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    SECTION-I (Multiple Choice Questions) : IIT - JEE: 2015 Crash Course (C-12) Date: Topic: Halogen Derivatives

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    Sachin Dedhia
    This document contains a crash course on halogen derivatives with multiple choice and other question types. It covers topics like halogen substitution reactions, elimination reactions, stereochemistry, and reaction mechanisms. The document tests the understanding of reaction types, products, intermediates, and determining stereochemistry from reaction sequences involving halogenated organic compounds. It contains 14 multiple choice questions, 5 integer answer questions and 2 paragraph type questions testing the comprehension of reaction pathways and identifying compounds from their reactions.

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    SECTION-I (Multiple Choice Questions) : IIT - JEE: 2015 Crash Course (C-12) Date: Topic: Halogen Derivatives

    Uploaded by

    Sachin Dedhia
    43 views7 pages
    This document contains a crash course on halogen derivatives with multiple choice and other question types. It covers topics like halogen substitution reactions, elimination reactions, stereochemistry, and reaction mechanisms. The document tests the understanding of reaction types, products, intermediates, and determining stereochemistry from reaction sequences involving halogenated organic compounds. It contains 14 multiple choice questions, 5 integer answer questions and 2 paragraph type questions testing the comprehension of reaction pathways and identifying compounds from their reactions.

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    PAPER C- 12

    Original Title

    PAPER C- 12

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    This document contains a crash course on halogen derivatives with multiple choice and other question types. It covers topics like halogen substitution reactions, elimination reactions, stereochemistry, and reaction mechanisms. The document tests the understanding of reaction types, products, intermediates, and determining stereochemistry from reaction sequences involving halogenated organic compounds. It contains 14 multiple choice questions, 5 integer answer questions and 2 paragraph type questions testing the comprehension of reaction pathways and identifying compounds from their reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    43 views7 pages

    SECTION-I (Multiple Choice Questions) : IIT - JEE: 2015 Crash Course (C-12) Date: Topic: Halogen Derivatives

    Uploaded by

    Sachin Dedhia
    This document contains a crash course on halogen derivatives with multiple choice and other question types. It covers topics like halogen substitution reactions, elimination reactions, stereochemistry, and reaction mechanisms. The document tests the understanding of reaction types, products, intermediates, and determining stereochemistry from reaction sequences involving halogenated organic compounds. It contains 14 multiple choice questions, 5 integer answer questions and 2 paragraph type questions testing the comprehension of reaction pathways and identifying compounds from their reactions.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 7

    s

    ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI


    IIT JEE: 2015 CRASH COURSE (C-12) DATE:
    TOPIC: HALOGEN DERIVATIVES

    SECTIONI (Multiple Choice Questions)


    This section contains 05 multiple choice questions. Each question has 4 choices (A), (B), (C)
    and (D) for its answer, out which ONLY ONE is correct.


    1. CH 3 Mg Br + Ethyl Ester
    H2O H
    Major product
    ( excess )
    Which can be formed as major product
    CH2H5 C3H7 C2H5 CH3
    C2H5 OH CH3 OH CH3 OH CH3 OH
    C2H5 C2H5 C2H5 CH3
    (a) (b) (c) (d)

    2. In the following reaction intermediate is


    OH

    O O
    O
    Br O

    (a*) Br (b*) Br Br (c*) Br (d) Br

    3.

    4.
    CH3

    NO 2
    Above reaction has maximum rate when
    (a) X = I (b) X = Cl (c) X = Br (d) X = F

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 1


    5. Which of the following pair differentiated by Iodoform reaction
    O O O O
    CH3
    H3C CHH33C H3C H H H
    (a) (b*)
    O O
    O O
    I I
    Ph H
    (c*) Ph H H H (d) I

    6. Which of the following is correct product for the given reaction

    (a) Cl (b)

    (c) Cl (d) Br

    7. Which of the following order is correct for the energy required for heterolytie cleavage of indicated
    C Cl bonds producing carbocation?
    CH2 Cl

    N CH2 Cl
    O O CH2 Cl H
    (I) (II) (III)
    (a) I > II > III (b) III > II > I (c) II > III > I (d) I > III > II

    8. Which of the following reaction will not give ether as a major product
    (a) CH 3 CH 2 Cl + Ag 2 O ( dry )

    (b) ( CH 3 )3 C Cl + C2 H 5 O N a

    (c)
    CH3
    O CH3
    CH3
    (d)

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 2


    9. Gemdichloride is not formed in the reaction as major product
    O
    CH3 CH3 and PCl5
    (a) CH 3 .CHO + PCl5 (b)
    (c) Cl CH 2 =
    CH 2 and HCl (d) CH 2 = CH 2 and Cl2

    SECTION-II (Multiple Choice Questions)


    This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C)
    and (D) for its answer, out which ONE OR MORE is/are correct.

