2.

2 Manual Calculation of Materials and Energy Balances

2.2.1 Mass Balance
Plant complete if the amount that targeted is achieved.
Here, in order to achieve the target, the amount needed for each hour need to
be known operation day are assumed 333 days with 32 days shutdown and the
plant operation 24 hours per day.
Butadiene will produce 333 MT/ year:
333 MT per year
1 MT per day
1000 kg per day
41.67 kg per hour
Therefore, to make sure we could achieve the amount production, the mass flow
rate production must be 41.67kg/hr. So below is the assumption that our group
have been made:
Assumptions:
The processes follow the law of conservation of mass where:

Material out = Material in + Generation Consumption Accumulation

Steady-state condition in all equipment
Pure reactants are used
No leakage in pipes and vessel in the system.
All stream flow rate is in unit kg/h.
Catalyst used in reactor does not contribute in mass.
The entire components in the system behave as ideal condition.
The total input of any substance to a pump, valve or mixer is assumed
equal to the total output of the substance where no reaction occurs in that
device.

Components involve:

Components Formula Molecular Weight

Butane C4 H10 58.12
1-Butene C4H8 56.10
2-Butene C4H8 56.10
1,3-Butadiene C4H6 54.09
Water H2O 18.016
Carbon dioxide CO2 44.01
Hydrogen H2 2.016
Oxygen O2 32.00
Nitrogen N2 28.02
Table: Components formulas and Molecular Weight
2.3 Mass and Energy Balance

2.3.1 Mass Balance in Fixed Bed Reactor (FBR) BDH

R-101

STREAM DESCRIPTION TEMPERATURE(0C) PRESSURE(atm)

3b Inlet 200 1.0

2 Inlet 300 2.0

4 Inlet 30 4.5

5 Outlet 550 1.0

Table: The Operation of Reactor 1

Stream Name S4 S2 S3b S5
Stream Phase Gas Gas Gas Gas
Pressure 1.0 atm 2.0 atm 1.0 atm 1.0 atm
Temperature(0c) 30 300 200 550
Total Flow Rate 45.8602324 100.468209 35.578701
(kg/hr)
For Initial Feed

Total Flow Rate - - 246.560494

(kg/hr)
Outlet or recycle
back

Table: Input stream of FBR (1st reactor)

Input Stream (kg/kg) Output

COMPONENT S4 S2 S3 S5
Butane 1.0 0 0 0.1860
1-Butene 0 0 0 0.0614
2-Butene 0 0 0 0.1316
1,3-Butadiene 0 0 0 0.0127
Water 0 0 1.0 0.1443
Carbondioxide 0 0 0 0.0065
Hydrogen 0 0.1429 0 0.2245
Oxygen 0 0.2853 0 0
Nitrogen 0 0.5718 0 0.2330
Table: Composition in FBR

Inlet FBR
 Stream 2
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 7894.647 0
Oxygen 0 8459.949 0
Nitrogen 5.69093505 8206.952 46705.2308

5868052.75
TOTAL
Table: Heat of FBR input

Inlet FBR
Stream 3b
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate

Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 11837.823
Carbondioxide 1.97 6009.047 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 11837.823
Table: Heat of FBR input
 Inlet FBR
Stream 1
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 490.207 38682.234
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 38682.234
Table: Heat of FBR input

Inlet FBR
Stream 5
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 26.99 54976.598 1483818.38
2-Butene 57.84 54709.397 3164391.52
1,3-Butadiene 5.79 50283.658 291142.38
Water 197.48 15107.457 2983420.61
Carbondioxide 3.64 18599.423 67701.9
Hydrogen 712.16 12328.319 8779735.66
Oxygen 0 0 0
Nitrogen 205.03 12849.743 2634582.81
TOTAL 24367012.9
Table: Heat of FBR output
 Heat Formation (Endothermic reaction)
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 -1.26E+005 -9926088.9
1-Butene 26.99 -5.40E+002 -14574.6
2-Butene 57.84 -5.40E+002 -31233.6
1,3-Butadiene 5.79 1.09E+005 632499.6
Water 197.48 -2.42E+004 -4779016
Carbondioxide 3.64 -3.94E+005 -1432372.8
Hydrogen 712.16 0 0
Oxygen 0 0 0
Nitrogen 205.03 0 0
TOTAL -15550786
Table: Heat formation of process

