Joshua Pearce

Joshua Pearce

London, Ontario, Canada
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My work and research are motivated by a need to create a just sustainable society. My…

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Education

  • Penn State University Graphic

    Penn State University

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    Activities and Societies: Green Destiny Council, Environmental Stewardship Initiative, Green Design Team

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Publications

  • Controlling optical absorption in metamaterial absorbers for plasmonic solar cells

    SPIE

    Metals in the plasmonic metamaterial absorbers for photovoltaics constitute undesired resistive heating. However, tailoring the geometric skin depth of metals can minimize resistive losses while maximizing the optical absorbance in the active semiconductors of the photovoltaic device. Considering experimental permittivity data for InxGa1-xN, absorbance in the semiconductor layers of the photovoltaic device can reach above 90%. The results here also provides guidance to compare the performance…

    Metals in the plasmonic metamaterial absorbers for photovoltaics constitute undesired resistive heating. However, tailoring the geometric skin depth of metals can minimize resistive losses while maximizing the optical absorbance in the active semiconductors of the photovoltaic device. Considering experimental permittivity data for InxGa1-xN, absorbance in the semiconductor layers of the photovoltaic device can reach above 90%. The results here also provides guidance to compare the performance of different semiconductor materials. This skin depth engineering approach can also be applied to other optoelectronic devices, where optimizing the device performance demands minimizing resistive losses and power consumption, such as photodetectors, laser diodes, and light emitting diodes.

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  • Impact of Snow and Ground Interference on Photovoltaic Electric System Performance

    IEEE Journal of Photovoltaics

    Assessing snow-related energy losses is necessary for accurate predictions of photovoltaic (PV) performance. A PV test platform with seven portrait-oriented modules placed at four tilt angles (0°, 15°, 30°, and 45°) was installed in Calumet, MI, USA, to measure the energy loss in this snowy climate. As a best-case snow-shedding configuration, similar to a carport or a plain sloped roof, three of the test modules were rack-mounted high enough to prevent surface interference. The opposite effect…

    Assessing snow-related energy losses is necessary for accurate predictions of photovoltaic (PV) performance. A PV test platform with seven portrait-oriented modules placed at four tilt angles (0°, 15°, 30°, and 45°) was installed in Calumet, MI, USA, to measure the energy loss in this snowy climate. As a best-case snow-shedding configuration, similar to a carport or a plain sloped roof, three of the test modules were rack-mounted high enough to prevent surface interference. The opposite effect of maximum surface interference, similar to many commercial rooftops, was introduced by mounting the other four modules at grade. The platform was monitored for one year beginning in October 2013. The snowfall that winter was normal: 5.3 m (209 in). Snow-related annual energy losses ranged from 5% to 12% for the elevated unobstructed modules, with the steepest tilt angle experiencing the least amount of energy loss. For the obstructed modules, there was little angular dependence on lost energy, with annual energy losses ranging from 29% to 34%. This relative three- to sixfold increase in lost energy when ground interference is present points out the importance of minimizing obstructions and prompt snow clearing for portrait-oriented PV. Depending on the breadth of an inverter's operating voltage limits, these results suggest that landscape-oriented array layouts and perhaps snow-clearing mechanisms may be advantageous in snowy climates.

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  • Total US cost evaluation of low-weight tension-based photovoltaic flat-roof mounted racking

    Solar Energy

    The economics in the U.S. of solar photovoltaic (PV) systems is changing rapidly as the cost per unit power of PV modules has dropped quickly. These costs reductions have two important results: marked decrease in levelized cost of electricity (LCOE) into ranges competitive or better than traditional electricity-generation technologies and the economic role of racking has been gaining prominence relative to that of modules. As the relative importance of costs of PV racking has been marginal…

    The economics in the U.S. of solar photovoltaic (PV) systems is changing rapidly as the cost per unit power of PV modules has dropped quickly. These costs reductions have two important results: marked decrease in levelized cost of electricity (LCOE) into ranges competitive or better than traditional electricity-generation technologies and the economic role of racking has been gaining prominence relative to that of modules. As the relative importance of costs of PV racking has been marginal historically, there has been relatively little progress on reducing the materials and costs associated with it, which has caused racking to contribute to a significant portion of costs of entire PV systems. In order to overcome this challenge this study investigates a novel low-weight PV racking system for commercial rooftops based on crossed cables (X-wires) and compares it to racking systems already available on the market on capital costs, labor costs for installation, and technical specifications such as adaptability and power packing factor. The results of over 80% cost reduction and 33% increase in power density are presented and conclusions are drawn about the potential for tension-based racking systems to further reduce total PV systems costs on commercial flat roof tops resulting in LCOE savings of $0.01–$0.02/kW h.

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  • Limitations of ultra-thin transparent conducting oxides for integration into plasmonic-enhanced thin-film solar photovoltaic devices

    Materials for Renewable and Sustainable Energy

    This study investigates ultra-thin transparent conducting oxides (TCO) of indium tin oxide (ITO), aluminum-doped zinc oxide (AZO) and zinc oxide (ZnO) to determine their viability as candidate materials for use in plasmonic-enhanced thin-film amorphous silicon solar photovoltaic (PV) devices. First a sensitivity analysis of the optical absorption for the intrinsic layer of a nano-disk patterned thin-film amorphous silicon-based solar cell as a function of TCO thickness (10–50 nm) was performed…

    This study investigates ultra-thin transparent conducting oxides (TCO) of indium tin oxide (ITO), aluminum-doped zinc oxide (AZO) and zinc oxide (ZnO) to determine their viability as candidate materials for use in plasmonic-enhanced thin-film amorphous silicon solar photovoltaic (PV) devices. First a sensitivity analysis of the optical absorption for the intrinsic layer of a nano-disk patterned thin-film amorphous silicon-based solar cell as a function of TCO thickness (10–50 nm) was performed by simulation. These simulation results were then used to guide the design of the experimental work which investigated both optical and electrical properties of ultra-thin (10 nm on average) films simultaneously deposited on both glass and silicon substrates using conventional rf sputtering. The effects of deposition and post-processing parameters on material properties of ITO, AZO and ZnO ultra-thin TCOs were probed and the suitability of TCOs for integration into plasmonic-enhanced thin-film solar PV devices was assessed. The results show that ultra-thin TCOs present a number of challenges for use as thin top contacts on plasmonic-enhanced PV devices: (1) optical and electrical parameters differ greatly from those of thicker (bulk) films deposited under the same conditions, (2) the films are delicate due to their thickness, requiring very long annealing times to prevent cracking, and (3) reactive gases require careful monitoring to maintain stoichiometry. The results presented here found a trade-off between conductivity and transparency of the deposited films. Although the sub 50 nm TCO films investigated exhibited desirable optical properties (transmittance greater than 80 %), their resistivity was too high to be considered as materials for the top contact of conventional PV devices. Future work is necessary to improve thin TCO properties, or alternative materials, and geometries are needed in plasmonic-based amorphous silicon solar cells.

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  • Feeding Everyone No Matter What: Managing Food Security After Global Catastrophe

    Academic Press

    Feeding Everyone No Matter What presents a scientific approach to the practicalities of planning for long-term interruption to food production.

    The primary historic solution developed over the last several decades is increased food storage. However, storing up enough food to feed everyone would take a significant amount of time and would increase the price of food, killing additional people due to inadequate global access to affordable food. Humanity is far from doomed, however, in these…

    Feeding Everyone No Matter What presents a scientific approach to the practicalities of planning for long-term interruption to food production.

    The primary historic solution developed over the last several decades is increased food storage. However, storing up enough food to feed everyone would take a significant amount of time and would increase the price of food, killing additional people due to inadequate global access to affordable food. Humanity is far from doomed, however, in these situations - there are solutions.

    This book provides an order of magnitude technical analysis comparing caloric requirements of all humans for five years with conversion of existing vegetation and fossil fuels to edible food. It presents mechanisms for global-scale conversion including: natural gas-digesting bacteria, extracting food from leaves, and conversion of fiber by enzymes, mushroom or bacteria growth, or a two-step process involving partial decomposition of fiber by fungi and/or bacteria and feeding them to animals such as beetles, ruminants (cows, deer, etc), rats and chickens. It includes an analysis to determine the ramp rates for each option and the results show that careful planning and global cooperation could ensure the bulk of humanity and biodiversity could be maintained in even in the most extreme circumstances.

