of natural radioactivity makes it possible
to determine the ages of rocks, i.e., the time which has passed since
the rocks were last chemically transformed. The principle is ffggyliMBiir
3.8 da vs #
simple. We determine the relative amounts of a long-lived radio¬ ct;

active isotope and the stable end product in the disintegration
chain which are present in a sample. Consider, for instance, the 3.05 min
uranium-radium decay chain which originates with U238 and ends a1
with the stable lead isotope Pb206. Suppose that we find, in a given
sample, an amount of Pb206 corresponding to ArPb atoms, and an • 27 min
amount of U238 corresponding to Nv atoms. If we assume that

t
all of the Pb206 atoms come from the decay of uranium, we can
write ■Wife ii min
Au ~ Aro e
1.8X10 4s»x*
where No is the number of U23S atoms present originally, A is the
«j
decay rate of uranium, and T is the age of the sample. Since
No — A u + Npb we have 21 yr
XT _ (A7Pb + Aru)
Nlt
(47b) ft
5.0 dav.s
and since A is known we can find T. This method actually gives 4

only an upper limit on T, because some of the Pb206 atoms present
138 days
today may have been present when the mineral was formed. A
more sophisticated approach is therefore necessary, and we have «T'
to compare the isotopic composition of lead in minerals which Stable
contain no uranium with the composition in minerals which contain
uranium. Our example was therefore oversimplified, but it does Fig.46B The uranium radium-lead radioactive chain.
illustrate the principle involved. Half-lives are shown at right and decay modes at left.
Another method depends on comparing the helium content of These isotopes occur naturally (in uranium minerals)
because they originate from the long-lived uranium
a rock with its uranium content. In each alpha-disintegration in
isotope 238. No transuranic elements belonging to
the decay chain a helium nucleus is produced, and if we can be this series (mass numbers of the form An + 2) have
sure that the helium did not escape from the interior of the rock appreciable half-lives on a geological time scale.
Fig* 48A Graph showing the estimated relative

abundances of the elements in the solar system, The
data are taken from a table (on pages 192-193) in
L. H. Alien The Abundance of the Elements (Inter-
science Publishers, lnc.F New York, 1961), and the
graph is inspired by a similar graph appearing on page
191 in the same book.
The ordinate is the logarithm to base ten of the rela¬
tive abundance, i.e., relative number of atoms. The
points representing neighboring elements have been
joined for ease of reading, A graph such as this one
is based on a variety of very different kinds of meas¬
urements, as well as on specific theoretical ideas.
The data for the lighter elements derive mostly from
spectroscopic studies of the sun, whereas the esti¬
mates for the heavier elements take into account
studies of the composition of meteorites. The graph
is a reasonable summary of present knowledge, but
it must be understood that some of the data shown
are quite uncertain and tentative.
It is believed that the abundances of the elements
in the entire (visible) universe is roughly similar to
the abundances in the solar system. The abundances
found in our immediate surroundings differ markedly
from the “cosmic1' abundances (see Table 48B),
X0 10 20 30 40 50 60 70 80 90
Atomic number Z
we can find out how many uranium atoms have disintegrated since
the rock was formed* t
Through methods such as these it has been found that the oldesi
rocks in the crust of the earth are about 3 X 10e years old. This
is definitely a lower limit on the age of the earth, because the crusi
has undergone many chemical transformations in the past. Mete¬
orites have also been studied, and they have been found to be about
4*6 X 109 years old, How the meteorites were formed is not
known with any certainty, but there is good evidenoe that the)
f The first estimate of the age of the earth on the basis of radioactivity was made bj
Rutherford. See E. Rutherford, “The Mass and Velocity of the a particles expellee
from Radium and Actinium,” Philosophical Magfizine 12, 348 (1906). See pp* 388-
369, where Rutherford arrives at the estimate of 400 million years for the minerah
he studied.
Sec. 7A8 The Wave Mechanics of Schrddlnger 303
were formed (crystallized) at about the same time as the other solid TABLE 48B The Eight Most Common Elements
bodies in the solar systerrii The age of the earth as a body would in the Earthrs Crust
thus be about 4,6 X 10e years. It is furthermore possible to esti¬
Number of Atoms
mate, using radioactive “clocks,” the time that elapsed between
Element percent
the latest formation of the chemical elements in the meteorite and
its crystallization* According to one such estimate,! it appears Oxygen 62.6
that this time was about 0.35 X 10e years. This implies that the Silicon 21.2
final building of the chemical elements contained in planets and Aluminum 6.5
meteorites took place about 5 billion years ago. This is thus the Sodium 2.64
estimated age of our solar system. Calcium 1.94
iron 1.92
48 It is natural to speculate further. How old is the universe? Magnesium 1.84
How were the chemical elements formed? We cannot discuss here Potassium 1.42
the ideas which lead to estimates of the age of the universe* It is
believed that the age of the universe might be something like 10 This table shows the estimated composition of the
billion years, roughly of the same order of magnitude as the age ten outermost miles of the earth's crust together with
the oceans and the atmosphere. These eight ele¬
of the solar system.
ments make up nearly 99 percent of the mass of this
It is believed that the chemical elements were formed from domain. The weak gravitational field of the earth
hydrogen in nuclear reactions in the stars. Fig. 48A shows the cannot retain the light elements hydrogen and helium,
estimated abundances of the chemical elements in the solar system. which explains their low abundances compared to the
The dots which represent individual chemical elements are not "cosmic" data. The abundances for the heavier ele¬
ments in the earth can be expected to be similar to
experimental points in the sense that they would all derive from
the cosmic abundances, but geological processes on
measurements on a single "standard sample.” The dots represent the earth have led to a chemical segregation of the
estimates based on a large number of different kinds of measure¬ elements, and the data for the crust are not represen¬
ments, such as spectroscopic determinations of relative abundances tative for the earth as a whole,
in the solar atmosphere, relative abundance measurements in mete*
orites and estimates of the chemical composition of the earth s
crust. Notice that hydrogen is by far the most abundant element.
Notice also the peaks in the abundance curve corresponding to
particularly stable elements. There is a clearly visible systematic
trend in that elements of even atomic number are more abundant
than neighboring elements of odd atomic number, which reflects
the fact that nuclei which have an even number of protons and an
even number of neutrons tend to be more stable than other nuclei.
To explain this curve in all details and thereby trace out the early
history of the solar system is a fascinating problem. The main
features of the abundance curve are believed to be fairly well under¬
stood at this time.
The author has absolutely nothing to say about the question of
where the hydrogen came from originally*
tj. H. Reynolds, "Determination of the age of the elements,” Physical Review

Letters 4, $ (I960), See also C, M. Hohenberg, F. A. Podesek, and J, H, Reynolds,
"Xenon-Iodine Dating: Sharp Isochronism in Chondrites,” Science 156, 202 (1967),
for some results which indicate that the time might be very considerably shorter.
Advanced Topic:
Normalisation of the Wave Function t
49 Let us consider the Schrodinger wave function, and for sim¬

plicity, let us restrict ourselves to the one-dimensional case, in
which case the wave function iff(x,t) is a function of x and t. We
have said that the absolute square of the wave function is propor¬
tional to a probability density. This means that the probability of
finding the particle at the time t in the interval #2 x *1 is
P(xi,x2) = N fJx
1
dx |ip(x,t)|2 (49a)
where N is some constant which is independent of x. How do we

determine the constant iV? By the simple requirement that the
probability of finding the particle somewhere must be unity, i.e.,
we must have
1 = N j+" dx\4>(x,t)\s (49b)

J — ZD
Now it could conceivably happen that the integral in (49b) does

not converge. If so the constant N must be zero* and it follows
from Eq. (49a) that the probability of finding the particle in any
finite interval must also be zero. This cannot correspond to any¬
thing physically meaningful and we draw the important conclusion
that the Schrodinger wave function \p(x,t) must, for all values of %
be a square-dntegrable function of x. By the term “square-inte-
grable” we understand the condition that the integral in (49b)
converges.
Suppose therefore that the wave function is indeed square-
integrable. We can then define a new wave function i/'nfc*) by
M*>*) = (49c)
where N is given by Eq, (49b). This wave function has the nice
property that
/+“ dx I j2 = L T(*i>*a) = fX2dx I 12 (49d)

J— oe J&l
and the probability density is thus equal to the absolute square of

the wave function.
A wave function which satisfies the first condition in (49d) is
called a normalized wave function, or is said to be normalized to
unity. It is clearly convenient to work with such a wave function
since its absolute square is equal to the probability density.
t Can be omitted in a first reading.

50 We must now settle an important question: does the constant

2V, as defined by (49b), depend on the time t? We have assumed
that $(x7t) is an actual solution of the Schrodinger equation
4*2 22 pi
2m ~dx^ ^X,t) + t50*)

and the new wave function ipn(xtt} would then also be a solution
of this equation provided the constant N is independent of the time.
We shall prove the following theorem: if tp(ar,f) satisfies the Eq.
(50a) and if ^(^f) tends to zero ‘^sufficiently rapidly” as x tends to
+ oc or — oo, then
ft * I 12 = 0 (50b)
Here “sufficiently rapidly” means, among other things, that

is square-integrable.
To prove this theorem we differentiate inside the integral sign:
I «*,<) |2 = ^ iPM iK*.t)
= r{x,t)*m + WMux.t) (50c)
Eq, (50a) gives us an expression for the time derivative of $(%£).

To obtain a similar expression for the complex conjugate of
the wave function we simply form the complex conjugate of (50a)
which gives us the equation
= - V(x)t*(x,t) (50d)
We have here assumed that V(x) is a real function, which is justi¬

fied in the Schrodinger theory since this potential is to correspond
to the potential in the “corresponding” classical problem. That the
potential is real is essential for our argument, and this assumption is
always made in the Schrodinger theory.
Eliminating now the time derivatives from (50c) using (50a) and
(50d) we obtain
(50e)
2m<br\r S# dx /
We therefore obtain
306 The Wave Mechanics of Schrodinger Sec* 7*51
a/_r *= 4-00
(50f)
If, however, the derivative of the wave function (with respect to

x) stays bounded, then the expression at right in (50f) will vanish
since we assumed that the wave function will vanish at infinity.
The relation (50b) therefore holds, and it follows immediately, from
(49b), that N is indeed a constant, independent of t. The function
\pn(x,t) is therefore also a bona-fide wave function, i.e,, a solution to
the Schrodinger equation (50a), We may always form a normalized
wave function from a given physical wave function, and if we like
we could work entirely with wave functions normalized to unity.
These important conclusions also hold in the three-dimensional
case. We shall not show this here, but merely state that the proof
is quite analogous to the proof in the one-dimensional case.
51 At this point the reader may be quite alarmed since our firm
conclusion that every physically meaningful wave function must be
square-integrable seems to cast doubts on our discussion of plane
monochromatic waves earlier in this chapter, It is clear that a wave
function of the form exp (ixpf'h — itp2/2m:H) is not squaro-integ-
rable and therefore cannot be normalized to unity. We are forced
to the conclusion that a wave of precisely defined momentum p,
which depends on the coordinate x only through the factor exp
(ixpffi), does not correspond to a physically realizable state of
motion of the particle. On the other hand we are not forbidden to
consider a wave which over a very large interval on the x-axis
depends on x through the factor exp (fecpM), provided that this
wave function does tend to zero as x tends to + oc or — oo. We can
therefore resolve our difficulty by agreeing that when we discuss
“waves of precisely defined momentum” we do not really mean
that the wave is everywhere of the form exp (ixpfff). We realize
that the wave function must tend to zero at infinity, but we assume
that the wave function is of this form in a very large interval of
the x-axis which includes the region in which we are primarily
interested. Our “monochromatic waves” are thus to be understood
as “almost monochromatic waves,” With this understanding we
can safely continue to talk about waves which depend on the co¬
ordinates through the factors exp (■ixp/&\ or exp (ix - p/#), as is done
in almost all texts on quantum mechanics. We can regard the non-
normalizable waves as limiting cases of normalizable waves, and if
we like we may call the former kind of wave functions improper
wave functions* This term will also serve to placate the mathema¬
ticians whose sensibilities are rightly offended by the frequently
careless manner in which physicists talk about “plane waves" as if
these would be bona-fide Schrodinger wave functions.
1) Schrodinger’s original papers on quantum mechanics have been published in trans¬

lation. E. ScbrOdinger Collected Papers on Wave Mechanics (Blackie and Son, Ltd,
Glasgow, 1928).
For the history of the subject we also refer to the books mentioned at the end of
Chap. 1. (Items 3 and 5.)
2) Some readers may feel a strong desire to learn more about the Schrfidingcr equa-
tion immediately. We therefore mention the following books:
a) R. M. Eisberg: Fundamentals of Modem Physics (John Wiley and Sons* New
York, 1961).
b) E. Merzbacher: Quantum Mechanics (John Wiley and Sons, New York, 1961),
c) L. L Schiff: Quantum Mechanics, 3rd edition (McGraw-Hill Book Company,
New York, 1968).
The third of these books is the most advanced, and they are all more advanced than
our book. The author mentions them only because the reader may be interested in
seeing a complete discussion of some particular topic. Simple barrier problems are
discussed in detail in the first two references.
3) Radioactivity and nuclear reactions are, of course, discussed in all books on nuclear
physics. Among the many books we mention the following:
a) D. H alii day: Introductory Nuclear Physics (John Wfley and Sons, New York,
1955).
b) E. Segr£: Nuclei and Particles (W, A. Benjamin, New York, 1964),
4) For the questions of the formation of the chemical elements, and the ages of the
solar system and universe, we refer to:
a) Eh M, Burbidge, G. R. Burbidge, W, A* Fowler, and F. Hoyle: “Synthesis of the
Elements in Stars/' of Modem Physics 29* 547 (1957).
b) W, A, Fowler and F* Hoyle: “Nuclear Cosmoehronology/' Annals of Physics ID,
280 (1900).
c) J, H. Reynolds: “The Age of the Elements in the Solar System/' Scientific Amer¬
ican^ Nov, I960, page 171.
Problems
1Consider the barrier shown in Fig. 28A for the case when E> VP.
(a) Consider first the case of a particle incident from the left* It, i.e., the
wave packet, will be partly reflected and partly transmitted by the step*
To discuss this case we desire a solution which in the right-hand region
describes a wave traveling to the right. Find this solution everywhere, and
308 Cfeap, 7 Problems
derive an expression for the reflection coefficient Rt i.e., the probability R

that the particle is reflected. The transmission coefficient T, i.e.3 the prob¬
ability that the particle is transmitted, is then equal to (1 — B).
(b) Consider next the case when the particle is incident from the right
In this case we desire a solution of the Schrodinger equation which in the
left-hand region represents a wave traveling to the left. Find this solution
everywhere, and derive an expression for the reflection coefficient B' and the
transmission coefficient T' — (1 — H')- Note that a particle would
not be reflected at all by the step.
2 Derive an exact expression for the transmission coefficient T of the

potential barrier shown in Fig. 31A and compare your exact result with our
approximate formula (33b). This comparison is best carried out by forming
the logarithm of both expressions for T, Our approximate result arises in
the limiting case of a “high and thick ^ barrier*
3 It is of interest to consider a specific example of the optical barrier

penetration effect illustrated in Fig. 34B. At the wavelength 6000 A (in air)
the refractive index of flint glass is 1.75. Suppose the optically denser medium
in Fig, 34B is flint glass, and suppose the rarer medium is air. Let the angle
of incidence be 45°, and let the separation between the plates be 0.01 mm.
Estimate the fraction of light which is able to pass through the barrier, (It is
not necessary to carry out a precise computation; An estimate in the spirit of
our discussion of barrier penetration will suffice.)
Note that the intensity of the transmitted light decreases exponentially
with the thickness of the air space between the two glass prisms. The impor¬
tant quantity is the ratio of the thickness to the wavelength* Note that the
component of the wave vector parallel to the interfaces is the same in the air
space as in the glass. (Why?)
4 Let us fuss about a small detail: Is the Fig, 34B appropriately drawn?
Consider the relationship between the transmitted ray and the incident ray.
Perhaps the transmitted ray should have been drawn as a continuation of the
incident ray, and not as in the figure? To find out how this picture should
really be drawn we could perhaps perform some experiments. Suppose that
the thickness of the optically rare medium is of the order of a wavelength of
the light used. By an arrangement with slits we select an extremely narrow
pencil of light as the incident beam, and this pencil is represented by the
dotted line in the lower right part of the figure. We can then study the
transmitted pencil of light, and find out whether it actually follows the dotted
line in the upper left part of the figure. You do not really have to do this
experiment in the laboratory; you can do it as a mental experiment instead,
because there is nothing in this experiment which cannot be accurately
predicted within electromagnetic theory.
After a consideration of this experiment, state your opinions as to whether
Fig. 34B is correctly drawn.
Problems The Wave Mechanics of Schr&dinger 309
5 Consider the motion of a particle in an “arbitrary” potential, such as

the one shown in the figure on this page. As x tends to + oo, or — oo, the
potential function V(x) tends to zero.
Suppose that a particle of energy E is incident from the left. The wave
function <p(x) must then be of the form: ^(x) = + Ae-1**] for very This figure refers to Prob. 5. Can you prove, for an
large negative x> and of the form: <p(x) = B for very large positive x. arbitrary barrier of this kind, that the reflection and
To actually find the two constants A and B we would have to solve the transmission coefficients, defined in terms of the
amplitudes of the waves traveling to the right and to
Schrodinger equation for the potential V(x).
the left, actually add up to unity?
We have been led to interpret \A\2 as the reflection coefficient of the
barrier, and | B |2 as the transmission coefficient. If this interpretation is to
make sense we must clearly have:
|A|2+ |B|* = 1 (a)
This raises an interesting question of principle. Is it really true that the

above relation holds for all potential functions V(x)?
Prove this relation in general. Hint; Consider the function
and show that dF(x)f dx = 0 if tp(x) satisfies the Schr5dinger equation.

This problem illustrates the fact that one can sometimes prove general
statements about the nature of the solutions, without actually finding the
solutions explicitly. In this particular case it is clear that we have discovered
an important general property of the Schrodinger equation and its solutions.
If the theory is to make sense the equation (a) must hold, and it is comforting
that we can prove it.
6 There are further interesting questions which we can ask about the
situation illustrated in the figure associated with the preceding problem.
For instance: Is the transparency of the barrier the same in both directions?
Theorem: The transmission coefficient when the particle is incident from
the left is the same as when the particle is incident from the right, provided
that the energies are the same in both cases.
Prove this theorem. Hintx Note that if <p(x), as discussed in the preceding
problem, is a solution of the Schrodinger equation, so is <p*(x), and so is every
linear combination of <p(x) and qp*(x). Consider a suitable linear combination
of <p(x) and qp*(x).
7 Many unstable nuclei decay through the emission of a positron and a

neutrino. The positrons emerge with energies ranging from IQ keV to a few
MeV, This kind of decay is a consequence of the weak interactions, as we
have stated before. We have also said that the reason for the long lifetimes
sometimes found for beta-active nuclei is the intrinsic weakness of this inter¬
action, This does not exclude the possibility that the barrier penetration
effect might also play an important role. Investigate this point with the help
310 Chap 7. Problems
of some explicit numerical examples* i.e,, estimate the transmission coeffi¬

cients for “typical” potential barriers which the positron has to pass through,
and convince yourself that the barrier penetration phenomenon is not here
the dominant factor determining the lifetime.
8 L. Meitner and W. Orthmann [Zeitschrift fiir Pkysik 60, 143 (1930)],

once carried out a calorimetric measurement of the energy released in the
beta-decay of RaE, (This is the old name for the nucleus Ri210,) In this
experiment they used a sample of RaE, placed in a suitable calorimeter, and
they measured the rate at which heat evolved in the calorimeter. From a
knowledge of the half-life of RaE (5*0 days), and the siae of the sample, they
were able to find the number of disintegrations per second, and hence the
amount of heat energy evolved per disintegration. This amount of heat
turned out to be (0.337 ± 0.020) MeV/disintegration.
On the other hand it was known that the maximum kinetic energy with
which the electron can be emitted is 1.170 MeV, There thus appears to exist
a disturbing discrepancy between the known maximum energy and the
calorimetrically determined energy, and it is not surprising that physicists
were quite worried at that time. Since we believe that the decay takes place
between two definite energy levels we must assume that the energy 1,170
MeV is the kinetic energy released per decay, and the question then arises
why this energy partly u disappears” in the calorimeter. Physicists were in
fact so disturbed that some people, including Bohr, contemplated the possi¬
bility that the principle of conservation of energy might not hold in micro¬
physics.
In the light of your knowledge of beta-decay, explain in detail the above
mentioned circumstances (including the worried feelings of the physicists at
that time).
9 In naturally occurring uranium the abundance of the isotope 235 is

0.71 percent and the abundance of the isotope 238 is 99,28 percent. The
half-life of U235 is 7,1 X 108 years and the half-life of U2as is 4.50 X 109
years,
(a) The abundances quoted above hold for all terrestlal samples, and also
for uranium-containing meteorites. What conclusion can you draw from
this circumstance?
(b) If you make the simplifying assumption that the original amounts of
the two isotopes of uranium in the solar system were equal, what estimate
of the age of the solar system do you then arrive at?
10 (a) Compute the amount of radium which you expect to find in an

amount of uranium ore which contains 1 ton of uranium. Does it make any
difference whether the mineral is 1 million years old, or 500 million years old?
(ft) How much lead do you expect to find if the mineral is 500 million
years old?
Chapter 8
Theory of Stationary States
Sections I to 26 Quantization as an Eigenvalue Problem 312

27 to 41 The Harmonic Oscillator. Vibrational and
Rotational Excitations of Molecules 328

42 to 48 Hydrogen-like Systems 339
49 to 58 Advanced Topic: The Position and Momentum
Variables in the Schrodinger Theory 344

Problems 350
Chapter 8 Theory of Stationary States
Quantization as an Eigenvalue Problem
1 Out subheading above is the English translation of the common

title of Schrodinger's four famous papers! on wave mechanics* in
which he showed how the existence of discrete energy levels in
atoms can be understood in terms of the wave picture, and spe¬
cifically in terms of the Schrodinger equation.
Preceding Schrodingers theory Bohr had formulated, in 1913*
a semi-classical theory of atoms. We say semi-classical because he
assumed a planetary model, to be described by the laws of classical
mechanics, but with the added assumption that not every orbit per¬
mitted classically is actually realized. The actual orbits are re¬
stricted by a number of quantum conditions of a definitely non-
classical nature, As an example we mention the rule that the total
angular momentum due to the orbital motion of the particles in
the atom must be an integral multiple of The values of total
energy associated with the orbits permitted by the quantum con¬
ditions form in many cases (but not always) a discrete set* In this
way Bohr created a theory of the discrete energy levels of an atom*
His procedure can be called the quantization of the motion in the
atom. This is the historical origin of the term “quantization,”
2 Bohr's quantum conditions were of an ad hoc nature, and they

could hardly be regarded as satisfactory. By the time of Schro-
dingers papers it had become evident that whereas Bohr’s theory
did explain some of the observed facts, the theory also had definite
shortcomings and outright failures* The time was therefore ripe
for new ideas*
Schrodinger’s great contribution was to show that if the wave
picture of matter is taken seriously, then there is a systematic and
natural way to “quantize.” He noted that his wave equation would
have, under suitable conditions, solutions describing standing
waves, and he associated these solutions with the stationary states
of atoms. The standing wave solutions are all characterized by a
time dependence of the form exp ( — udt), where the possible fre¬
quencies form a discrete set, say Wi, u2, , and the energy of
the nth stationary state is then given by En = In this chapter
we shall follow in Schrodinger s footsteps and explore this idea.
f E. Schrodinger, “Quantisierung als Eigenwertproblem,” Annalen der Fhysik T9,

361 (1928); 79,489 (1920); 80,437 (1920); 81, 109 (1920).
Sec* 8.3 Theory of Stationary States 313 (A) (B)
3 In Chap* 7 we arrived, via a number of plausibility arguments,

at the Schrodinger equation!
- V2 4>{x,t) + V(x)^(x,f) ~ (3a)
which describes a particle of mass m, moving in a field of force

derivable from the potential function V(x), In our “derivation” we
recognized that this equation is clearly an approximation: the
motion of the particle is treated non-relativistically, and all creation
and destruction phenomena are ignored. We gave reasons why
this equation should be very useful in atomic and molecular physics,
and in some situations in nuclear physics* In the latter realm we
scored a great success in being able to explain the dependence of
the lifetime of an alpha-emitter on the energy of the emitted particle
in terms of the quantum-mechanical tunnel effect.
Just as in our discussion in Chap. 7 it will be instructive here to
consider the simplified version of the Schrodinger theory which
describes one-dimensional problems. The Schrodinger equation
for such problems is of the form
= m |*(*,*) (3b)
The equation (3b) is much simpler to discuss mathematically than

the three-dimensional equation (3a). Since the essential features of
the phenomena in which we are now interested show up in pretty
much the same way in the two equations, we can gain a real under¬
standing of how Schrodinger s theory works out through a study
of the simpler equation (3b)* Furthermore, it should be stated
that this equation is not as unphysical as one may think at first:
many problems involving motion in three dimensions can be
reduced to equivalent one-dimensional problems.
4 Let us begin with a very simple problem* A particle is confined

inside a “box” of length a, with infinitely high walls* The solid
(C)
curve in Fig* 4A represents the potential V(r) for this problem*
The potential V(x) is zero for % in the interval (0,a), and + oo out¬ Figs. 4ABC The somewhat uhphysical situation of
side this interval. a particle confined to a one'dimensionaf box provides
In Sec, 26, Chap. 7, we considered the case when there is only us with a very simple illustration of the essence of
Schrddinger's theory of stationary states. (A) shows
one infinitely high potential wall. In that case we found mono¬ the potential, which becomes infinite at the points
chromatic standing wave solutions describing the reflection of a x = 0 and x = a. The wave function corresponding
particle of any positive energy E by the wall. The new element to a stationary state must vanish at these points.
in the present situation is that the particle is confined between two This is possible only if the (total) energy has one of
infinitely high potential walls* the values shown in (B) the term scheme (only the first
six levels are shown). (C) shows the corresponding
wave functions (eigenfunctions) for the first six sta*
f In this chapter we employ cgs or MKS units. tionary states.
314 Theory of Stationary States Sec. 8.4
Let us now try to solve the Schrodinger equation (3b) assuming

that the wave function depends on the time through a factor
which is a simple exponential function of t, Le.,
= <P(*) exp (- ^) (4a)
Inserting a wave function of this form into (3b) we obtain the time-
independent Schrodinger equation
-£,£,*(*) = v - mM*) (*)

In our discussion in Sec. 26, Chap. 7, we concluded that the wave
function must vanish in a region in which the potential is infinite, as
well as at the boundary of such a region. In the present problem
the wave function must thus vanish at the points x = 0 and x = a,
as well as outside the interval (0,a).
Inside the box the general solution of the equation (4b) is of the
form
qp(ac) = A exp (ixfc) + B exp (— ixfc) (4c)
where
>-v¥
and where A and B are constants. If we now first impose the con¬
<4d)
dition that the wave function must vanish at x = 0, we find that the
physically acceptable solution must be of the form
<p(x) = C sin (xfc) (4e)
where C is a non-zero constant. The wave function must also

vanish at x — ay and we obtain the further condition
C sin (afc) = 0 or ak = nn (4f)
This is a condition on fc, and thereby a condition on the energy E.

Talcing into account the relation between E and fe, as expressed by
(4d), we have
n2n2(Hfa)2
2m
where n is a positive integer: our problem has no physically accept¬
able solution unless E is of this form. The case n — 0 is ruled out
because it corresponds to an identically vanishing wave function,
which is not acceptable physically, Since we assumed that fc is
non-negative it follows that n is positive.
Sec. 8*5 Theory of Stationary States 315
5 We have thus found that for our particle in a box the Schro-
dinger equation (3b) has stationary solutions with a simple ex¬
ponential time-dependence, i,e., solutions of the form ^(xs#) =
<p(x) exp (— itEffi), only if the energy E assumes one of a discrete
set of values Elt E2j E3, ..., E^ *. . , given by
where n is any positive integer* The normalized^ wave function

corresponding to the nth possible energy En is then of the
form
inside the interval (0,n), and zero outside. (That this wave function
is correctly normalized to unity we see trivially by integrating
[ i^(x,t) 2 = (2fa) sin2 {nwx/a) from 0 to a\ the result is L)
H-oo +QP
We have represented the energies En in the form of a term
scheme for our system in Fig. 4B, which shows the first six energy
levels. In Fig. 4C we have drawn the corresponding wave func¬
tions <p,t(x). These functions are, of course, equal to the functions
at the particular time t = 0.
See also Fig. 5A for a composite picture,
6 Let us now study the difference between stationary and non¬

stationary solutions of the Schrodinger equation (3b).
Consider first the nth stationary solution, given by (5b). Since
the solution is normalized to unity, the absolute square of the wave
function gives us the probability density P*(x) of finding the particle
anywhere on the x-axis. We find
?n(x)= |W*,f)|2 = (|) sin2 (6a)
x=Q x—a
inside the interval (0,a)9 and Pn(x) = 0 outside this interval. As we
see, the probability density does not depend on the time for a
stationary solution. Fig. SA It is common practice in texts on quantum
Let us next consider a non-stationary solution. Since the Schro¬ mechanics to show figures such as the one above.
The three figures 4ABC have been collapsed into a
dinger equation (3b) is a linear differential equation the linear single figure. This is perhaps a deplorable practice,
combination of any two solutions gives a new solution. This new but since the author has never been misled by such
solution will satisfy the same boundary conditions ip(0,£) = pictures, he assumes that the reader will not be misled
ip(a9t) = 0, provided that the two original solutions satisfy these either.
The energy levels are indicated by the thin broken
lines. Each one of these lines also serves as the
f For a discussion of the normalization of the Schrd dinger wave function, see Sec, r-axis in a superimposed figure showing the corre*
49, Chap, 7. sponding wave function.
316 Theory of Stationary States Sec* 8*7
conditions* We can conclude that any linear combinations of the

stationary solutions (5b) give us new physically acceptable solutions,
in accordance with the Principle of Superposition*
To see what happens in such a superposition of two solutions, let
us consider the particular linear combination
4>(x4) = yA (6b)
where we assume that n' =^= nff. We claim that this new solution
of the Schrodinger equation is normalized to unity (for all times £).
The probability density P(x,t) corresponding to the solution (6b) is
given by
, * /nVx\ . /n"m\
+ 2 an (—j sin (—j COS
The reader should immediately verify, by integrating this expres¬

sion for F(xj) between 0 and a, that the wave function given in (6b)
is indeed normalized to unity*
As we see, the probability density P(x,t) is not time-independent:
the last term in the expression (6c) shows an oscillatory behavior,
and the frequency of this oscillation is given by
fcVn" —
7 A moment's reflection tells us that this behavior must be ex¬

hibited by all superpositions of the stationary solutions (5b) as long
as at least two different stationary solutions occur in the super¬
position, (The superposition may contain any number of stationary
solutions: even an infinite number could occur.) We furthermore
easily see that if the stationary solutions t/v and \j/n" occur in the
superposition, then there must be a term in the probability density
which oscillates with the frequency wn'n"> given by equation (6d)»
This term comes from the “cross-terms” and oc¬
curring in the expansion of the absolute square of the wave function
4'(xJ) = Vcn'K(^) (7a)

n
where the cn are constants*

Now it is actually possible to prove a theorem: every physically
acceptable solution of the Schrodinger equation for the particle-in-
the-box problem can be written in a unique way in the form of an
Sec* 8.8 Theory of Stationary States 317
expansion, as given in (7a), in terms of the stationary solutions (5b)

of the problem* We shall not prove this theorem here, but we ac¬
cept it as very plausible: mathematically the theorem is a theorem
about Fourier series* Accepting this theorem we can conclude that
the only solutions of the Schrodinger equation which correspond to
a time-independent probability density are the stationary solutions.
8 We have now learned the essence of the Schrodinger theory of

the stationary states and energy levels of a quantum-mechanical
system* The stationary states correspond to stationary solutions of
the Schrodinger equation, and for these the probability density is
independent of the time. For the non-stationary states the prob¬
ability density shows an oscillatory dependence on the time, and
the frequencies of oscillation which can occur are given by equation
(6d) in terms of the energy differences of the various stationary
levels. These frequencies are clearly the characteristic frequencies
of the system at which we might expect radiation to be emitted and
absorbed: these are the frequencies at which the system will reso¬
nate. The transition frequencies in turn determine the loca¬
tion of the energy levels, except for a common additive constant
which we can fix by assigning some suitable energy to the ground
state* (In our example we selected the “bottom of the well” as the
zero-point,)
We might now propose an ambitious program: to solve the Schro¬
dinger equations (properly generalized to apply to many-particle
systems) for all cases of physical interest in which the Schrodinger
theory can be expected to be a good approximation. In particular
we should look for the stationary solutions which can be normalized
to unity: they give us the stationary states and the corresponding
energy levels* Needless to say this grandiose program is very far
indeed from its completion: our mathematical abilities are totally
inadequate for solving the Schrodinger equation exactly for a com¬
plicated system, although we can handle simple systems quite well,
9 Considering the above-mentioned program we may ask whether

it is really what we want. As we carefully discussed in Chap, 3 the
“stationary” states are, strictly speaking, not stationary at all. Our
theory of the particle in the box, on the other hand, did give us
strictly stationary states. The program which we have outlined
would also give us strictly stationary states, in contradiction to
known observational facts* We here encounter a clear shortcoming
of the Schrodinger equation: it does not describe radiative transi¬
tions. The Schrodinger equation is therefore not the whole story:
something has been left out* In this respect the Schrodinger theory
is analogous to a classical theory in which all the electrostatic
interactions between the electrons and the nucleus are taken into
account, but in which the radiation of electromagnetic waves from
the moving particles is ignored* We can nevertheless hope that the
Schrftdinger theory is a good approximation in atomic and molecular
physics. We can thus expect that a stationary state predicted by
the SchrQdinger equation would correspond to an almost stationary
state in the “true” theory, and that the “mean energy” of the
latter state would be very close to the precise energy predicted by
the Schrodinger equation*
10 Let us explain some commonly employed terms before we go

on. The time-independent Schrodinger equation (4b) is typical of
the equations we have to consider when we wish to find the energy
levels of a system. Let us write this equation in the symbolic form
Hq>(x) — E<p(x) (10a)

where H stands for the differential operator
W__cP + V(x) (10b)