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream
S1 S2 S3b S5
Butane 45.8602324 0 0 45.8
1-Butene 0 0 0 15.1
2-Butene 0 0 0 32.4
1,3-Butadiene 0 0 0 3.13
Water 0 0 35.578701 35
Carbondioxide 0 0 0 1.60
Hydrogen 0 0 0 55.3
Oxygen 0 0 0
Nitrogen 0 100.468209 0 57.4
NMP 0
Total 45.8602324 100.468209 35.578701 246

2.3.3 Mass Balance in Fixed Bed Reactor (2nd reactor) - Oxo-D reaction
R-102
STREAM DESCRIPTION TEMPERATURE(0C) PRESSURE(atm)

5 Inlet 550 1.0

6 Inlet 34 1.0

7 Outlet 450 2.0

Table: The Operation Condition of Reactor 2

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream
S5 S6 S7
Butane 45.8602324 0 45.8602324
1-Butene 15.1388181 0 0
2-Butene 32.4473182 0 20.8692341
1,3-Butadiene 3.13131626 0 28.5921552
Water 35.578701 0 65.2543251
Carbondioxide 1.60265739 0 5.90065722
Hydrogen 55.3528237 0 17.3548706
Oxygen 0 17.354884 194.808461
Nitrogen 57.4486269 65.2873413 55.2318817
NMP 0 0 0
Total 246.560494 82.6422253 433.871817
Table: Inlet and Outlet stream of FBR (2 nd reactor)

Inlet FBR
 Stream 5
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 62884.548 4962219.68
1-Butene 26.99 54976.598 1483818.38
2-Butene 57.84 54709.397 3164391.52
1,3-Butadiene 5.79 50283.658 291142.38
Water 197.48 15107.457 2983420.61
Carbondioxide 3.64 18599.423 67701.9
Hydrogen 712.16 12328.319 8779735.66
Oxygen 0 0 0
Nitrogen 205.03 12849.743 2634582.81
TOTAL 24367012.9
Table: Inlet Stream of FBR (2nd reactor)

Inlet FBR
Stream 6
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0 0 0
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 281.83 270.038 76104.81
Nitrogen 492.93 262.032 129163.434
TOTAL 205268.244
Table: Inlet Stream of FBR (2nd reactor)
 Inlet FBR
Stream 7
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 0 0 0
2-Butene 37.2 54709.397 2035189.57
1,3-Butadiene 52.86 50283.658 2657994.16
Water 362.2 15107.457 5471920.93
Carbondioxide 13.41 18599.423 249418.262
Hydrogen 860.85 12328.319 10612833.4
Oxygen 608.78 13249.802 8066214.46
Nitrogen 197.12 12849.743 2532941.34
TOTAL 36588731.8
Table: Outlet Stream of FBR (2nd reactor)

Heat Formation
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 78.91 -1.26E+005 -9926088.9
1-Butene 0 -5.40E+002 0
2-Butene 37.2 -5.40E+002 -20088
1,3-Butadiene 52.86 1.09E+005 5774426.4
Water 362.2 -2.42E+004 -8765240
Carbondioxide 13.41 -3.94E+005 -5276955.7
Hydrogen 860.85 0 0
Oxygen 608.78 0 0
Nitrogen 197.12 0 0
TOTAL -18213946
Table: Heat of Formation for the process
2.3.5 Mass Balance in Heat Exchanger
E-101

STREAM DESCRIPTION TEMPERATURE(0C) PRESSURE(atm)

7a Inlet 200 2.0

8 Outlet 40 1.0

9a Outlet 40 0.095

Table : The Operation Condition of Heat Exchanger

Stream 7
E-101 Stream 7a

Function
To remove the water, maintain the temperature and recycle the
water into condenser

Condition
Phase : Liquid Phase
Operating Temperature : 160oc
Operating Pressure : 1 atm

COMPONENT Mass flow rate (kg/hr)