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  • Design of Multijunction Photovoltaic Cells Optimized for Varied Atmospheric Conditions

    International Journal of Photoenergy, Hindawi

    Band gap engineering provides an opportunity to not only provide higher overall conversion efficiencies of the reference AM1.5 spectra but also customize PV device design for specific geographic locations and microenvironments based on atmospheric conditions characteristic to that particular location. Indium gallium nitride and other PV materials offer the opportunity for
    limited bandgap engineering to match spectra. The effects of atmospheric conditions such as aerosols, cloud cover, water…

    Band gap engineering provides an opportunity to not only provide higher overall conversion efficiencies of the reference AM1.5 spectra but also customize PV device design for specific geographic locations and microenvironments based on atmospheric conditions characteristic to that particular location. Indium gallium nitride and other PV materials offer the opportunity for
    limited bandgap engineering to match spectra. The effects of atmospheric conditions such as aerosols, cloud cover, water vapor, and air mass have been shown to cause variations in spectral radiance that alters PV system performance due to both overrating and underrating. Designing PV devices optimized for spectral radiance of a particular region can result in improved PV system
    performance. This paper presents a new method for designing geographically optimized PV cells with using a numerical model for bandgap optimization. The geographic microclimate spectrally resolved solar flux for twelve representative atmospheric conditions for the incident radiation angle (zenith angle) of 48.1∘ and fixed array angle of 40∘ is used to iteratively optimize the band gap for
    tandem, triple, and quad-layer of InGaN-based multijunction cells.The results of this method are illustrated for the case study of solar farms in the New York region and discussed.

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  • Mobile Open-Source Solar-Powered 3-D Printers for Distributed Manufacturing in Off-Grid Communities

    Challenges in Sustainability

    Manufacturing in areas of the developing world that lack electricity severely restricts the technical sophistication of what is produced. More than a billion people with no access to electricity still have access to some imported higher-technologies; however, these often lack customization and often appropriateness for their community. Open source appropriate technology (OSAT) can over-come this challenge, but one of the key impediments to the more rapid development and distribution of OSAT is…

    Manufacturing in areas of the developing world that lack electricity severely restricts the technical sophistication of what is produced. More than a billion people with no access to electricity still have access to some imported higher-technologies; however, these often lack customization and often appropriateness for their community. Open source appropriate technology (OSAT) can over-come this challenge, but one of the key impediments to the more rapid development and distribution of OSAT is the lack of means of production beyond a specific technical complexity. This study designs and demonstrates the technical viability of two open-source mobile digital manufacturing facilities powered with solar photovoltaics, and capable of printing customizable OSAT in any community with access to sunlight. The first, designed for community use, such as in schools or maker-spaces, is semi-mobile and capable of nearly continuous 3-D printing using RepRap technology, while also powering multiple computers. The second design, which can be completely packed into a standard suitcase, allows for specialist travel from community to community to provide the ability to custom manufacture OSAT as needed, anywhere. these designs not only bring the possibility of complex manufacturing and replacement part fabrication to isolated rural communities lacking access to the electric grid, but they also offer the opportunity to leap-frog the entire conventional manufacturing supply chain, while radically reducing both the cost and the environmental impact of products for developing communities.

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  • Open-Source Syringe Pump Library

    PLOS One

    This article explores a new open-source method for developing and manufacturing high-quality scientific equipment suitable for use in virtually any laboratory. A syringe pump was designed using freely available open-source computer aided design (CAD) software and manufactured using an open-source RepRap 3-D printer and readily available parts. The design, bill of materials and assembly instructions are globally available to anyone wishing to use them. Details are provided covering the use of…

    This article explores a new open-source method for developing and manufacturing high-quality scientific equipment suitable for use in virtually any laboratory. A syringe pump was designed using freely available open-source computer aided design (CAD) software and manufactured using an open-source RepRap 3-D printer and readily available parts. The design, bill of materials and assembly instructions are globally available to anyone wishing to use them. Details are provided covering the use of the CAD software and the RepRap 3-D printer. The use of an open-source Raspberry Pi computer as a wireless control device is also illustrated. Performance of the syringe pump was assessed and the methods used for assessment are detailed. The cost of the entire system, including the controller and web-based control interface, is on the order of 5% or less than one would expect to pay for a commercial syringe pump having similar performance. The design should suit the needs of a given research activity requiring a syringe pump including carefully controlled dosing of reagents, pharmaceuticals, and delivery of viscous 3-D printer media among other applications.

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  • Multi-resonant silver nano-disk patterned thin film hydrogenated amorphous silicon solar cells for Staebler-Wronski effect compensation

    Journal of Applied Physics

    We study polarization independent improved light trapping in commercial thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic cells using a three-dimensional silver array of multi-resonant nano-disk structures embedded in a silicon nitride anti-reflection coating to enhance optical absorption in the intrinsic layer (i-a-Si:H) for the visible spectrum for any polarization angle. Predicted total optical enhancement (OE) in absorption in the i-a-Si:H for AM-1.5 solar spectrum is…

    We study polarization independent improved light trapping in commercial thin film hydrogenated amorphous silicon (a-Si:H) solar photovoltaic cells using a three-dimensional silver array of multi-resonant nano-disk structures embedded in a silicon nitride anti-reflection coating to enhance optical absorption in the intrinsic layer (i-a-Si:H) for the visible spectrum for any polarization angle. Predicted total optical enhancement (OE) in absorption in the i-a-Si:H for AM-1.5 solar spectrum is 18.51% as compared to the reference, and producing a 19.65% improvement in short-circuit current density (JSC) over 11.7 mA/cm2 for a reference cell. The JSC in the nano-disk patterned solar cell (NDPSC) was found to be higher than the commercial reference structure for any incident angle. The NDPSC has a multi-resonant optical response for the visible spectrum and the associated mechanism for OE in i-a-Si:H layer is excitation of Fabry-Perot resonance facilitated by surface plasmon resonances. The detrimental Staebler-Wronski effect in a-Si:H solar cell can be minimized by the additional OE in the NDPSC and self-annealing of defect states by additional heat generation, thus likely improving the overall stabilized characteristics of a-Si:H solar cells.

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  • Exchanging Ohmic Losses in Metamaterial Absorbers with Useful Optical Absorption for Photovoltaics

    Nature Scientific Reports

    Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted…

    Using metamaterial absorbers, we have shown that metallic layers in the absorbers do not necessarily constitute undesired resistive heating problem for photovoltaics. Tailoring the geometric skin depth of metals and employing the natural bulk absorbance characteristics of the semiconductors in those absorbers can enable the exchange of undesired resistive losses with the useful optical absorbance in the active semiconductors. Thus, Ohmic loss dominated metamaterial absorbers can be converted into photovoltaic near-perfect absorbers with the advantage of harvesting the full potential of light management offered by the metamaterial absorbers. Based on experimental permittivity data for indium gallium nitride, we have shown that between 75%–95% absorbance can be achieved in the semiconductor layers of the converted metamaterial absorbers. Besides other metamaterial and plasmonic devices, our results may also apply to photodectors and other metal or semiconductor based optical devices where resistive losses and power consumption are important pertaining to the device performance.

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  • Optimizing limited solar roof access by exergy analysis of solar thermal, photovoltaic, and hybrid photovoltaic thermal systems

    Applied Energy

    An exergy analysis was performed to compare a conventional (1) two panel photovoltaic solar thermal hybrid (PVT x2) system, (2) side by side photovoltaic and thermal (PV + T) system, (3) two module photovoltaic (PV) system and (4) a two panel solar thermal (T x2) system with identical absorber areas to determine the superior technical solar energy systems for applications with a limited roof area. Three locations, Detroit, Denver and Phoenix, were simulated due to their differences in average…

    An exergy analysis was performed to compare a conventional (1) two panel photovoltaic solar thermal hybrid (PVT x2) system, (2) side by side photovoltaic and thermal (PV + T) system, (3) two module photovoltaic (PV) system and (4) a two panel solar thermal (T x2) system with identical absorber areas to determine the superior technical solar energy systems for applications with a limited roof area. Three locations, Detroit, Denver and Phoenix, were simulated due to their differences in average monthly temperature and solar flux. The exergy analysis results show that PVT systems outperform the PV + T systems by 69% for all the locations, produce between 6.5% and 8.4% more exergy when matched against the purely PV systems and created 4 times as much exergy as the pure solar thermal system. The results clearly show that PVT systems, which are able to utilize all of the thermal and electrical energy generated, are superior in exergy performance to either PV + T or PV only systems. These results are discussed and future work is outlined to further geographically optimize PVT systems.

