Comm Profile Cement PDF
Comm Profile Cement PDF
Comm Profile Cement PDF
MATERI ALS
November 2005
BRITISH GEOLOGICAL SURVEY
MI NERAL PROFI LE
BRITISH GEOLOGICAL SURVEY
1: Definition, mineralogy and deposits
1.1 Definition and mineralogy
1.2 Deposits
2: Extraction and processing
2.1 Extraction
2.2 Cement making
3: Specification and uses
3.1 Specification
3.2 Uses
4: World production
5: Alternative materials
5.1 Alternative raw materials
5.2 Alternative fuels
6: Building stone - focus on the UK
6.1 Resources
6.2 Reserves
6.3 Structure of the Industry
6.4 Production
6.5 Consumption
6.6 Trade
6.7 Issues
7: Further reading
MI NERAL PROFI LE: CEMENT
RAW MATERI ALS
Contents
BRITISH GEOLOGICAL SURVEY
1.1 Definition and mineralogy
Cement is a manufactured product made by blending different raw materials and firing
them at a high temperature in order to achieve precise chemical proportions of lime, silica,
alumina and iron in the finished product, known as cement clinker. Cement is therefore
essentially a mixture of calcium silicates and smaller amounts of calcium aluminates that
react with water and cause the cement to set.
The requirement for calcium is met by using high calcium limestone (or its equivalent
calcareous raw material) and clay, mudstone or shale as the source of most of the silica
and alumina. Finished cement is produced by finely grinding together around 95% cement
clinker with 5% gypsum (or anhydrite) which helps to retard the setting time of the cement.
The quality of cement clinker is directly related to the chemistry of the raw materials used.
Around 8090% of raw material for the kiln feed is limestone. Clayey raw material
accounts for between 1015%, although the precise amounts will vary. Magnesium
carbonate, which may be present in limestone, is the main undesirable impurity. The level
of magnesia (MgO) in the clinker should not exceed 5% and many producers favour a
maximum of 3%; this rules out dolomite or dolomitic limestones for cement manufacture.
Other deleterious materials include excessive alkalis (sodium oxide, Na
2
O or soda and
potassium oxide, K
2
O) which would be unacceptable because of durability problems with
the concrete (due to the reaction of alkalis with some siliceous aggregates to form a
swelling gel
).
Portland cement is the most widely produced cement, both in the UK and worldwide. The
term Portland cement was created by its inventor in 1824 because of the presumed
resemblance of the set material to Portland Stone, the well-known natural building stone.
Other varieties include rapid hardening, low heat, sulfate resisting, and low-alkali cements.
In addition, blended cements are produced by finely grinding Portland cement clinker with
other constituents, such as blast furnace slag, natural pozzolanas
, silica fume,
metakaolin
A jelly-like substance that increases in volume with adverse effects on cement durability and strength.
Volcanic ash, named after the type locality Pozzuoli, in Italy, used in the manufacture of a kind of mortar
which hardens under water.