Inlet Outlet stream
stream
 S7a S8 S9a
Butane 66.955704 0.00969352 66.9570948
1-Butene 0 0 0
2-Butene 30.4689628 6.62067323 23.8212741
1,3-Butadiene 41.7443793 0.01938704 41.7945327
Water 9.52709355 90.1497234 4.88228816
Carbondioxide 8.61492502 0.10662871 8.47693989
Hydrogen 80.638232 0 80.638232
Oxygen 25.3380148 0.00969352 25.4308197
Nitrogen 284.419216 0.01938704 284.514001
NMP 0 0 0
Total 547.706527 96.9351864 536.515183
Table: Inlet and Outlet Streams

Inlet FBR
Stream 7
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 78.91 62884.548 4962219.68
1-Butene 0 0 0
2-Butene 37.2 54709.397 2035189.57
1,3-Butadiene 52.86 50283.658 2657994.16
Water 362.2 15107.457 5471920.93
Carbondioxide 13.41 18599.423 249418.262
Hydrogen 860.85 12328.319 10612833.4
Oxygen 608.78 13249.802 8066214.46
Nitrogen 197.12 12849.743 2532941.34
TOTAL 36588731.8
Table: Energy balance at inlet stream for Heat
Exchanger

Inlet FBR
Stream 7a
 H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.16 21056.087 2130033.76
1-Butene 0 0 0
2-Butene 47.69 18566.496 885436.194
1,3-Butadiene 67.77 16781.533 1137284.49
Water 464.37 6009.047 2790421.16
Carbondioxide 17.19 7258.533 124774.182
Hydrogen 3513.27 4988.39 17525560.9
Oxygen 69.53 5334.38 370899.441
Nitrogen 891.37 5175.577 4613354.07
TOTAL 29577764.2
Table: Energy balance at Outlet stream for Heat
Exchanger

Inlet FBR
Stream 9a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 1491.535 150824.019
1-Butene 0 0 0
2-Butene 37.27 1340.899 49975.306
1,3-Butadiene 67.82 1220.147 82750.37
Water 23.79 1125.511 26775.907
Carbondioxide 16.91 598.945 10128.16
Hydrogen 1107.25 0 0
Oxygen 780.43 450.326 351447.92
Nitrogen 252.61 436.974 110384.002
TOTAL 782285.684
Table: Energy Balance at Outlet stream for Heat
Exchanger
 Outlet
Heat Vapourization
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 22.305 2255.482
1-Butene 0 21.916 0
2-Butene 37.27 21.916 816.809
1,3-Butadiene 67.82 0 0
Water 23.79 40.706 968.396
Carbondioxide 16.91 15.326 259.163
Hydrogen 1107.25 0.964 1067.389
Oxygen 780.43 6.82 5322.533
Nitrogen 252.61 5.577 1408.806
TOTAL 12098.578
Table: Heat Vaporization at Heat Exchanger

2.3.7 Mass Balance in Condenser (Air cooled)

E-102

Stream Description Temperature(0c) Pressure(atm)

7a Inlet 200 1.0

8 Outlet 30 1.0

9 Outlet 40 1.0

Stream 8

E-102
Stream 7a Stream 9
Function
To recycle back the water to cover another process
Condition.
Phase : Liquid Phase
Operating Temperature : 100 oc
Operating Pressure : 1 atm

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream

S7a S8 S9

Butane 58.7966355 0.00853281 58.7724831

1-Butene 0 0 0

2-Butene 26.7560854 5.827779 20.9094411

1,3-Butadiene 36.6575048 0.01706495 36.6857089

Water 83.6614373 79.3533634 4.28549334

Carbondioxide 7.56512968 0.0938589 7.44074689

Hydrogen 70.8118416 0.00853281 22.3222413

Oxygen 22.2503822 0.00853281 249.735961

Nitrogen 249.760542 0.00853281 70.7812838

NMP 0 0 0

Total 556.259558 85.3261975 470.933359

Table: Inlet and Outlet Stream of Condenser (air
cooled )
 Inlet FBR
Stream 7a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.16 497798.8 50357326.6
1-Butene 0 0
2-Butene 47.69 48081.6 2293011.5
1,3-Butadiene 67.77 46364.4 3142115.39
Water 464.37 15454.8 7176745.48
Carbondioxide 17.19 37778.4 649410.696
Hydrogen 3513.27 1717.2 6032987.24
Oxygen 69.53 27475.2 1910350.66
Nitrogen 891.37 24040.8 21429247.9
TOTAL 92991195.5
Table: Inlet Stream of condenser (air cooled)