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  • Life Cycle Analysis of Distributed Recycling of Post-consumer High Density Polyethylene for 3-D Printing Filament

    Journal of Cleaner Production

    The growth of desktop 3-D printers is driving an interest in recycled 3-D printer filament to reduce costs of distributed production. Life cycle analysis studies were performed on the recycling of high density polyethylene into filament suitable for additive layer manufacturing with 3-D printers. The conventional centralized recycling system for high population density and low population density rural locations was compared to the proposed in home, distributed recycling system. This system…

    The growth of desktop 3-D printers is driving an interest in recycled 3-D printer filament to reduce costs of distributed production. Life cycle analysis studies were performed on the recycling of high density polyethylene into filament suitable for additive layer manufacturing with 3-D printers. The conventional centralized recycling system for high population density and low population density rural locations was compared to the proposed in home, distributed recycling system. This system would involve shredding and then producing filament with an open-source plastic extruder from post-consumer plastics and then printing the extruded filament into usable, value-added parts and products with 3-D printers such as the open-source self replicating rapid prototyper, or RepRap. The embodied energy and carbon dioxide emissions were calculated for high density polyethylene recycling using SimaPro 7.2 and the database EcoInvent v2.0. The results showed that distributed recycling uses less embodied energy than the best-case scenario used for centralized recycling. For centralized recycling in a low-density population case study involving substantial embodied energy use for transportation and collection these savings for distributed recycling were found to extend to over 80%. If the distributed process is applied to the U.S. high density polyethylene currently recycled, more than 100 million MJ of energy could be conserved per annum along with the concomitant significant reductions in greenhouse gas emissions. It is concluded that with the open-source 3-D printing network expanding rapidly the potential for widespread adoption of in-home recycling of post-consumer plastic represents a novel path to a future of distributed manufacturing appropriate for both the developed and developing world with lower environmental impacts than the current system.

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  • Mechanical Properties of Components Fabricated with Open-Source 3-D Printers Under Realistic Environmental Conditions

    Materials and Design

    The recent development of the RepRap, an open-source self-replicating rapid prototyper, has made 3-D polymer-based printers readily available to the public at low costs (<$500). The resultant uptake of 3-D printing technology enables for the first time mass-scale distributed digital manufacturing. RepRap variants currently fabricate objects primarily from acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA), which have melting temperatures low enough to use in melt extrusion…

    The recent development of the RepRap, an open-source self-replicating rapid prototyper, has made 3-D polymer-based printers readily available to the public at low costs (<$500). The resultant uptake of 3-D printing technology enables for the first time mass-scale distributed digital manufacturing. RepRap variants currently fabricate objects primarily from acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA), which have melting temperatures low enough to use in melt extrusion outside of a dedicated facility, while high enough for prints to retain their shape at average use temperatures. In order for RepRap printed parts to be useful for engineering applications the mechanical properties of printed parts must be known. This study quantifies the basic tensile strength and elastic modulus of printed components using realistic environmental conditions for standard users of a selection of open-source 3-D printers. The results find average tensile strengths of 28.5 MPa for ABS and 56.6 MPa for PLA with average elastic moduli of 1807 MPa for ABS and 3368 MPa for PLA. It is clear from these results that parts printed from tuned, low-cost, open-source RepRap 3-D printers can be considered as mechanically functional in tensile applications as those from commercial vendors.

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  • The effects of dispatch strategy on electrical performance of amorphous silicon-based solar photovoltaic-thermal systems

    Renewable Energy

    Previous work has shown that high-temperature short-term spike thermal annealing of hydrogenated amorphous silicon (a-Si:H) photovoltaic thermal (PVT) systems results in higher electrical energy output. The relationship between temperature and performance of a-Si:H PVT is not simple as high temperatures during thermal annealing improves the immediate electrical performance following an anneal, but during the anneal it creates a marked drop in electrical performance. In addition, the power…

    Previous work has shown that high-temperature short-term spike thermal annealing of hydrogenated amorphous silicon (a-Si:H) photovoltaic thermal (PVT) systems results in higher electrical energy output. The relationship between temperature and performance of a-Si:H PVT is not simple as high temperatures during thermal annealing improves the immediate electrical performance following an anneal, but during the anneal it creates a marked drop in electrical performance. In addition, the power generation of a-Si:H PVT depends on both the environmental conditions and the Staebler–Wronski Effect kinetics. In order to improve the performance of a-Si:H PVT systems further, this paper reports on the effect of various dispatch strategies on system electrical performance. Utilizing experimental results from thermal annealing, an annealing model simulation for a-Si:H-based PVT was developed and applied to different cities in the U.S. to investigate potential geographic effects on the dispatch optimization of the overall electrical PVT systems performance and annual electrical yield. The results showed that spike thermal annealing once per day maximized the improved electrical energy generation.

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  • A Low-Cost Open-Source Metal 3-D Printer

    IEEE Access

    This paper reports on the development of a < $2000 open-source metal 3-D printer. The metal 3-D printer is controlled with an open-source micro-controller and is a combination of a low-cost commercial gas-metal arc welder and a derivative of the Rostock, a deltabot RepRap. A preliminary technical analysis of the properties of the 3-D printer and the resultant steel products are performed. The results of printing customized functional metal parts are discussed and conclusions are drawn about…

    This paper reports on the development of a < $2000 open-source metal 3-D printer. The metal 3-D printer is controlled with an open-source micro-controller and is a combination of a low-cost commercial gas-metal arc welder and a derivative of the Rostock, a deltabot RepRap. A preliminary technical analysis of the properties of the 3-D printer and the resultant steel products are performed. The results of printing customized functional metal parts are discussed and conclusions are drawn about the potential for the technology and the future work necessary for the mass distribution of this technology.

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  • The Viability of Nanotechnology-based InGaN Solar Photovoltaic Devices for Sustainable Energy Generation

    MRS Online Proceedings Library, 1558, mrss13-1558-z03-06

    The unrestrained combustion of fossil fuels has resulted in vast pollution at the local scale throughout the world, while contributing to global warming at a rate that seriously threatens the stability of many of the world's ecosystems. Solar photovoltaic (PV) technology is a clean, sustainable and renewable energy conversion technology that can help meet the energy demands of the world’s growing population. Although PV technology is mature with commercial modules obtaining over 20% conversion…

    The unrestrained combustion of fossil fuels has resulted in vast pollution at the local scale throughout the world, while contributing to global warming at a rate that seriously threatens the stability of many of the world's ecosystems. Solar photovoltaic (PV) technology is a clean, sustainable and renewable energy conversion technology that can help meet the energy demands of the world’s growing population. Although PV technology is mature with commercial modules obtaining over 20% conversion efficiency there remains considerable opportunities to improve performance. The nearly global access to the solar resource coupled to nanotechnology innovation-driven decreases in the costs of PV, provides a path for a renewable energy source to significantly reduce the adverse anthropogenic impacts of energy use by replacing fossil fuels. This study explores several approaches to improving indium gallium nitride-based PV efficiency with nanotechnology: optical enhancement, microstructural optimization for electronic material quality and increasing the spectral response via bandgap engineering. The results showing multibandgap engineering with InGaN and impediments to widespread deployment and commercialization are discussed including technical viability, intellectual property laws and licensing, material resource scarcities, and economics. Future work is outlined and conclusions are drawn to overcome these limitations and improve PV device performance using methods that can scale to the necessary terawatt level.

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  • Environmental Life Cycle Analysis of Distributed 3-D Printing and Conventional Manufacturing of Polymer Products

    ACS Sustainable Chemistry & Engineering

    With the recent development of the RepRap, an open-source self-replicating rapid prototyper, low-cost three-dimensional (3D) printing is now a technically viable form of distributed manufacturing of polymer-based products. However, the aggregate environmental benefits of distributed manufacturing are not clear due to scale reductions and the potential for increases in embodied energy. To quantify the environmental impact of distributed manufacturing using 3D printers, a life cycle analysis was…

    With the recent development of the RepRap, an open-source self-replicating rapid prototyper, low-cost three-dimensional (3D) printing is now a technically viable form of distributed manufacturing of polymer-based products. However, the aggregate environmental benefits of distributed manufacturing are not clear due to scale reductions and the potential for increases in embodied energy. To quantify the environmental impact of distributed manufacturing using 3D printers, a life cycle analysis was performed on three plastic products. The embodied energy and emissions from conventional large-scale production in low-labor cost countries and shipping are compared to experimental measurements on a RepRap with and without solar photovoltaic (PV) power fabricating products with acrylonitrile butadiene styrene (ABS) and polylactic acid (PLA). The results indicate that the cumulative energy demand of manufacturing polymer products can be reduced by 41–64% (55–74% with PV) and concomitant emission reductions using distributed manufacturing with existing low-cost open-source 3D printers when using <25% fill PLA. Less pronounced positive environmental results are observed with ABS, which demands higher temperatures for the print bed and extruder. Overall, the results indicate that distributed manufacturing using open-source 3D printers has the potential to have a lower environmental impact than conventional manufacturing for a variety of products.

