WELDING PRODUCT PROGRAMME

Duplex and Super Duplex stainless steel

Customised formulations
Consistent quality
Single point source for complete range
Technical expertise
Experience in worldwide major projects
Selectarc range covers a wide range of specifications
 WELDING PRODUCT PROGRAMME
DUPLEX STAINLESS STEEL

FSH Welding Group works to ensure its customers to

get the full benefit of its very extensive expertise.
Founded in 1952, Selectarc Industries arc welding electrodes
manufacturing plant has built up a reputation for leading expertise
in the field, ranking it alongside the industrys key players both in
France and on the export market. Micro structure
The impeccable quality
and extensive range of its Details Micrographs
standard and customised
products, along with its Base metal Pure weld metal HAZ
quality control processes,
guarantee compliance with
its clients exacting specifi-
cations. Our aim is simple
yet ambitious: to constantly
improve to ensure the satis-
faction of every single cus-
tomer. 233-246 230-290 261-277
Hardness (Hv)

Applications:
De-salination equipments
Pumps, Pressure vessels, Tanks, Piping, and Heat
Duplex stainless steel exchangers in the Chemical processing industry
Piping, Tubing, and Heat Exchangers for the
Duplex means two. Duplex stainless steels consist of the
two phases, Ferrite and Austenite and are often termed Ferri- handling of Gas and Oil
tic-Austenitic stainless steels. Typically, duplex stainless steels
have a microstructure consisting of approximately 50% ferrite Effluent scrubbing systems
and 50% austenite.
Pulp and Paper industry digesters, Bleaching
Ferrite gives high strength and some resistance to stress equipment, stock-handling systems
corrosion cracking, the austenite provides good toughness,
and the two phases in combination give the duplex steels their Rotors, Fans, Shafts, and Press rolls requiring
attractive corrosion resistance. combined strength and corrosion resistance
The most important alloying elements of duplex stainless steels Cargo Tanks for Ships and Trucks
are Cr, Ni, Mo and N.
Food processing equipment
Duplex stainless steel
Properties / Advantages Welding procedure
High general corrosion resistance 1. Pre-heating treatment
To respect certain parameters as heat input and interpass
Pitting and Crevice corrosion resistance superior temperature:
to SS316L, 317L austenitic stainless steel
Preheating of Duplex Stainless Steels is not necessary and
High resistance to chloride stress corrosion not recommended
cracking
The temperature of the plates or pipes to be welded should
High resistance to corrosion fatigue and erosion be about 20C

Good sulfide stress corrosion resistance 2. Welding

High strength 2.1. Choose the right filler metal and welding process to get
the right weld metal toughness:
Excellent toughness
Lower thermal expansion and higher thermal con- TIG consumables give higher impact values than any other
ductivity than austenitic stainless steels consumable;

Good workability and weldability Basic coated/type consumables give better impact values
than rutile/ acidic coating;

Weldability of duplex stainless steel

Fabricating duplex stainless steels, special attention should be
paid to heat treatment and welding. Unsuitable heat treatment
can result in precipitation of inter-metallic phases and deteriora-
tion of toughness and corrosion resistance. Although most weld-
ing methods can be used to weld duplex steels, they require
special procedures for the retention of properties after welding.

To avoid problems such as corrosion resistance, toughness,

or post weld cracking, the welding procedure should focus
on minimizing total time at temperature in the Red Hot 500
- 790C range for the whole procedure rather than managing
the heat input for any one pass.
Influence of coating on Impact properties.
These are technically and economically optimal procedures!

2.2. To guarantee a balanced Austenite-Ferrite ratio in weld

deposit.

Phase balance
Too much ferrite (> 70 %)
Ductility and toughness
Corrosion resistance (Nitrides)

Too much austenite (> 80%)

SCC resistance
Mechanical strength
Typical requirements according to engineering specifications
Ferrite content: 30-55% (30-60%)
 2.5. Welding Parameters

Grade of Duplex Advice

2304 / 1.4362 Heat input 0.5 - 2.5 kJ/mm

2205 / 1.4462 Interpass temperature <170C

Grade of Super Duplex Advice

1.4507
Heat input 0.4 - 1.5 kJ/mm
2507 / 1.4410
Influence of Elements and Cooling rate on % Ferrite. Interpass temperature <150C
1.4501
Fast Cooling High Ferrite
Slow Cooling Low Ferrite The linear heat input "Es" is calculated based on welding
parameters:
Influence of elements
Es = ( V x A ) / S x 60/1000
V= Arc voltage ( V );
A = Welding current ( A );
S = Welding speed ( mm / min )

2.3. To get required Austenite Ferrite ratio in the heat

affected zone (HAZ)

2.4. To prevent phase precipitations which will reduce

corrosion as well as mechanical properties (ASTM A923)
3. Post Weld heat treatment
A post weld heat treatment (PWHT) is not recommended. For
temperatures above 290C it is dangerous as phase precipita-
tions will occur.

