„I have known Anupam for more than a decade now. He is very hardworking, dedicated and a highly intelligent person. He was the gold medalist from our university years and has always excelled at every task he undertakes through his sheer will. He is extremely great at grasping new concepts and at application of his knowledge. I wish him the best of luck with all his future endeavors. -Himanshu“
Anupam Yadav, ir. Dr.
München, Bayern, Deutschland
1641 Follower:innen
500+ Kontakte
Info
Since 2024, Anupam is working as a scientist and engineer at the Dynamic Structure and…
Serviceleistungen
Aktivitäten
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I’m excited to share the latest episode of GT Tech Talk on Fuel Reformers Technology! Talking to our experts and learning more about this fascinating…
I’m excited to share the latest episode of GT Tech Talk on Fuel Reformers Technology! Talking to our experts and learning more about this fascinating…
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☀️ 𝐒𝐭𝐚𝐫𝐭𝐢𝐧𝐠 𝐚 𝐍𝐞𝐰 𝐂𝐡𝐚𝐩𝐭𝐞𝐫 𝐢𝐧 𝐌𝐲 𝐂𝐚𝐫𝐞𝐞𝐫 🌞 Today marks my last day at Qcells in Germany—an appreciated opportunity to…
☀️ 𝐒𝐭𝐚𝐫𝐭𝐢𝐧𝐠 𝐚 𝐍𝐞𝐰 𝐂𝐡𝐚𝐩𝐭𝐞𝐫 𝐢𝐧 𝐌𝐲 𝐂𝐚𝐫𝐞𝐞𝐫 🌞 Today marks my last day at Qcells in Germany—an appreciated opportunity to…
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We need more people like pi Ventures (Alisha Parveen) who believe on the kind of impact quantum technology can have on the future. We need more…
We need more people like pi Ventures (Alisha Parveen) who believe on the kind of impact quantum technology can have on the future. We need more…
Beliebt bei Anupam Yadav, ir. Dr.
Berufserfahrung
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DFG MULTITRANS Project
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Ausbildung
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KU Leuven
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Activities and Societies: Interdisciplinary Research & Consulting Process Design & Product Development Data Analytics Computational Problem Solving Thin Film Deposition Instrumentation Microscopy & Operando Spectroscopy Catalysis & Electrochemistry Structure-Property Relationship Good Manufacturing Practice (GMP) Environment, Health, Safety (EHS) Risk Assessment Collaboration & Coaching Grant Proposal & Scientific Writing Programming & Information Technology International Mobility
Thesis Title: Unravelling the active sites in metal cluster based oxidation catalysts.
Supervisors: Prof. dr. Peter Lievens, Dr. Didier Grandjean
Opponents: Prof. Ib Chorkendorff (DTU), Prof. Christophe Detavernier (Ugent), Dr. Deepak Pant (VITO), Dr. Olga Safanova (PSI), Prof. Margriet Van Bael, Prof. Johan Hofkens, Prof. Bart Goderis (KUL) -
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Activities and Societies: • MITACS Globalink Ambassador 2013 • Human Values Quarter 2013 • All India Gennext Leadership Contest Finalist 2012 (Ramakrishna Mission) • Assistant Manager (Volunteers) Common Wealth Games-Delhi 2010 • Actor/Orator Aawaaz-The Dramatics Club • Amity Class Representative • Volunteer Agra Bhakt Jan Ramleela Samiti and Jaipur House Welfare Society
Major: Materials and Devices, Minor: Nanochemistry
Ehrenamt
Veröffentlichungen
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Gold Electrocatalysis: Frontispiece Cover Page (Small 27/2021)
Wiley-Small
In article number 2004541, Anupam Yadav, Didier Grandjean, Peter Lievens, and co-workers uncover the origin of the catalytic activity of 3 nm gold clusters by thorough experimental and computational characterization of their properties. Faceted geometries demonstrate significantly enhanced methanol electro-oxidation activity because of exposed undercoordinated gold atoms on their surface. Vertices and edges are the most active sites because of their favorable CO and OH adsorption energies.