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  • Progress in Indium Gallium Nitride Materials for Solar Photovoltaic Energy Conversion

    Metallurgical and Materials Transactions A

    The world requires inexpensive, reliable, and sustainable energy sources. Solar photovoltaic (PV) technology, which converts sunlight directly into electricity, is an enormously promising solution to our energy challenges. This promise increases as the efficiencies are improved. One straightforward method of increasing PV device efficiency is to utilize multi-junction cells, each of which is responsible for absorbing a different range of wavelengths in the solar spectrum. Indium gallium nitride…

    The world requires inexpensive, reliable, and sustainable energy sources. Solar photovoltaic (PV) technology, which converts sunlight directly into electricity, is an enormously promising solution to our energy challenges. This promise increases as the efficiencies are improved. One straightforward method of increasing PV device efficiency is to utilize multi-junction cells, each of which is responsible for absorbing a different range of wavelengths in the solar spectrum. Indium gallium nitride (InGaN) has a variable band gap from 0.7 to 3.4 eV that covers nearly the whole solar spectrum. In addition, InGaN can be viewed as an ideal candidate PV material for both this potential band gap engineering and microstructural engineering in nanocolumns that offer optical enhancement. It is clear that InGaN is an extremely versatile potential PV material that enables several known photovoltaic device configurations and multi-junctions with theoretic efficiencies over 50 pct. This potential is driving immense scientific interest in the material system. This paper reviews the solar PV technology field and the basic properties of InGaN materials and PV devices. The challenges that remain in realizing a high-efficiency InGaN PV device are summarized along with paths for future work. Finally, conclusions are drawn about the potential for InGaN photovoltaic technology in the future.

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  • Open-Source 3D-Printable Optics Equipment

    PLOS ONE

    This paper introduces a library of open-source 3-D-printable optics components. This library operates as a flexible, low-cost public-domain tool set for developing both research and teaching optics hardware.
    - The use of parametric open-source designs using an open-source computer aided design package is described to customize the optics hardware for any application.
    - Details are provided on the use of open-source 3-D printers (additive layer manufacturing) to fabricate the primary…

    This paper introduces a library of open-source 3-D-printable optics components. This library operates as a flexible, low-cost public-domain tool set for developing both research and teaching optics hardware.
    - The use of parametric open-source designs using an open-source computer aided design package is described to customize the optics hardware for any application.
    - Details are provided on the use of open-source 3-D printers (additive layer manufacturing) to fabricate the primary mechanical components, which are then combined to construct complex optics-related devices.
    - The use of the open-source electronics prototyping platform are illustrated as control for optical experimental apparatuses.

    This study demonstrates an open-source optical library, which significantly reduces the costs associated with much optical equipment, while also enabling relatively easily adapted customizable designs. The cost reductions in general are over 97%, with some components representing only 1% of the current commercial investment for optical products of similar function.

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  • Characteristics of Self-Assembled Ultra-thin Nafion Films

    Macromolecules (accepted)

    Self-assembled Nafion films of varying thickness were generated on SiO2 terminated silicon wafer by immersion in Nafion dispersions of different concentrations. The impact of solvent/dispersion media was probed by preparing films from two different types of Nafion dispersions—IPA-diluted dispersion and Nafion-in-water dispersion. The thickness of films was ascertained by three different techniques: variable angle spectroscopic ellipsometry (VASE), atomic force microscopy (AFM), and X-ray…

    Self-assembled Nafion films of varying thickness were generated on SiO2 terminated silicon wafer by immersion in Nafion dispersions of different concentrations. The impact of solvent/dispersion media was probed by preparing films from two different types of Nafion dispersions—IPA-diluted dispersion and Nafion-in-water dispersion. The thickness of films was ascertained by three different techniques: variable angle spectroscopic ellipsometry (VASE), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). The three techniques yielded consistent nominal thicknesses of 4, 10, 30, 55, 75, 110, 160, and 300 nm for films self-assembled from IPA-diluted Nafion dispersions of concentrations 0.1, 0.25, 0.5, 1.0, 1.5, 2.0, 3.0, and 5.0 wt %, respectively. Films generated from 0.25–5.0 wt % Nafion-in-water dispersions generated comparable thicknesses. An interesting finding of our work is the observation of bimodal surface wettability, investigated by water contact angle. The sub-55 nm films were found to exhibit hydrophilic surface whereas the thicker films showed hydrophobic surface similar to those reported for Nafion membranes. Employing XDLVO theory, surface energies of the hydrophobic, 160 nm film was found to be similar to that reported for Nafion membrane whereas those for the hydrophilic 4 nm film yielded high electron-accepting/proton-donating parameters resulting in an enhanced surface polarity. It can be concluded that the structure and properties of the ultrathin (<55 nm) Nafion films are distinct from those of the thicker (but still submicrometer) films, which are likely similar to those of the well-studied Nafion membranes. No significant effect of dispersion type was observed for 10–300 nm thick films.

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  • Distributed Recycling of Waste Polymer into Reprap Feedstock

    Department of Mechanical and Materials Engineering, Queen's University. Rapid Prototyping Journal

    Purpose – A low-cost, open source, self-replicating rapid prototyper (RepRap) has been developed, which greatly expands the potential user base of rapid prototypers. The operating cost of the RepRap can be further reduced using waste polymers as feedstock. Centralized recycling of polymers is often uneconomic and energy intensive due to transportation embodied energy. The purpose of this paper is to provide a proof of concept for high-value recycling of waste polymers at distributed creation…

    Purpose – A low-cost, open source, self-replicating rapid prototyper (RepRap) has been developed, which greatly expands the potential user base of rapid prototypers. The operating cost of the RepRap can be further reduced using waste polymers as feedstock. Centralized recycling of polymers is often uneconomic and energy intensive due to transportation embodied energy. The purpose of this paper is to provide a proof of concept for high-value recycling of waste polymers at distributed creation sites.

    Design/methodology/approach – Previous designs of waste plastic extruders (also known as RecycleBots) were evaluated using a weighted evaluation matrix. An updated design was completed and the description and analysis of the design is presented including component summary, testing procedures, a basic life cycle analysis and extrusion results. The filament was tested for consistency of density and diameter while quantifying electricity consumption.

    Findings – Filament was successfully extruded at an average rate of 90?mm/min and used to print parts. The filament averaged 2.805?mm diameter with 87 per cent of samples between 2.540?mm and 3.081?mm. The average mass was 0.564?g/100?mm length. Energy use was 0.06?kWh/m.

    Practical implications – The success of the RecycleBot further reduces RepRap operating costs, which enables distributed in-home, value added, plastic recycling. This has implications for municipal waste management programs, as in-home recycling could reduce cost and greenhouse gas emissions associated with waste collection and transportation, as well as the environmental impact of manufacturing custom plastic parts.

    Originality/value – This paper reports on the first technical evaluation of a feedstock filament for the RepRap from waste plastic material made in a distributed recycling device.

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  • A new method to determine the effects of hydrodynamic surface coatings on the snow shedding effectiveness of solar photovoltaic modules

    Solar Energy Materials and Solar Cells

    As solar photovoltaic (PV) installations have become more common in regions that experience substantial snowfall, losses in energy production due to snow coverage have grown in concern. Several post-production surface coatings have been proposed to enhance snow shedding to reduce these snow related losses. In this paper, a novel methodology is developed to determine the effectiveness of a snow clearing from a PV module and is used to evaluate the snow shedding effectiveness of any module…

    As solar photovoltaic (PV) installations have become more common in regions that experience substantial snowfall, losses in energy production due to snow coverage have grown in concern. Several post-production surface coatings have been proposed to enhance snow shedding to reduce these snow related losses. In this paper, a novel methodology is developed to determine the effectiveness of a snow clearing from a PV module and is used to evaluate the snow shedding effectiveness of any module surface treatment. Measured PV output is compared to modeled PV output in a generalizable method that allows for the determination of the length of time a panel is covered with snowfall using electrical performance data. This model accounts for module degradation during long-term outdoor testing and other external factors effecting performance, such as persistent soiling losses. This methodology was tested on modules that had one of four hydrodyanmic surface coatings, as well as one module with a prismatic glass front in order to determine the snow clearing effectiveness of these surfaces as compared to conventional plain glass. The methodology was validated, but the surface coatings tested did not have an appreciable positive effect on snow clearance, and in some cases tended to impede the shedding of snow. The physical mechanisms responsible for the results are discussed.

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  • Life-cycle economic analysis of distributed manufacturing with open-source 3-D printers

    Mechatronics

    The recent development of open-source 3-D printers (RepRaps) makes scaling of distributed additive-based manufacturing of high-value objects technically feasible and offers the potential for widespread proliferation of mechatronics education and participation. RepRaps have been demonstrated for conventional prototyping and engineering, customizing scientific equipment, and appropriate technology-related manufacturing for sustainable development. However, in order for this technology to…

    The recent development of open-source 3-D printers (RepRaps) makes scaling of distributed additive-based manufacturing of high-value objects technically feasible and offers the potential for widespread proliferation of mechatronics education and participation. RepRaps have been demonstrated for conventional prototyping and engineering, customizing scientific equipment, and appropriate technology-related manufacturing for sustainable development. However, in order for this technology to proliferate like 2-D electronic printers have, it must be economically viable for a typical household. A new low-cost RepRap is described and the costs of materials and time to construct it are quantified. The economic costs of a selection of 20 open-source printable designs (representing less than 0.02% of those available), are typical of products that a household might purchase, are quantified for print time, energy, and filament consumption and compared to low and high Internet market prices for similar products without shipping costs. The results show that even making the extremely conservative assumption that the household would only use the printer to make the selected 20 products a year the avoided purchase cost savings would range from about $300 to $2000/year. Assuming the 25 h of necessary printing for the selected products is evenly distributed throughout the year these savings provide a simple payback time for the RepRap in 4 months to 2 years and provide an ROI between >200% and >40%. It appears clear that as RepRaps improve in reliability, continue to decline in cost and both the number and assumed utility of open-source designs continues growing exponentially, open-source 3-D printers will become a mass-market mechatronic device.