4. Cleaning, Pickling and Passivation

To obtain the best corrosion resistance, it is essential to remove
oxide, tarnish, heat tint, and other surface contamination by me-
chanical or chemical methods, ideally both. Thorough washing
must be done after pickling.
Product range

Product name AWS/EN Main features Description

Inox 2209 Rutile-basic electrode with a duplex structure. Easy to weld in all positions,
AWS A5.4: E2209-17 except vertical down. Stable arc, regular drop transfer, easy slag removal,
For Duplex steels / rutile
EN 1600 / ISO 3581-A: finely rippled weld beads. The weld metal can be applied for operation tem-
E 22 9 3 N L R 3 2 peratures up to 250C.

Basic coated electrode with a Duplex microstructure (duplex). The weld

Inox 2209B deposit is characterized by a high resistance against Pitting, Crevice and
AWS A5.4: E2209-15 For Duplex steels / basic stress corrosion in chloride containing media, like sea water, combined with a
EN 1600 / ISO 3581-A: very high tensile strength. Easy to weld with, stable arc, easy to remove slag,
E 22 9 3 N L B 4 2
regular weld beads.

Inox 2509MoB Basic coated Super Duplex electrode(~ 40% ferrite). Weld metal is resistant
AWS A5.4: E2594-15 in chloride containing medias against pitting as well as crevice and stress
For Super Duplex steels
EN 1600 / ISO 3581-A: corrosion. Used for impellers and other components which require high
E 25 9 4 N L B 4 2 strength combined with corrosion attack. Pitting index: > 40.

Basic coated electrode with an austenitic - ferritic microstructure (duplex ~

Inox 2509MoWB 40% ferrite). Good resistant in chloride containing medias against pitting as
AWS A5.9: E2595-15 Basic coated / for Super
Duplex stainless steels well as crevice and stress corrosion. Electrodes are used for pumps, vessels,
EN 1600 / ISO 3581-A: piping systems etc. attacked by chloride containing solutions. Pitting index:
E 25 9 4 N L B 42 > 40.

TIG/MIG D22/09 Very low carbon content solid rod for GTAW / GMAW welding Duplex steels
AWS A5.9: ER2209 (austenitic-ferritic microstructure), such as Uranus 45N, 2205, 2304. Resis-
EN ISO 14343-A: For Duplex steels
tant in chloride containing media against pitting corrosion as well as crevice
W 22 9 3 N L and stress corrosion.
G 22 9 3 N L

TIG/MIG D25/09 Very low carbon content solid rod for GTAW / GMAW Duplex and Super
AWS A5.9: ER2594 Duplex Stainless Steels (austenitic-ferritic microstructure). Resistant in chlo-
EN ISO 14343-A: For Super Duplex steels
ride containing media against pitting corrosion as well as crevice and stress
W 25 9 4 N L corrosion. Pitting index (PREN): > 40.
G 25 9 4 N L

TIG/MIG D25/09W Very low carbon content solid GTAW rod for joining Duplex and Super Duplex
AWS A5.9: ER2594 Stainless Steels (austenitic-ferritic microstructure). Resistant in chloride
EN ISO 14343-A: For Super Duplex steels
containing media against pitting corrosion as well as crevice and stress
G 25 9 4 N L corrosion. Pitting index (PREN): > 40.
W 25 9 4 N L

FCW D22/09-F Flux cored wire to weld in flat positions with shielding gas protection with an
AWS A5.22 E2209T0-1/-4 For Super Duplex steels in austenitic-ferritic microstructure (Duplex). Stable arc, Less spatter and easy
EN ISO 17633-A: flat positions slag removal.
T 22 9 3 N L R M 3 Exist also with a basic slag : FCW D22/09-B.

FCW D22/09-AP Flux cored wire to weld in all positions with shielding gas protection with an
AWS A5.22 E2209T1-1/-4 For Duplex steels in all
positions austenitic-ferritic microstructure (Duplex). Stable arc, Less spatter and easy
EN ISO 17633-A: slag removal.
T 22 9 3 N L P M 1

FCW D25/09-F Flux cored wire to weld in flat positions with shielding gas protection with an
AWS A5.22 E2594T0/-4 For Super Duplex steels in austenitic-ferritic microstructure (Duplex). Stable arc, Less spatter and easy
EN ISO 17633-A: flat positions slag removal. Pitting index (PREN): > 40.
T 25 9 4 N L R M 3 Exist also in All Positions: FCW D25/09-AP.

Technical datasheets available on: www.fsh-welding.com/en/datasheets.htm

Welding of Dissimilar Metal
Welding Consumables used for Dissimilar Metal Welding

Base Material 2304 2205 2507 Super duplex

Carbon Steel / Inox 2209 Inox 2209 Inox 2509MoB
Low Alloy Steel D22/09 D22/09 D25/09

304L / 347
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

316L / 318
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

309L / 309LMo
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

410
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

2304
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

2205
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09

2507
Inox 2209 Inox 2209 Inox 2509MoB
D22/09 D22/09 D25/09
Legend: In black MMA In blue TIG/MIG Wires

Services
Advice and assistance
A team of engineers and experienced welders help customers with selecting the materials and consumables that are best suited for
each application.
Research and Development (R & D)
The R&D department carries out product tests (mechanical and non-destructive tests) in accordance with customer requests.
Customer Service
The sales department is available to respond quickly to any request.

Quality
ISO 9001 certification

SELWFDUPL201308EN

SELECTARC INDUSTRIES
Place des Forges
90600 Grandvillars France
Tel : +33 3 84 57 37 77
Email : [email protected]
www.fsh-welding.com