2m dx2
We wish to find the solutions <p(x) to the differential equation
(10a)* This equation will always have solutions, for any E, but not
all of these will be physically acceptable. We should therefore
regard the conditions for physical acceptability, namely that the
wave function be square-integrable,t as an essential part of the
problem. If we do this we find that E cannot be arbitrary. Those
values of E for which the equation (10a) has a physically acceptable
solution are called the eigenvalues of the differential operator ff.
The corresponding wave functions are called the eigenfunctions
of the operator* |
We can now understand why Schrodinger called his papers
“Quantisierung als Eigenwertproblem/’
11 The problem of a particle confined to a potential well with

infinitely high walls is a bit unrealistic* Let us now consider the
one-dimensional eigenvalue problem more generally. Let us as¬
sume that the potential V(e) is nowhere infinite, but rather of the
form shown in Fig. 11A. We assume that the potential function
F*g. 11A A particular kind of potential function,
which tends to the constant values V+ and V_ as x t In the case of a “potential well" with infinitely high walls this condition leads to
tends to + og or — oo. We shall study the nature of the condition that the wave function vanishes outside the well, as well as on the
the solutions of the Schrodinger equation for various boundary, as we found in Sec. 26, Chap. 7.
values of the total energy E, The dashed horizontal | The words "eigenvalue” and “eigenfunction" are German-English hybrids which
lines indicate four energies representative of the cases have become firmly established in physics. The German terms are Êigenwert” and
which can occur. * ‘Eigenfunktion, **
Sec. 8.12 Theory of Stationary States 319
tends to the constant value V+ as x —» +00, and to the constant

value V_ as * —> — 00. We denote the minimum of the potential
by Vo- This particular potential is, of course, a special case, but
it is very instructive to consider this special case. We assume that
V+ ^ V_.
We shall examine the nature of the solutions of the time-
independent Schrodinger equation (4b) for the potential V(x). Let
us write this equation in the form
= - (§?)[* - vMhM (n«)

We consider this differential equation for various values of the
energy-parameter E; namely for E ^ V0; for V_ g E > V0; for
V+ ^ E > V_; and for E > V+. It should be clearly understood
that the differential equation (11a) will have solutions for all values
of E, but these solutions will in general not all be physically accept¬
able.
The graphical representation of the (in general) complex wave
function presents some problems. One possibility is to plot the
absolute value of the wave function* Another possibility is to con¬
sider real solutions of equation (Ua), We note that if ip(ac) is any
(complex) solution of (11a), so is <jp*(x), since both E and V(x) are
real. The real part [<p(x] + (p*(x)]/2, and the imaginary part
[<p(x) — <p*(x)]/2f, of a solution <p(x) are also solutions, and we may
imagine that we plot these real functions.
12 Let us first consider the heal behavior of the real solutions

in a region throughout which [E — V(x)] < 0. Inspection of the
Schrodinger equation (11a) shows that in such a region the second
derivative of the wave function has the same sign as the wave func¬
tion, It follows that if the wave function does not vanish in an
interval, then it “bulges toward the x-axis,” as illustrated by the
two segements shown in Fig. 12A, If the wave function passes
through the axis it will “grow away" from the axis on both sides
of the zero, as shown in Fig, 12B, The wave function might
also approach the axis asymptotically either on the left side, or
else on the right side, as illustrated by the two segments shown in
Fig. 12C.
We conclude that if V(x) > E for all values of x, then the solu*
tions of (11a) cannot be physically acceptable, because the absolute
value of the wave function grows without bound either on the left Figs. 12ABC The segments shown in the figures
above illustrate the local behavior of the (real) wave
side or on the right side, or possibly on both sides. With reference
function in a region throughout which E < V(x). In
to Fig. 11A the physical system cannot have an energy E less such a region the second derivative has the same sign
than Vo. as the wave function.
13 We next consider the behavior of the wave function in a

region throughout which [£ — V(x)] ]> 0* In this case the second
derivative of the wave function and the wave function are of oppo¬
site sign. It follows that in a region in which the wave function
does not vanish it must ‘"bulge away from the x-axis.” This is
illustrated by the two segments shown in Fig. 13A, If the wave
function crosses the axis it will turn toward the axis on both sides
of the point of intersection, away from the tangent to the curve at
the zero point. This behavior is illustrated in Fig. 13B, which
should be compared to Fig. 12B,
A longer segment of the curve representing the wave function
might cross the axis several times, and we then have the “oscilla¬
tory17 behavior illustrated in Fig. 13C.
14 Finally we consider the case when [E — V(x)] = 0 through¬

out a region. (This very special situation can only arise if the
potential function V(x) is constant throughout the region*) The
second derivative of the wave function must be zero, and it follows
that the first derivative must be a constant. The curve representing
the wave function is a straight line, as illustrated by the segments
shown in Figs. 14AB.
Let us here note that for a potential of the kind shown in Fig*
11A a physically meaningful wave function and its first derivative
cannot both vanish at the same point, because if this happens then
the wave function must vanish everywhere. This statement is a
theorem in the theory of ordinary differential equations. For this
reason the curve segments shown in Figs, 12ABC, 13ABC and
14AB never touch the ar-axis, although they may cross the axis, or
approach the axis asymptotically,
15 Let us use our knowledge of the local behavior of the wave

function to discuss its global behavior, for all values of x, when the
potential function is as shown in Fig, 11A. We must now impose
on the solutions of the differential equation (11a) the conditions
which must be satisfied by physically meaningful wave functions.
With reference to Fig. 11A we first consider the case when the
Figs. 13ABC The segments shown in the figures energy E satisfies the condition E > V+. Such an energy E± is
above illustrate the local behavior of the (real) wave represented by the dashed line so labeled in the figure. This ease
function in a region throughout which E > V(jt). In is actually somewhat special because we have [E — V(*)] > 0 for
such a region the second derivative and the wave func¬
all x. The solutions are oscillatory everywhere, and in particular
tion are of opposite sign. The reader should carefully
compare the above figures with the figures 12ABC. at + oo and — oo. The solutions are also oscillatory at + oo and
— oo in the case when the energy E is below the maximum of the
potential V(x), provided E > V+: in this case we have a barrier
penetration problem. We can therefore find two linearly inde-
pendent solutions, oscillatory at infinity, for every E > V+, and

these solutions describe traveling particles (or waves). We have
already discussed such solutions, and their physical inteipretation,
in Chap, 7. The solution for a fixed £ is not normalized to unity,
but we can construct normalizable solutions in the form of a (con¬
tinuous) superposition of the traveling-wave solutions. We agreed,
in Sec. 51, Chap. 7, to call the solutions corresponding to a definite
E improper wave functions, and for any £ > V+ we thus have two
linearly independent improper wave functions. These wave funo-
tions, or rather the normalized wave packets which can be formed
from them, may describe, for instance, a particle incident from the
left of the “barrier/* This particle is partly reflected back to the
left, and partly transmitted past the barrier to the right. Similarly
the particle may be incident from the right.
<p(x)
16 Next suppose that V+ > £ > V_. In this case we have a

region to the right in which [£ — V(x)] < 0, and a region to the
left in which [£ — V(x)] > 0. This is the same kind of problem
as we considered in Sections 21-25, Chap. 7. In this case only one
of the two linearly independent solutions in the right region is
I X
physically acceptable, namely the solution which tends to zero as
x tends to + oo (corresponding to the segment at right in Fig. 12C).
This solution, when continued to the left, has an oscillatory be¬ Figs. 14AB The segments shown in the figures
above illustrate the local behavior of the (real) wave
havior in the region in which [£ — V(x)] > 0. (The wave func¬ function in a region throughout which E = Vfa). This
tion, and its first derivative, are, of course, everywhere continuous, is a very special case which can occur only if the poten-
otherwise the wave function does not correspond to a global solu¬ tial Vfr) is constant in the region. The second derive
tion of the SchrSdinger equation.) For every £ such that tive of the wave function vanishes, and the wave func«
tion is represented by a straight line.
V+ > £ > V_ we thus have one (improper) wave function, and
this wave function describes the reflection of a particle incident
from the left by the potential “hump,” just as in the problem con¬
sidered in Chap, 7.
17 Let us next consider the case when V_ > £ > V0. An exam¬
ple of this is the energy £3, indicated by the dashed line so labeled
in Fig. HA. In this case we have a region to the left and a region
to the right in which [£ — V(x)] < 0, and a region in the middle
in which [£ — V(x)] > 0. The two boundary points separating
these regions from each other are the classical fuming points: we
shall denote them by xi and x2.
To the left of xi the wave function must tend asymptotically to
the x-axis, and the behavior must be as indicated by the left seg¬ For the convenience of the reader we show Fig. 11A
once more. The potential function tends to the con’
ment in Fig. 12C (except for the sign of the wave function, which
slant values V+ and v_ as x tends to +00 or -00.
is immaterial). Unless the wave function behaves in this way it The dashed horizontal lines indicate four energies
would grow as x tends to — 00, and a steadily growing wave func- representative of the cases which can occur.
322 Theory of Stationary States Sec. 8*18
tion cannot be physically acceptable. To the right of x% the wave

function must behave like the right segment in Fig. 12C. In the
middle region between and x2 the wave function shows an oscil¬
latory behavior, and in this region we have two linearly independent
physically acceptable solutions. The problem is now to “match”
these different types of solutions so that we obtain a physically
Region in which acceptable wave function which is everywhere continuous and has
a continuous first derivative everywhere.t For an arbitrary E this
cannot be done: a physically acceptable solution (which is square
mtegrable) can only be found for certain discrete values of the
energy E. To each one of these energies corresponds a bound sta¬
tionary state of the system*
18 This phenomenon can be readily understood with the help

of Figs. 18ABC. Suppose we pick an arbitrary energy E such that
V_ > E > Vo- We satisfy the physical conditions “to the left”
by picking a solution which tends asymptotically toward the ar-axis
as x tends to — oo. At the turning point Xi this solution must be
“matched” to the oscillatory solution between xi and Since
both the wave function and its first derivative must be continuous
we obtain a unique solution for this region, This solution must
be “matched” to the solution to the right of x2i and we again obtain
a unique solution to the right of x2* This solution will not exhibit
the behavior of the right segment in Fig. 12C unless the energy E
is just right, but will instead grow away from the axis in which case
the overall solution is not physically acceptable. The conditions
that the wave function shall decrease to the left, as well as to the
right, are in general not compatible, except if £ has one of a discrete
set of values. These values must be greater than Vb. We have
already concluded that there can be no physically acceptable solu¬
tion for E Vo.
point point For the potential problem shown in Fig. 11A the term scheme
thus consists of a (possibly empty) set of discrete levels between
Figs* 18ABC Schematic representation of the be' Vo and V_, and a continuum above the energy V_,
havior of the solutions of the Schrodinger equation
which tend to zero asymptotically as x tends to — oo. 19 A one-dimensional problem of the kind just discussed, and
The three curves represent solutions for three differ¬
ent energies, Unless the value of the energy paranrv which is comparatively simple to handle analytically, is shown in
eter is "just right,5' the solution will diverge to +oo Fig. 19A. In this case we have V+ = V„, and the potential func¬
or - oo as x tends to + oc, The unbounded solutions tion V(x) is piecewise constant. The term scheme is shown to the
of the differential equation are not physically accept- right, and we see that there are four bound states below the con¬
able; they are not solutions of the Schrddinger prob¬ tinuum. The wave functions corresponding to these bound states
lem, The energy is "just right'1 for curve B\ the wave
function tends to zero asymptotically as x tends to
+ oo. This curve represents the wave function for a \ The ‘‘matching” is, of course, done automatically if we find a global solution of the
bound state. wave equation.
are shown in the left part of the figure. Note that the first wave E
function has one extremum (and no node), the second wave func¬ - 0.2B
tion has two extrema (and one node), and the fourth wave function*
corresponding to the highest discrete energy level, has four extrema - 0
(and three nodes). For a deeper potential well we would have — 0.2B
more bound states, and in the extreme case of an infinitely deep
- 0.503 — 0.43
well, which is the problem discussed in Sec. 4, we have an infinite
number of bound states. The term schemes in Figs. 4B and 19A -0.63
- 0.773
should be compared: the locations of the first four bound state -0.83
levels are similar, although not identical, in the two cases. — 0,943
-1.03
The reader may wish to try to solve the problem of finding the
bound states for the situation shown in Fig. 19A: it is not particu¬ Fig. 19A The case of a particle in a potential well
larly difficult. of depth 6. This figure is based on an example given
We have now learned that we can understand, on the basis of in R. B. Leighton, Princfp/es of Modern Physics, p. 154
the SchrOdinger theory* why a quantum-mechanical system will (McGraw-Hill Book Co., New York, 1959). The poten¬
have bound states, and why there will in general be a continuum tial well is shown at left, and the term scheme at right.
There are four bound states (four discrete energy
of possible energies above a certain limit. The beginning of the
levels). The corresponding eigenfunctions are shown
continuum is simply the energy above which the system can dis¬ at left, superimposed on the graph of the potential
sociate, which in our simple examples means that the particle can function. The continuum begins at the top of the
behave like a propagating wave packet far away from the 'central well, as indicated in gray on the term scheme.
region.”
20 Let us next indicate how one can understand the phenomenon

which we encountered in Sec, 38, Chap. 3, of energy levels above
the beginning of the continuum. (See the term scheme in Fig.
38A, Chap. 3.)
We consider the one-dimensional potential problem shown in
Fig. 20A. It differs from the problem in Fig. 19A in that the poten¬
tial does not stay constant outside the well, but decreases to the
value — in a stepwise fashion, at some distance from the well.
We assume that outside these steps the potential remains constant
at the value — B
In accordance with our theory the continuum will now begin
at the energy — as indicated in the term scheme to the ri^ht
in Fig, 20A. For a not too small b there will be three bound states.
These energy levels, Elt E2t E$, are very close to the three first Fig* 20A This figure illustrates a modification of the
situation shown in Fig. 19A, The potential functions
energy levels in the term scheme in Fig. 19A whenever the con¬
are identical within the interval (-£>, +fr), but outside
stant b is large> i.e., when the two potential barriers shown in Fig. this interval the potential shown above has the con¬
2GA are very thick. Let us restrict our considerations to the case stant value — < 0. The continuum therefore
of a very laige &, If b were infinite, then the problem in Fig. 20A begins at in the present case, and there are only
would become identical with the problem in Fig. 19A, The con¬ three strictly stationary states. However, if b is very
large, corresponding to a very thick "barrier/' then
tinuum would begin at the energy 0, and the fourth bound state
there will be a fourth almost stationary state. This
at the energy £4 would be present. For any finite bt no matter virtual level is designated by £4 above. It corresponds
how large, we have only three strictly stationary states, and the to the fourth stationary level in Fig. 19A.
continuum begins at — B«. However, suppose that the width of

the well is of typical atomic size, that its depth is of the order of
10 eV, that the particle is an electron, and that b is larger than one
kilometer. Under these conditions it is difficult to see how the situ¬
ation in Fig. 20A can really differ from the situation in Fig. 19A.
Common sense tells us that the behavior of the particle in the neighr
borhood of the well must be very similar in the two cases, and we
therefore expect that the fourth bound state present in the term
scheme in Fig. 19A must somehow manifest itself in the problem
in Fig. 20A also. A careful mathematical examination of the situ¬
ation, which we cannot undertake here, bears this out. Let us,
however, try to indicate a possible line of analysis*
21 We compare the behavior of a particular Schrodinger wave

function with time in the two cases. Suppose that at time
t = 0 the wave function is identical with the fourth eigenfunction
shown in Fig. 19A, corresponding to the fourth energy level
£4 ^ — 0.16B. We have, in other words,
$(x,0) = <p4(s) (21a)

where the wave function <p4(r) is the wave function represented by
the dotted line about the level of £4 in Fig* 19A* This same wave
function is also shown by a dotted line in Fig* 20A. Note that this
wave function tends to zero fairly rapidly outside the well.
For the problem in Fig* 19A it is easy to solve the time-dependent
Schrddinger equation (3b), subject to the initial condition given
by (21a), Since <pi(*) is an eigenfunction of the Schrtidinger dif¬
ferential operator we simply have
$(x,t) = <p4{ic) exp ( — (21b)
which expresses the stationary nature of ^(ac,f). We may now find

the probability, P(£), that the particle is found within the well:
P(t) = fa dx\ 12 = P(0) (21c)
and, as we see, this probability is independent of the time £, which

again reflects the stationary nature of the wave function ^(x,£).
Note that the integral in (21c) extends over the well only, from
— a to a.
22 If we now try to solve the same problem for the situation

shown in Fig. 20A, i.e., with the same initial condition (21a), then
the solution is not of the form (21b), although one may say that
Sec. 8*23 Theory of Stationary States 325
it is of approximately this form. If we actually find the time-

dependent wave function i//(;t,j) for the problem in Fig. 20A, and
then compute the probability P(t) for finding the particle in the
well, it is possible to show that we have, instead of (21c), an approxi¬
mate relation of the form
P(t) = f dx | ^ (x,t) |z = P(0) exp (- ^) (22a)
where T is a positive constant. We emphasize that the relation

(22a) is an approximate relation: it is valid only for times t which
are not "too large/' The detailed proof of this result would take
us too far, but we shall try to make it plausible.
The interpretation of the result (22a) is that if the particle is
placed “in the well” at time t = 0, with an energy roughly equal
to E4, then the particle will eventually leak out of the well. If T is
large, which is the case when b is large, it takes a long time for
the particle to leak out, and we have an approximately stationary
state. The time T is the mean-life of the state. If we let b tend
to infinity, T will tend to infinity, and we obtain a strictly stationary
state, as in the problem of Fig. 19A. If we let b tend to a, T be¬
comes smaller, and in the limit b = a the “state” of energy E4 loses
its meaning as a quasi-stationary state.
In view of this result we are justified in drawing the fourth energy
level £4 in the term scheme in Fig. 20A within the continuum: it
corresponds to an approximately stationary state. Such levels are
often called virtual energy levels.
The result (22a) can be understood in a qualitative fashion as a
consequence of a barrier penetration phenomenon, like the ones
we discussed in Chap. 7. A particle confined, at an energy £4,
inside the well would stay within the well forever if classical me¬
chanics applied. Within the framework of quantum mechanics
this is not so: the particle can leak through the barriers on both
sides of the well. The wider the barriers the longer it will take,
and the larger will be the constant T. For a very large T the par¬
ticle has to bounce back and forth very many times inside the well,
and the particle behaves approximately as if it were in a stationary
state.
23 In each case in our discussion so far the problem of finding

the stationary states can be regarded as the problem of fitting an
oscillatory wave function between two classical turning points.
For the ground state the wave function has one maximum, and no
node. For the next state the wave function has two extrema, and
one node. Generally the wave function corresponding to the mth
326 Theory of Stationary States Sec, 8.24
state will have m extrema, and (m — 1) nodes* Let us employ the

quantum number n to label the stationary states, where n is the
number of nodes (zeros) of the wave function. The ground state
is thus assigned the quantum number n = 0, and the nth excited
state is assigned the quantum number n. The wave function cor¬
responding to the quantum number n has (n + 1) extrema*
Let us now try to find a method to determine the approximate
energy levels of a particle in a potential valley. For this purpose
we consider Fig* 23A, which shows the potential for a typical
problem of this kind*
The heavy solid line represents the potential* The heavy dashed
line represents the energy, E$t of the sixth excited state, and the
oscillatory dotted line represents the corresponding wave function.
The wave function is drawn only between the turning points xi
and %2 [which are defined by Vfci) = Vfa) = Ee]* Outside this
interval the wave function tends asymptotically toward the axis*
24 Suppose we were to try to represent a wave function of the

kind shown in Fig, 23A by an expression of the form
—J IT 2ir 3T47T57T 6tt — ^)tt <p(x) = A(x) sin [fix)] (24a)

where A(x) is a positive amplitude, and where fix) is a phase func¬
tion which increases monotonically with x. Every time the phase
function fix) assumes a value kvr, where k is an integer, the wave
function has a node. Let us consider the change A/ in the phase
function between the turning points,
4f = ffa) ~ /(*i) (24b)

Looking at Fig* 23A we see that for the wave function shown in
point point
the figure the change in the phase is about (6 + £)ir. We shall
be guided by this suggestive picture and assume that the wave
Fig. 23A To illustrate our discussion of the so-called
WKB-approximation method for finding stationary
function for the nth excited state is such that the phase function
states. To find the (n + l)th state, i.e., the nth ex¬ fix) changes by the amount
cited state, we try to select the energy E such that we
can fit (n + \) N half-waves" between the classical Afn ^ (n + (24c)
turning points. The “local wavelength" at a point
between the turning points.
depends on the total energy and on the potential at
the point. We make the assumption (24c) for convenience, in order to have
The solid curve represents the potential and the a definite formula. If we wish to be more correct we might at most
dashed curve represents the wave function (between state an inequality, namely
the turning points) for the sixth excited state. Values
of the phase^) are shown above the turning points, (n 4- l)ir ^ Afn > nrr (24d)
and above the nodes. In this particular case the total
change in phase (between the turning points) obeys as the reader can easily convince himself* If we look at Fig* 4C
the relation A/^ {« + ±) = (6 + £) m. we see that in that case the upper limit in (24d) is assumed, whereas
Sec. 8.25 Theory of Stationary States 32 7
we are closer to the lower limit for the third excited state in Fig.
19A. The formula (24e) therefore represents a compromise.
25 Let us next try to derive an approximate expression for the

change in phase of the wave function, as a function of the energy
E* Consider first a region in which the potential is constant, and
has the value V. In such a region, and for E > V, the wave func¬
tion is of the form
<p(x) = A sin (25a)
where A and xo are constants, and where
p = — V) (25b)
Comparing (25a) with (24a) we find
fix) = (* - *o) [| (25c)
As we go a distance dx to the right the change in phase, df is

then
dx — — \/2m(E — V) dx (25d)
n
Let us now use (25d) as an approximate expression for the change
of phase with x in the case that V(x) is not a constant, This approxi¬
mation is better justified the more slowly the potential V(x) varies
with position. Within this approximation the total change of phase
Between the two turning points xi and X2 is given by
Let us apply this relation to the case of the (n + l)st stationary

state, of energy E = En, The total change in phase is also given
approximately by (24c), and if we equate the two expressions for
the change in phase we obtain
( dx y/2m[En — V(x) ] s (n + tyrrh (25f)
26 The equation (25f) is an equation by which we can determine

the energy En of the (n + l)st stationary state. To do this we first
find the turning points xi and X2> as functions of the energy para¬
meter £, by solving the equations
V(x±) = V(x2) = E, x2> x! (26a)

We denote the solutions by *i(E) and #2(£)' We next evaluate
the integral
g(£) = f <h \/2m[E — V(x)] (26b)

Jxi(E)
which gives us a function g(E) of E* The energies £w are finally
obtained as the solutions to the equation
g(£) = (n + (26c)
where n — 0, 1, 2, * * . .
The approximate method which we have just found for determin¬
ing the energy levels of a particle in a “potential valley/* like the
one shown in Fig* 23A> is known as the WKB-method. f In many
cases it gives fairly accurate results, and it is always useful when
we try to form a rough idea of the location of the levels* The
nature of the approximation is quite similar to the nature of the
approximation which we made in deriving the formula (36b) in
Chap. 7 for the transmission coefficient of a potential barrier: the
same kinds of integrals in fact appear in both cases.
It is interesting to note that our equation (25f) which we derived
within the framework of wave mechanics, is identical to the so-
called Bohr-Sommerfeld quantum condition of the old Bohr theory.
We thus achieve a certain understanding of why the Bohr theory
sometimes works quite well, and we can also see why the Bohr
theory might sometimes fail badly: the equation (25f) is not
rigorously true but is only an approximate relation*
The Harmonic Oscillator. Vibrational and Rotational

Excitations of Molecules
27 Let us apply our approximation method to one of the most

important eigenvalue problems: that of finding the energy levels of
a one-dimensional harmonic oscillator. For this problem the
potential V(x) is given by
V(*) = | x2 (27a)
where K is the "spring constant.” If the mass of the particle is m,
t Named after C. Wentzel, H. A, Kramers and L, firiUouin. See H* A. Kramers,

“Wettenmeclianik und halbzahlige Quantisiemng,” Zeitschrift fur Fhysik 39* 828
(1926).
Sec* 8.28 ITieory of Stationary States 329
then the (angular) frequency of oscillation, wo, is given within

classical mechanics as
/* -
(27b)
Wo = Vm
To carry out the quantization procedure described in Sec, 26 we
must first find the turning points. They are symmetrically placed
with respect to the origin, and we can write x± = — Xq, = x$r
where, in accordance with (26a), we have
ME) = \f^-, E = |:*o2 (27c)
We next find the function g(E), defined as in (26b) by
Introducing a new variable of integration 8 by x = Xo sin 8 we

obtain
g(E) — 2 \/Km xq2 J d9 cos2 8 = mE
where we have eliminated *o by using (27c). Inserting this expres-

sion for g(E) into (26c) we obtain the very simple result
£w = (ra + £)#wo (27f)

for the energy En of the (n -j- l)st stationary state of the harmonic
oscillator, where n = 0,1, % ..., is any non-negative integer.
28 It so happens that the rigorous solution of the Schrodinger

Term scheme Harmonic oscillator
equation (4b) for the case of a harmonic oscillator, i.e., for a poten¬
tial function as given in (27a), gives precisely the result (27f).
This book is not devoted to the solution of special cases of the
Schrodinger equation, and we will not try to solve the harmonic
oscillator problem rigorously. Due to a remarkable accident our
approximation method actually gives us the correct result, which is
more than we had a right to expect.
Figure 28A shows the term scheme (to the left) and the potential
function (to the right) for a harmonic oscillator. Note the charac¬
teristic equal spacing between the levels. In the figure we have
selected the bottom of the potential well as the zero-point of energy: Fig, 28A The potential (at right) and the term
this is, of course, an arbitrary convention. scheme (at left) for a harmonic oscillator. Measured
from the bottom of the potential “well1’ the energy of
If the oscillating particle carries a charge we can expect radiative the (n + l)st level is given by £* = (« + i)fooo, where
transitions between the energy levels, which, when the radiative un is the classical frequency The WKS-method gives
processes are taken into account, would then no longer be absolutely the same result as the rigorous theory.
stable for n > 0. One can show that the selection rule for electric
dipole transitions is that n changes by one unit. The quantum
emitted must accordingly be of the classical frequency coo for any
transition of this kind. This is also what we would predict on the
basis of classical theory.
29 The theory of the harmonic oscillator is important in physics

because the equations of motion for very many seemingly totally
unrelated physical systems are formally equivalent to the equations
of motion for a system of harmonic oscillators which interact with
each other only very weakly. To a first approximation, in which
the interaction between the oscillators is neglected, the quantum
theory of such systems is mathematically equivalent to the ana¬
lytically very simple theory of a system of completely independent
harmonic oscillators. The latter kind of system is simple to discuss
because each oscillator oscillates by itself as if the other oscillators
were not there, and it is clear that if we can describe one such
oscillator we can describe any number of them.
Term As examples of systems of this kind we can mention the electro¬
magnetic field, an elastically vibrating solid, and many quantum
fields. Furthermore all molecules have vibrational modes which
can be described to a good approximation in terms of the theory of
harmonic oscillators. Quite generally we can say that the harmonic
oscillator theory applies to systems which satisfy linear, or approx¬
imately linear, equations of motion.
30 Figure 30A illustrates the approximately harmonic nature of

an actual molecular linear oscillator, namely the hydrogen mole*
cule. This molecule has modes of excitation in which the two
protons oscillate against each other* These modes may be under¬
stood in terms of an effective internuclear potential, shown in the
right portion of the figure* The graph shows the potential energy
Fig. 30A The right portion of the figure shows the (in eV) of the system as a function of the internuclear separation*
effective internuclear potential LT<r) in the hydrogen The existence of this effective potential, and its functional depen*
molecule, and the left portion shows the correspond¬ dence on the internuclear separation, can be well understood
ing term scheme. For the lowest excited states the theoretically. We shall discuss this potential in the next section,
molecule behaves like a harmonic oscillator. The
To study the vibrational states of this, or any other diatomic mole¬
potential curve near the minimum is of approximately
parabolic shape, and the low-lying levels have roughly cule, we may therefore first find the effective potential, after which
the same locations as for a harmonic oscillator, (See we solve the one-dimensional SchrGdinger equation with this
Fig. 28A,) As the internuclear separation increasest potential to find the energy levels of the vibrational states.
the potential tends to a constant value. The conti n- We have selected the bottom of the potential well as the zero-
uum in the term scheme begins at this level, corre¬
point of energy, just as in Fig. 28A. As the internuclear separation
sponding to the dissociation of the molecule.
The potential [/(r) does not describe a “new” kind r goes to zero we can assume that the potential tends to infinity.
of force: it is the electromagnetic force in disguise. However, as r tends to infinity the potential tends to a constant,
Sec, 8.31 Theory of Stationary States 331
+ 4.8 eV in the figure. At this energy the molecule dissociates, and

the continuum begins, as indicated in the term scheme to the left
in the figure. The potential energy is therefore not identical with
the potential energy of a harmonic oscillator, but if we do not go
too high above the bottom of the potential well the curve has an
approximately parabolic shape. In fact any smooth curve with a
minimum* and a non-vanishing second derivative at the minimum,
has an “approximately parabolic shape” in the neighborhood of the
minimum. We can therefore expect the system to behave* for
not-too'high excitations, approximately like a harmonic oscillator.
We can see the difference between a true harmonic oscillator and
an approximately harmonic oscillator by comparing Figs. 28A and
30A, The levels are not equally spaced in the term scheme in Fig.
30A, but for small excitations they are approximately equally
spaced. Furthermore there is only a finite number of vibrational
states of a molecule.
The dissociation energy of the molecule is the energy which has
to be supplied to the molecule in its ground state to bring about
dissociation. From Fig. 30A we find that the dissociation energy
of the hydrogen molecule is about 4.5 eV: this is the energy differ¬
ence between the lower limit of the continuum and the ground
state.
When the molecule is in its ground state* the mean separation
between the nuclei (protons) is about 0.75 A: the ground state wave
function is clearly concentrated about the value of r corresponding
to the minimum of the potential.
31 Let us now discuss the meaning of the effective intemuclear

potential shown in the right part of Fig. 30A. We are led to this
potential in an approximation scheme for the study of molecular
structure, known as the Bom-Oppenheimer approximation. The
idea is the following. Since the nuclei (protons) are so much more
massive that the electrons they will move, in the molecule, with a
velocity which is small compared to the velocity of the electrons.
In a first approximation we can assume that the nuclei do not move
at all, but stay at a fixed separation r0 from each other. To be
specific we shall discuss the hydrogen molecule, but similar con¬
siderations apply to other molecules as well. The problem to solve
in this first approximation is then to find the ground state of the two
electrons in the electrostatic field of the two protons. Suppose that
we solve this problem for an arbitrary intemuclear separation r,
in which case we find the ground state energy I7(r) of the system,
ie., including the electrostatic energy of repulsion between the two
protons, as a function of r. For very small r the energy £7(r) is
large and positive, because the electrostatic energy of repulsion

between the two protons tends to + oo as the separation r tends to
zero* For very large r the energy U(r) tends to a constant value*
Ux., which is the ground state energy of two hydrogen atoms
infinitely far away from each other. It so happens that there is a
range of values r for which U(r) < Uas shown in Fig. 30A. The
function [7(f) has a minimum at the point ro = 0*75 A. The lowest
possible energy of the molecule, under the assumption that the
protons do not move* is thus l/(ro), and in this first step in the Bom-
Oppenheimer approximation this is the ground state energy of the
molecule,
32 However, the protons do move, and in the next step in the

