SENTRO Technologies Online Chemical Cleaning Presentation

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Efficiency & Savings through

On-Line Chemical Cleaning

SENTRO Technologies provides innovative cleaning services to the Refining, Petrochemical & Pipeline industries

www.sentro-technologies.com USA | UK | Germany | Russia | Turkey | India | Brazil | Indonesia SENTRO Technologies
Agenda

Introduction
Online Chemical Cleaning Solutions for
Furnaces, Heaters & Steam Boilers
Air Cooled Heat Exchangers (Fin Fans)
Case Study @ SAPREF
Credentials
Q&A
Introduction:
Online Cleaning for sustainable efficiency

Efficiency

Offline
Cleaning

Time
Introduction:
Online Cleaning for sustainable efficiency

Efficiency

Online
Cleaning

Offline
Cleaning

Time
SENTROMAX
On-line Chemical Cleaning of
Furnaces, Heaters & Steam Boilers

SENTRO Technologies provides innovative cleaning services to the Refining, Petrochemical & Pipeline industries

www.sentro-technologies.com USA | UK | Germany | Turkey | India | Brazil SENTRO Technologies


Radiation & Convection sections become fouled during normal
production

The fouling of the external tube surfaces with


dust, dirt & refractory materials leads to:
Reduced flue gas flow
Increased flue gas temperature
Reduced production Typical fouled radiation tubes
Increased fuel consumption
Increased emissions/pollution
Increased corrosion

And results in:


Plugging & the requirement to shut-down
Typical plugged convection fins
Traditional cleaning methods have significant disadvantages

Methods Disadvantages
Off-Line Cleaning Lost production during shutdown
Uses mechanical means such as high Damage to refractory/insulation
pressure water jet, sand blasting or manual Safety risks from entry to confined areas
labor using steel brushes. Partial cleaning due to limited access to
bundles in convection sections

On-Line Cleaning by Dry Ice Effective only on the upper surface of fin
Uses a spray of dry ice (CO2) bundles (does not penetrate between the
bundles)
Significant risk of thermal shock to fins and
tube supports (made of cast iron) causing
stress cracks, metal deformation &
accelerated corrosion
On-Line Cleaning by hazardous Non-environmental friendly method.
Creation of air pollution with hazardous
chemicals gases during the cleaning.
Uses spraying of toxic chemicals containing
In humid conditions hazardous gases in the
ammonia or low pH acids.
atmosphere can condense and accumulate
on the ground and into water resources.
SENTROMAX On-line Furnace Cleaning
Removal of scale and deposits from the external
tube walls during normal operating conditions
Increase efficiency
Increase production
Save energy
Reduce emission/pollution
Reduced temperature profile
Avoid shutting-down/start-up problems
Save maintenance activities
Future rights for carbon credits (Kyoto Protocol)
Reduced and inhibited tube corrosion
SENTROMAX cleaning procedure
Dry chemical granules are sprayed by compressed air
into the radiation and convection sections

High Return on
Investment
Innovative Chemistry
Safe Process
Environmentally
Friendly
SENTROMAX Radiant cleaning film-clip
SENTROMAX Convection cleaning film-clip
A process of chemistry & physics

Simultaneous combination of
mechanical & chemical effect

Erosion impact through heat and flames

Chemical neutralization reaction with


acidic deposits

Decomposition after reaction


Chemistry & physics cont.

Developed over years of R&D and field


experience

Non-toxic, non-hazardous, non-corrosive,


non-poisonous, non-flammable, non-
explosive, non-transport regulated

Complete decomposition in high temperature

Compatible with furnace metallurgy


On-Line Process

Using existing openings,


windows, or flanges

No need for extra scaffolding

No entry into confined spaces


Radiation section
before and after results
Radiation section
application
Convection section:
Applied through standard OR special
OR soot-blower openings
Plugged convection section before, during, and after

Before After

During During: SENTROMAX draws out dirt


SENTROMAX cleaning delivers Corrosion Resistance

Challenge: Solution:
Fuel impurities including sulphur and SENTROMAX chemical granules are
vanadium cause tube surface coated with nano-sized Alpha-Fe2O3
corrosion and thereby reduces tube Ecotrans R-1 (Magnetite).
life span and increases maintenance
costs. Once the tubes are cleaned of fouling
the Magnetite forms a mono-molecular
passivation film on the tubes that:

1. Acts as a barrier against corrosion

2. Passivates the metal tubes

3. Inhibits further corrosion

4. Extends the tube life


REGAP Refinery, BRASIL

Before cleaning
531C 758C 868C
REGAP Refinery, BRASIL, July
2012
After cleaning 461C 615C 721C
Final results :

A B C
BEFORE 758C 868 C 531C
AFTER 615C 711C 461C
delta T (143C( (147C) )70C(
% 18% 17 % 13%
Milazzo Refinery, ITALY

Before cleaning 900C 948C 973C


Milazzo Refinery, ITALY, May 2012

After cleaning 726C 753C 784C


Cell temp trends : Cell A

Cell B

Cell C
Final results:

Cell A Cell B Cell C


BEFORE 900C 949 C 973C
AFTER 726C 753 C 784C
delta T (174C) (196C) (189C)
% 19% 20% 19%
AXION Refinery, Argentina
Safety Benefits
Personnel hazards avoided
No personnel inside the furnace
Proper Personal Protective Equipment
Professional personnel and attitude

Maintenance & operational benefits


No shut down or start up time needed
No scaffold assembly
No damage to refractory or insulation
No damage to instrumentation
Environmental Benefits
Environmentally friendly process
NO creation of waste
Chemicals burned / dissolved inside the furnace
No creation of acidic waste water (like in off-line cleaning)
SENTROMAX Cost Benefit