Inlet FBR
Stream 8
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.01 7540 75.4
1-Butene 0 0
2-Butene 10.39 874.972 9090.959
1,3-Butadiene 0.03 7020 210.6
Water 440.46 11913.966 5247625.46
Carbondioxide 0.21 5720 1201.2
Hydrogen 0.42 260 109.2
Oxygen 0.03 4160 124.8
Nitrogen 0.03 3640 109.2
TOTAL 5258546.82
Table: Inlet Stream of Condenser
 Inlet FBR
Stream 9
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 10086.2 1019916.54
1-Butene 0 0
2-Butene 37.27 9738.4 362950.168
1,3-Butadiene 67.82 9390.6 636870.492
Water 23.79 3130.2 74467.458
Carbondioxide 16.91 7651.6 129388.556
Hydrogen 1107.25 347.8 385101.55
Oxygen 780.43 5564.8 4342936.86
Nitrogen 252.61 4869.2 1230008.61
TOTAL 8181640.24
Table: Outlet Stream Condenser (air
cooled)

Mole flow rate Heat Vaporization, Q= nH (J)

Hv
Butane 101.12 22.305 2255.482
1-Butene 0 21.916 0
2-Butene 37.27 21.916 816.809
1,3-Butadiene 67.82 0 0
Water 23.79 40.706 968.396
Carbondioxide 16.91 15.326 259.163
Hydrogen 1107.25 0.964 1067.389
Oxygen 780.43 6.82 5322.533
Nitrogen 252.61 5.577 1408.806
TOTAL 12098.578
Table: Heat of Formation for the process
2.3.9 Mass Balance in Compressor
C-107A/B

Stream Description Temperature(oc) Pressure (atm)

9 Outlet 100 1.50

9a Inlet 40 0.95

Table: The Operation Condition of Heat Exchanger

Stream 9 E-107 Stream 9a

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream
S9 S9a
Butane 58.7724831 58.7724831
1-Butene 0 0
2-Butene 20.9094411 20.9094411
1,3-Butadiene 36.6857089 36.6857089
Water 4.28549334 4.28549334
Carbondioxide 7.44074689 7.44074689
Hydrogen 22.3222413 22.3222413
Oxygen 249.735961 249.735961
Nitrogen 70.7812838 70.7812838
NMP 0 0
Total 470.933359 470.933359
Table: balance Inlet and Outlet Stream of Compressor

Inlet FBR
 Stream 9
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.12 1491.535 150824.019
1-Butene 0 0
2-Butene 37.27 1340.899 49975.306
1,3-Butadiene 67.82 1220.147 82750.37
Water 23.79 1125.511 26775.907
Carbondioxide 16.91 598.945 10128.16
Hydrogen 1107.25 422.643 467971.462
Oxygen 780.43 450.326 351447.92
Nitrogen 252.61 436.974 110384.002
TOTAL 1250257.15
Table: Energy Balance at Compressor

Inlet FBR
Stream 9a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 101.12 2122.514 214628.616
1-Butene 0 0
2-Butene 37.27 7189.784 267963.25
1,3-Butadiene 67.82 6609.026 448224.143
Water 23.79 2543.847 60518.12
Carbondioxide 16.91 3038.834 51386.683
Hydrogen 1107.25 2122.514 2350153.63
Oxygen 780.43 2264.693 1767434.36
Nitrogen 252.61 2197.475 555104.16
TOTAL 5715412.96
Table: Energy Balance at Compressor

Q= nH (J)
COMPONENT Mole flow rate Heat
 Vaporiztion,Hv

Butane 101.12 22.305 2255.482

1-Butene 0 21.916 0
2-Butene 37.27 21.916 816.809
1,3-Butadiene 67.82 0 0
Water 23.79 40.706 968.396
Carbondioxide 16.91 15.326 259.163
Hydrogen 1107.25 0.964 1067.389
Oxygen 780.43 6.82 5322.533
Nitrogen 252.61 5.577 1408.806
TOTAL 12098.578
Table: Heat Vaporization at Compressor

2.4.1 Mass Balance in Absorption Tower

T-101

Stream Description Temperature(0c) Pressure (atm)

9 Inlet 100 1.50
10 Outlet 40 0.95
11 Outlet 40 0.95
Table: The Operation Condition of Absorption Tower

Stream 10

Stream 9 Stream 11
T-101

Function
 To remove the water and inert gas .