Born-Oppenheimer approximation this motion is taken into ac¬
count, This is done by assuming that the protons oscillate against
each other, about the “equilibrium separation" % In this (slow)
oscillatory motion (which must, of course, be described quantum
mechanically) the effective potential energy is given by the function
U(r\ found in the first step of the approximation scheme.
The function f/(r) is thus the effective potential energy in the
second step in the Born-Oppenheimer approximation* in which the
oscillation of the two protons against each other is taken into
account* The fundamental interaction in terms of which we are
to understand molecular structure is thus the electrostatic inter¬
action between the four charged particles in the hydrogen molecule.
The effective potential I7(r) arises as a consequence of this funda¬
mental interaction, and it therefore does not describe some new
kind of force* We can say that it is the electrostatic force in dis¬
guise* This is an important point to understand.
33 The problem of how to find U(r) explicitly is beyond the scope

of this book. Let us, however, try to understand, in a very qualita¬
tive fashion, how it is that f/(r) can have a minimum. To do this we
must convince ourselves that there are configurations of the parti¬
cles in the molecule for which the electrostatic energy is smaller
(i.e., more negative) than for two infinitely separated hydrogen
atoms, although the electron-proton distances are not smaller in the
molecule than in the atoms. This is certainly a necessary although
not a sufficient condition for molecular binding.
Consider the configuration shown in Fig. 33A in which the two
electrons and the two protons are placed at the vertices of a square
of side length a. The lines symbolize the electrostatic interactions
between the six pairs of particles. For this particular configuration
the total electrostatic potential energy £p01 is given by
Sec, 834 Theory of Stationary States 333
Electron
EU = + 2^-4^ = ^(VS-4) (33a) —e
aV2 a a
This potential energy should be compared with the total potential
energy £p0t of two hydrogen atoms separated by a very large
distance from each other. This potential energy is given by
E'm = (33b)
where ao is the Bohr radius- In the particular case that we select

a = ao, the difference of the two quantities E'vot and £p0t is nega¬
tive, be,,
2 Fig. 33A If a = In the above configuration the
A4ot = Epot - Epot = — (V2 - 2) = - 1.2R. (33c) potential energy will be smaller than the totaJ poten¬
Oq tial energy of two hydrogen atoms separated by a large
distance. The electron-proton distances are then the
where Rw is the Rydberg constant, R* = e2/(2a0) = 13*6 eV. same for the above “molecule" as in the hydrogen
We have thus found a special configuration for which AEpot is atom, and we can think about the configuration as
negative* It is clear, however, that there are “neighboring” con¬ arising when two hydrogen atoms come together.
figurations for which AEpot is likewise negative; it is not necessary This example shows that the force between two hydro¬
gen atoms might be attractive, but it does not in any
that the particles be at the vertices of a square. way prove that a stable molecule can in fact exist.
34 The total energy of the hydrogen molecule is the sum of the

potential energy and the kinetic energy. If we now recall our
discussion in Sec. 14, Chap, 6, of the implications of the uncer¬
tainty relation for the structure of the hydrogen atom, we realize
that the electrons in the hydrogen molecule must be given "enough
space” within the molecule* because otherwise the uncertainty
relation requires their momenta, and thereby their kinetic energies,
to be large. In our discussion of the hydrogen atom we concluded
that if the uncertainty in the position of the electron is of order ao,
which means that it “occupies” a region of Linear size «o? then the
kinetic energy will be of order R„. The same considerations apply
to the hydrogen molecule: if the kinetic energy is to be of this order
of magnitude we must allow the electrons to occupy a region of
size Oq.
To proceed further we would have to experiment with various
regions of confinement for the electrons, and for each choice we
would have to compute the potential and kinetic energies, taking
into account the requirements of the uncertainty principle, TTiis
is a bit involved, and we shall not attempt to do it here. The best
way of attacking this problem is to try to invent suitable wave
functions which describe both electrons, and then to compute the
total energy for these wave Junctions in accordance with the
Schrddinger theory. Since we have not discussed two-particle
wave functions we are not prepared to try this approach.! In view

of what has been said the reader is perhaps prepared to believe
that a minimum exists for the total energy t7(r) as a function of the
intemuclear separation r. Just as in our discussion of the hydrogen
atom the minimum in the energy results from a compromise: the
electrons must be allowed enough space so that the kinetic energy
can be kept small* but yet be confined to a small enough region
for the potential energy to be appreciable. Roughly speaking the
total potential energy is negative and inversely proportional to the
“size” of the molecule, whereas the total kinetic energy is positive
and inversely proportional to the square of the size. For some
optimal size of the molecule the sum of these two contributions to
the energy will have a minimum.
35 Let us now try to estimate the “typical” vibrational frequen¬

cies in a (diatomic) molecule. The potential curve is approximately
parabolic in the neighborhood of the minimum (at r = r0)s and we
can try to represent the potential function E/(r) by the expression
r - r0
U(r) + U(r0) (35a)
( flo -y
This is a reasonable guess. For r = r<> the right side assumes the
correct value E7(ro). For |r — Tq\ = ao the potential is larger than
t/(ro) by the amount Rw. Since the size of a molecule is of order
oo» and since the binding energy is of order R.*, we would expect
the potential to behave roughly in this manner.
The right side in (35a) is the potential for a harmonic oscillator,
The “spring constant” K for this oscillator is given by
2RW a2mc2
(35b)
Qq2 do2
Suppose that the effective mass of the oscillator is M, The vibra¬

tional frequency of the molecule is then given by
= (35c>
where we have inserted the expression ao = OL^ftfmc) for the

Bohr radius. We emphasize that the estimate (35c) is only a crude
order of magnitude estimate.
In our discussion in Chap. 2 of characteristic magnitudes in
fThe first satisfactory theory of molecular binding was presented in W, Heitler

and F. London, “Wechselwirkung neutraler Atom? und homtiopolare Bindung nach
der Quantenmechanik,” Zeitschrift far Physik 44, 455 (1927).
atomic physics we concluded that we can regard the quantity TABLE 35A Vibrational Frequencies of
Selected Diatomic Molecules
(35d)
Frequency Wave number
Molecule cycles/sec cm
as a “typical” frequency associated with optical transitions in an
atom or molecule; i.e., transitions in which the electronic con¬ c2 4,921 x 1013 1641.35
figuration changes. We can then write (35c) in the form n2 7.074 x 1013 2359.61
Os 4.374 x 1013 1580.36
NO 5.708 X 1013 1904.03
(35e) CO 6.506 X 1013 2170.21
IBr 0.805 x 10” 268.4
The quantity M is for all molecules of the order of a nuclear $2 2,176 x 1013 725.68
mass, whereas m is the electronic mass. The “typical” electronic
frequencies, (Ce> lie in the visible region of the electromagnetic
spectrum. As we see the “typical” vibrational frequencies of
molecules, are smaller by the factor They will thus be
found in the near infrared region, and this prediction is in accor¬
dance with observations*
36 Let us find the effective mass M explicitly for a diatomic

molecule, in which the masses of the two nuclei are Mi and M2*
The two nuclei oscillate against each other, in such a way that the
center of mass lies on the line joining the two nuclei. Let r be the M2r
internuclear separation, and let ri and r2 be the distances of the Ml + M2
two nuclei from the center of mass, as indicated in Fig. 36A, The
kinetic energy of this system is then given by
Mxt
T= W = *(m7Tk) * <“■> Ml + M2
where the dots indicate time derivatives. The potential energy of
the oscillator is given by (35a) as a function of f, and the kinetic
energy is given by (36a) as a function of r. The effective mass M
of this oscillator is then the coefficient of fi/% i.e.,
M1M2 Fig. 3ftA Schematic representation of a diatomic

(36b) molecule. The masses of the nuclei are Afi and M2.
Mi + M2
The small white circle on the line joining the nuclei
and this is the expression which should be inserted into (35c). The indicates the center of mass of the system. In the
text we consider vibrational excitations in which the
quantity M is known as the reduced mass of the two-body system.
nuclei oscillate against each other.
37 Since we do not have available a precise expression for the

“spring constant” K, which we estimated in Sec* 35, we cannot
find the precise vibrational frequency of the diatomic molecule.
We can, however, make precise predictions concerning the isotope
effect. Consider first a molecule in which the nuclear masses are
Mi and M£, and the vibrational frequency Consider next an
336 Theory of Stationary States Sec, 8,38
otherwise identical molecule, i.e., a chemically identical molecule,

except that we substitute other isotopes, of masses M{f and M#, for
the original nuclei. Let the vibrational frequency for this molecule
be The spring constant K is the same for both molecules (within
the Bom-Qppenheimer approximation), because we found the
effective potential l/(r) by ignoring the nuclear motion. It follows
that the frequencies wi and must be related through
+ M£)
(37a)
teg V + Mg)
This prediction has been found to correspond quite accurately

to observations. That this is so increases our faith in the essential
correctness of the simple ideas which we have presented*
38 Let us now consider the rotational excitations of a molecule1.

With every molecule there is associated a system of discrete rota¬
tional states of the molecule, in which the molecule rotates as a
whole about some axis. Let us try to estimate the order of mag¬
nitude of the energy differences associated with rotational ex¬
citations.
For simplicity let us consider a diatomic molecule, as shown
schematically in Fig. 36A. Let us assume that in a particular rota¬
tional state the molecule rotates with an angular velocity about
an axis passing through the center of mass of the molecule and
perpendicular to the symmetry axis of the molecule, i.e. to the line
joining the two nuclei. We neglect for the moment the vibrational
motion, and we thus regard the molecule as a rigid “dumbbell.”
With the notation of Fig. 36A the speed of the nucleus 1 is then
toari and the speed of the nucleus 2 is war3. The kinetic energy Tt
of the rotational motion is thus given by
Tr = iAfi(co0ri)2 + W2{<eQr2}2 (38a)

Expressing and f2 hi terms of the masses Mi and M2i and in
terms of the internuclear separation r, as in Fig. 36A, we obtain
t-=*(»£+*) (“-r)2=m“-rf <3ab)
where M is the reduced mass of the molecule, as defined in Eq.

(36b),
The moment of inertia, J, of the molecule with respect to the
axis of rotation is given by
I = Mifi3 + M2r22 — Mr2 (38c)

Let us also find the angular momentum / of the molecule with
Sec. 8.39 Theory of Stationary States 337 ? = 7
respect to the axis of rotation. It is given by
/ = Miri2Wa + M2r22o>a = Mr2ua = Iwa (38d)
We can then write the kinetic energy of the molecule in the form 6 r1
Tt = £ (38e)
where we have eliminated the angular velocity <oa from the express D i
sion (38b) by the use of the relations (38d),
39 We can guess that the angular momenta which we encounter

in molecules will be typically of the order of ft. It follows that the 4
typical energies associated with rotational excitations will be of the
order of magnitude
3
(39a)
Denoting the corresponding frequency by wr we can write
Tr % 1
03r
a 27 0
Fig* 39A Term scheme showing the eight first rota¬
According to (38d) the angular momentum is given by J — 7<oa,
tional energy levels of a diatomic molecule (regarding
and since we assumed J — H it follows that wa — fi/7. The angular the molecule as a rigid dumbbell). According to Eq.
velocity and the characteristic rotation frequency defined (39c) the energy E* of the state of angular momen¬
by (39b) are thus of the same order of magnitude, as we would tum f is given by Ej = + l)t where B = fi2/{21)
expect on the basis of a classical model. is the rotationa/ constant of the molecule. The ver¬
tical arrows show electric dipole transitions in which /
The complete quantum-mechanical theory of the dumbbell
changes by one unit.
molecule leads to a very simple formula for the energy levels. Each
rotational state is characterized by a non-negative integral value
of the angular momentum quantum number j, and the energy of
the state is given by TABLE 39B The Rotational Constant Be for
Selected Diatomic Molecules
* _ id +1)*2
*** — - (39c) Be r
Molecule (Mc/sec) (A)
where / = 0, 1, 2, 3.Although we shall not derive the
formula in this book, the author felt it was worthwhile to quote it BrF 10700 1.76
KCI 3800 2.79
anyway.
KBr 2400 2,94
C12013 57900 M3
40 The separation between the nuclei in any molecule is of the OH 566000 0.97
order of the Bohr radius We thus estimate the moment of NO 51100 1,15
inertia as 7 ~ Mao2, and if we insert this expression for 7 into (39b)
The constant B (see Fig. 39A) is here expressed in
we obtain
terms of the corresponding frequency Be = B/k =
&/(8ffai), in megacycles per second. The third column
(40a) gives the internuclear distance t.
2Ma02
It is instructive to rewrite this estimate in terms of the character¬

istic electronic frequency o>e = ct2(mc2/jf). Since the Bohr radius
is given by a<> — ar^H/mc) we can write (40a) in the form
as an order of magnitude estimate* (Factors of two are, of course,

immaterial in such an estimate*)
Let us compare the characteristic rotational frequencies with the
typical vibrational frequencies which we estimated in Sec* 35.
Combining the estimates (35e) and (40b) we can write
: o>r ~ 1 : yJm/M : (m/M) (40c)

Here coe is the “typical” electronic transition frequency, the
To microwave detector "typical” vibrational transition frequency and the "typical”
and output meter
*
rotational transition frequency. As we see, the rotational transition
frequencies are much smaller than both the electronic and
vibrational frequencies. They lie in the far infrared (microwave)
tttmtt region,
■ ■r.1
■ ■'
?h'.V
■hi
J i 41 The key idea in the complete explanation of the very com¬
Waveguide^ Gas inlet plicated optical band-spectra emitted by molecules is the idea that
■1 -11 * m 4 . VI
"
vm every molecule has three different kinds of excitations: electronic

m excitations characterized by the electronic frequency vibrational
F^v-v: excitations characterized by the frequency wVi and rotational
excitations characterized by the frequency If we oversimplify
the situation we can imagine that we have three systems of energies
corresponding to the three different kinds of excitations. The
*
energy of a stationary state of a molecule is thus a sum of three
terms: an electronic term, a vibrational term and a rotational term.
From microwave source
In making transitions between the various possible energy levels
of variable frequency
the molecule emits or absorbs photons. In an optical transition the
electronic state (configuration) of the molecule changes, and in
Fig* 41A Very schematic representation of an ar¬ general the vibrational and rotational states will also change at the
rangement which may be used in microwave spec¬ same time. The number of possible transition frequencies is
troscopy- The molecules to be studied are present therefore very large, and the spectrum shows bands consisting of
in the form of a gas which fills a portion of a wave
extremely closely spaced lines. (See Fig* 6B, Chap, 3, for an ex¬
guide. Radiation (in the microwave region) passes
through the wave guide, and the amount transmitted ample.)
is measured by the detector and output meter. At It is possible to study the vibrational and rotational spectra
the resonant frequencies of the molecule the gas ab¬ separately, i,e,, to study transitions in which the electronic state of
sorbs the microwave radiation, and by measuring the the molecule does not change. After the Second World War new
absorption as a function of the frequency the locations
of the resonant frequencies can be determined.
methods for this study were introduced and microwave spectros¬
By the JJmicrowave region" is understood the wave¬ copy became established as a branch of ♦ spectroscopy comple¬
length region roughly between 1 mm and 1 meter. mentary to the older branch of optical spectroscopy.
Sec* 8A2 Theory of Stationary States 339
Scale
Spectrum IQ me
under low resolution
Theoreticof pottern
due to CJ quadruple done
Spectrum under
high resolution
Theoretical pottern
indudrng N r—r-4+ It
quadrupole effects X-XJ ii|i iL_f X X 4-4
; XX
LX%~XX ! XX
H-XX
, - XX ■
XX
V/2*V/2-ljj \ X sniXX-% % -J <~Xh~XX XX I
XX*XX~‘\ XVXX '4 %■*% X
X%
X V1 t XX
X X~X %-i
and ^ ^2' Ji [X %-%X -i X H
\XX-1>XX
Fig* 41B Microwave spectra under low, and under

Hydrogen-like Systems high resolution, showing the/ = 1 to / = 2 transition
in the triatomic molecule CIMClsNw, As we see, this
42 Let us now consider a three-dimensional problem, namely microwave transition "line" exhibits a fine structure;
the problem of finding the energy levels of the hydrogen atom* We it consists of several closely spaced components. The
frequency of the central peak is 23883,30 mega¬
shall not really solve this problem in this course, but it will be cycles/sec. The jagged curves show what is actually
illuminating to consider some aspects of it* measured; the absorption of microwave power as a
Let us actually consider a somewhat more general problem* A function of frequency.
particle of mass m, and charge — e, moves in the electrostatic The lower spectrum gives a good picture of the high
precision which can be achieved in microwave spec¬
potential due to a nucleus of charge +eZ* We shall assume that
troscopy. Note also how well everything can be ac¬
the nucleus does not move, but stays fixed at the origin* Actually counted for theoretically.
the nucleus would stay fixed only if it were infinitely heavy. How¬ This figure appears on page 171 in C* H* Townes
ever, if the ratio M/m of the nuclear mass M to the “electron* and A, L. Schawlow, Microwave Spectroscopy
mass m is very large, we can, in a first approximation, regard the (McGraw-Hill Book Co., New York, 1955), See also
nucleus as being infinitely heavy* C. H. Townes, A. N, Holden and F. R. Merrit, "Micro-
wave Spectra of Some Linear XYZ Molecules," Phys¬
The time-independent Schrodinger equation for our problem is ical Review 74,1113 (1948). (ff/ustrat/on by courtesy
then of the form of Professor C. H. Townes, Berkeley.)
e2Z
V2 <p(x) <p(x) = E<p(x) (42a)
2m
where x =
Let us introduce the new independent variable y by
a
x = where a = (43a)
mcaZ he
and let us also introduce a new “energy parameter'* A by
E = (aZ)2mc2\ (43b)
n = oo OeV
tt5* 5 0.54 eV as well as the wave function/(y) defined by
n=4 0.85 eV
n bs 3 1.51 eV <p(x) = /(y) (43c)
Paschen
series
Brackett Rewriting the differential equation (42a) in terms of our new
series variables and parameters we obtain
n=2 3.39 eV
Balmer First excited
series state
- \^v2 f(y) --Ky) = M(y) (43d)
57
where Vv2 stands for Laplace's differential operator with respect to

the variable y.
ii The equation (43d) is the “dimensionless form” of the Schro-
i
Lyman
dinger equation (42a). It is dimensionless in the sense that the
series physical constants m, e, h, c, and Z no longer appear in it. If we
can solve (43d) we can re-introduce the old variables by making use
of Eqs. (43a) to (43c) and the two equations (43d) and (42a) are
clearly completely equivalent.
44 We are thus faced with the purely mathematical problem of

solving the equation (43d), We shall not solve this problem but
n =1 13.6 eV merely give the results, which are as follows:!
Ground state
L The Schrodinger equation (43d) has square-integrable solu¬
tions only when the parameter A is of the form
Fig. 45A Term scheme of the hydrogen atom. To
a very good approximation the energy En of a level of 1
(44a)
principal quantum number n is given by En = —KH/n2r t 2n2
where flH = (1 + m/Mp)-1/?* — 13.5976 eV.
The vertical lines indicate possible electric dipole where n is any positive integer. This integer is called the principal
transitions. These transitions have been arranged quantum number of a hydrogen-like atom. (It should not be con-
into four series, named after early workers in spec¬
troscopy. The Lyman lines all lie in the ultraviolet
region. The Balmer series lies in the visible region. I The solution for the hydrogen problem is naturally derived in every advanced or
See Fig. IB, Chap. 3t for the appearance of the visible intermediate book on quantum mechanics. It was first presented by Schrodinger in
hydrogen spectrum, and for wavelengths of some of his first paper on wave mechanics: "Quantisierung als Eigenwertproblem, Annalen
the Balmer lines. der Physik 79, 361 (1926).
fused with the quantum number n which we introduced in our dis¬ $ p d f g

cussion of the quantum mechanical oscillator.) 1=0 1=1 1=2 l=3 1=4
IL The continuum begins at X — 0. It follows, in view of (43b),
that the atom is ionized above the energy E = 0. %
IIL For any given value of n, and with X ^ Xn, the differential
equation (43d) has n3 linearly independent solutions. These solu¬
tions can be classified with the help of a quantum number l which
describes the spatial symmetry properties of the wave functions.
For example, all the solutions for which l = 0 are spherically sym¬
metric. The quantum number l ranges for 0 to (n — 1), and for
each pair (n,l) the equation has (21 + 1) linearly independent solu¬
tions which correspond to different orientations of the atom. The
quantum number l can also be given the physical interpretation
that it measures the angular momentum of the atom, and it is there¬
fore called the orbital angular momentum quantum number, f
45 In view of these mathematical facts we can now conclude

that the possible energy levels of the atom (in its non-ionized state)
are given by
£„= (^) (45a)
To satisfy the curiosity of the reader we wish to quote one ex¬

plicit solution of the Schrodinger equation (42a), namely the wave
function for the ground state. In this case we have n = 1, and
consequently l = 0, which means that the wave function is spher¬
ically symmetric. Explicitly the wave function is given by
<Pio(x) = (45b)
where ao — Ji/(mca).
The reader may wish to verify for himself that the wave function
<Pio(x) does satisfy the wave equation (42a), and that it is normalized
to unity, which means that the integral over all of space of the Fig* 45B Term scheme for a hydrogen-like atom.
square of the wave function equals unity. The levels have been arranged into columns corre¬
sponding to different values of the orbital angular
momentum quantum number l All electric dipole
46 Our discussion so far has been based on the assumption that
transitions between levels ot principal quantum num¬
the nucleus remains fixed at the origin. We can very easily general¬ ber four or less are shown. In such transitions l must
ize our discussion to the case when the nucleus also moves. Let the change by one unit. Note that the state 2s cannot
nuclear mass be M, and let the mass of the electron be m. The decay by an electric dipole transition: the level is
reduced mass /a of the nucleus-electron system is then given by metastable.
The above term scheme should be compared to the
alkali term schemes in Figs. 28A and 32A, Chap. 3.
t Compare vvith the discussion in Secs. 30-31 and 54, Chap. 3. There are many similarities.
342 Theory of Stationary States Sec* 8*47
^ H1+sr
in accordance with our discussion in Sec, 36,
<**
The problem of studying the motion of two particles in their
center of mass system, moving under the influence of a force
describable by a potential which depends only on the distance
between the two particles is completely equivalent to the problem
of studying the motion of a single (fictitious) particle, carrying the
reduced mass of the system. This particle moves in sl fixed potential
field of force, described by the original potential as a function of
the separation of the particles. In order to take the nuclear motion
into account we must thus replace the mass m everywhere in our
formulas by the reduced mass ju. The energy levels of the system
are given by
£*= (46b)
We can also write this as
<46c)
where is the Rydberg constant
= ia2me2 = 13,6 eV (46d)

We should note immediately that in the case of the hydrogen
atom (for which m/M ^ 1/1836) the reduced mass is very close to
the electron mass. As we can see from Eq. (46a) the difference
amounts to about 1 part in 2000.
Let us also note that the reduced mass for the deuterium atom is
not identical with the reduced mass for the hydrogen atom, and for
this reason the deuterium spectrum differs slightly from the hydro¬
gen spectrum. (See Prob. 7, Chap. 2.) Hie difference is easily
observed spectroscopically.
47 Our formulas (46c) describe the energy levels of “hydrogen¬

like systems” in general, by which we mean bound systems of two
oppositely charged particles, provided that the binding is due only
to the Coulomb attraction between the particles. Setting Z = 2
in (46c) we obtain the energy levels of singly ionized helium, and
setting Z ^ 3 we obtain the energy levels of doubly ionized lithium.
The correct reduced masses, which are very dose to the electron
mass, are obtained from Eq. (46a), where M stands for the mass
of the helium nucleus, or the lithium nucleus.
Sec. 8A8 Theory of Stationary States 343
“Atoms'* in which an electron is replaced by a muon (mu-meson)

are known as muonic atoms. They are formed when a negative
muon is captured by the Coulomb field of a nucleus as the muon is
being slowed down in bulk matter. Let us first note that the Bohr-
radius of an "atom'* is inversely proportional to the mass of the
“electron/* This means that a muonic atom must be about 200
times smaller than an ordinary atom, because the muon mass is
about 200 electron masses. Suppose now that a muon is captured
by* say, an aluminum atom. Through emission of electro-magnetic
radiation the system rapidly goes into a state in which the muon
is very close to the aluminum nucleus: i,e., the muon wave packet
is much more concentrated around the nucleus than the wave
packet of the electrons. The muon and the aluminum nucleus then
form a small muonic atom inside the electron “cloud/* and this
muonic atom is clearly a hydrogen-like system.
That muonic atoms indeed form in the manner described has
been proved experimentally through the observation of the electro¬
magnetic radiation emitted by these “atoms/7 f This radiation
always lies in the X-ray region, as we can see by considering (46b):
the reduced mass is in this case close to the muon mass*
One of the subheadings in Chap* 5 was: “There is but one
Planck's constant/* We note here that the experimental verifica¬
tion of the theoretical prediction for the energy levels of muonic
atoms is a very good piece of evidence for the universality of the
de Broglie relation,
48 Let us summarize our discussion of hydrogen-like “atoms7* as

follows. The system consists of two particles, one of charge — e,
and one of charge + eZ. Without explicitly solving the two-
particle Schrodinger equation which describes the system (and
which we have not even written down), we can conclude that its
discrete energy levels are given by
En = (aZ)2 (fie2) \ (48a)
where ju is the reduced mass, a the fine structure constant, and

where the dimensionless numbers \n are the eigenvalues defined by
the dimensionless one-particle Schrodinger equation (43d), To
find the numbers is a purely mathematical problem which we
have left for a later course* although we have revealed that these
numbers are in fact given by = — l/(2n2).
In other words: if we know the hydrogen spectrum we also know
f V. L. Fitch and J. Rainwater, "Studies of X-rays from Mu-Mesonic Atoms/" The

Physical Review 92, 789 (1953).
344 Theory of Stationary States Sec* 8.49
the spectra of deuterium* singly ionized helium* doubly ionized

lithium, and of all the muonic atoms in which one muon is bound by
the electrostatic field of any nucleus* This is so because we were
able to find out how the energy levels must depend on the relevant
physical parameters such as the charge number Z, and the masses
of the two particles. Our discussion iDustrates the power of simple
dimensional arguments.
Advanced Topic: The Position and Momentum Variables

in the Schrodinger Theory t
49 ^.et us now try to find* within our simple Schrodinger theory*

the mathematical objects which in quantum mechanics play the
role of the classical position and momentum variables*
Let ^(x,£) be a Schrodinger wave function* which is normalized
to unity. In this and the next sections we are going to consider
the wave function at a fixed instant of time f; therefore we may
suppress the time variable* and write i^(ac) for brevity.
Since | ${x) |2 is a probability density which defines a probability
distribution in the physical observable x, the averages of x and x2
must be given by
Av (x) = = = / dxx\\p(x) (49a)

J—Vi
Av (x2) = f
J—®
dxx2 |i//(x)|2 (49b)
The notation {^|x|^)s which is read “the expectation value

of x for the state is very commonly employed in quantum
mechanics*
Now* if 3P denotes the average of x we define the uncertainty
m x, or the root-mean-square deviation of x, by
(49c)
or
(Ax)2 = j dx (x — S)2 | i//(x) |2
= Av (x2) — 2x Av (x) + E2 (49d)
from which it follows that
t Can be omitted in a first reading.

Sec. 8,50 Theory of Stationary States 345
(Ax)2 = Av ^(x — x)2j = Av (x2) — [Av (x) ]2 (49e)
We note that the more concentrated the wave function i//(x) is

about the mean position x, the smaller is Ax, A state for which
the position is precisely known, i.e«, for which Ax = 0, cannot be
realized physically-
The average of any function of x is computed in analogy with
the formulas (49a) and (49b) which give the averages of x and x2.
In particular the average of the potential energy is
Av (EPot) - Av (V(x) U <iH Vfx) I *)
= / dx V(x) | iP(x) 12 (49f)

J—
50 Let us think very carefully about what the above really means.
The probability interpretation of the Schrodinger wave function
farces us to define the average of the position variable x as in Eq*
(49a). The integral in the right-hand side of this equation thus
permits us to find the numerical value of the average of the
quantummechanical position variable x, given the wave function
which describes any particular state of the particle. But what is
the numerical value of the ^quantum-mechanical variable x itself ”?
The answer is that a quantum-mechanical variable does not have
a numerical value: it is defined only in terms of a procedure whereby
its average can be computed for any given wave function.
The position variable x is a particularly simple variable in the
Schrodinger theory, and for this variable the full implication of
the basic principle that quantum-mechanical variables are defined
through their averages (for all states) is not immediately obvious.
The symbol x also occurs as an independent variable in the wave
function, and therefore the definition (49a) might not strike us as
being particularly profound* Consider, however, the quantum-
mechanical momentum variable (which we shall denote by p). The
symbol p does not “occur” in the wave function, and in view of
this we may at first wonder whether a momentum variable “exists”
at all. To settle this question we shall define the quantum-
mechanical momentum variable p through a definite prescription
whereby the average of p can be computed for any given state.
The real problem is therefore whether we can define the average
momentum in a physically reasonable way,
51 To orient ourselves we first consider a wave function, nor¬

malized to unity, which over a very large interval is of the form
i^(x) = C exp (ixp'/fi). Outside this interval the wave function
tends to zero. For such a wave the average momentum must be

very dose to p\ and we may write Av (p) ^ p'. In the interval
mentioned above we have
*K*) = pW*)
and, since the wave function is normalized to unity, we have
dx$*(x) 4>(x) (51b)
We have here assumed that most of the contribution to the

integral comes from the region in which (51a) holds. For a wave
function of the special form considered we may thus find the aver¬
age momentum by evaluating the integral (51b), We shall now
assume that this integral gives the average momentum exactly, for
all (normalized) wave functions. We thus postulate:
Av (p) = | P \ V') = [ dx x^*(x) ^(x) (Sic)
for every normalized Schrodinger wave function i£(a:), This means

that in the Schrodinger theory the momentum variable p is repre¬
sented by a differential operator which acts on the wave function
standing to the right of it in the integral in Eq, (51c), In other
words:
p = (51d)
dx
52 The square of the momentum variable is then represented by

the differential operator
P2 = -*2 § (52a)
and the average of the square of the momentum is given by
Av (p2) s | p21 *) = J ” dx r(x) (-*2§) iK*) (52b)
In complete analogy with the formulas (49c) to (49e) we define

the uncertainty Ap in p, by the equations
Ap = vAv f(p - p)2j (52c)
(Ap)2 = Av ^(p — p)2 j = Av (p2) — [Av (p)]2 (52d)
where p = Av (p).
Notice that the same argument which led us to define the average
momentum as in Eq* (51c) applies to the definition of the average
of p2, as in Eq* (52b)*
53 If we now look at the expressions (49a), (49b), (49f), (51c) and

(52b) we discover a common element: the average value of a
quantum-mechanical variable Q is given by an expression of the
form
Av (Q) = (i I <31 *) = r dx r(x)Q *(x) (53a)
where Q is either a differential operator acting on the wave funo

tion standing to the right of it, or else just x, or x2 or some other
function of x♦ This is in fact the general scheme according to
which quantum-mechanical variables are defined (in the Schro-
dinger theory); the average of the variable Q is given by an expres¬
sion such as the right-hand side of Eq. (53a) where Q is a suitable
linear operator acting on the wave function standing to the right
of it, (For the position variable the linear operator is simply
“multiplication by x,”) Furthermore: the average of Q2 is obtained
by replacing Q in the integral by Q2> where {?fy(x) k what we
obtain if we let Q act twice on tp(x).
54 We illustrate these ideas through further examples. Let the

mass of the particle be m. The kinetic energy, of the particle
is then described by the differential operator
- iL- (54a)
2m 2m dx2
The total energy of the particle is described by the operator H,

which is the sum of the operators describing the kinetic and poten¬
tial energies. In the Schrodinger theory the energy operator H is
thus a differential operator:
fl=l;+vw=-isiiP + vw
in accordance with our discussion in Sec, 10 of this chapter.
55 The reader should note that up to Sec, 51 we have been vague

about what we mean by the momentum in the Schrtidinger theory.
As long as we deal with a wave of the form exp (tip/fi) it is clear
that the p occurring in the exponent is the momentum. We must,
however, define the momentum generally, for aU (normalized)
Schrodinger wave functions, and this is precisely what we have
done through the relations (51c) and (51 d).
We may wonder whether the momentum could have been de¬

fined differently. A careful examination of this point shows that
our definition is essentially unique in the sense that it is demanded
by the requirement that our chosen momentum variable shall have
a sensible physical interpretation in accordance with our notion of
momentum in classical physics.
56 The plausibility of the definition (51c) of the average momen¬

tum can be tremendously strengthened by the following theorem,
due to P. Ehrenfest, which we shall state, but not prove here:f
The averages of the quantum-mechanical variables satisfy the
same equations of motion as the corresponding classical variables
in the corresponding classical description. Specifically this theorem
says that
cl Av ^ = m Av ^ (56a)
|av(p) = -Av(^») (56b)
provided that the Schrodinger wave function, i//(i,£), with respect

to which the above averages are computed* satisfies the Schrodinger
equation
= m (56c)
ot
where H is the differential operator given in Eq. (54b),