Production increased
Fuel consumption reduced
Temperature profile (cell, bridge wall,
stack) decreased

TOTAL EFFICIENCY of the furnace can be


increased by 4-12%

Typical Return On Investment 2-12 weeks


Applicable for all furnaces, heaters and
steam boilers that have negative pressure
and cleaning access (at least 1.5" flanges)
Delayed coker units Hydrotreaters
Flexi coker units Topping units
FCC units Visbreakers
Platformers Vacuum unit
Reformers Atmospheric distillation
Hydrocrackers Process furnaces
Agenda

Introduction
Online Chemical Cleaning Solutions for
Furnaces, Heaters & Steam Boilers
Air Cooled Heat Exchangers (Fin Fans)
Case Study @ SAPREF
Credentials
Q&A
SENTROFIN
On-line Dry Chemical Cleaning of
Air Cooled Heat Exchangers (Fin Fans)

SENTRO Technologies provides innovative cleaning services to the Refining, Petrochemical & Pipeline industries

www.sentro-technologies.com USA | UK | Germany | Russia | Turkey | India | Brazil | Indonesia SENTRO Technologies
Fouled Air Cooled Heat Exchangers lead to the
following problems:

- Low heat transfer efficiency


- High pressure drop
- High outlet temperature
- High energy consumption (fan power)
- Low throughput
- Low total efficiency
Traditional cleaning methods have disadvantages
SENTRO guarantees no damage to the fins

No cleaning means low efficiency High pressure water & walking on fins causes
fin damage

Acid causes damage to fins Foam/Soap evaporates before penetrating


all the way through the bundles
SENTROFIN cleaning solution is:

EFFICIENT
SAFE
ENVIRONMENTALLY
FRIENDLY
COST EFFECTIVE
SENTROFIN dry-chemical cleaning method
Spray dry chemical,
from bottom-to-top,
with compressed air.

Each fan is temporarily


switched off for 45
minutes for cleaning
SENTROFIN Air Coolers cleaning film-clip

Air Cooler Cleaning - Video


SENTROFIN chemical powder

SENTROFIN is a fine It penetrates all the way through


powder that does not the bundle, and disperses like
damage the fins. steam.
SENTROFIN removes 100% of the fouling
(both organic & inorganic) from the bundles
SENTROFIN Advantages

Cleaning during normal operation


Removes all types of fouling from bundles
No damage to fins
No need for scaffolding
No need to enter into the housing
No need to remove the safety net
Visible Cleaning Results !!

Before Cleaning

Half-clean, Half-dirty After Cleaning


fins
Parameters to monitor effectiveness:

Inlet/Outlet temperatures
Airflow
Power of the fan
Visual Inspection

Dirty (light blocked)

Clean (light visible)


Example of increased Air Cooler efficiency

Before Treatment: T in = 47.9C


T out = 40.8C
After Treatment: T in = 47.2C
T out = 37.5C
Delta T = 3.3 C (8.1%)

Throughput benefit: 1,180 $/day


Energy consumption benefit: 243 $/day
Environment:
SENTROFIN cleaning is environmentally friendly

NO creation of waste water


Safety: SENTROFIN is SAFE
Temporarily turn-off each fan for only 45min
No Scaffolding needed
Chemicals are non-corrosive and compatible with all
types of metallurgy, non-hazardous, non-explosive, and
non-toxic
Agenda

Introduction
Online Chemical Cleaning Solutions for
Furnaces, Heaters & Steam Boilers
Air Cooled Heat Exchangers (Fin Fans)
Shell Case Study @ SAPREF
Credentials
Q&A
Case Study: SENTROMAX and SENTROFIN for
SAPREF, Shell BP JV Refinery, Durban, South Africa
To whom it may concern,
The furnace on line cleaning (F7101 A/B/C) of both the radiant and convection bank of Crude
Distiller 2 and the fin fan bank (E7209) was successfully done from Monday 8th April 2013 until
Saturday 13th April 2013.

SENTRO performed this activity with the highest degree of competency and safety. In addition the
housekeeping was excellent.

The final benefit with regards to BWT (bridge wall temperature) is 80 degrees and 25 degrees
benefit with regards to stack temperature. The benefit would have been higher if there were more
accesses to the convection bank.

The fin fan bank of E7209s were cleaned. Prior to the cleaning the fan pitch was at 100%, the feed
rate was at 260 t/d and we were flaring. Soon after the cleaning the fan pitch was at 20%, the unit
feed rate increased to 340t/d and there was no flaring,

Kindest regards
Baker Moodley
Cross Zonal and Combustion Engineer
Shell and BP South African Petroleum Refineries (Pty) LTD
+27314801657 , +27(0)836482300
email: [email protected]
Agenda

Introduction
Online Chemical Cleaning Solutions for
Furnaces, Heaters & Steam Boilers
Air Cooled Heat Exchangers (Fin Fans)
Case Study @ SAPREF
Credentials
Q&A
Track record of On-Line Chemical Cleaning success
across the Americas, Europe, the Middle East & Asia

Eni MOL Dow Chemicals


Italy Italy Canada

YPF
Argentina SAPREF Essar
South Africa India

Petrobas AXION, Tupras


Brazil Argentina Turkey

References & recommendations available


Agenda

Introduction
Online Chemical Cleaning Solutions for
Furnaces, Heaters & Steam Boilers
Air Cooled Heat Exchangers (Fin Fans)
Case Study @ SAPREF
Credentials
Q&A
SENTRO Technologies is an international services
company specializing in on-line dry chemical cleaning
solutions for the petroleum, petrochemical, and power
industries.

To discuss your cleaning requirements please contact:

Email: [email protected]

www.sentro-technologies.com USA | UK | Germany | Russia | Turkey | India | Brazil | Indonesia SENTRO Technologies

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