    Press coverage & further details: http://www.appropedia.org/Life-cycle_economic_analysis_of_distributed_manufacturing_with_open-source_3-D_printers

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  • Open-Source Colorimeter

    Sensors

    The high cost of what have historically been sophisticated research-related sensors and tools has limited their adoption to a relatively small group of well-funded researchers. This paper provides a methodology for applying an open-source approach to design and development of a colorimeter. A 3-D printable, open-source colorimeter utilizing only open-source hardware and software solutions and readily available discrete components is discussed and its performance compared to a commercial…

    The high cost of what have historically been sophisticated research-related sensors and tools has limited their adoption to a relatively small group of well-funded researchers. This paper provides a methodology for applying an open-source approach to design and development of a colorimeter. A 3-D printable, open-source colorimeter utilizing only open-source hardware and software solutions and readily available discrete components is discussed and its performance compared to a commercial portable colorimeter. Performance is evaluated with commercial vials prepared for the closed reflux chemical oxygen demand (COD) method. This approach reduced the cost of reliable closed reflux COD by two orders of magnitude making it an economic alternative for the vast majority of potential users. The open-source colorimeter demonstrated good reproducibility and serves as a platform for further development and derivation of the design for other, similar purposes such as nephelometry. This approach promises unprecedented access to sophisticated instrumentation based on low-cost sensors by those most in need of it, under-developed and developing world laboratories.

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  • Open-Source Lab: How to Build Your Own Hardware and Reduce Research Costs

    Elsevier

    This book details the development of the free and open-source hardware revolution. The combination of open-source 3D printing and open-source microcontrollers running on free software enables scientists, engineers, and lab personnel in every discipline to develop powerful research tools at unprecedented low costs.

    After reading Open-Source Lab, you will be able to:

    >Lower equipment costs by making your own hardware
    >Build open-source hardware for scientific…

    This book details the development of the free and open-source hardware revolution. The combination of open-source 3D printing and open-source microcontrollers running on free software enables scientists, engineers, and lab personnel in every discipline to develop powerful research tools at unprecedented low costs.

    After reading Open-Source Lab, you will be able to:

    >Lower equipment costs by making your own hardware
    >Build open-source hardware for scientific research
    >Actively participate in a community in which scientific results are more easily replicated and cited

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  • The effect of spectral albedo on amorphous silicon and crystalline silicon solar photovoltaic device performance

    Solar Energy

    Ground reflected energy can have a large effect on the performance of some photovoltaic systems. This paper explores the effects of spectral shift on the effective irradiance from ground reflection, and its effects on system performance.

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  • The effects of snowfall on solar photovoltaic performance

    Solar Energy

    Solar photovoltaic (PV) systems are frequently installed in climates with significant snowfall. To better understand the effects of snowfall on the performance of PV systems, a multi-angle, multi-technology PV system was commissioned and monitored over two winters. A novel methodology was introduced and validated with this system, which allows for the determination of snowfall losses from time-series performance data with correlated meteorological observations down to a 5-min resolution. In…

    Solar photovoltaic (PV) systems are frequently installed in climates with significant snowfall. To better understand the effects of snowfall on the performance of PV systems, a multi-angle, multi-technology PV system was commissioned and monitored over two winters. A novel methodology was introduced and validated with this system, which allows for the determination of snowfall losses from time-series performance data with correlated meteorological observations down to a 5-min resolution. In addition, a new method for determining the probability distribution of snow deposition on a module from image data was developed. It was found that the losses due to snowfall are dependent on the angle and technology being considered and the effects of increased albedo in the surroundings of a PV system can increase expected yields, particularly in the case of high tilt angle systems. Existing methods for predicting losses due to snowfall were investigated, and were found to provide overly conservative estimates of snow losses. Overall the results show that the proper assessment of snow related losses can help improve system performance and maintenance. It is concluded that proper characterization of the snowfall effect on PV system performance can influence better systems optimization for climates experiencing snowfall.

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  • Life cycle analysis of silane recycling in amorphous silicon-based solar photovoltaic manufacturing

    Resources, Conservation and Recycling

    Amorphous silicon (a-Si:H)-based solar cells have the lowest ecological impact of photovoltaic (PV) materials. In order to continue to improve the environmental performance of PV manufacturing using proposed industrial symbiosis techniques, this paper performs a life cycle analysis (LCA) on both conventional 1-GW scaled a-Si:H-based single junction and a-Si:H/microcrystalline-Si:H tandem cell solar PV manufacturing plants and such plants coupled to silane recycling plants. Both the energy…

    Amorphous silicon (a-Si:H)-based solar cells have the lowest ecological impact of photovoltaic (PV) materials. In order to continue to improve the environmental performance of PV manufacturing using proposed industrial symbiosis techniques, this paper performs a life cycle analysis (LCA) on both conventional 1-GW scaled a-Si:H-based single junction and a-Si:H/microcrystalline-Si:H tandem cell solar PV manufacturing plants and such plants coupled to silane recycling plants. Both the energy consumed and greenhouse gas emissions are tracked in the LCA, then silane gas is reused in the manufacturing process rather than standard waste combustion. Using a recycling process that results in a silane loss of only 17% instead of conventional processing that loses 85% silane, results in an energy savings of 81,700 GJ and prevents 4400 tons of CO2 from being released into the atmosphere per year for the single junction plant. Due to the increased use of silane for the relatively thick microcrystalline-Si:H layers in the tandem junction plants, the savings are even more substantial – 290,000 GJ of energy savings and 15.6 million kg of CO2 eq. emission reductions per year. This recycling process reduces the cost of raw silane by 68%, or approximately $22.6 million per year for a 1-GW a-Si:H-based PV production facility and over $79 million per year for tandem manufacturing. The results are discussed and conclusions are drawn about the technical feasibility and environmental benefits of silane recycling in an eco-industrial park centered around a-Si:H-based PV manufacturing plants.

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  • The effect of hybrid photovoltaic thermal device operating conditions on intrinsic layer thickness optimization of hydrogenated amorphous silicon solar cells

    Elsevier - Solar Energy

    Historically, the design of hybrid solar photovoltaic thermal (PVT) systems has focused on cooling crystalline silicon (c-Si)-based photovoltaic (PV) devices to avoid temperature-related losses. This approach neglects the associated performance losses in the thermal system and leads to a decrease in the overall exergy of the system. Consequently, this paper explores the use of hydrogenated amorphous silicon (a-Si:H) as an absorber material for PVT in an effort to maintain higher and more…

    Historically, the design of hybrid solar photovoltaic thermal (PVT) systems has focused on cooling crystalline silicon (c-Si)-based photovoltaic (PV) devices to avoid temperature-related losses. This approach neglects the associated performance losses in the thermal system and leads to a decrease in the overall exergy of the system. Consequently, this paper explores the use of hydrogenated amorphous silicon (a-Si:H) as an absorber material for PVT in an effort to maintain higher and more favorable operating temperatures for the thermal system. Amorphous silicon not only has a smaller temperature coefficient than c-Si, but also can display improved PV performance over extended periods of higher temperatures by annealing out defect states from the Staebler–Wronski effect. In order to determine the potential improvements in a-Si:H PV performance associated with increased thicknesses of the i-layers made possible by higher operating temperatures, a-Si:H PV cells were tested under 1 sun illumination (AM1.5) at temperatures of 25 ?C (STC), 50 ?C (representative PV operating conditions), and 90 ?C (representative PVT operating conditions). PV cells with an i-layer thicknesses of 420, 630 and 840 nm were evaluated at each temperature. Results show that operating a-Si:H-based PV at 90 ?C, with thicker i-layers than the cells currently used in commercial production, provided a greater power output compared to the thinner cells operating at either PV or PVT operating
    temperatures. These results indicate that incorporating a-Si:H as the absorber material in a PVT system can improve the thermal performance, while simultaneously improving the electrical performance of a-Si:H-based PV.