The Schrodinger wave function ^(^t) depends on the time £,
and this time-dependence is described by the Schrodinger equation
(56c), It follows that the averages of x and p will also depend on
the time, and one may show that the equations (56a) and (56b)
must hold. The proof is not particularly difficult. We carry out
the time differentiations inside the integral which defines the aver¬
age in question. We then eliminate the time derivatives of yp and
by making use of the Schrodinger equation (56c) and its complex
conjugate form. Rearranging the terms through integration by
parts we obtain the results stated in equations (56a) and (56b), The
interested reader may wish to carry out this process in detail at
this point: we shall not give the detailed proofs as they are a bit
tedious,|
f P. Ehrenfest, "Beinerkung iiber die angeniiherte Giiltigkeit der kkssischen Mecha-

nik innerhalb der Quantenmechanik,” Zeitschrift fur Physik 45* 455 (1927),
| The reader will find proofs in E. Merzbacher, Quantum Mechanics (John Wiley
and Sons, New York, 1961), p. 41, and L. L Schitf, Quantum Mechanics, 3rd ed.
(McGraw-Hill Book Co., New York, 1966), p. 28.
Sec, 8.57 Theory of Stationary States 349
57 The theorem which we just stated, and which can be gener¬

alized without difficulty to the three-dimensional case, is of great
importance for our conceptual understanding of quantum mech¬
anics, It explains why classical mechanics can be regarded as a
limiting case of quantum mechanics whenever the uncertainty in
the variables, i.e., the statistical spread in the variables typical for
quantum mechanics, can be ignored. We wish, of course, to have
this kind of correspondence between classical and quantum mech¬
anics, and the fact that Ehrenfest’s theorem can be proved for
our momentum variable strongly indicates that our choice is the
correct one.
That classical mechanics should arise as a limiting case of quan¬
tum mechanics is the essence of the so-called correspondence
principle of Bohr. It is an important principle because if quantum
mechanics is to be a comprehensive description it must be able to
account for all physical phenomena, including the phenomena
which can also be described classically. Historically the corres¬
pondence principle served as a guide in the early development of
quantum mechanics. It places a constraint, we may say, on possible
new theories, but it should not be thought that it determines these
uniquely. There can be no rules for “quantization,” he*, there
can be no prescription for how one passes from a classical descrip¬
tion to a quantum-mechanical description, It obviously makes no
sense to say; “In order to find the correct (quantum-mechanical)
equations it is necessary first to state the wrong (classical) equations,
after which one passes from the wrong equations to the correct
equations by a certain magical operation.” The correct equations
of physics are rather found by clever guessing, guided by known
experimental facts, and these guesses are then subjected to further
experimental tests.
58 For any quantum-mechanical variable Q the quantity
AQ = VAv(Q2) ~ [Av(<?)]2 (58a)

computed for a given wave function, can be used as a measure of
the precision with which the variable Q is known for the state
described by this wave function. The variable Q has a precise
value in a particular state if and only if A£) = 0 for this state. As
an example of this idea we can mention that the energy variable H
is precisely known for each stationary state: it has the value E,
where E is the energy of the state. For a non-stationary state we
have AH > 0.
An uncertainty relation in general is a restriction on the precision
with which two different variables can be known simultaneously:
it takes the form of an inequality involving AQ* and AQff for the
350 Chop. 8 References for Further Study
two variables Q' and Q". We now have available a precise defini¬
tion of Ax, as given by Eq. (49e), and a precise definition of Ap, as
given by Eq. (52d). We could, without too much difficulty, prove
the precise uncertainty relation
AxAp^Z (58b)
i*e*, prove that the inequality (58b) holds for all wave functions,
and that furthermore there are some wave functions for which
(58b) holds as an equality* We shall not undertake this task here
since we already have a good qualitative understanding of why a
relation such as (58b) must hold, and that is sufficient for this course.
1} For further discussions of simple problems in the Schrodinger theory we refer to

the books mentioned at the end of Chap. 7 (items 2).
2) G, M, Barrow; The Stiwtwre of Molecules (W, A. Benjamin, Inc.* New York,
1963), is a readable introduction to molecular structure and molecular spectra. The
discussion is elementary, and our preparation suffices for a complete reading of this
book*
3) F, 0. Bice and E, Teller; The Structure of Matter (Science Editions, Inc., 1661),
is, as the name of the book indicates, devoted to a general discussion of the structure
of matter (from the standpoint of quantum-mechanical ideas). The discussion is ele¬
mentary, and the book can easily be read with our preparation. The reader may want
to supplement our discussion by reading selected portions from this book.
Problems
1 (a) Consider the problem of a particle confined to a potential well

with infinitely high walls, as shown in Fig. 4A. Let us study the wave func¬
tion given by the expression (6b), for n' = 17 and nf* = 18* Plot the prob¬
ability density, given by Eq* (6c), for the following times: t = Oj t = to/4;
t = to/2; t = 3to/4 and t = to, where to = (4mdz)/(35^rH). These plots will
suggest to you the periodic motion of a particle back and forth between the
walls. The period of this motion is fo-
(f?) Consider the motion of a classical particle of mass m and energy
Ec = £{Ei7 + F1S) in the same potential well, and compare the period of
this motion with to found above.
(c) The wave packet in part (a) of this problem is not particularly well-
confined. In fact it is spread out over about £ the size of the well* To
produce a sharply defined wave packet which resembles the classical point
particle more closely, we need a superposition of a large number of eigen-
Problems Theory of Stationary States 351
functions. If the position is to be well-defined, the momentum, and thereby

the energy, will be poorly defined. Note now that the energy of the nth
level is proportional to n2, whereas the spacing between two neighboring
levels is approximately proportional to n. For a wave packet of high average
energy it is therefore possible to have a superposition of a large number of
eigenfunctions such that the instantaneous position of the particle is reason¬
ably well-defined, and such that the fractional spread in the energy is also
small. We here encounter another example of the passage to the classical
limit. A wave packet in a potential well can behave like a classical particle
provided that its average eneigy is high compared with the ground state
energy.
We cannot here study the passage to the classical limit in complete detail,
but let us study just one aspect of the problem. Let n' = n, and n" = n + 1.
Find the period of the motion of the packet represented by the superposition
(6b) and compare this period with the period of a classical particle moving
with an eneigy E such that En+1 ^ E ^ En. Consider, in particular, the
limit as ft co.
2 For the sake of argument the author makes the following assertion
(inspired by some attempts to “explain*' quantum mechanics in certain
popular writings). The probability density P(x) — |2 for a stationary
state represented by the wave function can be understood as repre¬
senting the thne-averagp of the probability density for a particle moving
classically in the potential, with the energy of the stationary state. In other
words: the particle moves classically, but if we average this motion over a
time which is large compared with the natural period of the motion, then we
are led to the probability density P{r). For a particle in three-dimensional
motion, for instance an electron in the hydrogen atom, we can give a similar
interpretation of the absolute square of the wave function representing
a stationary state. The particle moves classically, but our measuring instru¬
ments are too crude to follow the details of the motion, and we therefore
observe instead a probability distribution of the electron in the atom, and
this can be understood as arising from averaging the classical motion over
a large time.
The reader will note that this assertion, interpreted literally, can be im¬
mediately refuted, The author therefore backs away a bit. He asserts
instead that whereas this interpretation of the square of the wave function is
not strictly correct, it is nevertheless a very useful way of thinking about the
quantum-mechanical motion of a particle; it gives us real insight into what
goes on, provided it is understood in an approximate sense.
It is the task of the reader to utterly refute these ideas; both the naive
first assertion and the modified second assertion. In so doing the reader
should take into consideration the discussion in the beginning of this chapter,
as well as our discussion of “double-slit experiments” in Chaps. 4 and 5.
3 The integration in Eq* (22a) extends from —a to + a, Suppose that

we instead integrate from — oc to + oo, How does this integral depend on
die time t, and what is its value at t = 0?
4 We should convince ourselves that an attractive potential does not

necessarily lead to bound states. To do this we consider the specific example
shown in the figure next to Prob. 5* Let B be the depth of the well* let its
width be a, and let m be the mass of the particle* Show that if the quantity
G = a2Bm/H2 is smaller than a certain number Go, then there will be no
bound states, whereas there will be at least one bound state whenever
G > Go* Find the constant Go* Note that these considerations only apply
to a well for which one wall is infinitely high. For a well such as shown in
Fig* 19A, at least one bound state will exist no matter how shallow the well is.
Guided by this example, present arguments why each one of the following
conditions is favorable for the occurrence of bound states: (a) A large mass
m. (b) A deep well, (c) A wide well. Illustrate your arguments, which
should be given for a more general potential well than the one shown in
Fig. 19A, with suitably drawn graphs.
On the basis of this example we can understand why two atoms do not
always form a stable molecule, despite the fact that the forces between the
atoms might be attractive for certain separations between the atoms. (If the
force is everywhere repulsive, as is sometimes the case, there can naturally
not be any bound states.) We can regard the potential shown in the figure
of this problem as an idealization of the more realistic molecular potential
shown in Fig, 30A
+ oo 5 As a simple one-dimensional model of the deuteron (which is a bound

state of a neutron and a proton) let us assume that the neutron-proton
potential is as shown in the adjoining figure, with a = 1*85 x 10-13 cm, and
with B = 4110 MeV, Find the binding energy of the deuteron in this model,
and compare it with the experimental value 2,21 MeV. The good agreement
is, of course, not a triumph for the theory because the observed binding
energy has been used, together with other observational data, to find reason¬
able values for a apd B, The potential which we are considering is not
realistic, although it reproduces some features of the neutron-proton inter¬
action correctly* The problem of finding the effective potential from “first
principles” is unsolved* Note: The mass m is the reduced mass of the
proton-neutron system, m = Mp/2.
This figure refers to Probs. 4 and 5. In Prob. 5 the
solid curve represents the potential energy of the neu¬ 6 In the vibrational spectrum of hydrogen chloride, HC1, it is found
tron-proton system according to an oversimplified that the spectral lines are actually closely spaced doublets. The short wave¬
model which, however, is useful in understanding
some properties of the deuteron and some features length member of these doublets has an intensity of roughly three times the
of low energy neutron-proton scattering. The abscissa intensity of the long wavelength member. For the lines which occur in the
is the separation between the neutron and the proton. neighborhood of about 5600 cm-1 (wave numbers) the separation of the two
components is measured to be about 4 cm-1* Give an explanation of this

phenomenon, and derive the separation between the components theoret¬
ically. Also explain the relative intensities of the two members of the dou¬
blets.
7 In the study of the frequencies associated with rotational transitions

J =]«-<). u=0
in the iodine-chlorine molecule, the following frequencies (in megacycles Isotopic Rotational frequencies
per second) have been measured species (Mc/see) Ba (Me
IC135 6980 me 27,336 me Cia0lfi 115 271.204±0.005 57 89

C13018 110 201.370±0.008 55 3
ICl37 6684 me 26,181 me C1201B 109 782.182±0.008 55
C14018 105 871.110±0.004 53
The upper row refers to the molecule containing the isotope Cl35, whereas C1301S 104 71l.416±0.008 5
Cl*On 112 359.276±0.060b
the lower row refers to the molecule containing the isotope Cl37. The iodine
nucleus is the isotope 53l127 in both molecules*
(a) Can you explain the frequencies in the lower row, given the frequencies
in the upper row? Experimentally measured rotational frequencies for
carbon monoxide molecules of different Isotopic com¬
(b) If the sample used in the measurement is prepared from naturally
positions. The fragment of the table is taken from
occurring chlorine, all four frequencies will naturally be observed* Can you a paper by B. Rosenblum, A. H. Netheroot, Jr., and
predict the ratio of the intensities of the lines in the upper row to the C. H. Townes, "Isotopic mass ratios, magnetic mo¬
intensities of the corresponding lines in the lower row? ments and sign of electric dipole moment in CO/1
(c) Consider the isotope effect in general for the rotational levels of a The Physics/ Rev/ew 109, 2228 (1958). The numbers
quoted give a good picture of the accuracy which can
diatomic molecule. Let wj be a rotational transition frequency for a mole¬
be achieved in microwave spectroscopy.
cule in which the nuclear masses are Mi and MJ, and let w" be the corres¬ The reader who has solved Prob. 7 might wish to
ponding frequency for a chemically identical molecule, which, however, is test his results against the data given in the above
built of different isotopes, the nuclear masses of which are Mi' and MV. We table. The agreement will be good but not perfect.
can again relate to w" without a detailed theory of the molecule. Show Our theory, in which the diatomic molecule is regarded
as rigidt represents an oversimplification. To account
that the ratio of the two frequencies is of the form
for the experimental numbers to the precision with
which they are known requires a more sophisticated
_ /Mj'Afg(Mi + M'jV
theoretical approach.
v" ~ \MiMi(Mr + MS)}
and determine the correct exponent fc* Your expression should be carefully
compared with the expression (37a), which describes the isotope effect on the
vibrational spectrum* The dependence on the isotopic masses is different in
the two cases*
8 Consider a “typical” crystal, built of atoms of atomic weight A.

Let the crystal be in the form of a cube, of side length L. Derive an
order of magnitude estimate for (a) the lowest (vibrational) resonant fre¬
quency of the crystal; (h) the highest resonant frequency of the crystal.
Write your results such that the dependence of the frequencies on the funda¬
mental constants at, ft — m/Mp and Ji/mc2 as well as on the constants A and
N L/0$ (where Oo is the Bohr radius, and Mp is the mass of the proton) is
clearly shown, (c) Give some specific numerical examples in which you give
the frequencies in megacycles/second.
3B4 Chap* 8 Problems
9 In Sec* 50, Chap* 2, we said that it is possible, in principle* to derive

an expression for the ratio of the velocity of sound* c9r in a crystal to the
velocity of light c, such that cjc is expressed in terms of four constants only:
the fine-structure constant a ^ 1/137, the electron-proton mass ratio 0 =
m/Mp and the atomic weight A and the atomic number Z of the atoms in the
crystal, To derive a precise expression for cs/c is a formidable problem, but
we can easily make an order of magnitude estimate which shows the main
dependence of cjc on a, 0 and A. Derive such an order of magnitude
relation, and test your formula for the case of copper* (A = 63,6, ca =
4700 m/sec.)
10 (a) For the potential U(r) shown in Fig. 30A we note that the spacing
between neighboring levels decreases as the quantum number n increases.
Explain in a qualitative way why this is so,
(b) Draw a parabola representing the potential for a strictly harmonic
oscillator* On the same graph draw two other potential curves, symmetric
with respect to the origin, representing two “almost harmonic" potentials,
and such that the radius of curvature of all three curves is the same at the
origin (= the minimum of the potential). These two curves are to be drawn
such that for the first one of these the spacing between neighboring levels
increases with the quantum number n, whereas for the second one the
spacing between neighboring levels decreases with n. It is not necessary tx>
find the levels explicitly, but you should explain why the two curves have
the stated properties.
11 As we explained in Sec* 47 the energy levels of doubly ionized lithium

are obtained by a simple scaling from the energy levels of singly ionized
helium, the scaling factor being close to 9/4, Both ions are hydrogen-like
one-electron systems. For the sake of argument the author now wants to
maintain that the energy levels of singly ionized lithium should be obtainable
by a similar scaling from the energy levels of neutral helium, because both
systems are two-electron systems, differing only in the magnitude of the
nuclear charge* In otlier words, the ratios of the wavelengths of correspond¬
ing spectral lines ought to be a constant, just as is the case with doubly
ionized lithium and singly ionized helium. This is, however, not the case
experimentally. The term schemes of neutral helium and singly ionized
lithium are quite similar, but not obtainable from each other by a simple
scaling* Explain clearly why it is that the simple scaling argument works for
the one-electron systems but not for the two-electron systems.
12 The mean life of the 2p-state in hydrogen is 0*16 X I0_s sec* What
is the mean life of the 2p-state in singly ionized helium?
13 With reference to the preceding problem: What is the mean life of

the 2p-state in the muonic atom formed when negative muons are captured
in aluminum?
14 Compute the wavelength of the photon emitted when a muonic alu¬

minum atom makes a transition from the 3s-state to the 2p-state.
15 Find the “Bohr radius" of (a) a muonic aluminum atom; (h) a muonic
lead atom, and compare these radii with the nuclear radii. It is interesting to
make this comparison, because if the “Bohr radius" turns out to be com¬
parable with the nuclear radius then we can clearly not regard the nucleus
as being a charged point without extension, which means that the energy
levels of the muonic atom cannot be given precisely by a formula like (46b).
It has been found, experimentally, that the level systems of heavy muonic
atoms deviate considerably from the prediction (46b) * Through a systematic
observation of these deviations it has been possible to draw definite con¬
clusions about the charge distribution in nuclei, and about the sire of nuclei.
16f Make an attempt to prove Ehrenfest's theorem, mentioned in Sec.

56, along the lines indicated in that section. For further inspiration, see
Sec. 50, Chap. 7.
17f {#) Apply Ehrenfest’s theorem to the case of a harmonic oscillator

for which the potential function is given by V(x) = (Kf 2) x\ and obtain two
differential equations satisfied by Av [*(£)] and Av [p(f)]. Solve these equa¬
tion and express Av [x(f) ] in terms of Av [*(0) ] and Av [p(0) ]. Compare the
solution with the solution of the corresponding classical problem.
(b) For a stationary state Av [*(*)] =0, but for a non-stationary state
Av [x(t) ] is, in general, an oscillatory non-zero function of the time. Keeping
in mind the discussion in Sec. 27, present arguments based on your results in
part (a) of this problem, to the effect that the energy levels of the harmonic
oscillator must be equally spaced, with spacing ft \/K/m. Note that our
discussion in Sec. 27 only tells us that the level spacing must be approximately
constant, although it so happens that the level spacing is exactly constant and
equal to ft \fK/m,
18 Let us consider a “dumbbell" diatomic molecule. We discussed the

rotational excitations of such a molecule in Secs. 38-40. Let us suppose that
the center of charge of the molecule does not coincide with its oenter of mass.
The molecule will then carry an electric dipole moment, and as it rotates we
t These problems refer to an advanced topic.

356 Gfeap. 5 Problems
expect, classically, that it will emit electromagnetic radiation at a frequency

equal to the classical angular velocity ooa.
According to quantum mechanics the energy levels of the molecule are
given by Eq. (39c), It is reasonable to assume that the quantum number /
changes by one unit if the molecule emits, or absorbs, electric dipole radia¬
tion. Express the frequency of the emitted radiation in terms of the angular
momentum quantum number / of the initial state of the molecule, and com¬
pare the result with the classically derived formula. For large values of / we
ought to approach the “classical limit/' Is this indeed the case?
Chapter 9
The Elementary Particles

and their Interactions
Sections l to is Collision Processes and the Wave Picture 358
19 to 31 What Is Meant by a Particle? 372
32 to 46 Basic Ideas of Quantum Field Theory 382
47 to 55 Fions and Nuclear Forces 393
56 Concluding Remarks 400
Problems 401
Chapter 9 The Elementary Particles
and their Interactions
Collision Processes and the Wave Picture

1 In our final chapter we want to discuss some aspects of the
most basic and central issues of physics today, which concern the
elementary particles and their interactions. In this realm of physics
we encounter a host of problems for which we have no solutions at
present. We would like to have a theory in terms of which we
could “understand” why the various elementary particles exist and
why they have the properties they have. We hope, in other words,
that it is possible to state a few very basic principles in terms of
which we can account for the great multitude of phenomena which
have been observed. Is this hope justified? Certainly not on any
logical grounds* It could well happen that we are condemned to
live with phenomenological theories which summarize the experi¬
mental facts in a slightly more economical way than a set of tables
and graphs could do, but which lack the comprehensiveness, con¬
ceptual simplicity and beauty which we would like to see in a
fundamental theory* The author finds it most disagreeable to
contemplate this possibility* He prefers to believe that in some
sense things are ultimately simple, and he finds some encourage¬
ment through meditation over the historical development of physics.
Fig• 2A General plan of an experiment to measure
As a body of knowledge physics has expanded at a very rapid rate,
various cross sections for anti proton-proton elastic and
inelastic scatteri ng. The anti protons emerge from the and the amount of information which we now possess about
target in the accelerator (top right) and they are detailed phenomena is astonishing. What is even more astonishing,
deflected and focused or a liquid hydrogen target however, is the fact that we can account for the details as well as
(bottom left). Ci, C2 and M are deflecting magnets. we do in terms of fairly simple theories. In saying this the author
Qi-Q? are focusing magnets. A~H are scintillation
does not want to imply that theoretical physics is a trivial subject,
counters. C is a Cerenkov counter. The events taking
place in the liquid hydrogen target are observed but he does feel that the underlying basic principles of our theories
through counters surrounding the target. (These (such as they are perceived today) are characterized by a con¬
counters are not shown in the figure.) The purpose of ceptual simplicity which is quite striking. As we have indicated
the somewhat elaborate arrangement of counters and before there does not exist today a “simple” comprehensive theory
magnets is to define the anti proton beam and to dis¬
of the elementary particles. In this chapter we shall try to give the
criminate against events in the target due to particles
other than antiprotons. The measurements were reader some idea of the approaches which have been tried, and
carried out at anti proton energies of 1.0, L25 and of the issues and problems which we encounter in this realm of
2.0 SeV. physics.
The illustration is taken from R, Armenteros et a!,P
"Anti proton-Proton Cross Sections at 1,0, 1,25, and
2.0 BeV,” The Physical Review 119, 2068 (1960).
2 The bulk of our knowledge about the elementary particles
This article should be consulted for further details. derives from collision experiments. It is therefore appropriate that
For results, see Fig. 5A in this chapter, (Courtesy of we here say something about the interpretation of such experiments.
The Physical Review,) In a scattering experiment a beam of A-particles from an accelerator
Sea 9.2 The Elementary Particles and their Interactions 359
Ftg. 2B Photograph of the liquid hydrogen target

used in the experiment described in Fig. 2A. The
hydrogen is in the container in the center of the device.
The antiprotons are incident perpendicularly to the
plane of the picture. (Photograph by courtesy of the
Lawrence Radiation Laboratory, Berkeley.)
impinges upon a target of B-particles (in the form of a solid, liquid

or gas*) We observe the particles which emerge from each collision
of an A-particle with a B-particle. We say that the collision is
elastic if no new particles appear in the collision; the A-particle is
then merely scattered by the B-particle. If other particles appear
we speak of an inelastic process.
The observational results are commonly expressed in terms of
various cross sections. Let us first consider the simplest of these,
namely the total cross section. We denote this quantity by a?*
To define oT operationally we imagine that the target is a very thin
plane layer of randomly distributed B-particles. Let the (on the
360 The Elementary Particles and their Interactions Sec. 9.3
average) uniform density of particles in the layer be n particles per

unit area. The total cross section is then defined by
Of =■ — (2a)
n
where P is the probability that an A-particle incident perpendic¬
ularly on the layer undergoes some interaction with one of the
B-particles such that it is removed from the incident beam. In this
definition it is essential that the layer be sufficiently thin so that the
observed probability P will be small compared to unity. (We shall
elaborate on this point in Sec. 4.)
3 We can think about the total cross section in terms of the

following model. A circular disc of area or is assigned to each
B-particle. The discs are oriented perpendicularly to the incident
beam of A-particles, and we imagine that they have the property
Fig. 3A We can express the effectiveness by which that an A-particle which hits a disc is removed from the beam,
the B-particles (in the target) remove A-partides from whereas the A-particle is unaffected if it misses the discs* Consider
the incident beam by a total cross section or, With again our thin target layer of n B-particles per unit area, The
each B-particle is associated a circular disc of area total area covered by the discs contained in a region of area F is
ot, such that an A-particle (imagined to be a point)
equal to nFaT. This means that a fraction noT of the layer is
interacts with the B-particle if and only if it hits the
disc. The figure above shows these imaginary discs “opaque” and a fraction (1 — nor) is “transparent.” The prob¬
for a very thin layer of B-particles. If there are n ability that an A-particle in the incident beam is removed from the
B-particles per unit area the total IJblocked" area beam is accordingly P = noy. The relation (2a) can thus be inter¬
within a unit area will be The probability that an preted in this manner, but the reader should understand that the
A-particle passes through such a layer is accordingly
opaque discs exist only in our imagination. The cross section is a
(1 — no-r). The above figure should not, of course,
be taken literally. The B-particles are not in reality very convenient measure of the tendency of particles A and B to
small discs or spheres. interact with each other, but it should not be thought that it refers
to geometric properties of either one of the particles.
4 Let us consider the generalization of the relation (2a) to the

ease when the target layer is not necessarily thin. Let F(fi) be the
probability that an A-particle is removed from the beam if it hits
a layer of B-particles uniformly distributed with a projected surface
density n* The quantity T(n) = 1 — P{n) is then the probability
for transmission through the layer. Suppose that we place a layer
of projected surface density ni behind another layer of projected
surface density n2* The surface density of the combined layer is
then (ni + r^). The probability that a particle passes through
both layers is obviously given by
T(ni + n2) = T(ni)T(rc2) (4a)
This equation must hold for all positive real numbers n\ and n2.
Its general solution is
T(«) = exp ( — Cn) (4b)

Sec* 9.5 The Elementary Particles and their Interactions 361
where C is a real constant. We thus have
F(n) = 1 — exp ( — Cn) (4c)

Notice now that
lim^= C (4d)
»->o ri
and if we compare this relation with the relation (2a) (which is

supposed to hold for very small n) we conclude that C = Of. We
thus have
P(n) = 1 — exp (— noT}> T(n) = exp( — no?) (4e)
As we see the intensity of the transmitted beam decreases ex¬

ponentially with the thickness of the target In practice we might
have targets in the form of thin foils of various thicknesses. To
measure the total cross section we perform a simple attenuation
measurement: we determine (with counters) the fractional decrease
in the intensity of the transmitted beam as a function of the thick¬
ness of the foil. The cross section is then computed with the help
of the relations (4e).
5 In a similar manner we define other kinds of cross sections. We

can imagine, for instance, that the A-particle can react with the
B-particle to produce a C- and a D-particle:
A + B —» C + D (5a)
The reaction cross section oae-»cd for this process is then defined
by
0AB-*)D = (5b)
where Pab-*cd is the probability that the reaction (5a) takes place
when an A-particle is removed from the beam through an inter¬
action with a B-particle in the target. Let us assume that (5a) is
the only reaction, Le., the only inelastic process, which can take Fig*5A Graph showing anti proton-proton cross
sections as functions of the Kinetic energy of the anti¬
place. A particle can, however, also be removed from the beam by
proton. The three experimental points denoted by
an elastic scattering, in which the A- and the B- particles remain open circles were obtained in the experiment de¬
after the collision. We define the elastic cross section oe by scribed in Fig. 2A, The cross section for proton*
proton scattering are shown on the same graph for
ae = aT Pf? (5c) comparison. Note that the total anti proton-proton
cross section is about twice as large as the total
where Fe is the probability that a collision event which removes a
proton-proton cross section.
particle from the beam is elastic. The three cross sections are thus This graph is taken from R. Armenteros et al.h “Anti-
related by proton-Proton Cross Sections at 1.0, 1.25, and 2.0
BeV/1 The Physics/ Review 119, 2068 (1960). (Cour¬
aT — + <Jab-»cd (5d) tesy of The Physical Review.)
since we obviously have Fe + Pab^cd = 1*

362 The Elementary Particles and their Interactions Sea 9,6
6 To express cross sections in nuclear and elementary particle

physics the units bam (b) and millibam (mb) are employed* where
1 bam = 10"24 cm2, 1 mb — 10~3 barn (6a)
Fig. 6A shows the total neutron cross section for cadmium a5 a
function of the kinetic energy of the neutron, and Fig. 6B shows an
analogous graph for neutron collisions with silver. Note that these
curves refer to the chemical elements, and they are therefore
averages for the different naturally occurring isotopes.
A look at these graphs makes it immediately clear that the total
cross section has nothing to do with the “geometric” properties of
the nuclei. Note, for instance, the dramatic dependence of the
cross section on the energy. In cadmium the cross section drops
from the peak value of 7200 bams at the neutron energy 0.176 eV
to the value 20 br at 1 eV. The cross section curve for silver
similarly shows a strong energy dependence, with a very pro¬
nounced resonance peak at about 0.52 eV.
Let us also consider the magnitudes of the cross sections. The
silver and cadmium nuclei are of roughly the same size. On the
basis of the formula
r ^ A1/3 X (1,2 X 10-13 cm) (6b)

Figt6A Curve showing total cross section of neu¬ which gives the radius r of a nucleus in terms of its mass number A*
trons against cadmiurn as a function of the neutron we estimate that the radii are r ~ 5,8 fermi (since A ~ 110.) The
energy. Note that this curve refers to naturally
corresponding geometric cross section wfi is accordingly about
occurring cadmiurn. The cross section is therefore
an average of the cross sections of the different iso¬ 1.0 bam. This is 7000 times smaller than the peak cross section in
topes. Such a cross section is of limited interest Fig. 6A.
from the standpoint of basic theory which is concerned The reader should also look at Figs. 24A and 24B in this chapter.
with cross sections for individual isotopes. The Fig. 24B shows the elastic cross sections for the scattering of pos¬
average cross section is however a useful concept in
itive and negative pions against protons. Fig. 24A shows what is
engineering applications. Because of its large cross
section for low-energy neutrons cadmium is commonly essentially the reaction cross section for the reaction Al27 + p
used to control the reaction rate in nuclear reactors. Si28 + y. Note the many very sharp resonance peaks.
The above curve is a portion of a graph in a com¬
pilation by H. H. Goldsmith, H. W. Ibser, and B. T. 7 The cross sections which we have discussed (measured as func¬
Feld, "'Neutron Cross Sections of the Elements,"
tions of the energy) provide us with some information about the
Reviews of Modern Physics 19, 259 (1947),
interactions between the particles in a collision process. We obtain
much more information if we also measure the angular distribution
of the particles emerging from the collision region. We consider,
for simplicity, the elastic scattering of the A-particles in the beam
by the B-particles in the target. We measure the intensity of the
scattered A-particles in different directions with the help of a
counter placed at various positions at a fixed distance from the
target. The intensity of the incident beam is kept constant during
this sequence of measurements. We express the results in terms of
Sec 9J
* The Elementary Particles and their Interactions 363
Fig* 6B Curve showing total cross section of neu¬

trons against naturally occurring silver as a function
of the neutron energy. Note the pronounced reso¬
nance peak, A glance at this figure, and the anal¬
ogous Fig. 6Af shows immediately that the cross
section has no particular relationship to the size of
a nucleus. The curves for silver and cadmium are
very different, and both show a rapid variation with
energy. The wave theory of collisions can account
very well for the general nature of the observed cross-
section curves.
The above curve is a portion of a graph appearing
in the compilation by H. H. Goldsmith, h, W, Ibser,
and B, T, Feld, "Neutron Cross Sections of the Ele¬
ments,^ Reviews of Modern Physics 19, 259 (1947).
This paper should be consulted for references to the
early work in this field.
a differential cross section oe(E;8,tp). This quantity is a function of

suitable polar angles 0 and <p used to specify the direction of ob¬
servation* It is also a function of the energy as we have indicated
explicitly* The differential cross section is so defined that
oe(E;6,<p)dQ equals the probability that an incident A-particle is
scattered into a solid angle of magnitude dG, centered about the
direction defined by the angles $ and tp, for the case when the target
is a layer of B-particles of unit surface density* For the same
counter held at a fixed distance from the target, but at different
directions, the counting rate is directly proportional to the differen¬
tial cross section*
In most scattering situations in practice the differential cross
section depends only on the energy and on the angle between the
incident beam and the direction of the scattered A-particle, If we
denote this angle by 8 we can write the differential cross section as
oe(E;8) since it does not depend on the other polar angle, f
The total elastic cross section is obtained by integrating the Incident | Transmitted
differential cross section over all directions* If it is independent of beam Target beam
the angle <jp, as above, we thus have

Fig* 7A Very schematic representation of a scat¬
oe(JE) = j dQ <Je(E;8) = 2tt j dB sin 8 oe(E;ff) (7a)
tering experiment. A beam of particles from an accel¬
Jq Jo
erator impinges upon a target The relative number
of particles scattered in various directions is deter¬
f Our Dotation, which is fairly standard, is not entirely satisfactory since the same mined by a counter. The figure shows the detection
symbol is used for the differential cross section and for the "total” cross sections dis¬ of particles at the scattering angle 0. In an experi¬
cussed earlier. The two kinds of cross sections are distinguished from each other by the ment of this kind we can determine the differential
explicit presence or absence of the angular variables in the symbol for the quantity. cross section of the scattering process.
We could define a differential cross section for an inelastic

process in an analogous manner*
8 The various cross sections, as functions of the energy, con¬

stitute the primary data which we obtain from scattering experi¬
ments. We are then faced with the problem of inferring something
d<r/dH (m&/ST£RAD)
about the nature of the perhaps unknown interactions from these

data. Or, we might already have a theory, in which case we com¬
pute the expected cross sections within the theory and then com¬
pare our predictions with the experimental results.
As we said before, most of our information about the elementary
particles comes from the analysis of scattering experiments* Special
mathematical methods have been developed for this analysis* It
would take us too far to discuss these here. Needless to say, the
problem of finding the “forces” from the cross sections is far from
trivial in practice although it is straightforward (in a sense) in
principle*
9 If we were to interpret a scattering event classically we would

say that the incident particle is deflected in the force field of the
The differential cross section for the elastic scattering target particle. Quantum mechanically we regard scattering as a
of neutrons from the bismuth isotope Bi20S. The manifestation of the diffraction of waves. This is in fact how we
graph shows the experimental points together with a discussed electron diffraction in Chap. 5. Our explanation of the
theoretical curve based on a particular model. The
observed phenomena was that the incident electron wave is
abscissa is the scattering angle, and the ordinate is
the differential cross section in units of millibarns per diffracted by all the atoms in the crystal. In certain directions the
unit solid angle. The kinetic energy of the neutrons diffracted waves can interfere constructively, and these are the
was 7 MeV. directions in which we observe intensity maxima. Scattering is
This graph is taken from C. D. Zafiratos, T. A. thus a manifestation of the diffraction of de Broglie waves by
Oliphant, J, S. Levin, and L, Cranberg, "Large-Angle obstacles, i.e*, by the atoms in the crystal.
,
Neutron Scattering from Lead at 7 MeV," Phys/caf
Review Letters 14 913 (1965). (Courtesy of Phys/ca/
Review Letters.)
Now the reader will note that our description of electron diffract
tion has an objectionable “unsymmetric” feature. We say that
the incident electron waves are diffracted by “obstacles." But the
“obstacles" are also physical particles, and we know that all physical
particles are waves. It is clearly not consistent to arbitrarily
regard some particles as waves, and other particles as classical
“obstacles.” What we see in the electron diffraction experiments is
the interaction of the incident electron waves with the wave packets
which represent the atoms in the crystal* If we want to be con¬
sistent we must say that scattering arises as a consequence of the
interaction of waves with waves.
Later in this chapter we shall explore this idea further. Let us
note at this point that this new insight in no way invalidates our
discussion of electron diffraction. The important thing is that the
incident wave encounters something, and that its interaction with
Sec. 9.10 The Elementary Particles and their Interactions 365
this something leads to a diffraction of the wave. As long as we

focus our attention only on the incident particle it is quite im¬
material what it is that the particle encounters, be it a "classical
obstacle," or a concentrated wave packet.
10 Let us now try to present the barest outline of a wave theory

of scattering* We consider the simplest possible case in which the
wave representing an A-particle is scattered (diffracted) elastically
in a fixed centrally symmetric field of force. We can imagine that
the force field is derivable from a potential which tends rapidly to
zero with increasing distance from the center of the force field.
Our problem is somewhat analogous to the barrier problems which
we discussed in Chap. 7. The A-particle finds itself in a region in
which the potential function varies with position and as a result an
incident plane wave will be diffracted by the potential*
According to the model which we are considering we represent
the B-particle in the target by a spherically symmetric potential,
although we know that the B-particle should also be described as
a wave, It is the case, however, that the correct quantum mech¬
anical description of two-particle scattering is mathematically
equivalent to our model. Our model is therefore not bad at all*
If we think carefully about what we are doing we will realize that
we have done similar things before. In discussing alpha-radioac¬ Graphs showing the differential cross sections for the
tivity in Chap, 7 we described the situation in terms of the motion of elastic scattering of electrons from two different iso¬
a “quantum-mechanical" alpha-particle in a potential field of force. topes of cafcium. The ordinate is the differential
cross section in units of cm2 per unit solid angle, pro¬
In discussing molecular vibrations we considered the motion of a vided that the data for Ca4S are multiplied by 10 and
single particle under the influence of an approximately harmonic the data for Ca40 are divided by 10, (The curves are
molecular potential* In each of these cases we replaced the real very similar, which is why they have been separated
problem, which always involves the motion of at least two particles, by the use of these scale factors.) The electrons were
by a model problem in which a single particle moves in a potential of energy 750 MeV.
The electromagnetic interaction between the elec¬
which describes its interactions with all the other particles*
tron and the nucleus is responsible for the scattering,
and the purpose of the measurement was to explore
11 Suppose a plane wave of the form the charge distribution in the nuclei. Note the tre¬
mendous variation (by a factor of 109) of the differen¬
^= C exp (tx - pi - iut) (Ila) tial cross section with scattering angle.
Graph taken from J. B. Bellicard et at, "Scattering
represents an A-particle incident on a single B-particle (located at of 750-MeV Electrons by Calcium Isotopes/' Physical
the origin x = 0)* Here p* is the momentum of the wave, o> is the Review Letters 19, 527 (1967). (Courtesy of Physical
energy,! and C is a normalization constant. The wave will be Review Letters.)
diffracted by the B-particle. We shall try to guess the form of the
wave function which describes the diffracted wave at a very large
distance from the origin. We shall argue that the function
f We employ units such that ft ^ 1.