Phase : Gas Phase

Operating Temperature : 60oc
Operating Pressure : 1 atm

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream

S9 S10 S11

Butane 58.7724831 0.20973285 58.5653918

1-Butene 0 0 0

2-Butene 20.9094411 0.27964313 20.6465765

1,3-Butadiene 36.6857089 0.1398219 36.5350942

Water 4.28549334 1.01370778 3.28937204

Carbondioxide 7.44074689 5.24331458 2.1726851

Hydrogen 22.3222413 70.7847479 0

Oxygen 249.735961 22.196699 0.1092414

Nitrogen 70.7812838 249.686644 0.06068944

NMP 0 0 0

Total 470.933359 349.554311 121.379051

Table: Mass balance Inlet and Outlet Stream

Inlet FBR
Stream 9
 H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 101.12 2122.514 214628.616
1-Butene 0 0
2-Butene 37.27 7189.784 267963.25
1,3-Butadiene 67.82 6609.026 448224.143
Water 23.79 2543.847 60518.12
Carbondioxide 16.91 3038.834 51386.683
Hydrogen 1107.25 2122.514 2350153.63
Oxygen 780.43 2264.693 1767434.36
Nitrogen 252.61 2197.475 555104.16
TOTAL 5715412.96
Table: Energy balance for Input Absorption Tower

Inlet FBR
Stream 10
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.361 1491.535 538.444
1-Butene 0 0
2-Butene 0.498 1340.899 667.768
1,3-Butadiene 0.258 1220.147 314.798
Water 5.627 1125.511 6333.25
Carbondioxide 11.914 598.945 7135.831
Hydrogen 3511.148 422.643 1483962.12
Oxygen 69.365 450.326 31236.863
Nitrogen 891.102 436.974 389388.405
TOTAL 1919577.48
Table: Energy Balance for Output Absorption
Tower

Inlet FBR
 Stream 11
H, Enthalpy
(kj/mol) Q= nH (J)
Mole flow rate
COMPONENT
Butane 100.766 1491.535 150296.016
1-Butene 0 0
2-Butene 36.803 1340.899 49349.106
1,3-Butadiene 67.545 1220.147 82414.829
Water 18.258 1125.511 20549.58
Carbondioxide 4.937 598.945 2956.991
Hydrogen 0 422.643 0
Oxygen 0.341 450.326 153.561
Nitrogen 0.217 436.974 94.823
TOTAL 305814.906
Table: Energy Balance for Output Absorption
Tower

Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 100.766 22.305 2247.586
1-Butene 0 21.916 0
2-Butene 36.803 21.916 806.575
1,3-Butadiene 67.545 0 0
Water 18.258 40.706 743.21
Carbondioxide 4.937 15.326 75.664
Hydrogen 0 0.964 0
Oxygen 0.341 6.82 2.326
Nitrogen 0.217 5.577 1.21
TOTAL 3876.571
Table: Heat Vaporization at Absorption Tower
Function
To remove water, maintain the temperature and recycle the water
into waste boiler
Condition
Phase : Liquid Phase
Operating Temperature : 30 oc
Operating Pressure : 5 atm

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream

S11 S12 S13

Butane 58.5653918 66.722855 0.42090904

1-Butene 0 0 0

2-Butene 20.6465765 23.5395758 0

1,3-Butadiene 36.5350942 0 41.67

Water 3.28937204 3.76053181 0

Carbondioxide 2.1726851 2.47479729 0

Hydrogen 0 0 0

Oxygen 0.1092414 0.1256733 0

Nitrogen 0.06068944 0.05800306 0

NMP 0 0 0

Total 121.379051 96.6814362 42.090909

 Inlet FBR
Stream 11
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 100.766 1491.535 150296.016
1-Butene 0 0
2-Butene 36.803 1340.899 49349.106
1,3-Butadiene 67.545 1220.147 82414.829
Water 18.258 1125.511 20549.58
Carbondioxide 4.937 598.945 2956.991
Hydrogen 0 422.643 0
Oxygen 0.341 450.326 153.561
Nitrogen 0.217 436.974 94.823
TOTAL 305814.906
Table: Energy balance for Input Extractive
Distillation Column

Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 92.084 4659.945 429106.375
1-Butene 0 0 0
2-Butene 36.478 4169.698 152102.244
1,3-Butadiene 0.293 0 0
Water 16.723 1521.028 25436.151
Carbondioxide 4.504 1810.12 8152.78
Hydrogen 0 0 0
Oxygen 0.322 1354.907 436.28
Nitrogen 0.17 1314.716 223.502
TOTAL 615457.332
Table: Energy Balance for Output Extractive
Distillation Column
 Inlet FBR
Stream 13
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 0.724 209.3 151.533
1-Butene 0 0 0
2-Butene 0 0 0
1,3-Butadiene 77.038 7251.714 558657.543
Water 0 0 0
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 558809.076
Table: Energy Balance for Output Extractive
Distillation Column

Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 92.084 22.305 2053.934
1-Butene 0 21.916 0
2-Butene 36.478 21.916 799.452
1,3-Butadiene 0.293 0 0
Water 16.723 40.706 680.726
Carbondioxide 4.504 15.326 69.028
Hydrogen 0 0.964 0
Oxygen 0.322 6.82 2.196
Nitrogen 0.17 5.577 0.948
TOTAL 3606.284
Table: Heat Vaporization at Extractive Distillation
Column
 COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet Outlet stream

stream

S12 S12a S12c

Butane 66.722855 49.0802571 0

1-Butene 0 41.0178316 0

2-Butene 23.5395758 3.01615919 0

1,3-Butadiene 0 0 0

Water 3.76053181 0.2513466 0

Carbondioxide 2.47479729 0 0

Hydrogen 0 0.08700459 0

Oxygen 0.1256733 0.03866871 0

Nitrogen 0.05800306 0 0

NMP 0 0 13.3210655
Total 96.6814362 93.4912678 0

Table: Inlet and Outlet streams

Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 114.802 4659.945 534971.006
1-Butene 0 0 0
2-Butene 41.96 4169.698 174960.528
1,3-Butadiene 0 0 0
Water 20.873 1521.028 31748.417
Carbondioxide 5.623 1810.12 10178.305
Hydrogen 0 0 0
Oxygen 0.393 1354.907 532.478
Nitrogen 0.207 1314.716 272.146
TOTAL 752662.88
Table: Energy balance for Input Solvent Recovery
Column

Inlet FBR
Stream 12a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 84.446 53583.913 4524947.12
1-Butene 73.098 46892.33 3427735.54
2-Butene 5.376 46698.873 251053.141
1,3-Butadiene 0 0 0
Water 1.395 13233.507 18460.742
Carbondioxide 7.271 16244.64 118114.777
Hydrogen 4.316 0 0
Oxygen 0.121 11639.901 1408.428
Nitrogen 0 11289.699 0
TOTAL 8341719.74
Table: Energy Balance for Output Solvent
Recovery Column
 Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 84.446 22.305 1883.568
1-Butene 73.098 21.916 1602.016
2-Butene 5.376 21.916 117.82
1,3-Butadiene 0 0 0
Water 1.395 40.706 56.785
Carbondioxide 7.271 15.326 111.435
Hydrogen 4.316 0.964 4.161
Oxygen 0.121 6.82 0.825
Nitrogen 0 5.577 0
TOTAL 3776.61
Table: Heat Vaporization at Solvent Recovery
Column
 Mass flow rate (kg/hr)
COMPONENT

Inlet stream Outlet stream

S12 S12a

Butane 66.722855 49.0802571

1-Butene 0 41.0178316

2-Butene 23.5395758 3.01615919

1,3-Butadiene 0 0

Water 3.76053181 0.2513466

Carbondioxide 2.47479729 0

Hydrogen 0 0.08700459

Oxygen 0.1256733 0.03866871

Nitrogen 0.05800306 0

NMP 0 0
Total 96.6814362 93.4912678
Table: Inlet and Outlet streams

Inlet FBR
Stream 12
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 114.802 4659.945 534971.006
1-Butene 0 0 0
2-Butene 41.96 4169.698 174960.528
1,3-Butadiene 0 0 0
Water 20.873 1521.028 31748.417
Carbondioxide 5.623 1810.12 10178.305
Hydrogen 0 0 0
Oxygen 0.393 1354.907 532.478
Nitrogen 0.207 1314.716 0
TOTAL 752390.734
Table: Energy balance for Input Isomerization Stage
in FBR