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Enhanced Methanol Electro‐Oxidation Activity of Nanoclustered Gold
Wiley-Small
Size‐selected 3 nm gas‐phase Au clusters dispersed by cluster beam deposition (CBD) on a conducting fluorine‐doped tin oxide template show strong enhancement in mass activity for the methanol electro‐oxidation (MEO) reaction compared to previously reported nanostructured gold electrodes. Density functional theory‐based modeling on the corresponding Au clusters guided by experiments attributes this high MEO activity to the high density of exposed under‐coordinated Au atoms at their faceted…
Size‐selected 3 nm gas‐phase Au clusters dispersed by cluster beam deposition (CBD) on a conducting fluorine‐doped tin oxide template show strong enhancement in mass activity for the methanol electro‐oxidation (MEO) reaction compared to previously reported nanostructured gold electrodes. Density functional theory‐based modeling on the corresponding Au clusters guided by experiments attributes this high MEO activity to the high density of exposed under‐coordinated Au atoms at their faceted surface. In the description of the activity trends, vertices and edges are the most active sites due to their favorable CO and OH adsorption energies. The faceted structures occurring in this size range, partly preserved upon deposition, may also prevent destructive restructuring during the oxidation‐reduction cycle. These results highlight the benefits of using CBD in fine‐tuning material properties on the nanoscale and designing high‐performance fuel cell electrodes with less material usage.
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Titanium Nitride Nanodonuts Synthesized from Natural Ilmenite Ore as a Novel and Efficient Thermoplasmonic Material
Nanomaterials Basel
Nanostructures of titanium nitride (TiN) have recently been considered as a new class of
plasmonic materials that have been utilized in many solar energy applications. This work presents
the synthesis of a novel nanostructure of TiN that has a nanodonut shape from natural ilmenite ore
using a low-cost and bulk method. The TiN nanodonuts exhibit strong and spectrally broad localized
surface plasmon resonance absorption in the visible region centered at 560 nm, which is well
suited…Nanostructures of titanium nitride (TiN) have recently been considered as a new class of
plasmonic materials that have been utilized in many solar energy applications. This work presents
the synthesis of a novel nanostructure of TiN that has a nanodonut shape from natural ilmenite ore
using a low-cost and bulk method. The TiN nanodonuts exhibit strong and spectrally broad localized
surface plasmon resonance absorption in the visible region centered at 560 nm, which is well
suited for thermoplasmonic applications as a nanoscale heat source. The heat generation is investigated by water evaporation experiments under simulated solar light, demonstrating excellent solar light harvesting performance of the nanodonut structure.Andere Autor:innenVeröffentlichung anzeigen -
Platinum-nickel bimetallic nanoclusters ensemble-on-polyaniline nanofilm for enhanced electrocatalytic oxidation of dopamine
Royal Society of Chemistry: Nanoscale
We report a new approach to design flexible functional material platforms based on electropolymerized polyaniline (PANI) polymer nanofilms modified with bimetallic nanoclusters (NCs) for efficient electro-oxidation of small organic molecules. Composition defined ligand free Pt0.75Ni0.25 NCs were synthesized in gas phase using the Cluster Beam Deposition (CBD) technology and characterized using RTOF, HAADF-STEM, XAFS and XPS. NCs were then directly deposited on PANI coated templates to construct…
We report a new approach to design flexible functional material platforms based on electropolymerized polyaniline (PANI) polymer nanofilms modified with bimetallic nanoclusters (NCs) for efficient electro-oxidation of small organic molecules. Composition defined ligand free Pt0.75Ni0.25 NCs were synthesized in gas phase using the Cluster Beam Deposition (CBD) technology and characterized using RTOF, HAADF-STEM, XAFS and XPS. NCs were then directly deposited on PANI coated templates to construct eletrodes. Dopamine (DP) molecule was used as representative organic analyte and the influence of NCs-PANI hybrid’s atomistic structure on the electrochemical and electrocatalytic performance was investigated. As prepared, nearly monodispersed, Pt0.75Ni0.25 NCs of ca. 2 nm diameter featuring a PtOx surface combined with a shallow platelet like Ni-O(OH) phase formed a densely packed active surface on PANI at ultralow metal coverages. Electrochemical measurements (EIS and CV) show a 2.5 times decrease in charge transfer resistance and a remarkable 6-fold increase at lower potential in the mass activity for Pt0.75Ni0.25 NCs in comparison to their pure Pt counterparts. The enhanced electrochemical performance of the Pt0.75Ni0.25 NCs hybrid interface is ascribed to the formation of mixed Pt metal and Ni-O(OH) phases at the surface of the alloyed PtNi cores of the bimetallic NCs under electrochemical conditions combined with an efficient charge conduction pathway between NCs.