^(x,f) = Cf(8) - exp — Lot) (lib)
is a reasonable choice. We denote the distance from the origin by

x and the magnitude of the incident momentum by p, i,e,, x = | x |,
p = | pi | * The function f(6) is some function of the angle & between
die direction of the incident momentum p* and the direction of the
position vector x (from the origin to the “point of observation").
Let us now study various features of the wave function to see
whether it can represent the scattered wave. The amplitude of the
scattered wave is proportional to the amplitude C of the incident
wave, and our guess thus reflects the reasonable assumption that
the response is linear, The frequency a; of the scattered wave is
the same as the frequency of the incident wave. This means that
the energy of the A-particle is conserved, as it has to be since we
wanted to consider elastic scattering in the fixed field of force of the
B-particle.
The factor exp (iap — Lot) obviously describes a spherical wave
which propagates outward. At any one point the phase velocity is
10 .8 .6 4 Z 0-2 -4 -6 -.0 -1.0 -.98 -99 -10
directed away from the origin along the radius vector. A wave
Cos 0cm
representing a scattered particle must clearly have this feature.
The factor 1/x in the expression (11b) describes the decrease in the
A plot of the elastic pion-proton differential cross sec¬
amplitude of the scattered wave with distance, The intensity of
tions for a pion momentum of 4 BeV/c. The abscissa
is the cosine of the scattering angle in the cervter-of- the wave is proportional to the absolute square of the wave function.
mass system. The ordinate is the differential cross The intensity of the scattered wave measures the outgoing prob¬
section in units of microbarns per unit solid angle. ability flux (or if we like, the particle flux in a sequence of repeated
The cross section in the neighborhood of the back¬ measurements) and this quantity must decrease as 1/x2 with dis¬
ward direction (i.e. for cos 9via close to — 1) is shown
tance. The amplitude must therefore decrease as \/x, as we have
at right on an expanded horizontal scale. Note that
data are presented both for positive and negative assumed.
pions: the identification of the different experimental
points is given in the top portion of the graph. 12 As wc see, simple physical considerations demand that the
This figure is taken from W. R. Frisken etal.r ‘Back¬ wave function describing the scattered wave be of the form stated
ward Elastic Scattering of High-Energy Pions by Pro¬
in (lib). The function f(0) is called the scattering amplitude. It
tons,'1 Physrcaf Review Letters 15, 313 (1965).
(Courtesy of Physical Review Letters.) obviously describes the angular distribution of the scattered par¬
ticles. To relate the scattering amplitude to the differential cross
section we argue as follows. Consider a small surface-region con¬
taining the point x on the surface of the sphere centered at the
origin and passing through x. Let its area be dF, The probability
dP that the scattered particle passes through this area must then
be proportional to the product of dF and the absolute square of the
wave function ^(x7f). We can accordingly write
(12a)
where k is some fixed constant of proportionality. Since dF/x2 =

dQ is the magnitude of the solid angle subtended by the small area
with respect to the origin we can also write
dF = k |C|2 \m\2dQ (12b)
and we note that dP is the probability that the scattered particle

emerges within the small cone of solid angle dQ.
Consider next the incident wave, given by (11a)* We imagine a
(circular) disc of unit area, perpendicular to the incident momentum
Pi and centered about the origin. The probability that the incident
particle passes through this disc must be equal to
(12c)
where k is the same constant which occurs in (12a) and (12b)*
Considering the expressions (12b) and (12c) we can say the fol¬
lowing* In a sequence of repeated scattering experiments (in
which the A-particles always have the same initial momentum p*)
the ratio of the number of scattered particles emerging within the
cone of solid angle dQ to the number of particles incident on the
unit disc is equal to
^ = (/(») | * <m <i2d)
If we now recall our discussion of the differential cross section

ae(0) in Sec* 7 we realize that the ratio dF/Pi is just the product of
the differential cross section with dQ* We thus obtain the impor¬
tant relation
<#)= \m\* (12e)

which says that the differential cross section is simply the absolute
square of the scattering amplitude.
13 If we want to find a theoretical expression for the scattering

amplitude j\0) we must, of course, solve our diffraction problem
explicitly. This means that we have to find a solution of the Schro-
dinger equation, or perhaps of some other equation, which applies
to the problem at hand* In our model we must find a solution to
the Schrodinger equation with the potential which the A-partiele
sees because of the presence of the B-particle* The wave equations
of quantum mechanics have an infinity of solutions, and it is also
necessary that we find the right one, which can be interpreted as
describing the scattering situation. The condition which we must
impose is that for large distances from the origin the wave function
must be of the form
368 The Elementary Particles and their Interactions Sec, 9J4
$ (x,£) = C exp (ix * pi — tot) + Cf{9) - exp (txp — tot) (13a)

This means that far away from the scattering center we have
the plane "incident wave” together with the outgoing scattered
wave, We shall not attempt to solve such problems here. It is
possible to prove, under very general conditions, that for every
choice of the incident momentum pi there exists a unique solution
of the wave equation which has the asymptotic form (13a), The
scattering amplitude is thus uniquely determined for a given inci¬
dent momentum and for a given interaction (potential). It will
in general depend on the magnitude p of the incident momentum;
and if we want to emphasize this we can write the scattering am¬
plitude as f(p;6). Once we have determined the scattering ampli¬
tude we find the differential cross section by (12e)*
14 Let us consider the important and simple special case when

the scattering amplitude is independent of the scattering angle 9t
Le,? f(ff) = f = a constant. The differential cross section is then
given by oe(9) — |/|2 = a constant* and the angular distribution
is spherically symmetric. This situation tends to occur for low-
energy scattering. It is easy to understand qualitatively the reason
for this. The angular distribution tends to be complex* i.e., rapidly
varying as a function of 0, when the wavelength of the incident
wave is small compared to the size of the "object” by which the
wave is diffracted. We can think about the diffraction as taking
place all over the object, so that each “part” of the object sends
out a diffracted wave. In a given direction these waves can inter¬
fere constructively or destructively, depending on their relative
phases. If the wavelength is small compared to the object a small
change in the direction of observation can have an appreciable
effect on the relative phases, and the differential cross section can
thus vary rapidly with the angle 9. However, if the wavelength
is large compared to the object these “geometrical” interference
effects do not occur, and the scattering amplitude is a slowly varying
function of direction. In the extreme low-energy limit, in which
the wavelength is eery long compared to the size of the scattering
object, the scattering amplitude is independent of angle, and the
scattering is spherically symmetric.
15 In the case f(8) = f — a constant, the scattered wave

Cf
= — exp (ixp — tot) (15a)
x
depends on the incident wave only through the parameter C which
expresses the amplitude of the incident wave at the origin. In

particular the scattered wave is independent of the direction of the
incident momentum pj. This is what we would expect if the scat¬
tering object is very small compared to the wavelength.
Suppose that we replace the plane wave given in (11a) by its
(uniform) average over all directions of p4. That is, we consider
a new scattering problem in which the incident wave is of the form
îo(M) = C exp (ix • pi ■ twf) (15b)

457
This integral over all directions is easily evaluated if we select

the angle 0 between x and p* as one of the polar angles of pi. We
obtain
'/'io(M) = — / dtp j dd sin 0 C exp (ixp cos 0 — iwf)
“ ~2ixp (exp (**p) - «P £ “ M) exp (- t«f) (15c)
If the scattered wave does not depend on the direction of the

incident momentum, an incident wave of the form will produce
the same scattered wave as the plane wave in (Ila). We can think
about the wave iô as the spherically symmetric part of the incident
plane wave* Only this part of the incident wave leads to the
spherically symmetric wave ^ given in (15a).
16 The spherically symmetric part i/'io of the incident plane wave

has an interesting form. If we look at the expression (15c) we
notice that the wave is the sum of an outgoing spherical wave and
an ingoing spherical wave, A plane wave "contains1'* two waves
of this kind because it describes motion toward the origin as well
as motion away from the origin, The amplitudes of the two waves
are identical in magnitude. This must be the case, because other¬
wise the outward flux would be different from the inward flux.
Since we have assumed elastic scattering (in which the A-particles
are preserved) the inward and outward fluxes (of A-particles) must
be the same.
Let us now consider the spherical average of the expression (13a)
in the case fid) = f = a constant. This average is given by
i£o(x,f) = ô(x^) +
~2Axp (t1 + 2ip/] exp {ixp) - exp (-ixp)) exp (-iuf) (16a)
We can interpret this expression as the asymptotic form of the

wave function which describes the scattering situation in which
the spherical wave i/'io plays the role of the incident wave. Inspeo
tion of (16a) shows that the wave ipo(x5f) also has both an ingoing
and an outgoing part. If the scattering process is elastic the abso¬
lute values of the amplitudes of these two waves must be equal.
This leads to the important condition
11 + 2ipf\ = X (16b)
on the scattering amplitude /.

It is convenient to write the general solution of the equation
(16b) in the form
(16c)
where S is any real number. The quantity S is called the (s-wave)

phase shift, It is in general a function of the magnitude p of the
momentum.
17 Let us investigate how large the elastic cross section can be

in the case of spherically symmetric scattering. The differential
cross section equals \f\2, and the total elastic cross section ae is
obtained by integrating the differential cross section over all direc¬
tions. We thus have [talring (16c) into account]
= S- \eZii - 1i2 (17a)

For a fixed p this quantity assumes its maximum value if 8 is of
the form fi = (n + where n is any integer. The maximum
value equals
(17b)
The above formula refers to a system of units in which fi = 1.

It is very easy to "restore" the constant -fi. It must occur squared
in the numerator because dimensionally the cross section is an area.
With the cgs or MKS system of units we thus have
^ (l^c)
The maximum cross section for spherically symmetric scattering

is thus (1 /if) times the square of the de Broglie wavelength h/p of
the incident particle. For small momenta this cross section can
be very large. On the basis of the wave picture of scattering we
Sec. 9A8 The Elementary Particles and their Interactions 371
can thus easily understand the large cross sections mentioned in

Sec* 6, which may have caused the reader some worry*
18 As we have said the phase shift 8 is a function of the mag¬

nitude p of the incident momentum* Since the incident energy w
is a monotonic function of p we can just as well regard 8 as a func¬
tion of the energy. Let us therefore write 8(w) for the phase shift
to emphasize that it depends on the energy.
Whenever the phase shift, as a function of the energy, passes
through one of the values (n + the cross section assumes the
maximum value given in (17b), We say that the scattering is
resonant at such a point* Let us study the behavior of the scat¬
tering amplitude and the cross section in the immediate neighbor¬
hood of a resonance. We denote the energy at the resonance by wo>
and we thus have S(<oq) = (no + i)rr for some integer no-
We shall rewrite (10c) using the defining relations
rot /Jfi - cos (S) _ e~iS)

i(ei3 +
(18a)
W ” sin (S) “ (g»* - «-«)
for the cotangent. As the reader should immediately convince

himself we can write
J_ (e2iS(w) _ 1) _ (I/?) (18b)

2ip cot [8(o>)] — i
At the point w = wq we have cot [8(<oo)] = 0. We can then try
to expand cot [5(<o)l in powers of (o> — too) in the neighborhood of
the point to = Retaining only the linear term we have
cot [6(to)] s - Tp- (« - Wo) (18c)
where, following established custom, we have written the derivative

of cot [fi(to)] at too as — 2/F,
We shall assume that the phase shift increases with energy in
the neighborhood of the resonance. This means that cot [S(to)]
decreases with energy, and the parameter T which we have intro¬
duced in (18c) is positive* Inserting the approximate expression
(18c) (which is only valid near the resonance) into (18b) we obtain
i / r/2 (18d)
p \ (u — a>o) + iT/2
and
(r/2)*
(18e)
(<o - u0)2 + (r/2)2
The reader will recognize the formula (18e) as the Breit-Wigner

resonance formula (2 Id) in Chap. 3, which we derived there through
a different line of reasoning. The quantity T is the width of the
resonance. In Chap. 3 we associated excited levels with reso¬
nances, and we shall adhere to this idea here. The quantity 1/T = t
is then the mean life of the excited level which manifests itself as
a resonance.
What Is Meant by a Particle?
19 Before we consider the problem of interactions further it is

in order for us to examine our notions of what a particle is. Let
us imagine that we try to formulate reasonable qualifications for
membership in the Set of Particles.
A particle is, in some sense, a “single" coherent object which
has a definite identity, and which can be localized in a limited
region of space at a given time. It is characterized by definite
physical attributes, and we may tentatively require that it should
have a definite mass, a definite charge, a definite intrinsic angular
momentum, etc., and that it should be absolutely stable when alone
in space.
20 Under these rules we would admit the proton, the electron,

the positron, the neutrinos, the photon and the stable nuclei. This
admission procedure raises, however, some immediate problems.
The neutral atoms and all the ions in their ground states also satisfy
the criteria and should thus be admitted. The same applies to all
molecules and molecular ions, in their ground states, and our set
becomes distressingly large if we include these objects as well,
which in all fairness we have to do. On the other hand we would
have to reject an object such as the alpha-active radium nucleus
&§Ra226 on the grounds that it is not stable. This is not satisfactory
because we must admit that it is almost stable (half-life 1622 years),
and from the standpoint of the chemist the radium atom is just as
respectable as the barium atom. Worse still, we would have to
reject the neutron. The neutron is the twin brother of the proton,
and we regard it as one of the building blocks of nuclei. Inside
a stable nucleus the neutron is as stable as the proton, although
it does decay when alone in space. Its mean life is, however, 17
minutes, which is a very long time on a nuclear or atomic time
scale (i.e. long compared to 10-24 or 10_s seconds). In an experi¬
ment in which the phenomenon under study takes plaoe in a time
very small compared to 17 minutes the neutron behaves just like
Sec, 9.21 The Elementary Particles and their Interactions 373
a stable particle. For instance, we can perform diffraction experi¬

ments with neutrons against a crystal.
Finally it can be stated against our admission policy that it could
well happen that some of the “stable” nuclei which we have ad¬
mitted are in fact unstable, although their lifetimes are so long that
we have not yet become aware of their instability. This might
lead to a later expulsion of objects which we have already happily
admitted.
21 In view of the above we realize, as sensible men, that we must

modify our admission criteria. We will now admit objects which
are “just a little bit unstable,” and under the new rules we welcome
the neutron and the radium nucleus. This means that we also give
up our requirement that a particle shall have a definite mass,
because as we have learned in Chap. 3, if a system has a finite life¬
time t, then the energy (in this case the rest energy of the particle)
is defined only within an uncertainty of the order of -S/r. In other
words, if the mean life of a particle is r, then the uncertainty in its
rest mass must be of the order
Am ~ JL (21a)
For the neutron this uncertainty is extremely small; it amounts to

less than 10™27 amu.
22 Once we have given way on the requirement of absolute

stability we find it very difficult to decide just how unstable we will
allow a particle to be. The muon has a half-hfe of about 10-6
seconds which is short on a macroscopic scale but very long on the
nuclear time scale* The same is true of the charged pions, which
have half-lives of about 10-fi seconds. These particles must there¬
fore be admitted. The neutral pion has a mean-life of the order of
10”16 seconds. This is still long compared to 10^24 seconds, and
furthermore the neutral pion is obviously related to the charged
pions. We accordingly admit the neutral pion as well, together
with such particles as the X-mesons and the hyperons, The mean-
lives of the K-mesons and hyperons are generally of the order of
10-10 seconds. Note that the corresponding uncertainties in their
rest masses, as given by Eq, (21a), are still very small compared to
their rest masses.
23 We must now decide whether we should admit all the excited

states of atoms, molecules and nuclei. In favor of their admission
it can be argued that many of the excited states have lifetimes which
Fig. 24A Yield curve for the reaction Al27 + p are very long compared to the lifetime of the neutral pion, or in
Si28 4- y, from a paper by K. J. Brostrom, T. Hu us, fact long compared to the lifetime of the neutron. Some of the
and R. Tangen, “Gamma-Ray Yield Curve of Aluminum
Bombarded with Protons,” Physical Review 71, 661
excited states decay through the emission of material particles,
(1947), The ordinate is a measure of the cross sec¬ and some decay through the emission of photons* Is it fair to
tion for the reaction. The abscissa is the kinetic exclude the excited states if we admit the "ground state” of 88Ra226t
energy of the incident protons, in keV, in the lab frame which also decays through the emission of a particle? Furthermore:
of reference. The sharp peaks are resonances. They perhaps some of the hyperons should be regarded as “excited states”
reveal the existence of excited states in the silicon
of the nucleon? (The hyperons all decay into other particles, one,
nucleus produced in the reaction, (Courtesy of The
Physical Review,) and only one, of which is a nucleon.) We find it very difficult to
resist these pressures, and we accordingly admit the “excited
states,”
24 At this point we realize that our membership has well exceeded

the million mark, which we find disagreeable. If our original
intention was to form a fairly small and manageable society of
respectable particles, this aim has now been thwarted. Further¬
more, our latest concession, to admit the "excited states,” raises
some serious doubts about our entire admission policy. To see this,
let us consider the experimental determination of an excited state,
i.e., an energy level above the ground state of a system. In Chap.
3 we explained how the excited states manifest themselves as
resonances in scattering processes. An example of this is the
resonant scattering of light by an atom. If we measure the effec-
*
tiveness of an atom as a scattered of light, as a function of the N,3/2
frequency of the light, we find sharp maxima at the frequencies
corresponding to the energy differences between the excited states
and the ground state. This phenomenon is, however, not restricted
to the scattering of light: we also encounter it in the scattering of
material particles. Figure 24A shows an example* The ordinate
is a measure of the cross section, and the curve thus shows the
experimentally measured cross section, as a function of the energy,
for the absorption of protons be aluminum. The sharp peaks in the
cross section reveal the locations of the excited states in the silicon
nucleus produced in the reaction.
The width T of a resonance peak measures the uncertainty in the
energy of the corresponding excited state. As long as the reson¬
ances are very sharp the interpretation of the resonances as mani¬
festations of excited states is clear-cut* We have agreed that such
excited states are “particles.” Let us now look at Fig* 24B which Fig, 24B The two curves show the observed cross
shows the cross section for the scattering of pions on protons, as a section in the scattering of positive and negative pions
against protons. The ordinate is the total cross sec
function of the energy* The cross section for positive pions shows tion in millibarns, and the abscissa is the totaf energy
one pronounced peak, as well as a slight “bump” at a higher energy* of the pion and the proton in the center-of-mass sys¬
The cross section for negative pions shows three moderately well tem of reference. It is convenient to express the
defined peaks* Do all these peaks correspond to particles? The in¬ energy in this manner, because the location of a
clination of many physicists today is to say that they do. The prominent peak directly corresponds to the mass of
the “ particle" or resonant state.
masses of these “particles” (?) are simply the abscissas of the Note the large peaks at an energy of about 1.238
maxima* BeV, This energy corresponds to a pion kinetic energy
of about 195 MeV in the laboratory system of refer¬
25 The dilemma which we are facing is where to draw the line* ence in which the incident pion collides with a proton
We certainly do not want to say that every small “bump” in a at rest.
We have denoted these resonances by the symbol
curve showing a cross section as a function of energy corresponds to A^/2- The notation A(1238) also occurs frequently in
a particle, but on the other hand, any rule according to which a the literature.
resonance must be “sufficiently” narrow if we are to accept it as
defining a particle is somewhat arbitrary* In other words; if an
object is to be admitted into the set of particles then its lifetime
cannot be too small, but where do we draw the line?
Let us re-examine our aims* Perhaps nothing is really gained by
trying to define precisely what we mean by a particle in general.
Our attempts have led us to a class of objects with millions of mem¬
bers, containing, among other particles, such qualitatively distinct
objects as pions and protein molecules* According to common
English usage these objects can reasonably be called particles, but
we can hardly expect to learn anything profound about fundamental
interactions if we try to treat pions and protein molecules as
equals in our basic theory* Some of the particles are obviously
composite systems, and we should describe them as such in our
TABLE 26A The Leptons TABLE 26B The Principal Meson Octet
Mass Mass Mean life Principal

Particle Charge Particle
MeV MeV sec decay modes
e- electron —e 0.511 9T+
e+ positron +e 0.511 charged pions 139.60 i

2.61 x 10-*
i
ft~ p- \
—e 105.7 i
muons 77
f»+ 105.7 neutral pion 134.98 0.89 X 10-m
ye+ e~
e-neutrino 0 0
^ e-antineutrino 0 0 V
^ charged ft- it0
493.8 1.23 x 10-8
0 0 „ & mesons
rr
Vp ^-neutrino K~
77± tt+
Vp jti-antineutrino 0 0
7T+ ft~
0.87 X 10-™1
The muons are unstable and decay according to: K°| neutral f*1 IT^TT0
^ f + p, (Of the neutrinos ond is presum¬ *" K-Mesons < 497.9
ably a ^-neutrino, and the other an e-neutrino,) The X°J l** 5.68 X 10-* IT0 77° 7T°
mean life of the muons is 2.20 x 10-fl sec, The 7T+ rr~
other particles are stable. The leptons all have spin ft H V
angular momentum ft e v
7 7
TABLE 26C The Principal Baryon Octet 71
5T°
eta-meson 548,6 < 7 X 10-*° Y7

Principal ff" 57°
Mass Mean life > 7 X 10-21 7T+
Particle decay 7T+ ft- y

MeV sec
i modes
The above mesons have spin angular momentum 0
p proton 938.256 stable and baryon number 0. The two neutral K-mesons
n neutron 939.550 1.01 x 103 pe~P JK° and l?°behave in their decays as if they were "mix¬
tures” of two particles Ki and K2 of different lifetimes
A lambda- pr~ and very slightly different masses.
1115.58 2.51 x 10-10
hyperon twr°
P7T()
2+ 1189.47 0.81 x 10-“
fl7T+
sigma- theory: we should “explain” them in terms of the interactions of
20 hyperons 1192.56 < io-« Ay their more elementary constituents.
From a practical point of view we can think about a hierarchy of
2“ 1197.44 1.65 X 10-10 tw7” increasingly more elementary particles, Depending on the kind of
i physical phenomenon we wish to consider our notion of the “ele¬
1314.7 1 3.0 x 10-“ Ait* mentary constituents” of a composite system changes. It is com¬
cascade
mon English usage to say that a molecule is a bound state of atoms,
r_ particles 1321.2 Ait-
1,7 X 10-“ that an atom is a bound state of a nucleus and a number of electrons,
These particles all have spin angular momentum and that a nucleus is a bound state of protons and neutrons. The
and baryon number +1. There exists an anti'baryon proton, neutron and electron are, however, not in any obvious way
octet consisting of the anti-particles of the above par¬ bound states of anything else: they might well be among the ulti¬
ticles. The anti-particles have the same masses,
mate elementary particles. As such they are objects of particular
spins, and mean lives, but opposite charges and
baryon number. interest in basic theory.
Sec. 9*27 The Elementary Particles and their Interactions 377
26 Let us consider the subset of the (truly?) Elementary Particles 600

among all our particles. Our first principle will be that we do not V
admit any object which is “obviously composite” into this smaller 500-e
and more exclusive set* In Chap. 1 we discussed some experi¬ K~ K°,K° K+
mental criteria for the composite or elementary nature of a particle. > 400 H
to
irH
z
All atoms, all molecules and all nuclei heavier than the proton are ^ 1
clearly composite and hence excluded from our new set. This ^ 300-j
leaves us with about a hundred particles which “are not obviously
composite.” We admit the proton, the neutron, the anti-proton, l mi ir ir° tt+
the anti-neutron* the long-lived hyperons and their anti-particles,
the pious, the K-mesons* the muons, the neutrinos, the electron and 100-=
the positron, and the photon. Except for the proton, the anti¬
proton, the electron, the positron, the photon and the neutrinos, -r-1-n-
all these particles are unstable* but in view of our earlier discussion “I 0 -hi
we shall not use absolute stability as a condition for admissibility. Electric charge
The elementary particles are divided into four classes. The Fig* 27A Mass spectrum of the meson octet to
which the pions and JC-mesons belong. These par¬
photon is the sole member of the first of these. The other classes ticles ell have baryon number zero and spin angular
are the leptonst the mesons and the baryons (including the anti- momentum zero. The two neutral tf-mesons and
baryons)* Tables 26A-C list some of the properties of the leptons indicated by the double line in the term scheme,
and the most respectable mesons and baryons.t (See also Table B have the same mass to the accuracy of this drawing.
in the Appendix.) Particle-antiparticle pairs are symmetrically situated
with respect to the vertical line corresponding to zero
charge. The particles ir° and t? are their own anti¬
27 In Figs. 27A-B the mesons and baryons listed in Tables 26B-C particles. R® is the anti-particle of
are shown in diagrams which strongly resemble the term schemes
discussed in Chap. 3. Each particle is represented by a short
horizontal bar on a graph in which the ordinate is the rest mass
(in MeV) and the abscissa is the electric charge. (The center of
the bar indicates the charge of the particle.)
According to current ideas our particle diagrams should be
>to 2+
regarded as entirely analogous to term schemes for atoms. Each
EQ
diagram corresponds to a “multiplet” of closely related particles .3 A
which might in some sense be regarded as different states of the
“general” particle of the multiplet. 2
Fig. 27C shows the anti-baryon multiplet of eight particles which
are the anti-particles of the eight baryons in Fig. 27B. The anti¬ 1.0^
particles of the mesons shown in Fig. 27A are contained in the n
same diagrams; we say that the meson octet is self-conjugate. The
0.9^ 1-1-T"
negative pion is thus the anti-particle of the positive pion and the - 1 0 + 1
Electric charge
Fig. 27B Mass spectrum of the baryon octet to
t The nomenclature for elementary particles appears to have been invented to give which the proton (p) and neutron («) belong. These
a certain classical Greek flavor to the subject. Although the author's knowledge of the particles all have baryon number +1 and spin angular
classical languages is extremely limited, he nevertheless feels that he has very good momentum The diagram can be interpreted as a
reason to suspect that the linguistic principles which underlie the construction of the term scheme, showing the eight different states of
“Greek”-sounding terms are not entirely correct. the "general particle'f associated with this multiplet
Fig. 27C Mass spectrum of the anti baryon octet

which consists of the anti-particles of the particles
shown in Fig. 27B. The particles in the multiplet at the
right all have baryon number —1 and spin angular
momentum
+
If we reflect the baryon diagram with respect to the 2
vertical line corresponding to zero charge we obtain
the anti-baryon diagram, and vice versa.
A
p n
~1 I T"
- 1 0 + 1
Electric charge
negative K-meson is the anti-particle of the positive Ki-meson. The

particles denoted fCo and Ko form a particle-antiparticle pair. The
neutral pion and the eta-meson are their own anti-particles.
Fig. 27D shows a multiplet of ten baryons which contains the
resonance marked N%/2 in Fig. 24B. The status of these particles
(resonances) is perhaps still open to some doubt, but most physicists
would today be willing to accept them among the elementary
particles.
28 We classify the interactions occurring in nature into strong

interactions {the “nuclear forces” belong to this class), electro¬
magnetic interactions, weak interactions and gravitational inter¬
Electric cl large actions, The mesons, baryons and anti-baryons all interact strongly
Fig. 27D Term scheme showing a multiplet of ten with each other. The photon and the leptons are not affected by
baryons which includes the most prominent reso¬ the strong interactions: their behavior is governed by the electro¬
nances in pion-nucleon scattering. (See Fig. 24B for magnetic and weak interactions. The strongly interacting particles
the pion-nucleon cross sections,) The resonances are
(which are nowadays often referred to as hadrons) also participate
denoted Nt/2 in the diagram. (The symbol A is also
employed in the literature for these particles.) Ah
in the electromagnetic and weak interactions. Many of the un¬
the particles shown have baryon number + 1 and spin stable ones among them decay “via" the weak interactions, and
angular momentum |, consequently have lifetimes which are very long on the nuclear
The regularities in the above pattern of particles time scale.
are very striking. At this time the details are not well The interactions of the elementary particles are governed by a
understood. That the pion-nucleon resonances
number of very striking conservation laws and symmetry principles.
should be included in a multiplet of ten particles can
be understood on the basis of the symmetry principle One of these conservation laws says that the total electric charge
known as the Eightfold Way, The omega-minus par¬ is conserved in all interactions, f There is an analogous conserva-
ticle was in fact predicted theoretically before it was
found experimentally. The mean life of this particle
is 1.5 x 10-w sec. All the other particles in the f Charge conservation is a basic principle of electromagnetic theory. See Berkeley
diagram have extreme/y short lifetimes. Physics Course, Vol. II* Electricity and Magaetisrr^ p. 4, for a discussion.
tion law for baryon number* If we assign baryon number zero to

