Intl Tel/Fax Code : 00 91 22

Tel.: 4082 8100 * 22 66 3150

Fax: 4082 8181 * 2202 4657

G. AMPHRAY LABORATORIES E-mail : [email protected]

Sambava Chambers, 4th Floor, Sir P. M. Road, Mumbai 400 001, INDIA. Web : www.amphray.com

MATERIAL SAFETY DATA SHEET

1) CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Common Name / Trade Name : PIPERAZINE HEXAHYDRATE

Catalog Number : P008
Name of Manufacturer / Supplier : G. AMPHRAY LABORATORIES
4th Floor, Sambava Chambers, Sir. P. M. Road, Fort,
Mumbai 400 001, India.

Telephone No : 00 91 (22) 4082 8100 / 2266 3150 / 6631 77 50

Fax No : 00 91 (22) 4082 8181 / 2202 4657 / 6631 77 47
Email : [email protected]

Commercial Name : Arpezine, Arthriticine, Parid, Vermisol

Synonym : Not Available

Chemical Name : Piperazine Hexahydrate

Chemical Family : Not Available

Chemical Formula : C4-H10-N2.H20

CAS : 142-63-2

RTECS : TM0850000

TSCA : T S C A 8 (b) Inventory : No products were found.

2) COMPOSITION AND INFORMATION ON INGREDIENTS

EXPOSURE LIMITS

Name CAS TWA (mg/m3) STEL (mg/m3) CEIL (MG/M3) % by Weight

Piperazine Hexahydrate 142-63-2 100

Toxicological Data & Ingredients : Piperazine Hexahydrate

Oral LD50 Acute : 11200 mg/kg [Mouse]

3) HAZARDS IDENTIFICATION

Potential Acute Health Effects : N. A.

Potential Chronic Health Effects : N. A.

irritant, lung sensitizer)
Carcinogenic Effects : Not available.
Mutagenic Effects : Not available.
Teratogenic Effects : Not available.
Developmental Toxicity : Not available.
The substance may be toxic to to lungs, skin.

Plant 1: 43/2, Narpoli, Amina Compound, Near Dhamankar Naka, Bhiwandi - 421 302. MAHARASHTRA
Plant 2: 10/1 MIDC Industrial Area, Ambernath - 421 510. MAHARASHTRA
 Intl Tel/Fax Code : 00 91 22
Tel.: 4082 8100 * 22 66 3150
Fax: 4082 8181 * 2202 4657

G. AMPHRAY LABORATORIES E-mail : [email protected]

Sambava Chambers, 4th Floor, Sir P. M. Road, Mumbai 400 001, INDIA. Web : www.amphray.com

4) FIRST AID MEASURES

Eye Contact : Check for and removal any contact lenses. Incase of contact, immediately
flush eyes with plenty of water for at least 15 minutes. Cold water may be
used. Do not use any ointments. Seek medical attention.
Skin Contact : In case of skin contact, immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Cover
the irritated skin with an emollient. Wash clothing before reuse. Thoroughly
clean shoes before reuse. Get medical attention immediately.
Serious Skin Contact : Wash with a disinfectant soap and cover the contaminated skin with an
anti-bacterial cream. Seek medical attention.
Inhalation : If inhaled, remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Get medical attention immediately.
Serious Inhalation : Evacuate the victim to a safe area as soon as possible. Loosen tight
clothing such as a collar, tie, belt or waistband. If breathing is difficult,
administer oxygen. If the victim is not breathing, perform mouth to mouth
resuscitation. WARNING : It may be hazardous to the person providing aid to
give mouth to mouth resuscitation when the inhaled material is toxic, infectious
or corrosive. Seek immediate medical attention.
Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person. Loosen tight clothing
such as a collar, tie, belt or waistband. Get medical attention if symptoms
appear.
Serious Ingestion : Not available.

5) FIRE & EXPLOSION DATA

Flammability of the product : May be combustible at high temperature.

Auto-Ignition Temperature : Not available.
Flash Points : Not available.
Flammable Limits : Not available.
Products of Combustion : These products are carbon oxides (CO, CO2), nitrogen oxides
(NO, NO2.)

Fire Hazards in presence of Various Substances: Slightly flammable to flammable in presence of heat, of oxidizing
materials. Non flammable in presence of shocks.
Explosion Hazards in Presence of Various Substances: Slightly explosive in presence of open flames and sparks, of heat. Non
explosive in presence of shocks.
Fire Fighting Media & Instruction : Small Fire : Use Dry chemical powder.
Large Fire : Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards : As with most organic solids, fire is possible at elevated temperatures.
When heated to decomposition it emits highly toxic fumes.
Special Remarks on Explosion Hazards : N. A.

Plant 1: 43/2, Narpoli, Amina Compound, Near Dhamankar Naka, Bhiwandi - 421 302. MAHARASHTRA
Plant 2: 10/1 MIDC Industrial Area, Ambernath - 421 510. MAHARASHTRA
 Intl Tel/Fax Code : 00 91 22
Tel.: 4082 8100 * 22 66 3150
Fax: 4082 8181 * 2202 4657

G. AMPHRAY LABORATORIES E-mail : [email protected]

Sambava Chambers, 4th Floor, Sir P. M. Road, Mumbai 400 001, INDIA. Web : www.amphray.com

6) ACCIDENTAL RELEASE MEASURES

Small Spill : Use appropriate tools to put the spilled solid in a convenient waste
disposal container.
Large Spill : Corrosive solid.
Stop leak if without risk. Do not get water inside container. Do not
touch spilled material. Use water spray to reduce vapors. Prevent
entry into sewers, basements or confined areas, dike if needed
Eliminate all ignition sources. Call for assistance on disposal

7) HANDLING AND STORAGE

Precautions : Keep container dry. Keep away from heat. Keep away from sources of
ignition. Do not breathe dust. Never add water to this product. In case
of insufficient ventilation, wear suitable respiratory equipment. If
ingested, seek medical advice immediately and show the container or
the label. Avoid contact with skin and eyes. Keep away from
incompatibles such as oxidizing agents, acids.
Storage : Keep container tightly closed. Keep container in a cool, well-ventilated
area. Hygroscopic sensitive to light. Store in light-resistant containers.

8) EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls : Use process enclosures, local exhaust ventilation, or other engineering
controls to keep airborne levels below recommended exposure limits.
If user operations generate dust, fume or mist, use ventilation to keep
exposure to airborne contaminants below the exposure limit.
Personal Protection : Splash goggles. Lab coat. Dust Respirator. Be sure to use an approved /
certified respirator or equivalent. Gloves.
Personal Protection in case of a Large Spill : Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self
contained breathing apparatus should be used to avoid inhalation of
the product.
Suggested protective clothing might not be sufficient, consult a
specialist BEFORE handling this product.
Exposure Limits : Not available.

Plant 1: 43/2, Narpoli, Amina Compound, Near Dhamankar Naka, Bhiwandi - 421 302. MAHARASHTRA
Plant 2: 10/1 MIDC Industrial Area, Ambernath - 421 510. MAHARASHTRA
 Intl Tel/Fax Code : 00 91 22
Tel.: 4082 8100 * 22 66 3150
Fax: 4082 8181 * 2202 4657

G. AMPHRAY LABORATORIES E-mail : [email protected]

Sambava Chambers, 4th Floor, Sir P. M. Road, Mumbai 400 001, INDIA. Web : www.amphray.com

9) PHYSICAL AND CHEMICAL PROPERTIES

Physical State and Appearance : Solid ( Crystals Solid )

Molecular Weight : 194.23 g/mole
pH ( 1 % solution / water ) : Not applicable
Boiling Point : 145 C (293F) 156 C
Melting Point : 42 C (107.6F) 45 C
Critical Temperature : Not Available
Specific Gravity : Not Available
Vapor Pressure : Not Applicable
Vapor Density : Not Available
Volatility : Not Available
Odor Threshold : Not Available
Water / Oil Dist. Coeff. : Not Available
Ionicity (in water) : Not Available
Dispersion Properties : Not Available
Solubility : Insoluble in cold water.

10) STABILITY AND REACTIVITY DATA

Stability : The product is stable.

Instability Temperature : Not available.
Conditions of Instability : Excess heat, incompatible materials, light, moisture.
Incompatibility with various substances : Reactive with oxidizing agents, acids
Corrosivity : Not available.
Special Remarks on Reactivity : Hygroscopic, keep container tightly closed.
Also incompatible with acid chlorides, acid anhydrides,
dicyanofurazan
Special Remarks on Corrosivity : Not availbale
Polymerisation : Will not occur

11) TOXICOLOGICAL INFORMATION

Routes of Entry : Inhalation. Ingestion.

Toxicity to Animals : Acute oral toxicity (LD50) : 11200 mg/kg (Mouse)
Chronic effects on Humans : Not available
Other Toxic effects on Human : Hazardous in case of Skin Contact (irritant, sensitizer), of ingestion, of
inhalation (lung sensitizer). Slightly hazardous in case of skin contact
(corrosive), of eye contact (corrosive).
Special Remarks on Toxicity to animals : Not available.
Special Remarks on Chronic Effects on Humans: Not available
Special Remarks on other Toxic effects on Humans: Potential health effects.

Plant 1: 43/2, Narpoli, Amina Compound, Near Dhamankar Naka, Bhiwandi - 421 302. MAHARASHTRA
Plant 2: 10/1 MIDC Industrial Area, Ambernath - 421 510. MAHARASHTRA
 Intl Tel/Fax Code : 00 91 22
Tel.: 4082 8100 * 22 66 3150
Fax: 4082 8181 * 2202 4657

G. AMPHRAY LABORATORIES E-mail : [email protected]

Sambava Chambers, 4th Floor, Sir P. M. Road, Mumbai 400 001, INDIA. Web : www.amphray.com

12) ECOLOGICAL INFORMATION

Ecotoxicity : Not available

BOD5 and COD : Not available
Products of Biodegradation : Possibly hazardous short term degradation products are not likely.
However, long term degradation products may arise.
Toxicity of the products of Biodegradation : The product of degradation are more toxic.
Special Remarks on the Product : Not available.

13) DISPOSAL CONSIDERATIONS

Water Disposal : Waste must be disposed of in accordance with federal, state and local
environment.

14) TRANSPORT INFORMATION

DOT Classification : N. A.
Identification : Piperazine
Special Provisions for Transport : Not available

15) OTHER REGULATORY INFORMATION

Federal and State Regulations : No products were found.

California Proposition 65 Warnings : N. A.

Other Regulations : N. A.

Other Classification : N. A.

16) OTHER INFORMATION

All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies
only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it
may pose hazards not mentioned in this MSDS. It shall be the users responsibility to develop proper methods of handling
and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be
reliable, G. Amphray Laboratories assumes no responsibility for the completeness or accuracy of the information contained
herein.

Certified True Copy

For G. AMPHRAY LABORATORIES

AUTHORISED SIGNATORY

Plant 1: 43/2, Narpoli, Amina Compound, Near Dhamankar Naka, Bhiwandi - 421 302. MAHARASHTRA
Plant 2: 10/1 MIDC Industrial Area, Ambernath - 421 510. MAHARASHTRA