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Surface-Modified Titanium Dioxide Nanofibers with Gold Nanoparticles for Enhanced Photoelectrochemical Water Splitting
Catalysts (MDPI)
High-stability, high-efficiency, and low-cost solar photoelectrochemical (PEC) water splitting has great potential for hydrogen-energy applications. Here, we report on gold/titanium dioxide (Au/TiO2) nanofiber structures grown directly on a conductive indium tin oxide substrate, and used as photoelectrodes in PEC cells for hydrogen generation. The titanium dioxide nanofibers (TiO2 NFs) are synthesized using electrospinning, and are surface-modified by the deposition of gold nanoparticles (Au…
High-stability, high-efficiency, and low-cost solar photoelectrochemical (PEC) water splitting has great potential for hydrogen-energy applications. Here, we report on gold/titanium dioxide (Au/TiO2) nanofiber structures grown directly on a conductive indium tin oxide substrate, and used as photoelectrodes in PEC cells for hydrogen generation. The titanium dioxide nanofibers (TiO2 NFs) are synthesized using electrospinning, and are surface-modified by the deposition of gold nanoparticles (Au NPs) using a simple photoreduction method. The structure and morphology of the materials were characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The surface plasmon resonance (SPR) of the Au NPs was investigated by ultraviolet-visible (UV-Vis) diffuse reflectance spectroscopy. The PEC properties of the as-prepared photoelectrodes were measured. The obtained photoconversion efficiency of 0.52% under simulated-sunlight illumination by a 150 W xenon lamp of the Au/TiO2 NFs structure with 15 min UV irradiation for Au NP deposition was the highest value from comparable structures. Working photoelectrode stability was tested, and the mechanism of the enhanced PEC performance is discussed.
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Composition-Tuned Pt-Skinned PtNi Bimetallic Clusters as Highly Efficient Methanol Dehydrogenation Catalysts
American Chemical Society: Chemistry of Materials
Platinum is the most active anode and cathode catalyst in next-generation fuel cells using methanol as liquid source of hydrogen. Its catalytic activity can be significantly improved by alloying with 3d metals, although a precise tuning of its surface architecture is still required. Herein, we report the design of a highly active low-temperature (below 0 °C) methanol dehydrogenation anode catalyst with reduced CO poisoning based on ultralow amount of precisely defined PtxNi1–x (x = 0 to 1)…
Platinum is the most active anode and cathode catalyst in next-generation fuel cells using methanol as liquid source of hydrogen. Its catalytic activity can be significantly improved by alloying with 3d metals, although a precise tuning of its surface architecture is still required. Herein, we report the design of a highly active low-temperature (below 0 °C) methanol dehydrogenation anode catalyst with reduced CO poisoning based on ultralow amount of precisely defined PtxNi1–x (x = 0 to 1) bimetallic clusters (BCs) deposited on inert flat oxides by cluster beam deposition. These BCs feature clear composition-dependent atomic arrangements and electronic structures stemming from their nucleation mechanism, which are responsible for a volcano-type activity trend peaking at the Pt0.7Ni0.3 composition. Our calculations reveal that at this composition, a cluster skin of Pt atoms with d-band centers downshifted by subsurface Ni atoms weakens the CO interaction that in turn triggers a significant increase in the methanol dehydrogenation activity.