the photon, the leptons and the mesons, baryon number +1 to the
baryons in Table 26C and baryon number — 1 to the corresponding
anti-baryons, then we can state that the total baryon number is
conserved in all interactions* This principle 4 explains” in a sense
the stability of the proton. Since it is the lightest among the
baryons it cannot decay into any other particles without violating
the conservation principle*
29 The two conservation laws which we have mentioned are

believed to hold for all interactions* Other conservation laws are
known which appear to be characteristic of the different types of
interactions* The conservation of something known as hypercharge
by the strong and electromagnetic interactions is an example* We
can assign a hypercharge quantum number (which is an integer)
to each one of the strongly interacting particles in such a way that
the total hypercharge is always conserved in all strong and electro¬
magnetic processes* The weak interactions, however, do not con¬
serve hypercharge. The diagrams in Figs. 29A-D show the
assignments of the hypercharge quantum numbers to selected
strongly interacting particles.
Let us consider some examples which iDustrate the implications
of conservation of hypercharge. The reaction
ir~ + p ~> K° + A0
(0) (+i) (+i) (0) (29a)
is allowed by the hypercharge conservation principle, and it is well
known to occur readily whenever negative pions of sufficient energy
collide with protons* (The numbers below the symbols for the
particles show their hypercharges*) The reaction Fig* 29A Diagram showing electric charge and
hypercharge of the particles in the meson octet whose
7T- + p tT0 + A0 mass spectrum appears in Fig. 27A, The total hyper¬
(29b) charge is conserved in any strong or electromagnetic
(0) ( + 1) (0) (0)
interaction. The total charge is conserved in aH inter¬
is forbidden by the hypercharge conservation principle* This im¬ actions.
The pattern becomes particularly pleasing to the
plies in particular that a lambda particle cannot be produced in a
mind if the particles are plotted on a hexagonal co
pion-proton collision unless there is sufficient energy available for ordinate net as above. The Eightfold Way theory of
the creation of a £-meson according to the reaction (29a). No symmetries predicts that the pattern should be as
example of the reaction (29b) has ever been observed The reaction shown for such a plot. In particular the theory pre¬
dicts two particles in the center of the diagram, in this
n + p A0 + V case the particles tr° and ij.
(29c) The abscissa expresses another commonly used
(+1) ( + 1) (0) (+1) quantum number called the third component of iso¬
is also forbidden* Tliat it actually does not occur in nature as a topic spin. This quantity (denoted by Ja) is also con¬
served in all strong and electromagnetic interactions.
strong interaction is well established experimentally*
The particles in the diagram all have baryon number
0 and spin angular momentum 0.
Fig. 29B Eightfold Way symmetry diagram for the

baryon octet to which the proton and neutron belong.
It should be clearly understood that the pattern of
particles in a plot of hypercharge versus charge is
determined by the experimenta/Jy observed values of
these quantities. The diagram therefore expresses
experimental results, which, however, fit very nicely
into the Eightfold Way symmetry theory. Note that
the structure of this octet is the same as the structure
of the meson octet in Fig. 29A.
AH the above particles have baryon number + 1 and
spin angular momentum Third component of isotopic spin I5
One of the decay modes of the lambda particle is
A0 iTT~ + P
(29d)
(0) (0) ( + 1)
which violates hypercharge conservation. The weak interactions
are responsible for this decay, as indicated by the comparatively
slow rate at which it takes place. The explanation for the long life¬
time (a mean life of 10™10 sec is long on a “nuclear” time scale)
of the lambda particle is that the principles of conservation of
baryon number and hypercharge prevent it from decaying in any
other way than through the weak interactions*
30 The diagrams in Figs. 29A-D reflect experimentally observed

properties of the particles. They are of a very striking appearance,
and it is clear that we here see a glimpse of some secret symmetry
of nature. We get the same impression if we look at the term
+ scheme in Fig* 27D: note the remarkably regular spacing of the
“2 -1 0 +1 +2 levels*
Third component of isotopic spin At this time we have only a very limited understanding of what
“lies behind” all the tantalizing symmetries and regularities which
Fig* 29C Eightfold Way symmetry diagram for the have been discovered experimentally. There is, however, a phe¬
octet of anti-baryons corresponding to the baryons nomenological theory (known as the Eightfold Way) of the sym¬
shown in Fig. 29B. The anti-partfcles are here indh metry diagrams in Figs. 29A-D, On the basis of this theory one
cated by a bar above the symbol for the particles.
can find all the possible symmetry diagrams, and one can say a
The particles represented on this diagram all have
baryon numbers — 1 and spin angular momentum good deal about the particles which are associated with the dia¬
An anti particle has the opposite charge and the grams* The most striking support of this theory came with the
opposite hypercharge of the corresponding particle. experimental verification of the earlier prediction by Murray Cell-
Pig* 29D Eightfold Way symmetry diagram for the

baryon decupfet to which the main piorv nucleon reso¬
nances belong. The diagram shows the assignments
of hypercharge to the particles in the decuplet. The
masses of these particles are shown in Fig, 27 D.
Mann that the particle denoted f2“ in Figs. 27D and 29D exists.!
31 The elementary particles which we have mentioned (plus

some additional ones) ail appear to be “equally elementary”: none
of them appears to be “composite/7 Some people have neverthe¬
less speculated that there might exist still more elementary entities*
It has thus been suggested by Gell-Mann that the mesons and
baryons might be composite systems made of hitherto unknown
particles which he proposed to call quarks. This is not a wild and
irresponsible suggestion: Gell-Mann had noticed that certain prop¬ Fig. 31A If quarks indeed exist they would have an
Eightfold Way symmetry diagram as shown above.
erties of the mesons and baryons, and in particular the symmetry
The particles in this triplet would all have baryon num¬
principles which govern their interactions, might be explained in ber +£i and presumably spin angular momentum
an esthetically pleasing manner if quarks (and anti-quarks) indeed Note that two of the particles carry electric charge —
existed. According to Gell-Mann's ideas these particles would whereas the third carries charge +f The corre¬
carry the charges ±e/3 and ±2e/3, where e is the charge of the sponding triplet of anti-quarks has a symmetry dia¬
gram which is obtained from the above diagram by a
proton, and in this respect they would differ strikingly from all
reflection with respect to the line corresponding to
known particles. The symmetry diagram for quarks is shown in zero electric charge. The anti-quarks would have
Fig. 31 A* baryon number — The mesons in the octet shown
The search for quarks goes on, but to date none has been found. in Fig. 29A could be regarded as bound states of a
Compared with nucleons quarks must be very heavy: otherwise quark and an anti-quark. The baryons in the octet
shown in Fig. 29B could be regarded as bound states
they would have been “seen” in accelerator experiments. We can
of three quarks.
conclude from this that if a nucleon is indeed a bound state of If the quark theory has any relation to reality, there
must exist at least one stable fractionally charged
particle. No such particle has ever been detected
f V. E. Barnes et al> "Observation of a Hyperon with Strangeness Minus Three," experimentally, and it could well be that fractionally
Physical Review Letters 12, 204 (1964). (It may be mentioned that this paper lists charged particles do not exist At this time the idea
33 authors!) of quarks is pure speculation.
3&2 The Elementary Particles and their Interactions Sec. 9.32
(three) quarks, then the binding energy must be very large com¬
pared to the mass of the nucleon. The nucleon would thus be a
very tightly bound system* and in this respect it would differ radi¬
cally from the bound systems which are familiar to us, namely
atoms, molecules, and nuclei. (The binding energy of an atom, a
molecule, or a nucleus is small compared to the mass of the system.)
It is therefore safe to say that whereas nucleons might one day be
found to be composite, they are certainly not composite in the
same sense as, for instance, the deuteron is composite.
Basic Ideas of Quantum Field Theory
32 Let us next consider some theoretical attempts to understand

the interactions of particles. We shall pursue the idea, which we
arrived at in Sec. 9, that scattering phenomenon should be regarded
as a manifestation of the interaction of waves with waves. The
classical idea of two particles exerting a force on each other corre¬
sponds in quantum mechanics to the idea that the de Broglie waves
of the particles interact. What does this mean? It means that the
presence of a de Broglie wave of one particle influences the propa¬
gation of a de Broglie wave of another particle. This can happen
only if the medium in which the de Broglie waves propagate is
non-linear, i,e. the medium “responds” non-linearly. In a linear
medium, for which the propagation of waves is described by a
linear differential equation, any linear superposition of two waves
is another possible wave, and the presence of one wave does not
affect the behavior of another wave.
33 Let us discuss the nature of the vacuum, or empty space.

When electromagnetic theory was developed in the nineteenth
century the vacuum was known under another name, namely as
the "ether.” When we consider waves it is natural to ask what
it is that “oscillates,” and a physicist of the last century would have
said that it is the ether which oscillates. The behavior of electro¬
magnetic waves in the ether is described by Maxwell's equations.
It appeared natural to the physicists of the time to try to under¬
stand electromagnetism in terms of mechanical models, and to
regard electromagnetic waves as somewhat analogous to elastic
waves in a solid. Much effort went into the construction of such
interpretations. The mechanical properties of the ether certainly
turned out to be quite unlike the properties of any bona fide solid
or fluid, but that circumstance in itself should not be held against
the theory.
One may, however, raise grave objections against the mechanical

theory of the ether on epistemological grounds: consideration of
the mechanical properties of the ether is an unnecessary activity
which adds nothing to our understanding of electromagnetism.
Maxwell's equations by themselves, without any mechanical inter¬
pretation, tell us everything about classical electromagnetic theory
that has any experimental significance. For instance, if we wish
to describe the propagation of radio waves from one antenna to
another, it suffices to solve Maxwell’s equations with the appro¬
priate boundary conditions, and it is of no consequence whether we
have a mechanical model for the wave propagation or not. Phy&-
idsts gradually came to realize that in the study of electromagnetism
all that matters are Maxwell's equations. Consequently the at¬
tempts to construct mechanical models were abandoned, and the
question of “what it really is that oscillates” was recognized to be
an operationally meaningless question.
34 The development of the theory of special relativity did much

to hasten the demise of the mechanical ether theory. Let us recall
the reasons for this. If the ether has any properties at all akin to
those of an ordinary solid, or fluid, then we certainly expect that
there exists an inertial frame with respect to which the ether is at
rest, at least locally. On the other hand, every relevant experi¬
ment seems to indicate that there is no way of determining an
absolute state of motion relative to the ether: all inertial frames
are completely equivalent to each other. This latter statement is,
of course, one of the cornerstones of the theory of special relativity.
If it is really true, which we believe firmly, it means that the moving
ether has the same physical characteristics as the ether at rest, and
this is certainly a property which is foreign to any ordinary solid
or fluid. In view of this fundamental “unmechanical” property
of the ether, it seems senseless to try to assign other mechanical
properties to it.
35 Today the mechanical ether has been banished from the world
of physics, and the word “ether” itself, because of its “bad” con¬
notations, no longer occurs in textbooks on physics. We talk osten¬
tatiously about the “vacuum” instead, thereby indicating our lack
of interest in the medium in which the waves propagate. We no
longer ask what it is that "really oscillates” when we study electro¬
magnetic waves or de Broglie waves. All we wish to do is to for¬
mulate wave equations for these waves, through which we can
predict experimentally observable phenomena. As we have already
said, these wave equations must be non-linear if they are to describe
Elementary Particles and their Interactions Sec. 9.35
Bubble chamber picture showing the production and

decay of an antisigma-zero particle. The insert shows
the reactions, and identifies the various tracks. The
neutral particles (represented by dotted lines in the
schematic figure) of course leave no visible tracks.
The tracks of the charged particles are curved because
the chamber is in a magnetic field perpendicular to
the plane of the figure.
The production reaction, in which the antisigma-
zero particle and a lambda particle result in a collision
of an anti-proton with a proton, is a strong interaction.
The antisigma-zero particle decays by an electro¬
magnetic interaction into an anti-lambda particle and
a gamma ray. The other decay processes seen in the
picture are all manifestations of the weak interactions.
(Photograph by courtesy of Lawrence Radiation Labo¬
ratory, Berkeley.)
interacting particles. The formulation of such wave equations

and the extraction of experimental predictions from them are the
objectives of quantum field theory, which has a claim to being the
fundamental theory of the elementary particles. In this theory the
waves are described by quantum fields, and in a sense the theory
is a quantum-mechanical generalization of the classical theory of
waves.
The idea of describing interacting particles in terms of quantum
fields is attractive in many respects, and we may properly try to
understand the broad features of this theory, A complete discus¬
sion requires somewhat complex mathematical tools which we do
not have at our disposal at this time, and we must therefore omit
all details.
EXPANSION TANK j—EXPANSION VALVE
36 Let us consider, quite generally, the problem of describing an

interaction between two (or several) particles. To orient ourselves f^“ERA CHAMBER
we first consider this problem within the framework of classical COMPRESSOR / Ha SUPPLY
RECOMPRESSlOhr VENTS
physics. In a non-relativistic theory we might introduce position- TANK - LN2
TO VACUUM PUMP
dependent forces acting between the particles. The force acting
on one particle depends on the position of that particle, as well as LIQUID Na JACKET VENT
on the positions of the other particles at the same time. The action VACUUM TANK
of the force is in this case instantaneous; if the position of one LIQUID H£ FLASK
particle is suddenly changed the corresponding change in the force
EXPANSION LINE
is perceived instantaneously by the other particle.
HEAT LEAK
We believe that every fundamental theory of nature must be in
accordance with the principles of special relativity. We note that RADIATION SHIELD
\ X?> *
AT LIQUID N£
an interaction of the kind described above stands in glaring contra¬ TEMPERATURE
CHAMBER BEAM
diction with these principles. No signal can be propagated by a ^7—» .At.
velocity larger than c> and it follows that the action of the force
cannot be instantaneous. If the position, or state of motion, of W/W////////J
one particle suddenly changes it must take some time before this
’©
J
change is perceived by the other particle, and the minimum time it
must take is the time it takes for a light signal to pass between the Schematic picture of a liquid hydrogen bubble cham¬
two particles. ber. The chamber is activated by a sudden decrease
It is not at all a trivial matter to formulate a relativistically invari¬ in the pressure of the hydrogen liquid. The temper¬
ature of the liquid is above the boiling point at the
ant theory of interacting classical particles. A profound change in reduced pressure, but boiling does not start imme¬
the non-relativistic idea of an instantaneous action at a distance is diately: the liquid stays for a short interval of time in
required, a superheated stage. The passage of a charged par¬
ticle through the liquid leads to local vaporization
along the path. A visible track consisting of very tiny
37 One possible way out of this dilemma is through the intro¬
gas bubbles is formed, and it is photographed with
duction of a (classical) field. Each particle is the source of a field the camera above the chamber The pressure is then
which can propagate in space, but never with a velocity greater raised again and all tracks disappear. The chamber
than c, and this field may then influence the motion of other par¬ is ready for the next exposure, (//lustration by cour¬
ticles, In a relativistic classical theory of this kind we are thus led tesy of Lawrence Radiation Laboratory, Berkeley.)
386 The Elementary Particles and their Interactions Sec, 9.38
to consider both particles and fields. The interaction of charged

particles through the mediation of the electromagnetic field is a
good example of such a theory: the charges are the sources of the
electromagnetic field, and the electromagnetic field in turn influ¬
ences the motion of the charged particles,
38 Let us look upon the problem of particle interactions from

another angle. In the classical non-relativistic theory in which we
describe the interaction through a force acting instantaneously the
future behavior of an isolated system of several particles is uniquely
determined if we are given the positions and velocities of all the
particles at some instant of time* In other words, if there are N
particles present the state of motion of the system is determined by
6N parameters: the system has a finite number of degrees of free¬
dom. In a relativistic theory, on the other hand, in which the
interaction is described by a field, it is not enough to merely specify
the positions and velocities of all the particles at a given instant of
time. We must also specify the state of the field. Classical electro¬
magnetic theory illustrates this very clearly: the electromagnetic
field is by no means uniquely determined by only the positions and
velocities of all the charged particles at an instant of time* Among
the initial conditions we must also include the specification of the
electric and magnetic fields everywhere in space* The state of the
electromagnetic field requires, however, an infinite number of
parameters for its description, and our system is no longer a system
of a finite number of degrees of freedom. This is clearly a pro¬
found distinction between the relativistic and non-relativistic
theories*
39 There is another feature of the (classical) relativistic theory

which we should note: part of the total energy of the system will,
at any instant of time, reside in the field. Tîis is necessarily the
case in a theory in which the interaction is mediated through a
field. Consider, for instance, two particles A and B interacting
with each other. Suppose particle A undergoes a sudden collision
with a third particle C which does not interact directly with particle
B* The state of motion of A will then change, and in due time this
change will manifest itself in a change in the field due to particle A
Bubble chamber picture showing the production and p + — A0 + K9. The decay interactions are all
decays of a (neutral) lambda particle and a neutral weak. The negative muon emitted in the decay of
K-meson. The various tracks are identified in the the K° decays into an electron, a neutrino, and an
insert. Only the charged particles leave visible tracks, antineutrino. The last two particles are neutral and
and these are curved because the chamber is in a cannot be seen. (Photograph by courtesy of Lawrence
magnetic field. The strong production reaction is: Rad/arton Laboratory, Berkeley.)
-r
388 The Elementary Particles and their Interactions Sec. 9,40
at the location of particle B. The state of motion of particle B will

therefore also eventually change, and in particular the kinetic
energy of the particle may change. There is thus an exchange of
energy between the two particles A and B, mediated through the
field. If we wish to have a theory in which it makes sense to speak
of the total energy at an instant of time, and if we wish to preserve
the principle that the total energy of an isolated system is a constant
of motion, then we may ask where the energy which is eventually
going to be given to B is to be found during the time which elapses
between the instant A collides with C, and the instant when the
resulting change in the state of motion of A is first felt at B. We
are forced to conclude that this energy must reside in the field.
40 This line of reasoning leads to an interesting further conclu¬

sion. Suppose that the situation is otherwise the same, but that
particle B is absent. At the instant A collides with C the field due
to A undergoes a change: a certain quantity of energy is trans¬
ferred to the field. This quantity of energy must be the same as in
the case when B is present, because particle A cannot very well
“know” that particle B is not there at all, ready to receive (he
energy. Now, if B is not there, where does the energy transferred
to the field go? It has to go somewhere, and one possibility is that
it is radiated away. This is in fact the case in electromagnetic
theory: If a charged particle A collides with another particle C
(which we may assume to be uncharged) the particle A will emit an
electromagnetic wave, and this wave will carry away energy “to
infinity” if there is no other particle present to absorb part of this
energy.
We are therefore led to the very general expectation that if the
interaction between the particles is mediated through a field, then
this field can also manifest itself in the form of freely propagating,
energy-carrying waves.
41 Let us now look at the problem of particle interactions from

the standpoint of quantum mechanics. Our discussion in the
earlier chapters has conditioned us to believe that there is a wave
associated with eveiy particle, and that conversely every wave has
some particle aspects. We may say that the quantum-mechanical
wave is really the same thing as the quantum-mechanical particle:
it is a single object which is neither quite a classical particle, nor
quite a classical wave packet. This now leads us to a most remark¬
able unification in our concepts. In classical physics we introduce
two distinct kinds of objects, namely on the one hand the particles,
and on the other hand the fields which mediate the interactions
Sec. 9A2 The Elementary Particles and their Interactions 389
between the particles. In quantum physics we can avoid this

unsatisfactory dualism by treating the “particles” on the same
footing as the fields. We formulate a field theory which describes
the propagation of wave-fields* which are de Broglie waves of
particles. At the same time the field theory describes the inter'
action between the waves, and thereby, in a sense, describes the
effective forces between the particles.
This is clearly a very attractive idea, and it is the basic idea of
quantum field theory. In the Schrodinger theory the forces be¬
tween the particles have to be introduced ad hoc. Given these
forces we can make predictions about the motion of the particles,
but the Schrodinger theory does not provide us with any “explan¬
ation” of why the forces are what they are. In quantum field
theory* on the other hand, the existence and nature of the forces
is intimately connected with the existence of the particles: we have
a unified description of particles, waves and forces. Quantum
electrodynamics, which is an example of a field theory, provides
us with an illustration of these features. It describes the forces
between electrons (and positrons) mediated by the electromagnetic
field, and it also describes the electromagnetic quanta (photons)
which can be emitted by the interacting electrons.
42 Let us review the main features of a quantum field theory.

To describe particles and their interactions we introduce quantum
fields. The fields are functions of position and time and they de^
scribe, we may say, the heal state of the vacuum, t The wave
aspects of matter are built into the theory from the very beghming:
the solutions to the equations of quantum field theory are waves.
The waves also have particle aspects. A well-localized particle
corresponds to a concentrated wave packet: the particle is most
likely to be found in those regions in space-time in which the field
amplitude is large.
The field equations are non-linear equations and they can thus
describe interactions between wave packets (particles). The non¬
linearity naturally manifests itself only when the field amplitudes
are large: if the amplitudes are small the waves propagate approx¬
imately as in a linear theory. If two wave-packets corresponding
to two particles overlap in a region in space at an instant of time,
the non-linearities become manifest and the two waves influence
f The fields are actually not "ordinary" complex-valued functions of position and
time. They are mathematical objects known as “operator-valued distributions.”
However, for our purposes we can think about them as ordinary functions (representing
“sound waves in the non-linear ether” )♦
each other. In the classical picture this corresponds to an inter¬

action between the two particles. On the other hand the waves do
not interact much if they do not overlap significantly, and to this
corresponds the classical picture that two particles have a very weak
interaction if the separation between the two is large.
43 Quantum field theory is in an essential way a many^partick

theory: we have a single unified formalism through which we can
describe states of the world in which there is any number of par¬
ticles of a given kind present. The phenomenon of creation and
destruction of particles is a natural feature of quantum field theory.
It comes about through the non-linear nature of the field equations.
Two wave packets (corresponding to two particles) may overlap and
interact and give rise to new wave packets (corresponding to new
particles). Thus, for example, if two electrons collide (i.e. come
close to each other) an electromagnetic wave may be emitted.
We say that a photon has been created.
44 Many more or less comprehensive quantum field theories have

been formulated in accordance with these ideas. The theory of
quantum electrodynamics is a theory of this kind, and this theory
has scored some spectacular successes in the description of the
electromagnetic interactions of charged particles, and in particular
in atomic physics. The specific proposals for other field theories,
designed to describe the weak and the strong interactions, have
been much less successful. These theories have provided us with
some understanding of a few very general properties of elementary
particles, but beyond that they have not really led to any useful
experimental predictions. In the case of the strong interactions it
has turned out that the scheme of successive approximations on
which the predictions of quantum electrodynamics have been
based does not work. The reason for the success of electro¬
dynamics is undoubtedly the smallness of the fine structure con¬
stant, i.e. the weakness of the electromagnetic interactions. The
strong interactions are stronger in an essential way. It has there-
Bubble chamber photograph showing the production quently collides with a proton and annihilates into
and subsequent decay of a lambda-antilambda pair, pionsr of which four are charged and leave visible
The drawing in the upper right corner identifies the tracks.
tracks of the various particles. An incoming anti’ This photograph is shown in the middle of our dis¬
proton collides with a proton and produces the lambda- cussion of quantum fields to remind the reader that
antilambda pair. The latter particles do not produce one of the objectives of quantum field theory is to
visible tracks since they are neutral. The lambda give us a theoretical understanding of events such as
decays into a negative pion and a proton (via the weak those seen in the photograph. (Photograph by cour¬
interaction) and the antilambda decays into a positive tesy of Lawrence fiadiafion Laboratory, Berkefey:)
pion and an anti-proton. The anti-proton subse¬
fore not been found possible to solve the field equations which have
been proposed and we cannot tell whether these equations are
really correct. Most likely they are not. There is actually an
infinite latitude in the selection of equations, and our only guiding
principle in the past has been the “principle of simplicity.” In
quantum electrodynamics we have been further guided, in a de¬
cisive way, by the classical analog of charged billiard balls inter¬
acting with the electromagnetic field,
45 The fact that we have been unable to overcome the consider¬

able mathematical difficulties which arise in the theory and actually
solve the specific field equations which have been proposed to
describe the strong interactions has naturally led to a certain dis¬
illusionment with field theory as such, and voices have been heard
urging abandonment of all attempts along these lines.
More weighty objections, of an epistemological character, can be
raised against quantum field theory. One may say that it is object
tionable that many of the primary concepts of this theory do not
have any immediate operational significance. It is thus unclear
how the fields themselves are to be measured: only in certain
specific cases has this problem found an even remotely satisfactory
solution. What do we mean by the field in a very small region,
say of linear dimensions 10-100 cm? How, and with what instru¬
ments, are we to measure the fields in such a region? Who has
really, in any sense of the word, measured distances smaller than
10-13 cm?
These are certainly serious objections. Against them one may
say that it is not really necessary that every concept in a theory
should have an immediate operational significance. Even if it is
hard to see how distances of 10~100 cm could ever be “measured”
it may still be possible to retain our space-time coordinates as
describing the “arena” in which physical events take place* On the
other hand it may also be that a future satisfactory theory of ele¬
mentary particle interactions must be based on the abandonment
of some of our notions of space and time. The quantum field
theories describe in detail what happens at every point in space at
every instant of time, and this may be too much: it may be beyond
our knowledge in principle.
46 Considerations such as these led Werner Heisenberg to try to

formulate, in 1943, the so-called S-matrix theory of particle inter¬
actions. In this theory, which we shall not discuss here, Heisen¬
berg tried to admit only those concepts into the theory which have
a clear operational significance, thereby following the same principle
which in 1925 led him to his formulation of matrix mechanics*

We might say that the theory is concerned only with the outcomes
of collision processes and not with the detailed sequence of events
taking place during the process* So far these attempts have not led
to a satisfactory theory*
At this time there does not exist any fundamental theory of the
strong interactions. Many attempts have made but the results do
not appear particularly convincing* Whether the future ultimate
theory will be a field theory, or an S-matrix theory, or perhaps an
entirely new kind of theory created by one of the readers is futile to
speculate about*
Pions and Nuclear Forces
47 It is out of the question that we could discuss quantum field

theory in any detail in this book: to do this effectively requires
fairly advanced mathematical tools. On the other hand we have
just seen that the basic ideas of this theory are not complicated at
all. Before we leave this subject we shall consider a problem which
was first successfully attacked by Hideki Yukawa in 1934*
The problem is concerned with the following question* Is there
a particle associated with the nuclear force, i.e* a quantum of the Hideki Yukawa. Born 1907 in Tokyo. Yukawa studied
nuclear force field? If so, what are the properties of this particle? physics at Kyoto University, from which he graduated
in 1929. After holding positions as a lecturer at
Can we find the particle experimentally? Kyoto University and Osaka University he was ap¬
We know that there is a particle associated with the electro¬ pointed professor of theoretical physics at Kyoto Uni¬
magnetic forces acting between charged particles, namely the versity in 1939. After World War II Yukawa spent
photon* We also know that the forces which hold the nuclei to¬ some time in the United States as a member of the
gether cannot be electromagnetic in origin. These forces are much Institute for Advanced Study in Princeton, and as a
professor of physics at Columbia University. He re¬
stronger than the electromagnetic forces, and they are furthermore
turned to Japan in 1955 to become director of the
distinguished by their short range* At distances beyond, say, 10”12 newly established Research Institute for Fundamental
cm these forces tend rapidly to zero and become non-existent for Physics in Kyoto, and to resume his position as a
all practical purposes beyond a distance of 10”11 cm* If we now professor of physics at Kyoto University. Yukawa
accept the ideas of quantum field theory we must expect that the was awarded the Nobel prize in 1949 for his work on
mesons and field theory. (Photograph by courtesy
nuclear force field can also manifest itself as freely propagating of Physics Today.)
waves, and we may look for the corresponding particles. Just as
photons are emitted when two charged particles collide we can
expect the quanta of the nuclear force field to be emitted in a suffi¬
ciently violent collision of two nucleons*
48 The reader has very likely heard that these particles do exist,
and that they are none other than the pions* In the days of
Yukawa's work, however, no mesons were known and his sugges¬
tion that they existed was truly a prediction* He knew the two
394 The Elementary Particles and their Interactions Sec . 9.49
outstanding properties of nuclear forces, namely their strength and

short range, and he asked himself the same questions we have
asked. On the basis of his knowledge of the properties of the
nuclear forces he was able to predict the existence of the quanta,
and to predict that their mass should be approximately 200 electron
masses* In this study he was undoubtedly guided by the analogy
with the electromagnetic interaction.
There is an amusing twist to the experimental discovery of
Yukawa's mesons. Around 1937 particles of a mass of about 200
electron masses were discovered in the cosmic radiation and these
particles were naturally thought to be identical with Yukawa s
quanta* Further work revealed, however, that these particles, now
known as muons, or mu^mesons, interact only very weakly with
matter (i*e* with nuclei). Consequently they could not very well
be the particles responsible for the strong nuclear forces. This
mystery was eventually solved, largely through the work of C F*
Powell and co-workers in 1947, when another kind of particle was
discovered in the cosmic radiation.! This particle was the pion*
It has a mass of about 280 electron masses; it interacts strongly with
nuclei and it must without doubt be identified with Yukawa’s
quantum.
By 1948 the development of particle accelerators had reached a
stage where it became possible to produce pions copiously in high-
energy nucleon-nucleon collisions* The properties of pions have
been extensively studied experimentally, and it is now known that
they play an essential role in all phenomena involving strong inter¬
actions.
49 Let us now try to “repeat” Yukawa’s feat*! We shall regard

the force between two stationary nucleons as analogous to the
electrostatic force between two stationary charged particles, and
we shall attempt to solve our problem on the basis of this assumed
analogy. It must be admitted that the analogy is far from perfect,
but this line of reasoning nevertheless leads us to the correct funda¬
mental relationship between the mass of the pion and the nature
of the force between two nucleons*
t G. M. G, Lattes, H. Muirhead, G, P. S. Occhialini, and C. F. Powell, “Processes

involving charged mesons," Nature 159, 094 (1947). Also, C, M. G. Lattes* G. P. S.
Oeehialmi, and C. F, Powell, “Observations on the tracks of slow mesons in photo¬
graphic emulsions/' Nature 160, 453 (1947).
t This will not qualify us for the Nobel prize. It is easy to do something when we
know that it can be done and has been done before. The trick is to be the first to do it.
Yukawa s theory appears in the paper: “On the Interaction of Elementary Particles/'
Proceedings of the Fhy$ico-Mathematical Society of Japan, 17, 48 (1935).
Stfc, 9.50 The Elementary Particles and their Interactions 395
We argue as follows. Maxwell's equations describe freely propa¬

gating electromagnetic waves, in the absence of any sources. The
same equations also describe the electrostatic field of a stationary
point charge, and thereby the potential energy of interaction of
two stationary point charges. In fact the electrostatic potential
due to one of the stationary charges satisfies the wave equation
everywhere outside the charge, and this solution of the wave equa¬
tion has the special properties that it is spherically symmetric and
static, i.e,} independent of the time. Suppose, therefore, that we
consider the wave equation satisfied by freely propagating mesons,
and look for solutions of this equation which are spherically sym¬
metric and static. Hopefully this will give us the potential of the
nuclear force field due to a single nucleon situated at the origin.
We denote the potential by V(r). The interaction energy of two
stationary nucleons separated by a distance r will then be propor¬
tional to V(r), where the constant of proportionality describes the
strength of the coupling of the nucleon to the pion field.
50 The wave equation satisfied by the pion de Broglie wave

function is the Klein-Gordon equation, which we have
already derived and discussed in Chap, 5. If we denote the mass
of the pion by and employ units such that f\ = c — 1, the wave
equation reads
^ $(x,t) — VV(x,f) = (50a)
where V2 stands for the Laplacian operator
(50b)
The wave equation (50a) describes the behavior of de Broglie

waves of mesons in the absence of sources. In accordance with our
program let us now try to find a static, spherically symmetric solu¬
tion of this equation which could describe the meson field outside
a nucleon located at the origin. The source is in this case a point
source, namely the nucleon at the origin, and the wave equation
(50a) need not be satisfied at the origin, but it must be satisfied
outside the origin. We regard the solution as a potential function,
and we shall denote it by V(r). This solution is thus independent
of the time, and consequently die term involving the second time
derivative in equation (50a) can be omitted. Our equation assumes
the form
V2 V(r) = m-jr2 V(f) (50c)
51 The function V(r) is a function of r = vî2 + x22 + X32 only,

and we next have to find the action of Laplace s differential oper¬
ator on such a function. We note first that
_3r_ _ xi
(51a)
axi r
By the chain rule of differentiation we then have
5V(r) = dV(r) dr _ /aA dV(r)

(51b)
3*i dr dx\ \r / dr
Differentiating once more with respect to Xi we obtain

32V(r) = 5 /Xl dV(r)\ _ 1 dV(r) Xl* d (1 dV(r)
(51c)
dx±2 3xi\r dr J r dr r dr\r dr
which gives us
V(f) _ 3 dV(r) d( 1 dV(r)'