Inlet FBR
Stream 12a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 84.446 53583.913 4524947.12
1-Butene 73.098 46892.33 3427735.54
2-Butene 5.376 46698.873 251053.141
1,3-Butadiene 0 0 0
Water 1.395 13233.507 18460.742
Carbondioxide 7.271 16244.64 118114.777
Hydrogen 4.316 0 0
Oxygen 0.121 11639.901 1408.428
Nitrogen 0 11289.699 0
TOTAL 8341719.74

Table: Energy Balance for Output Isomerization

Stage in FBR

Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 114.802 22.305 2560.659
1-Butene 0 21.916 0
2-Butene 41.96 21.916 919.595
1,3-Butadiene 0 0 0
Water 20.873 40.706 849.656
Carbondioxide 5.623 15.326 86.178
Hydrogen 0 0.964 0
Oxygen 0.393 6.82 2.68
Nitrogen 0.207 5.577 1.154
TOTAL 4419.922
Table: Heat Vaporization at Isomerization Stage in
FBR

COMPONENT Mass flow rate (kg/hr)

Inlet stream Outlet stream
S12a S14 S15
Butane 49.0802571 45.9570008 2.69638414
1-Butene 41.0178316 0 41.2324049
2-Butene 3.01615919 3.07529957 0
1,3-Butadiene 0 0 0
Water 0.2513466 0.2513466 0
Carbondioxide 0 0 3.33138498
Hydrogen 0.08700459 0 0
Oxygen 0.03866871 0 0.09003743
Nitrogen 0 0 0.03317169
NMP 0 0 0
Total 93.4912678 49.283647 47.3833832
Table: Inlet and Outlet streams
 Inlet FBR
Stream 12a
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 84.446 53583.913 4524947.12
1-Butene 73.098 46892.33 3427735.54
2-Butene 5.376 46698.873 251053.141
1,3-Butadiene 0 0 0
Water 1.395 13233.507 18460.742
Carbondioxide 7.271 16244.64 118114.777
Hydrogen 4.316 0 0
Oxygen 0.121 11639.901 1408.428
Nitrogen 0 11289.699 0
TOTAL 8341719.74
Table: Energy balance for Input Distillation
Column

Inlet FBR
Stream 14
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 79.073 490.207 38762.138
1-Butene 0 0 0
2-Butene 5.507 441.451 2431.071
1,3-Butadiene 0 0 0
Water 1.395 168.254 234.714
Carbondioxide 0 0 0
Hydrogen 0 0 0
Oxygen 0 0 0
Nitrogen 0 0 0
TOTAL 41427.923
Table: Energy Balance for Output Distillation
Column
 Inlet FBR
Stream 15
H, Enthalpy
(kj/mol) Q= nH (J)
COMPONENT Mole flow rate
Butane 4.639 887.404 4116.667
1-Butene 73.498 780.367 57355.414
2-Butene 0 0 0
1,3-Butadiene 0 0 0
Water 0 0 0
Carbondioxide 7.57 358.833 2716.366
Hydrogen 0 0 0
Oxygen 0.281 270.038 75.881
Nitrogen 0.118 262.032 30.92
TOTAL 64295.248
Table: Energy Balance for Output Distillation
Column

Q= nH (J)
COMPONENT Mole flow rate Heat
Vaporiztion,Hv
Butane 79.073 22.305 1763.723
1-Butene 0 21.916 0
2-Butene 5.507 21.916 120.691
1,3-Butadiene 0 0 0
Water 1.395 40.706 56.785
Carbondioxide 0 15.326 0
Hydrogen 0 0.964 0
Oxygen 0 6.82 0
Nitrogen 0 5.577 0
TOTAL 1941.199
Table: Heat Vaporization at Distillation Column