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  • Optimizing the Solar Water Disinfection Method by Decreasing Turbidity with NaCl

    Journal of Water, Sanitation and Hygiene for Development

    Solar water disinfection (SODIS) has proven to be effective at reducing diarrheal incidence in epidemiological intervention studies. However, the SODIS method is limited to waters of low turbidity (<30 NTU). This study investigates the use of common table salt (NaCl) to reduce the turbidity of water containing suspended colloidal clay particles for use in the SODIS method. Three representative clays found in tropical soils (kaolinite, illite and bentonite) were tested at three levels of…

    Solar water disinfection (SODIS) has proven to be effective at reducing diarrheal incidence in epidemiological intervention studies. However, the SODIS method is limited to waters of low turbidity (<30 NTU). This study investigates the use of common table salt (NaCl) to reduce the turbidity of water containing suspended colloidal clay particles for use in the SODIS method. Three representative clays found in tropical soils (kaolinite, illite and bentonite) were tested at three levels of turbidity (50, 100 and 200 NTU) for their flocculating behavior with multiple NaCl concentrations to find the optimum. Supernatants were tested for sodium concentration for comparison against health and taste thresholds. Results show that unlike kaolinite and illite, pure bentonite solutions were shown to be very responsive to NaCl and produced supernatants with as low as 4 NTU (98% particle removal efficiency). This study has shown that NaCl, in combination with high-activity clay particles in solution, may effectively reduce turbidity to levels suitable for SODIS treatment, thereby expanding the number of people who can utilize the technology effectively.

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  • Analytical model for the optical functions of indium gallium nitride with application to thin film solar photovoltaic cells

    Materials Science and Engineering: B, 177, 239-244 (2012).

    This paper presents the preliminary results of optical characterization using spectroscopic ellipsometry of wurtzite indium gallium nitride (InGaN) thin films with medium indium content (0.38 < x < 0.68) that were deposited on silicon dioxide using plasma-enhanced evaporation. A Kramers–Kronig consistent parametric analytical model using Gaussian oscillators to describe the absorption spectra has been developed to extract the real and imaginary components of the dielectric function (ɛ1…

    This paper presents the preliminary results of optical characterization using spectroscopic ellipsometry of wurtzite indium gallium nitride (InGaN) thin films with medium indium content (0.38 < x < 0.68) that were deposited on silicon dioxide using plasma-enhanced evaporation. A Kramers–Kronig consistent parametric analytical model using Gaussian oscillators to describe the absorption spectra has been developed to extract the real and imaginary components of the dielectric function (ɛ1, ɛ2) of InGaN films. Scanning electron microscope (SEM) images are presented to examine film microstructure and verify film thicknesses determined from ellipsometry modeling. This fitting procedure, model, and parameters can be employed in the future to extract physical parameters from ellipsometric data from other InGaN films.

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  • Effects on Amorphous Silicon Photovoltaic Performance from High-temperature Annealing Pulses in Photovoltaic Thermal Hybrid Devices

    Elsevier

    There is a renewed interest in photovoltaic solar thermal (PVT) hybrid systems, which harvest solar energy for heat and electricity. Typically, a main focus of a PVT system is to cool the photovoltaic (PV) cells to improve the electrical performance; however, this causes the thermal component to under-perform compared to a solar thermal collector. The low temperature coefficients of amorphous silicon (a-Si:H) allow the PV cells to be operated at high temperatures, which are a potential…

    There is a renewed interest in photovoltaic solar thermal (PVT) hybrid systems, which harvest solar energy for heat and electricity. Typically, a main focus of a PVT system is to cool the photovoltaic (PV) cells to improve the electrical performance; however, this causes the thermal component to under-perform compared to a solar thermal collector. The low temperature coefficients of amorphous silicon (a-Si:H) allow the PV cells to be operated at high temperatures, which are a potential candidate for a more symbiotic PVT system. The fundamental challenge of a-Si:H PV is light-induced degradation known as the Staebler–Wronski effect (SWE). Fortunately, SWE is reversible and the a-Si:H PV efficiency can be returned to its initial state if the cell is annealed. Thus an opportunity exists to deposit a-Si:H directly on the solar thermal absorber plate where the cells could reach the high temperatures required for annealing.

    In this study, this opportunity is explored experimentally. First a-Si:H PV cells were annealed for 1 h at 100 °C on a 12 h cycle and for the remaining time the cells were degraded at 50 °C in order to simulate stagnation of a PVT system for 1 h once a day. It was found when comparing the cells after stabilization at normal 50 °C degradation that this annealing sequence resulted in a 10.6% energy gain when compared to a cell that was only degraded at 50 °C.

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  • Building Research Equipment with Free, Open-Source Hardware.

    Science 337 (6100): 1303–1304.

    Most experimental research projects are executed with a combination of purchased hardware equipment, which may be modified in the laboratory and custom single-built equipment fabricated inhouse. However, the computer software that helps design and execute experiments and analyze data has an additional source: It can also be free and open-source software (FOSS). FOSS has the advantage that the code is openly available for modification and is also often free of charge. In the past, customizing…

    Most experimental research projects are executed with a combination of purchased hardware equipment, which may be modified in the laboratory and custom single-built equipment fabricated inhouse. However, the computer software that helps design and execute experiments and analyze data has an additional source: It can also be free and open-source software (FOSS). FOSS has the advantage that the code is openly available for modification and is also often free of charge. In the past, customizing software has been much easier than custom-building equipment, which often can be quite costly because fabrication requires the skills of machinists, glassblowers, technicians, or outside suppliers. However, the open-source paradigm is now enabling creation of open-source scientific hardware by combining 3D printing with open-source microcontrollers running on FOSS. These developments are illustrated below by several examples of equipment fabrication that can better meet particular specifications at substantially lower overall costs.

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  • Distributed Recycling of Post-Consumer Plastic Waste in Rural Areas

    MRS Online Proceedings Library

    Although the environmental benefits of recycling plastics are well established and most geographic locations within the U.S. offer some plastic recycling, recycling rates are often low. Low recycling rates are often observed in conventional centralized recycling plants due to the challenge of collection and transportation for high-volume low-weight polymers. The recycling rates decline further when low population density, rural and relatively isolated communities are investigated because of the…

    Although the environmental benefits of recycling plastics are well established and most geographic locations within the U.S. offer some plastic recycling, recycling rates are often low. Low recycling rates are often observed in conventional centralized recycling plants due to the challenge of collection and transportation for high-volume low-weight polymers. The recycling rates decline further when low population density, rural and relatively isolated communities are investigated because of the distance to recycling centers makes recycling difficult and both economically and energetically inefficient. The recent development of a class of open source hardware tools (e.g. RecycleBots) able to convert post-consumer plastic waste to polymer filament for 3-D printing offer a means to increase recycling rates by enabling distributed recycling. In addition, to reducing the amount of plastic disposed of in landfills, distributed recycling may also provide low-income families a means to supplement their income with domestic production of small plastic goods. This study investigates the environmental impacts of polymer recycling. A life-cycle analysis (LCA) for centralized plastic recycling is compared to the implementation of distributed recycling in rural areas. Environmental impact of both recycling scenarios is quantified in terms of energy use per unit mass of recycled plastic. A sensitivity analysis is used to determine the environmental impacts of both systems as a function of distance to recycling centers. The results of this LCA study indicate that distributed recycling of HDPE for rural regions is energetically favorable to either using virgin resin or conventional recycling processes. This study indicates that the technical progress in solar photovoltaic devices, open-source 3-D printing and polymer filament extrusion have made distributed polymer recycling and upcycling technically viable.

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  • Expanded Microchannel Heat Exchanger: Design, Fabrication, and Preliminary Experimental Test

    Proceedings of the Institution of Mechanical Engineers, Part A: Journal of Power and Energy

    This paper first reviews non-traditional heat exchanger geometry, laser welding, practical issues with microchannel heat exchangers, and high effectiveness heat exchangers. Existing microchannel heat exchangers have low material costs, but high manufacturing costs. This paper presents a new expanded microchannel heat exchanger design and accompanying continuous manufacturing technique for potential low-cost production. Polymer heat exchangers have the potential for high effectiveness. The paper…

    This paper first reviews non-traditional heat exchanger geometry, laser welding, practical issues with microchannel heat exchangers, and high effectiveness heat exchangers. Existing microchannel heat exchangers have low material costs, but high manufacturing costs. This paper presents a new expanded microchannel heat exchanger design and accompanying continuous manufacturing technique for potential low-cost production. Polymer heat exchangers have the potential for high effectiveness. The paper discusses one possible joining method - a new type of laser welding named "forward conduction welding," used to fabricate the prototype. The expanded heat exchanger has the potential to have counter-flow, cross-flow, or parallel-flow configurations, be used for all types of fluids, and be made of polymers, metals, or polymer-ceramic precursors. The cost and ineffectiveness reduction may be an order of magnitude or more, saving a large fraction of primary energy. The measured effectiveness of the prototype with 28 micron thick black low density polyethylene walls and counterflow, water-to-water heat transfer in 2 mm channels was 72%, but multiple low-cost stages could realize the potential of higher effectiveness.