(51d)
r dr dr \r dr ,
With a trivial rearrangement of the right side we can write (51d)
in the form
V2 V(r) 1 dfrdVtf
(51e)
r2 dr l dr
This important equation thus describes the action of Laplace s

differential operator on a function V(r) which is a function of r
only.
52 Our differential equation which is now an ordinary, linear,

second-order differential equation is therefore of the form
1 d U dV(r)
m^2V(r) (52a)
r2 dr \ dr
It so happens that this equation can be solved in closed form in

terms of elementary functions, and as the reader should verify by
carrying out the differentiations, two linearly independent solu¬
tions are
^ exp (— rm^T), ^ exp (+ m^) (52b)
The general solution is obtained as a linear combination of the

two above special solutions, Now we note that the second solution
would correspond to a potential which increases beyond any limit
as r increases, and this solution would describe an inter-nucleon
force which increases with the distance* It is clearly not acceptable
physically* and we conclude that the potential must be proportional

to the first solution (52b)* and we thus have
V(r) = C - exp (—rm^) (52c)

r
where C* is a constant.
Our rejection of the second solution illustrates again an import
tant principle which we have encountered before: not every solu¬
tion of the wave equations of quantum mechanics has a physical
meaning. The wave functions which are physically meaningful
not only have to satisfy the wave equation but they must also satisfy
a number of boundary conditions, one of which is that the solution
must not increase indefinitely at infinity.
53 We have now reached our goal: the potential energy U(r) of

two stationary nucleons separated by the distance r is given by
U(r) = exp (- ^-) (53a)
where = l/m^, and where C is a constant which describes the

strength of the coupling.
Due to the exponential factor the potential C7(r) decreases very
rapidly as r increases. Very roughly one may say that the range of
the potential is as we go much beyond this distance the poten¬
tial eventually becomes completely negligible. We have already
examined this point through some numerical examples* in Sec. 38,
Chap. 2.
We know today that the mass of the pion is 140 MeV. The quan¬
tity tin = l/m-n- is nothing but the Compton wavelength of the
pion. (In cgs units we would have ^ Numerically
we have = 1.4 X 10“13 cm, and this is thus the “range” of
the nuclear force field. At the time of Yukawa's prediction he
knew, from a variety of experiments* that the range of the force
field is about 10”13 cm* and he was thus able to predict that the
mass of the hypothetical meson should be about 100 MeV, which
is about 200 electron masses.
We should note that the range is inversely proportional to the
mass of the particle* in this case the pion. A massless particle* like
the photon* mediates a force of “infinite range”: the potential C7(r)
given by Eq. (53a) then becomes the Coulomb potential. This
potential, of course* still decreases with distance but it does not
decrease exponentially. We can thus claim, with justification, that
we have gained a certain understanding of the connection between
the pion and the properties of the nuclear force field.
39$ The Elementary Particles and their Interactions Sec, 9*54
54 We use this opportunity to explain a commonly employed

terminology. Many physicists would say that the interaction be¬
tween two nucleons arises through the exchange of a pion. Simi¬
larly they would say that the Coulomb interaction of two charged
particles arises through the exchange of a photon, These statements
actually merely mean that the interaction between two nucleons
can be found just as we have found it: Le., that the same wave
equation which describes the propagation of free pions (or photons)
also describes forces mediated by the pions (or photons), When
hearing this terminology the reader need not have any visions of
billiard balls being exchanged between two nucleons: it is merely
a figure of speech. Once this is understood there is of course no
harm in talking about “exchanges of particles”; it is a common
practice. If we follow custom we can describe our discoveries as
follows. The forces between two particles which can interact with
each other through their interactions with a third particle can be
said to arise through an exchange of the third particle. The range
of the resulting force is inversely proportional to the mass of the
particle exchanged.
55 There is one point which we should clarify as the reader may

otherwise be bothered by it. Earlier in this chapter we talked much
about the non-linear nature of the equations of quantum field
theory. Nevertheless we found the Yukawa potential, given by the
expression (53a) by solving a linear wave equation. The reader
may therefore have doubts as to whether we have done the right
thing, In fact these doubts are to a certain extent justified. The
linearized theory which we have studied is to be regarded as an
approximation, valid whenever the meson field, or the potential
V(r), is not too large. The Yukawa potential should therefore be
correct at large distances, i,e,? outside the pion Compton wav&-
length, but could possibly be wrong at very small distances. The
truth is that we do not know at present what the interaction is at
very small distances, but we have no reason to doubt that at dis¬
tances larger than say 10-13 cm the effective force is of the same
Bubble chamber photograph showing the annihilation track is hard to distinguish from the pion track, but
of a proton and an anti-proton into pions. The main the beginning of the positron track can be clearly seen.
event takes place in the middle of the field of view. The chamber is in a magnetic field perpendicular
The anti-proton is incident from below, and its path to the plane of the picture. The tracks of negative
is shown by the almost straight “dotted" track. Eight particles turn in the clockwise direction and the tracks
charged pions are produced in the annihilation. One of positive particles in the opposite direction. Slowly
of these, the one whose track is initially directed against moving particles leave dense tracks, whereas the
the direction of the incoming anti-proton, decays into tracks of very fast particles tend to have a “dotted"
a muon and a neutrino. The muon subsequently de¬ appearance. (Photograph by courtesy of Lawrence
cays into a positron and two neutrinos. The muon Radiation Laboratory, Berke/ey.)
general type as the one given by the Yukawa potential, The fact
that we have employed a linear approximation therefore does not
invalidate our main conclusion which was that the range of the
force is inversely proportional to the mass of the particle exchanged.
Concluding Remarks
56 In the preceding chapters we have learned how to think

quantum mechanically about many physical phenomena. Our dis¬
cussion is certainly very incomplete, which should surprise no one
since this is really intended to be an introductory book. There are
many important general principles which we have not discussed
at all, and our discussion of the systematic application of the prin¬
ciples which we have learned is deficient both in scope and depth.
We should remember, however, that quantum physics is a subject
which has been studied intensely during the last 40 to 50 years, and
that an enormous amount of knowledge has been accumulated in
this field. No introductory book could possibly survey this vast
field, and there is therefore much more to be learned through the
simple process of attending lectures and reading books. No reader
should feel either discouraged or offended by this statement: it is
a simple statement of fact.
We have, however, made a good beginning. We have learned
about the wave nature of all physical particles. We have seen how
many physical phenomena which cannot be understood on the basis
of classical physics can be understood on the basis of the wave
picture, and we have also gained a certain understanding of how
the classical laws of physics can arise as “limiting cases” of the
quantum-mechanical laws. We have learned about the energy
levels associated with every physical system, and we have learned
how the occurrence of these levels might be understood within
quantum mechanics. In the course of our studies we have gained
a certain general familiarity with the (at first sight) strange world
of microphysics. We have learned something about the order of
magnitude of physical quantities in microphysics, and we have
learned how to make simple estimates, based on simple models.
The reader who has worked his way through the book to the end
of the final chapter has had a glimpse of some of the most central
issues of modern physics. He has learned that physics is not a
closed subject; many basic problems exist for which no solutions
are in sight at this time.
The author concludes by wishing the reader Happy Future
Studies in Quantum Physics.
Chap. 9 References for Further Study 401
1) D. H, Frish and A. M, Thorndike; Elementary Particles (D. van Nostrand Co.^

Inc., 1964}* This little book (148 pages) presents a simple, up-to-date account, and is
hereby recommended Experimental techniques in this field are nicely described.
2) Note the following articles in the Scientific American:
a) F. J. Dyson: "Field Theory,” April 1953, p. 57.
b) G. F. Chew, M. Gell-Mann and A. H. Rosenfeld: "Strongjy Interacting Particles,"
February 1964, p, 74.
c) M. Gell-Mann and E. P. Rosenbaum; "Elementary Particles,” July 1957, p, 72.
d) G. Feinberg and M. Goldhaber: “The Conservation Laws of Physics," Oct. 1963,
p. 36.
e) F. J. Dyson: “Mathematics in the Physical Sciences,” September 1964, p. 128.
f) W. B. Fowler and N. P. Samios: "The Omega-Minus Experiment,” October 1964,
p. 36.
g) K. W- Ford: "Magnetic Monopoles,” December 1963, p. 122.
h) G. W. Gray; "The Ultimate Particles,” June 1948, p. 26.
i) H. A. Bethe: “What holds the Nucleus Together?" Sept. 1953, p. 58.
j) R. E. Marshak: “The Nuclear Force,” March 1960, p. 98.
k) S. Penman: “The Muon,” July 1961, p, 46.
Problems
1 (a) Compute the transmission probability for neutrons of energy 0.1 eV

incident normally on a cadmium foil of thickness 0*1 mm. The density of
cadmium is 8.7 gm/cm3. Obtain neutron cross section from Fig, 6A.
(b) Similarly compute the transmission probability for neutrons of energy
1 eV incident normally on a 1 cm thick sheet of cadmium,
2 The total cross section for the interaction of a K+-meson with a proton
is about 15 mb when the kinetic energy of the K-meson (incident on a proton
at rest) is 400 MeV. What is the average number of interactions per cm of
path for a K-meson of this energy in liquid hydrogen (in a bubble chamber)?
The density of liquid hydrogen is 0.071 gm/cm3.
3 The cross section for the production of an electron-positron pair when

a gamma quantum of energy 10 MeV collides with a lead atom is about
14 bams. What is the probability that a pair is produced when a gjamma
ray of this energy is incident normally on a lead plate of thickness 2.5 mm?
The density of lead is 11.3 gm/cm3.
4 At a gamma ray energy of 100 keV the cross section for Compton
scattering was measured in one experiment as 0.49 bam. At this energy,
which is considerably smaller than the rest energy of an electron, a simple
non-relativistic classical computation comes close to the right value. Try to

carry out such a computation to see how close you can come* In Compton
scattering a gamma ray is scattered by a “free” electron originally at rest.
(We discussed the Compton effect in Chap. 4, but we did not discuss the
cross section for the scattering.) Suppose a plane wave of amplitude A and
frequency w is incident on an electron originally at rest. The electron will
be set in oscillatory motion in the direction of the electric vector of the wave¬
let the amplitude of this oscillation be x. The quantity x is obviously pro¬
portional to the amplitude A of the wave, and in addition x depends on the
frequency to and on the mass and charge of the electron. The oscillating
electron acts like an electric dipole of dipole moment ex. This dipole emits
electromagnetic radiation at a total rate W. (We quoted the formula for
this rate in Sec. 48, Chap* 3.) You should thus be able to compute what
fraction of the energy incident through a unit area (containing the electron)
will be scattered by the electron. Reêxpress your result in terms of a cross
section for the scattering; this is the Compton cross section. The Compton
cross section for an atom is the product of the cross section for an electron
with the number of electrons in the atom.
5 (a) In Sec, 17 we presented a simple theory for the maximum cross

section for the case that the scattering is spherically symmetric. It is of
interest to compare this theory to the experimentally measured tf+-p cross
section shown in Fig, 24B. We simplify the problem by regarding the proton
as infinitely heavy. The relevant energy in the scattering is then the kinetic
energy of the positive pion, which is about 195 MeV (in the laboratory frame
of reference) at the location of the prominent resonance denoted iV|/2. Carry
out such a comparison. You will find that the order of magnitude is right,
but that the experimental cross section differs from the theoretical cross
section by “a factor of order unity,” The explanation for the discrepancy
is simply that the scattering is noJ spherically symmetric. Our simple theory
would have to be modified to include other possible angular distributions*
With such a modification it is found that the experimental cross section at
maximum agrees well with the- theoretical prediction,
(b) On the basis of the curve shown in Fig. 24B, estimate the mean life
of the N*-“particle*”
6 Using our simple theory in Secs. 17-18 for resonant scattering, esti¬
mate the cross section for the resonant absorption of gamma rays of energy
14.4 keV by the Fe57 nucleus. (This estimate is relevant to the experimental
results presented in Fig. I6A, Chap. 4.) Assuming that the absorbing iron
nuclei are in a foil 1 mil thick, what is the probability that a gamma ray passes
through the foil?
Note that our simple theory does not really apply to photons, among other
things because photons have spin angular momentum one. You can there-
The Elementary Particles and their Interactions 403
fore not expect to obtain a numerically correct value for the cross section.
The dependence of the maximum cross section on the wavelength is how¬
ever given correctly by our theory, and your estimate is therefore useful as
an order of magnitude estimate,
7 The maximum cross section for resonant scattering of light by an atom

can obviously be very large because of the long wavelength of visible light*
Let us consider the case of resonant scattering of yellow light of wavelength
5896 A by sodium atoms,
(a) In the spirit of the preceding problem, estimate the maximum cross
section at resonance.
(b) In an actual experiment we might have sodium vapor in a glass vessel
as our "target” in the scattering experiment. (Consider, for instance, the
experimental arrangements described in Frob* 3, Chap, 3*) The sodium
atoms will not all have the same velocity, and as a result the Doppler shift
will broaden the absorption line. The mean life of sodium in the 3pi/2_state
is about 10-s sec. From this you can compute the width of the line for an
isolated sodium atom at rest. Suppose that the incident light has this line-
width* Suppose further that the atoms in the, absorbing vessel have an aver¬
age random velocity corresponding to a temperature of 200° C, Estimate
the effective scattering cross section which an atom in the vessel presents to
the photons in the incident beam,
(c) Using the estimate of the effective cross section obtained in part (&)
above, find the number of sodium atoms per cm3 which have to be present
in the vessel in order that the intensity of the incident light be reduced by
a factor two in passing through a layer of gas I cm thick. Needless to say
such a gas is completely transparent to light of any other wavelength than
the resonant wavelength*
8 Consider the particles forming the baryon octet for which the mass
spectrum is shown in Fig, 2715 and the Eightfold Way symmetry diagram in
Fig, 29B, Of these particles one is stable. Among the remaining unstable
particles one decays through an electromagnetic interaction (it has a notably
shorter lifetime than the other particles) and the others decay through the
weak interaction. See whether you can account for these features of the
octet in tenns of the conservation laws for baryon number, charge, and hyper¬
charge which we have mentioned* To do this you should investigate all
possible decays you can think of into particles which have been mentioned
in the text, taking into account the experimentally determined masses of
these particles. For example: you might begin by asking whether the 2+
particle could decay into a K+-meson and something else. You will soon
discover that the possibilities are severely limited, and that there are not too
many cases to consider.
The problem is thus to show in detail that the conservation laws which
404 Chap, 9 Problems
we have discussed imply that none of the particles can decay through the
strong interaction, and that only one can decay through the electromagnetic
interaction,
9 The symmetry diagrams in Figs, 29A-D show the values for the various
particles of a quantity called the third component of isotopic spin (denoted
h)- We have mentioned that this quantity is also conserved in all strong
and electromagnetic interactions.
Investigate whether this conservation law implies anything more than the
other conservation laws which we have mentioned and which concern con¬
servation of charge, hypercharge, and baryon number*
10 In the literature on the elementary particles an attribute called

"strangeness" is often used to characterize the strongly interacting particles.
Each such particle can be assigned a strangeness quantum number S, which
we can define by S = Y — B, where Y is the hypercharge and B the baryon
number. According to this rule the pions and the nucleons have strangeness
zero: they are not strange but '‘familiar."
(a) In what kind of interactions is total strangeness conserved?
(b) There is a simple linear relation between strangeness S, electric charge
Q, baryon number Bt and third component of isotopic spin 13, Find this
relation (as it reveals itself in the symmetry diagrams in Figs, 29A-D).
11 We want to produce lambda-particles in proton-proton collisions.

What is the minimum kinetic energy which a proton incident on a proton
at rest must have for this to be possible?
12 (a) In Sec. II we guessed that a scattered wave must be of the foim
= Cf(0) - exp (ixp — tcoi) (a)
at large distances from the scattering center. Show that for the special case
of spherically symmetric scattering, in which f{0) = / is independent of the
scattering angle 6, the wave function given in (a) is actually a solution of the
KJein-Gordon equation (except for the point x = 0) in empty space. It will
be helpful to consider our discussion in Secs, 51-52 in this connection,
(b) Show that for an arbitrary f[8) the expression in (a) is an approximate
solution of the Klein-Gordon equation. You should show that if this wave
function is substituted into the Klein-Gordon equation, then the equation
is satisfied except for an error term which tends to zero as 1/x2 when x tends
to infinity.
Appendix
A. General Physical Constants 406
B. The Most Stable Elementary Particles 40S
C The Chemical Elements 410
For tables of units and conversion factorSj see inside back cover of book.
For a table of crude values of important physical constants, see inside front cover of book.
406 Appendix
TABLE A General Physical Constants*
Planck's constant: h = (6.62559 ± 0.00015) x 10-2T erg sec

ft = = (1.05449 ± 0.00003) x 10-21 erg sec
Velocity of light: c = (2.997925 ± 0.000001) x 1010 cm sec-1
Electronic charge: e = (4.80298 ± 0.00006) x 10-10 esu

= (1.60210 ± 0.00002) x 10-lfl coul
Gravitational constant: G — (6+670 d= 0,005) x 10-8 dyne cm2 gm™2
Fine structure constant: a = = (7.29720 ± 0.00003) X 10-*
- = 137.0388 ± 0.0006
a
Avogadro's number: No = (6-02252 ± 0.00009) x 10M mol-1

Boltzmann's constant: k = (1.38054 ± 0.00006) x 10~ie erg {” K)-1
Faraday constant: Nê - (96487.0 ± 0.5) coul mol-1
Universal gas constant: R = Nok = 8.314 x 101 erg ("K)-1 mol-1

= 1.986 ca!(°K)-! mol-1
Mass of electron: m = (9.10908 ± 0.00013) X 10-2Sgm
= (5.48597 ± 0.00003) x 10-* amu
= (0.511006 =t 0.000002) MeV/c2
Atomic mass unit: (amu) = (1.66043 ± 0.00002) x lO-2* gm

= (931.478 ± 0.005) MeV/c2
Proton mass: Mp = (1.67252 ± 0.00003) x 10-2* gm

= (1.00727663 ± 0.00000008) amu
= (938.256 ± 0-005) MeV/c2
* Most of the data in this table are taken from an article by E. R. Cohen and J. W. M. DuMond, “Our Knowledge of the Fundamental
Constants of Physics and Chemistry in 1965,” Reviews of Modem Physics 37, 537 (1965).
Appendix 407
TABLE A General Physical Constants ficontinued)
Neutron mass: Mr - (1.0086654 ± 0.0000004) amu

= (939.550 ± 0.005) MeV/c*
Compton wavelength of electron: X. = -A- = (2.42621 ± 0.00002) x 10-10 cm

me
Ke = — = (3.86144 ± 0.00003) x 10-11 cm
me
First Bohr radius: a0 = —z -

me~
= (5.29167 ± 0.00002) X 10-9 cm
“Classical radius” of electron: = aXe = (2.81777 ± 0.00004) X 10"13 cm

me2
Non relative stic ionization potential of hydrogen

with infinite proton mass: Rx = ia2mc2 ~ (13.60535 ± 0.00013) eV
Rydberg constant for infinite proton mass: fl«,= -q~- = = (109737.31 ± 0.01) cm-1
Rydberg constant for hydrogen: R-a = (109677.576 ± 0.012) cm-1
Bohr magneton: _ eH
^B 2me
— (9,27314 ± 0.00021) x 10-21 erggauss-
Frequency associated with 1 eV: (2.41804 ± 0.00002) x 1014 cycle/sec

Wave number associated with 1 eV: (806573 ± 0.08) cm-1
Temperature associated with 1 eV: (11604.9 ± 0.5) °K

408 Appendix
TABLE B The Most Stable Elementary Particles*
Important Decays t
Mass Mean life Partial Branching Q
Particle Spin MeV sec mode fraction MeV
r photon 1 0 stable stable
LEPTONS
e- neutrino 1 0 « 0.2 keV) stable stable
v* ji-neutrino 2 0 « 2 MeV)
e+ electron-positron 1 0.511006 stable stable
2
muons 1 105.659 2.20 x 10-» eyp 100% 105

2
BARYONS $
p proton i 938.256 stable stable
n neutron 2 939.550 1.01 x 103 pe~p 100% 0.78
A lambda-hyperon 1 1115.58 2.51 x 10-10 pn~ 66% 30
2 34% 41
Pfw 1.4 x 10-4 72
pev 0.88 x 10-3 177
sigma-hyperons 1189.47 0.81 x 10-10 p-17° 53% 116
nir+ 47% 110
1
1 Py 1.9 X lO"3 251

20 2 1192.56 < 1.0 x 10-m Ay 100% 77
2- 1197.44 1.65 X 10-w 100% 118
1.3 x 10-3 257
ESI
mgm 0.6 x 10-3
0.6 X 10-4
152
81
jo cascade particles 1314.7 3.0 x 10-10 Aw° 100% 7
i
(■ “
2 1321.2 1.74 X 10-io Air~ 100% 5
Ae~v 3.0 x lO-3 205
J2~ omega-minus 3 1674 1.5 X lO"10 il77 -50% 221

2 AK -50% 66
Appendix 409
TABLE B The Most Stable Elementary Particles (continued)
Important Decaysf
Mass Mean life Partial Branching Q

Spin MeV sec mode fraction MeV
Particle
MESONS
0 139.58 2.608 x 10-8 pv 100% 34
charged pions
ev 1.24 X 10-* 139
pvy 1.24 x 10-4 34
1.0 X 10-8 4.08
134.98 0.89 X 10~16 yy 98.8% 135

77° neutral pion 0
ye+e- 1.2% 134
0 493.8 1.235 X 10-® pv 63.4% 388

charged kaons
?r±7ft 21.0% 219
(K-meson)
77±17,“77 + 5.6% 75
ttW 1.7% 84
prw <V 3.4% 253
: e=t7r°j' 4.8% 358
1
K° neutral kaons 0 497.9

0.87 X 10-10 77+77” 69.3% 219
30.7% 228
5.68 x 10-8 77%°^ 23.5% 93

fV2
77+ 77“77 0 11.5% 84
TTflV 27.5% 253
wev 37.4% 358
77 + 77“ 0.15% 219
•
77%° 0.36% 228
0 548.6 < 7 x 10-20 yy 31.4% 549

u eta-meson
> 0.7 X 10-20 77 21.0% 144
7T°y7 20.5% 414
77+77” 77° 22.4% 135
77+77“Y 4.6% 269
.1_
t Q stands for the kinetic energy released in the decay,
t To each one of the baryons corresponds an anti-baryon, not listed separately. l( .
*The data in this table are taken from a survey article by A. H. Rosenfeld et al., "Data on Particles and Resonant States, Reviews of
Modem Physics 39, 1 (1967). Data for many more particles are presented in this article. Additional information about the particularly stable
particles is also given. Some of the rarer known decay modes have been omitted from our table.
410 Appendix
TABLE C The Chemical Elements
Atomic Atomic mass* Atomic Atomic mass*

Element Symbol Element Symbol
number amu number amu
Actinium Ac 89 (227) Erbium Er 68 167.26

Aluminum Al 13 26.9815 Europium Eu 63 151.96
Americium Am 95 (243) Fermium Fm 100 (253)
Antimony Sb 51 121.75 Fluorine F 9 18.9984
Argon Ar 18 39.948 Francium Fr 87 (223)
Arsenic As 33 74.9216 Gadolinium Gd 64 157.25
Astatine At 85 (210) Gallium Ga 31 69.72
Barium Ba 56 137.34 Germanium Ge 32 72.59
Berkeiium Bk 97 (247) Gold Au 79 196.967
Beryllium Be 4 9.0122 Hafnium Hf 72 178.49
Bismuth Bi 83 208.980 Helium He 2 4.0026
Boron B 5 10.811 Holmium Ho 67 164.930
Bromine Br 35 79.909 Hydrogen H 1 1.00797
Cadmium Cd 48 112.40 Indium In 49 114.82
Calcium Ca 20 40.08 Iodine 1 53 126.9044
Californium Cf 98 (251) Iridium lr 77 192.2
Carbon c 6 12.01115 Iron Fe 26 55.847
Cerium Ce 58 140.12 Krypton Kr 36 83.80
Cesium Cs 55 132.905 Lanthanum La 57 138.91
Chlorine Cl 17 35.453 Lawrencium Lw 103 (257)
Chromium Cr 24 51.996 Lead Pb 82 207.19
Cobalt Co 27 58.9332 Lithium Li 3 6.939
Copper Cu 29 63.54 Lutetium Lu 71 174.97
Curium Cm 96 (247) Magnesium Mg 12 24.312
Dysprosium Dy 66 162.50 Manganese Mn 25 54.9380
Einsteinium Es 99 (254) Mendel evium Md 101 (256)
The numbers within parentheses in the atomic mass column arc the mass numbers of the most stable isotopes of radioactive elements.
Appendix 411
TABLE C The Chemical Elements (continued)
Atomic Atomic mass* Atomic Atomic mass*

Element Symbol Element Symbol
number amu number amu
Mercury Hg 80 200.59 Samarium Sm 62 150.35

Molybdenum Mo 42 95.94 Scandium Sc 21 44.956
Neodymium Nd 60 144.24 Selenium Se 34 78.96
Neon Ne 10 20.183 Silicon Si 14 28.086
Neptunium Np 93 (237) Silver Ag 47 107.870
Nickel Ni 28 58.71 Sodium Na ii 22.9898
Niobium Nb 41 92.906 Strontium Sr 38 87.62
Nitrogen N 7 14.0067 Sulfur s 16 32.064
Nobelium No 102 (255) Tantalum Ta 73 180.948
Osmium Os 76 190.2 Technetium Tc 43 (98)
Oxygen 0 8 15.9994 Tellurium Te 52 127.60
Palladium Pd 46 106.4 Terbium Tb 65 158.924
Phosphorus P 15 30.9738 Thallium Tl 81 204.37
Platinum Pt 78 195.09 Thorium Th 90 232.038
Plutonium Pu 94 (244) Thulium Tm 69 168.934
Polonium Po 84 (209) Tin Sn 50 118.69
Potassium K 19 39.102 Titanium Ti 22 47.90
Praseodymium Pr 59 140.907 Tungsten W 74 183.85
Promethium Pm 61 (145) Uranium u 92 238.03
Protactinium Pa 91 (231) Vanadium V 23 50.942
Radium Ra 88 226.0254 Xenon Xe 54 131.30
Radon Rn 86 (222) Ytterbium Yb 70 173.04
Rhenium Re 75 186.2 Yttrium Y 39 88.905
Rhodium Rh 45 102.905 Zinc Zn 30 65.37
Rubidium Rb 37 85.47 Zirconium Zr 40 91.22
Ruthenium Ru 44 101.07
The numbers within parentheses in the atomic mass column are the mass numbers of the most stable isotopes of radioactive elements.
Index
Absolute motion, 383 Angular momentum (continued)

Absolute temperature, 22, 52 quantum numbers, 115, 341
Absolute zero, 22, 53 selection rules, 115, 134
Absorption and emission of light, 96,403 and symmetry principles, 134
KirchhofFs law, 24 Annihilation, 8, 158, 390
Absorption spectra, 99 of antineutron and proton, 161
Abundance of elements, cosmic, 302 of antiproton and proton, 391,399
terrestrial, 303 star in photographic emulsion, 161
Acoustically modulated gamma-rays, 151 Antibaiyons, 160, 376, 378, 380
Actinide elements, 121 Antilambda, 376, 391
Action, 14 Antineutrino, 126, 376
Action at a distance, 385 Antineutron, 162, 376
Age of earth, 301 Antiparticle, 160, 376
Ajzenberg, Ft, 124, 136,139 Antiproton, 160, 162, 358, 361, 376, 391,398
Alkali atoms, 117,120 Armenteros, R., 358, 361
Allowed transitions, 113, 136 Aston, F. W.j 67
Alpha-particles, cloud chamber photo, 293 Atomic mass, weight, 45
counting, 40 tables, 45, 46, 410
discovery of transmutations of nuclei, 7 Atomic mass unit, 47, 406
range in air, 293 energy equivalent, 51, 406
scattering by nuclei, 32, 88 Atomic number, 46, 66,121, 122, 410
Alpha-radioactivity, 292 Atomic radii, 32, 35, 58, 62,230
barrier penetration, 294 Atomic spectra, 94 (See also Spectra; Spectrum)
decay of radium, 40, 85, 86 absorption and emission, 99, 100
evolution of heat, 85 Atomic standards of measurement, 82
fine structure in decay of bismuth, 125 Atomic structure, Bohr theory, 32, 58,139
lifetime versus energy, 297 Schrodinger theory, 313, 339
typical emitters, 298 uncertainty relation, 231
Aluminum, cross section for protons, 374 Atomic weight, 45 (See also Atomic mass)
Amplitudes and intensities, 249 Atoms, energy levels {see Energy levels)
Anderson, C. D., 158, 177 of Greek Atomists, 5
Angstrom, A, J., 30 hydrogen-like, 339
unit of length, 30 muonic, 343
Angular distribution in light emission, 133, 140 size and stability, 32, 58, 231
Angular distribution in scattering, 362, 366 Attenuation of beam passing through matter, 361
electrons on calcium, 365 Averages of physical variables, 236, 244
neutrons on bismuth, 364 Avogadro’s number, 6,19, 47, 406
pions on protons, 366 determination, 20, 21, 27, 40
Angular frequency, 48
Angular momentum, 14, 35,115 Balmer series, 340
of diatomic molecules, 336 Band spectra, 98, 338
orbital, spin, total, 115 photograph, 99
414 Index
Barkla, C. G., 155 Broadening of spectra lines, 127 (Se£ also Line widths)
Bam, 362 de Broglie, VP, 181
Bames, V, E., 381 biography, 183
Barrier penetration, 288 theory of matter waves, 181
and alpha-radioactivity, 392 wavelength, 185-187
optical analog, 290 Brostrom, KP JP, 374
transmission coefficient, 292 Bubble chamber design, 385
Barrow, G. M., 350 Bubble chamber picture, charge exchange scattering, 162
Baryon number, 379 antisigma-zero, 384
Baiyons, 376-381, 408 lambda and jK-meson, 387
Bearden, J. A,, 158 lambda-antilambda pair, 391
Becquerel, H,, 39 proton-antiproton annihilation, 399
Bellicard, J* B., 365 Burbidgc, E* M., 307
de Benedetti, S., 137 Burbidge, C. R., 175, 307
Beta decay, 125, 300
of cobalt, 127 Cadmium atom, energy levels, 120
evolution of heat, 310 Calorie, 52
Beta particle, beta rays (see Electron- Beta decay) Cascade particle, 376
Beta spectroscopy, 246 Cascade shower, 8
Bethe, H+ AP, 401 Cerenkov counter, 176, 358
Bilaniuk, O. M., 262 Cerenkov radiation, 176
Binding energy, in atoms, 58, 62, 102, 123, 230 Cerium atom, portion of spectrum, 111
of deuteron, 103, 352 Cesium chloride crystal structure, S3
of molecules, 64, 330 Chadwick, J+, 66
of nuclei, 66,102, 232 Chain reaction, 89
Black-body radiation, 23 Chamberlain, (X, 160
Planck's radiation law, 26 Chambers, R. G*> 203
Bloom* A. L,, 137 Characteristic X-ray radiation, 156
Bohr, N., 35, 95 Charge, of electron, 19, 20,45, 57,406
biography, 35 of elementary particles, 376—381
correspondence principle, 349 fractional, 381
prediction of hafnium, 121 of nuclei, 66, 123
theory of atoms, 32, 58, 139 Charge conservation, 80, 378
theory of emission and absorption of light, 95 Charge exchange scattering, 162
Bohr magneton, 90 Charge independence of nuclear forces, 71, 124
Bohr radius, 35, 58, 407 Chemical elements, 46
Bohr-Sommerfeld quantum condition, 328 origin, 303
Bolef, D. I., 151 periodic chart, 121
Boltzmann, L., 6 shell structure, 122
Boltzmann’s constant, 23, 52,406 tables, 45, 46, 410
determination, 27 Chemical reactions, 6
Boorse, H. A., 39, 122, 174 bulk reaction energies, 65
Born, M., 215,272 Chew, G, FP, 401
biography, 272 Classical physics, 2
Bom*Oppenheimer approximation, 331 limiting case of quantum physics, 229,349
Boron nucleus, energy levels, 124 Classical radius of electron, 13, 34, 407
Boundary conditions for wave functions, 282, 284, 287, Cloud chamber picture, alpha emission, 293
304, 314, 318, 397 cascade shower, 9
Brackett series, 340 positron, 158
Branching ratio, 120, 125 Cohen, E. R,, 85,406
Breit-Wigner formula, 109, 371 Coherent superposition, ensembles, 249
Bremsstrahlung, 10, 156 light, 253, 262
Brillouin, L>, 328 Collins, G. B., 175, 262
Index 415
Collision broadening of spectral lines, 128 Crystal lattice (continued)