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Highly Active Oxygen Evolution Reaction Model Electrode based on supported Gas-Phase NiFe Clusters
Catalysis Today
Under alkaline conditions mixed NiFe oxides/oxyhydroxides are among the most active catalysts for the oxygen evolution reaction (OER). Here we investigate Ni0.5Fe0.5 clusters as a well-defined model highly active electrocatalyst system for the OER. The electrodes were prepared using gas-phase deposition of mixed Ni0.5Fe0.5 metallic clusters produced by cluster beam deposition (CBD), a technique offering precise control of composition and loading. Highly dispersed Ni0.5Fe0.5 clusters were…
Under alkaline conditions mixed NiFe oxides/oxyhydroxides are among the most active catalysts for the oxygen evolution reaction (OER). Here we investigate Ni0.5Fe0.5 clusters as a well-defined model highly active electrocatalyst system for the OER. The electrodes were prepared using gas-phase deposition of mixed Ni0.5Fe0.5 metallic clusters produced by cluster beam deposition (CBD), a technique offering precise control of composition and loading. Highly dispersed Ni0.5Fe0.5 clusters were deposited at 1 equivalent monolayer and used as OER catalyst in 1 M KOH. The low loading allows assessment of the intrinsic catalytic activity and their extensive structural characterization by XAFS and XPS spectroscopies. Ni0.5Fe0.5 clusters demonstrate high stability as there is no apparent potential increase after a 12 h constant current density anodization test. After electrochemical aging, the lowest overpotential was achieved and amounts to 372 mV at 10 mA cm−2. The Tafel slope reaches 37 mV dec−1. The measured electrochemical activity is also compared with other systems. After OER reaction in KOH the cluster surface is enriched in NiOOH, while concomitant Fe depletion from the catalyst surface is observed. These findings help to shed light on the formed active phase at the nanoscale.
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Unravelling the nucleation mechanism of bimetallic nanoparticles with composition-tunable core–shell arrangement
Royal Society of Chemistry (Nanoscale)
The structure and atomic ordering of Au–Ag nanoparticles grown in the gas phase are determined by a combination of HAADF-STEM, XPS and Refl-XAFS techniques as a function of composition. It is shown consistently from all the techniques that an inversion of chemical ordering takes place by going from Au-rich to Ag-rich compositions, with the minority element always occupying the nanoparticle core, and the majority element enriching the shell. With the aid of DFT calculations, this…
The structure and atomic ordering of Au–Ag nanoparticles grown in the gas phase are determined by a combination of HAADF-STEM, XPS and Refl-XAFS techniques as a function of composition. It is shown consistently from all the techniques that an inversion of chemical ordering takes place by going from Au-rich to Ag-rich compositions, with the minority element always occupying the nanoparticle core, and the majority element enriching the shell. With the aid of DFT calculations, this composition-tunable chemical arrangement is rationalized in terms of a four-step growth process in which the very first stage of cluster nucleation plays a crucial role. The four-step growth mechanism is based on mechanisms of a general character, likely to be applicable to a variety of binary systems besides Au–Ag
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TiO2 Films Modified with Au Nanoclusters as Self-Cleaning Surfaces under Visible Light
Nanomaterials MDPI
In this study, we applied cluster beam deposition (CBD) as a new approach for fabricating efficient plasmon-based photocatalytic materials. Au nanoclusters (AuNCs) produced in the gas phase were deposited on TiO2 P25-coated silicon wafers with coverage ranging from 2 to 8 atomic monolayer (ML) equivalents. Scanning Electron Microscopy (SEM) images of the AuNCs modified TiO2 P25 films show that the surface is uniformly covered by the AuNCs that remain isolated at low coverage (2 ML, 4 ML) and…
In this study, we applied cluster beam deposition (CBD) as a new approach for fabricating efficient plasmon-based photocatalytic materials. Au nanoclusters (AuNCs) produced in the gas phase were deposited on TiO2 P25-coated silicon wafers with coverage ranging from 2 to 8 atomic monolayer (ML) equivalents. Scanning Electron Microscopy (SEM) images of the AuNCs modified TiO2 P25 films show that the surface is uniformly covered by the AuNCs that remain isolated at low coverage (2 ML, 4 ML) and aggregate at higher coverage (8 ML). A clear relationship between AuNCs coverage and photocatalytic activity towards stearic acid photo-oxidation was measured, both under ultraviolet and green light illumination. TiO2 P25 covered with 4 ML AuNCs showed the best stearic acid photo-oxidation performance under green light illumination (Formal Quantum Efficiency 1.6 × 10−6 over a period of 93 h). These results demonstrate the large potential of gas-phase AuNCs beam deposition technology for the fabrication of visible light active plasmonic photocatalysts.