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  • Open-Source Development of Solar Photovoltaic Technology

    The rise of solar photovoltaic (PV) technology as a driver of rural electrification in the developing world and a contributor to climate change mitigation suggests that innovations enhancing PV efficiency and scalability could make considerable strides in reducing both poverty and greenhouse gas emissions. Open-source software development has proven to produce reliable and innovative computer code at lower costs than proprietary software through sharing development responsibility with a large…

    The rise of solar photovoltaic (PV) technology as a driver of rural electrification in the developing world and a contributor to climate change mitigation suggests that innovations enhancing PV efficiency and scalability could make considerable strides in reducing both poverty and greenhouse gas emissions. Open-source software development has proven to produce reliable and innovative computer code at lower costs than proprietary software through sharing development responsibility with a large community of invested individuals. Concepts of open-source design have been applied to other fields in an attempt to reap the same benefits realized within software development; however, applying open-source strategies to solar PV research is uncommon. This paper reviews and examines how open-source design can be utilized to catalyze rapid innovation in the PV industry. The results show how successful open design and development methods can be created and utilized by identifying business models that provide PV researchers, turnkey suppliers and solar PV module manufacturers with the opportunity to utilize open-source design principles to accelerate innovation.

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  • Renewable Energy Policies and Programs in Nunavut: Perspectives from the Federal and Territorial Governments

    Arctic Institute of North America (Vol 65(4))

    Nunavut, the youngest Canadian territory, has developed a complete dependence on diesel-generated electricity over the last 50 years, which has led to environmental and economic stress on the territory. However, renewable energy technologies (RETs) could provide substantial electricity to communities, thereby reducing the use of diesel fuel. This study explored the perspectives of government policy-makers, northern energy consultants, and NGOs in order to understand the current status of…

    Nunavut, the youngest Canadian territory, has developed a complete dependence on diesel-generated electricity over the last 50 years, which has led to environmental and economic stress on the territory. However, renewable energy technologies (RETs) could provide substantial electricity to communities, thereby reducing the use of diesel fuel. This study explored the perspectives of government policy-makers, northern energy consultants, and NGOs in order to understand the current status of renewable energy policy and development in Nunavut. Challenges identified included capacity gaps within the communities and government, bureaucratic barriers, barriers to financing RET projects, technological uncertainty, and development and infrastructure challenges. Opportunities explored include future RET funding options, strong renewable resources, increased community engagement through partnerships, and increased education opportunities. Respondents also discussed anticipated short- and long-term actions of each department. We recommend the establishment of a clear point of contact within the federal government: a group that would oversee all renewable energy policy and development in Nunavut. The group would also assess the full economic life cycle of renewable electricity to compare its true cost to that of unsubsidized, diesel-generated electricity.

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  • Technical Feasibility of Renewable Electricity Generation in Nunavut

    M.D. Tiwari, A. Vaish (Ed.), Green Energy, River Publishers: Alborg, Denmark, pp. 41-74

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  • A review of solar photovoltaic levelized cost of electricity

    Renewable and Sustainable Energy Reviews

    As the solar photovoltaic (PV) matures, the economic feasibility of PV projects is increasingly being evaluated using the levelized cost of electricity (LCOE) generation in order to be compared to other electricity generation technologies. Unfortunately, there is lack of clarity of reporting assumptions, justifications and degree of completeness in LCOE calculations, which produces widely varying and contradictory results. This paper reviews the methodology of properly calculating the LCOE for…

    As the solar photovoltaic (PV) matures, the economic feasibility of PV projects is increasingly being evaluated using the levelized cost of electricity (LCOE) generation in order to be compared to other electricity generation technologies. Unfortunately, there is lack of clarity of reporting assumptions, justifications and degree of completeness in LCOE calculations, which produces widely varying and contradictory results. This paper reviews the methodology of properly calculating the LCOE for solar PV, correcting the misconceptions made in the assumptions found throughout the literature.
    Open Source: http://www.appropedia.org/Review_of_Solar_Levelized_Cost

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  • Bandgap and Microstructural Engineering of InGaN for Solar Photovoltaic Applications

    ISPlasma 2011 Proceedings, 3rd International Symposium on Advanced Plasma Science

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  • “Understanding the Ionomer Structure and the Proton Conduction Mechanism in PEFC Catalyst Layer: Adsorbed Nafion on Model Substrate”

    ECS Trans., 41, 1393

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  • Effects of Substrate Temperature on Indium Gallium Nitride Nanocolumn Crystal Growth

    Crystal Growth & Design 11 (2), pp 565–568.

    Indium gallium nitride films with nanocolumnar microstructure were deposited with varying indium content and substrate temperatures using plasma-enhanced evaporation on amorphous SiO2 substrates. Field emission scanning electron microscopy and X-ray diffraction results are presented, showing that more crystalline nanocolumnar microstructures can be engineered at lower indium compositions. Nanocolumn diameter and packing factor (void fraction) was found to be highly dependent on substrate…

    Indium gallium nitride films with nanocolumnar microstructure were deposited with varying indium content and substrate temperatures using plasma-enhanced evaporation on amorphous SiO2 substrates. Field emission scanning electron microscopy and X-ray diffraction results are presented, showing that more crystalline nanocolumnar microstructures can be engineered at lower indium compositions. Nanocolumn diameter and packing factor (void fraction) was found to be highly dependent on substrate temperature, with thinner and more closely packed nanocolumns observed at lower substrate temperatures.

    Other authors
    • S. Keating
    • M.G. Urquhart
    • D.V.P. McLaughlin
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  • Institutional-Scale Operational Symbiosis of Photovoltaic and Cogeneration Energy Systems

    International Journal of Environmental Science and Technology 8(1), pp. 31-44.

    Due to the negative environmental effects of fossil fuel combustion, there is a growing interest in both improved efficiency in energy management and a large-scale transition to renewable energy systems. Using both of these strategies, a large institutional-scale hybrid energy system is proposed here, which incorporates both solar photovoltaic energy conversion to supply renewable energy and cogeneration to improve efficiency. In this case, the photovoltaic reduces the run time for the…

    Due to the negative environmental effects of fossil fuel combustion, there is a growing interest in both improved efficiency in energy management and a large-scale transition to renewable energy systems. Using both of these strategies, a large institutional-scale hybrid energy system is proposed here, which incorporates both solar photovoltaic energy conversion to supply renewable energy and cogeneration to improve efficiency. In this case, the photovoltaic reduces the run time for the cogeneration to meet load, particularly in peaking air conditioning times. In turn, however, the cogeneration system is used to provide power back up for the photovoltaic during the night and adverse weather conditions. To illustrate the operational symbiosis between these two technical systems, this study provides a case study of a hybrid photovoltaic and cogeration system for the Taleghani hospital in Tehran. Three design scenarios using only existing technologies for such a hybrid system are considered here:1) single cogeneration + photovoltaic, 2) double cogeneration + photovoltaic, 3) single cogeneration + photovoltaic + storage. Numerical simulations for photovoltaic and cogeneration performance both before and after incorporating improved thermal energy management and high
    efficiency lighting were considered. The results show that the total amount of natural gas required to provide for the hospitals needs could be lowered from the current status by 55 % for scenario 1 and 62 % for both scenarios 2 and 3, respectively. This significant improvement in natural gas consumption illustrates the potential of hybridizing solar photovoltaic systems and cogeneration systems on a large scale.

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    • M. Mostofi
    • A. H. Nosrat
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  • Peer-to-peer financing mechanisms to accelerate renewable energy deployment

    Journal of Sustainable Finance and Investment

    Despite the clear need to reduce greenhouse gas emissions, lack of access to capital and appropriate financing mechanisms has limited the deployment of renewable energy technologies (RETs). Feed-in Tariff (FIT) programs have been used successfully in many countries to make RETs more economically feasible. Unfortunately, the large capital costs of RETs can result in both the slow uptake of FIT programs and incomplete capture of deployment potential. Subsidies are concentrated in financial…

    Despite the clear need to reduce greenhouse gas emissions, lack of access to capital and appropriate financing mechanisms has limited the deployment of renewable energy technologies (RETs). Feed-in Tariff (FIT) programs have been used successfully in many countries to make RETs more economically feasible. Unfortunately, the large capital costs of RETs can result in both the slow uptake of FIT programs and incomplete capture of deployment potential. Subsidies are concentrated in financial institutions rather than the greater population as traditional bank loans are required to fund RET projects. This paper critically analyzes and considers the political, financial and logistical risks of an innovative peer-to-peer financing mechanism. This mechanism has the goal of increasing RET deployment capacity under a FIT program in an effort to equitably distribute both the environmental and economic advantages throughout the entire population. Using the Ontario FIT program as a case study, this article illustrates how the guaranteed income stream from a solar photovoltaic system can be modeled as an investment and how peer-to-peer lending mechanisms can then be used to provide capital for the initial costs. The requirements for and limitations of these types of funding mechanisms for RETs are quantified and discussed and future work to deploy this methodology is described.

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  • The Viability of Spectral Splitting for the Reduction of Recombination Losses in Multi-Bandgap Solar Photovoltaic Devices

    Photons 9(1), pp. 53-55.