Collision cross section, 359 (See also Cross section) diamond, graphite, 21
Collision experiments, 358, 363 sodium chloride, 20
Collision processes (See also Scattering) Crystals, 5
and barrier penetration, 299 and Avogadro’s number, 21
conservation laws, 198 as diffraction gratings, 21, 187,191
Combination principle, 95 Curie, M, 86
Compton, A. H,, 153,154 Curie, P., 86
Compton effect, experiments, 153
theory, 152 Damped oscillator, 106
Compton wavelength, 152 Darrow, K, K+, 216
Condon, E. U,, 299 Daughter nucleus, 125
Conjugate variables, 42 Davis, S, P., 97,98, 99
Conservation, of angular momentum, 114 Davisson, C, J,, 187
bar yon number, hypercharge, 379 Davisson-Germer experiment, 187
charge, 80, 378 Debye-Scherrer method, 189
energy in beta decay, 310 Decay constant, 39, 299
energy and momentum, 198 Decay modes, baryons and mesons, 376, 408-409
Constants of nature, 78,406—407 Destruction phenomena, 8, 390
Continuum of energy levels, 102 Detectors {see Particle detectors)
Correspondence principle, 349 Deuterium, 87
Cosmic rays, discovery of pions and muons, 394 Deuteroo, binding energy, 79,103
photograph of shower, 9 ground state, 352
Coulomb barrier in nuclear reactions, 88, 294,299 term diagram, 103
Coulomb energy of nuclei, 88 Diatomic molecules (see Molecules)
Coulomb’s law and exchange of photons, 398 Differential cross section, 363 (See also Cross section)
Counters (see Particle detectors) Differential operators, 206, 318, 347
Coupling constants, 79 eigenvalues, 318
beta decay, weak interactions, 126 energy, 347
electrodynamics, 57, 269 momentum, 346
gravitational, 73 Diffraction, in crystals, 21, 188-190, 194-197, 201
meson Held, strong interactions, 72, 79,392 in periodic structures, 191
Courant, R., 216 in slit-systems, 106,172,177, 203, 228, 239, 249-253
Cranberg, L., 364 Diffraction of atoms and molecules, 190
Creation phenomena, 8, 159, 384, 386,390 Diffraction of electrons, discovery, 187
and field theory, 390 effect of grain size, 196
Critical potentials, 101 effect of thermal fluctuations, 239
Cross section, 359 in nickel crystal, 194
Breit-Wigner, 109, 371 in tin, 196
differential, 363 Diffraction of X-rays, 21
elastic, inelastic, reaction, 361 Debye-Scherrer method, 189
geometric interpretation, 360 in tin, 190
in terms of phase shift, 370 Diffraction grating, 219
total, 359 Dimensional arguments, 60
Cross section graphs, electrons on calcium, 365 Dipole moment in atoms, 131
neutrons on bismuth, 364 Dipole radiation, 114, 130
neutrons on cadmium, 362 Dirac, P, A, M.? 213
neutrons on silver, 363 equation, 269
pion-proton, 366,375 Discrete energy levels, 95, 312 (See also Energy levels)
protons on aluminum, 374 Dissociation energy of molecules, 65, 330
Crowe, K., 85 Dissociation limit, 124, 330
Crystal lattice, 21, 191 Doppler broadening of spectral lines, 127,242
cesium chloride, 83 Doppler shift of frequency, 143
416 Index
Driven oscillator, 108 Electron microscope, resolving power, 217

Diiker, H., 203 Electron-proton mass ratio, 20
Dumb-bell molecule, 335, 355 Electron spin, 115
DuMond, J. W. M,, 85, 406 Electron volt (eV), 49
Dynamical variable, 14 Electronic configuration in atoms, 122
associated differential operator, 346 Electrostatic energy, of electron, 12
Dyson, F. J., 401 of nuclei, 88
Elementary charge, 19
Earth, age, 302 Elementary particles, 5, 372
composition of crust, 303 classification of interactions, 378
Ehrcnfest, P., 348 mnltiplets, 377-4382
theorem, 348 tables, 376, 408-409
Eigenfunctions, 318 (See also Wave function) Elements (see Chemical elements)
hydrogen ground state, 341 Emission of light, 96
linear combinations, 316 selection rules, 114
for square-well potentials, 313, 323 Emission spectra of atoms, 100 (Se# also Spectra)
Eigenstates, 318 (See also Stationary states; Energy levels) Energy, characteristic magnitudes, 54
Eigenvalues, 31S {See also Energy levels) units, 49
Eightfold Way theory, 380 Energy level diagrams (see Term diagrams)
Einsporn, E+, 101 Energy levels, 95
Einstein, A,, 3, 28, 102 graphic representation, 98 (See also Term diagrams)
biography, 3 of harmonic oscillator, 329
general relativity, 73 of hydrogen-like systems, 341
photoelectric theory, 28, 102 rotational, of molecule, 337
Eisberg, R* M., 307 Schrodinger theory, 312
Elastic cross section, 361 (See also Cross section) for square-well potentials, 313, 323
Elastic scattering, 359 vibrational, of molecule, 330
Electric dipole transitions, 114,130 widths, 106
Electric quadmpole transitions, 133 Energy quantum of oscillator, 26
Electromagnetic field (also Field) Energy operator, 347
interaction of cha1 ed particles, 386, 395 Ensemble, 234 (Se# also Statistical ensemble)
Lorentz transformation, 149 Esfcermann, I., 190
maximum strength of macroscopic fields, 74 Eta^meson, 376, 379, 409
quantum interpretation, 170 Ether, 382
Electromagnetic mass of electron, 12 Even-odd effects in nuclei, 70
Electromagnetic radiation, in annihilation, 158 Excitation of atoms, by collisions, 100
black-body, 23 and temperature, 99
Compton scattering, 152 Excitation potentials, 101
Einstein’s photon hypothesis, 28, 102 Excited states, 96, 99 (See also Energy levels; Term diagrams)
emission and absorption by atoms, 96 lifetime and width, 110
emission and scattering by oscillator, 107 Exclusion principle, 63
energy density, flux, 146, 170 and periodic table, 122
particle properties, 145 Expectation values, 344, 347
polarisation, 259 Exponential law of decay of nuclei, 39, 299
quantum-theoretic description, 169
radiation pressure, 145 Faraday constant, 19, 47, 406
from X-ray tube, 155 Feinberg, G., 401
Electron, charge, mass, 20, 57, 406 Feld, B. T„ 362,363
classical radius, 13, 34, 407 Fermi, E., 71
Compton wavelength, 152, 407 unit of length, 69
cross section in scattering on calcium, 365 Feynman, R. P., 216
diffraction, 187 (See also Diffraction of electrons) Field, 385, 389
Electron capture, 300 and description of particles, 389
Index 417
Field (continued) Group velocity of matter waves, 182

electromagnetic, 382, 380, 389^-390, 395 Guide waves, 204
meson, 395 Gurney, R. W., 299
theory, 382
Fine structure, 76 Hadrons, 378
in alkali atoms, 117 Hafnium, Bohr prediction, 121
Fine structure constant, 57, 77, 406 Halhday, D„ 136, 262,307
and quantum electrodynamics, 270 Harmonic oscillator, 323
Fission of nuclei, 89 response to electromagnetic wave, 108
Fitch, V, L., 343 Harnwell, G. P+, 38
Fluorescence, 101 Harrison, G* R,? 94
resonance, 104 Heat, 21, 53
Flux of radiation, 146 Heathcote, N. H* de V., 39
Forbidden transitions, 135 Heavy hydrogen, 87
Ford, K* W., 401 Heisenberg, W., 215, 223
Fourier analysis, 207 biography, 215
Fourier integral and uncertainty relations, 226 matrix mechanics, 215
Fowler, W. A., 307 S-matrix theory, 392
Fowler, W, B+, 401 uncertainty principle, 10 (See also Uncertainty principle)
Fractionally charged particles, 381 Heitler, W„ 334
Franck, J,, 101 Helium, spectrum, 98
Frauenfelder, IL, 176 term diagram, 118
Fretter, W« B,, 9 Henry, G. E., 175
Frequency, 48 Hertz, G-, 100
Friedrich, W., 21,155 Herzberg, G., 136
Frisch, D, KL, 262, 401 Hess and Lawson s experiment, 40
Frisken, W. R., 366 Hilbert, D*, 216
Fusion of nuclei, 90 Hines, W., 190,190,197
Hofstadter, R,, 69
Gamma decay cascades, 127 Hohenberg, C. M+, 303
Gamma-rays, acoustically modulated, 151 Holden, A+ N«, 339
from excited state of nickel, 126 Hooke, B., 5
Gamow, G,, 217, 299 Hoyle, F., 175, 307
Gas constant, 23, 47 Huus, T,, 374
Geiger and Marsden experiments, 32 Huygens, C., 5
Geiger-Muller counters, 234,235 Hydrogen atom, Bohr theory, 35, 58,139
Gell-Mann, M., 401 effect of nuclear motion, 342
Eightfold Way theory* 380 ground state wave function, 341
General relativity, 73 Rydberg constant, 58, 342, 407
Geometric cross section, 362 Schrodinger theory, 339
Germer, L, H., 187 spectrum, 95, 139
Glaser, D. A., 262 term diagram, 340, 341
Goldhaber, M., 401 Hydrogen-like systems, 339
Goldsmith, H, H,, 362, 363 Hydrogen molecule, vibrational states, 330
Goorvitch, D., 95 Hypercharge, 379
Gordon, G*s 190 Hyperons, 8, 376
Gordon, J. P*, 137
Gravitation, 73 Ibser, H. W., 362, 363
Gray, G. W„ 401 Ideal gas, 23
Grimsehl, E«, 38 Incoherent light, 262
Grotrian, W.t 112, 120, 136 Incoherent superposition, 247,249
diagrams, 112 (See also Term diagrams) Inelastic scattering, 359
Ground state, 99 of wave packets, 390
418 Index
Interactions, 385 Lattice (see Crystals)

classification, 378 Laue, M., 21, 155
electromagnetic {see Electromagnetic field) Lauritsen, T., 124,136, 139
strong, 69, 79 Lead, in radioactivity, 301
weak, 79, 126 Leighton, R. B,, 216, 323
Interference of light, feeble sources, 169 Lenard, P+, 28
visibility of fringes, 241 Leptons* 376,377, 408
Ionization energy of hydrogen, 59 Levin, J. .S., 364
and uncertainty principle, 229 Lifetime of excited states, ill* 131
Ionization limit, 102 and widths of energy levels, 110
Ionization potentials of atoms, 62 Light, emission (see Emission of light)
Isotope effect, molecular rotations, 353 polarized and unpolarized, 259
molecular vibrations, 335 visible region, 61
Isotopes, 46, 70, 335,353 Line, spectral, 94
graph, 70 Line widths, collision broadening, 129
mass spectrum of xenon, 09 Doppler broadening, 127
relative abundance in hydrogen, 87 natural broadening, 110, 127
relative abundance in oxygen, 46 uncertainty principle, 233
table, 46 Liquid hydrogen, bubble chamber, 385
Isotopic spin, 379 target, 359
Isotropy of physical space, 134 Livingood, J. J*, 38
London, F., 334
Jammer, M,, 38 Lorentz transformation, frequency, 143
Johnson, F. T+, 158 energy and momentum, 144, 184
Jordan, P+, 215 position and time, 184
Jordan, W+ H., 175 Loschmidt, 6
Lyman series, 340
K-capture, 300 Lyons, EL, 137
K-mesons, 8, 376
Ka-series formula, 123 MacRae, A. U«, 194
A*-shells, 122 Magnetic dipole moments in atoms, 90,133
Kelvin degree, 22, 52 Magnetic dipole transitions, 133
Kepler’s law, 34 Magneton, 90
Kilogram, SI Marsden, E., 32
Kinetic theory of gases, 23 Marshak, R. E., 401
King, J. G>, 80 Mass, electron, 20,406
KirchhofFs law, 24 elementary particles, 408—409
Kittel, C., 216 Mass defect of nuclei, 66
Klein-Gordon equation, 206, 271 Mass spectrograph, 68
for mesons, 395 Mass spectrum, baryons, 377,378
Klemperer, O,, 159 mesons, 377
Knight, W., 190,196,197 of xenon, 69
Knipping, P*, 21, 155 Mass unit, atomic, 47
Kramers, II. A., 328 energy equivalent, 51
Knrlbaum, F,, 27 Matrix mechanics, 215
Matter waves, 180
Laborde* 85 Maxwell, J. C.* 6
Lambda hyperon, 376 Maxwell's equations, 210, 382,395
lambda-antilambda pair, 391 Mean life, 108, 299
production and decay, 387 Measurement theory* 234
Lanthanide elements, 121 Mechanical mass of electron, 12
Laplacian operator, 206, 395 Meitner, Lf, 293, 310
Lattes, C. M, C,, 394 Mendelejeff, D. L, 122
Index 419
Mercury, spectrum, 100 Natural line width, 111

term diagram, 100,120 Nethercot, A. H+, 353
Merritt, F* Rt, 339 v. Neumann, J., 216
Merzbacher, E+, 307, 348 Neutrino, in beta decay, 126
Meson octet, 376, 377, 379 in meson decay, 376
Mesons, discovery, 394 Neutron, beta decay, 127
and nuclear forces, 393 cross section on bismuth, 364
tables, 376, 409 cross section on cadmium, 362
Metastable states, 325 cross section on silver, 363
Meter, 82 discovery, 66
Michel, G., 27 mass, 66, 407
Michelson interferometer, 241 Noble gas elements, 122
Microwave spectroscopy, 338, 339 Nodes of wave functions, 326
Mjllibarn, 362 Non-lincar field equations, 389
Millikan, R. A. 21, 29, 30 Nudear binding energy, 66
biography, 164 graph, 67
measurement of electronic charge, 20 Nuclear charge, determination, 123
measurement of Planck’s constant, 29 Nuclear Coulomb repulsion energy, 88
Mirror nuclei, 89, 124 Nuclear fission, 89
Mitchell, D, P+, 191 Nuclear forces, 69
Mole, 6, 47 and meson theory, 393
Molecular band spectra, photo, 99 range and strength, 71, 231
theory, 338 Nuclear fusion, 90
Molecular binding, 64, 332 Nuclear radii, 69, 88
Molecular potential, 331 and alpha-particle scattering, 32
Molecules, characteristic properties, 65 and mirror nuclei, 89
diatomic, 335 Nuclear reactions. Coulomb barrier, 300
electronic excitations, 338 discovery, 7
internuclear distances, 65 N uclear reactor, 89
isotope effect, 335, 353 Nuclei, composition, mass, 66
rotational excitations, 336,337 stable, graph, 70
vibrational excitations, 334 Nucleon, 66
Mollenstedt, G., 203 number, 66
Momentum transfer in diffraction, 193
Momentum operators, 346 Occhialini, G. P. S+, 394
Moog, F,, 85 Oliphant, T. A., 364
Moore, C. E., 114,117 Omega-minus particle, 378, 381
Morrison, E+1 217 One-electron atoms, 339
Morrison, P., 217 quantum numbers, 340
Moseley, H, G, J., 122 term diagrams, 340-341
diagrams, 123 O'Neill, G. K., 262
Mossbauer, R. L+, 176 Operators, energy, momentum, position, 344
Motz, L., 39,122,174 Optical excitation of atoms, 96, 104
Muirhead, H., 394 Optically active electrons, 63
Multi-electron atoms, 62 Orbital angular momentum, 115, 341
shell structure, 62,121 quantization in Bohr theory, 35
Multiplet, in atomic spectroscopy, 118 Origin of elements, 303
in elementary particle theory, 377 Orthmann, W., 310
Multiplicity of energy levels, 118 Oscillator, Planck s, 26,41
Mu-neutrino, 376 in wave mechanics, 328
Muon, 343, 376, 394
decay, 163,387 Pair creation and annihilation, 8} 10, 158, 391, 399
Muonic atoms, 343 Pake, G. E,} 137
420 Index
Parent nucleus, 125 Positrons (continued)

Partial wave analysis for S-wave scattering, 309 discovery, 158
Particle, definition of, 372 properties of, 376
Particle-antiparticle symmetry, 160 in showers, 10
Particle detectors, Geiger-Muller counter, 234,235 Potential, in Schrodinger theory, 275
photomultiplier, 230, 237, 238 square-well, 313, 323
resolving time, 266 Yukawa, 397
scintillation counters, 244, 245 Potential barriers, 279
Particle interactions in field theory, 388 Potential energy, in atoms, 59
Paschen series, 340 molecular, 331
Pauli, W., 63 Powder method, 189, 196
exclusion principle, 63, 122 Powell, C. F<, 394
Penman, S<, 401 Powers, P. N,, 191
Periodic table of elements, 121 Prediction in quantum mechanics, 254
Phase plane of oscillator, 42 Pressure broadening of spectral lines, 129
Phase shift in scattering, 370 Principal quantum number, 340
Phase velocity of matter waves, 182 Principle of superposition, 205
Photodisintegration of deuteron, 103 Pringsheim, E., 15, 27
Photoelectric effect, early experiments, 28,29 Probability of counting, 237
quantum theory of, 28 Probability amplitude, 249
Photomultiplier tube, 236, 237 Probability density, 271
quantum efficiency, 238 stationary and non-stationary states, 315
Photon, 28 Probability interpretation of quantum mechanics, 272
emission from moving source, 151 Proton, 66
particle properties, 142 -antiproton annihilation, 161
quantum theory, 169 cross section on aluminum, 374
Tecoil effect in emission and absorption, 175 Prout s hypothesis, 39
zero rest mass of, 144 Pure ensemble, states, 254
Physical constants, associated with electrons, 58
concerning their nature, 78 Quantization, 312
tables, 45, 406-407 of angular momentum, 35, 114
Pilot waves, 204 of charge, 80
Pi-mesons, pions, 8,294 of momentum transfer in diffraction, 193
cross section on protons, 366, 375 and standing waves, 312
decay, 103, 387 Quantum of action, 14
and nuclear forces, 393, 397 Quantum conditions, Bohr, 35
Planck, M,, 26, 39 Bohr-Sommerfeld, 328
biography, 15 Quantum efficiency, 238
quantization postulate, 26 Quantum electrodynamics, 56, 270
theory of black-body spectrum, 20 and Coulomb’s law, 395,398
Planck's constant, 14,48, 406 Quantum field, 389
determination by Millikan, 29 Quantum field theory, 382 (See also Field)
and uncertainty principle, 16, 229 Quantum jumps, 96, 104
universality of, 196 Quantum limit, 158
and X-ray spectrum limit, 156 Quantum mechanics, 2
Plane waves in theory, 306 Quantum numbers, 113
Podesek, F. A., 303 Quantum states, 96, 312
Polarization, of light, 259 Quantum theory of transitions, 96
of materia] particles, 210 Quarks, 381
of X-rays, 155 Quasistationary states, 325
Position operator, 344
Positrons, annihilation, 158 Radiation Electromagnetic radiation)
in beta decay, 126 Radiation pressure, 145
Index 421
Radiative recombination, 102 Rutherford (continued)

Radii, of atoms, 35, 58, 62 theory of alpha-particle scattering, 32
of nuclei* 69 Rydberg constant* 58,407
Radioactivity, 39, 125,292, 300
alpha-emitters, 298 S-matrix, 392
exponential law of decay, 39,299 S-wave scattering, 369
4n + 2 series, 300 Samios, N. P+, 401
in geology, 301 Sands, M., 216
uranium-radium-lead series, 301 Scattering, amplitude, 366
Radium, 86,296, 301 antiprotons by protons, 358
heat evolution, 85 cross section, 359 (See also Cross section)
Rainwater, L. J., 262, 343 experiments, 358, 363
Random motion, 23, 53,240 quantum mechanical interpretation, 364
Random variable, 244 resonance, 371
Range of alpha-particles, 293 S-wave, 369
Range of nuclear forces, 71, 393 theory, 365
Rare earth elements, 121 Schawlow, A, L+, 137, 339
Reaction cross section, 361 Schiff, L. L, 226, 307,348
Recoil effect in photon emission and absorption, 175 Schilpp, P, AtJ 39
Reduced mass, in diatomic molecules, 335 Schmidt, P., 162
in hydrogen-like atoms, 341 Schrodinger, E>, 215, 216,269, 307, 312, 340
Reflection of photons, 146 biography, 268
Refraction of light, 181 Schrodinger equation, basic assumptions, 268
Relativistic transformation laws (see Lorentz transformation) derivation, 276
Relativistic wave equation, 206, 269, 271 one-dimensional barrier problems, 279
Relativity, general theory, 73 time-dependent form, 273, 279
special theory, 14, 143,154,183, 385 time-independent form, 278
Resolving time of particle detectors, 266 WKB-approximation, 328
Resonance, universal curve of response, 109 Schrodinger theory of quantum mechanics, 317
Resonance fluorescence, 104 position and momentum variables, 344
Resonances, and atomic energy levels, 105 stationary states, 312, 317
Breit-Wigner formula, 109, 371 Schrodinger wave function, 273
in elementary particle physics, 374 group and phase velocities, 274
in pion-proton scattering, 375 probability Interpretation, 271
in proton-aluminum collisions, 374 Scintillation counter, 244, 245
Retarding field method, 29 Scintillations, 40, 244
Reynolds, J. H«, 68, 69, 303, 307 Second, 82
Rice, F. O., 350 Segre, E„ 136, 160, 161, 307
Rigid rotator, energy levels, 337 Selection rules, for alkali spectra, 114
Ritz combination principle, 95 for angular momentum, 115
Rochester, G, D., 262 for dipole transitions, 135
Rontgen, W* C,, 155 Series in hydrogen spectrum, 340
Rosenbaum, E. P., 401 Shamos, M, H, 39
Rosenblum, B., 353 Shell structure in atoms, 122
Rosenfeld, A, H,, 401,409 Shull, C. G+, 191
Rotational excitations in molecules, 336 Sigma hyperon, 376
isotope effect, 353 Simon, A. W., 154
Rotational symmetry, 134 Sodium atom, energy level table, 117
Rubens, H., 27 term diagram, 116
Ruby, S> L>, 151 yellow doublet, 117, 138
Rutherford, 7, 32, 302 Sodium chloride crystal, 20
biography, 32 Sommerfeld, A+J 59
discovery of nuclear reactions, 7 Special relativity, 14,143,154,183, 385
422 Index
Spectra, band, 99, 338 Term diagrams (continued)

characteristic X-ray, 156 beta-decay of neutron, 127
emission and absorption, 96,99,100 boron and carbon isotopes, 125
fragment of table of lines, 94 boron nucleus, 124
microwave, 338 decay of cobalt, 127
Spectral terms, 95 deuteron, 103
Spectroscopic notation, 115 helium atom, 118
Spectrum (photo), carbon molecule, 99 hydrogen atom, 340, 341
helium, 98 lithium and beryllium isotopes, 125
hydrogen, 95 lithium atom, 112
mercury, 100 mercury atom, 100
microw ave, of molecule, 339 sodium atom, 116
Spin angular momentum, electron, 115 thallium atom, 119
elementary particles, 376, 408-409 zinc, cadmium, mercury atoms, 120
Spontaneous fission, 89 Terms, spectral, 95 {See also Term diagrams)
Square-well potentials, 313, 323 in iron, 114
Stability, of atoms, 231 in sodium, 117
of nuclei, 69 Thermal motion, 53, 240
Stable nuclei, graph, 70 Thomson, G> R, 187
Standing waves and quantization, 312 Thomson, J, J., 20, 46
Stark effect, 74 biography, 19
Static meson field, 395 Thorndike, A. M+, 262, 401
Stationary state, 96 Time-dependent Sehrodinger equation, 279
in Sehrodinger theory, 312 Time-independent Sehrodinger equation, 278
Statistical ensemble, 244 Tomaschek, R,, 38
average of variables, 244 Total angular momentum, 115
coherent superposition, 249 Total cross section, 359 (See aho Cross section)
incoherent superposition, 247, 249 Total internal reflection, 290
mixed and pure ensembles, 254 Townes, C+ H., 339, 353
and wave functions, 257 Transition rates for light emission, 130
Statistical interpretation, of measurements, 236 Transitions, quantum postulates, 96
of wave function, 271 Translational energy of molecules, 53
Statistical mixture, 247 Transmission coefficient in barrier penetration, 292
Statistical spread, 244 Triplets of energy levels in helium, 118
Step potential in Sehrodinger theory, 281 Tunneling effect, 288 (See also Barrier penetration)
Stern, O., 190 Turning point, 280, 326
Stokes rule, 101 Twinkling of stars, 41
Strangeness, 404
Sub she 11s in multi-electron atoms, 122 Uhcy, C, T„ 156
Sugar, J., Ill Uncertainty principle, 16, 222
Sun^s radiation, 86 and atomic structure, 231
Superposition, coherent, incoherent, of light, 253, 262 attempts at refutation, 262-264
Superposition of wave functions, 205, 316 and binding energy of hydrogen, 229
Superposition principle of quantum mechanics, 205 and diffraction, 229
and Fourier transform, 226
Tangcn, Ih, 374 and nuclear structure, 232
Target, liquid hydrogen (photo), 359 and rest mass of unstable particles, 373
in scattering, 359, 363 Uncertainty relation, 16,222
Taylor, G+1., 169 meatflife-linewidth, 233
Teller, E., 350 position-momentum, 225
Temperature, 22, 52 time-frequency, 232
Term diagrams, 98, 99, 102 Unit? of measurements, macroscopic, 44,81
alpha-decay of bismuth, 126 natural-units in quantum physics, 50
Index 423
Universal gas constant, 23, 47, 406 Wave number, 48

Unstable particles, 373 Wave train of light, classical picture, 163
Uranium, in the earth, 301 Weak interactions, 126, 378
fission, 39 Wentzel, G., 328
Uraninm-radium-lead series, 301 White, H>, 136
Urey, H., 87 Whittaker, E„ 38
Widths of energy levels, 104
Vacuum, in theory, 382 and life-times, 110
Vector space, 212 and uncertainty principle, 233
dimensionality of, 213 Wiegand, G, 160
of physical states, 211 Wien s displacement law, 24,41
Velocity of light, 14, 84,406 Wigner, E. P+, 135
Vibrational excitations of molecules, 334 Wilson, C, T. R., 154
characteristic parameters, 335 Wilson, J+ G., 262
hydrogen molecule, 330 WKB-approximation, 328
isotope effect, 335 Wollan, E. O., 191
Virtual level, virtual state, 124, 325 Work function, 28
Voltaic cell, 65 Wii, C, S., 262
Volt, standard of, 65
Xenon mass spectrum, 69

Watts, H. M., 158
X-ray characteristic radiation, 156
Wave amplitude {See also Wave function)
continuous spectrum, 156
in momentum space, 208
X-ray diffraction (See also Diffraction)
Wave equations, 209
in crystals, 21
Dirac, 269
by powder sample, 189, 190
initial data, 208
X-ray minimum wavelength, 157,158
Klein-Gordon, 206
X-ray tube, 155
negative frequency solutions, 208
X-rays, Moseley's measurements, 122
Schrodinger (see Schrodinger equation)
polarization, 155
Wave function, de Broglie, 272
scattering, Compton effect, 153
global behavior, 320
ground state of hydrogen, 341
local behavior, 319 Yagoda, H., 262
mathematical properties of, 282,304, 319 Yield curve for nuclear reaction, 374
nodes, 326 Yount, D. E., 262
normalization, 304 Ypsilantis, T., 160
particle in potential wells, 313,323 Yukawa, H., 394
plane wave, 205, 306 biography, 393
Schrodinger, 273 meson theory of nuclear forces, 393
and statistical ensembles, 257 potential, 397
for step-potential, 281
superposition principle, 205 Zafiratos, C. D., 364
Wavelength, 48 Zeeman effect, 74
fragment of table, 94 Zinc atom, energy levels, 120
lass Frsq.
E/c3 E/h E/(hc)

cycles
amu
sec
: 1,6021 1.0736 2.
1 I
x 10 13 XlO9 X
6.2418 6.0226 1439 I 7.244

! i
XlO11 X 102:l x 10,s X i 01-=J x 10- x 10 8
1.0364 1.6604 2.389 ; 1.203 1.1963

I 250.61
XlO w XlO » XlO-« x 10 8 x IQ9 xlO1*1
4.338 6.951 4,186 1.049
1 0303 0.3499
XlO5 x 10 171 XlO7 XlO
8.617 1.381 8.314 1.439

1.9S6 1 0.6950
xlO5 XlO 18 XlO7 x 10U1 XlO8
931.48 1.4923 8.9876 2.147 2.2524 7.5131
X 10s I X 10 3 j x 10» xlO13 xlO23 xlO12 x IQ'5
4.1355 6.6255 9.532 3.3356 2.99/9

1
X 10 15 X 10 27 x 10 n XlO11 j xlO18
- 1 ■
1.9863 1.1963 1.3310 2.9979

1 10*
XlO 16 XlO8 x 10 18 xlO10 !
------—-
1.9863 1.3310 2.9979 ;

10s 1
xlO 8 XlO16 x 10 5 xlO18
8.1868 4.9306 5.4859 1.2356 ' 4.1217 2.4262

511006
XlO7; xlO17 x 10! X10 } xlO20 XlO9 XlO 2
2.17971 1.3127 1.4606 3.2898 I

13.605 109737 [I 911.27
xlO 11 xlO‘s x xlOs: xlO15
its
Length: 1 micron (/i) = lQ-e meter
1 millimicron (m/i) =- IQ-9 m = IQ-7 cm
1 Angstrom: (A) = T0~s cm
1 fermi (f) = IQ-13 cm
1 barn (b) =
I millibarn (r = iO~2T cm2
Time: 1 year ^ 3,156 x 107 sec
1 newton = 103 dyne
Energy: 1 joule = 107 erg ^ {0,2389 = 1/4,186) calories

1 electron volt (eV) = (1.60210 ±: 0.00002) x IQ-19 joule
Mass: 1 atomic mass unit (amu) = (1.66043 =t 0.00002) x lO^24 gm
Charge: 1 coulomb = (2.997925 ± 0. X 109 esu = 0,1 emu
Potential: 1 esu = (299.7925 zt 0.0001) volt (V)
Magnetic induction: 1 volt-sec/m2 = 104 gauss
Energy equivalent of
atomic mass unit: (1 amu) X c2 = (9.31478 ± 0. 00005) x 108 eV
Activity of radioactive
sample: 1 curie = 3.7 x lO10 disintegrations per second
Frequency associated with 1 eV: (2,41804 ± 0,00002) x 1G14 sec
Wavelength associated with 1 eV: (1.239810 =±= 0,000013) x IQ"4 cm
Wave number associated with 1 eV: (8,06573 ± 0.00008) x 103 cm-1
*For other tables of physical constants, see Appendix.

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The constants In this table might well be memorized so that

they are always available for simple estimates. See Table A

! Avogadro’s number; Nn ^6x IQ2B (mol)-1

Velocity of light; 6 ^ 3 x IQ10 cm/sec

Electronic charge; e;1.6x IQ-10 coulomb

Fine-structure constant: a cr 1/137

Rest energy of electron; me2 ^ 0.5 MeV

Rest energy of proton: Mpc2 ~ 940 MeV

Ratio of proton to electron mass: Mp/m zz 1800

Ionization energy of hydrogen: = fa£mc2 ~ 13,6 eV

Bohr radius in hydrogen: ao = %/a ^ 0.5 A - 0.5 x 10^s cm

Bohr magneton: (eH)/(2mc) ^ 5,8 x TO-9 eV/gauss

Nuclear radius (mass number A): r ^ A1/3 x (1.2 x 10 13 cm)

Nuclear binding energy/nucleon; ~ 8 MeV

11 Room temperature”: k x (293*K) sr (1/40) eV

"Optical region”: 4000 A-70G0 A

ONE ELECTRON VOLT corresponds to:

Frequency: ~ 2.4 x 1014 cycles/sec

-< Bulk energy; ^ 23,000 cal/mol

Wave number: ^ 8000 cm-*

L Wavelength: :zr. 12,000 A

Front cover: Term scheme of neutral thallium atom .

The preparation of this course was supported by a grant

Library of Congress Catalog Card Number

This is a two-year introductory college physics course for students

Massachusetts Institute of Technology, and C. Kittel late in 1961,

Frank S. Crawford, Jr,

* Formerly Educational Services Incorporated.

This volume of the Berkeley Physics Course is devoted to Quantum

magnitude of physical parameters in microphysics, and to introduce

I am greatly indebted to the other members of the Berkeley Physics

in the Scientific American, which require very little preparation for

systems and term schemes, and to show how simple conclusions

decay (Sections 37-48, Chapter 7) should probably not. be omitted,

1-7 The Scope of Quantum Physics 2

Chap ter 2 Magnitudes ofPhysical Quantities in Quantum Physics 43

1-10 Units and Physical Constants 44

Chapter 3 Energy Levels 93

1-13 Term Schemes 94

Chapter 4 Photons 141

Chapter 5 Material Particles 179

1-15 The de Broglie Waves 180

Chapter 6 The Uncertainty Principle and the Theory of Measurements 221

1-19 Heisenberg's Uncertainty Relations 222

Chapter 7 The Wave Mechanics of Schrodinger 267

Chapter 8 Theory of Stationary States 311

42-48 Hydrogen-like Systems 339

Chapter 9 The Elementary Particles and their Interactions 357

1-18 Collision Processes and the Wave Picture 358

s to 19 Atoms and Elementary Particles 5

20 to 26 The Limits of Applicability of Classical Theory 14

27 to 40 The Discovery of Planck's Constant 18

41 to 46 The Photoelectric Effect 28

47 to 55 The Problem of the Stability and Size of Atoms 32

References for Further Study 38

The Scope of Quantum Physics

1 In this part of our course we shall study physics in the realm

2 In the preceding volumes of the Berkeley Physics Course we

or model, which has worked successfully in a seemingly analogous