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Role of AuxPt1–x Clusters in the Enhancement of the Electrochemical Activity of ZnO Nanorod Electrodes
American Chemical Society (JPCC)
This study quantitatively elucidates the role of metal clusters in the electrochemical activation of metal-oxide nanostructured electrodes. Through the deposition of nearly monodisperse AuxPt1–x (x = 0, 0.5, 1) clusters, smaller than 3 nm, on the ZnO nanorod (NR) electrode surface, a controlled enhancement of charge transfer and activation of electrocatalytic processes was achieved. The interfacial electrical states of the hybrid electrodes were probed by electrochemical impedance spectroscopy…
This study quantitatively elucidates the role of metal clusters in the electrochemical activation of metal-oxide nanostructured electrodes. Through the deposition of nearly monodisperse AuxPt1–x (x = 0, 0.5, 1) clusters, smaller than 3 nm, on the ZnO nanorod (NR) electrode surface, a controlled enhancement of charge transfer and activation of electrocatalytic processes was achieved. The interfacial electrical states of the hybrid electrodes were probed by electrochemical impedance spectroscopy (EIS). Analysis of the charge-transfer resistance and interface capacitance, estimated by modeling EIS curves in different bias regimes, indicated the presence of a large amount of active donor states (∼1020 cm–3) at the surface of the ZnO NRs. Decoration of the ZnO NRs with AuxPt1–x clusters strongly increased the charge-transfer process at the cluster–ZnO/electrolyte interface. This induced a more effective depletion of the electron charge available in the donor states of the ZnO NRs, leading to the formation of a positively charged layer at the interface between ZnO and the clusters. These two effects, intrinsically linked with the alignment between the electronic states of the AuxPt1–x clusters and ZnO, strongly enhance the interface reactivity of the ZnO NR electrodes toward the redox reaction of potassium ferricyanide. This is particularly relevant for understanding and improving the performance of electrochemical biosensors
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Auszeichnungen/Preise
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Editor's Choice Badge
Royal Society of Chemistry Journal Nanoscale
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Oral Presentation at European Physical Society Condensed Matter Division
CMD2020GEFES, Virtual Conference
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Oral Presentation Award at 14th European Congress on Catalysis
EUROPACAT 2019, Germany
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Presenter’s Grant Award
Gordon Research Seminars, Switzerland
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MIT-KU Leuven Mobility Award
KU Leuven, Belgium (YouReCa Seed Fund Initiative)
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Oral Presentation Award at Material Research Society, USA
MRS Meeting, USA
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European Commission Outreach Micro Grant
Marie Curie Association
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Marie Curie Fellowship (European Commission).
European Commission
Professionally trained as researcher in Marie Curie ITN Project 2015-2018
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Gold Medal ( Masters and Bachelors Nanotechnology)
Amity University
Gold Medal Awarded for Consecutively Topping Amity University Rankings, 2009-14 (India).
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KAUST Research Fellowship
KAUST, Saudi Arabia
I was selected and awarded full fellowship to work at KAUST, Saudi Arabia.
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MITACS Globalink Fellowship Award
MITACS, Canada
MITACS selected me and awarded full fellowship to pursue research at McGill in Canada owing to my academic merit and all round excellence.