    As the search intensifies to produce low-cost high-efficiency solar photovoltaic cells, several device designs have been proposed to split the solar spectrum and focus only photons of a bandgap appropriate for a given absorber layer in a sub-cell or graded bandgap cell. The intention of such designs is to decrease the electrical path length of charge carriers and the concomitant recombination losses observed in conventional tandem multi-bandgap devices. This article explores the viability of…

    As the search intensifies to produce low-cost high-efficiency solar photovoltaic cells, several device designs have been proposed to split the solar spectrum and focus only photons of a bandgap appropriate for a given absorber layer in a sub-cell or graded bandgap cell. The intention of such designs is to decrease the electrical path length of charge carriers and the concomitant recombination losses observed in conventional tandem multi-bandgap devices. This article explores the viability of such spectral splitting photovoltaic designs by investigating amorphous silicon and microcrystalline silicon tandem and individual cells using numerical simulation with D-AMPS.

    Other authors
    • M. Pathak
    • F. Rubinelli
  • Leveraging Photovoltaic Technology for Sustainable Development in Ontario's First Nations Communities

    Journal of Sustainable Development

    The Ontario feed-in tariff (FIT) for solar photovoltaic (PV) technology has provided Ontario's Aboriginal communities with an opportunity to i) weaken the cycle of poverty; ii) directly counteract climate change by producing renewable energy; and iii) become more self-sufficient. This paper critically analyzes the technical, cultural, and economic viability of leveraging the FIT for PV to provide green electricity and revenue to assist First Nations communities in sustainable development. A…

    The Ontario feed-in tariff (FIT) for solar photovoltaic (PV) technology has provided Ontario's Aboriginal communities with an opportunity to i) weaken the cycle of poverty; ii) directly counteract climate change by producing renewable energy; and iii) become more self-sufficient. This paper critically analyzes the technical, cultural, and economic viability of leveraging the FIT for PV to provide green electricity and revenue to assist First Nations communities in sustainable development. A generalized free GIS-energy-based protocol was developed to determine the PV potential for Aboriginal communities. This model was applied to a case study of the Constance Lake First Nations community and an economic analysis showed financially-viable rates of return over 20 years. By generalizing these findings to Ontario, the potential PV deployment on First Nation rooftops alone is over 200MW, which clearly provides an opportunity for developing pride associated with owning a community-led, environmentally beneficial, local energy project.

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  • 3-D Printing of Open Source Appropriate Technologies for Self-Directed Sustainable Development

    Journal of Sustainable Development

    The technological evolution of the 3-D printer, widespread internet access and inexpensive computing has made a new means of open design capable of accelerating self-directed sustainable development. This study critically examines how open source 3-D printers, such as the RepRap and Fab@home, enable the use of designs in the public domain to fabricate open source appropriate technology (OSAT), which are easily and economically made from readily available resources by local communities to meet…

    The technological evolution of the 3-D printer, widespread internet access and inexpensive computing has made a new means of open design capable of accelerating self-directed sustainable development. This study critically examines how open source 3-D printers, such as the RepRap and Fab@home, enable the use of designs in the public domain to fabricate open source appropriate technology (OSAT), which are easily and economically made from readily available resources by local communities to meet their needs. The current capabilities of open source 3-D printers is reviewed and a new classification scheme is proposed for OSATs that are technically feasible and economically viable for production. Then, a methodology for quantifying the properties of printed parts and a research trajectory is outlined to extend the existing technology to provide complete village-level fabrication of OSATs. Finally, conclusions are drawn on the potential for open source 3-D printers to assist in driving sustainable development.

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  • Open Design-Based Strategies to Enhance Appropriate Technology Development

    National Collegiate Inventors and Innovators Alliance 14th Annual Conference Proceedings - Open

    Explores how open sharing of designs, specifications, and technical information can enhance effectiveness, widespread use, and innovation of appropriate technologies (technologies that are culturally, environmentally, and economically appropriate, and feasible to construct and use for people anywhere in the world).

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  • Producer Responsibility and Recycling Solar Photovoltaic Modules

    Energy Policy, 38:11, 7041-7047

    Rapid expansion of the solar photovoltaic (PV) industry is quickly causing solar to play a growing importance in the energy mix of the world. Over the full life cycle, although to a smaller degree than traditional energy sources, PV also creates solid waste. This paper examines the potential need for PV recycling policies by analyzing existing recycling protocols for the five major types of commercialized PV materials. The amount of recoverable semiconductor material and glass in a 1 m2 area…

    Rapid expansion of the solar photovoltaic (PV) industry is quickly causing solar to play a growing importance in the energy mix of the world. Over the full life cycle, although to a smaller degree than traditional energy sources, PV also creates solid waste. This paper examines the potential need for PV recycling policies by analyzing existing recycling protocols for the five major types of commercialized PV materials. The amount of recoverable semiconductor material and glass in a 1 m2 area solar module for the five types of cells is quantified both physically and the profit potential of recycling is determined. The cost of landfill disposal of the whole solar module, including the glass and semiconductor was also determined for each type of solar module. It was found that the economic motivation to recycle most PV modules is unfavorable without appropriate policies. Results are discussed on the need to regulate for appropriate energy and environmental policy in the PV manufacturing industry particularly for PV containing hazardous materials. The results demonstrate the need to encourage producer responsibility not only in the PV manufacturing sector, but also the entire energy
    industry.

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  • Utilization of Virtual Globes for Open Source Industrial Symbiosis

    Open Environmental Sciences

    The paper showed examples of how Virtual Globes such as Google Earth can be used to map sources of industrial waste, and identify potential reuses and synergies.

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  • Energy services companies as a component of a conprehensive university sustatinability strategy.

    International Journal of Sustainability in Higher Education, 7(1), pp. 16-33.

    The sustainability deficit observed in modern universities is not necessary to fulfill the education, research, or administrative functions of the university system, because a vast quantity of natural resources are currently wasted. The current waste thus provides a large number of opportunities to improve environmental stewardship while reducing operating costs. Guaranteed energy savings programs (GESPs), which utilize the technical and financial expertise of energy service companies (ESCOs)…

    The sustainability deficit observed in modern universities is not necessary to fulfill the education, research, or administrative functions of the university system, because a vast quantity of natural resources are currently wasted. The current waste thus provides a large number of opportunities to improve environmental stewardship while reducing operating costs. Guaranteed energy savings programs (GESPs), which utilize the technical and financial expertise of energy service companies (ESCOs), provide a means to capitalize on these opportunities to move universities towards sustainability. The guaranteed savings from energy conservation measures provide more than sufficient funds to service loan payments each year for the capital needed to make efficiency improvements and generally completely pay for themselves in ten years or less. Energy savings projects are win-win situations, addressing both ecological and economic stewardship. The utilization of ESCOs can accelerate the implementation of energy savings projects and garner institutional support for sustainability initiatives. This paper focuses on the best practices of a comprehensive Environmental Stewardship Strategy that includes a GESP to expand a university’s environmental stewardship. The GESP improved the operational efficiency, decreased the ecological footprint, and reduced the operating costs of the University. The environmental and economic benefits and limitations of this approach will be critically analyzed in the context of sustainability with the goal of providing a model for other universities to improve upon.

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    • Laura Little Miller
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  • Community Voices: Perspectives on Renewable Energy in Nunavut

    Arctic Insitute of North America (Vol 66(1))

    Nunavut communities currently depend on imported diesel fuel for virtually all of their energy needs. This dependency not only hinders the ability of communities to be self-sufficient, but also has negative impacts on their environment, health, and social well-being. The current practices waste 65% of the energy created and place a serious economic strain on the society by consuming 20% of the government’s annual budget. Although renewable energy technologies (RETs) could partially offset…

    Nunavut communities currently depend on imported diesel fuel for virtually all of their energy needs. This dependency not only hinders the ability of communities to be self-sufficient, but also has negative impacts on their environment, health, and social well-being. The current practices waste 65% of the energy created and place a serious economic strain on the society by consuming 20% of the government’s annual budget. Although renewable energy technologies (RETs) could partially offset diesel use, there is a lack of sufficient information to mold appropriate policy. This investigation of community perspectives contributes to information needed to develop sustainable energy policies for Nunavut. Open-ended interviews with approximately 10 members from each of three communities were studied using logical analysis, pattern coding, and content analysis. The respondents’ greatest concerns about energy in Nunavut are the impacts of technology on the environment and the economy and the lack of government initiatives to explore RETs. In identifying these concerns, respondents expressed an overwhelming need to protect their land and wildlife, likely stemming from Nunavut’s dominant Inuit culture. Moreover, Nunavummiut generally supported wind and solar power in their community, but greatly opposed hydropower, though some of these views on hydropower might shift if better information were available to residents. Finally, respondents suggested a variety of community-accepted actions that could be used to increase RET expansion in Nunavut. These actions fit into four categories: policy development, economics, suitable RETs, and capacity and knowledge building.

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