    1. Which of the following reaction is example of syn. elimination



    (a*) CH 3 .CH 2 .CH 2 .OCO.CH 3
    (b*)

    (c)

    (d*)

    SECTION III (Integer Answer Type)


    This section contains 5 questions. The answer to each of the questions is a single digit integer,
    ranging from 0 to 9. The correct digit below the question number in the ORS is be bubbled.

    9. Find sum of ( A + B + C ) in following reactions


    R-1:-
    O
    Ph C CH3
    R-2:-
    Br
    CH3
    H3C
    Br
    R-3:-
    Ph CH CH2
    Cl Cl

    10. How many correct statements (s) about following reaction and related graph is
    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 3
    S-I. P & Q are nucleophilic substitution products by SN 2 mechanism
    S-II.Only R & S are elimination products by E 2 reaction mechanism
    S-III. P is the nucleophilic substitution product by SN 2 reaction mechanism
    S-IV. Q, R, S are elimination products by E 2 reaction mechanism

    11. How many possible products in following reaction


    Br CH CH3

    Me

    12. How many substrates will show rearrangement during SN1 reaction
    CH3
    CH3 I
    H3C CH3 Ph Br
    H3C
    H3C Br H3C CH3
    CH3 CH3
    Br
    Br H3C

    CH3 Cl
    Br
    CH3
    CH3 Br
    Cl
    CH3

    13. Find number of equivalents of GRIGNARD reagent (X) used in following reaction is

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 4


    OH
    CH3.O 2C NH-C 2H5

    HS
    SECTION IV (Paragraph Type)
    This section contains 2 multiple choice questions relating to 1 paragraph. Each question has
    four choices (A), (B), (C) and (D) out of which ONLY ONE is correct.

    Passage for (Que. No. 14-15)


    An optically active hydrocarbon (A) has molecular formula C8 H18 . A on monochlorination give five
    alkyl halide B to F with their molecular formula C8 H17 Cl . B does not undergo dehydrohalogenation
    on treatement with alcoholic solution of KOH. Treatment of either C or D with alcoholic KOH yield
    same alkene ( C8 H16 ) , which on ozonolysis following by work up with zn dimethyl sulphide give an
    optically inactive compound C6 H12 O and ethanal. Also (C) enantiomeric where as ( D) is
    distereomeric E on dehydrohalogenation yields analkene. Which on reductive ozonolysis yields
    ( H )( C7 H14O ) , which is optically inactive ( H ) on treatment with LiAlH 4 yields I ( C7 H16 O ) which
    can be resolved into enantiomers. (F) on dehydrohalogenation yields an alkene ( C8 H16 ) , which on
    reduction ozonolysis yields ( J )( C7 H14 O ) which is optically active and have same configuration as
    that of (A) Identifiy (A) to (Z)
    14. Structure of (A) is
    CH3 CH3
    H3C CH3
    H3C
    CH3 CH3
    (a) (b)
    CH3 CH3
    H3C
    H3C CH3 CH3
    CH3
    CH3 CH3
    (c*) (d)

    15. Structure of (B) is


    Cl
    Cl
    H3C CH3 H3C CH3
    CH3
    CH3 CH3
    (a) (b*)
    CH3
    Cl CH3 CH3
    H3C CH3 Br
    CH3 H3C
    CH3 CH3
    (c) (d)

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 5


    SECTION - IV (Matrix Match Type)
    This section 1 Question. Each question has four statements Given in Column - I and four
    statements in Column II. Any given statement in Column I can have correct matching with
    one or more statement (s) given in column II.

    16. Match the following

    Column I Column II
    (A) CH 3 CH ( Br ) CD3 on (P) E1 reaction
    treatment with alc. KOH gives
    CH =2 CH CD3 as a major
    product
    (B) Ph CHBr CH 3 reacts faster (Q) E 2 reaction
    then Ph CHBr CD3
    (C) Ph CH 2 CH 2 Br on (R) E1CB reaction
    treatment with

    C2 H 5OD / C2 H 5 .O gives
    Ph.CD = CH 2 as the major
    product
    (D) Ph CH 2 CH 2 Br and (S) First order
    Ph CD 2 .CH 2 Br react with
    same rate

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 6


    ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
    TOPIC: (ANSWER KEY)

    1 [] 2 [] 3 [] 4 [] 5 [] 6 [] 7 []

    8 [] 9 [] 10 [] 11 [] 12 [] 13 []

    14 [] 15 [] 16 []

    CENTERS: MUMBAI / DELHI / AKOLA / KOLKATA / LUCKNOW / NASHIK / GOA / PUNE # 7

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