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Indian Academy of Science Summer Research Fellowship
Indian Academy of Science
Qualified IAS Summer Research Fellowship Program
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Medal for Merit (Batch 2007)
St. Peters College, Agra
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Merit Scholarships
Amity University, India
Funded by Amity University for the years 2009-2014 for consecutively topping the university rankings and maintaining excellent academic record
Sprachen
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English
Muttersprache oder zweisprachig
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Hindi
Muttersprache oder zweisprachig
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German
Grundkenntnisse
Organisationen
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Material Research Society
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Marie Curie Fellows Association
Member Finance Affairs and Strategy Group
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Belgium Physics Society
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–Heute
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Jetzt anmelden und ansehenWeitere Aktivitäten von Anupam Yadav, ir. Dr.
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On 16 December 2024, we had the honour of welcoming Minister Tobias Goldschmidt from the Ministry for Energy System Transformation, Climate…
On 16 December 2024, we had the honour of welcoming Minister Tobias Goldschmidt from the Ministry for Energy System Transformation, Climate…
Beliebt bei Anupam Yadav, ir. Dr.
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Stay tuned for the 12 exciting series from Dunia, this is just (1/12) of what is to come in the following days! 🐉
Stay tuned for the 12 exciting series from Dunia, this is just (1/12) of what is to come in the following days! 🐉
Beliebt bei Anupam Yadav, ir. Dr.
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So long, and thanks for all the coffee… After about 10.5 years leading the Catalysis Research Laboratory (CaRLa) in Heidelberg, it's time to move on.…
So long, and thanks for all the coffee… After about 10.5 years leading the Catalysis Research Laboratory (CaRLa) in Heidelberg, it's time to move on.…
Beliebt bei Anupam Yadav, ir. Dr.
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This is really about an important innovation by Vishal Mehta Director, Sustainable Materials Program at STEER World This is a new paradigm in…
This is really about an important innovation by Vishal Mehta Director, Sustainable Materials Program at STEER World This is a new paradigm in…
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I think anyone saying #climatetech is dead has not understood the enormity of the problem and thus also its opportunity. Climate tech is about…
I think anyone saying #climatetech is dead has not understood the enormity of the problem and thus also its opportunity. Climate tech is about…
Beliebt bei Anupam Yadav, ir. Dr.
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🎄 We thank you for a very successful 2024 ✨ Thanks to our customers, friends, supporters, collaborators, suppliers and partners we were able to…
🎄 We thank you for a very successful 2024 ✨ Thanks to our customers, friends, supporters, collaborators, suppliers and partners we were able to…
Beliebt bei Anupam Yadav, ir. Dr.
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Doing some emergency surgery greasing the sample stages before the Christmas run (without disassembly which would’ve required recalibrating). One of…
Doing some emergency surgery greasing the sample stages before the Christmas run (without disassembly which would’ve required recalibrating). One of…
Beliebt bei Anupam Yadav, ir. Dr.
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🎄 𝗦𝗘𝗔𝗦𝗢𝗡’𝗦 𝗚𝗥𝗘𝗘𝗧𝗜𝗡𝗚𝗦 𝗳𝗿𝗼𝗺 𝘆𝗼𝘂𝗿 Heraeus Precious Metals Trading Team ✨ 🎁 As we approach the end of the year, we would like…
🎄 𝗦𝗘𝗔𝗦𝗢𝗡’𝗦 𝗚𝗥𝗘𝗘𝗧𝗜𝗡𝗚𝗦 𝗳𝗿𝗼𝗺 𝘆𝗼𝘂𝗿 Heraeus Precious Metals Trading Team ✨ 🎁 As we approach the end of the year, we would like…
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Coherent Corp. laser portfolio has (almost) every laser to meet your requirement … THE one-stop-shop for laser solutions 👍👍👍 And the team at…
Coherent Corp. laser portfolio has (almost) every laser to meet your requirement … THE one-stop-shop for laser solutions 👍👍👍 And the team at…
Beliebt bei Anupam Yadav, ir. Dr.